a. | afta ysl at wean : 6 |No. No. of printed pages : 6 0 430 (IDB) 2017 Tarr faa ( agian ) CHEMISTRY (Theory) 1:3 ave | Taeite : 70 e:3hours | [ Max. Marks : 70 a: () ga ued va Y Gor 30 wea S| wT wer afrard B @) 7 Year 8 8 ow aft og uate wer é oie uete 1 sim aT aI Gi) WET Hear 9 S 18 dH oy Sata wer S aie wed 2 vie wT a] (iv) 5 BAT 19 S 27 geo A ag wala wer z aie weaw 3 aie aT a1 (v) Wet Wear 28 B30 ae def sata wes s sik uedw 5 sip wT] (vi) ae oraeee et ct cit ah or watt oe wad 81 Haqeex wr waht afta B1 (vi) WE eT S oreey Gif she ort ga Ged TIga| VT wee a soa te OR wT are 4 aia ) There are in all 30 questions in this question paper. All questions are compulscry. (ii) Question No. 1 to 8 are very short answer questions and carry 1 mark each. ii) Question No. 9 to 18 are short answer questions and carry 2 marks each. (iv) Question No. 19 to 27 are also short answer questions and carry 3 marks each. (¥) Question No. 28 to 30 are long answer questions and carry 5 marks each. (vi) Use Log tables, if necessary. Use of calculator is not allowed. (vii) Start from the first question and proceed to the last. Do not waste time over a question, if you cannot solve. sateen at sarevor wiser uftarer fered | 1 Write definition of adsorption with example. we egy fers HF aftr a we saree Hy! 1 Give definition and one example of monodentate ligand, Wrote apc See... PE ae TAP A vat 81 1 Phenol is mostly used for the preparation of ... . plastic, (CH),CHCOOH @1 sTg.AarRh, rr ferfera | 1 Write IUPAC name of (CH,),CHCOOH. t1) [P.T.0. @ myCBSEguide.com A Complete guide for CBSE students10. N 12. 13. 14, 15 feet ft fedtae wits or art wd vive ferftay 1 Write the name and structure of any secondary amine. tiferteugs & et vere fatty) 1 Write two examples of polysaccharides. eRe cern Sata SS ara oie B ? 1 How terylene or dacron is prepared 2 SoRa or reraha wa va vw ore fea 1 Write chemical formula and one use of Saccharin. Brea wre cen gars Wet BY Trea | 2 Explain crystal lattice and unit cell, saa war et & ? gid a) yer vert wt wasga| 2 ‘What are semiconductors ? Define two main types of semiconductors. 300K YRtar & Searfer lor S wee are a oa DASA | 2 [R = 0.0821 lit. atm /degree/mol] Calculate the osmotic pressure of decinormal solution of urea at 300 K. [R = 0.0821 lit. atm./degree/mol] faege warettes aot ad xt orpueiter feriee | 2 Write two applications of electrochemical series. date & Gly Baer Sway oer ae & ? wre wiser ftw 2 Which of the elements of d-block are not transition element ? Write with reason. varity waraeraer er Her fered! (PUCl(NH,),] @ Pre wd gia wai a fa ae feared 2 Write the reason of Geometrical Isomerism. Ilustrate cis and trans forms of [PICl,(NH),]- | 317A (OR) TUPAC Prat & omer we PT yoraftert ara feftag — Using IUPAC norms write the systematic names of the following — ()— [Mn(H,0),?* (i) Tia, (ii) cc, (iv) [Ni(CO))} Pr oftirasit a yet afer) Ad Bet cemfay — ‘Complete the following reactions. Identify A and B - @) CH—cH,—cH, + snk AaB (i) CH.NH, + CHCI, +A —> B+3KC1+3H,0 430 (IDB) [2]CHCl ® ceili wary a foarefleran siftres cet CHCl 4 Clo Prarie a 1 STS wife 2 In C,H,Cl, chlorine atom is highly reactive, while in C,H,Cl, it is less reactive. Clarify. rR Zerit wae & Prater at eevee affirar fered | 2 Write the chemical reaction for the preparation of styrene-butadiene rubber. (@) wearifeas an & ? gad ord fetta) 1 What are Antibiotics ? Write its functions. (@) fart we are oReete oF ar a soar fafa i Write the name of any one Food Preservative and its use. ween & soraq or ore fee) ya srarerefter facta S 10 wr BT 100 aH aos FH alert ay dof } aaertin F rec at gfer ure one 81 era S ep at er afer [acit & fer K, = 2.53 K kg mol] 3 Write the reason of elevation in boiling point. 10 gm non-volatile solute is dissolved in 100 gm benzene. The elevation in boiling point of benzene was found to be 1°C. Calculate the molecular weight of the solute. [K, for benzene is 2.53 K Kg mol] (@) @erres wr Pre fered) 1 Write Kohlrausch’s law. (@) Fe te O ae Ga fra HoT Hera — 2 Zn | Zn**(1 M) || Cu** (1 M)| Cu aq = 0.76 V TAT Egg, = +0.34 V] alculate the standard potential of the given cell ~ Zn | Zn"(1 M) |} Cu"* (1 M)| Cu [Ep 4a, = 0.76 V and B,, ++, = +0.34 V] Fret oy viferer ecohy ferfera— 141+1=3 Write short notes on the following— (©) watt ware (@) age om tae (1) ontert Homogeneous catalysis, Electrophoresis Dialysis Tat (OR) (@) maRPA wa Zafer diet or uate aig cer wee oT VEO Vere REG) 2 Define lyophilic and lyophobic sols. Give one example of each. (a) wafer eter smart W vafta wat ey om & 2 1 Why are lyophobic sols easily coagulated ? (IDB) [3] [PT.0. @ myCBSEguide.com A Complete guide for CBSE students22. fiw cen Cahir & wwe sere ora a a fea) eae sree fA are ata or viet be far ora & ? 