AITS – 1 CHEMISTRY (MAIN)

PART (B): CHEMISTRY

SECTION I: (SINGLE CHOICE QUESTIONS)

This section contains 30 Multiple Choice Questions. Each question has four choices (1), (2), (3)
and (4) out of which ONLY ONE is correct.

31. The number of primary, secondary and tertiary amines possible with the molecular formula C3H9N
is given by the set:
(1) 1, 2, 2 (2) 1, 2, 1 (3) 2, 1, 1 (4) 3, 0, 1
31. (3)

32. IUPAC name of (CH3)3C–CH2–CH(CN)–CH3

(1) 2-Cyano-3-methylhexane (2) 2, 4, 4-Trimethylpentanenitrile
(3) 2,2-Dimethyl-4-cyanopentane (4) 2-Cyano-3-methylhexane
32. (2)

33. Product A is:

Me
conc. H2SO4
Me A

OH OH

Me Me
(1) (2)
O Me Me
Me Me

(3) C Me (4) Me

O O
33. (4)
Pinacol–Pinacolone rearrangement
CH

CH

RE
3

CH
CH
3
3

OH
O
On the basis of -hydrogen H2O will removal]

34. The minimum number of carbon atoms in an alkane having four primary carbon atoms are :
(1) 4 (2) 8 (3) 5 (4) 6
34. (3)
2,2-DIMETHYLPROPANE

35. Number of  &  bonds present in pent-2,3-diene, respectively, are

(1) 12 & 2 (2) 10 & 4 (3) 12 & 4 (4) 10 & 2
35. (1)

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36. Tautomerism is exhibited by

O O
O O
(I) C6H5–CH=CH–OH (II) (III) (IV)
O O

(1) All four (2) II, III & IV (3) I, III & IV (4) only II
36. (3)

37. Which of the following is non-aromatic?

(1) (2) (3) (4)

N

37. (3)

38. In each of the following pairs, the one which represent homomeric relationship is-
Cl CH3 H2C Br H

(1) H3C CH2CH3 and H Cl (2) C OH and C CH3

H CH3 HO
H CH2CH3 CH2 Br

H2C CH3 CH 2Br H OH

(3) C and C (4) H3C OH and H CH3

Cl Cl
H3C H3C
CH2 Br CH 2 CH 3 NH2 NH2
38. (4)
a,b,c enantiomers d. homomers

39. Identify the product X –

OH
(i) aq. NaHCO3
(X)
(ii) H3O+
OH
OH

(1) No-reaction (2)

OH
CO 2H
- +
OH O Na

(3) (4)

HO 2C OH - +
HO 2C O Na
39. (2)

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It is a Kolbe-schmitt reaction. When ring contain two m-hydroxy group the passion ortho to one and
para to other is now sufficiency activated to be carboxylated under mild condition.
OH OH OH

NaHCO3 H3O+

OH OH OH
CO 2Na CO 2H

40. The product(s) of the reaction is/are?

H+

N OH

OH
OH

(I) (II) (III) (IV)

N N N OH
N
(1) II, III and IV (2) II and IV (3) only I (4) only IV
40. (4)
HC CH
HC CH
Rimexpensia
C
+ localized
N O H N
CH

H
H 2O
CH

N OH

41. A 4 : 1 molar mixture of He and CH4 gases is contained in a vessel at 20 bar pressure. Due to a hole
in the vessel, the gas mixture leaks out. The ratio of number of moles of He to CH4 in the mixture
effusing out initially will be :
(1) 8 : 1 (2) 1 : 8 (3) 1 : 4 (4) 4 : 1
41. (1)
rate of effusion of gas A PA M B

rate of effusion of gas B PB M A
1
For gas CH 4 : PCH4   20  4 bar, M CH4  16
5
4
For gas He : PHe   20  16 bar, M He  4
5
rate of He 16 16 8
 
rate of CH 4 4 4 1

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N
42. 20 ml of H2O2 after acidification with dil. H2SO4 required 30 ml of KMnO4 for complete
12
oxidation. The strength of H2O2 solution is [Molar mass of H2O2 = 34]
(1) 2 g/L (2) 4 g/L (3) 8 g/L (4) 6 g/L
42. (1)
x 20
Assume strength of H2O2 solution is x gm/L moles of H2O2 in 20 ml = 
34 1000
n–factor of H2O2 is 2
eq. of H2O2 = eq. of KMnO4
x 20 1 30
 2  
34 1000 12 1000
x2

43. The correct figure representing isothermal and adiabatic expansions of an ideal gas from a particular
initial state is :
(1) (2)

(3) (4)

43. (1)
Slope of adiabatic should be more than isothermal in magnitude at point of intersection.

44.  H 2O    which of the following statements is true.

For an equilibrium H 2 O  s  
(1) The pressure changes do not affect the equilibrium.
(2) More of ice melts if pressure on the system is increased.
(3) More of liquid freezes if pressure on the system is increased.
(4) The pressure changes may increase or decrease the degree of advancement of the reaction
depending upon the temperature of the system.
44. (2)
If we increase pressure then system want to reduce pressure by increasing volume of water vapour
which can be done by melting more ice because ice occupy more volume then liquid H2O.

