1- (2006) the following questions about thermodynamics.

(A) The heat of combustion of propane is 2220 kJ/mol when the water formed is liquid.
Evaluate the Heat of formation of propane by using this fact as well as the
thermochemical equation.

C(grafite) + O2 = CO2 +394 kJ

2H2 + O2 = 2 H2O + 572kJ

(1) 64 kJ/mol
(2) 85 kJ/mol
(3) 106 kJ/mol
(4) 137 kJ/mol
(5) 182 kJ/mol

(B) What is the volume os propane needed at STP to raise the temperature of 2.00 L water
from 15.0 to 95.0 ºC using the heat evolved through its combustion, given that the
density of water is 1.00 g/cm3 and that the specific heat of water is 4.18 J/g.ºC. The
calculation should be done under the assumption: 1.0 cm3 = 1 mL

(1) 4,85 L
(2) 6,75 L
(3) 8,65 L
(4) 11,7 L
(5) 18,5 L

2- (2007) Evaluate the heat of reaction of the following reaction from the heat of
formation data each material.

CH3CHO (l) = CH4 (g) + CO (g)

Here, l is liquid and g is gas. The data of heat of formation for each material are
as follow

CH3CHO : 192 kJ/mol

CH4: 74.9 kJ/mol

CO : 110.5 kJ/mol

3- Answer the following question (A) and (B). Condition: When a 10 L flask holds 1 mole
each of H2 e CO2, and the temperature is kept low, 0.5 mole each of CO and H2O are
produced at equilibrium.
(A) Calculate the equilibrium constant of the following reaction.
CO2 + H2 = CO + H2O

(B) How many moles of CO in total are profuced if 0.5 mol of CO2 is added in the
above equilibrium situation.
4- The following reaction is in an equilibrium state
2 NO2 (brown) = N2O4 (colorless) + 57 kJ
From 1 – 4 below choose two correct ones out of statements a-d.
(a) As the temperature increased, the color darkens.
(b) As the temperature increased, the color lightens.
(c) As the pressure is increased, the brown color first darkens, and then, after a few
seconds, lightens.
(d) As the pressure is increased, the brown color first lightens, and then, after a few
seconds, darkens.

1 a,c 2 a,d 3 b,c 4 b,d

5- What is thee pH of 50 mL of the 0.14 mol/L HCl solution mixed with 50 mL of 0.10
mol/L NaOH solution? Log 2 = 0,3

6- Wich is the acid salt of wich the aqueous solution is basic?

1 NaHSO3 2 Na2SO4 3 NaHCO3
4 Na2CO3 5 Mg(OH)2 6 MgCL(OH)