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Test - 27th July 2019 - Physics and Chemistry Test For NEET / AIIMS Examination © Biomentors

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1) An electric dipole of moment ‘p’ is placed in an electric field of intensity ‘E’. The dipole acquires a
position such that the axis of the dipole makes an angle θ with the direction of electric field.
Assuming that the potential energy of the dipole to be zero when θ = 90֯, then the ratio of the
torque and the potential energy of the dipole will be.

एक िधु  व को िजसका िधु  वाघूण ’p ' है, को एक िवुत िधु  व तीवता 'E' म रखा गया है। िधु  व एक ऐसी िथित पात करता है िक िधु  व का
अ िवुत े की िदशा के साथ θ कोण बनाता है। यह मानते हुए िक िधु  वीय की िथितज ऊजा कोण θ = 90 होने पर शूय होती है | तब
जड़वाघूण एवं िथितज ऊजा का अनुपात होगा।

a) tan θ b) cot θ
c) - tanθ d) -cot θ

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2) Charge is distributed uniformly with charge density λ on a finite line of length ‘d’. The electric
field at a point p from this at perpendicular distance ‘a’ in the direction perpendicular to the charge

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distribution is given by, if the point P makes an angle α from top end and β form the lower end.

आवेश को घनव λ के साथ लंबाई 'd' की एक सीिमत रेखा पर समान प से िवतिरत िकया जाता है। यिद िबंद ु P ऊपरी शीष से कोण α
बनाता है और िनचले िसरे से β बनाता है।आवेश िवतरण के लंबवत िदशा म लंबवत दूरी 'a' पर एक िबंद ु P पर िवुत े का मान होगा

a) kλ/d (sin⁡ α + sin⁡ β) b) kλ/a (sin⁡ α + sin ⁡β)


c) kλ/d (cos⁡ β - cos ⁡α) d) kλ/a (cos⁡ β - cos ⁡α)

3) A positively charged particle moving along x-axis with a certain velocity enters a uniform electric
field directed along positive y-axis. Its (if only electrostatic force is considered)

एक िनिचत वेग के साथ X-अ के अनुिदश चलने वाला एक धनामक आवेिशत कण, धनामक Y-अ के साथ िनदिशत एक समान िवुत
े म पवेश करता है। इसका (यिद केवल इलेोटै िटक बल माना जाता है)

a) Vertical velocity changes but horizontal velocity b) Horizontal velocity changes but vertical velocity
remains constant (ऊवाधर िदशा म वेग पिरवितत होता िकतु remains constant (ैितज िदशा म वेग पिरवितत होता िकतु
ैितज िदशा म वेग िनयत रहता है) ऊवाधर िदशा म वेग िनयत रहता है)
c) Both vertical and horizontal velocities change (दोनों d) Neither vertical nor horizontal velocity changes
िदशाओं म वेग पिरवितत होता है) (दोनों िदशाओं म वेग अपिरवितत रहता है)

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4) The number of electrons to be put on a spherical conductor of radius 0.1 meter to produce an
electric field of 0.036N/C just above its surface is

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0.1 मीटर िया के गोलाकार चालक की सतह पर 0.036N/C का े उपन करने के िलए आवयक इलेॉनों की संया होगी
a) 2.7 x 105 b) 2.6 x 105
c) 2.5 x 105 d) 2.4 x 105

5) The spatial distribution of the electric filed due to two charges (A, B) is shown in figure. Which
one of the following statements is correct?

दो आवेशों (A, B) के कारण िवुत े का थािनक िवतरण िच म िदखाया गया है। िननिलिखत म से कौन सा कथन सही है

a) A is +ve and B is –ve and |A| > |B| b) A is –ve and B is +ve; |A| = |B|
c) Both are +ve but A > B d) Both are –ve but A > B

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6) A dipole of electric dipole moment P is placed in uniform electric field of strength E. If θ is the
angle between positive directions of P and E, then the potential energy will be largest when θ is

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िवुत िधु  व आघूण P का एक वैतु ोधव को एक समान िवुत े E म रखा जाता है। यिद, P और E के सकारामक िदशाओं के बीच
का कोण θ है, तो िथितज ऊजा का मान अिधकतम होगा जब θ = ?

a) 0 b) 45
c) 90 d) 180

7) A rod of length L lies along the X-axis with its left end at the origin. It has uniformly distributed
charge Q. Find the field at point x = 2L.

L लबाई की एक छड़ X- अ के अनुिदश मूल िबंद ु पर इसके बाएं छोर के साथ िथत है। इसम समान प से िवतिरत आवेश Q है। िबंद ु x =
2L पर िवुफ़ी े की तीवता ात कर।

a) KQ / L2 b) 2KQ / L2
c) KQ / 2L2 d) KQ2 / L2
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8) A large non-conducting sheet M is given a uniform charge density. Two uncharged small metal
rods A and B are placed near the sheet as shown in the figure.

