PHYSICS - 1998 PART -A Directions 1. Section I consists of 40 objective type questions. 2. This section should take about one hour to answer. 3. Each question in this section carries 2 marks. 1. A transistor is used in common emitter mode as an amplifier, then : (A) the base emitter junction is forward biased (B) the base emitter junction is reverse biased (C) the input signal is connected in series with the voltage applied to bias the base emitier junction (D) the input signal is connected in series with the voltage applied to bias the base collector junction. 2. Water from a tap emerges vertically downwards with an initial speed of 1.0 m/s. The cross-sectional area of tap is 10“? m?. Assume that the pressure is constant throughout the stream of water and that the flow is steady, the cross-sectional area of stream 0.15 m below the tap is : (A) 5.0« 10° m? (B) 1.0x 10™ m? (©) 5.0x 10°° m? (D) 2.0x 10> m? 3. Areal image of a distant object is formed by a planoconvex lens on its principal axis, Spherical aberration + (A) is absent {B) is smaller if the curved surface of the lens féices the object (C) is smaller if the plane surface of the lens faces the object (D) is the same whichever side of the lens faces the object. 4. Let 0, Vmms and v, respectively denote the mean speed, root mean square speed and most probable speed of the molecules in an ideal monoatomic gas at absolute temperature T. The mass of a molecule is m, Then : (A) no molecule can have a energy greater than VV sms {B) no molecule can have speed less then v,/V2 (O) vp 2M; (C) Mz <2My (D) My <10(m, + my) A parallel monochromatic beam of light is incident normally on a narrow slit. A diffraction pattern is formed on a screen placed perpendicular to the direction of the incident beam. At the first minimum of the diffraction pattern, the phase difference between the rays coming from the two edges of the slit is : (A) 0 (B) W2 (x (D) 2n ‘The electron in a hydrogen atorn makes a transition ny > ng where ny and ng are the principal quantum numbers of two states. Assume the Bohr model to be valid. The time period of the electron in the intial state is eight times that in the final state. The possible values of ny and ng are : (A) ny =4,ng =2 @) ny =8,ng =2 (© ny, =8,ng=1 (D) m1 =6,ng =3 A stone tied to a string of length L is whirled in a vertical circle with the other end of the string at the centre. At.a certain instant of time the stone is at its lowest position and has a speed u. The magnitude of the change in its velocity as it reaches a position, where the string is horizontal, is : (ay yu? - 2a ®) J2gL (©) fu? - ot ©) y2u? - gl)13. 14. 15. 16. 17. 18. In the circuit shown in the figure, the current through : 30, 20 20 v= 8a, 8Q 40 20 20 20, (A) the 3Q resistor is 0.50 A (B) the 39 resistor is 0.25 A (C) the 4Q resistor is 0.50 A (D) the 40 resistor is 0.25 A A dielectric slab of thickness d is inserted in a parelle] plate capacitor whose negative plate is at x = Oand positive plate is at x = 3d. The slab is equidistant from the plates. The capacitor is given some charge. As x goes from Oto 3d: (A) the magnitude of the electric field remains the same {B) the direction of the electric field remains the same (C) the electric potential increases continuously (D) the electric potential increases at first, then decreases and again increases. The (x, y) coordinates of the comers of a square plate are (0,0), (L, 0), (L, L) and (0, L). The edges of the plate are clamped and transverse standing waves are set up init. Ifu (x, y) denotes the displacement of the plate at the point (x, y) at some instant of time, the possible expression (8) for u is (are) (a= positive constant) (A) a cos (nx/2L} cos (ny/2L) (B) a sin (nxL) sin(ny) (©) a sin (mL) sin (2nyL) {D) a.cos (2nx/1) sin (nyL} = aa A force F = — Ki y i+ x j) (where K is a positive constant} acts on a particle moving in the xy plane. Starting from the origin, the particle is taken along the positive x-axis to the point (a, 0) and then parallel to the y-axis to the point fa, a}. The total work done by the force F on the particle is : (A) -2Ka? (B) 2Ka (C) —Ka? . {D) Ka? A small square loop of wire of side | is placed inside a large square loop of wire of side L(L> >). The loops are coplanar and their centres coincide. The mutual inductance of the system is proportional to + (A) IAL BPA (LA (D) 2A The half life of 1311 is 8 days. Given a sample of 1511 at time t = 0, we can assert that : (A) no nucleus will decay before t (B) no nucleus will decay before t = days days19. 20. 21. 22. 23. 