FOPNOTCH MEDICAL 80, For inguin vist wa eat? BIOCHEMISTRY PEARLS BY RONNIE. BATICULON, MO Ron ‘ttepnotenboaranman sm 3h ror Bios we Facebokes ~ formation of reactants, what to prods | isthe value of? ; See | apocyes - i Detradation ode TAC [Tre reqaremenira mall intestine on oxidative phosphorylation Degradation of FAG—— Two pathways where fusing nc race oc transport of electrons by the ‘Adenine, Guanine. = Say Hypoxanthine Nn: depratedwohphiokie | | erastoamse eae ‘reaction velocity varies with -eatzupotne For NADH | substrate concentration [Fenty point for Fan? ——] This is 3 double reiproca ‘Generation of proton gradient lot used to caleulate Km and ‘ATP production by oxidative Vmax a wellasto determine hosphorylation the methanizm of ation of Non-proten component enzyme inhibitors | Mobile components of ETC Substrate concentration at —] which the reaction velo is Fil decron scepter qual to Uae Cir Maximal Tena PRODUCTION Aspirin The structure ofthe nhbtor ‘Amt rotenone, esembles the substrate barbiturates, Vint is owered Oligonyem Tr does not change eet ‘Afinityofenyme tothe ‘Carbon mononde, cyanide substrates decreased hydrogen slide The inhibitor and the Dimercapol Atimgan A substrate bind a diferent Malonate TEA sites on the enzyme ‘Atraetylorde Nalathion’ eect on ; acetylehoineterase Simvastatin effect on MG [1 Cohreductase be of gucoseto mmolecle of ether pyruvate What isthe formar orlacate standart fre energy? [West commanypeat Measure of energy salable [2 lvesisie tadowork Production ogicos Fom Messe of andomnes precursors suchas laate Measure ofhestreleased o Blyerl lacogenicaming absorbed duings reaction ds intermediates of Fre energy change under fiveolyss nd Tek yee standard conditions Synthesis of storage frm o7 (rentants and products a Carbohydrates rm UDP. rift) sucose Fora reacion oe Syhers TES Spontaneous ond favorable, | Bemossheierate ‘what shouldbe thevaluect | Tariva ol Goose Fame 30) storage form (Chav offormation ofprodoas | Prodsces NADPH Fase eesvos reuse HATE SYFor inquire or BOARD Prep. BIOCHEMISTRY PEARLS BY RONNIE E, BATICULON, MD @SirRonMD prep/ snd provides aca Ss t2bntehbourdprep,com.ph or oF Nps acebookcom/Ropnotchmed\calboat pret Metsnen anism for | PATHWAY era Fatabolic use of SC sug “ay Smithers fesse tenes a nual Common pathway fer ‘carbohydrates, lipids, and Grcogen sess san [asia — marannree ——— setofelecroncamens —— 04 nentone night fie soluble compound in humans pears Otiername ofthe wes ee [Bearon rapa can Seatene aaa ro — acer con Srekdown pala cen Con om Synthesis oTaReratve a etaboiful fom sag rari Con during fa Lactate in exercng mands convereduckto fucose, In muscle pravir | tanseminated to frm i | alanine wen shared theiver where the ann [ieee monophosphate st sroupentrstheuren ge Faty sash Secthepyravateisuseds Imake ico whichis Bea aaa lumedbacktomuice _ Further elongation and vides the glycerol desaturation of tty acide : | Hexave Monophophate Shunt TAGE Tica anspor cae backbone oftracypiycerl in ae liver and adipose ss, and i ‘carbon skeleton of sonezenal amin sls Degrade o ome Provides the energy requied ‘Oxidation of very Tong cain by gluconeogenesis fatgyacids [ Only two pathways present in facts erythrocytes (Trceyiaveoroteyathens — Teconvert purines abuaned [-resclavcorol synthesis from det and