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एक बड़ी कु चालक शीट M को एक समान आवेश घनव िदया जाता है। आकृित म िदखाए अनुसार शीट के पास दो अनावेिशत छोटे धातु की
छड़ A और B रखी जाती ह।

a) M attracts A b) M attracts B
c) A attracts B d) All of the above

9) A long thin strip of white paper is cut and is lightly ironed. Now it is been taken nearer to TV
screen. What is the possibility?

वेत प की एक लंबी पतली पटी काट दी जाती है और हके से इी की जाती है। अब इसे टीवी ीन के पास ले जाया गया है। या
संभावना है

a) Paper strip gets attracted towards the screen (पेपर b) Paper strip get distracted from the screen (पेपर
पटी ीन की ओर आकिषत हो जाती है) पटी ीन से िवचिलत हो जाती है)
c) There is no effect at all on the paper strip (पेपर पटी d) May be either attracted or distracted (या तो आकिषत
पर कोई पभाव नही ं पड़ता है) या िवचिलत हो सकता है।)

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10) Two identical charges of 10 C each, are placed at a distance of 10 cm from each other are fixed.
Which of the following charge will be in equilibrium when it is placed at the midpoint of the line

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joining these charges.

ु न म होगा, जब इसे इन आवेशों को


10 C के दो समान चाज, एक दूसरे से 10 सेमी की दूरी पर लगाए जाते ह। िनन म से कौन सा चाज संतल
िमलाने वाली रेखा के मय िबंद ु पर रखा जाता है।

a) 1 C b) 5 C
c) 10 C d) All of these
11) The intensity of the electric field required to keep a water drop of radius 10-5 cm just suspended
in air when charged with one electron is approximately

िया 10-5 सेमी की एक पानी की बूदं को केवल एक इलेॉन के साथ आवेिशत िकया जाता है तो हवा म िनलंिबत रखने के िलए आवयक
िवुत े की तीवता ............ होगी

a) 260 V/cm b) 260 N/C


c) 130 V/cm d) 130 N/C

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12) The maximum electric field produced due to uniformly charged ring of radius a and charge Q
will be?

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िया a और आवेश Q के समान प से आवेिशत वलय (िरंग) के कारण उपन अिधकतम िवुत े होगा

a) KQ / (3√3a2) b) 3KQ / (√2a2)


c) 2KQ / (√3a2) d) 2KQ / (3√3a2)

13) A charged ring of charge ‘Q’ of radius R is kept vertical. There exist a rod of charge density λ
C/m of infinite length as shown in the figure. What will be the force on ring due to rod?

िया R वाली तथा आवेश Q के आवेश से आवेिशत एक िरंग को लंबवत रखा जाता है। जैसा िक िच म िदखाया गया है, अनंत लंबाई की
एक रॉड िजसका आवेश घनव λ C/m है, वो भी िचानुसार रखी हुयी है। रॉड के कारण िरंग पर बल या होगा

a) KQλ / R b) 2KQλ / R
c) KQλ / 3R d) None of these

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14) An electric dipole of moment p is placed at the origin along the x-axis. The electric field at a
point P, whose position vector makes an angle θ with the x-axis, will make an angle ..... with the x-

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axis, where tan α = 1/2 tan θ

X-अ के अनुिदश मूल िबदु पर आघूण p का एक वैघत ृ -िदधुव रखा गया है | एक िबदु P पर, िजसका िथित सिदश X-अ के साथ कोण θ

बनाता है, वैघत े X-अ के साथ कोण होगा (जहाँ tan α = 1/2 tan θ)

a) α b) θ
c) θ + α d) θ + 2α

0
15) Electric field at a point varies as r for
0
वैतु े r के साथ पिरवितत होता है

a) An electric dipole (एक वैतु िधु  व के कारण) b) A point charge (एक िबंद ु आवेश के कारण)
c) A plane infinite sheet of charge (आवेश एक अनंत चादर d) A line charge of infinite length (अनंत लबाई के रेखीय
के कारण) आवेश के कारण)

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16) q1, q2, q3 and q4 are point charges located at points as shown in the figure and S is a spherical
Gaussian surface of radius R. Which of the following is true according to the Gauss’s law