24. (C) all nuclei will decay before t = 16 days (D) a given nucleus may decay at any time after t = 0 ‘Two identical containers A and B with frictionless pistons contain the same ideal gas at the same temperature and the same volume V. The mass of the gas in A is ma and that in Bis mg. The gas in each cylinder is now allowed to expand isothermally to the same final volume 2V. The changes in the pressure in A and B are found to be AP and 1.5 AP respectively. Then : (A) dma = 9mp (B) 2m, =3mg (C) 8m, =2mg (D) 9m, = 4m A given quantity of an ideal gas is at pressure P and absolute temperature T. The isothermal bulk modulus of the gas is : a) 2p BP (c) 3p (D) 2P A charge + qis fixed at each of the points x = x9, x = 3x9, X= 5xq ... eon the x-axis and a charge -q is fixed at each of the points x= 2x9, x = 4xq, X= 6xq ...: Here Xo is a positive constant. Take the electric potential at a point due to a charge Q at a distance r from it to be Q/4negr. Then the potential at the origin due to the above system of charges is : a wy ® SS and (x qin (2) In & xo Let I be the moment of inertia of a uniform square plate about an axis AB that passes through its centre and is parallel to two of its sides. CD is a line in the plane of the plate that passes through the centre of the plate and makes an angle 9 with AB. The moment of inertia of the plate about the axis CD is then equal to: (A) 1 @B) Isin? @ (©) Leos? @ ©) Icos? (@/2) Two cylinders A and B fitted with pistons contain equal amounts of an ideal diatomic gas at 300 K. The piston of A is free to mave, while that of B is held fixed, The same amount of heat is given to the gas in each cylinder. If the tise in temperature of the gas in A is 30 K, then the rise in temperature of the gas in Bis: (A) 30K ®) 18K (©) 50K (0) 42K A concave mitror is placed on a horizontal table with its axis directed vertically upwards. Let 0 be the pole of the mirror and C its centre of curvature. A point object is placed at C. It has a real image, also located at C. If the mirror is now filled with water, the image will be = (A} real and will remain at C (B} real and located at a point between C and «25. 26. 27. 28. 29. (C) virtual and located at a point between C and 0 (D) real and located at a point between C and 0 A metal rod moves at a constant velocity in a direction perpendicular to its length. A constant uniform magnetic field exists in space in a direction perpendicular to the rod as well as its velocity. Select the correct statement (s) from the following : (A) the entire rod is at the same electric potential (B) there is an electric field in the rod {C) the electric potential is highest at the centre of the rod and decreases towards its ends. (D) the electric potential is lowest at the centre of the rod and increases towards its ends. A positively charged thin metal ring of radius R is fixed in the xy plane with its centre at the origin O. A negatively charged particle P is released from rest at the point (0, 0, 29) where 29 > 0. Then the motion of P is : {A) periodic for all values of zp satisfying 0 < zy < © (B) simple harmonic for all values of zg satisfying 0 < zp sR (C) approximately simple harmonic provided zp << R {D) such that P crosses 0 and continues to move along the negative z-axis towards z = - A satellite S is moving in an elliptical orbit around the earth. The mass of the satellite is very small compared to the mass of the earth : (A) The acceleration of S is always directed towards the centre of the earth. (B) The angular momentum of S about the centre of the earth changes in direction, but its magnitude remain constant. (C) the total mechanical energy of S varies periodically with time (D) The linear momentum of $ remains constant in magnitude. > as The torque t on a body about a given point is found to be equal to A x L. > > where A is a constant vector and L is the angular momentum of the body about that point. From this it follows that : = : > (A) = is perpendicular to L at all instants of time ~ > (B) the component of L in the direction of A does not change with time. + (C) the magnitude of L does not change with time. (0) L does not change with time During the melting of a slab of ice at 273K at atmospheric pressure : (A) positive work is done by the ice-water system on the atmosphere (B) positive work is done on the ice-water system by the atmosphere. (C) the internal energy of the ice-water system increases. (D) the internal eneray of the ice-water sustem decreases30. 31. 32. 33. 34. 35. 