turnover of Protein gee Sess ebeaeai ‘Degradation of sphingolipids, eos i Beenie, cence ———} anEieom Gluconeogenesis “Transport of cytosolic NADH, fe tothe inner mitochondrial Giyeagenests membrane, present in rain ‘Glycogenaisie and white muscle ‘Transport of etosoie NADH Texase Monophoaphate Shunt tothe nner mtochondtil ‘membrane, present in heart TEA Gye muscle and most tissues “Transport of mitochondrial Tipogenesie acey-CoA nt the eytoplasm Tpolysie to produces 16-carbon fatty a Ketogenesis "Transport af resale Cholesterol Sjathess palmitoy-Coa int the mitochondria for beta Te Ad Symtewie oxidation ‘Steroid Hormone Sthesie {ATs produced from eae anaerobiosis, TPs produced rom ae Fae Sp ae AYPs produced rom each Pars eneinors molecule of FADH in TCA APs produced rom eich De Nove Pyridine Stes ccromesten ies = [iat Ps produced rom comple TOPNOTCH MEDICAL BOARD PRE IEE. BATICULON, MD @SirRonD Page 4 of 10 For inquires vist wovw.topnotchboarpreo.com.ph or o http://www facebook, com/topnetchedicalbosrdprep/For nn ch MEDK Tot Inquest mane to PREP Bo = re. ten INISTRY PEARLS BY RONNIE, BATICULON, MD @sirRonM ATPS produced PCa deere es —— gee [2tidation of palmitate Peete ATPsreiredio cee molecule of ures IRM of sont ATP required teats —| ‘Activator of PFK-1 7 | [ty acids (0, seach On pivaton of CFS APs required te comes | boss? to Pare | ATS required te acr aoa —| sent patente srinidtinegene cslsandsetelsot he Polycepsie chain during —— Tansition Phosphoratsgacose nd athe erases Mest comma Functions asa glucose seator” Producing enayme deficiency inthe maintenance of blood [reese sucerhoncsss | Brravate > ane51toA——] = Prravate > Lacate et Una a Repent Hietwate > emanat ‘Tenptoyie doen Syravate > Alanine peas cess | B9PA=> Dopamine ———~ Dopanine > NoreinagITa Pyrvate> Ltt Nerepinepiiae ey 9a 3 alias [Giatmate > casa —— [scoriaare fine > Hite detycogenace Pheslalanine 3 Tyree Nabe dehydro Thelveris sbletomuce icra dehy depese [Hecate cehydegense ketone bodiestur crane Asse tlie them duets sence of Succinate Ogee Muscle unable vo provide tree ] lucas fom gycopenclyss Predominant hormone nthe ‘ue to lack ofthis enzyme inc fe state [[Sehane coli agney and Hormone that help maintain *etinalck this enayme to Dood glecose levels during metabolize srttel causing sarvation ama - Beet effec simiarta Enzyme deficient ia Rumans scagon ich is why we canoe Ratio of arbor dione synthesize viaminc—__| produced oxygen conta Creates a(T-4 linkages and Main metabolic vel of longates he gyeogen chains | neurons and erythrocytes | Transters 58 lucesyl Main metabolic eel of eat residues and ereates (1-6) muscle Nnages Main fuel ofthe sialon Cleaves a4) bone heart muscle, ane strmative produce glucose 1P fue othe rain drig ast Geaves al and o(-6) Tercetagecithebaine bonds to produce ree glucose | energy reurement that an irreversible eraymes bemetby ketone bodies ras duet of aerobic coh ot Product anaerobic] vets Product cTaeoeraia iw ler | | [ PoeuctcTahsapenopa Ta ee muscle “Through this enayme, amino ‘Building Block oT ata Tnaymes of Guconeogenens thatreverse the reversible | stops in ayctyis acide tater tr ome sections soups to gutanae Nas er “Through hr eayme,——] acneogneis during fas firme een” thereat at can eter Ecaminte to iberte foe ered {ammonia ‘uring the Bist 18 to 24 