R. K. MALIK'S NEWTON CLASSES JEE (MAIN & ADV.), MEDICAL + BOARD, NDA, IX & X Enjoys unparalleled reputation for best results in terms of percentage selection www.newtonclasses.net ATOMIC STRUCTURE [JEE MAIN PREVIOUS YEAR SOLVED PAPER] JEE Main - Ina hydrogen atom, if energy of an electron in ground state is-13.6 eV, then that inthe second excited state is a -151eV) b. 34eV 6.04 eV 4. -136eV [AIEEE 2002] Uncertainty in position of'a minute particle of mass 25 g in spaceiis 10°° m. The uncertainty in its velocity (in mis) a. 21x10 b. 05x10 21x10 4. 05% 10 [AIEEE 2002] Which has the maximum magnetic moment? Mn" eT [AIEEE 2002] J. The number of d-electrons retained in Fe" ion is as bo 63 aa [AIEEE 2003] 5. The orbital angular momentum for an electron revolvingin anorbit is + JIT. This momentum for alectron is a h ah ate & oe 4. Zero (AIEEE 2003) In Bohr series of lines of hydrogen spectrum, third line from the red end corresponds to which one of the following inner orbit jumps ofelectron for Bohr’s orbit in atom of hydrogen a4) b.255 «392 552 [AIEEE 2003) ‘The de Broglie wavelength ofa tennis ball of mass 60 g ‘moving wit a velocity of 10 m/sis approximately a 10" b. 107m 4.10°%m [AIEEE 2003] Which sets correct for an electron in 4f-orbita? mi=-2 0 ms=+% ml=-4 ms=-% mi=s1 0 men+¥ mi=+4 0 ms=+% AIEEE 2004] . The number of electrons with the azimuthal quantum, ‘number = 1 and/=2in ground stat of Cris respectively a. tandS b. 12and 5 © Wand 4. 12and4_ [AIEEE 2004) 10, ‘The wavelength of the radiations emitted, when in a hydrogen atom electron falls from infinity to stationary state, is (Ry = 1.097 x 10" me) a. 9.1 x10 am b. 192mm. e406 nm 4. 91nm [AIEEE 2004] |. Ofthe following outer electronic configurations of toms, ‘the highest oxidation stat is achieved by which one of them a (n-)ont b. (n= dns! © ent @ (ni) dine [AIEEE 2004} Ina multielectron atom, which of the following orbitals described by the three quantum numbers will have the same energy in the absence of magnetic field @ m=10=0,m=0 (i) m=20 (i) n=3b () m=3,1=2,m=0 ‘a. (i) and (i) © (ii) and (iv) (ian Gi 4, (iv) and [AIEEE 2005] 13. Which of he following statement i correct in relation to the hydrogen atom? sorbital slower in energy than 3p-orbital 3p-orbitl is lower in energy than 3d-orbital 3sand 3p-orbitals are oflower energy than 3d-orbitals |. 3sand 3p-orbitalsall have the same energy [AIEEE 2005} Which one of the following sets of ions represents a collection of soclectronie species? a. Lit, Na’, Mg, Cab, K’,Cr Ca, So" c. Bal, se*, Kad. NOR FS [AIEEE 20061 ‘The “spin-only” magnetic moment [in units of Bobr magneton, (i) of Ni in aqueous solution would be: b 284 ao [AIEEE 2006) According to Bohs theory, the angular momentum of an electron in the fifth orbit i a 25h b. Lobe © hi 4. 25h/e [ATE 2006) ‘Uncertainty in the position of an electron (mass = 9.1 « 10° kg) moving with a velocity 300 mvs, accurate up to 0.001% will be: (h = 663 x 10 Js) Office.: 606 , 6” Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.: 0661-2662623, 3836600812, 0507613968 NEWTONCLASSES.NET PERS [LAST 16 YEARS]R. K. MALIK’S NEWTON CLASSE a. 192x10%m © 192x10%m b. 576 10%m 4. 