36. In a p-n junction diode not connected to any circuit : {A] the potential is the same everywhere (B) the p-type side is at a higher potential than the n-type side (©) there is an electric field at the junction directed from the n-side to the prtype side (D) there is an electric field at the junction directed from the p-type side to the n-type side, A spherical surface of radius of curvature R, separates air (refractive index 1.0) from glass (refractive index 1.5). The centre of curvature is in the glass. A point object P placed in air is found to have a real image Q in the glass, The line PQ cuts the surface at a point O and PO = OQ. The distance PO is equal to : (A) 5R (B) 3R (©) aR (0) 15R A non-conducting solid sphere of radius R is uniformly charged. The magnitude of the electric field due to the sphere at a distance r from its centre ; (A) increases as r increases for r < R (B) decreases as r increases for 0 Up (D) Up >U, Let [eq] denote the dimensional formula of the permittivity of the vacuum and [uo] that of the permeability of the vacuum. IfM = mass, L = length, T = time and I= electric current : (A) [eg] = IMT? B) [eg]= IMLS T47] (©) Wol=IMLT 1?) (D) fkol= (MT The SI unit of the inductance, the henry can be written as ; (A) Weber/ampere. {B) Volt-second/ampere (C) JouleAampere)? {D) ohm-second37. Two verylong straight parallel wires carry steady currents I and I respectively, The distance between the wires is d. At a certain instant of time, a point charge q is at a point equidistant from the two wires in the plane of the wires. Its instantaneous velocity v is perpendicular to this plane. The magnitude of the force due to the magnetic field acting on the charge at this instant is : Holav Bolav ond - Bd 2u ol wc “ow (D) 0 ad 38. X-rays are produced in an X-ray tube operating at a given accelerating voltage. The wavelength of the continuous X-rays.has values from : (A) Oto B) Amin to Where Ximin > 0 (C)0 to Ammax Where Amax < (D) Xmmin tO % max Where 0 < Rinin Varsiter This has been shown a n-p-n transistor. Therefore, base-emitter are forward biased and Input signal is connected between base and emitter, «© From conservation of energy VE = V? + 2h i [ean also be found wy applying Bernouili's theorem between 1 and 2) From continuity equation AqV; = ApVp: Ve -(2)v o Ag Substituting valug of Vz from equation (2) in equation (1) Ay V2 = Vy? +2gh Ag 2y 72 ATV; VP 4 2gh -— AM vy? + 2gh Substituting the given values Ap = 2 or AB Ae (10-4 m?) (1.0 ms) ny) + 2 (10) (0.15) Ap =5.0x10% m? {B) In general spherical aberration is minimum when the total deviation produced by the system is equally divided on all refracting surfaces. A planaconvex lens isused for this purpose. In order that the total deviation be equally divided on two surfaces, it is essential that more parallel beam (of the incident and refracted) be incident on the convex side. Thus when the object is far away from the lens, incident rays will be more parallel than the refracted rays, therefore, the object should face the convex side, but if the object is near the lens, the object should face the plane side. This has been shown in figure (C.D) '3RT Yims = “M_ 5. [8 Ri, [25RT rene ape and 2RT YPM From these expressions we can see that Vp <3 critical angle, 6. or sini> sine, or sin 45¢> 1 Li Asl or Bs or n> or n>1414 Therefore, possible values of n can be 1.5 or 1.6 in the given options. (C,D) Due to mass defect (which is finally responsible for the binding energy of the nucleus), mass of a nucleus is always less than the sum of masses of its constituent particles. JoNe is made up of 10 protons plus 10 neutrons. Therefore, mass of 29Ne nucleus My <10(mp +m) Also, heavier the nucleus, more is the mass defect. Thus, 20 (my +mp)—Mz >10(mp, + mp) —My or 10(mp + ma)> Mz ~My or Mz (Slope) as Becouse Ey 4 = Epa aq andE,- 4 >Ea—2g 15. 8,0) ve Since the edges are clamped, displacement LL of the edges u (x, y) = 0 for (01) € B OsxsL OsysLl : OsxsL OC ie. x=0, O oS & dW = F , ds where ds = dxi + dy} + dah and Fa-Klex) AW = = K gd + acy) = = kd 3) ={* = 3 = 1, 2) = Jog, SY ~¥ fgg, 868) = Kb, 3 W-=- Ka? Alternate Solution While moving from (0, 0) to (a, 0) along positive x-axis, y = 0 uFe- Kxji.e. force is in negative y-direction while the displacement is in positive x-direction. Therefore, Wy = 0 (Force 1 displacement) Then it moves froma, 0) to (a, a) along a line parallel to y-axis (x = + a). During this s F =-Kyi + aj) The first component of force, —ky! will not contribute any work because this component is along negative x-direction (1) while displacement is in positive y-direction [la, 0) to (a, al]. The second component of force i.e. —Kaj will perform negative work We = (~ka) (a) = - Ka? W= wy + wy = Ka?— The given force is conservative in nature. Therefore, work done is path 17. 18. 19. independent. it depends only on initial and jinal positions. Therefore, first method is brief and correct. 