Ambition Academy Question paper is solved by Dr.

Ashok Choudhary

Solved Questions of Paper

1. Naturally occurring chlorine is 75.53% Cl35 which has an atomic mass of 34.969 amu and 24.47%
Cl37 which has a mass of 36.966 amu. Calculate the average atomic mass of chlorine-
(A) 35.5 amu (B) 36.5 amu (C) 71 amu (D) 72 amu
Ans. (A)
Sol.
𝐴𝑣𝑒𝑟𝑎𝑔𝑒 𝑎𝑡𝑜𝑚𝑖𝑐 𝑚𝑎𝑠𝑠
[(% 𝑜𝑓 𝐼𝑠𝑡 𝑖𝑠𝑜𝑡𝑜𝑝𝑒 𝑋 𝑖𝑡𝑠 𝑎𝑡𝑜𝑚𝑖𝑐 𝑚𝑎𝑠𝑠) + (% 𝑜𝑓 𝐼𝐼𝑛𝑑 𝑖𝑠𝑜𝑡𝑜𝑝𝑒 𝑋 𝑖𝑡𝑠 𝑎𝑡𝑜𝑚𝑖𝑐 𝑚𝑎𝑠𝑠)]
=
100
= 75.53 x 34.969 24.47 x 36.96
100
= 35.5 amu.
2. How many carbon atoms are present in 0.35 mol of C6H12O6 –
(A) 6.023 X 1023 carbon atoms (B) 1.26 X 1023 carbon atoms
(C) 1.26 X 1024 carbon atoms (D) 6.023 X 1024 carbon atoms
Ans. (C)
Sol. 1 mol of C6H12O6 has = 6 NA atoms of C
0.35 mol of C6H12O6 has
= 6 × 0.35 NA atoms of C
= 2.1 NA atoms
= 2.1 × 6.022 × 1023 = 1.26 × 1024carbon atoms
3. Calculate the mass in gm of 2NA molecules of CO2 –
(A) 22 gm (B) 44 gm (C) 88 gm (D) None of these
Ans. (C)
Sol. NA molecules of CO2 has molecular mass = 44 gm
2NA molecules of CO2 has molecular mass = 44 × 2 = 88 gm.
4. 18gm molecule of glucose contains
(A) 6X1022 gm glucose (B) 6X1023 gm glucose (C) 108 X 1022 gm (D) 108 X 1023gm
glucose glucose
Ans D
18 gm molecule = 18 mole

5. How many years it would take to spend Avogadro’s number of rupees at rate of 1 million rupees in
one second –
(A) 19.098 × 1019 years (B) 19.098 years
(C) 19.098 × 109 years (D) None of these
Ans. (C)
Sol. 106 rupees are spent in 1sec.
1
6.023 X 1023 rupees are spent in 106 𝑋 6.023 𝑋 1023 𝑠𝑒𝑐
1 6.023 𝑋 1023
𝑋 𝑦𝑒𝑎𝑟 𝑜𝑟 𝟏𝟗. 𝟎𝟗𝟖 𝑿 𝟏𝟎𝟗 𝐲𝐞𝐚𝐫𝐬
106 60 𝑋 60 𝑋 24 𝑋 365
6. Calculate number of electron in 5 mol 𝑆𝑂4−2
(A) 150 X 1023 (B) 150 X 1024 (C) 150 X 1025 (D) 150 X 1022
Ans B
 1𝑆𝑂4−2 𝑐𝑜𝑛𝑡𝑎𝑖𝑛𝑠 50 𝑒𝑙𝑒𝑐𝑡𝑟𝑜𝑛
5 mol will contain 50 X 6 X 1023 X5 electron

