CHEMISTRY CLASS XII DESIGN OF THE QUESTION PAPER Time : 3 Hrs. Max. Marks : 70 The weightage of the distribution of marks over different dimensions of the question paper shall be as follows : 1, Weightage to Learning Outcomes S.NO. OBJECTIVE MARKS PERCENTAGE L Knowledge (K) 21 30 @ Understanding (U) 35 50 3. Application and skill (A&S) 14 20 TOTAL 70 100 2. Weightage to Content/Subject units UNIT MARKS I Atomic Structure and 5 Chemical Bonding TL. The Solid state 4 iil Solutions 4 TV. Thermodynamics 4 Vv. Electrochemistry 3 VI Chemical Kinetics 4 Vit Surface Chemistry 3 VUL p-Block Elements 7 IX. d-and f- Block elements 3 x. Coordination Compounds and 3 Organomentallics XT. Nuclear Chemistry 3 94UNIT MARKS XI. Stereo Chemistry v XII. Organic Compounds with Functional 2 Groups containing Oxygen -I XIV. Organic Compounds with Functional 4 Groups containing Oxygen - II XV. Organic Compounds with Functional 4 Groups containing Nitrogen XVI. Polymers i) XVII. Biomolecules 5 XVII. Chemistry in everyday life we Total 70 3. Weightage to form of questions S.No. Form of Marks for No. of Total marks questions cach question questions 1. Long Answer 5 3 15 Type Qs.(LA) 2. Short Answer 3 12 36 Qs. II (SAIL) Short Answer 2 7 14 Qs. 1(SAD we 4. Very Short Answer 1 5 5 Type Qs. (VSA) Total - 27 70 Note : The expected length of answer and time taken under different forms of questions shall be as follows : 95T Form of Expected Expected Total Question Length time for each Expected question time 1. VSA Type One word to 2 Minutes 10 Minutes one sentence 2. SA-I Type 20 10 30 5 Minutes 35 Minutes words 3. SA-II Type 30 to 40 7 Minutes 84 Minutes words 4. E/LA Type 70 to 80 15 Minutes 45 Minutes words Total Time 174 Minutes This is only an approximation. Though the students are advised to be as near the approxi- mation as possible the actual length, however, may vary. As the total time is calculated on the basis of the number of questions required to be answered and the lengths of their anticipated answers, it would therefore, be advisable for the candidates to manage their time properly by avoiding details not required. 4. Scheme of Options (1). There will be no overall choice (2) _ Internal choice (either/or type) in five questions is to given in questions testing higher mental abilities in the following types of questions :~ (i) One in two marks questions (SA-I Type) (ii) One in three marks questions (SA-II Type) (iii) All the three in five marks questions (E/LA Type) Guidelines for evaluation in organic chemistry units and numericals. i) Organic Chemistry Units : a. Two conversions involving not more than 2 marks 2 steps each 96OR One application question on conversions involving four unknown compounds b. Two distinctions 2 marks c. IUPAC nomenclature 1 marks d. Reasoning questions 2 marks e. Mechanism I marks f, Name Reactions 2 marks g. Stereochemistry 2 marks 12 marks Numericals : Weightage of about 12 marks in total has been assigned to numericals, Weightage to difficulty level of questions S.No. Estimated difficulty level Percentage 1. Easy 15 2. Average 70 3. Difficult re A question may vary in difficulty level from individual to individual. As such, the approximation in respect of each question will be made by the paper setter on the basis of general expectation from the group as a whole taking the examination, This provi- sion is only to make the paper balanced in nature rather than to determine the pattern of marking at any stage. 97(42) OL Or (£1) SE (8) 17 WoL, agi Aepaiony We We uy Answray{ “81 (s Me | Mz Sopnoafoworg] *L] (Dz Wz sxouts|od “9 | Or (De Mt dion “B10 “$1 (vs We 1 I-O--duto9 819 “pL (Wz We LO-'duso 819 “€1 (ve Me “WY OBIS “ZI We Me way] Wva}ONN “TL (We We spunodwiod “P1009 “01 (Ds (Ws ‘suawia]> YOo19 J PUY P “6 @z ae Ws Me squauta] yoo|g-d °g We We “WAY P2BJNS “L Or (OL We Sonaupy “Wey '9 (Ws Ms wiayponDo[A °S @s We | Wz somuMeUcpoULioy., “>| @r Me Mi SUOHINIOS *€ @r Me (DL BIS PHOS “Z| @s We | (Wz aUMyONIIS SIWOTY *| ©v1|@nvs| @rvs | Dvsa | v1 ]|Onvs | @rvs | Ovsa|(sv1] Ouvs| @1vs | (vsa omen Teo, uoneonddy Surpurysaopup, aSpajmouyy << saanrafqo| 02: SEIN XE] IIX SSV'TD — AULLSUNAHD ALN 9018 Sanoy] € + OWL,SAMPLE QUESTION PAPER -I CHEMISTRY CLASS XII Time : 3 Hours Max. Marks : 70 General Instructions : fi) “i (iii) (iv) ay) (vi) (vii) All questions are compulsory Marks for each question are indicated against it. Question numbers I to 5 are very short-answer question, each of one mark. Answer these in one word or about one sentence each. Question numbers 6 10 12 are short answer questions of two marks each. Answer these in about 30 words each Question numbers 13 to 24 are short answer questions of 3 marks each. Answer these in about 40 words each. Question numbers 25 to 27 are Long-answer questions of 5 marks cach. Answer these in about 70 words each. Use log tables if necessary. Calculators are not permitted. How many effective sodium ions are located at the centres of edges of a unit cell in a sodium chloride crystal? 