TABLE J—THRESHOLD LIMIT VALUES (T.L.V.) mg/M3 (b) 15 360 25 20 2,400 70 14 0.25 0.3 45 0.25 5 3 45 12 2 35 15 525 650 19 0.5 0.5 0.3 0.5 0.2 0.2 0.5 80 A 5 5 0.002 low lo (In Alphabetical Order) Substance bpm (a) * Abate _ Acetaldehyde . 200 Acetic acid ... a 10 Acetic anhydride .... 5 Acetone 1,000 Acetonitrile oe 40 Acetylene dichloride, see 1,2 Dicloroethylene Acetylene tetrabromide ..... 1 Acrolein oe 0.1 Acrylamide-skin .... _ ‘Actylonitrile-skin . 20 Aldrin-skin ........ _ Allyl alcohol-skin . 2 Allyl chloride ... 1 C Allyl glycidyl ether (AGE) 10 Allyl propyl disulfide . 2 2-Aminoethanol, see Ethanolamine 2- ‘Aminopyridine 0.5 Ammonia .. 50 Ammonium sulfamate (Ammate) _ n-Amyl acetate ..... 100 sec-Amyl] acetate 125 Aniline-skin : 5 Anisidine (0, p-isomers)-skin . —_ Antimony & compounds (as Sb) co ANTU (alpha naphthyl thiourea) : _ Arsenic & compounds (as AS) . 7 : —_ Arsine we 0.05 ‘Azinphos-methyl-skin Barium (soluble compounds) ..... pe : ~ C Benzene (benzol)-skin ..... ees 7 we : 25 Benzidine-skin _— p-Benzoquinone, see Quinone Benzoyl peroxide 22.......cescceccsseeteeeceecseeeeeeeeneeenees _ Benzyl chloride 1 Beryllium ... a Biphenyl, see Diphenyl Boron oxide .... “Boron tribromide . C Boron trifluoride Bromine : *Bromine pentafluoride . (a) Parts of vapor or gas per million parts of contaminated air by volume at 25 degrees Centigrade and 760 mm. Hg pressure. (b) Approximate milligrams of particulate per cubic meter of air. * 1969 Addition. C Ceiling limit which shall not be exceeded even momentarily or infrequently. A No exposure or contact permitted by any route (respiratory, oral or skin).TABLE I—THRESHOLD LIMIT VALUES (T.L.V.) Substance Bromoform-skin ...... Butadiene (1, 3-1 butadiene) Butanethiol, see seat mercaptan 2-Butanone ...... fe 2-Butoxy ethanol. (Butyl Celisoive) vskin por Buryl acetate (n-butyl acetate) .. sec-Butyl acetate . : tert-Butyl acetate Buryl alcohol ... sec-Butyl alcohol tert-Butyl alcohol C Butylamine-skin : C tert-Butyl chromate (as C103 sskin n-Butyl glycidyl ether ee Butyl mercaptan p-tert-Buryltoluene Cadmium (Metal dust and soluble salts) . Cadmium oxide fume . ie Calcium arsenate Calcium oxide *Camphor : Carbaryl (Sevin* Carbon black . Carbon dioxide . Carbon disulfide-skin Carbon monoxide .... Carbon tetrachloride-skin Chlordane-skin Chlorinated camphene-skin Chlorinated diphenyl oxide “Chlorine Chlorine dioxide C Chlorine trifluoride .. C Chloroacetaldehyde .. alpha-t Chloroacetophenone (phenacylchloride) Chlorobenzene (monochlorobenzene) ......... o-Chlorobenzylidene malononitrile (| OCBM) Chlorobromomethane .. we 2-Chloro-1, 3 butadiene, s see e Chloroprene Chlorodiphenyl (42% Chlorine) -skin .... Chlorodipheny! (54% Chlorine) -skin ........ 1, Chloro, 2, 3, epoxypropane, see Epichlorhydrin 2 Chloroethanol, see Ethylene chlorohydrin bpm (a) 0.5 1,000 200 50 150 200 200 100 150 100 5 50 10 10 mg/M3 (b) 5 2,200 590 240 710 950 950 300 450 300 15 O01 270 35 60 0.2 0.1 (a) Pars of vapor or gas per million parts of contaminated air by volume at 25 degrees Centigrade 760 mm. Hg pressure. (b) ‘Approximate milligrams of particulate per cubic meter of air. C Ceiling limit which shall not be exceeded even momentarily or infrequently. * 1969 Addition. ** Registered trade name.TABLE I—THRESHOLD LIMIT VALUES (T.L.V.) Substance bpm (a) mg/M8 (b) Chloroethylene, see Vinyl chloride C Chloroform (trichloromethane) 50 240 1-Chloro-1-nitropropane ........... 