7. Calculate the number of Cl– and Ca+2 ions in 222 g anhydrous CaCl2.
(A) 2NA ions of Ca+2 4 N ions of Cl– (B) 2NA ions of Cl– & 4N ions of Ca+2
(C) 1NA ions of Ca+2 & 1N ions of Cl– (D) None of these.
Ans. (A)
Sol. mol. wt. of CaCl2 = 111 g
111 g CaCl2 has = NA ions of Ca+2
222g of CaCl2 has = NA X 222/111 = 𝟐𝐍𝐀 𝐢𝐨𝐧𝐬 𝐨𝐟 𝐂𝐚+𝟐 𝐢𝐨𝐧𝐬
Also111 g CaCl2 has = 2NA ions of Cl–
222 g CaCl2 has = 2NA X 222/111 = 𝟒𝐍𝐀 𝐢𝐨𝐧𝐬 𝐨𝐟 𝐂𝐥− 𝐢𝐨𝐧𝐬
8. What is the molecular mass of a substance, each molecule of which contain 9 carbon atom, 13
hydrogen atom and 2.33 X 10-23 g of other component?
Ans. 135.04
Sol. The molecule has C, H and other component.
Mass of 9 C atoms = 12 × 9 = 108 amu
Mass of 13 H atoms = 13 × 1 = 13 amu
2.33 𝑋 1023
Mass of other component = = 14.04𝑎𝑚𝑢
1.66𝑋1024
∴ Total mass of one molecule = 108 + 13 + 14..04 = 135.04 amu
∴ Molar mass of substance = 135.04 gm
9. The density of O2 at 0ºC and 1 atm is 1.429g / litre. The molar volume of gas is -
(A) 22.4 lit. (B) 11.2 lit (C) 33.6 lit (D) 5.6 lit.
Ans. (A)
Sol. 1.429 gm of O2 gas occupies volume = 1 litre.
32
32 gm of O2 gas occupies = 1.429 = 22.4 litre/ mole

10. How many molecules are in 5.23 gm of glucose (C6H12O6) –

(A) 1.65 × 1022 (B) 1.75 × 1022 (C) 1.75 × 1021 (D) None of these
Ans. (B)
Sol. 180 gm glucose has = NA molecules
5.23 𝑋 6.022 𝑋 1023
5.23 gm glucose has = = 1.75 𝑋 1022 𝑚𝑜𝑙𝑒𝑐𝑢𝑙𝑒𝑠
180
11. How many g of S are required to produce 10 moles and 10g of H 2SO4 respectively?
Ans. 320 g, 3.265 g
Sol. 1 mole of H2SO4 has = 32g S
10 mole of H2SO4 has = 32 × 10 = 320 g S
Also, 98g of H2SO4 has = 32 g S
10 g of H2SO4 has = (32 × 10)/98 = 3.265 g S
12. P and Q are two elements which form P2Q3 and PQ2 molecules. If 0.15 moles of P2Q3 and PQ2
weights 15.9 g and 9.3 g, respectively, what are atomic mass of P and Q?
Ans. P = 26, Q = 18
Sol. Let at. mass of P and Q be a and b respectively,
Mol. mass of P2Q3 = 2a + 3b
and Mol. mass of PQ2 = a + 2b
 ∴ (2a + 3b) × 0.15 = 15.9
and (a + 2b) × 0.15 = 9.3
a = 26, b = 18
atomic mass of P = 26
atomic mass of Q = 18
13. In the Haber process 4 mol of ammonia is formed then quantity of nitrogen will be
(A) 16 gm (B) 32 gm (C) 64gm (D) 80gm
Ans C
𝐻𝑎𝑏𝑒𝑟 𝑝𝑟𝑜𝑐𝑒𝑠𝑠; 𝑁2 + 3𝐻2 ⇌ 2𝑁𝐻3
When 1mol nitrogen reacts with 3 mol of hydrogen then 2 mol of ammonia will produce
To produce 4 mol ammonia 2 mol of nitrogen are required
2 mol means 2 X 32 gm nitrogen

14. 1mole CO2 is equal to

(A) 22.4 liter at STP (B) 6.02X1023molecules (C) 44 gm of gas (D) All of these
Ans D
𝑁𝐴 𝑚𝑎𝑠𝑠 𝑣
𝑛= = = 𝑙𝑖𝑡𝑒𝑟 𝑎𝑡 𝑆𝑇𝑃
𝑁 𝑚𝑜𝑙𝑒𝑐𝑢𝑙𝑎𝑟 𝑚𝑎𝑠𝑠 22.4