1 A reaction : Reactant —___y Product is represented by [Rol Time () Predict (i) the order of the reaction in this case 1 (ii) what does the slope of the graph represent. Propose the mechanism for the following reaction : CH,CHO+HCN—*5 H,C-CH-CN 1 OH 994 Write the IUPAC name of the compound No, CH; 5 Carefully examine the diagram and name the process involved : PT LF Piston Water coming out 6 Identify the type of inter-molecular forces that exist between the following pairs : (i) Na* ion and water molecules Gi) Ag* ion and ion (iii) | Argon and Argon (iv) HF and H,0 7 Predict the entropy change (Positive/Negative) in the following : (i) A liquid substance crystallises into a solid (ii) Temperature of crystal is increased. (ii) CaCO(s) —> CaO(s)+CO,(g) (iv) N5(g)(latm) —+N,(g)(0.5atm) 8 — Howis [(CH,),SiO], prepared? Write its two applications. 100What is a stereospecific reaction? Give one example of this reaction, Identify A, B, C and D in the following reactions. OH () CHCI, + NaOH faq) Br (CS,) Bn, n,—>n, n,—>n, or ~all require the same energy OR Suppose the velocities of an electron and a rifle bullet of mass 0.03kg are each measured with an uncertainty of ay = 19" ms-! calculate the (a minimum uncertainties in their positions. (Given : mass of an electron = 9.1 < 10~ kg) (b) Comment on the calculated values of uncertainties in positions in the two cases. Explain the following terms with suitable examples : @)_ Ferrimagnetism (i) n~type semiconductor Gili) forbidden zone 101 u N wQ.16 Qu7 Qs The Henry law constant for oxygen dissolved in water is 4.34 = 10# atm at 25°C. If the partial pressure of oxygen in air is 0.2 atm. under ordinary atmospheric conditions. Calculate the concentration (in moles per litre) of dissolved oxygen in water in equilibrium with air at 25°C. At elevated temperatures, HI decomposes according to the chemical equation : 2HI(g) —> H(g) + 1(g) at 443°C. The rate of the reaction increases with concentration of HI, as shown in the following table : 1 2 3 HI (mol L") 0.005 0.01 0.02 Rate (mol L's) 75x 104 3.0x105 1.2 x 107 (a) Determine (i) order of this reaction and (ii) write the rate expression. (b) — Calculate the rate constant and give its units. (a) Among the iron complexes, K3[Fe(CN)g] in weakly Paramagnetic whereas K3[Fe¥] is highly paramagnetic, explain. (b) Define crystal field orbital splitting energy. (c) Write the shape of Fe(CO), molecule. Represent the following using a nuclear equation each : (i) Production of C-14 in nature (ii) B - emission (iii) K - capture Write chemical tests to distinguish between the following pair of compounds : ou coon @ @ oO and CH,CHO (ii) oO and CH,COCH, 102 we(b) — Write a chemical equation examplifying Clemmensen reduction. 3 we Q.20. Give reasons for the following : (a) (i) The basic strength of aliphatic amines in solution is of the order of sec> tert > primary. (ii) Nitro compounds have higher boiling point than hydrocarbons having ~ same molecular mas (b) — Give an example of carbylamine reaction. Q21 (a) Which bonds in the back bone of a peptide can rotate freely and which cannot? Give reasons. (b) Write one diffference between parallel and antiparallel) pleated sheets Give one example of parallel B pleated sheet. Answer the following : (a) “ An unknown fibre (A) is stronger than steel, stiffer than titanium and lighter than aluminium”. What could the fibre (A) be? (b) Why are liquid propellants favoured over solid propellants? (c) What type of medicines are Omeprazole and Lansoprazole? 3 23. The change in entropy with respect to temperature in case of a sample is graphically represented below : Entropy ‘Temperature 10324. 25. 26 Carefully analyse the graph and answer the following : (i) What does T, and T, indicate ? (ii) What does AB Curve show ? we (ili) What does BC curve show ? Why temperature does not change? Describe the following giving one example each : (a) Mechanism of heterogeneous catalysis (b) Hardy Schulze Rule (4+1%) (a) Write the reactions occurring during the electrolysis of : (i) Sulphuric acid at the anode. (ii) Aqueous Silver Nitrate solution using silver electrodes. (iii) Aqueous sodium chloride Solution. (b) @)_ Write the anodic and cathodic reactions involved during the discharging of lead storage battery. (ii) How many Paradays of electric charge is involved per mole of HSO, consumed. when the lead storage battery is in use? (3.2) OR (a) Ina Leclanche cell, write the following : (i) | The chemical equations involved at the cathode. (ii) Change in the Oxidation state of Mn. (iii) The complex entity formed between 7?" (aq) and NH (g) (1. %. 4) (by Ina hydrogen ~ oxygen fuel cell, write the reactions involved at the (dy anode and the cathode. (c) How will the value of Ecel] change in an electrochemical cell involving the following reaction if the concentration of Ag"(aq) (2) is increased? Mg(s) + 2Ag* (aq) —> Mg*(aq) + Ag (s) (a) __ Identify the species from A to D in the extraction of silver from its ore (A) Xo) On(8) z A ah nC) B Zals) CO +(0 7) (A) —how > @ —e, © (D) 2) (b) Give reasons for the following : (i) With d! configuration in ¢,2+_ is reducing whereas in y4p3*is oxidising, 104”2. ii) Interstitial compounds are well known for transition metals. The highest oxidation state of a metal is exhibited in oxides and @) fluorides. OR Answer the following (a) Ky Cry O7 is orange in colour but turns yellow in an alkaline medium, why? (b) Draw the structure of dichromate