20 100 Chloropicrin .. : 01 07 Chloroprene (2-chloro-1, 3 -butadiene) oskin . 25 90 Chromic acid and chromates (as CrO3) : _ 0.1 Chromium, sol. chromic, chromous salts (as Cr) _ 0.5 Metal and insoluble salts = 2 Coal tar pitch volatiles (benzene soluble fraction, anthracene, BaP, phenanthrene, acridine, chrysene, pyrene) ...... = 0.2 Cobalt, metal fume and dust . _ 0.1 Copper fume : _ 01 Dusts and mists — a Cotton dust (raw) ... _ 1 Crag** herbicide - 15 Cresol (all isomers) -skin 5 22 Crotonaldehyde ” 2 6 Cumene-skin .......... 50 245 Cyanide (as CN) -skin _— 2: *Cyanogen . . 10 = Cyclohexane . 300 1,050 Cyclohexanol ... 50 200 Cyclohexanone 50 200 Cyclohexene 300 1,015 Cyclopentadiene 75 200 2,4-D — 10 DDT-skin ee : _— i. DDVP-skin 7 ssttieeeeeeneesteeseeneeseentecnes 0 1 Decaborane-skin ef : 0.05 03 Demeton**-skin ....... peut ee 0.1 Diacetone alcohol (4- -methyl- 2. -pentanone) eae 50 240 1, 2 Diaminoethane, see selected Diazomethane 0.2 0.4 Diborane z 0.1 0.1 C 1, 24 Dibromoethane (ethylene dibromide) skin. 25 190 Dibutyl phosphate . 1 2 Dibutylphthalate . _ 5 C_ o-Dichlorobenzene e eee : : 50 300 p-Dichlorobenzene 7 : 7 75 450 Dichlorodifluoromethane .......... eee 1,000 4,950 1, 3-Dichloro-5, dimethyl hydantoin. ee 0.2 1, 1-Dichloroethane . fees 100 400 1,2-Dichloroethane . 50 200 (a) Parts of vapor or gas per million parts of contaminated air by volume at 25 degrees Centigrade and 760 mm. Hg pressure. (b) Approximate milligrams of particulate per cubic meter of air. C Ceiling limit which shall not be exceeded even momentarily or infrequently. * 1969 Addition. ** Registered trade name.TABLE I—THRESHOLD LIMIT VALUES (T.L.V.) Substance bpm (a) —_mg/M3 (6) 1, 2-Dichloroethylene .... 200 790 C Dichloroethyl ether-skin 15 90 Dichloromethane, see Methylenechloride Dichloromonofluoromethane . 4,200 C 1, 1-Dichloro-1-nitroethane ..... e 60 1, 2-Dichloropropane, see Propylenedichloride Dichlorotetrafluoroethane 7,000 Dieldrin-skin 0.25 Diethylamine 7 75 Diethylamino ethanol-: skin 7 50 C Diethylene triamine-skin ..... a Diethylether, see Ethyl ether Difluorodibromomethane ...... 100 860 C Diglycidyl ether (DGE) ........ 0.5 2.8 Dihydroxybenzene, see Hydroquinone Diisobutyl ketone 50 290 Diisopropylamine-skin 2: 20 *Dipheny! amine _ 10 Dimethoxymethane, see Methylal Dimethyl! acetamide-skin Sete eeeaet oe 10 35 Dimethylamine .... eee 10 18 Dimethylaminobenzene, s see Xylidene Dimethylaniline (N-dimethylaniline) -skin .................. p] 25 Dimethylbenzene, see Xylene Dimethyl 1, 2-dibromo-2, 2-dichloroethyl, (Dibrom).. — 3 Dimethylformamide-skin ... 10 30 2, 6 Dimethylheptanone, see Diisobucy k ketone 1, 1-Dimethylhydrazine-skin 0.5 1 Dimethylphthalate a 5 Dimethylsulfate-skin 1 2 Dinitrobenzene (all isomers) skin - _ 1 Dinitro-o-cresol-skin . _— 0.2 Dinitrotoluene-skin _ ES: Dioxane (Diethylene dioxide) skin 100 360 Diphenyl . 