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densitas mr 46

volum pic 10 18 komposisi


picno kosng 8.513 %
massa densitas kondensat
no kondensat boiling kondensat boiling 1.360 0.014
1 8.061 8.913 0.8061 0.8913 1.4 0.014
2 8.074 8.973 0.8074 0.8973 2.23 0.022
3 8.148 9.219 0.8148 0.9219 3.9 0.039
4 8.122 9.223 0.8122 0.9223 boiling
mol etanol air fraksi mol etanol air 3.9 0.039
0.1752391304 0.495167 0.261392624 0.738607 4.2 0.042
0.1755217391 0.4985 0.260409611 0.73959 4.9 0.049
0.1771304348 0.512167 0.256972551 0.743027 5.1 0.051
0.1765652174 0.512389 0.256280086 0.74372

etanol air 1.3


A 16.6758 16.262
B 3674.49 3799.89 R
C 226.45 226.35 8.314

uap cair T av (K)


suhu 65 78 344.65
65.5 77 344.4
65 78 344.65
65.5 78 344.9 y1
0.245189
ln P1dan ln P2 4.068182913 3.776736 P1 P2 0.241641
4.0897749957 3.735578 62.31335494 54.58796 0.241296
4.068182913 3.776736 64.36543828 55.08746 0.239764
4.0897749957 3.776736 62.24803784 54.65327
P1sat dan P2sat 58.450656111 43.67327 63.84056133 55.61234
59.726451485 41.91226
58.450656111 43.67327
59.726451485 43.67327

A12 A21
72.559 0.014 -72.53151128 145.1043974 -3.98628 0.29812
70.459 0.014 -70.430170749 140.90295 -3.95835 0.29667
43.861 0.023 -43.815401658 87.69924954 -3.49186 0.289163
24.651 0.041 -24.570075748 49.26193532 -2.92262 0.282199

margules van laar WILSON


ln γ 1 ln γ 2 ln γ 1 ln γ 2 ln γ 1 ln γ 2
-10.3430 7.3229 2.6204344E-06 0.01379 -2.658 -1.031
-10.0322 7.0668 2.8618181E-06 0.01420 -2.630 -1.030
-6.2162 4.3030 1.1855665E-05 0.02279 -2.163 -1.016
-3.4829 2.4063 6.662977E-05 0.04046 -1.594 -0.990
NRTL
Ɛ12 0.064 ln γ 1 ln γ 2
Ɛ21 0.084 2.6577292E-11 6.505618E-12
2.6648083E-11 6.469769E-12
-6.979779E-06 2.6896337E-11 6.34434E-12
6.979779E-06 2.6946493E-11 6.319056E-12
G12 0.9999930202
G21 1.0000069798

1.000409 1.0002977056
1.000426 1.0002863936
UNIQUAC 1.00041 1.000297038
10.0000
ln γ 1 ln γ 2 1.000416 1.0002927756
4.2330230894 2.0007069567 f(x) = 905.3392405951x - 228.9941887725
4.3894012691 3.2719609733 5.0000 R² = 0.9391960901

4.2415605376 3.3436933464
4.2946870427 3.316673322 0.0000
0.256 0.257 0.258 0.259 0.26

-5.0000 f(x) = - 1259.0739968206x + 318.2840847368


R² = 0.9329603536

-10.0000

-15.0000
l n gamma 1 Linear (l n ga mma
l n gamma 2 Linear (l n ga mma

0.045

0.04

0.035
f(x) = - 4.3009584695x + 1.1357411117
0.03 R² = 0.7521989305

0.025 L
L
0.02 L
L
0.015

0.01

0.005

0 f(x) = - 0.0092183963x + 0.0024063784


0.256 R²
0.257 0.258 0.259 0.26 0.261 0.262
= 0.5699309389
0.00
0.256 0.257 0

-0.50

-1.00
f(x) = - 6.6
R² = 0.777
-1.50

-2.00 f(x) = - 18
R² = 0.853

-2.50

-3.00
v
etanol (ml) air (ml) V2/V1 V1/V2

0.136 9.864 72.529411765 0.013788


0.14 9.86 70.428571429 0.014199
0.223 9.777 43.843049327 0.022809
0.39 9.61 24.641025641 0.040583 persamaan konsistensi
margules van laar wilson
0.39 9.61 24.641025641 0.040583 -46.429817 0.8595691718 -2.293785
0.42 9.58 22.80952381 0.043841 -46.42485 0.860730208 -2.277569
0.49 9.51 19.408163265 0.051525 -46.407482 0.8647897196 -2.220871
0.51 9.49 18.607843137 0.053741 -46.403983 0.8656075908 -2.209448

= 100
0.104793
0.13
0.113036

0.14

y2 alfa12 alfa21
0.5909252426 1.1724365651 0.852925
0.5627034119 1.2196232427 0.819925
0.5937510846 1.1750711558 0.851012
0.5840553054 1.1913118265 0.839411