and chromate ion. (©) Name metals extracted from the ores (i) cinnabar (ii) Proustite. (4) Transitonal elements have high heat of atomisation why? (e) Silver halides dissolve in thiosulphate solution. Write chemical reaction and the structure of silver complex formed in the reaction. Account for the following :- i) All the bonds in PCI; are not equivalent. ii) Sulphur in vapour state exhibits paramagnetism. iii) Fluorine is the strongest oxidant amongst the halogens. iv) Among the noble gases, only xenon is known to form true chemical compounds. V) PbO, is a stonger oxidising agent than SnO,. (5) OR (i) Name chief ore of Lead. Write chemical reactions involving the extraction of Lead from this ore. (ii) Describe the preparation of C1O,, HOCI and XeF,.MARKING SCHEME-I SAMPLE QUESTION PAPER-I CHEMISTRY Note :The marking scheme given here does not include complete detailed answers for all the questions. At few places, the actual answer is too obvious and therefore, only the scheme of distribution of marks has been indicated. Students are advised to w complete answers in the actual examination. Q.No. Value Points Marks T. Marks Lo 3 1 1 2. (i) Zero order reaction % 1 (ii) Slope =—K % } OH Z 0 CNT 1 HY 1 3. CHy- uaF CH; ~C-CN == CH; ~C-CN 1 1 OH 4. 4-Methy nitrobenzene OR 4-Nitro toluene 1 al 5. Reverse Osmosis 1 1 6. (i) ion —dipole attraction “ (ii) ion-ion attraction % (iii) Dispersion forces Y 2 (iv) H-bonding % 7. (i) decreases % (ii) increases % (iii) increases % 2 (iv) increases as the volume increases % cu 8 2CH,Cl+Si_- —-» (CH,), SiCl, 22> [(CH3),SiO], 1 Uses : (1) Electrical insulators % 2 (2) Greases or any other uses '” 9. A reaction is stereospecific when a particular stereoisomeric form of the starting material reacts in such a way that it gives streoisomeric form of the product. 1 1 106Q.No. Value Points Marks T. Marks Example : Addition of halogens to alkenes or any other suitable example. on OH Br 10. A= oO or \y Br Hi Bs CHO % ecocH, on ou i on a CocH, OR ® Lal, () CH,CooH -=--~ CH,CH,OH ih «iy H,0 CH, H; C-CH-CH, von, o . -O-O- 1,0 =H" (i) oO ==} Os — CH, 11. Benzo quinone traps the radial intermediate to form a non reactive radical. which is highly stabilised by resonance : Because of the lack of reactivity of this intermediate, further progress of the chain reaction is interrupted and the reaction stops 2 12. Isomers which differ in streochemistry at C, in cyclic structure % Two anomers : A a—-D-glucose % 2 B-D-gucose % 107Value Points Marks T. Marks 13. % Energy of the electron in the first shell = =-1312* 10? kJ mol 12 x 10° J mol"! = , 6.02 x 10 atoms mol ~~0-219 * 10°" J atom 4 =-2.19 x 10" J atom™ A WIE Energy of the electron in the third shell = Gr = 2.19 x 1078 “1 = atom! % = 0.244 x 10°" J atom AE=E,-E, =[-0.244 x 10° —(-2.19 x 10") J atom" =1.95 x 10 Jatom Energy of photon = 1.95 * 10° J. % (b) nn, 1 OR ar ap= ¥ P= an 4 ax. mAv= 7 a 4nmAv - 6.625 x 10-4 defor slegion "F514 nlx te 810” 5 = 0.05796m 1 .058m. 108,Q.No. Value Points Marks T. Marks 6.625 x 10" Ax for bullet= 77314 x 003x107 =1.76* 10m 1 Comments : We can approximately measure macroscopic object’s position as the error calculated is neglible but not microscopic object’s position. ‘A 14, (i) Ferrimagnetism : When magnetic moments (electron spins) in a substance align in parallel and antiparallel directions in unequal numbers so that there is net dipole moment, the substance is ferrimagnetic. % Example : Fe,O,, M,’ Fe,O, where M= Mg. Cu, Zn (any one) (ii) n-type semiconductor : It is formed when impurity atom containing more valency electrons than the parent insulator atom is introduced into it. The unbounded electrons are the current carriers. nn Example : A trace amount of phosphorus on adding to extremely pure silicon by a process called doping forms an n - type semiconductor. (iii) Forbidden Zone : In case of insulators, the energy gap between valence band and the conduction band is so great that electrons cannot easily jump from valence band to conduction band hence practically no electrical conductivity is observed. Example : Silicon and Germanium (any one) 15. Mole fraction of oxygen in the solution : Po, =K, * Xo, Pow 0.2 atm Xo Sy Sa age kw 4.34 104 (atm) = 4.6 x 10% % changing from mole fraction to molarity 1000 uo = 7g = 555 moles Xo, is very small as compared to Xo ~ 2 No, + Myo = 1,0 Poy MH0 109Q.No. 16. 17. Value Points Marks Xo, Bi,0 = Mo, 4.6 x 10° 55.5 = ny, =2.6x 10 moles % Molatity = 2.6 x 104 M 1 1, =k (HIP .) 1, =k (HIP 2) a _ KH! @ «(uy 30x10" _ (0.01)" ote 4=2"=>n=2 75x10" (.005)" a. +. Order of Reaction = 2 1 Rate Expression : Rate = k{ HI (b) Rate= K{HI}? 75x10 = k [0.005] ad ke 15x aor (0.005)" =30 L mol” (a) Since F- ion is a weak ligand, d - electrons remain unpaired whereas CN" ion is a strong ligand and electrons get paired up. 1 (b) The energy difference (A ) between the lower and higher orbitals obtained as a result of spliting of d - orbitals in a crystal field is known as spliting energy. 1 (c) Trigonal bipyramidal. 1 ON) odie ep Oo tH (i) Th —, 34pa + B Gili) $3Ba + e~ —> Cs + X-ray 110 T. Marks we weQ.No. 19. (a) (b) 20.