384x107 m [AIEEE 2006] Which of the following sets of quantum numbers represents the highest energy of an atom? a. ne3l= m= l= 412 bo n23,122,m=1s= 912 € n=41=0,m=0,5= 41/2 4 n23,120,m=0,5=412 IATERE 2007] ‘The ionization enthalpy of hydrogen atom is 1.312 x 10 j/mol. The energy required to excite the electron in theatom from #= 110n=2is a. 851%10°Jimol 656% 10°J/mol © 756% 10° Jmol, 9.84% 10° /mol [AIEEE 2008] In an atom, an electron is moving with ¢ speed of ‘600 m/s with an accuracy of 2005 %, Certainy with which the position of the electron canbe located is (h= 6.6 x 10 kg m/s, mass of eletron y= 9.1 10" kg) a 152x10%m 5.10% 10m © 192x107 m 4.384% 107m [AIEEE 2005] Calculate the wavelength (in nanometer) asocited with a proton moving at 1x 10° ms (Mass of proton = 1.67 « 10°” kgand h= 663 x 103) © 0032nm b. 040m «© 25nm 4. 140nm_ [ATEEE 2009], ‘The energy required to break | mol of CI-Cl bonds in Cl, {242 kjfmol. The longest wavelength of ight capable of breaking single I-Cl bond is a. 594mm b. si0am € 700nm 4. 49%am _ (ATEEE2010] Toniraton energy of" is 19.6x 10" Jatom. The energy ofthe frst stationary state (n= 1) of LP" is a 441x 10" Jfatom —b. ~4.41x 10°" atom & -22%10""Yatom —, 882 10" atom [AIEEE 2010] 24, A gas absorbs photon of 355 nm and emits at two ‘wavelengths. Ione ofthe emission ist 680 nm, the other isat a. 1035 b. 25am © 743 1m 4. 518nm [AIEEE 2011] 5. The frequency of light emitted forthe transition n = 4 to ‘of He" is equal to the transition in H atom corresponding to which ofthe following? b.n=2ton=l ton @. n=4t0 [AIEEE 2011] 26. The electrons identified by quantum niambers n and] a Q) n=4, @ @) n=3, can be placed in the order of increasing energy as a 3)<()<@)<)—b ()<(2) 1 eo 5uned 4 2 450144 2 UE Main 2014] . Which of the following isthe energy of a possible excited state of hydrogen? a. 136€V © -34eV b. -68 eV, d. 468eV UEE Main 2015} ST 16 YEARS] asa aris MANY PEOPLE WIN RSs ay tT) TO BE CERTAIN FAILURE. BN a #RKMALIKSNEWTONCLASSES, Office.: 606 , 6" Floor, Hariom Tower, Circular Road, Ranchi, Ph. 0861-2662628, 9696608612, 8607619968, NEWTONCLASSES.NETATOMIC STRUCTURE [JEE MAIN PREVIOUS YEAR SOLVED PAPER] Answer Key JEE MAIN 3. a. 8. 13. 18. 23. 28. Hints and Solutions JEE Main 1a, Second exited state means third energy level PERS [LAST 16 YEARS] 91.15.10 m=91 am = #2110" nfs 11a, $7 satecanbeachicvedby five d-decrons and wo electrons 5 Sea, Maas ive unpaired electrons (12,27 2p, 32 p*ad*)and 12d. Orbital having (+1) posses same energy inthe absence of = has marinsum magnetic moment magnetic eld. Ab. Fes be 2p, 3px 13.4, Subshels ofeach shellin H-atom posses he same enrgyleve 5d. 1-0 fors-orbtl 64. The emsion isn vsble(VIBGYOR) region. Thus, Balmer series thats ether (La there isonly one emission “The tht ine wil be inthe jump fom 5 02. ne pat = 626x101 6:39 5 Ccsrcere in Gox10 10 SP = 16 +2 t8e" (001 soelecronio) Be Boshi 15.b, Ni" has tv unpated letons For! 2. mayne Bab geen hae pha Gaur 1, forp-sbshell 8 Laer eer 16.4. Angulo! monetumofan cron mh alge by 122, for dsubsel v= No.of lectrons = 5 on BC eA unpopulated wasteland.” 606 , 6” Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.: 0651-2662623, 9836608812, 8507613968 NEWTONCLASSES.NET