Homowork 1 CChemie6201; Fundamentals of Chemical Engineering Assignment 1 1. The schematic below shows the flow sheet for the production of ammonia from nitrogen and hydrogen. The feed stream is a nitrogen and hydrogen mixture in the 1:3 ratio required of the reaction chemistry: N, +3H, > 2NH, Trace amounts of the inert gas argon (0.1 moles) occur in the feed (100 moles). In the converter, 10 percent of the nitrogen and hydrogen react to form ammonia. The ammonia product is removed by the condenser in which only ammonia Is liquefied, and the unreacted nitrogen and hydrogen, along with the argon, recycle to the converter. Without a bleed stream, argon would only enter the process and would accumulate to dominate the recycle. The bleed stream vents part of the recycle stream to prevent the buildup of argon. {f-for-the proper performance of the converter, its feed is limited to 0.5 percent argon, what (fraction of the recycle stream must be vented? The Table 1 includes all the flow rates in the process. Fill out all the flow rates in the table. @© Recycle Np, Hp and Ar | Bleed N,, Hy and Ar ‘Ammonia Converter (300 atm) Condenser 2 (0.5% Ar N28 moles sithe stream = Ar-O.1 0) NH; Fig. 1 Ammonia Production Table 1. Material Balance on Ammonia Process_( mates) Fresh | Converter | Converter | Condenser | Ammonia | Bleed | Recycle Species | Feed | Feed1 | Effluent2| Effluent3 | Product4| 5 6 No se 208 12hS 18.5. ¢ BE 728 He | LAS sind S357 oO | as fe Ar Ot hl eh wl o aah ¢ NH. @ ca 2 YI a e © 2017 Cornel Universit. Al rights reserved. All other copyrights, trademarks trade names, an logos are th sote property of thee respective owners.+ ar ected Fob. 1 Of By Ort neglected) fe He Cha) De ——— r © — o —_)—— ——} > seh Ma feet Ares) OS (Br) 22S OUR | Ha Cb) 984 @ py c#s) ov Na He V Ar (elt Ry? a9) wonky Ha pe en) Arne! hH3 9g NH CSHB) Ode = HE OE too2kr OFIF Rit Br ~Gs4hi)vad BIR +BY = 22 2D 00 Bre 22.6-5.7R, ie Be 9.5.9 gen eWR3= P3483 3 By 28 Bo 43 CrS-o) Ri)ool = Ry > DPi= 180.32, D Ri 3K, = 540.66 , Py ETO PIEY C2S4 18D) OID = 4 0F fb to028; ere ~9 2B 4 ov (FPS RI Wo, YOR, ° 2. OYR, —O. 3/052, Gro x] —© Os F 4ore ig 2225-1 RIS 448 — O 21nd) — zoBy ae = O2EkS NiOS#PD ea ArcoD Arlt) WH QO: wes, ott Ps =o. 00s [oo + Rit ke a ee cece Ria aert Pe BxC2S HR) Kare CITE DKS | GS#BR = ®>.0 Ov | tRy = 0.54 028k Pz = b+ 002K, ——Srrepyotynnrg gs4Rr 3k = kr on Ne Ha cys) Happs4ee) asl - | © on As Hr: Ar: e Costhe) KO Prove OF Bow neglected as trace jn esi cles nto) ye ca ante?! 1 (Bo) 3B Arch) oy > Veeco) @ ne Dosti) CONE? fin @ Cort ipop pater = | Nas = 184 SF CIS4H Bi) KOT = ESPS ott Pee hd ow to.02 Py Cruse (Ri) a-t= Fre eas @.@ Ri + Bi = C25 4k) K2.7 =) Rt (80, 3F — @ OD RAAB, = 3207 D Br =3hr= She Bye ru Sol eke hz = Ou to.02 Kieoe & re Be @. 