hours ‘Through tis ony, ofstarvaton which pathway sfuamine is syrthesized from Is responsible maintaining [ltamate nd ammonia Blood lacs level? Bn carne TERE ooo [lstamate nthe hicneys and son ay» fncestnes ‘sponse or mata liponueleotides 3 | blood glucose levels? _| tem _, fea - 5 ND @SiRonO Page 5 of ‘TOPNOTCH MEDICAL BOARD PREP BIOCHENISTRY PEARLS BY RONNIE. BATICULON, Pure S For inquires visit wan, opnotchboer preD.con.oh oor hips: wae feebok,cemvtopnotcedcaboarprep/TYSTFTES VIE Wor, topngten CHEMISTRY PEARLS BY RONNIE E, BATICULON, MD @SirRonMD PN ONEO Enea Dat OSCR teat prep.com.ph OF oF Nttps// www Jae phook eermeoeeeoeedicalboardprep! in the kidney during so = te fe rslongac rhe saccingl CoA Frstonged fat 8 All amunotransTeraees 4 lours ef fasting before ——}. Carbowyltion of glutamic acd j#tsoken stores are exhausted 'ause of death in stone Sa Saat a polonged —] factors Contactor Metabolic effects of ——— and component of fatty acid Uncontrolled diabetes a melitus ‘Glycogen phoaphonisee | 4 [increases ron absorption. Ye Conversion of propiony! COR} ¥ oxiucose _| 4 synthesis of glycerol and ‘ot strictly Ramin becaue nonessential no aes scan be syathesiaed inthe Retoacidosis with = $— ody from an amino aid 4 pbeperaivcemia Required te sythesige nada etozeidoss wih Som tryptophan 4 | byporiycema Really s hormone q Critical intermediate} | [nao ast onaine ‘ecessary to maintain TCA 0 prectely defined ‘cle activity usually depleted metabolic function 4 in rolnged starvation nd [emer fon carbon ae q alcoholintake [[DoPA decatbosyias q ‘TCA intermediate Tate Dopamine hydroqisse | ] depleted during sanionine sate q hyperammenemia ethiovinesyrthaxe q ‘TCA interne RATTLE Intense yellow eclor used tothe ureaycle food addhive Formula for BMI computation esd to st hyperipiaom | [Bermatkis chess gosuas ‘State of nitrogen balance in Burning foot eyndrome pregnancy ickets and osteomalacia ‘State of nitrogen Balance Ta Hemolysis malignancy Veacing caved of preventable 7 Which 3 compounds are the ioaness di immediate donors ef the Wemorrhagic dacase of te toms of urea? newborn | ecketoacid of slanine | | ‘Subacute combined ‘esketoacid @utemate | [degeneration eketoack | [Megaiotiasticanemia ‘Amine aci thet performs a Fernicous anemia Pyruvate kinase High epinephrine Dilation of blood vessd ‘ushing Iver cam: HMC CoA reductase Least toxic of fat-soluble 4 High cAMP vitaming Hormone sensitive lipase ‘Most toxic of water sehuble 4 Phosphorylation itamine Glycogen synthace Dephosphorylation ‘SRN of vitamin A deficiency, rruvate dehydrogenase ‘Transketolase reactions in the HMP Shunt Prevents atherosclerotic aque formation Normallzes calcu Tevels tw response wo hypocalcemia _| | Major source of WaminD Main storage form of vitamin D ag cast Haag an [Grameen — Teeter fea 0 Iytroftonf varia 8 certs ot |_| liafaocees Kira deeme ancl ions oe | Tietssenzwanpeage ee wr | [binding protein secretedTCH MEDICAL. UITI€S Visit wwe For ing Sicenretein serena by —t intestinal bears Vitamin Bi OCB deficency leads impairment of meth Synthase, resulting in = accumulation of . homocyste folme se methyltetraby drofelate ce fel Senin aw egg whey —] inhi es inhibits absorption of biotin Coagultio system protein alfeced by vitamin Gletum-bindingproteing Bar| equite vitamin J Ne and trapping Anemia