3 Write the name and formula of one ore each of Zinc and Aluminium. How copper is refined using an electrolytic method ? 23, (@) warrenen 4 SReTEgior art Br fa wr ary aAfeTE | Write the method of preparing di-nitrogen in the laboratory ? (@) HS.H,te # amen at opeta qaf 2? 1 Why H,S is less acidic than H,Te ? 24. (®) srefa KMnO, ot aifacifern orca } rer warafre afifirar fee | | Write chemical reaction of acidic KMnO, with oxalic acid, (@) eerngs cet & sifttore orat +3 sitaviaen craven # argyraaita wapfa d Bef] at? 1 Most of the Lanthanides in +3 oxidation state are paramagnetic in nature. Why ? (71) ,,U ar gelagifra farare feted | 1 Write electronic configuration of ,,U 25. (@) We versa HF Wifes sora & oer werahe fifa fafa 1 Write chemical reaction of ethyl alcohol and acetic acid, @ Oeic 8 RoRe ora aM A erate afifrar faea 1}, Write chemical reaction to prepare picric acid from phenol. (7) -wrg—AARrer fore aor Bhrareres rere FBR | 1 Write functional isomer of di-methyl ether, 26. Pe ari @ errata sified fees — 13-3 Write chemical reactions for the formation of the following — | @) Wieags 8 yea Vir Ethyl amine from Acetamide (@) aegisis @ thi Aniline from Nitrobenzene @) dia sewer airigs Y Orie Phenol from benzene diazonium chloride 27. (©) wargrr S woah fata) 1 Write uses of enzymes. 430 (IDB) (41(@) facta St ar werahta ar a gaat ah @ Geo Wr fea) 1 Write chemical name of Vitamin D and disease caused due to its deficiency. @) Seay aig wres gar der @ ? 1 What is DNA fingerprinting ? 23. (@®) wate aftr at ae er warts oe are areal a orem aera | Discuss the factors which affect the rate of chemical reaction. (a) wa ale a aftira & fey warafear ar whee ot aah afta | 2 Derive integrated rate equation for zero order reaction. SIAAT (OR) ‘ (@) sffifear 2NO+0,—>2NO, 4 snftawar srt Ta 1 In the reaction 2NO +O, —>2NO, , calculate molecularity. (@) we vem aie at oifhfieer i 30% faetorr er A 40 Pte cera BI otal sary (1,) Bt rors afer | 2 A first order reaction takes 40 minutes for 30% decomposition. Calculate half life period (t,). (1) area offrar an -deee Rrarer & Agel fay fea 2 Write important points of ‘collision theory of chemical reaction’. 20. Fr afttirarit at yet afer — 1x5=5 Complete the following reactions — (®) PCI,+CH,COOH —> (@) 2KI+H,0+0,—> @) S80, +Cl, Se, ‘Smt (@) MnO, +4HCI—4-> (S) Ca(OH), +Cl,h —> ‘17aT (OR) (@) sere thi & ecagiite ferure feed) arama vRReftal a cape Wi eae sififearatt Farr tél act F) aat ? 2 Write electronic configuration of inert gases. In normal conditions inert gases do not take part in chemical reactions. Why ? 30 (IDB) [5] [P-T.0. @ myCBSEguide.com A Complete guide for CBSE students430 (IDB) 16] a @ ser wer @ orihar > stele Pater at wera siren a srgaet uaa ferfera | 2| Roll Write the chemical reaction and favourable conditions for industrial manufacturing of ammonia by Haber’s proc @) weit a gaagifre age ait Bt get ¥ oa 2) wai? 1 Electron affinity of F is less than Cl. Why ? @) fra aftfiensit of wera witeer ufeta fees — Write the following reactions with chemical equations — @ Wraps aia (i) Teele afifirar Rosenmund reaction Gatterman-Koch reaction (a) Prat at art a rata oififireny fea — Write the chemical reactions for the preparation of the following — @ wher & weiter (i) Tees & Wefessrgs Chloretone from acetone Acetaldehyde from acetylene @) fret ot asd gy ort afar & wr F fetta — 1 Write increasing order of acidic nature of the following — CICH,COOH; CH,COOH; CI,CCOOH; Cl,CHCOOH IAAT (OR) we odie aifte 4 69.77% ods, 11.63% eeghort cen Ay siteitord 2) afte aT SPAR 868 | Te cert aiftade or amafia wet wean #1 Sta Siar eegiort wep & ares arr veng tar @ she care srastort afer tor 81 act steer we rE whiga car wielge sre tar 1 wife of wenfaa deer a werahte afhfrart fee’ | 5 An organic compound contains 69.77% carbon, 11.63% hydrogen and rest oxygen. Its molecular |1 weight is 86. It does not reduce Tollens’ reagent, but gives addition product with sodium hydrogen sulphite. It gives positive test with iodoform. On strong oxidation it gives ethanoic and propanoic acid. Write the possible structure and chemical reactions of the compound.