8-8 mye a Br a ane ot he Ee IF R3=R3 tBs =) By =o [ Bo = Bx QT (KS By >a]Pressure: J bo tor 2.Consider a binary mixture of acetone and toluene. Assume acetone and toluene form an (‘ideal’mixtdre, and the vapor pressure for the pure compounds can be obtained from the ‘Antoine equation, fs ) sat (A~ Tae at logy Pe = 4 - wr f’ 2 eC where PSat is in torntt atm = 760 torr = 101.6 kPa) and fis in °C. The Antoine constants for acetone and toluene are, component A B c applicable range acetone 7.63130 1566.690 273.419 57 to 205 °C i ¥ toluene 6.95087 1342.310 219.187 —27to1149C (A) Estimate the boiling points at 4 atm for pure acetone and pure toluene. Acetone bos 2b2;30- (EEE EZO Ppops-viy mopnerg = 66377 Ce) | toluene: _p 13 ¥rdre g2ho = 6.9ree7 ~ 12% W200 = © OSE7 ~ Tag 187 > cap 94187 = 110. bE LC) (B) Calculate the bubbie point fora mixture of 40, mol % scetone and 60; mol % : Liege tact Daten beBacalh's Lewd Yas 4 , 0. TEEING [0% y= 182049398 7 (ol br Tser? — a7 se i ey egyR20el , Y boa, Pramas) 734 144 = 6399529 (C) Calculate the dew point for a mixture of 40. mol % acetone and 60. mol % toluene, pase guess oe 1 (a9m4 Antoine egs ane eae ot oe ace tone’ Pa = [ph OBO” Brapw I opp ret 2372 Kaa FOE P Lola ene Pt = po 69857 BE aay sr sild Ke = eens 263209 f gt OlelTD (0) Gatulate he Fav and apo? compositions for a 40. mol % acetone and 60. mol % toluene mixture, ium with moles liquid / moles vapor = 3. (foal P= 96p torr) Liguid acetone mole Xa, Binetwning | By trial ands error Cby sng excel) Ligeik toluene pape Kofinctn% | ete | Pact Eten) oC) Heycte) Vapor acetane male Yn, fisctor “Ye | fw bl RG | PLo [ Po 56.3769 106143 3 [ins laos BE 995| 03.2 6705 we toloene mI Vy, fiarton #67 | 64 0.33 jugs! 20-4783 3p. Aine eae ape O60] poses Moy. eop Dottes| Thee) OF ca Oa | aamade 2 | oaens [orise gee pooys pusinh aprnet es (eet amuse. [aslo par bie ha | he cot | Ty yo b~3K4 Badel Lotto lo. cree4 fo. 30343 17se-911 - | 7d 5, 30136), CIGOARKD. oP] a SYR LISTEPi, 2 (Pressure = 940 torr) a) Leg Pe a we Reston Log Bb0 = ROHIV0- aa —Ynso4ee 2 — (966.676 tt ape Pedy ~ 16h Jo LISCES GS E24 D= 399.99 £2 66.397 Co) Cb) Trial and err Coonider arbors | as get) 10 ques ave Pa= 1598. 9902] , ya rag aeqet Pe = 247.3029282, Ye = 0.909996 Yarye = hobedbh ot agers swalley mess Pe Pas HUE AEST, Ya > Pe = 262-262659 Ye ln + Y = 0.968. ! 9 guess a5ee Po = 2392.39024 , Xa= 0.129090 Pe = borsesy jy ¥e= O4SS4F>> Het Fe = pobz9gg >) aguess Larger D jue anste Pa = 3586. 60899 p¥qz OBIS FLO Pe = st. sugrsus, Ke» 0. BR UEIDO Hate = Peers alert! error (consrker mxtare-rs 9 goon lege Mot Hy = Hecoysge 2 Gasqe = hevedi¢r | atmeste @ guess 96. % Ba = 149 G f2/ 72K 2 Ya = O2BEITIE | Pee apa etrave, Ye zo s752g 5¢ Yate =n 00/ ¢bs — SL a be ble pore ot just wneer guess We eg 22187 fo = 232200944 1 Kas Os2etze Pe Son esi bY, Kee 89g 538 Nat Xe = org D gees longer O guess 9% Pa = SPI GEYS , a 20.112 00D Pee S235 019, x4 2 D9 0993 Kathe 2 098 PL 3c > ger seeller Oguess 7.6% Pa =>562,3) 287) Haz OD EWIT ee t feud point 3 arene Mow