and hemochromatari Glutathier f ne peronidase Cartonic anhydrase alcohol —] dehydrogenase, DNAaNG RNA | Gytochrome oxidase} opamine B hydroxylase, ‘monoamine oxidase, rosinase “Thyroid hormone synthesis [Tnorganic substance ofbones ‘and teeth gas Rules ins uracil Usually double stranded More susceptible to hydrolysis DNA tRNA’ RNA to Protein DNA to DNA. RNA to DNA. Pribnow Box Hogness Hox. CAAT Bor ‘Shine Dalgarno sequence Lac Operon Rho and Sigma Factor ‘DNA stranc copied during RNA synthesis DNA strane matching the sequence ofthe RNA transcript Short T-Grepeate at end oF ‘exch chromosome responsible foraging or cell survivability and malignancy | (Coding regions of DNA Noncoding regione of DNA ‘Unwinds double hele Removes eupercoils Identifies origin of replication ‘pnthesie of RNA primer Maintains the separation oF ‘he parental strands Elongation ofleading strand |) inthe’ 103 direction Excision of primers Seais the nick between Okazaki fragments Synthesis of FRNA. YARD PREP Yanan? BIOCHEMSTRY PEARLS BY RONNIE E. BATICULON, 1” =< ph oF oF httpes/Awnvw facebock.com (eee Sralest ‘ [ Most abundant Contained in themachinery 1 {or protem syathesie Carries geneuc information Irom nuclear DNA to the ‘ytosol, servesas the template for protein synthesis Contains abundant anual bases [rota a CCA sequence Cloverleaf shape and server aa the adapter molecule during translation Metiylguancaine cp Contains the codon ta Contains the anticodon Conserved fromvery early Yt stages of evolution Given amino acé mayfave —[q han one codon coding Cedon always code forthe | same amino acid ‘No punctuation beaween codons [Empey NA, rowing peptide chain Incoming aminoacy! tA [Foive te 3 stop codons ive the codon for methionine consisting af repeting units ofan sugars and eile [Provensvownich ig oligosaccharides are attached Cate patente which i ycosaminoglyeans are ached Derwvatvescfeeramide ——[% Alccholatached bya t phosphodiester bridge to Aicygicerel Phospholipc witha Hl sphingsine backbone No sera repeats, reatvey short carbohydrate chaine May contain glucuronic acid and iduronicacid May contain i actyiglucosamine and N- acetylgalactosamine May contain choine, i «ethanolamine, ering inositl include cerobrosdes, i ebosies, angiosices, sulfatides Include yaturonieaed [1 chondrotin sift, keratin sulfate, heparin, heparin sulfate, dermatan sulfate Include mucins, TSH, ‘For inguities vine eOARO PRED gy = Setomerane tone wit on ISCHEMISTRY PEARLS By RONNIE E. BATICULON, MD @SIPRETMD, pons pre cal her or Mpg /aenfatbock con “~~~ BESET — 2 [reduetsce | server on ma Thessntiosaraaee Ti " ena Farce srtntacaral DNA se [preci oacoug Sattar [ imporanc eon {ope ee | myelin a ‘This amtneoplonicand [ierantataai — lenin dat tracts water ins byeretlate into he ECM | reduce ‘or cell migration, repa Memnd "The anineoplanic ag Inhibits hymidyate sythase and eases thyminedess cell Determines ange -— one mse ot Homeruhue "Toxicy Fon oe catedat ster ——— artmycobacteral drugmay ‘aletieatien of ene beallevited by bene poses | acminisration ofViamin B6_ | Hestiiatieas—| Ths armor dag Maina nbs NA dependent I oo ibs dependen RNA cornea poles | | teantandprancive — This once " | retanone pepndytransfrase and tide bor formation “This ani prevents binding ofaminoacy RNAE Twanspor molecules Tnmunolagic motes ——| Oliapeaccharide in seed yp | tothe Aste pace ue anibioda Bnd Be | Oligosaeenarie in olood ype 305 subunit and blockthe rn formation ofthe ination {somal “These antibiotics bind tothe |] During myocardaleche SoSeatunieandianie thiscrug inhib oxidaon | tansoston of ee ity acids, thereby ihintor increasing the metabob rae dehydrogenase wed 6 an a gucore inumunonappresant [ inhibi xanthine ode Yin K antagonist sed in the teat goat Tnhibls HMG CoA wecuctave. 