1.

𝑆2 𝑂8 2− + 2𝐼 − → 𝐼 2 + 2𝑆𝑂4 2−

Velocidad de reacción= 𝑘 [𝑆2 𝑂8 2− ]𝑚 [𝐼 − ]𝑛

Temperatura del experimento: 21°C

2.

EXPERIMENTO [𝐼 − ] Inicial (M) [𝑆2 𝑂8 2− ] Inicial (M) [𝑆2 𝑂3 2− ] Inicial (M)

N°1 0.036M 0.036M 0.0018M

N°2 0.036M 0.073M 0.0018M

N°3 0.073M 0.036M 0.0018M

N°4 0.036M 0.018M 0.0018M

N°5 0.018M 0.036M 0.0018M

CALCULOS:

EXPERIMEN [𝐼 − ] Inicial (M) [𝑆2 𝑂8 2− ] Inicial (M) [𝑆2 𝑂3 2− ] Inicial (M)

TO
2.0 𝑚𝑙 ∗ 0.20 𝑀 2.0 𝑚𝑙 ∗ 0.20 𝑀 2.0 𝑚𝑙 ∗ 0.010 𝑀
No.1 = 0.036 𝑀 = 0.036 𝑀 = 0.0018 𝑀
11 𝑚𝑙 1𝑚𝑙 11𝑚𝑙

2.0 𝑚𝑙 ∗ 0.20 𝑀 4.0 𝑚𝑙 ∗ 0.20 𝑀 2.0 𝑚𝑙 ∗ 0.010 𝑀

No.2 = 0.036 𝑀 = 0.073 𝑀 = 0.0018 𝑀
11 𝑚𝑙 11𝑚𝑙 11𝑚𝑙

4.0 𝑚𝑙 ∗ 0.20 𝑀 1.0 𝑚𝑙 ∗ 0.20 𝑀 2.0 𝑚𝑙 ∗ 0.010 𝑀

No.3 = 0.073 𝑀 = 0.018 𝑀 = 0.0018 𝑀
11𝑚𝑙 11𝑚𝑙 11𝑚𝑙

2.0 𝑚𝑙 ∗ 0.20 𝑀 2.0 𝑚𝑙 ∗ 0.010 𝑀 2.0 𝑚𝑙 ∗ 0.010 𝑀

No.4 = 0.036 𝑀 = 0.0018 𝑀 = 0.0018 𝑀
11 𝑚𝑙 11𝑚𝑙 11𝑚𝑙

1.0 𝑚𝑙 ∗ 0.20 𝑀 2.0 𝑚𝑙 ∗ 0.20 𝑀 2.0 𝑚𝑙 ∗ 0.010 𝑀

No.5 = 0.018 𝑀 = 0.036 𝑀 = 0.0018 𝑀
11𝑚𝑙 1𝑚𝑙 11𝑚𝑙

3. ∆[𝑆2 𝑂3 2− ] = −0.0018
4. Tabla de Velocidad de reacción del Ion

EXPERIMENTO ∆𝑡 (s) ∆[𝑆2 𝑂3 2− ] (M) Vel 𝑆2 𝑂8 2− 𝑀⁄𝑠

N°1 3.8 s −0.0018 2.34 × 10−6 𝑀⁄𝑠

N°2 92 s −0.0018 9.8 × 10−6 𝑀⁄𝑠

N°3 198 s −0.0018 4.5 × 10−6 𝑀⁄𝑠

N°4 ---- ---------- ------------

N°5 2.69 s −0.0018 3.3 × 10−6 𝑀⁄𝑠

CALCULOS:

EXPERIMENTO Vel 𝑆2 𝑂3 2− 𝑀⁄𝑠

1 0.0018𝑀
N°1 Vel 𝑆2 𝑂8 2− = 2
( 385𝑠 ) = 2.34 × 10−6 𝑀⁄𝑠

1 0.0018𝑀
N°2 Vel 𝑆2 𝑂8 2− = ( ) = 9.8 × 10−6 𝑀⁄𝑠
2 92𝑠

1 0.0018𝑀
N°3 Vel 𝑆2 𝑂8 2− = 2
( 198𝑠 ) = 4.5 × 10−6 𝑀⁄𝑠

N°4 N-A

1 0.0018𝑀
N°5 Vel 𝑆2 𝑂8 2− = 2
( 269𝑠 ) = 3.3 × 10−6 𝑀⁄𝑠

5.
𝑚
𝑣𝑒𝑙𝑜𝑐𝑖𝑑𝑎𝑑 2 𝑘 [𝑆2 𝑂8 2− ] [𝐼 − ]𝑛
= 𝑚
𝑣𝑒𝑙𝑜𝑐𝑖𝑑𝑎𝑑 1 𝑘 [𝑆2 𝑂8 2− ] [𝐼 − ]𝑛
𝑛
𝑣𝑒𝑙𝑜𝑐𝑖𝑑𝑎𝑑 2 [𝐼 − ]𝑛 [𝐼 − ]
= − 𝑛 =( − )
𝑣𝑒𝑙𝑜𝑐𝑖𝑑𝑎𝑑 1 [𝐼 ] [𝐼 ]

9.8 × 10−6 𝑀⁄𝑠 0.0073𝑀 𝑛

=( )
2.34 × 10−6 𝑀⁄𝑠 0.0036𝑀

2=2n
n=1
6.
𝑚
𝑣𝑒𝑙𝑜𝑐𝑖𝑑𝑎𝑑 2 𝑘 [𝑆2 𝑂8 2− ] [𝐼 − ]𝑛
= 𝑚
𝑣𝑒𝑙𝑜𝑐𝑖𝑑𝑎𝑑 1 𝑘 [𝑆2 𝑂8 2− ] [𝐼 − ]𝑛

𝑚
𝑣𝑒𝑙𝑜𝑐𝑖𝑑𝑎𝑑 2 𝑘 [𝑆2 𝑂8 2− ]
= 𝑚
𝑣𝑒𝑙𝑜𝑐𝑖𝑑𝑎𝑑 1 𝑘 [𝑆2 𝑂8 2− ]

𝑚
𝑣𝑒𝑙𝑜𝑐𝑖𝑑𝑎𝑑 2 [𝑆2 𝑂8 2− ]
=( )
𝑣𝑒𝑙𝑜𝑐𝑖𝑑𝑎𝑑 1 [𝑆2 𝑂8 2− ]

9.8 × 10−6 𝑀⁄𝑠 0.073𝑀 𝑚

=( )
2.34 × 10−6 𝑀⁄𝑠 0.036𝑀

4.2 = 2.1m

m=2
7.ley de velocidad determinada para la reacción
Velocidad de reacción= 𝑘 [𝑆2 𝑂8 2− ]2 [𝐼 − ]1

8.

2
𝑣𝑒𝑙𝑜𝑐𝑖𝑑𝑎𝑑 𝑑𝑒 𝑟𝑒𝑎𝑐𝑐𝑖𝑜𝑛 = 𝑘 [𝑆2 𝑂8 2− ] [𝐼 − ]1
𝑣𝑒𝑙𝑜𝑐𝑖𝑑𝑎𝑑
𝑘= 2
[𝑆2 𝑂8 2− ] [𝐼 − ]1

2.34 × 10−6 𝑀⁄𝑠

𝑘=
[0.036 𝑀]2 [0.0036 𝑀]1
.

𝑘 = 5 × 10−2 1⁄ 2 ∗ 𝑠
𝑀