bape (recee) '7)(@); A. moderately concentrated syueous salution of copper(tI) Sle herbed The du ne npr SE oe toe cope! sind rs nal ene sit Ua in ake the hapa oat gion cp Tape) bende (DU he cna ti Be ake __whtvn sete been seve How many gan of exper lt be Segue tnone ho by Pena Fame ies 8) How many faradays of electricity ae required to liberate the following ‘quanti of elements in elctolyas? (@) 0.1 mol of ealeum (©) 1208 % 10%" slminium toms (6) 3 moles of oxygen molectes © 23 g of sodium () 224 dm? of chlorine at st, 9) Find (2) number of motes and (&) mass of ser deposited in plating bath by passing a current of 5A for 1S how. 10) How many Hours wilt tke fora current of LS A to deposit 00 g of metalic copper from a solution of copper) sephate? 11) If 1 mole of electrons pessas though ditite sulphuric seit during cleetrolyis, what vohime of liydroge gat at 28°C and 760 sun He ‘would be berate at cathode? 12) When an squcous solution of sodlun hydroxide is sectrolysed using platinum elctodes, the hydroxide fons ate charged atthe anode to give oxygen acooing tothe follwing bal squation 40H (eq) —> 21,010) + O16) + 40 ea cutront of 25 A pasted for 15 minutes, (2) ow many oles of OM ans ate dtcharged? (©) how many noes oF oxygen (03) ae produce? () whats the volume ofthis oxygen a tp. [A dzect current vac psised dough slivte eulphusic acd ui Platinum electrode, (©) IF 1 Faraday of elecuicty was passed, calculate the number of| soles of hydrogen and oxygen formed at the volumes they would ossupy a tp. 4b) What would be the volumes of ses if only 0.01 ved? ray wae (©) What sine would it take fo puss O01 fury af » coment of 0.5 ampore woe wed? 14) What mass of copper will be lherated fiom copper sulphate solution by + quantity of ekctcity that sets fice’? grams of onyern? (nKCFE) 15) What total volume of gas, measured at sip, would be Hberated fom date sulphuric aid by the cent which, Mowing forthe same lume, deposits 0.635 g of copper fom copper) supe solution? 16) A direct cient is paued between platinum plates tvough solutions ‘ot copperHi) supe, ver ntate and dite sulphur ac comected 4 seis. IF 0210 g of copper is deposited i the first el, ealeate {@) the mass of slver septeted from the vecond solution (b) the volume of hydrogen, measured at room conditions, whichis iterated ‘hom the thd wlaton 17) If the cost of elettlty to produce magnesium is $x per kg of the tet, whit Is the cost of eletiity for producing y ky of aural stthesame rates? 18) The quantity of decticty which depts 0.3 mele of aver cn epost 45g of the meta scandium (Gymbol Se, atomic mass 45). ~g4 the symot for sver ion i Ag", what is dhe symbol for scandium GA cae of 186 A was pred fF 1000+ tigh an agus ‘huson af saltafe mal M Toe me of Sepa ie ces saan (2) How many conombs oes weal te epee toned? (0) te sons at of i 112,how many oe of ome of seen in2 24g a (© How mony () costs) fandoe of setiay wo be redo pT nolo tno (@ How many charges are eatted ty a on of A {) Wate a halfequaton to show what happens to aa on of AF when itis discharged atthe cathe, 20).An clement X has a molar mass of M8 g. When 2 curent of OS A was pased for 955 5,022 x of X was deposited on te cathe (@) Calelate tie numberof faradays of lcinsty needed to tberate {mole of ¥ atoms (6) Wiite the Fora for the on of X {) Wate tse fom forte hydrox of X 21) A inolten compound containing Ni ions was electvaysed by 2 funeat of | ampero, After 2 hors and 40 minutes, 292 gf nickel Wer deposted on the cathode. Calelate the elitve atomic muse of nike 22) The same curent is pasted thcough copper) sulphats soliton for 90 sninutes and another solution contaimag. metal ion MP for 60 minutes, ABE g of copper and 02238 g of AF were liberated respectively. Caleuite