0.2 1 *Diphenyl Amine = 10 Diphenylmethane diisocyanate (see ‘Methylene bispheny] isocyanate) (MDI) .... Dipropylene glycol methyl ether: skin . i 100 600 Di-sec, octyl phthalate (Di-2- -ethylhexylphthalate) _ 5 Endrin-skin 0.1 Epichlorhydrin-skin 2 19 EPN-skin —_ 0.5 1, 2-Epoxypropane, see Propyleneoxide 2, 3-Epoxy-1-propanol, see Glycidol (a) Parts of vapor or gas per, ae Parts of contaminated air py volume at 25 degrees Centigrade and 760 mm. Hg pres (b) Approximate milligrams ‘of particulate per cubic meter of air. C Ceiling limit which shall not be exceeded even momentarily or infrequently. * 1969 Addition.TABLE I—THRESHOLD LIMIT VALUES (T.L.V.) Substance bpm (a) —-mg/M3 (b) Ethanethiol, see Ethylmercaptan Ethanolamine 3 6 2 Ethoxyethanol-skin ... 200 740 2 Ethoxyethylacetate (Cellosolve acetate)-skin ........... 100 540 Ethyl acetate vsstisatinseeee 400 1,400 Ethyl acrylate-skin 25 100 Ethyl alcohol (ethanol) 1,000 1,900 Ethylamine ........ 10 18 Ethyl sec-amyl ketone (5-methyl- 25 130 Ethyl benzene seve 100 BS Ethyl bromide : 200 890 Ethyl butyl ketone (3+ "Heptanone) . 50 230 Ethyl chloride . : 1,000 2,600 Ethyl ether 400 1,200 Ethyl formate .. 100 300 Ethyl mercaptan 10 25 Ethyl silicate .. 100 850 Ethylene chlorohydrin-skin 5 16 Ethylenediamine 10 25 Ethylene dibromide, see 1, 2- Dibromoethane Ethylene dichloride, see 1, ; 2-Dichloroethane C Ethylene glycol dinitrate and/or Nitroglycerin-skin ..... 0.2(4) 1 Ethylene glycol monomethyl ether acetate, see Methy! cellosolve acetate Ethylene imine-skin 0.5 1 Ethylene oxide 50 90 Ethylidine chloride, see 1, 1-Dichloroethane N-Ethylmorpholine-skin .... — 20 94 Ferbam cece - 15 Ferrovanadium dust sesso — 1 Fluoride (as F) sevssensete a 25 Fluorine : OL 0.2 Fluorotrichloromethane 1,000 5,600 C Formaldehyde a eee 5 6 Formic acid sossesee : 5 9 Furfural-skin 5 20 Furfuryl alcohol 50 200 Gasoline ae = A Glycidol (2, 3-Epoxy-1-propanol) ... 50 150 Glycol monoethy! ether, see 2- -Ethoxyethanol Guthion* *, see Azinphosmethyl (a) Parts of vapor or gas per million parts of contaminated air by volume at 25 degrees Centigrade and 760 mm. Hg pressure. (b) Approximate milligrams of particulate per cubic meter of air. C Ceiling limit which shall not be exceeded even momentarily or infrequently. (d) An atmospheric concentration of not more than 0.02 ppm, or personal protection may be necessary to avoid headache. A Requires development of TLV based on benzene, other aromatics and additives content. +* Registered trade name.TABLE I—THRESHOLD LIMIT VALUES (T.L.V.) Substance ppm (a) —_mg/M3(b) Hafnium _— 0.5 Heptachlor-skin . — 0.5 Heptane (n-heptane) ..... 500 2,000 Hexachloroethane-skin ..... a 10 Hexachloronaphthalene-skin _ ‘ 0.2 Hexane (n-hexane) . 500 1,800 2-Hexanone 100 410 Hexone 7 100 410 sec-Hexyl acetate . 50 300 Hydrazine-skin 1 13 Hydrogen bromide 3 10 C Hydrogen chloride .. 5 7 Hydrogen cyanide-skin ........ 10 1L Hydrogen fluoride ......... 3 2 Hydrogen peroxide, 90% ... 1 14 Hydrogen selenide 7 0.05 0.2 Hydrogen sulfide 10 15 Hydroquinone .. _ 2 *Indium and compounds (as In) . _ O1 C Iodine : 0.1 1 Iron oxide fume _— 10 “Iron salts, soluble (as Fe) _ a Isoamyl acetate 100 525 Isoamyl alcohol 100 360 Isobutyl acetate 150 700 Isobutyl alcohol . 100 300 Isophorone . 25 140 Isopropyl acetate . 250 950 Isopropyl alcohol . 