8) Magnetic field produced by a current j in a large square loop at its centre, Bat L i B=K+ say c ~ Magnetic flux linked with smaller loop, o=BS o-(K Therefore, the mutual inductance 2 M-$-K5 or Mal Dimensions of self inductance (L) or mutual inductionce (M) are : (Mutual inductance] = [Self inductance} Wo] Length} N Similarly, Dimensions of capacitance are : feapacitance]=[<] [Length] Ny From this point of view options B and D may be correct. ©) Number of nuclei decreases exponentially N=Noe™ and Rete of decay (- S). aN t=0 Therefore, decay process . upto t = «. Therefore, a given nucleus may decay at any time after t = Ke) Process is isothermal. Therefore, T= constant. (pad) vohime is increasing, therefore, pressure will decrease. In chamber A> RT RT RT AP (Pq) (Pa), = “A= - PA = BA Vv av av {Ly In chamber B> + (2) 1.5 AP = (Pp); - (Pp); = 2B - PBS LSFrom (1) and (2) n, or or or 3m, = 2mg 20. (B) In isothermal process PV = constant s PdV + vee. =0 7 or (@--@ Bulk modulus, B= -() _ (¥) v B= -[(-2) i P Vv B=P > Adiabatic bulk modulus is given by B = 21. (D) Potential at origin will be given by ~ 22. (A) P AB LAB and C'D'1CD From symmery A 8 Fromm theorem of perpendicular axes, Izz =Iap + lap =lep + low = 2a = 2lep : lap = ep cop ° Alternate Solution The relation between Ian and Icp should be true for all values of 6. and at @=0,lep = Ian Similarly at 6= 1/2, Icon =laB (by symmetry) Keeping these things in mind, only option (A) is correct.23. 24. 25. 26. ©) A is free to move, therefore, heat will be supplied at constant pressure 5 dQq =nCpdTs (1) Bi is held fixed, therefore heat will be supplied at constant volume * (2) But (Given) 7 =1.4 Giatomic) o) yf Nonmel at P will fo ass through C Image oO oO The ray diagram is shown in figure. Therefore, the image will be real and between C and D. @) ‘ A motional emf, e = Bivis induced in the rod. Or we can say a potential difference is induced between the two x x || x ends of the rod AB, with A at higher potential and B at B lower potential. Due to this potential difference, there is xe an electric field in the rod. (A, C) Let @ be the charge on the ring, the negative charge -q is released from point P (0, 0, Zo). The electric field at P due to the charged ring will be along positive z-axis and its magnitude will be -L_ __ Yo __ Ax & (R? + 297)? E~ Oat centre of the ring because Z, = 0 x x xB z27. 28. Therefore, force on charge P will be towards centre as shown, and its magnitude is = __ trey Rs 2g Similarly, when it crosses the origin, the force is again towards centre O. Thus the motion of the particle is periodic for all values of Zy lying between 0 and © Secondly ifZo < oat T= ak dt d_o dk = ot deed 7 at dt 7 ~ 4 But since rik at 7a i=. dt :29. ‘Therefore, from equation (1) * > or magnitude of L i.e. L does not change with time. (B) So far we are confirm about two points : Cc > a) tor a Land > (2)| L lorLisnot changing with time, thereforeitisa r case when direction of i is changing but its magnitude is constant and t is perpendicular to L at all points. L This can be written as : > = = If L =(acos@j i +(asin® j Herea = positive constant > 7 : then t =(a sin@i-(e cos 6) j a oF sothat L.t=QandLict > > > Now Ais a constant vector and it is always perpendicular to t. Thus A can be written as A=AK +> We can see that L.A =0 > > ie Lt Aalso > > + ‘Thus we can say that component of L_ along A is zero or component of L ss along A is always constant. Finally we conclude t, A and L are always mutually perpendicular. (B,C) There is a decrease is volume during melting on an ice slab at 273K. Therefore, negative work is done by ice-water system on the atmosphere or positive work is done on the ice-water system by the atmosphere. Hence option (B) is correct. Secondly heat is absorbed during melting (Le. dQ is positive} and as we have seen, work done by ice-water system is negative (dW is negative). Therefore, from first law of thermodynamics dU =dQ- dW change in internal energy of ice-water system, dU will be positive or internal energy will increase.30. 31. 32. © At junction a potential barrier/depletion layer is formed as shown, with n-side at higher potential, ° and p-side at lower potential. Therefore, there is an electric field at the junction directed from the |° © n-side to p-side. oo (A) Letussay PO=OQ=X Applying He Bi Be ML u R v Substituting the values with si 4510 1 S10 +X -X +R (Distances are measured from O and are taken as positive in the direction of ray of light) 05 R X=5R (A, C) Inside the sphere , 1&8, tre Ro = Ear for rR ie, Eat centre=0 &=0 and Eat surface = zt & (=i Outside the sphere 1. Q E 2 R ane 12 = or Ext r Thus variation of electric field (E) with distance (r) from the centre will be as follows :33. (A, C) Maximum speed of any point on the string = aa =a (2ni) 0) (Given) =10/10 (v= 10 ms) =1 2naf =1 fe 2a a=10%m (Given) f-—1__.10 4, Qnx108 an Speed of wave v=fa (10 m4) = (2 s*) » 2x b= 2x x10 m 34. (0) Wein's displacement law is : dmT=b {> = wein’s constant) aw B 2:88 x 10% nok mot 2880 nm = 1000 nm Energy ait with wavelength will be as follows : nm) a =1000nm From the graph it is clear that Ug >U, (In fact Ug is maximum) 35. BO pet ace 4neg” 1? leg) = @ullaa!_ tm? TY yt r4y2] (Fite?] (MLT~?)(L7)36. 37. 38. Speed of light, c= Veo Ho ole —L leo lle! a MOL T4) wrt? =(MLT71?