the relative tome is of met Al 23) An aqueous solution of swaiue cthanoate (CHSCOO'Ns") was lective. The halfreactions which oocir at the cletrdes may be sspretnted by the folowing half uations: cathode : 21"(aq) #20" —— Hy(g) anode + 2CH,COO Gq) —+ CH) + 20056) + 26° (@) What were tre rave whumes of the gases collect at the sathode and anode respectiely? (The salublty of carbon iow a water may be nelecte.) () Alter passing the gas colleted at anole through concentrated sodium hyioxide Solution, etbiae (C;H,) wat collect. and It vlame was mesure. Ti wat fond tobe 25 cm? (comected fo stp). How many iaradays of alectiety fad Been pasted "rough the sodium ethancatsolton? (2) What volume (eomected to 5.) of @ Aydopen (Ui cazdon ion was als produced during the eectzlyais? eae cae Ste: 18 copys aipate Sitio OF M mph od “The diagram stows 2 cirsut for the dectolys of 0.1 M copper) sulphate solution and 0.1 M sulphuric aid in snes, A seudy curent ‘spasing through the erat (2) Witte inde equations for the reactions taking pace at elects KL, Mand, (©) What would be observe in el BF the electrodes A and were ‘moved closer togethat? (© Use tee factors which could incense the ste of eectralyss incall (@) How tong would & curteat of 1 ampere need to passin cell A before 00635 g of copper were deposited? (6) What sonld he the volume of hydrogen liberated at sip. in xl Bin ho same time withthe sre curren? ‘GHKCEE) Ry25) A compound was found to condustelsctity when solten 26) An clecuolsis experi but Dot wen sol. Afler the paige of an electric curtent in molten X for some tine, 4 metal which would mark paper when solidified ‘was formed at one of the electrodes. At the other electrode, a volt ‘vapour was evolved. The mal mas cemoved, rebested bait in 4 cnicible and kept molten for seveal minetes. On cooing, a yollow solid was formed (2) What wa the ott vapour Uber? () At which elactrode would it be formed? (©) What compound 2? (4) Name the yellow substance formed by bestng the metal in a. (©) Compound X wat found 19 dissolve in boiling water, Oa cooing {he solution, gokten yellow shiny crystals were sen to form, ‘Comment onthe elublity of Xin wate, (9) X vas spin disolved in boing water ané 2 piece of zine foi Idded, ‘hat would be observed? Write an onic equation for ‘he oaction tht takes ple was cried ou! wing the ert shown aap below ete oie (@) lt was noticed thatthe bulb up only whe the potassium iodide Jn Pad melted, and not before. Explain, (©) A colour appeared round the anode in each beaker. What was being formed? (© rm which ap tid was fn at he hed Whaat isin? : sme 40) Agar was formed atthe cathode @. What st? (©) Explain he farmation of he gs meationed in (2) (A sure of A ped 1 inte How my nay of electricity is this? oD ]) 12 ca? oF gas wove produced at te cathode in Q. How mn oes this? e * (9) Comment he esas a (aa. (he expninent ws permed under rst of | atau, ‘then what was the temperature? 7 " ee 21) The uppartus shown in the digs below ws setup. |» srt ain usr ihe sh (@) Name the gas you would expect 1 be gia off iat (A) at ¥ (6) After 30 sinus it was noted that colours had spread into the ulate suiphure ack st A und 8. Pepsin what colo you would expect oid nach li (©) Ths content was left on ovemight in an step to incest the spread of colour, Next momisg. = reddthrown. solid was ‘ote om the negative electiode, ¥. What is this eds down soli key o be? Explain ow it may base been forbes (CDC Sample Question)28) An eletic current is passed for some tine dough two voltameters onected in series. Tho fist voltmeter conning 4 concentrated ‘olution of potasiom chlodde and the second contains soltion te coppett}nitiate, The elctodes used ae all platinum eletrode Te is Found that 29.0 