672972019 (CHEM205-FinalExam-Answers 1 | Which fhe followings NOT biti component of se petromatar? ‘Choose one Aion source 8. mas anahaer C.detecor D. diffraction grating ¥ |The most bund nina spect which ase a ele bundance of 10, referred to he Choose one ‘A. Base peak ¥ 8. Reererce peak €.beteton it Dank coreaion 3 Theat pera of fuerine Greece one a. Is similar to the spectra of bromine and chlorine b. Const font ne peak, since tis monoSotople €: Cons of wo eas, separate byte Da 6. Consists of wo peaks, appearing at 19 Da ard 38 Da Y 4 The vps in ams petra of corn a be atrbted o Choose one a: Loss of lets bss tae sity c:The presence af wo abuncatsopes 6. Alot the stove 5 Caron as putea i Choose one 2. Pelomed exter, with a own spe messed independent b. Performed internally, with a known sample that is prembced with the unknown Unnecessary because the mass detector Is highly stable 6. Both a and b are correct; calbration can be internal or external ¥ The x-axis ofa mass spectrum typeally reports ‘saylordotorg github iofLegacyExams/CHEM/CHEMZ05/CHEMZ0S-FinalExam-Answers. html r8672972019 10 wn (CHEM205-FinalExam-Answers CChoose one Groose 2a. Mass to charge (m2) ratios 4 Parts per milion (ppm) « Wavenumbers (cmt) @, Wavelength (nm) Ifa mass spectra contains peaks at 38 and 37 Da, CChoase one 2 It most likely contains chlorine ¥ b. it can be identified as RbBr «It was analyzed in a gas matrix containing argon 6. it was analyzed in @ gas matrix containing krypton |. MALDI and ES! are CChoase one croose 2 Toten meds coment sed oboe ras b. Detection methods used for spectal fingerprinting «. Separation methods used prior to MS analysis 6. Mass analysis techniques requiring external calibration Tandem mass spectrometers Choose one Choose a. Contain two or mare mass analyzers Can be used for structural studies Can be used for sequencing studies 6.Allof the above ¥ The molecular ion (M+) CChoose one Groose Is the highest molecular weight peak observed in a spectrum % Has an assigned relative abundance of 100 «Represents the parent molecule minus an electron. 6, Both a and c are correct Due to structural stability, the molecular ion peaks are strong in mass spectra of CChoase one 2. alcohols b, aromatics ‘saylordotorg github iofLegacyExams/CHEM/CHEMZ05/CHEMZ0S-FinalExam-Answers. html 208672972019 (CHEM205-FinalExam-Answers alkanes 6. crbonylic adds 12 Timerosighe (TOF) mass analyzers Choose one 2. Allow simultaneous detection ofall species and have unlimited mass ranges X », Measure the time required for anion to travel a known distance, dependent onthe mass ofthe species X «. Require extremely igh vacuum conditions to avoid colisons of ion and are often paired with pubed ionization sources 6. Allofthe above Y 13 Ina mass spectrum of an alcoho, the molecular ion is usally small or non-existent due t© Choose one 2a. Cleavage ofthe hydroxy group Rearrangement of the molecule to form an ester «Cleavage ofthe C-C bond adjacent to the hydroxyl grou 6 Formation of@ dimeric species 14 | Wanalysis ofa ntrogen-containing molecule shows & molecular ion peak with an odd miz ratio Choose one 2. It contains an even numberof rtrogen atoms b, It contains an odd number of nitrogen atoms «.Tthas rearranged via the MeLaferty cearrangement 6. The mass analyzer needs tobe recalibrate; nitrogen containing molecules avays ove an even m/z ratio X 15 Which ofthe fllowing is true about sector mass analyzers? Croose one a. They are inexpensive and compact They have low resolution and senstuty ¢. They are incompatible with ESI and MALDI ionization methods 6. They can detect only low mass ranges 16 (Quadrupole and ion trap mass analyzers iolate ions for analysis by CChoase one Choose 2 Ving te appli voage and aioreqveney potentials b. Accelerating fons through an electric eld Accelerating ions through a magnetic field ‘saylordotorg github iofLegacyExams/CHEM/CHEMZ05/CHEMZ0S-FinalExam-Answers. html 328