| B.ED) Weber =? Henry = Weber (A) Les or erty = ere di ° a “) second __e _ Volt-secon: Loam Henry = Vettsecon oO U- 3 Le 2u Joule -W Henry = “owe 2 i. (Ampere)? oO U=$L? =i?R ‘ es L=R.t or Henry = ohmrsceond (D) and velocity in z-direction a 2 VA I -l x z Wires are in x-y plane _— oo Net magnetic field due to both the wires will be downward as shown above. +S Since angle between v and B is 180° Therefore, magnetic force Fm'=qlv x B)=0 ®) The continuous x-ray spectrum is shown in figure. All wavelengths > Amin are found, where a. = 123754 mn “"'V (in volts) » Here V is the applied voltage. Panis39. (A) U®=kIxP y- Met? we) ‘Now time period may depend on T « (mass) * (amplitude)? (k)? ‘ (M°L°T] = IM}* ILI¥ (ML Tr * [Metz 72 7-2 Equating the powers, we get -2z=1 or z=-1/2 y-2=0 of yaze-1/2 Hence Ts (amplitude) “/? MLIT ela)? or ted ane 2375 sn A*) w 12375 _ 12375 ji 2 = Eo eg A = 8093 A or a » 309.3 nm or 310 nm. > 1 (in A2) = 12375 comes from W = BE WleV) hCHEMISTRY - 1998 PART -A 1. Read questions 1 to 28 carefully and choose from amongst the alternatives given below each question the correct lettered choice (5). A question may have one or more correct alternatives. In order to secure any marks for a given question, all correct lettered alternative(s) must be chosen Which of the following statement(s] is(are) correct when a mixture of NaC] and K C1907 is gently warmed with conc. Hy$Oq : (A) A deep red vapour is evolved. (B) The vapour when passed into NaOH solution gives a yellow solution of NagCrO4 (C) Chlorine gas is evalved (D) Chromyl chloride is formed. Highly pure dilute solution of sodium in liquid ammonia = (A) shows blue colour 7 7 exhibits electrical conductivity (C) produces sodium amide (D) produces hydrogen gas ‘The reaction CH3CH = (an with HBr gives : rN) never oe crycH,cHa—€\—on wo) crgcrigcri—{_\—er p-Chloroaniline and anilinium hydrochloride can be distinguished by = (A) Sandmeyer reaction (B) NaHCO; (©) AgNO3 (D) Carbylamine test The energy of an electron in the first Bohr orbit of H atom is -13.6 eV. The possible energy value(s) of the excited state(s) for electrons in Bohr orbits of hydrogen islare) : (A) 34 eV @) -4.2eV (C) -6.8eV (D) +68eV In nitroprusside ion the iron and NO exist as Fe!’ and NO* rather than Fell and NO. These forms can be differentiated by : (A) estimating the concentration of iron. (B) measuring the concentration of CN. (C) measuring the solid state magnetic moment. {D) thermally decomposing the compound. (C) CH3CHBrCH9:10. 11. 12. 13. 14, 15. Which of the following statement{s) is(ere) correct (A) The coordination number of each type of ion in CsCl crystal is 8. (B) A metal that crystallizes in bec structure has a coordination number of 12. ({C) Aunit cell of an ionic crystal shares some of its ions with other unit cells. (D) The length of the unit cell in NaCl is 552 pm. (ry. = 95 pm; Tg- = 181 pm) Sodium nitrate decomposes above -800°C to give : (A) No (B) Og (OQ) NOg (D) NazO Which of the following statement(s) is (are) correct with reference to the ferrous and ferric ions : (A) Fe3+ gives brown colour with potassium ferricyanide. (B) Fe** gives blue precipitate with potassium ferricyanide (CQ) Fe* gives red colour with potassium thiocyanate. {D) Fe?* gives brown colour with ammonium thiocyanate. Which of the following statement(s} is(are) correct : {A) The electronic configuration of Cr is [Ar] 35451. (Atornic Number of Cr = 24) (B) The magnetic quantum number may have a negative value (C) In silver atom, 23 electrons have a spin of one type and 24 of the opposite type. [Atomic Number of Ag = 47} (D) The oxidation state of nitrogen in HN; is -3. A new carbon-carbon bond formation is possible in : (A) Cannizzaro reaction (B) Friedel-Crafts alkylation (C) Clemmensen reduction (D) Reimer-Tiemann reactior White phosphorus (Pq) has : (A) six P-P single bonds (B) four P-P single bonds (C) four lone pairs of electrons (D) PPP angle of 60°. Which of the following will react with water : (A) CHCls (B) ClxCCHO (C) Clg (D) CICH2CH2Cl The standard reduction potential values of three metallic cations, X,Y, Z are 0.52, -3.03 and -1.18V respectively. The order of reducing power of the corresponding metals is : (A) Y>Z>X (B) X>Y>Z ( Z>Y>X (0) Z>X>¥ Among the following compounds, which will react with acetone to give 2 product containing > C = N — (A) CgHsNHp (B) (CHs)3N (CQ) CgHaNHCgHs _ (D) CgHsNHNH2,16. 17. 18. 19. 20. 21. 22. 23. 