400 980 Isopropylamine 5 12 Isopropylether ..... 500 2,100 Isopropyl glycidyl ether (IGE) 50 240 Ketone ... 0.5 09 0.2 Lead arsenate . 0.15 Lindane-skin 0.5 Lithium hydride .. 0.025 LP.G. (Liquified petroleum gas) . 1,800 Magnesium oxide fume .. — 15 Malathion-skin .. — 15 Maleic anhydride 0.25 I (a) Parts of vapor or gas per million parts of contaminared air by volume at 25 degrees Centigrade and 760 mm, Hg pressure. (b) Approximate milligrams of particulate per cubic meter of air. C Ceiling limit which shall not be exceeded even momentarily or infrequently. * 1969 Addition,TABLE I—THRESHOLD LIMIT VALUES (T.L.V.) Substance bpm (a) mg/M3 (b) Ce Manganese; _— 3 Mercury-skin = 0.1 Mercury (organic compounds)-skin — 0.01 Mesityl oxide ...... ae 25 100 Methanethiol, see Methyl mercaptan Methoxychlor - 15 2-Methoxyethanol, see Methyl cellosolve Methyl acetate ....csecssens 200 610 Methyl acetylene (propyne) 1,000 1,650 Methyl acetylene-propadiene mixture ( 1,000 1,800 Methyl acrylate-skin ......... | 10 35 Methylal (dimethoxymethane) . . 1,000 3,100 Methyl alcoho! (methanol) . 200 260 Methylamine 10 12 Methy! amy! alcohol, see Methyl isobutyl carbino! Methyl (n-amyl) ketone (2-Hleptanone) 100 465 C Methyl bromide-skin 20 80 Methy! butyl ketone, see 2-Hexanone Methyl cellosolve-skin 25 80 Methyl cellosolve acetate-skin 25 120 C Methyl chloride ......... 100 210 Methyl chloroform ..... 350 1,900 Methylcyclohexane 500 2,000 Methyicyclohexanol . 100 470 o-Methylcyclohexanone-skin 100 460 Methy] ethyl ketone (MEK), see 2- Butanone Methyl formate : 100 250 Methyl iodide-skin 2. 28 Methyl isobutyl carbinol-skin 25 100 Methyl isobutyl ketone, see Hexone Methyl isocyanate-skin ......... 0.02 0.05 C Methyl mercaptan 10 20 Methyl! methacrylate ee 100 410 Methyl propyl ketone, see 2-Pentanone | C *Methyl silicate : 5 — C alpha-Methyl styrene 100 480 C Methylene bispheny! isocyanate (MDI) 0.02 0.2 Methylene chloride (dichloromethane) 500 1, as Molybdenum (soluble compounds) .. _- (insoluble compounds ) _ : Monomethy! aniline-skin ..... 2 9 Monomethyl hydrazine-skin . 0.2 0.35 Morpholine-skin 20 70 (a) Parts of vapor or gas per million parts of contaminated air by volume at 25 degrees Centigrade and 760 mm. Hg pressure. (b) Approximate milligrams of particulate per cubic mever of air. C Ceiling limit which shall not be exceeded even momentarily or infrequently. * 1969 Addition.TABLE I—THRESHOLD LIMIT VALUES (T.L.V.) Substance Naphtha (coal tar) .. Naphthalene beta-Naphthylamine - Nickel carbonyl .... Nickel, metal and ee compounds . Nicotine-skin : Nitric acid Nitric oxide . p-Nitroaniline-skin Nitrobenzene-skin p-Nitrochloro-benzene-skin | Nitroethane . C Nitrogen dioxide ........ Nitrogen Trifluoride ... C Nitroglycerin-skin Nitromethane 1-Nitropropane 2-Nitropropane N-Nitrosodimethyl-amine (Dimethyl- nitrosoamine) -skin Nitrotoluene-skin ... Nitrotrichloromethane, s see Chloropicrin Qcrachloronaphthaleneskin Octane . Oil mist (mineral) Osmium tetroxide Oxalic acid Oxygen difluoride Ozone Paraquat-skin Parathion-skin Pentaborane . Pentachloronaphthalene-skin Pentachlorophenol-skin . Pentane : 2-Pentanone ... Perchloroethylene.. Perchloromethyl ‘mercaptan Perchloryl fluoride .... Petroleum Distillates (nap] Phenol-skin a p-Phenylene diamine- skin Phenyl ether (vapor) .. bpm (a) mg/M3 (b) 0.1 2,350 0.002 0.1 0.2 0.5 0.1 0.01 0.5 2,95 0 700 670 0.8 13.5 2,000 19 0.1 7 (a) Parts of vapor or gas per million parts of contaminated air by volume at 25 degrees Centigrade and 760 mm. Hg pressure. (b) Approximate milligrams of particulate per cubic meter of air. A No exposure or contact permitted by any route (respiratory, oral or skin). C Ceiling limie which shall not be exceeded even momentarily or infrequently.TABLE I—THRESHOLD LIMIT VALUES (T.L.V.) Substance bpm (a) Pheny! ether-Biphenyl mixture (vapor) ... Phenylethylene, see Styrene Phenyl glycidyl ether (PGE) Phenylhydrazine-skin . Phosdrin (Mevinphos* . )-skin . Phosgene (carbonyl chloride) Phosphine Phosphoric acid . Phosphorus (yellow) Phosphorus pentachloride Phosphorous pentasulfide . Phosphorus trichloride Phehalic anhydride . Picric acid-skin ........ Pival** (2-Pivalyl-1, 3- -indandione) Platinum (soluble salts) : Polytetrafluoroethylene decomposition ‘products : Propane beta- Propiolactone *Propargyl alcohol-skin . n-Propyl acetate . Propyl alcohol . n-Propyl nitrate Propylene dichloride Propylene imine-skin Propylene oxide Propyne, see Methylacetylene Pyrethrum .. Pyridine .. Quinone *RDX-skin .. Rhodium, Metal fume and dusts .. Soluble Salts Ronnel Rotenone (commercial) . 1 Till ecii ilocos Selenium compounds (as Se) .. Selenium hexafluoride . Silver, Metal and soluble compounds . Sodium fluoroacetate (1080)-skin . Sodium hydroxide eee Stibine - . Stoddard solvent | a 0.1 500 oe a mg/M3 (b) 7 Ro ods Pooohvrroros m Sae eOone Ss 8 1, ie Sl>8 Me 500 110 350 5 240 5 15 04 15 0.1 0.001 15 5 0.2 0.4 0.01 0.05 2 0.5 2,900 (a) Parts of vapor or gas per million parts of contaminated air by volume at 25 degrees Centigrade and 760 mm. Hg pressure. (b) Approximate milligrams of particulate per cubic meter of air. At No exposure or contact permitted by any route (respiratory, oral or skin). A? No TLV recommended pending determination of toxicity of products, but air concentrations should be minimal. * 1969 Addition. ** Registered trade name.TABLE I—THRESHOLD LIMIT VALUES (T.L.V.) Substance bpm (a) —mg/M3 (b) Strychnine ... = 0.15 C Styrene monomer (phenylethyiene) 100 420 Sulfur dioxide . : 5 B Sulfur hexafluoride . 1,000 6,000 Sulfuric acid ........ —_ 1 Sulfur monochloride 1 6 Sulfur pentafluoride ... 0.025 O29 Sulfuryl fluoride ... : > 20 Systox, see Demeton** 2,4, 5, T _ 10 Tantalum — 2 TEDP-skin .... : _— 0.2 Teflon** decomposition Products . — Az Tellurium _ 0.1 Tellurium hexafluoride 0.02 0.2 TEPP-skin — 0.05 C Terphenyls ....... 1 9 1, 1, 1, 2-Tetrachloro-2, 2- difluoroethane 500 4,170 1 1 2, 2-Tetrachloro-1, 2-difluoroethane 500 4,170 1, 1, 2, 2-Tetrachloroethane-skin 5 35 Tetrachloroethylene, see Perchloroethylene Tetrachloromethane, see Carbon tetrachloride Tetrachloronaphthalene-skin ... _ 2 Tetraethyl lead (as Pb)-skin _ 0.075 Tetrahydrofuran ......... 200 590 Tetramethyl lead (TML) “Gs Bb) skin _ 0.075 Tetramethyl succinonitrile-skin . 05 3 Tetranitromethane 1 8 Tetryl (2, 4, 6-trinitrophenylmethylnitramine)-skin... © — 15 Thallium (soluble compounds) -skin _- 0.1 Thiram e _- 5 Tin (inorganic compoun Is, except SnH4 an _- 2 Tin (organic compounds) . _ 0.1 Titanium dioxide ....... — 15 Toluene (toluol) ................ 