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DNNIE E. BATICULON, MD @SirRonk For inquiries vist won. topr Ulva facebook com/topnotchm,ures y DenaVCTa psig " PEARLS BY RONNE E. BATICULON seaman se neat aa ‘ubh or or tps facebO0K.c2 void plagues in the hipre Ppocampus federal cre | Secessintene antes sl neurodes or fiscasescharaceer acrenenb enna spongiform changes © trom accomulation of ALA ond 28t7Ocytcglomae sng ie sro iy Her tonmen pair Fn free ot SADRS i rele oy aTae Frocrenttyand rine ‘Romeo ote Getoreite deve mont that polymertes nore | ughccuetoucopenphyrine | that polymertas nee ie Severe conptal oedee Synthesis ofechaing — | with brain damage decreased or abeere | decreased or aber ae Specie typerrbinemis spherical RBCs that are yen ee Protein deprivation tats Bue sir mis elects cl care {tare conductive hering Caloric deprivation is ——— reatnly pester tae the err anata reduction pot wPerexenste sc, Conan mares by bypermodie joint deny increated pravincatbolsm ee Tip malbaorion resting | Lose eth soe spongy inincreased ids in feces, ums, poor wound heatng ! sand eficiency of essential | Bacio oni and mous fy asa fascia | “The skin dreakeand Waters — roms Cronic leon ends to 353 resultof minor trauma [ataccurulaton in he ver Heredia nephritis ath Cerebrepatrert senorita ts toners ou oabeenee of fore dation tensomes delichostenomelia, [Delete peranonar | aechnodacnyy Secnatin 0 VLEPR eadsto acinar ephvinand Secumsation af VIC Inthe ier ico nd tees -Accunulavon of PEESGE ‘legeneration Fo yponyts om orcpe a fSceumlatin of copper in tate tee lnctates {sues wth low eves medium ad short-htn2 feralplacmin Gan debydroenase. 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BATICULON, MD @SirRonnO Fer inquiries visit wwrw.topnot Wavwn.facebook.com/topnatchmecTOPNOTCH wep" =~ fy" Forgas vents by KONE E84 Toverhipas CULON, ME 1 ebook, comite eer and pee fom Pateptir | edie fen ean ae aoe ‘canara tatledstomena |reardton ta | covey Aecanioe TOASTER ren soa ‘Sota bcos Stoaalsterealeston socal pee Seailgrerteeet |ieomes Leyswls associated wih gout Severe combiee lrnmunodefiency “Abnormal goth tregablaic ane, cere ‘erodermapipmentcsure Tieatiary nonpabpae ploncaneer Huntington dase Gat syeerome Scheel dense Duchenne Museu ty questions? rp titer com/SirRonm © ‘Topnotehochem ‘MAINANDOUT ERRATA age 154 ISOLEUCINE re image sme very ge 26 ofS [SUMMARY OF APOLIPOPROTEN ‘Apo 8:48 > Change to Apo 8-100 ‘Ape 8-100 > Change Apo B- Page 25 of 5¢ VITAMIN 812: COBALAMIN binding COBALOPHIN + Char TOPNOTCK MEDICAL BOARD PR Fer inultes ioe wo topnett |. alepetl estan ate 100f v0SL 2Ee ToPNorcH —__BocieN egative logarithm of trogen on cone Peseta Protensaegativesy a Beat physiclone abel 7 OPH AS Toney — red at physiologic pit Gabove > a Substance thayegaaa” ‘hange in pit whengtotons 2 produed or conus femal compose ar