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Urea [(NH,),CO] is prepared by reacting ammonia with carbon dioxide: 2NH3(g) + COx(g) —> (NH3):CO(aq) + H,0(1) In one process, 637.2 g of NH are treated with 1142 g of COs. (a) Which of the two reactants is the limiting reagent? (b) Calculate the mass of (NH,),CO formed. (c) How much excess reagent (in grams) is left at the end of the reaction” ‘The food we eat is degraded, or broken down, in our bodies to provide energy for growth and function. A general overall equation for this very complex process represents the degradation of glucose (CeH)0,) to carbon dioxide (CO.) and water (HO): CiHy0, + 60; —> 6CO; + 6H;0 If 856 g of CyH,sO, is consumed by a person over a certain period, what is the mass of CO) produced? Assign oxidation numbers to all the elements in the following compounds and ion: (a) LiO, (b) HNOs, (c) C07”. 4.11 In a titration experiment, a student finds that 23.48 mL of a NaOH solution are needed to neutralize 0.5468 g of KHP. What is the concentration (in molarity) of the NeOH solution? How many milliliters (mL) of a 0.610 M NaOH solution are needed to neutralize 20.0 mL of a 0.245 M H,SO, solution? ‘A mixture of gases contains 4.46 moles of neon (Ne), 0.74 mole of argon (Ar), and 2.15 moles of xenon (Xe). Calculate the partial pressures of the gases if the total pressure is 2.00 atm at a certain temperature. pe the root-mean-square speeds of helium atoms and nitrogen molecules in 1 at 25°C. ‘A flammable gas made up only of carbon and hydrogen is found to effuse through a porous barrier in 1.50 min. Under the same conditions of temperature and pressure, it takes an equal volume of bromine vapor 4.73 min to effuse through the same barrier. Calculate the molar mass of the unknown gas, and suggest what this gas might be. Calculate the change in internal energy when 2 moles of CO are conver d t0 2 mal, of CO; at 1 atm and 25°C: 2CO(g) + O2(g) —> 2C02(8) AH = ~S66.0\i A quantity of 1.435 g of naphthalene (Cyt) ‘ f moth repellents, was burned in a constant-volumne bomb calorimeter. Consequently, the temperature of the water rose from 20,28°C Lo 25. 95°C. If the heat capacity of the bomb plus water was 10.17 KI/°C, calculate the heat of combustion of naphthalene on a molar basis; that is, find the molar heat of combustion. A lead (Pb) pellet having a mass of 26.47 g at 89.98°C was placed in & cor calorimeter of negligible heat capacity containing 100.0 mL of water. The temperature rose from 22.50°C to 23.17°C. What is the specific heat of the lead pe Het? The wavelength of the green light from a traffic signal is centered at 522 nm. What is the frequency of this radiation? Ea Calculate the energy (in joules) of (1) « photon with a wavelength of 5.00 % 10" am, (infrared region) and (b) a photon with a wavelength of 5.00 X 10-7 nm (X ray region). To Leddne 4: Isotope composition 9 ——— eSeSes—sS aA vampk 4 tahraly euwieg ciliton anit ¢ 7G (a8. 9S amu) ond * G (49-9798 umu) «IF maou _4, is 28 0p66 amu aide _notwal i $2637. what ee rafal aburclave vou 9 lectiy 2: so fepic Abundone, 2 pies Rubidium —har_2 natiraly oausry xoppe “© Rb % a masc wy $4. ag amu and Rb maw g By. 90% amu. If he eS ahnic vat 4 rubidium ic %6 9? » whor is the lative abundance & re By? | tea #3" pumber twos, Nardone ond How ony poo, ceuton’ and vlechont are in the amtnic_tempound? Ca Hs 07 7 silly eke Lecson “Nhich is ned polar 7 Se Us ty Cla CHC Colaiakng te omownt ef fat Ped? given: j__ as + AH —> Cath + MO + 7 nay like 4 (> fm at

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