2) United States Patent 6a a cy 0) o a @ (66) on 6s) (oo) or US010; POLYMER MATRIX COMPOSITE 315452 25315 (0) Patent No: US 10,253,154 B2 Nosker et al. (45) Date of Patent: *Apr. 9, 2019 U EXFOLIATION METHOD TO cost. 77700 200501) ICATE. A GRAPHENE-REINFORCE! CosL. 79/08 2006.01), (Continved) 5 , (2) Us.cL Applicant: Rutgers, The State University of New C Coax 304 2013.01); 8328 9700 ‘ervey, New Brunswick, NJ (US) (2013.01); Case 828 (2013.01), Caas 720 (2013.01); 08K 3/042 (2017.03), COBL 23706 Inventors: ‘Thomas Nosker, Stockton, NJ (US) e013 01% CORE 203 GOL301y CNBE 2306 Jennifer Lyneh, Franklin Park, NJ (201301): Cost 2716 (201301): CoBr. 2776 (US); Bernard Kear, Whitehowse 2013.01): C081 278 2013.01): COB 33/72 Station, NJ (US); Justin Hendets, (2013.01); Cass 4920 2013.01); Cost S32 Washington, DC (US): Gordon Chu 013.01): C084 61/16 201301), COBL 6700 Summit, NJ (US) (2013.01); C082 69700 2013.01), CoB 7700 2013.01): C081. 77700 2013.01): Cost, 79708, Assignee: RUTGERS, THE STATE (2013.01); Cass 81/04 2013.01); B82¥ 30000 UNIVERSITY OF NEW JERSEY 2013.01) New Brunswick, NJ (US) (58) Field of Classification Search Roe eee crc CCO8K 3/04; C085 3/20; COs 3/201 ‘otice: Subject o any disclaimer, the term ofthis ce application file foe complete seareh histo patent is extended or adjusted under 35 = e a USC. 154(b) by 318 days, 66) References Cited This patent is subject to terminal dis- claimer US. PATENT DOCUMENTS Appl. Nox 14rm84974 602765 4 + 32000 Sugshara Bac Tos PCT Filed: Apr. 18, 2014 6.962431 BL 112005 Laker (Continved) PCT Nos PCTUS2014/034624 POREIGN PATENT DOCUMENTS 5371 XD) (2)Date: Oct. 16, 2018 x lo1si7si6 4 92010 = fats At 220m PCT Pub, No WO2014/172619 PCT Pub. Date: Ot. 23, 2014 Prior Publication Data 20161008355 Comtinved) (OTHER PUBLICATIONS Choudhary, ea: “Plymer'Carbon Nanotube Nanocomposites” Al Mar. 24, 2016 Aug 17.2011, Chaper 4 pp. 6590, Retieved fromthe Internet “if: wwwintechopen com books carbon-nanotubes-plymer nanocomposites polymes-arbor-aanotube-nanocomposites™ Related U.S. Application Data Provisional application No, 61/813,621, filed om Ape. (Coutinved) 18, 2013, Primary Examiner —Viekey Nerongis (14) Attorney, Agent, or Firm —Fox Rothschild LLP Int. : : CosK 04 (2006.01) Rac cuBs 320 (2006.01), on ABSTRACT 328 9700 (2006.01) A. method for forming a graphene-reinforeed-polymer COG 828 (2006.01) matrix composite by distributing graphite microparticles cast 2306 (2006.01) intos molten tennoplssle polymer phase comprising one CSL 24/12 (2006.01) ‘or more molten thermoplastic polymers: ane applying a cost 2506 (2006001) sucowssion of shar ain events to the molten polymer Cost 2706 (2006.01) phase so that the molten polymer phase exfoliates the eae aeae eonsaiy raphone successively with each event, until tearing of COBL 2778 (2006.01) 7 Fi CosL 33/12 (2005.01), COL (2006.01) CosL 58 (2005.01), COB (2006.01) Cost (2005.01) CoB (2006.01) (2006.01) ‘exfoliated multilayer graphene shoots occurs arid produces reactive edges on the multilayer sheets that react ‘with and crost-liak the one or more thermoplastic polymers; where the one or more thermoplastic polymers are selected from thermoplastic polymers subject to UV degradation. 11 Claims, 6 Drawing SheetsUS 10,253,154 B2 Page 2 (1) nec. wo ao12m0099 AL 22012 ce {gooc.o1 WO Goons At 43014 ‘BS2¥ 30/00 (2011.01) Wo 20140172619 AL 102014 wo aoisonars 4301s 650) References Cited wo aoient8mos AL 22016 USS. 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