45. Which of the following will decrease with dilution at a given temperature?
(1) pH of 10-3M acetic acid solution
(2) pH of 10-3M aniline solution
(3) degree of dissociation of 10-3M acetic acid
(4) degree of dissociation of 10-3M aniline solution
45. (2)
On dilution degree of dissociation increases for weak acid as base but dilution also increases volume,
hence in case of weak base.
  OH    P OH  P H 

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46. The increasing order of acidic nature of Li2O, BeO, B2O3, CuO is :
(1) Li2O < BeO < CuO < B2O3 (2) BeO < CuO < B2O3 < Li2O
(3) Li2O < CuO < BeO < B2O3 (4) B2O3 < CuO < BeO < Li2O
46. (3)

47. In which of the following sets the central atom of each member involves sp 3 hybridisation ?
(1) IO 4 , ICl4 , IF4 (2) XeO3, XeO4, XeF4
(3) SO 3 ,SO 32  ,SO 24 (4) PCl 4 , BF4 , ClO 4
47. (4)
Cl F O 3
3 3 SP
SP P SP B Cl
-
O O
Cl Cl Cl F F F O

48. Correct order of bond energy is:

(1) N 2  N 2  N 2  N 22  (2) N 2  N 2  N 22   N 2
(3) N 2  N 2  N 2  N 22  (4) N 2  N 2  N 2  N 22 
48. (1)
N2 N 2 N 2 N 22 
Bond order
3 2.5 2.5 2
Bond energy > > >
Note: N 2 has less antibonding e s hence more bond energy

49. KO2 (potassium super oxide) is used in space and submarines because it:
(1) absorbs CO2 and increases O2 contents
(2) eliminates moisture and increases CO contents
(3) absorbs CO2 only
(4) produces ozone
49. (1)
KO 2  CO 2   K 2 CO 3  O 2

50. The structural unit present in pyrosillicates is :

(1) Si3O96– (2) SiO44– (3) Si2O76– (4) (Si2O52–)n
50. (3)

51. Three lines are drawn from a single corner of an FCC unit cell to meet the other corner such that they
are found to pass through exactly only 1 octahedral void, no voids of any type and exactly 2
tetrahedral voids with 1 octahedral void. Identify the line in the same order.
(1) Edge, Face diagonal, Body diagonal (2) Face diagonal, Edge, Body diagonal
(3) Body diagonal, Face diagonal, Edge (4) Edge, Body diagonal, Face diagonal
51. (1)

52. The vapour pressure of the solution of two liquids A(pº = 80 mm) and B(pº = 120 mm) is found to be
100 mm when XA = 0.4. The result shows that :
(1) solution exhibits ideal behaviour.
(2) solution shows positive deviation.
(3) solution shows negative deviation.
(4) solution will show positive deviation for lower concentration and negative deviation for higher
concentrations.
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52. (3)
Pressure from Raoult’s law
P  0.4  80  0.6  120
P = 32 + 72 = 104 mm of Hg
Actual pressure is less than Raoult’s law pressure means negative derivation.

53. Given :
(i) MnO 4  8H   5e  
 Mn 2   4H 2 O E 0  x 1V
(ii) MnO2  4H   2e   Mn 2   2H 2O E0  x2V
0
Find E for the following reaction :
MnO 4  4H   3e  MnO 2  2H 2O
5x1  2x 2 2x1  5x 2
(1) x2 – x1 (2) x1 – x2 (3) (4)
3 3
53. (3)
(i) – (ii) gives final reaction
Hence G  for final reaction  5 F x1  2 F x 2
G  3F E  5 F x1  2 Fx 2
5x  2x 2
E  1
3

54. Which of the following ions will be most effective in coagulating the As2S3 sol :
(1) Fe3+ (2) Ba2+ (3) Cl– (4) PO 34
54. (1)
As2S3 is negatively charged sol hence we need +ve charge ion for coagulation effective coagulation
 charge on ion.

55. Rate constant for the reaction NO2  CO  NO  CO 2 are 1.3 M–1S–1 at 700 K and 23 M–1S–1 at 800 K.
 23 
What will be the rate constant at 750 K ?  n  2.873, e1.53  4.629, e1.34  3.822 
 1.3 
(1) 12.15 M–1S–1 (2) 24.3 M–1S–1 (3) 6.0 M–1S–1 (4) 20.0 M–1S–1
55. (3)
EA

RT
K  Ae
EA

700R
1.3  A e …(i)
EA

800 R
2.3  A e …(ii)
EA

K  A e 750 R …(iii)
Eliminate A and EA from (1) and (2) and then calculate K from (3)

56. Which metal is extracted using a hydrometallurgical process involving complexation ?

(1) Mg (2) Ag (3) Cu (4) Zn
56. (2)

57. .... is obtained when ammonium dichromate is heated.

(1) nitrogen (2) oxygen (3) ammonia (4) none

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57. (1)

 NH 4 2 Cr2O7   N 2  4H 2O  Cr2O3

58. Which has maximum paramagnetic nature ?

(1) [Cu(H2O)4]2+ (2) [Cu(NH3)4]2+ (3) [Mn(H2O)6]2+ (4) [Fe(CN)6]4–
58. (3)
Mn 2 has five unpaired e– because H2O is not strong enough to force Mn2+ for pairing.

59. In which of the pair the precipitates are red and black coloured respectively and both are soluble in
excess KI solution ?
(1) HgI2, Hg2 I2 (2) HgI2, BiI3 (3) Cu2I2, AgI (4) CdI2, PbI2
59. (2)

60. The thermal stability of hydrides of oxygen family is in order :

(1) H2Po < H2Te < H2Se < H2S < H2O (2) H2Po < H2O < H2Te < H2Se < H2S
(3) H2S < H2O < H2Te < H2Se < H2Po (4) H2O < H2S < H2Te < H2Se < H2Po
60. (1)

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