cm? of 0200 M rulphunc acd are required to reutilize completely the potas hydroxide Formed in the fist saltsmete. (a) Find number of moles of hydroxite ons formed in the se soltameter, (6) Find umber of mole of hydrogen ions dichayged in the fs voltameter (@) Find number of moles of elestons required to discharge this mou of hydrogen ons 48) Find @) rumber of moles (iH) mass of copper Uberted in the second voltemete. » 109 en? ot so.) cat cae The adore dlagram shows 4 cull for the eleetrayss of X80s(09) and AgNOs(@q) in sexes (X i rota ess electropositive than hydrogen) MI, Pau Q se platinum cectodes The corset Hnilly posed fora peiod of ime sich that 0.189 & of X is depodted «nM and 0.622 g of slvr on Q. The cucent is then pased for a further period of time unt all the metal X is Geposted in coll A, a indeated by constant weighing of 8. The total increase the mas of Min cell 162.58 g (@) xpi the eaetions taking place in els and () Caleulite the snoaity of the () hydrogen ion (8) sulphur acid which & produced im call 4 after all the metal X has boon ‘epost, (You may asume that the volume of solution in ell A sinains snchanged) wx 30) The folowing table gives some information about two el and “Relative atone mass | Poston nthe Pedic Teble BI ‘Geupt r 243 Group tt Soe nunber of moles of two chlorides formed fom X and ¥ ae tnised together and meted, Two carbon olectodes A and B are placed in the molten chlorides aud an eletsic current is pased through the Bquid as shown below: | rants (4) What ace dhe streturd formulae of the chlorides formed by and Y expecivy? () Hes found that X Hush stronger reducing agent shan ¥ ‘Wie haleesctons forthe changes which take pace at electrodes AaB, (©) When a carrent of two anpees has pestod through the molien chlosde mixture for two hours, clelate the moss ofthe product formed at ()electoded (i) clstrode 8 (2) () IY) astronger oxdcing agent shan X07) G@ ts Y"taq) a suonger oxidizing agent than (aa) of the {e) I an aqueous soon of the chloride mixture is elecolysed 6 shown above, whit i the product formed at clectnde (0 What 60 you expect to observe when a small piece of X re3) 2) dropped fata + heaker of cold water? White an equation fo the reaction whist occurs, laments A, B and C ae in the sme period inthe psioie table ‘A compound xX is formed by A end C, and 8 compound Y i formed by B and C. In the cectlyss of ¥ and of ¥, the amount of C produced fiom T mole of ¥ is half of that produced from ¥ mole oY. (0) Ifthe formule of Xi represented by AC, what i the foenule ory IF he fon of C has one unit negative charge 10 which groups of the periodc (ble do elements , B and C belong respectively? (© From which electrode would C be Mberaed dug dhe lectus oft? (© Explain bony why there i Lite tendency for A to form an oat compoued uth B, (@) Using outermost shells ony, daw an electronic digram to show hhow atoms of C would jin topetber to form molecules, and ©) Peete jg ong ned ‘uxctr) moant — ster cpp sesropee sth mor ‘An vngazed porous pot with 1 M copper) sulphate solution and ‘copper plates immersed into a beaker ontaning 1M zine slphate Solution and 2 zine rod. A eiratt i completed hetween the copper Date st the sine rd, an # cere ean be rege by an ume. (4) Weite lone equations co show the reactions at the copperplate and thei 04 (6) Would an eecton flow occur fram the copper pate (othe dine rod in the externa cout? Explain your anor, (©) Im what tection woul’ the sphite tons pas thrcugk the porous pot” Flan your answer. (@) 1 the change in mass of tho zine vo atthe end ofthe experiment 1s 1.00, what would e the change in mass oF the copper pate? ©) “Magrstum is a srongor reducing agent than either xine oF {Expnin the above statement inten of eletvon