(a) (i) (i) (b) 21. (a) (b) Value Points Marks OH COOH @ oO and oO can be chemically distinguished by adding NaHCO, to both the containers. Evolution of CO,(g) ie. 1 (OOH effervescence indicates presence of Or any other suitable test. (ii) Add Tollen's reagent to both the containers, the container in CH,CHO which silver mirror is formed indicates Oo or any other suitable test. . ZnHg Clemmensen reduction : 7C = O aon ?CH, + H,0 1 Basic character of Amines is due to the electron density on the Natom. Alkyl group is an electron releasing group which 1 increases the electron density on the N atom. Hence electron density will be the greatest on N atom in the tertiary amines. But because of steric hidrance, the capture of proton H’ is obstructed and hence the given order. Due to polar nature, the boiling points of nitro compounds are usually high in comparison with hydrocarbons having ~ same molecular mass. 1 Carbylamine reaction : RNH, +CHCI, +3KOH——> RNC + 3KCl + 3H,0 1 Due to the partial double bond character of C - N bond on the _C-N- peptide linkage, the amide part ie) is planar and rigid ie no free rotation about this bond is possible. _ No free rotation around peptide (amide) bond. 1% . Free rotation around the bonds connecting to amide bond to o.-e The N terminals are aligned head to head ie. on the same side in the parallel 8 pleated sheet conformation and are aligned head to tail ie N - terminal of one chain and C— terminals of another chain are on the same side in antiparallel B— pleated sheet is parallel in keratin 1% HI T. MarksQNo. 22. 24, 25. Value Points Marks T. Marks (a) Carbon fibre 1 (b) Liquid propellants give higher thrusts than solid propellants and the thrust can be controlled by switching on and off the flow of 3 the propellant. 1 (c) Antacids. 1 (i) T, indicates m.pt of the solid. % T, indicates b.pt of the liquid. ”% (ii) AB curve shows increase in entropy of solid with increase in temperature. 1 3 (iii) BC curve shows change of solid ___, Liquid + of latent heat of fusion ’ An example of hete.rogeneons catalysis : (@) CH, = CH, (g) + Hy(g) SP" , cH, - CH, (g) Machanism : Steps involved (i) Chemical adsorpton of C,H, and H, onto the surface of metals. (ii) H, splits into H atoms which get chemically bound to the solid catalyst i.e. metal atom (M) H - H(g) + 2M(s) ==2M-H This step is the rate determining step in the overall process. (iii) The H atoms migrate over the surface of the metal and enventually collide with an adsorbed C,H, molecule and the reaction takes place. C,H,(g) + 2M-H ==C,Hg(g) + 2M(s) 1% (b) Hardy - Schulze Rule : (i) The ions carrying charge opposite to that of sol particles are effective in causing the coagulation of the Sol * 3 (ii) Coagulating power of an electrolyte is directly proportional the fourth power of the valency of the ions causing coagulation. % Example : For the coagulation of Sols carrying negative charge (like As, S, Sol) Fe** ions are more effective than Ba®* or Na* ions. % (i) 2H,0 () —+ 0,(g) + 4H* (ag)+4e™ (in dilute solution) 4 2804?" (aq) —> $0; (aq) + 2e~ (In Cone. Solution) % (ii) at anode: Ag(s)—+ Ag*(aq) + e7 % at cathode : Ag*(aq) +e” —> Ag(s) % (iii) at anode : 2CI- (aq) Cl,(g)+2e % 5 at cathode : 2H, + 2¢"(aq)—> H,(g)+20H" (a) (b) (i) atanode : Pb, +$O,* (a) —> PbSO,(s) +2e” % at cathode : PbO, + SO} (aq) + 4H* (aq) +2E—> PSO ge) + 2H,0y, % 112Q.No. 26. Value Points Marks T. Marks (ii) 1 Faraday of electric charge per mole of H,SO, is consumed 1 OR (@) @ MnO, + NH,* +e” —> MnO(OH) +NH, (ii) Change in oxidation state is from 4+ to 3+ Gi) [Zn (NH), (b) at anode 2Hy¢y) + 40H aq) —> 4H,0+4¢ at cathode : 0, +2H,0+4e” —+ 40H™ (c) The cell potential remains constant during its life in low current ase 0151, [Me] devices. since E,,, = Ey - 2 [ae'} (a) A— Ags B— [Ag(CN), 7° C—>[Zn(CN), D—>+Ag (b) (i) The third ionization energy is relatively low as it results in d? configuragion which is more stable than d* whereas in the case of Mn, the third lonisation energy is very high as the third 1 electron is to be removed from an extra stable dé configuration. (ii) Because small atoms like H, N and C can enter into the voids sites between the packed atoms of the crystalline metal. (iii) Because of small size of thier atoms O and F they can form strong bonds which may also facilitate the multiple bonding, OR (a) Chromate and dichromate are inter convertible in aqueus solution depending on PH of the solution. Cn0,7" +20H—+ 210," + Hj0 Orange Y= Yellow oO ° inion aed | a , C1 (b) o~] \ +o ur | So oO oO 113 1 1 t'sQ.No. 27. 27. Value Points Marks T. Marks (c) (i) Cinnabar :- mercury (ii) Proustite -— Silver Yate (d) due to strong interatomic attraction in d-orbitals (n-1) d electrons. (e) AgBr+2Na,$,0,__, Na,{Ag(S,0,),}#NaBr 1 Ds ig a Zao 0% Ss No No (i) There are two axial and three equatorial bonds in PCI, molecule as a result of sp’ d hybridisation, There is repulsive force between the electrons in the axial plane and equitorial plane which results in the axial elongation of bonds. 1 (ii) Sulphur in vapour state forms some S, molecules which like O, molecules contain unpaired electrons and hence paramagnetic in nature. 