15. Calculate number of carbon atoms in 18 gm glucose

(A) 36 X 1022 (B) 36 X 1023 (C) 18 X 1022 (D) 18 X1023
Ans A
18 𝑁
𝑛= = ; 𝑁 = 0.1𝑋6𝑋1023 𝑚𝑜𝑙𝑒𝑐𝑢𝑙𝑒𝑠 𝑜𝑓 𝑔𝑙𝑢𝑐𝑜𝑠𝑒
180 𝑁𝐴
Each glucose molecule contain 6 carbon
Number of glucose = 6 X 6 X 1022 atoms
16. Calculate specific density of Na if density of sodium is 0.9 gm/cc
(A) 0.45 gm/cc (B) 0.9 gm/cc (C) 0.45 (D) 0.9
Ans D
𝑑𝑒𝑛𝑠𝑖𝑡𝑦
𝑠𝑝𝑒𝑐𝑖𝑓𝑖𝑐 𝑑𝑒𝑛𝑠𝑖𝑡𝑦 =
𝑑𝑒𝑛𝑠𝑖𝑡𝑦𝑜𝑓𝑤𝑎𝑡𝑒𝑟 𝑎𝑡 4℃
Density of water at 40C = 1gm/cc
Specific density is dimensionless
17. Low of conservation of mass was proposed by
(A) Richter (B) Lavoisier (C) Dalton (D) Proust
Ans A
18. Number of neutrons in 1mole protium (1H1)
(A) 6.023X1023 (B) 6.023X1012 (C) 1 (D) None
Ans D
Neutron is absent in protium
19. Sum of (3.44 + 33.2) is
(A) 36.64 (B) 36.6 (C) 36.640 (D) A and C
Ans B
20. The fraction of total volume occupied by the atom present in a simple cube is
𝜋 𝜋 𝜋 𝜋
(A) 3√2 (B) 4√2 (C) 4 (D) 6
Ans D
4
Volume of a sphere is 𝜋𝑟 3
3
Z for SC = 1
 𝑍 𝑋 𝑣𝑜𝑙𝑢𝑚𝑒 𝑜𝑓 𝑜𝑛𝑒 𝑠𝑝ℎ𝑒𝑟𝑒
𝐹𝑟𝑎𝑐𝑡𝑖𝑜𝑛 =
𝑣𝑜𝑙𝑢𝑚𝑒 𝑜𝑓 𝑐𝑢𝑏𝑒

21. Which of the following FCC structure contains cation in alternate tetrahedral voids
(A) NaCl (B) ZnS (C) Na2O (D) CaF2
Ans B
In ZnS structure S-2 ions are in FCC and Zn+2 ions occupy alternate T.V