tater. What would happen wn the copperplate ard I Mt copped) ruiphate solution ato replaced by a magnesium pte and tM ‘magnesium sulpate olution? (KCEE) osu_| a 0, ‘the diagram above iasrates the apprata wed for the eeeruysi cof two solutions. Hectode A is mae of metal X. The formula of te sulphate of metal ¥is X80, Electrodes 8, C and D are all mide ‘of planus. Pand Q ate the poles ofthe battery ‘On completion of the eel, metal X buyns to deposit on electrode B, ani gs bubbles bepin fo appear abowe eestades C ané D. (a) Which one ofthe pols? and Q isthe poste poe? (@) Wate an Jonie equation forthe reaction occurring at electrode A. What is thls ype of rection called? (©) What woul be the gases collected in tne tubes abovs (i) ecto 6, @ elecirodie DY (8) Aor the passage of a corteat of 2 amperes for 3 minutes 13 pyseconds, 0.127 g of metal X i deposted on elecvode B. Calenlste the eelativo omic mate of metal X. (0 faraday = 96 $00 coulomb) ‘The carest is now reversed for § minutes, Desebe bristy ‘bra obsorations that can be mde at eletrade 2 ding this period KCEE) ci same istnum dstoes Dang the aacteoyse of tine water, carbon dioxide gs is bub continuously into the solution, The euact measured by an aruneter f= plotted against time, and the following graph © obtamed:— (@) Wat would te obsered when catbon dioude is? bubbled ‘continuously into the ins water? (©) With rference to the above graph, explain with the ald of tonic uations why the curentat Pis maximum, (i) the eunent decreases rar Pte Q, (2) the curentat Qs minimum, (the eaten increases from Q t0 2, (9) the catent shows ao significant change ftom R to S. (AKER)(PY) Se Cxampir 110 Mote tht 9) fos ao £0 It soto; co {envaton of Cua decrees sey) aN gilt a3" ee 1) 0184 eam Si ome) Soe sorousne tn} teat NG) 8029 1 a9ms3 ew {18} feces nit a doe Oo3sma.em ane ih tigeatbaseans St pola 13) Stee BOP Bie Aen ons fosse" {iis s5s0¢ 6) osmomm 0 a mw wa | BS) ee ae ay aot? Be 2) mom : sar ti IG 13g 22xwe 1 @ ee eet | HANG) Rida cia eaes eleamo fe © Ey Ms sObt ash» 3H OIL) + Onin, aN oa ae" = HE) (0) Rao slecoiys iene {c) merase cnentatun of CSD neat wtp, ove estos om (Gradua teu ts lower eta) fey tg ade 291 oh Armin Ue) pots (8) Let ne 1 {6} Soule nhotapuingty sot cd wae (Grey coatings tas tormedP6 oq) Zo) = FH» 20ach 126) 2) Gument's anaictes oy mole an, tae wee able Rand. ee {e)_ Kaa) ano Hach ors mate oo th atods, soar Mag) on Peet dactarge arnt (0 9008510 Fa) A974 HE mo / (i) 9968 x 10" F ole produce 4976 3 104 sa af Hy or 11,6 en ave @ ps) 1 0) io ip s o a ona) 3 & (2a im io @ 89) a) a eo) “1 (i Osvaen i) tysouen range ve yO el oa ae 8 eo or) cuscutags 2 eae) Paco! Ye) O60Sa0.nei fe) 608 CO me Gh "050809 mor Gay ase ‘At «OW ag) ule 2H, O1E BNO ag) ae Eh aah 3H Ps Sow ie) = Ong) aN) ae 20: Arash! ayb Ui oasaa (a) "Ou02 sm were, EASING) Cy} 0 ae: VER +26 + v8) ('s207¢010 Gi tatapot {Bo Xana vate vat i at ee ao tal san utc of water and senate 2x6} ¢ 24, 0G8)» 2X0te © Hee eee) Lav kde Btn tend ton sone a CBE) + costco ‘cele: Cu”) 126° Cue At toad: zn) antag 20 Note ssvonerwavene spent than cy 5044"ton se of the pot. Tir cane Ca) ate eases 1 fom ul) aun SOs sen se pos eae ans 2s nies to phe Zn" om which rte Seven ene ent 804" fon) tno ua ut te pn the Bee Me meres etn more ey han Zor Cette tow fom Wy ve {oz nie enero cau Zana, Zns0) 30s Desens ae, Nato) Me ae) #27504" Soe pn ie yor Be igh ol Xan Qevonsaton Ca) Gi) O48) te 625; te met depated on 0 aol sappts compe se 3c), un eaouten ps ate veto cacao Or oe) 1 mca caveman of bie or (a sn OW (8) eae te formaton of ihe akin extonate deen the aah 20) # Con) = e2C056) +14 0%) th At Cea om nd Fh tay et fr ie {elnima anon re) oe eee See ys rn oa) nd HCO] oan ESCO, HOE) osteo Cag) NC ea wt RT