neta af tere aia which theptedommnant toner amc conga Tiisedtatante er pretaethe cnegecon pet cid andi congue pdanothergrar-onpond Patccr wane camaaan dis clige an ssi cence amine aaGTTRT [Beeen nacondes A nana Se Sond ol Gea Btanchipgbend a glacogT meena eoweeh gece snd TS GRY ween wo gieine es ncystine oveen the ‘purine/pynmicite ring and ribose /deoxyribose in nydeotides [itanear Comat Tse — catabolism of carbohydrates, rotein and pts, [lett preduerormammaan 7 fatty arid syrthose fa) steroids ne prinspal ig eneray ‘compoundotthelivingeel! | | Wieed in the diagnosis offalic STRY PEARLS BY RONNIE E. BATICULON ‘Com.ah or or hitpe:/ wow facebook. ct = Precursor of nti oxide — [Precursor of catecholamines Facade recareicane —7} sro | Prreciterattenoaree oa | facie } +} Pasinessnsenogoms — | (otegat ted nena, of Qaieked Pate of ainkezaveonvation af ppoteine amine ad Wat eae 4 fami aaE Fevedonianc ee anine SOs + Tobiecs t aetna Tier — >t {Pari saat vin pereae sched Sa ann aE arvaattana sae [Fania sed with impaled renal reabsorption selnura (Armin seidr whose ‘metabolism s impaired in smethylmalenie seduria amine acid iritionally essentsTamino ‘asics Purely etogenie amino 36s [ath elucogenic and ketogenic ‘amino acids iraly gucogenie amino acids lic and B.pleated sheet ence of amine acids termines whether protein ‘sglobularor Bbrous r [i aon poeseoae—Zt Bétermined veing Edman’ eagent and Sanger’s reagent [Aniy exibit trary structure jundin heartand skeletal ‘muscle concentrationtomer ore — fern utara axes [26 gem aca estaba fmogictinbowey Hemoglobin witoicany — eavzenmoicueteced ont PAsrenemsnr iat fei heed ad ede eer [Phaeton ertne berg — Component ef wemapobnto Fede whicheamoetiog |veen apm a — ‘ighty bat reversibly tothe | nomoglbin iron rbon dxide Domne hemogioni fr transport in thebioed [Aasement men Aranslaion issue icin, blood veel Pacoarpebene ston pulposus vitreous ‘body. and carla don fra bone te wound a rthecempications of 7 Hinbetes metas Polysaccharide inp “one be digested by humans (Cars Tce pose taeve Feel and feardiae muscle ‘chai of carbone ac hth ne double bond! ‘TOPNOTCH MEDICAL BOARD P Fer inquires vist warw tepne IRY PEARLS BY RONNIE E. BATICULON, mph or or htsp:/rwww, facebook. co [Pera chain ofearbonghe sod) | aonedesbictone | [Zang chain orearboxyic ad ‘rth roo er more double bonds [Paty acids thatare yproduets of tycrorenation, ‘hich makes therm more sold ny acids associated with Predominant ayaa aie —t SE ; Jeoanenc ered See orgnes an Ketone boy Teed rng [tone body tarcamnarbe voles For [areal deeredation thstean undergo [Arcaror ct vianin Dine [> skin recurs ofa teed hormones derive rom pir seccoT erage Posmeropavsal women Gelenerolexceatton | # the body acpi ie ees Ge primary be ae ‘Give molecules conjuented toile ache to conver: them tobe st ‘Give 2 secondary bie weds complexes compesed of lipids andpecfic proteins Proven moiety of ipopraiene Transportdletary tgiycerde sndcholetero trom itertine ‘Transports rghyceride rom Delivers chotesterol into cell Reverse cholesterol transport ‘Shuttes ape Ciland apo Ein the blood Wighest eighyeerde content Highest protein content Highest enlertrol content adeno = Mediate eylomicron ‘ctvates lipoprotein pase Mediates upeake of LNNIE E, BATICULON, MD @SirRonD 1 ‘Uren facebook, com/topnotchmnedt