Experiment 3 Topic_* Volumetric analysis. - Purity and. Stoichiometry, Purpose : To defermne the purity of a sample of sodium sulphite Results ¥ Titration number Rough Aare First Second | Third Final reading [em > 33.60 33,00 | 32.90 | 33.00 Initial reading im? | 0.00 0.00 0.00 | 0.00 Volume of KA2/cm> | 33.60 | 33.00 | 32.90 | 33.00 (W) Average +e value = 33.00 + 32.90 433.00. 3 = 32.44? (ii)_50.0cm® of KAL required 32.43cm® of KA2 for a complete reaction Questions (A balanced equation for the reaction between iodine and tne thiosulphate ion Half onic equations = Lote? 2207 28,03" > $40," + 2e7 Overall chemical equation * Ia t 2805" > SyO,* + 20 (4) To calculate the vume of 12 that did aot react with the sulphite ions. \ mole of iodine reacts with 2 moles af thiosulphate ions Using the formula Maa, a my, > while ma * Concentration of iodine in mol dm” mb = concentration of thiosulphate ions_in_mo| dm" *Va = volume of jodine in cm? Vy volume oP thiosulphate ions in. cm? a bet Hence , (0.050) Va : 0.100 X 32.94 _ Va = 32.940m* ++ The volume of Is that did not react with the sulphite ions is 32.9%0n* (@) To calculate the volume of I2 that reacted with the Sulphite tons Volume of Is that reacted with the sulphite ions = Total volume of I used - volume of I, that did not react with the suiphite ions = 50,0 m> - 32.94¢m* = [4.03 em? The volume bf I, that reacted with the sulphite jon is [.03.cm* (8) To calculate the concentration ..in mal dm™*, of the sulphife ions in solution KA3 $0; + J, + HO F 909" 4 IHL Mt 4 2HC@Os = 21° 4 2H,0 #200, 1 male of sulphite tons reacts with | mol of iodine. Using the formula Max, X My ¥y 4g while mg + conentration of Sulphite ions in _mol_dm”® my + concentration of iadinein_mol dm’? Vi = volume of sulphite ions in cm? x: Yy > volume of iodine in om® ytHence, Mx _¥ (25.0) ot 0.050 x 17,03 \ Me = 3.406 x10" mol dm”? The concentration of the sulphite ions in solutien KA3 is 3.406 X10 * mol dm” ®Y (i) To calculate the mass of Nas SOs prerent in 250cm > of KA3., Concentration of NasSOs in g dm’ Concentration of Na, S03 in mol dm’* ¥ Molar mass of Nas SOs (3.406 x07] « [ 2073.6) + 32-1 + 3(16.0)] 4.195. g dm The mass of Na.SOs present in 1000cm? of KA3 is 4.2959 ~The mass of Na, SOs present in 250cm* of KAS = 4.05, 000 Low x 250 (9) Tp calculate the percentage purity of NaxSOs used: Te mass oP impure NasSOs present in {000cm* of KA3 is 14.00g. ~ The_massof impure Nas S0a_ present in 250em* of KAS = 1400 69 Woo = 6,009 The mass of pure NasSOs present in 2500m* of KAS is LORY g Percentage purity = Mass of pure Naz SOs Mass of impure NasSOs = LOT 6.00 K 100% xto9% 1%