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Review of Engineering Thermodynamics Universal Balance Equation for Any Extensive Prope ‘Accumulation ansport + generation Iegredtom tr some par stime [eon [Smet -[anorg (cry [S| [ag Rate form [rege [apo] [erro oa Engineog, Univers of Uh Mass Balance + Unsteady balance for CV pie Emde flees + Steady balance for CV (am, de = + Averaged flow pit = p,,Vel,,A= Geof Steox Crema Enginaorng, Jory ef ah Energy Balance e=uehvel" +g heutPv + Unsteady balance for CV + Steady balance for CV Syne Ee) Son net + Balance for closed system [0 = Quer + Wn +W, aE, oro W, AE... at anes * Wine Geet tens, Comical Engaening, Unnerny of US Entropy Balance There is only one form of entropy. + Unsteady balance for CV 5, > 0 ireversible process| mw = 0 Feversible process s,.. <0 impossible process ‘Geo Seon Chere Engineng. Universi of lah Combined Entropy and Energy Balance & du = 5p 50 t= digg = Bay * Bi Big, =~ Pa [fds= aux Pav} or ‘An alternate form follows from the relation d(P0)= PivendP TA « [a 2 Geet Seo Chem Engng, Urner tah Combined Entropy and Energy Balance for Ideal Gases "Paap Tot p, Pe Jas = [Pett IS + Rin las = { (TIS Ring For constant or averaged heat capacities, T, v; T, P, = =2 + Rin-2| = — =2| [58 = eal ge + Rin‘ [48 = Gym Inge Rings where Ty = 247 and ¢,, =0(T) Geot Seas Chamcl Engneerag, Univers of ah

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