24. Which of the following compounds will show geometrical isomerism (A) 2-butene . (B)_ propene (C) Lephenylpropene (D) 2-methyl-2-butene The geometry and the type of hybrid orbital present about the central atorn in BF is: (A) linear, sp (B) trigonal planar, sp? (©) tetrahedral, sp* (D) pyramidal, sp* Benzyl chloride (Cg H5CHpCl can be pr pared from toluene by chlorination with : (A) SO2Cly (B) SOClz (O Cp (D) NaOCl Which of the following will undexgo aldol condensation (A) acetaldehyde (B) propanaldehyde (C) benzaldehyde (D) trideuteroacetaldehyde Addition of high proportions of manganese makes steel useful in making rails of railroads, because mangenese : (A) gives hardness to steel. (B) helps the formation of oxides of iron. (C) can remove oxygen and sulphur. (D) can show highest oxidation state of +7. Decrease in atomic number is observed during : (A) alpha emission (8) beta emission (C) positron emission (D) electron capture. Benzenediazonium chloride on reaction with phenol in weakly basic medium gives : (A) diphenyl ether {B) phydroxyazobenzene {C) chlorobenzene (D) benzene Among the following compounds, the strongest acid is (A) HC =CH B) CcHe (C) CoH, {D) CH30H For a first order reaction : (A) the degree of dissociation is equal to (1 - e”*), ®) a plot of reciprocal concentration of the reactant vs. time gives a straight ine. (C) the time taken for the completion of 75% reaction is thrice the t 1/2 of the reaction. (D) the pre-exponential factor in the Arrhenius equation has the dimension of time, T>25. 26. 27. 28. Tautomerism is exhibited by (A) & S-c1c1—on ‘B) ox =o © (re i) Cre oO oO According to Graham's law, at a given temperature the ratio of the rates of diffusion r4/rg of gases A and Bis given by (A) (Pa/Pg) (Ma/M g)¥? (B) (Ma/Mp) (Pa/Pp)¥? (© (Pa/Pg) (Mg /Ma)¥? (D) (M4/Mp) (P3/Pa)/* (Where P and M are pressures and molecular weights of gases A and B respectively.) For the reaction CO (g) + HzO(q) CQg (q) + H{q) at a given temperature the equilibrium amount of CO (g) can be increased by : (A) adding a suitable catalyst. @) adding an inert gas. (C) decreasing the volume of the container, (D) increasing the amount of CO (a) Which of the following statementts) islare) correct : (A) The pH of 1.0 x 107° M solution of HClis 8. (B) The conjugate base of HyPO4” is HPO4”” (C) Autoprotolysis constant of water increases with temperature. (D) When a solution of a weak monoprotic acid is titrated against a strong base, at half-neutralisation point pH = (1/2) pK, ASSERTICN-REASON TYPE QUESTIONS Directions : The questions below (29 to 40) consist of an assertion in column 1 and the reason in column 2. Against the specific question number, write in the appropriate space. (A) If both assertion and reason are correct, and reason is the correct explanation of the «~°-rtion. (B) If both assertion and reason are correct, but reason is not the correct explanation of the assertion. (C) If assertion is correct but reason is incorrect. (D) If assertion is incowect but reason is correct.Example : 29. 30. 31. 32. 33. 34. 35. 36. 37. 38. 39. 40. Assertion F-F bond in Fy molecule is strong, Answer : (D) Benzonitrile is prepared by the reaction of chlorobenzene with potassium cyanide. Fatom has a less negative electron. affinity than Cl atom. Nuclide 79 Al is less stable than 40, 294 Al (OH)g is amphoteric in nature The value of Van der Waals’ constant ‘a’ is larger for ammonia than for nitrogen. Zn?* is diamagnetic. Addition of Brgto 1 -butene gives two optical isomers. The electronic structure of O3 is 3 tS 6 LCI is predominantly a covalent compound. HNOg is a stronger acid than HNO, Sulphate is estimated as BaSOg and not as MgSO g Acetic acid does not undergo haloform reaction Reason F atom is small in size. Cyanide (CN ~)is a strong nucleophile. Additional electrons are repelled more effectively by 3p electrons in Cl atom than by 2p electrons in F atom. Nuclides having odd number of protons and neutrons are generally unstable Al—O and O—H bonds can be broken with equal ease in AKOH)3 Hydrogen bonding is present in ammonia. : The electrons are lost from 4s orbital to form Zn** The product contains one asymmetric carbon. o. “O. — .O" structure is not allowed because octet around O cannot be expanded. Electronegativity difference between Li and Cl is too small. In HNO3 there are two nitrogen-to- ‘oxygen bonds whereas in HNO9 there is only one. Ionic radius of Mg”* is smaller than that of Ba?* Acetic acid has no alpha hydrogens.ANSWERS 1. (B), (C), (D) 2. (A), (B) 3. B) 4(C 5. (A) 6.0 7.14), (C.D) 8.(A,B) 9.) 10. (A), B,C) 11. B), ©) 12.4), ©, 0) 13.6) 14.(A) 15.14), (0) 16.0), 17.8) 18. 19. (A), B), (D) 20. (A), (C) 21. (A), (©, ©) 22. B) 23.(D) 24. (4), (D) 25. (A), (©), (D) 26. (C) 27. (D) 28. (B), (C) 29. (D) 30. (C) 31.0 32.(A) 33. (A) 34. (B) 35. (A) 36. (A) 37.0) 38.