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q1, q2, q3 व q4 िबदु आवेश िचानुसार िथत ह | S एक R िया का गौसीय पृ ठ है | गॉस िनयम के अनुसार िनन म से या सही है

a) ∮s(Ē1 + Ē2 + Ē3)(dA) ⃗ = (q1 + q2 + q3) / (2ε0) b) ∮s(Ē1 + Ē2 + Ē3)(dA) ⃗ = (q1 + q2 + q3) / ε0


c) ∮s(Ē1 + Ē2 + Ē3)(dA) ⃗ = (q1 + q2 + q3 + q4) / (2ε0) d) None of the Above

17) If the electric flux entering and leaving an enclosed surface respectively is ∅1 and ∅2 the electric
charge inside the surface will be

यिद िकसी बंद पृ ठ से पवेिशत तथा िनगत िवुलस मशः ∅1 व ∅2 होंतो पृ ठ के अंदर िवुत ् आवेश होगा

a) (∅1 + ∅2)ε0 b) (∅2 - ∅1)ε0


c) (∅1 + ∅2) / ε0 d) (∅2 - ∅1) / ε0

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18) Three particles, each having a charge of 10 μC are placed at the corners of an equilateral
triangle of side 10 cm. The electrostatic potential energy of the system is (Given 1/(4πε0) = 9 × 109 N
- m2/C2)
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10 सेमी भुजा वाले एक समबाहु िभुज के शीष पर तीन कण रखे हुए ह | पयेक कण पर 10 माइोकूलब आवेश है | इस िनकाय की िथर
वैतु िथितज ऊजा होगी

a) Zero b) Infinite
c) 27 J d) 100 J

19) A charge of 5C experiences a force of 5000 N when it is kept in a uniform electric field. What is
the potential difference between two points separated by a distance of 1 cm

5 कूलब के एक आवेश को जब एक समान िवुे म रखते ह तो उसपर 5000 N बल लगता है | दो िबंद ु जो एक-दुसरे से 1 सेमी की दूरी
पर है, के बीच िवभवांतर होगा

a) 10 V b) 250 V
c) 1000 V d) 2500 V

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20) An alpha particle is accelerated through a potential difference of 106 volt. Its kinetic energy will
be

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एक अफा कण को 106 वोट के िवभवांतर से विरत िकया जाता है, कण की गितज ऊजा होगी

a) 1 MeV b) 2 MeV
c) 4 MeV d) 8 MeV

21) Figures below show regular hexagons, with charges at the vertices. In which of the following
case the electric field at the centre is not zero?

नीचे िदए गए आकृित म षभुज िदखाए गए ह, िजसके शीष पर आवेश रखे हुए ह। िननिलिखत म से िकस िथित म कद म िवुत े शूय
नही ं है
a) 1 b) 2
c) 3 d) 4

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22) Five balls numbered from 1 to 5 are suspended using separate threads. Pairs (1,2); (2,4) and
(4,1) show electrostatic attraction, while pair (2,3) and (4,5) show repulsion. Therefore, ball 1 must
be
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1 से 5 तक िगने गए पांच गदों को अलग-अलग धागे का उपयोग करके िनलंिबत िकया जाता है। जोड़े (1,2); (2,4) और (4,1) िथर वैतु
आकषण िदखाते ह, जबिक जोड़ी (2,3) और (4,5) पितकषण िदखाते ह। इसिलए, गद 1 होनी चािहए

a) Positively charged b) Negatively charged


c) Neutral d) Either positive or negative

23) Two point charges of charge q1 and q2 are placed at a distance r. The electrostatic force is F.
Now a substance of dielectric constant k is inserted fully in between them. What should be the
distance between these charges so that one can get the same amount of force F.

q1 और q2 के दो िबंद ु आवेश कु छ दूरी r पर रखे गए ह। िथर वैतु बल F है। अब उनके बीच पूरी तरह से ढांकता हुआ आपेिक
परावैतु ांक k का एक पदाथ डाला जाता है। इन आवेशों के बीच की दूरी िकतनी होनी चािहए तािक िकसी यित को F की समान माा िमल
सके।

a) rk b) r / k
c) r / √k d) r√k

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24) When a plastic rod is rubbed with cat’s fur, then the charge on plastic rod and cat’s fur are
respectively.

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जब एक लािटक की छड़ को िबली के फर से रगड़ा जाता है, तो मशः लािटक की छड़ और िबली के फर पर चाज होता है

a) Positive, positive b) Positive, negative


c) Negative, positive d) Negative, negative

25) A charge q1 exerts some force F on charge q2 when these charges are placed at a distance r from
each other. Let if charge q3 is brought near to these charges such that they form an equilateral
triangle. New force exerted by charge q1 on q2will

जब िकसी आवेश q1 को आवेश q2 से कु छ दूरी r पर रखा जाता है तो यह q1, q2 पर बल F लगाता है | यिद िकसी तीसरे आवेश q3 को इस
पकार से इनके नजदीक लाया जाये की ये तीनों िमलकर एक समबाहु िभुज की रचना कर तो q1 ारा q2 पर आरोिपत बल होगा

a) Increases b) Decreases
c) Remains unchanged. d) Increases if all charges are of same sign.

