Review of Engineering Thermodynamics
Universal Balance Equation for Any Extensive Prope
‘Accumulation
ansport + generation
Iegredtom tr some par stime
[eon [Smet -[anorg (cry [S| [ag
Rate form
[rege [apo]
[erro oa
Engineog, Univers of Uh
Mass Balance
+ Unsteady balance for CV
pie Emde flees
+ Steady balance for CV
(am,
de =
+ Averaged flow
pit = p,,Vel,,A=
Geof Steox Crema
Enginaorng, Jory ef ahEnergy Balance
e=uehvel" +g heutPv
+ Unsteady balance for CV
+ Steady balance for CV
Syne Ee) Son net
+ Balance for closed system
[0 = Quer + Wn
+W,
aE,
oro W, AE...
at anes * Wine
Geet tens, Comical
Engaening, Unnerny of US
Entropy Balance
There is only one form of entropy.
+ Unsteady balance for CV
5, > 0 ireversible process|
mw = 0 Feversible process
s,.. <0 impossible process
‘Geo Seon Chere
Engineng. Universi of lahCombined Entropy and Energy Balance
&
du = 5p 50 t= digg
= Bay * Bi Big, =~ Pa
[fds= aux Pav} or
‘An alternate form follows from the relation
d(P0)= PivendP
TA « [a 2
Geet Seo Chem
Engng, Urner tah
Combined Entropy and Energy Balance
for Ideal Gases
"Paap Tot p, Pe
Jas = [Pett IS + Rin las = { (TIS Ring
For constant or averaged heat capacities,
T, v; T, P,
= =2 + Rin-2| = — =2|
[58 = eal ge + Rin‘ [48 = Gym Inge Rings
where Ty = 247 and ¢,, =0(T)
Geot Seas Chamcl
Engneerag, Univers of ah