(8) 39. (8) 40.10 SOLUTIONS Reason of correctness 1. The reactions are 4NaCl + KyCtp07 + GH2SO4 + 2CrOpCly + 4NaHSO, + 2KHSO4 +3H20 CrOgCly + 4NaOH — NagCrOg + 2NaCl + 2H,0 ‘chromy] chloride yellow solution ve Ans. (B), (C), (D) 2. Na+ (x+y) NHgiy > [Na(NHg)e]* 40" - y(NH I Solvated cation Solvated electrons (Blue colour) Due to formation. of solvated electron it shows blue colour and electrical conductance exhibits due to both ions Ans. (A) & (B) 3. The reaction of CH3—CH= ox Yon with HBr is given as follows, CH; —CH = cu—(_S—on1 + HBr >» CH3—CHp oi S—on Br The mechanism of this reaction is represented as follows. CH3 Gh of Yon ——> CH; —CHg —tn_{_V-on set carbonium (Stable due to resonance) —" 5 CHy—CHy nan Oa Fast step J Br Ans. (B) 4. Anilium hydrochloride gives the white precipitates of AgCl with AgNO3 CgHsNHg*Cl” + agNO3 > CgHsNHg*NOg + AgCl Ans. (C) _ 5. The energy of an electron on Bohr orbits of hydrogen atoms is given by the expression, Constant Ene nWhere n takes only integral values. For the first Bohr orbit, n = 1 and it is given that Ey = -13.6 eV _ 13.6 eV ne of the given values of energy, only -3.4 eV can be obtained by substituting n= 2 in the above expression. Ans. (A) The magnetic moment (u) of a species is related to its number of unpaired electrons (n) in form of following expressions. u= ain (+ 2) BM. (BM. = Bohr Magnetons) ‘The number of unpaired electrons in the given pairs are as follows : Hence Ey, = Fo2* = 16, 2s? 2p%, 35” 36 34% or | 4) FeS+ 2152, 2s? 20%, 38? Sp6 Sp% or | f NO or This given combinations differ in the number of unpaired electrons. Hence these can be differentiated by the measurement on the solid state magnetic moment of nitroprusside ion. Ans. (C) The crystals of CsCl has bedy-centred cubic unit cell. Hence, each ion in this structure has coordination number of eight In case of crystals of NaC! two interpenetrating face-centred cubic lattices are present is these one composed entirely of Na* ions and the other of Cl7 ions. Each Na* ion is located half way between two Cl” ions and viceversa. A unit cell of NaCl crystal has C1” ions at the corners as well as at the face centres and Na* ions are located in octahedral voids. On each edge of cubic unit cell, there are two Cl” ions and one Na* ions. Hence a=2(ry.+ + To-) = 2(95 pm.+ 181 pm) = 552 pm Ans. (A), (C), (D) Sodium nitrate on decomposition upto 500°C to give NaNO and oxygen. a 2NaNO3 —»> 2NaNOg + Op 7 while at higher temperature (i.e. above to 800°C) this NaNOp is decomposed into N20, Np and Op. 800°C: 2NaNOz ——>+ NazO+3/2027+N27T Ans. (A), (B)10. 11. The blue precipitate of Fe®* ions with potassium ferricyanide is due to formation of Turnbull's blue K Fe!’ {Fe""' (CN) g] Fe®* + Ky [Fe(CNg] > K -Fe!! [Fell (Cn) ] + 2K* Potassium Ferro Ferricyanide The red colouration of Fe3* ions with potassium thiocyanate is due t6 the formation of [Fe(CNS]]?* Fe5* + 3KCNS = [Fe(CNS)3] + 3K* Fertic thiocyanate {Red colour) Ans. (B), (C) og Cr = 1s", 25% 2p®, 35” 3p® 345, 4st =[Ar3d5, 4s? For magnetic quantum number (m) negative value be possible. For s-subhell ! = 0, hence m = 0 for p-subshell | = 1 hence m = -1,0,+1 47 Ag= Is®, 25% 2p®, 3s?3p® 3d), as? ap® aa? 554 Hence 23 electrons have aspeciesof one type and 24 of the opposite type Oxidation state of N in HN is -1/3. Ans. (A), (B), (C) In Cannizzaro's reactions 2HCHO + NaOH cong — CHgOH + HCOONa new C—C bond is not formed. In Friedal-Craft reaction CHs So +cHc eA, + HCl new C—C bond is formed In Clemmenson reduction R: 2n—Hg Senora 2 R—CHy +Hy0 H +conc-HCl new C—C bond is not formed. In Reimer Tiemann reactions OH OH CHO + CHCl; + 3NaQH —> + 3NaCl + 2H,0 (Major) New C—C bond is formed. Ans. (B),-(P)12. The structure of Pg is tetrahedral which is given as follows poe: Hence six p _psingle bonds, four lone pairs of electrons and p—_P—P angle of 60° are present. Ans. (A), (C), (D) 13. CCl3CHO reacts with water to give stable chloral monohydrate. H,0 CClgCHO ———+ CCIgCH (OH) ia ~H-O or ClL—C———_C—H CHO chloral monehydrate (stability is due to intramolecular H-bonding) Ans. (B) 14. Ondecreasing the negative value of reducing electrode potential of metals, the reducing character is regularly decrease due to decreasing cation formation tendency. (i.e. electron donating tendency} % Y, Zz +0.55 3.03 -118V Hence correct order Y > Z>X Ans. (A) 15. Carbonyl compound (acetone) forms condensation product with hydrazine, phenyl hydrazine aniline etc. CHy CH > O+ Ha] NCgHs —> > cHy Aniline CHy = NCgHs + HO CHg CH Ye £ O+Hg| N.NHCgHs —> C= N.NHCgHs + HzO CHg CHy Hence in these reaction >C=.N bonds are formed in products Ans. (A),(D)16. 17. 18. CH3—CH = CH—CH3—4 Trans-isomer CH CHs > > c= oS cis-isomer H: H x H CH3 —CH = CHp does not show the property of geometrical isomerism, CHy CeHs, Senet cen H H CH H Sone" tas H CoHs CH —C —CH—CHg does not show the property of geometrical CH3—CH =» CH—C,Hs CHy isomerism. Ans. (A), (©) In BFs, Boron is sp? —hybrid. Ba 1s?, 281 2p} 2p5 sp? —hybridisation These three sp? hybrid orbitals are attached to each other trigonally with an angle of 120° and they are overlapped with three p-orbitals of three F-etoms on their axes. Hence the geometry of BF; molecule is trigonal planar Ans. (B) CH, oe Ans. (C) — In absence of sunlight and Boil} halogen esnier49. Those aldehydes give aldo! condensation which have o-hydrogen atoms 2 NaOH 2CH3—CHO ——+ CH3—CH —CHz —CHO All pt ba Acetaldol 4 NaOH CH3—CH2 CHO + BLOB CH oy a CHa CHC CH Propanaldehyde CH OH CH3 Benzaldehyde (CgHsCHO) does not have a-hydrogen atom, NaOH 2CDsCHO — > CDs —FH-eDacHO oD Ans. (A), (B), (D) 20. Manganese (Mn) imparts hardness to steel as well as removes oxygen and sulphur from steel by forming slag as MaSiO3 Fey03 + 3Mn — 3MnO + 2Fe MnO + SiOz -> MnSiOz . (es) Ans. (A), (C) a1. 