1 (iii) Because of the lower bond energy of F-F bond and higher hydration energy of F- ions. 1 (iv) Xenon has the lowest ionisation energy among the noble gases (v) The lower oxidation state gets stablished with increase in atomic number in the same group of p-block elements (inert pair effect). hence PbO, is a stronger oxidant than SnO, 1 OR Chief are of Lead in Galena Pbs. VytYy Reactions occuring in blast furance are ww Gi 2PbS + 30, —+2PbO +280, % PbS,,) + 2PbO,,) —> 3Pbicy + S024) % (ii) Chlolrine dioxide ClO,as prepared by reduction of ClOz with SO, in strongly acidic medium. INaCIO g(a) + $034) 2 2C1O x4) Na SO 44a) Chilorie (1) acid HOel is prepared by disproportionation of chlorine in water in presence of HgO 2Cl, + 2HgO + H¥O——> HgO. Hgel, + HOCI Xenon tetrafluride XeF, is prepared by reaction of Xenon and F, in the ratio of 1:5 at 873 K and 7 bar. 873K Xe) + 2Payg) SOR Xe 1 114Stl bl SE ita (0 04 We = @r_| Ws | Me | wz = @s | Wr z (Or Teo. agit AepArong (we We uy Anstey “81 Ws Ws sanoajoworg “£1 Wz Wz suauidjod “91 @r Wl We (D1 | spunodwos'si9 “s1 Or Or (WE 1-0-810 ‘rL (Dz Wz 10-10 ‘€1 (wz Wz *WOYD O2u7I5 “Z| We (We “WOYDIO}ONN “LL sorpeyout BQ (Me Me We WOD ‘P1009 “01 ()s Ms [w9]> 49014 JP P'S (L Wz (Ds juounojo yaoiq-d'g Me (We ‘UIA a9BpINS “LZ @r We (Or We (1 | sonsupy wey -9] @s We Wz Austunyoon sofa “¢ @s We Wz porwmeucpouuoy |p @r Me HONIN]OS “€, Or Me (DL areas ptlos eu “Z Fupuog jawiayy y @s Me | Mz (1 Jaimonns orwory “| (v1 | (Onvs | rvs | (Ovsa} (v1 | (uvs| @1vs | Mvsa] (vt | (Onvs [@lvs |(Dvsal _T suun, Tey, uopeayddy Surpavyssapuy aSpaynouy <+— saanaafqo OL SHARIA XE IX SSV'19 saMoH € # ONL AULSINAHD TI-LNd 40718SAMPLE QUESTION PAPER-II CHEMISTRY Class — XII Time : 3 Hours Max. Marks : 70 General Instructions : @ (ii) (iii) (iv) w) wi) (vii) 1. 2. All questions are compulsory Marks for cach question are indicated against it. Question numbers I to 5 are very short-answer questions each of one mark. Answer these in one word or about one sentence each Question numbers 6 10 12 are short answer questions of two marks each Answer these in about 30 words cach Question numbers 13 10 24 are short answer questions of 3 marks each, Answer these in about 40 words each. Question numbers 25 to 27 are Long-answer questions of 5 marks each. Answer these in about 70 words each. Use log tables if necessary. Calculators are not permitted. Give one example of Peizoelectric substance. What type of azeotrope is formed on mixing nitric acid and water? 1 State the unit of rate constant’ in a zero order reaction. 1 Write IUPAC name of : : ° u 1 cH,~CH-C- CH -COoH Br CH, a, Write the reaction for the preparation of *3C— C—N : cH, Write the MO configuration of diatomic molecule of the element with atomic number 9. Calculate its bond order and predict its magnetic behaviour. No(g)+0(g)—» 2NO(g) is an endothermic reaction yet it is spontancous. — 2 Explain the reason. 11610. 13. With the help ofa diagram explain the difference in the variation of molar con- ductivity with concentration for strong and weak electrolytes. Aluminium is significantly electropositive metal still it is used as a structural material. Explain the properties of Aluminium which make it suitable for this use. Optically active 2-iodobutane on tretment with Nal in acetone gives a product which does not show optical activity. Explain. Write the steps and conditions to carry out the following conversions : @) Phenol to Salicylic Acid (ii) 2-Methyl - 1 pentene to 2 - Methyl 2- pentan-2-ol OR An organic compound A (molecular formula C,H,O when reduced with Na BH, gives compound B which reacts with HBr to form compound C (opti- cally active). Identify A,B,C, and write the two enantiomers of compound C, Write the (i) names and (ii) structures of monomers present in the followingpolymers () PMMA. (ii) Buna-N Caleulate (i) frequence and (ji) wave number of the radiations required for the excitation of the electron in hydrogen atom from second to third energy level. Ionization energy of hydrogen atom is 1.312*10°kI mol. An element has a face centred cubic (f.c.c) structure with a cell edge of 0.2nm Calculate its density in g em? if 400g of this element contains 48 x 102? atoms take Na = 6x10” Mol" Explain with suitable examples in each case why the molar masses of some substances determined with the help of colligative properties are (i) higher (ii) lower than actual values. (a) The standard gibbs energies of formation (4 f G*) of SO, (e) and SO, (g) are — 300.0 and — 371.1 kJ mol” at 300K respectively Calculate A G and equilibrium constant for the following reaction at 300K. 2S0(g)+0.(2) == 280,(g) 11719, 20. (b) Explain why entropy ofa perfectly crystaline substance is less than that of its imperfect crystals. 