200 750 C Toluene-2, 4-diisocyanate . 0.02 0.14 - o-Toluidine-skin ........... 5 22 Toxaphene, see Chlorinated camphene Triburyl phosphate _ 5 1, 1, 1-Trichloroethane, see Methy! chloroform 1, 1, 2-Trichloroethane-skin 45 Trichloroethylene ............ 535 Trichloromethane, see Chloroform Trichloronaphthalene-skin ... com 5 (a) Parts of vapor or gas pe million parts of contaminated air by volume at 25 degrees Centigrade and 760 mm. Hg pressure. (b) Approximate milligrams of particulate per cubic meter of air. C Ceiling limit which shall not be exceeded even momentarily or infrequently. A2 No TLV recommended pending determination of toxicity of products, but air concentrations should be minimal. ** Registered trade name.TABLE J—THRESHOLD LIMIT VALUES (T.L.V.) Substance ppm (a) mg/M8 (b) 1, 2, 3-Trichloropropane ... 50 300 1, 7 2-Trichloro 1, 2, 2-trifluoroethane 1,000 7,600 Triethylamine ss 25 100 Trifluoromonobromomethane 1,000 6,100 2, 4, 6-Trinitrophenol, see Picric 2, 4 6-Trinitrophenylmethylnitramine, see ¢ Tetryl Trinitrotoluene-skin ...... _— 15 Triorthocresyl phospate _ 0.1 Triphenyl phosphate ... _ 3 *Tungsten and compounds, as W soluble . —_ iy Insoluble _ 2) Turpentine ..... 100 560 *Uranium (natural), soluble and insoluble compounds, (as U) _ 0.2 C Vanadium (V2Os dust) . _ 05 C Vanadium (V203 fume) - O.1 Vinyl benzene, see Styrene C Vinyl chloride ........... 500 1,300 Vinylcyanide, see Acrylonitrile Vinyl toluene 100 480 Warfarin ....... — 01 Xylene (xylol) 100 435 Xylidine-skin ... 5 25 Yeerium .... — 1 Zinc chloride fume . Zinc oxide fume ... Zirconium compounds (as (Zr) ue (a) Parts of vapor or gas per million parts of contaminated air by volume at 25 degrees Centigrade and 760 mm. Hg pressure. (b) Approximate milligrams of particulate per cubic meter of air. * 1969 Addition. C Ceiling limit which shall not be exceeded even momentarily or infrequently.TABLE JI—MINERAL DUSTS Substance Million Particles Per Cubic Foot* Asbestos 2.0... 5 Dust (nuisance, no free silica) ..... 50 Graphite (natural) 15 Mica (below 1% free silica) ... 20 Portland cement 50 Silica — Class I** 50 Class II** 20 Class I** 10 Class IV** .. 5 Slate (below 19% free silica) ............... an 50 Soapstone (below 1% free silica) ........ ae 20 Talc (below 1% free silica) . 20 Teemolite 5 Total dust (below 1% free silica) 50 * Using the light field low-power method of counting as described in the U.S. Public Health Report 47 No. 12, March 12, 1932, pp. 669-672 or its equivalent and a standard type impinger or other ‘equivalent instrument for taking atmospheric dust samples. ** Class I Rock. Any rock formation uniformly containing up to and including 5%, by weight, of free silicon dioxide. ** Class Il Rock. Any tock formation uniformly containing more than 5%, up co and including 10%, by weight, of free silicon dioxide. © Class III Rock. Any rock formation uniformly containing more than 109%, up to and including 40%, by weight, of free silicon dioxide. . Glass Rock. Any rock formation containing more chan 40%, by weight, of free silicon oxide.