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26) Which of the following species contains equal number of σ and π-bonds:

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िननिलिखत म से िकस पजाित म समान संया म σ और π-बॉड होते ह:

a) XeO4 b) (CN)2
c) CH2(CN)2 d) HCO3-

27) Which one of the following molecules contains no π bond?

िनन अणुओ ं म से िकस म π बॉड नही ं है

a) H2O b) SO2
c) NO2 d) CO2

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28) Be2+ is isoelectronic with which of the following ions?

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Be2+ िनन आयनों म से िकसके साथ आइसोइलेॉिनक है

a) H+ b) Li+
c) Na+ d) Mg2+

29) Some of the properties of the two species, NO3- and H3O+ are described below. Which one of
them is correct?

दो पीशीज, NO3- तथा H3O+ के कु छ गुणधम नीचे विणत है | इनम से कौन सा (गुणधम) सही है

a) Similar hybridization for the central atom with b) Dissimilar in hybridization for the central atom
different structures. with different structures.
(केदीय परमाणु का एक जैसा संकरण तथा उनकी अलग - अलग (िभन संरचना एवं केदीय परमाणु का िभन संकरण)
संरचनाएं)
c) Isostructural with different hybridization for the d) All of the above
central atom.
(िभन संरचना एवं केदीय परमाणु का समान संकरण)

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30) H2O has a non zero dipole moment while BeF2 has zero dipole moment because

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H2O म अशूय िधु  वीय आघूण होता है | जबिक BeF2 का िधु  वीय आघूण शुय है योंिक

a) H2O molecule is linear while BeF2 is bent b) BeF2 molecules is linear while H2O is bent
c) Fluorine has more electro negativity than oxygen d) Beryllium has more electro negativity than oxygen.

31) Which of the following bonds will be most polar?

िननिलिखत म से कौन सा बॉड सबसे अिधक धु  वीय होगा

a) N – Cl b) O – F
c) N – F d) N – N

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32) In PO43- ion, the formal charge on each oxygen atom and P – O bond order respectively are

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PO43- आयन म पयेक आसीजन पर फॉमल आवेश तथा P - O आबंध कोिट मश: है :-

a) – 0.75, 0.6 b) – 0.75, 1.0


c) – 0.75, 1.25 d) – 3, 1.25

33) Among the following the electron deficient compound is:

िननिलिखत म से कौन इलेॉन की कमी वाला यौिगक है

a) BCl3 b) CCl4
c) PCl5 d) BeCl2

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34) The correct order of decreasing polarizability of following ions is

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िननिलिखत आयनों के धु  वीकरण को कम करने का सही म या है

a) Cl- > Br- > I- > F- b) F- > I- > Br > Cl-


c) F- > Cl- > Br- > I- d) I- > Br- > Cl- > F-

35) Which one of the following pairs is isostructural (i.e., having the same shape and hybridization)?

िनन म से कौन एक युम समसरचनामक (अथात िजसका आकार तथा संकरण एक ही है ) होगा :
a) [BCl3 and BrCl3-] b) [NH3 and NO3-]
c) [NF3 and BF3] d) [BF4- and NH4+]

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36) N2 and O2 are converted into monocation, N2+ and O2+ respectively. Which of the following
statement is wrong?

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N2 और O2 अणु को , N2+ और O2+ म पिरवितत िकया जाता है तो िननिलिखत म से कौन सा कथन गलत है

a) In N2+, N-N bond weaken b) In O2+, the O-O bond order increases

c) In O2+, paramagnetism decreases d) N2+, becomes paramagnetic.

37) Which of the following ion has not bond order of 2.5

िनन म से िकस आयन म बंधन 2.5 कोिट नही ं है

a) O2- b) O2+

c) N2+ d) N2-

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38) Among the following ions, the pπ-dπ overlap could be present in

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िननिलिखत आयनों म, pπ-dπ अितयापन िकस म मौजूद हो सकता है

a) NO3- b) PO43-

c) CO32- d) NO2-

39) Maximum number of water molecule that one water molecule can hold through hydrogen
bonding is

पानी का एक अणु अिधकतम िकतने पानी के अणु के साथ हाइोजन बंध बना सकती है

a) 2 b) 4
c) 6 d) 8

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40) In XeF2, XeF4, and XeF6, the number of lone pair on Xe are respectively