3 (a) How many coulombs of electric charge must be passed through a solu- tion of silver nitrate to coat a copper sheet of area 100 cm? on both the 2+! sides with a 0.005 mm thick layer. Density of silver is 10.5 g em. Rela- tive atomic mass of silver is 108. (b) Three Iron sheets have been coated separately with three metals (A,B and C) whose standard electrode potentials are given below : Metal A B Gc Tron E* values — 46V —0.66V —0.20V 0.44V Identify in which case rusting will take place faster when coating is damaged. (a) The following initial rate date were obtained at 300 K for the reactions: 2,1 2A+B — C+D [A] mol L* [B] mol L* Rate mol LS" I 0.2 0.1 6.0 x 10? IL 0.4 0.1 24x 107 sit 0.2 0.2 1.2* 107 Deduce the rate law. (b) If half life of a reaction is inversely proportional to intital concentration of the reactant, what is the order of the reaction? Gives reasons for the following : Lt (a) Enzyme catalysts are highly specific in their action. (b) The path of light becomes visible when it is passed through As,O,sol. in water. (c)_ The enthalpy in case of chemisorption is usually higher than that of physisorption. (a) Give the IUPAC name of [PtCl (NH, CH,), (NH,),JCL 111 (b) Write the name of linkage isomer of [Co (ONO) (NH,)5}* (c) Though CO is a weak lewis base yet it forms a number of stable metal carbonyls, Explain 11821. (a) Complete the following nuclear reactions 11, (i) 7AL(a, n) —> (i). (b) What is meant by K-electron capture? (c) Which of the two type of reactions, fission or fusion is currently found usefull in harnessing energy and why? 22. Give reasons 2 se > (0, 20 9g At (a) _ Ketones are less reactive towards nucleophiles than aldehydes 1% (b) _ Benzoic acid is a stronger acid than ethanoic acid, 23, (a) _ Explain the following with the help of suitable examples bt (i) coupling reaction. (ii) Hofmann’s bromamide reaction (b) Give one chemical test to distinguish between CH;CH,NH) and C,HsNH) OR (a) _ Describe the following with the help of suitable examples : (i) Clemmensen reaction (ii) Cannizzaro’s reaction (b) Give one chemical reaction that can distinguish 2 - pentanone from 3 - pentanone (21) 24. Describe the following giving one example of each (a) Vat dyes 11 (b) Tranquilizers (c) Hybrid rocket propellants. 2 25. (a) _ Discribe the steps involved in the contact process for the manufacture of 2 sulphuric acid. 22,1 (b) What are silicones? How are they prepared? (c) Predict the probable structure of BrF, on the basis of VSEPR theory. OR () (a) __ SF, in not hydrolysed by water where as SF, is. 2 (b) Alcl, is used as a catalyst in organic reactions. (ii) Complete the following reactions : 2 (a) Ca3P) +H,O0—> (b) Pb30, +HNO,; —> (iii) Arrange the following in the increasing order of their acidic strength. ; HOCIO,, HOCI, HOCIO, HOCIO, 1 11926. 27. (a) @ (b) (a) (b) (a) (b) (c) (a) (b) ©) (d) State the probable oxidation states of the transition metals with the following configuration in their ground states: 3@ ii) 3d iii) 34° Gili) 3 What happens when (write balanced chemical equations): (i) Acidified potassium permangnate solution reacts with aqueous potassium iodide solution, Write the colour change taking place, if any. (ii) Acidified solution of potassium dichromate reacts with aqueous solution of Sn(II) chloride. Write the colour change taking place, if any. OR Name the chief ore of iron. Write balanced chemical reactions involved in its extraction. Compare the chemistry of Actinoids and lanthanoids with special reference to (i) Electronic configurations (ii) Oxidation states Write two differences between vitamins and hormones. Give one example of each. List four biological functions of proteins. Name two diseases which are caused by the deficiency of vitamin A and B. OR Name the nitrogen bases which are present in RNA and DNA What is the difference between c-D glucose and B-D glu- cose? Write the chemical reaction for commercial preparation of glucose. What are fibrous and globular proteins? Give one example of each. Name the disease caused by the deficiency of insulin where in human system insulin is secreted. 120MARKING SCHEME-II SAMPLE QUESTION PAPER - II CHEMISTRY Time : 3 Hours Max. Marks : 70 QNo. Value Points Marks Total 1. Lead zirconate or any other example. 1 1 2. Maximum Boiling Azeotrope 1 1 3. mol L+ $+ 1 1 4, 4—Bromo-2-methyl — 3 — Oxopentonoie acid 1 1 CH; Cis 1 1 5. 1,C— C—NH, —KMnOy_, HyC— C—NO, cH, CH; OR 6 ol s?a*1 s°62s7o *2s’o2p? n2p? n2py n*2px n*2p2 1 Ng = 10, Na =8 1 Bond order = (Nu Na) “ 2 1 = 5(10-8)=1 oy Diamagnetic as all the electrons are paired 7. Ny +0,—> 2NO % As the reaction is spontaneous, AG is —ve % AG = AH - TAS Endothermie reaction therefore, aH is positive for 4G to 4 be negative : (i) AS should be positive and % (ii) numerical value of TAS > AH % 121Q.No. Value Points Marks Total Stone Al(Scm’ mot") w weak 7 c%/ (mot ")? In both cases, molar conductivity increases with dilution. Reason : In weak electolytes, the increase on dilution is due % to the increase in the degree of dissociation which increases the number of ions, In strong electrolytes, the increase is because of decrease in ” the inter ionic hindrance towards mobility of ions. » Aluminium is used as a structural material because nv (i) [tis light weight and has high tensile strength, 1 (ii) Being highly eletropositive it reacts with oxygen of air | to form a hard protective layer of Al,O, which makes it passive. 