22. Silicon doped with arsenic is an example of which type of semiconductor

(A) Intrinsic (B) p type (C) n type (D) p, n type
Ans C
It is an example of doping of N family member in silicon
23. The closet packing sequence ABAB…represents
(A) SC (B) BCC (C) FCC (D) HCP
Ans D
The hexagonal called HCP, the HCP packing has ABABAB…two layer sequence
Where A and B represent the location of the layer, in other words , the thired layer is
exactly above the first layer in HCP
24. Which of the following statement is not true about NaCl structure
(A) Each unit cell contains 4 NaCl molecule
(B) CN of Cl ion is 6
(C) CN of Na ion is 4
(D) Cl ions are in FCC arrangement
Ans C
25. Which of the following statement about amorphous solids is incorrect?
(A) They melt over a range of temperature
(B) They are anisotropic
(C) There is no orderly arrangement of particles
(D) They are rigid and incompressible
Ans B
Amorphous solids are isotropic
26. Due to Frenkel defect, density of ionic solid
(A) Decreases (B) Increases (C) Does not change (D) None
Ans C
In Frenkel defect, ion get only displaced from their original position to interstitial site
27. Iron crystallizes in BCC system with a lattice parameter of 2.861A o. calculate the density of iron in
the BCC system (atomic weight of Fe is 56)
(A) 7.92 gm/cc (B) 8.96 gm/cc (C) 2.78 gm/cc (D) 6.72 gm/cc
Ans A
Value of Z for BCC = 2
Lattice parameter √3 𝑎 = 4𝑟
Volume of cube = a3
Value of a = 2.861 X 10-8 cm
Density
𝑍 𝑀𝑤 2𝑋56
𝑑 = 𝑁 𝑎3 = [{6.023𝑋1023 𝑋(2.861𝑋10−8 )3}] = 7.94 𝑔𝑚/𝑐𝑐
𝐴
28. In Stoichiometric defect, the type of compound exhibit Frenkel defect have/ has
(A) Low coordination
(B) High coordination
(C) Small difference in size of cation and anion
(D) None of these
 Ans A
Frenkel defect occur in compound having low CN and different size of cation and anion
29. On cooling oxygen freezes to dark blue crystalline solid. It is belongs to which of following type of
solid
(A) Covalent solid
(B) Ionic solid
(C) Molecular solid
(D) Metallic solid
Ans C
Solid O2 contains Vander waal attraction
30. Coordination number of Zn in ZnS is
(A) 4 (B) 6 (C) 2 (D) None of these
Ans A
In ZnS structure Zn ions are present in T.V
31. A substance AxBy has FCC lattice in which atoms ‘A’ occupy corners and ‘B’ atoms occupy face
centers. Identify the correct composition of substance A xBy
(A) A3B (B) AB3 (C) A4B3 (D) None of these
Ans B
32. Frenkel and Schottky defect are
(A) Nucleus defect
(B) Non crystal defect
(C) Crystal defect
(D) Nuclear defect
Ans C
33. The crystal system of a compound with unit cell dimensions a= 0.87, b = 0.87, c = 0.504nm and  =
= 900 and  = 1200 is..
(A) Hexagonal
(B) Cubic
(C) Rhombohedral
(D) Orthorhombic
Ans A
34. If Z is number of atoms per unit cell that represent the closest packing sequence ABCABCA..the
number of tetrahedral void in the unit cell is equal to
(A) 4 (B) 6 (C) 8 (D) 12
Ans C
35. Zn converts its melted state to its solid state. It has HCP structure then find out nearest neighbor of
Zn atom
(A) 4 (B) 6 (C) 8 (D) 12
Ans D
36. The Ca+2 and F- are located in CaF2 crystal respectively at face centered cubic lattice points and in..
(A) T.V (B) Half of TV (C) OV (D) Half of OV
Ans A
37. Schottky defect in crystal is observed when…
(A) Equal number of cation and anion are missing from lattice
(B) Density of crystal is increased
(C) An anion leaves its normal site and occupy interstitial site
(D) Unequal number of cation and anion are missing from crystal
Ans A
38. The Ca and F- are located in CaF2 crystal respectively at face centered cubic lattice points and in..
+2

(E) T.V (F) Half of TV (G) OV (H) Half of OV

Ans A
39. Schottky defect in crystal is observed when…
(E) Equal number of cation and anion are missing from lattice
(F) Density of crystal is increased
(G) An anion leaves its normal site and occupy interstitial site
(H) Unequal number of cation and anion are missing from crystal
Ans A
40. Sodium chloride, NaCl usually crystallizes in a face centered cubic lattice. How many ions are in
contact with any single Na+ ion
(A) 1
(B) 4
(C) 6
(D) 8
Ans C
41. Percentage of free space in cubic close packed structure and in body centered packed structure
respectively
(A) 74% and 68%
(B) 30% and 48 %
(C) 26% and 32%
(D) 32% and 26%
Ans C
Hint Packing percent of
FCC is 72% and BCC is 68%
42. Copper crystallize in FCC with a unit cell length of 361pm. What is the radius of copper atom
(A) 157pm
(B) 128pm
(C) 108pm
(D) 181pm
Ans B
Hint In FCC
√2𝑎 = 4𝑟
43. An ionic compound is expected to have tetrahedral structure if r +/r- lies in the range of
(A) 0.414 to 0.732
(B) 0.732 to 1
(C) 0.155 to 0.225
(D) 0.225 to 0.414
Ans D
44. in which of the following crystal alternate tetrahedral voids are occupied
(A) NaCl
(B) ZnS
(C) Na2O
(D) CaF2
Ans B
45. Density of a crystal remain unchanged as a result of
(A) Vacancy defect
(B) Interstitial defect
(C) Schottky defect
(D) Frankel defect
Ans D