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XeF2, XeF4 और XeF6 म, Xe पर एकाकी युम की संया िकतनी है

a) 2, 3, 1 b) 1, 2, 3
c) 4, 1, 2 d) 3, 2, 1

41) The pair of species with the same bond order is


िनन म से कौनसी जोड़ी म एक समान आबंधन कोिट मौजूद है

a) O22-, B2 b) O2+, NO+


c) NO, CO d) N2, O2

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42) Considering greater polarization in LiCl than in NaCl which of the following is wrong

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NaCl की तुलना म LiCl म अिधक धु  वीकरण को मानते हुए िननिलिखत म से कौनसा गलत है

a) Fused LiCl would be less less conducting than b) LiCl has lower melting point than NaCl (LiCl म
fused NaCl (यूड LiCl यूड NaCl की तुलना म कम चालक NaCl की तुलना म कम गलनांक है)
होगा)
c) LiCl dissolves more in organic solvent whereas d) LiCl would ionise in water more than NaCl (NaCl
NaCl does not (LiCl काबिनक िवलायक म अिधक घुलता है की तुलना म LiCl पानी म अिधक आयिनत होगा)
जबिक NaCl नही ं)

43) The common features among the species CN-, CO and NO+ are

िनन पजाितयों CN-, CO और NO+ म समान िवशेषताएं या है

a) Bond order is three and isoelectronic b) Bond order three and weak field ligand
c) Bond order two and pi acceptor d) Isoelectronic and weak field ligands

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44) The pair of species having identical shape for molecules of both species is

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दोनों पजाितयों के अणुओ ं के िलए समान आकार वाली पजाितयों की जोड़ी कौनसी है

a) CF4, SF4 b) XeF2, CO2


c) BF3, PCl3 d) PF5, IF5

45) Number of sigma bonds in P4O10 is

P4O10 म िसमा बंध की संया िकतनी है

a) 6 b) 7
c) 17 d) 16

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46) Which one of the following molecule is expected to exhibit diamagnetic behaviour?

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िननिलिखत म से िकस अणु से पितचुबं कीय यवहार पदिशत करने की उमीद है

a) S2 b) N2
c) O2 d) None of the above
47) Among the following the paramagnetic compound is

िननिलिखत म से कौनसा अणु अनुचबं कीय है

a) Na2O2 b) O3
c) N2O d) KO2

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48) Dipole-induce dipole interaction are present in which of the following pair:

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िधु  व –उपेरण िधु  व (Dipole-induce dipole) अंतःिया िनन म से िकस युम म मौजूद ह

a) Cl2 and CCl4 b) HCl and He


c) SiCl4 and He d) H2O and alcohol

49) The structure of PCl5 molecule is

PCl5 अणु की संरचना या होगी

a) Tetrahedral (चतुफलकीय) b) Square planar (वग समतलीय)


c) Trigonal bipyramidal (िकोणीय ििपरिमड) d) Pentagonal bipyramidal (पंचकोणीय ििपरिमड)

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50) Which of the following molecule will form a linear polymeric structure due to hydrogen bonding?

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िननिलिखत म से कौन सा अणु हाइोजन बंध के कारण एक रैिखक बहुलक संरचना का िनमाण करेगा

a) HCl b) HF
c) H2O d) NH3

Answers

1) C. The torque on the dipole is given as τ = pEsinθ


The potential energy of the dipole in electric field is given as U = -pEcosθ
Taking ratio the answer will be –tan θ
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2) B. Direct formula of electric field at a distance r from the line charge
Ex = Kλ/r [sinα + sinβ]
Now put r = a;
We get
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kλ/a (sin⁡ α + sin ⁡β)

if the point P makes an angle α from top end and β form the lower end, then also answer will remain
same.

3) A. Electric field is directed along y direction.


It means there exist an electrostatic force on the charged particle due to this electric field in y
direction. This y direction is vertical direction.
It means the velocity changes due to this force in vertical direction. But there is no change in
horizontal direction because there is no effect of electric field in horizontal direction.

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4) C. E = 1/(4πϵ0) q/r2
but q = ne
therefore

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E = 1/(4πϵ0) ne/r2
∴ n = (4πϵ0)/1 (Er2)/e
n = (0.036 x 0.1 x 0.1)/(9 x 109 x 1.6 x 10-19) = 360/144 x 105 = 2.5 x 105

5) A. The lines proceed from the positive and lines will reach B, if B is negative.
The number of lines /unit area i.e. the density of lines is greater for the greater charge.

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6) D. The potential energy at an angle θ from the direction of electric field is given as
Uθ = −PEcosθ
It means that the potential energy depends on the value of cos θ.