TO TO
DIKALI DIKALI
1.0000036489 6.979805E-06 0.999989689 -6.979707E-06
1.0000036352 6.979805E-06 0.999989676 -6.979707E-06
1.0000035872 6.979804E-06 0.999989628 -6.979707E-06
1.0000035776 6.979804E-06 0.999989618 -6.979707E-06

-6.979756E-06 6.979803E-06
-6.979756E-06 6.979803E-06
-6.979756E-06 6.979803E-06
-6.979756E-06 6.979803E-06
3E-11

51x - 228.9941887725 2.5E-11 f(x) = - 7.22177223791819E-11x + 4.54543775905609E-11


R² = 0.9999996863

2E-11
.258 0.259 0.26 0.261 0.262 Ln gamma 1
1.5E-11 Li near (Ln gamma 1)
68206x + 318.2840847368 Ln gamma 2
Li near (Ln gamma 2)
1E-11

5E-12 f(x) = 3.64914807980179E-11x - 3.03297560242613E-12


R² = 0.9999999856

mma 1 Linear (l n ga mma 1) 0


mma 2 Linear (l n ga mma 2) 0.256 0.257 0.258 0.259 0.26 0.261 0.262

4.5

4 f(x) = 4.681794728x + 3.0781893736


R² = 0.026873061
x + 1.1357411117 3.5
f(x) = - 188.533713863x + 51.7689434335
3 R² = 0.5235095979
Ln ga mma 1 Ln Gamma 1
Li near (Ln ga mma 1) 2.5 Li near (Ln Gamm
Ln ga mma 2 Ln Gamma 2
2 Li near (Ln Gamm
Li near (Ln ga mma 2)
1.5

0.5

x + 0.0024063784 0
0.26 0.261 0.262 0.256 0.257 0.258 0.259 0.26 0.261 0.262

Chart Title
Chart Title
0.00
0.256 0.257 0.258 0.259 0.26 0.261 0.262

-0.50

Ln gamma 1
-1.00
f(x) = - 6.6274100382x + 0.6984485843 Li near (Ln gamma 1)
R² = 0.777897445 Ln gamma 2
-1.50 Li near (Ln gamma 2)

-2.00 f(x) = - 183.2602073772x + 45.1600620898


R² = 0.8532225685

-2.50

-3.00
samaan konsistensi
uniquac nrtl
141.357 -0.0000000000478
141.5607 -0.0000000000478
142.2727 -0.0000000000477
142.4162 -0.0000000000477

Sampel suhu (C) Condensat Still


Etanol Aquadest massa
T air T uap r
(ml) (ml) picno isi
50 78 66 16, 574 0.8061
60 77 65,5 16, 587 0.8074
200
70 78 65 16 0.8148
80 78 65,5 16,635 0.8122

Sampel suhu (C) Boiling Still


Etanol Aquadest massa
T air 0C T uap r
(ml) (ml) picno isi
50 78 66 17,426 0,8913
60 77 65,5 17,486 0,8973
200
70 78 65 17,732 0,9219
80 78 65,5 17,736 0,9223
Condensat Still
Kadar
Indeks
%
1.3 1,36
13,355 1,4
13,356 2,23
1,339 3,9

Boiling Still
Kadar
Indeks
%
13,389 3,9
13,395 4,2
1,340 4,9
13,405 5,1
x1 y1 p1sat p γ1 ln γ 1 x2 y2 γ2 ln γ 2
0.2562 0.738607 58.45066 62.31335 3.073451 1.122801 0.7438 0.261393 0.374653 -0.98176
0.2569 0.73959 59.72645 64.36544 3.10251 1.132211 0.7431 0.26041 0.377655 -0.97377
0.26041 0.743027 58.45066 62.24804 3.03867 1.11142 0.73959 0.256973 0.370026 -0.99418
0.2613 0.74372 59.72645 63.84056 3.042286 1.112609 0.7387 0.25628 0.370832 -0.99201

Chart Title
-2.23
-2.24
-2.25
-2.26
-2.27
-2.28
-2.29
-2.3
f(x) = - 0.2047448177x - 2.2456697708
-2.31 R² = 0.0004195505
-2.32
-2.33
0.255 0.256 0.257 0.258 0.259 0.26 0.261 0.262
0.190562 0.287662 -0.73023 -0.44257 -2.32244
0.190902 0.290865 -0.72361 -0.43275 -2.26684
0.192597 0.289425 -0.73529 -0.44586 -2.31501
0.193022 0.290725 -0.7328 -0.44207 -2.29026

y = -0.2047x - 2.2457
697708

A12 = -2.2457
A21 = -2.2453
59 0.26 0.261 0.262

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