10. In the reaction with Nal, C-I bond first cleaves and then reforms. This leads to the formation of a racemic mixture which is optically inactive. CH; CH; &, 2 1, tir > H-C-I —~H- —_—_ 7 H-" “Nab CoHs CoHs cH; CH; 1 1 H-¢-I4 ee CoHs CoH; racemic mixture 122Q.No. Value Points Marks Total OH i i COOH ul. () — CoHsOH igre Salicylic acid 2 cH, CH, 1 (i) CH;~CH, ~CH, -C= CH,#85cu, ~cH, ~cH, -¢-CH, | sxo8 ~ 2 methyl -1- pentene CH, L CH, ~ CH, ~CH, ~C-CH, - OH 2 — methyl — 2 — pentanol OR ou I NaBH, 1 CH, ~C—CH, ~CH, “5 cH, -¢H-CH, —CH, (A) 3) | HBr Br 1 CH, -CH-CH, -CH, © Mirror i CH ae. ty yea 2 Enantiomersof Cy H=C-Br | Br=C-H CH,-CH! Hy yy Methyl methacryl i 12. i thyl it be @ Methyl methacrylate yc- & coocty ss (ii) Butadiene H,C = CH-CH = CH, 2 and acrylonitrite NC-CH, = CH, 123).No. Value Points Marks Total 48x 10 atoms ~~ 4 atoms/ unit cell % = 12x10” Unit cells 3 Volume of substance=No.of unit cells x Volume of unit cell = 12x10 x8 x10 4 cm? - 3 = 9.6 cm i mass 400g snails ae 7 sagt % Density = clue = 9.6em> 7 41-7eem’ " OR Calculation of molar mass Mass of 48 x 10 atoms = 400g. 23, *. Molar mass = massof 6 x 1023 atoms pds Gwe 50gmol™! 48 x 10° For Fee unit cell, Z= 4 = 0.2 mm = 2x10em 2M a'NA 4x50 © 8x 1074 x 6x 1072? =41.7¢ cm? 3 The relation for determination of molar masses using colli- gative properties is based on the assumption that the solu- tions formed are ideal and there is no change in the number of particles. % 125Value Points Marks Tot In some cases molecules associate. Thus the effective number of solute particles becomes less and the molar mass so obtained is more than the calculated molar mass. For ex- ample, ethanoic acid dimerises in non-polar solvents togive CHy- C. C-CH, No-H~ 04% Molar mass of ethanoic acid is 60 whereas that determined by colligative properties is 120. 2 w In case of ionic solutes, the dissociation of solute into ions increases the effective number of particles. Thus the volume of colligative property increases and molar mass decreases. For example, in KCl which dissociates as KCl= K*+Cr’, the calculated molar mass is 74.5 whereas that determined by colligative properties gives the value 37.25. 16. (a) 28O,(g)+O>(g) == 2S0;(g) A,G° =[2(-371) - 2(-300)] KJ mol” = -742 +600 =-142 kJ mol! 4,G° at xo oe * © 73303 RT " 142000 © 2303x8314 x 300 = 24.72 k = antilog 24.72 = 5.248 x 10* (b) In imperfect crystal, there is more disorder, therfore its entropy is more than that of the perfect crystal. 17. (a) Volume of silver to be deposited = 100cm? x 0,0005cm x 2 sides =0.lem® 1 Mass = 10.5 x O.1g = 1.058 126Q.No. (b) 18. (a) Value Points 108g Ag (Imol) is deposited by 96500C. 0.5g Ag is deposited by 96500C 108g x 105g = 938.2C When the coating is damaged, rusting would be faster when the metal is less eletropositive that iron. Therefore, sheat coated with metal C whose standard electrode potential (— 0.20) is more than that of iron (0.44), would corrode faster. Let the rate law be as follows rate = k [A] [BP my _24x10t koa) for] 60x10? K’fo2] x [ory i) 02 4oei2* x=2 a _ Koz} x[o2?” K(o2}* x[o.)’ 2 = 2 youl Thus, rate law is rate = KAP [B) 127 Marks Total 1 3Q.No. 19, 20. 21. 22. Value Points Marks (by fs te [Ro] Given that ts - Hence, n—1=1 [Ro] Therefore n = 2 or it is second order. (a) Each enzyme has a specific active site on which only a spe- cific substrate can bind. (b) It is because of Tyndall effect caused by scattering of light by colloidal particles (c) Chemisorption involves the formation of a chemical bond between adsorbent and adsorbate which involves high energy changes while in physisorption adsorbate and adsorbent are held by weak van der Waals interactions. (a) Diamminechloro(methylamine) platinum(I1) chloride. (6) Pentaaminenitrito — N — cobalt(II) cation (c) CO isa weak donar and still metal carbonyls are stable com- pounds because of back bonding resulting from delocalisation of electrons from filled d orbitals of metal into the empty orbitals of CO ligands. 30 209 @@ jsP Gi) 4g, Bi (b) The capture of electrons from the K shel! by the necleus of a nuclide. (c) Nuclear fission, because the reaction can be controlled. (a) Ketones are less reactive than aldehydes towards nucleophilic addition reactions because (i) they have two electron - donating alkyl groups which reduce the residual positive charge on carbonyl carbon, and (ii) the tetrahedral intermediate is more crowded in case of ketones. (b) Benzoic acid is a stronger acid than ethanoic acid because 128 1% TotalQ.No. Value Points Marks Total (i)_benzene ring is electron withdrawing and facilitates the release of H’ ion, and e~ (ii) the resulting carboxylate anion is stabilized by resonance. In ethanic acid, CH, ~ group increases the electron density on coo group and makes the release of H* difficult. Also the resulting carboxylate anion cannot stabilize by resonance. 23. @ Coupling reaction : Reaction of an aromatic diazonium 1% 3 salt with phenol / aromatic amines at low temperature to give coloured azo compounds. mi eri OroO) az0 compound OR any other suitable example (i) Hofmann Bromamide reaction : Primary amides react with bromine in presence of an aikali to give a primary amine having one carbon atom less than the amide Br R-CONH, ——2-5 R-NH, on” (b) Aniline decolorizes bromine water and CH; CH, NH> does not or aniline gives azodye test while CH, CH, NH, doesn't, OR (a) (i) Clemmensen reduction : Aldehydes or ketones get reduced to hydrocarbons on treatment with zink amal- gam and cone. HCI Zn-Hg - BS = CH, +H,0 i‘? GIs Seroeets ae (ii) Cannizzaro reaction : Aldehydes having no ot - hy- drogen undergo disproportionation with concentrated alkali to give an alchohol and the salt of cerboxylic acid. 1 129Q.No. 24, 25. Value Points 2 RCHO —°#+RCH,OH + RCOO™ Na* (b) 2—Pentanone would give positive iodoform test in which the compound is keated with alcoholic NaOH and I, to give a yellow coloured solid with characteristic smell. 