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If θ = 0 then
cos θ = cos0 =1
The potential energy will be U = -PE
If θ = 90 then
cos θ = cos90 = 0
The potential energy will be U = 0
If θ = 180 then
cos θ = cos180 = -1
The potential energy will be U = -PE(-1) = PE
This is the maximum value of potential energy.

7) C. We know that electric field at a distance ‘a’ from one end of the uniformly charged rod of
density λ is given as
E = Kλ[1/a - 1/(a + L)]
Now in the question it is asked for the point x = 2L
X = 2L is the point which is L distance away from right end of the rod.
Therefore, putting a = L in the given question, we get
E = Kλ[1/L - 1/(L + L)] = Kλ/2L
But, λ = Q/L
Therefore,
E = KQ / (2L2)
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8) D. In this case if M is considered as positively charged, then the charge due to induction will be as
shown in the figure.
So, from the figure it is clear that
M attracts A
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A attracts B

9) A. Cut out long thin strips of white paper and lightly iron them. Take them near a TV screen or
computer monitor. You will see that the strips get attracted to the screen. In fact they remain stuck
to the screen for a while. (NCERT page no 2, 4th line)

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10) D. Let say the charges are as Q = 10 C placed at point A and C.
The charge q will be in equilibrium if the forces exerted on it by the other charges are equal and
opposite.

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K (Qq/x2) = K (Qq/(r - x))2
On solving we get as x = r – x and x = r/2
Now if we observe carefully, then we find that, the equilibrium of third charge is independent of the
nature of charge ‘q’.
Because while solving we have not used the sign of charge ‘q’. Also while applying the condition of
equilibrium on charge q, the charge q is getting cancelled out.
So if any charge is placed at the midpoint of the line joining these two charges, this third charge will
always be in equilibrium.

11) B. Let say the mass of water drop is m and the charge of electron is q
Then the weight of water drop will be
W = mg
According to question this weight is balanced by equivalent electrical force.
The electrical force in terms of electric field intensity is given as
F = qE
Hence according to question
E=W
⇒ qE = mg
But mass of water drop is not given, and radius is given.
Also we know that the density of water is 1000 kg/m3
density = mass/volume
⇒ mass = density x volume

⇒m=ρxV
But water drop is spherical
So the volume of the water drop will be equal to
3
V = 4/3 πr
∴ m = ρ x (4/3) πr3 = 1000 x 4/3 x 3.14 x (10-5 x 10-2)3

⇒ E = mg/q = (1000 x (4/3) x 3.14 x (10-5 x 10-2)3 x 10)/1.6 x 10-19 = 260 N/C

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12) D. We know that the electric field due to ring of radius ‘a’ at a point P, ‘x’ distance away from
the centre of the ring is given by
E = kxQ/(a2 + x2)3/2

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For the maximum value of electric field
dE/dx = 0
(d/dx)E = (d/dx) kxQ/(a2 + x2)3/2 = 0
On solving we get
x = ± a/√2
putting this value in the formula of electric field we get
Emax = Q/(6√3 πε0a2) = 2KQ/(3√3 a2)

13) A. Observe the diagram again.

We know that electric field due to ring at a distance ‘x’ from the centre of the ring of radius ‘a’ is
given as
E = kQx/(a2 + x2)3/2
Let us consider a small element on the infinite rod of length dx at a distance x from the centre of the
ring. Let say the small charge on this element is dq.
Then
dq = λdx
So a small force on this element due to ring will be written as
dF = dq.E
(As we know that electrostatic force and electric field are related as F = QE)
Since the rod is placed at the right side of the ring so electric field is also towards right hand side
and the electric force will also be in the right hand side.
This small electric force will be
dF = kQx/(a2 + x2)3/2 .λdx
The total force on the rod due to ring will be given as integration of this small force, ranging from x
= 0 to x = ∞.
Hence,
F = 0∫ ∞ dF
⇒ F = 0∫ ∞ kQx/(a2 + x2)3/2 .λdx
Now for integration
Let say
a2 + x2 = t2
Differentiating both sides we get
0 + 2xdx = 2tdt
⇒ x.dx = t.dt
Also for limits of integration
When x = 0, then
a2 + 02 = t2
Then t = a

Also, when x = ∞ then t = ∞.

Hence the force due to ring on the rod will be


⇒ F = a∫ ∞ KQλ/(t2)3/2 t.dt

⇒ F = KQλ a∫ ∞ 1/t2 .dt


⇒ F = KQλ [-1/t]a∞

⇒ F = KQλ [(-1/∞) - (-1/a)]

⇒ F = KQλ/R

In the question we have calculated the force on the rod due to ring.
But since they form a pair, and we know that the force exerted by body A on body B is always equal
to the force exerted by body B on body A.
Hence the force exerted by the rod on the ring will be
F = KQλ/R

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14) C. The resultant electric field makes an angle of α with the direction of position vector of the
point considered.
Also, the position vector is at an angle θ, with the horizontal.

