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Qf wi Lies Ab 4 UNDERSTANDING LIME CALCINATION KINETICS FOR ENERGY OST REDUCTION. Wicky Moffat and M. RW. Walmsley Prom eA pie CfA Nes aad 16-19 May 2006 ABSTRACT “The cintion of cao bone (ineson ian ngonane ep inthe rene o ft paling hema onthe prsction ofall ae ever nerndg [ibe and ogre nen fens a both pcm ead pri ener ‘se. Fer th reson fendenentalimesigton io le ciion aa or te prpoe of lnproving in efisencywasunderen Iinporaat kn eto tt apply o cao carbonate canon ae svewe The efecto tcl te an hs ngs Secon rt te ecru exten phn, Dineionss vale whch dense betwen mas tant, bet ander ad econ Sa ctl a Met dlc. im wo dam Te dap ao ‘xpi of improving cnc Ts pene wor eed expen ina bor Udy and then tafe t a0 nd fly whew 2 198 ssw in egy fin and prokton war read INTRODUCTION eon of cian cote igh nda: ection, eg 3166) of he nt 1 Proce ome of ine (20). Tae cso oly Kop when the emer abo the {Eecceon emperors te etre oe maT peal tron ‘eC ant 13080 (i). Ome he ecto ar th ener ret be med shove the dsc tengentin tenon ned i tn meee Dont the ean cbr pre gc from deer sae the pair et prot inert coc deed presen “The intl pcs of ein way cia ot ina Rey Kil, whee he neg from turing he opie or ding, ening, snd Somos the cum enboonte sone OF Fr. Gabe dete from bork the et sure and he ton ection © pode age {sd pres on gh npn en con ny ove cn Kp pyar ani mo of ae fares though he hn shel nda athe pct Improving the ney liny of i, ot onl ees eentose sar eriniom bot ao hus signin pact othe cst rong i, Undesaingline citon nc potential oid rican of eo ction 0 ney en: opptnis ‘An enemy at, cad ut at Perry Line Ld ele the dibson of ene we in ine Kn proses sate in Fgu . The process wae» pal qa inet proceting lacy with a convent Rerary Kn, The resus are indeed are apps to the imestoneprocestng [ace The sim ofthe sae was ot the oa mou of enemy ed inthe proces ane to qaatyingand quelling energy bosses Figo 1: En Dic na Lie Bb Pes (2) “The highs ney loses. wer recoded inthe fs ss (2). Orbe ase inca convection ee fiom the kn shell (5.8%), at content ses inthe predoct (2%) and mcelanecutlones (345) aly 8.8% of te het suppl we wed to decompore cam carbonate or in ter words 43.2% of the enegy was ter inven ly kt vo sundng or no coveted for moe well appltion. 7 is yes sy prs rye ein of 4 Fey Line Lid, a oe thi owl to speding wp the etl scp wiht aes bet Shion Allough de lsat and waco nec of the theme econponin of oon Sabon eben cheer any ts he se many specs tht ae tl na apd wel a millvel One reas thes ot orn sbnt any fandom spe th proces. For ‘Sample ae config pa shout spplealy othe pic retin model the proces Sep tha ir mening he infnce of she Serbon Gove pata pur the elle of tal fg adhe ls off ot tegh te an one er coving he tng fk ‘The sinking core reaction model isthe mast obvious pice rexton model to examine and is considered to have apples. The enti eaton aed fo nay ae plea the eet Suvace ofthe pie, acl asthe reaction precede exer sac of the par covered by the porous produc er, whe an nated core reams i the ine pon of the pace The orcs layers sure stay ita, ving parle of constant size wis sheng unseated core SHRINKING CORE MODEL. Inthe shaking core model dhe are four inoran eps which sonra tert of decomputon of cium carbone: the conducion of hes tough the reed yer (he othe wating coe, the chemi racton tse a he cor th ifsion of catbon dixie avy fom the core foro eran the dita of cen ole ry fom he pce ugh the pn Eovounding the parc, ‘ibm Dificion Reson: This res wo he difusion through the gs ln surounding the reacting Paice which col crete aconsentton grafico the lm, In mio reaction the reine to fiffason through th sh eis sully far greater than esstance to fon through the ga fir. ‘The ga film reste is tucfore seme to be nel, Reseaches have generally apd hat fim dfsion eles ae an igs factor inthe deeomporton of Hinetone. Pm dioson wll, thetlore be grovel inti pet (CenotRastion ark Ths whe the ae reseton athe esting urfce the me determining, on “Theme cxpesion = era Sat 0 Sohing the equation 2K,C, 1d z_)? Ray (x2) CR a Tce {id GR -C- 49)” PaR OKC, t t Where: (and) At Dif Raion This + rsisce tot ow of ysis the ret pt sel gly ‘nthe port fo rd ler. By preao ease Eater bce of be tog pone been coca be mci Scan nen

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