3 - Pentanone would not give iodoform test. (a) Vat dyes — insoluble in water. They are applied as aque- ous solution of the leuco form. On re-oxidation, the origi- nal dye is formed on the fabric. Example - Indigo or any other suitable example b Tranquilizer —chemical compounds used for treatment of stress, mild and severe mental diseases. Example-veronal or any other suitable example ( Hybrid rocket propellant — consists of solid fuel and lig- uid oxidant example acrylic rubber + liquid NjO,. (a) The steps involve three stages : (i) Sulphur or sulphide ore is burnt in air to form SO, gas. (ii) SO, is converted to SO, by reaction with oxygen in in the presence of a catalyst. Marks 280,(g) +0,(g) 2%» 280,(g) A,H® =196.6kI mol"! In practice the plant is operated at a pressure of 2 bar and a temprature of 720K. The SO, gas from the catalytic converter is absorbed in conc H,SO, to form oleum H,$,0, which on dilution with water gives H,SO, of desired concentration. SO, +H,SO, —> H,8,0, H,S,0,+H,0 —> 2H,SO, (b) Silicones are the polymers, which contain R.,SiO repeating units. The empirical formula is analogous to that of aketone RCO, hence these materials are named as silicones. 130 % Total weQ.No. (c) @) (b) 26. Value Points Marks Total They are prepared by the hydrolysis of 1 R2 SiC1,[R = Me or Ph] * I R,sicl, 20, -O-Si -O-Si-O-Si-O -HCl 1 1 1 R R R Br F, has T shaped structure. The central Br atom has 1 7 valence electrons. Out of these 3 electrons form bonds with F atoms, Two lone pairs occupy the equitonial positions along with one F atom. The remaining two F atoms occupy the axial posi- tions to form a T shaped structure. OR () InSF,, S atom is sterically protected by F atoms which does not allow thermodynamically favourable reactions like 2 hydrolysis to take place. 2 SF, is less sterically hindered and undergo hydrosysis easily @) AICI, isa strong Lewis acid and acts as a catalyst in organic reactions. 1 (ii) @)_CasP, + 6H,0 —> 3Ca(OH), +2PH3 (b) Pb3O, +4HNO; —> 2Pb(NO,), + PbO, +2H;0 (iii) HOC] < HOCIO < HOCIO, 2Mn** +8H,0+51, 1 (ii) Tin (II) chloride is oxidised to tin (LV) chloride and the 131Q.No. Value Points Marks = Total orange colour of K,Cr,0, Solution tums to green. CrOF +14H* +3Sn?* —>3Sn** +2Cr** +7H,0 OR {a) Heamatite. Fc.03 1% 3Fe,0,;+ CO—» 2Fc,0,+ CO, — upper part of Fc,0, +4CO —s 3Fe+4CO, blast furnace F,0;+CO —+ 2Fe0 +CO, Lower part of FeO+C —> Fe+CO Blast furnace 1 (b) Lanthanoids Actinoids @) Electronic 4fO'4 sa! 65? Ist .6do 5 fot configuration NR (i) Oxidation states | ‘The principal oxidation | In general +3. The “state is +3 although +4 | element in the first and +2 oxidation states’ | half of the sources are also exhibited by frequently exhibit some occasionally higher oxidation states of Th= +4 Pa=+5 U=+6, Np =+7 % Harmones Vitamins 27. (a) Molecules that transfer (i) These are essential dietary information from one group of factors required by an organism cells to distant tissue or organ. in minute quantities. (i) These are synthesised by the (ii) Supplied to the body chiefly body's own glands. from the food eaten. NR Examples: Harmones ; Estrogens Vitamins : Vitamin D or any other suitable example. 132Qo. Value Points Marks Total (b) Functions : For transport mechanism as oxygen by heamoglobin © For maintainance of fluid balance. For regulation of metabolism. Connective tissues. or any other functions aupe (c) The deficiency of the Vitamin A causes Xerophathalmia disease. Deficiency of Vitamin B, causes Beri-beri disease. OR (a Adenine, Guanine, Cytosine CH,OH CH,OH () H}- “0+ H H O\ on it H ou H oH OH H OH a otf OH H ; Ou ( Commercially, glucose is obtained by the hydrolysis of starch, by boiling it with dil HjSO, at 393K under pres- sure (CoH00s),, + 1H{0 E> nC gH 20, - @ Fibrous proteins have large helical content and have rod like rigid shape and are insoluble in water e.g. silk in globular protein polypeptide chain consists of partly helical section, which are folded about the random cuts to give it a spherical shape e.g. globins. (e) Diabetes mellitus, Insulin is secreted by islets of langerhans. 133Q.No. Value Points Marks Total (b) Functions : For transport mechanism as oxygen by heamoglobin For maintainance of fluid balance. For regulation of metabolism Connective tissues. or any other functions fee (c) The deficiency of the Vitamin A causes Xerophathalmia disease. Deficiency of Vitamin B, causes Beri-beri disease. OR (a Adenine, Guanine, Cytosine CH,OH CH,0OH () oH on H H ‘O\ OH i H H ou H oH OH OH HB H OH HOH « Commercially, glucose is obtained by the hydrolysis of starch, by boiling it with dil H)SO, at 393K under pres- sure (CoH 1095), +H,0 > nC gH 20, - SKB (d Fibrous proteins have large helical content and have rod like rigid shape and are insoluble in water e.g, silk in globular protein polypeptide chain consists of partly helical section, which are folded about the random cuts to give ita spherical shape e.g. globins. Diabetes mellitus, c Insulin is secreted by islets of langerhans. 133