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So the direction of resultant electric field with the horizontal (or x – axis ) will be θ + α

15) C. Electric field due to infinite sheet of charge is given as


E = σ / (2ε0)
Which is independent of the distance ‘r’.

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16) B. According to gauss law
By using ∫ Ē.(dA) ⃗ = (charge enclosed inside gaussian surface ) / ε0
∮s(Ē1 + Ē2 + Ē3)(dA) ⃗ = (q1 + q2 + q3) / ε0

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17) B. ∅net = 1 / ε0 × Qenc ⇒ Qenc = (∅2 - ∅1)ε0

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18) C. For pair of charge U = 1/(4πε0).(q1q2)/r

USystem = 1/(4πε0) [(10 × 10-6 × 10 × 10-6)/(10/100) + (10 × 10-6 × 10 × 10-6)/(10/100) + (10 × 10-6 ×

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10 × 10-6)/(10/100)]

= 3 × 9 × 109 × (100 × 10-12 × 100)/10 = 27 J.

19) A. F = QE = QV/d ⇒ 5000 = (5 × V) / 10-2 ⇒ V = 10 volt

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20) B. K = qV = 2e × 106J = (2e × 106) / e eV = 2 MeV

21) B. We now that electric field due to positive charge is always away from the charge and in the

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case of negative charge it is towards the charge.
Diagram no 1– all the charges are equal. The distance of the centre point from the charges is also
equal. So all the electric fields produced will cancel out each other.
Diagram no 2–In this case observe the diagram given below we find that the charges present on the
horizontal line only will cancel out the electric fields. But the remaining charges are not same in sign
so these electric fields will get added and at the end the resultant electric field will be in east
direction as shown in the figure given below.
Diagram no 3–equal charges are present at the opposite ends so electric fields will cancel out.
Diagram no 4–here also in observation in first look, it seems that electric field is not zero. But on
carefull observations we find that Electric fields are in such a way that firstly (2E – E) = E will be
present. But this E is present in such a way that they are forming concurrent vectors with equal
magnitude. So the net field is zero.

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22) C. Now let say consider that sphere 1 is positively charged
So according to question
1 – 2 = attraction = it means 2 should be negative as we have consider 1 as positive.

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1 – 4 = attraction = it means 4 should be negative as we have consider 1 as positive.
Now
2 – 4 = attraction
But according to our calculations 2 and 4 are negative, it means there must be repulsion.
It simply means that 1 can not be positive.

Now assume that 1 is negatively charged.


So according to question
1 – 2 = attraction = it means 2 should be positively charged as we have considered 1 as negative.
1 – 4 = attraction = it means 4 should be positively charged as we have considered 1 as negative.
2 – 4 = attraction
But according to our calculations 2 and 4 are positive, it means there must be repulsion.

From this discussion it is clear that 1 is neither positive nor negative.


It means that 1 is neutral.

23) C. When there is no medium present in between the charges, then the electrostatic force will be
F = (1 / 4πε0) / (q1q2 / r2)
Now a substance of dielectric constant k is inserted between them,the new force can be written as
F' = (1 / 4πε0k)(q1q2 / (r')2)
But according to given condition these two forces should be equal, then F = F'
⇒ (1 / 4πε0)(q1q2 / r2) = (1 / 4π0k)(q1q2 / (r')2)
⇒ r' = r / √k

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24) C. When a plastic rod is rubbed with cat’s fur then the charge on plastic rod is negative and the
charge on cat’s fur is positive.
By convention, the charge on glass rod or cat’s fur is called positive and that on plastic rod or silk is

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termed negative. (NCERT page no 3)

25) C. We know the property of electrostatic force that if any other charge is introduced in the
vicinity of two charges then there is no effect of this charge on the electrostatic force between two
previous charges.

The individual forces are unaffected due to the presence of other charges. (NCERT page no 15 in the
section 1.7 – Forces between multiple charges)

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26) A. Number of σ bonds = 4
Number of π bonds = 4

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27) A. H2O
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28) B. Be2+ = (4 – 2) = 2
Is isoelectronic with Li+ (3 -1 = 2)
Since both have same number of electrons in their outermost shell.

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29) B. In NO3-, nitrogen is in sp2 hybridization, thus planar in shape. In H3O+, oxygen is in sp3
hybridization, thus tetrahedral in shape.

