Reg. No. ca conten ig MANIPAL UNIVERSITY ay famcoorure 7 ender — ‘THIRD SEMESTER B.E. (CHEMICAL ENGINEERING) END-SEMESTER EXAMINATION ~ NOV/DEC 2007 SUBJECT: CHEMICAL ENGINEERING THERMODYNAMICS (CHE-207) REVISED CREDIT SYSTEM. Time: 3 Hrs Max. Marks: 100 Instructions (o candidates: : Answer any FIVE FULL questions © All questions carry equal marks © Missing data, if any, may be suitably assumed 1A. Explain the following giving examples: (i) heat and work (ii) reversible and irreversible processes (iii) open and closed systems (iv) internal energy and entropy (12) 1B. State the first law of thermodynamics. What is its limitation?. Derive Bernoulli's equation using the first law of thermodynamics. (08) 2A. What are the four basic thermodynamic processes?. Explain them by tracing in a relevant thermodynamic diagrams. (06) 2B. Derive the modified dU and dH equations from the fundamentals, stating, clearly all the constraints involved in the derivation. Hence show that for an ideal gas U , Hand Cy are functions of temperature only a4) 3A. What are the basic characteristics of an ideal gas? (02) 3B. Why is a third parameter required for the calculation of compressibility factor? Explain any one three parameter correlation used for its calculation with relevant charts, Discuss the behaviour of various types of isotherms. (12)6A. OB. 6c. Calculate the pressure developed by 1kmol of gaseous Nitrogen contained in a vessel of 0.6 m? capacity at a constant temperature of 100°C by using: (i) Ideal gas equation of state (i) Vander wall equation of state a= 0.4233 Nm/mol?; b= 3.73* 107m’ /mol Compare the pressure and comment. A compressor is fed with 0.25 (m3/s) of dry air at 0.IMPa total pressure and 30 deg C which is flowing in an entrance pipe of 0.154 m in diameter. Down stream from the compressor a cooler removes 276.4 (MJ/h) from the gas. In the exit line of 0.028 m in diameter, the air is at 43 deg C and 0.55 MPa total pressure. Assuming the gas is ideal with a molal heat capacity of 29.3 ( ki/ (kg.K), determine the power input to the compressor. lain the cycles used for the thermodynamic analysis of the following cases giving relevant diagrams: )) steam power plant i) gas based power plant spark ignition engine (iv) refrigerator Discuss the corresponding Carnot cycles and give all the equations for the thermal efficiency / COP of all the cycles Explain the Dual cycle with diagrams. What is the necessity for the development of Air-Standard cycle for the thermodynamic analysis of internal combustion engines? ‘A vapour compression refrigeration system with ammonia as the working fluid is to operate between 266K and 300K. Determine the following: (i) COP, given that the enthalpy of saturated vapour at 266K is 656 (ki/kg) and enthalpy of superheated vapour leaving the compressor is 724(kl/kg), enthalpy of saturated liquid at 300K is 144(kW/kg) Gi) COP of the corresponding Carnot refrigerator What is the assumption you make to solve the problem? (06) (20) (20) (08) (04) (08)