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30) B. BeF2 is linear and hence has zero dipole moment while H2O, being a bent molecule, has a
finite or non-zero dipole moment.

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31) C. Polarity of the bond depends upon the electro negativity difference of the two atoms forming
the bond. Greater the electro negativity difference more is the polarity of the bond.
(N - Cl @ 3.0 - 3.0) (O - F @ 3.5 - 4.0) (N - F @ 3.0 - 4.0) (N - N@3.0 - 3.0)
As the electro negativity difference between N and F is maximum hence this bond is mot polar.

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32) C. Bond order between P – O
= (no.of bonds in all possible direction )/(total no.of resonating structures ) = 5/4 = 1.25 ,
Or Formal charge on oxygen = -3/4 = -0.75.

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33) A. Boron in BCl3 has electrons in outer most shell. Hence BCl3 is an electron pair deficient
compound.
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34) D. The larger the size of the anion more is the polarizability

35) D. BF hybridization sp3, tetrahedral structure. NH4+ hybridization sp3, tetrahedral structure.
-
4

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36) D. It contain unpaired electron hence paramagnetic

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37) A. In O2-
It has total 13valence electrons to be filled in molecular orbital hence its electronic configuration is
given as
σ2s2 , σ * 2s2, σ2pz2, π2px2 = π2py2, π* 2px2 = π* 2py1
There are 8 bonding electrons and 5 antibonding electrons
Hence bond order = (number of bonding electron - number of antibonding electrons)/2
= (8 - 5)/2 = 1.5
O2- has bond order 1.5

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38) B. Hybridization in PO43- = 1/2(Number of valence electron of central atom + number of
monovalent atom attached to it + negative charge if any – positive charge if any)
= ( 5 + 0 + 3) / 2 = 4

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39) B. Maximum number of water molecule that one water molecule can hold through hydrogen
bonding is 4

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40) D. In XeF2 total number of valence electrons of Xe is 8, two electrons shared with 2F atoms, 6
elctrons are left hence three lone pair, in XeF4 four electrons shared with four F atom, four electrons
are left hence two lone pair, in XeF6 six electrons are shared with six F atom , two electrons are left

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hence one lone pair

41) A. The electronic configuration is O22-


σ2s2 ,σ * 2s2, σ2pz2, π2px2 = π2py2, π*2px2 = π*2py2, hence there are 8 bonding electrons and 6
antibonding electrons.
Therefore ond order = (number of bonding electron - number of antibonding electrons)/2
= (8 - 6)/2 = 2/2 =1.
The electronic configuration is B2
σ2s2 ,σ * 2s2, π2px1 = π2py1, hence there are 4 bonding electrons and 2 anti-bonding electrons
Therefore ond order = (number of bonding electron - number of antibonding electrons)/2
= (4 - 2)/2 = 2/2 =1
Both O22- and B2 has bond order equal to 1

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42) D. LiCl is covalent in nature due to small size of Li+ ion hence LiCl will ionise less than NaCl

43) A. Bond order in CN-, CO and NO+ is three and they are isoelectronic

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44) B. XeF2 and CO2 have linear structure

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45) D. Number of sigma bonds in P4O10 is 16

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46) B. Electronic configuration of N2
σ2s2, σ * 2s2, σ2pz2, π2px2 = π2py2, hence it contain all the paired electrons, hence diamagnetic

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47) D. In Na2O2, we have O22- ion. Number of valence electrons of the two oxygen in O22- ion = 8 × 2
+ 2 = 18 which are present as follows

vσ1s2, σ * 1s2 σ2s2 ,σ*2s2, σ2pz2, π2px2 = π2py2, π*2px2 = π*2py2

Therefore number of unpaired electrons = 0, hence O22- is diamagnetic

In O3 number of valence electrons = 6 × 3 = 18

Thus it does not have any unpaired electron, hence it is diamagnetic

In N2O, number of valence electrons of all atom = 2 × 5 + 6 = 16, hence here also all electron are
paired. So it is diamagnetic

In O2, we have O2-, therefore its electronic configuration

σ1s2, σ * 1s2 σ2s2 ,σ*2s2, σ2pz2, π2px2 = π2py2, π*2px2 = π*2py1

This it contain one unpaired electrons, hence it is paramagnetic

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48) B. This type of attractive force operates between the polar molecule having permanent dipole
moment and molecule lacking permanent dipole. HCl is polar and He is non-polar, thus givig dipole-
induce dipole interaction

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49) C. Hybridization in PCl5 is = ½[5 + 5 + 0 - 0] = 5, sp3 d hence the structure is trigonal
bipyramidal

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50) D. In HCl No-H-bonding, H—F form zig-zag, cage like by H2O only NH3 form linear polymeric
structure

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