2X8 5 y¥A~4 (remission) 8 2X* > 24124 (B-emission} af 2X4 5 2,D4 (positron-emission) 2X™ + ye° > 7 1D (Electron-emission) Ans. (A), (C), (D) OH” CéHgNeCl + CobigOH > n=n(O)-oH readion p-Hydroxyezobenzene Ans. (B) 22. 23. Order of acidic strength (CH3OH > CH = CH > CgH, > CoH Although all are neutral towards the litmus paper. Ans. (D) 24. In first order reaction, ifa is the degree of dissociation therefore 1 k=t loge Wa—log, (1-0) or ket = loge 80 Tay or e* cia a=1-e* Plot of reciprocal concentration of the reactant Vs.time is linear for completion of 75%of reaction is first order, 2 x Tryp time is required for first order reaction dimensions of pre-exponential factor ‘A’ are dimensions of k ie, T7! Ans. (A), (D) 25. Tautomerism is exhibited by (A), (C), (D). ( \-cxcr—on = €\-on-cHo (Enol form) (Keto form) o={_ 0 ‘Tautomerism is not possible Ore =O = (p= ° OH .OH Qe = Qe Qe ° 0 ‘OH Ans. iA), (C), (D) 26. “According to Graham's law of diffusion for two gases undergoing diffusion at different pressures through same hole ta. [Mp , Pa (raps [Ea constant temperature. | te Ma “Pa M “ee Ans. (C) 27. COg +H20gq = Oxy, + Hayy _[COzI THz] [CO] [20] A caialyst simply helps in attaining the equilibrium:earlier. Addition of inert gas has no effect on a reaction because in it An = 0. This equilibrium is not based upon volume because in it An = 0.28. On increasing the amount of CO, Ke will be decreased but it is constant ate constant temperature, so for maintaining the constant value of Kg, the amount of CO increases. Ans. (D) pH of 1 x 10-8 Mis below to 7 HpPO3 + H,0 ——=HPOF + H30* conjugate base of HgPO4q acid HO + HgO = OH" +H,0* K (Auto protolysis constant of water i.e. with ionic product of water.) increases with temperature. isalth lecid] For half neutralisation of a weak acid by a weak base PH:= pK, + log (Salt] = [Acid]. pH = pKaMATHEMATICS - 1998 PART-A Directions : Read questions 1 to 40 carefully and choose from amongst the alternatives given below each question the correct lettered choice(s). A question may have ONE OR MORE correct aliernatives. In order io secure any marks for a given question, ALL correct lettered alternative(s) must be chosen. 1. 3. If is an imaginary cube root of unity, then (1 + @ - 0)’ equals : (A) 128 0 (B) -128.0 (©)128 0? (D) -128 0. . Let T, be the r'? term of an A.P., for r =1,2,3....... If for some positive integers _m, nwe have Ty = Land T, = 4, then Tan equals : n m a. miei mn mon OL (D)0 Ina college of 300 students, every student reads 5 newspapers and every newspaper is read by 60 students. The number of newspapers is : {A) at least 30 (B) at most 20 (C) exactly 25 (D) none of the above . The diagonals of a parallelogram PQRSare along the lines x + 3y = 4 and 6x - 2y = 7. Then PORS must be a: (A) rectangle (square (C) eydlic quadrilateral (D) rhombus. . The number of common tangents to the circles x? +y°=4 and x2 +P — 6x - By = 24 is: (A) 0 B) 1 (3 (0) 4 . Let f (x) = « = [x], for every real number x, where[x]is the integral part of x. Then gy Fld dx is: (@) 1 (B) 2 1 © p) 2 co (D) 3 He P=(x,9-F, =O, =(-3,0) and 16x* +25y’ = 400, then PF, + PF; equals (A) 8 (B) 6 (©) 10 (D) 128. If PG, 2), Q(4, 6, RG, 7) and S(a, 5) are the vertices of a parallelogram PORS, then : (B) a=3,.b=4 (D} a=3,6=5 jek baal e3ps4k and c=f+a)+Bk are linearly dependent vectors and | c! = V3, then : (A) a=1,B=-1 B a=1p=41 (OQ a=-1p=21 D) a=t1p=1 10. If from each of the three boxes containing 3 white and 1 black, 2 white and 2 black, 1 white and 3 black balls, one ball is drawn at random, then the probability that 2 white and 1 black ball will be drawn is : 7 13 1 (A) 35 By 1 3 35 ) i6 13, 11. The value of the sum EG" +i°* }), where i = ¥=T, equals : ne (A) i (By i-1 . (© -i m0 12, The number of values of x where the function f(x) = cos x + cos (V2x) attains its maximum js : (A) 0 (Bl (2 {D) infinite 13. f 69 = ech for every real number x, then the minimum value of f : (A) does not exist because f is unbounded. (B} is not attained everi though f is bounded (C) is equal to 1 (D) is equal to -1 14. Number of divisors of the form 4n + 2(n 2 0) of the integer 240 is : (A) 4 (©) 10 () 3 15. yl cos2e tim xol x1 (A) exists and it equals J2. (B) exists and it equals — V2 (C) does not exist because x - 1 0 {D) does not exist because left hand limit is not equal to right hand limit16. 17. 18. 19, 20. 21. aa 23. 24, If ina triangle PQR, sin P, sin Q, sin Rare in A. P., then : (A) the altitudes are in A. P. (B) the altitudes are in H. P. {C) the medians are in G. P. (D) the medians are in A. P. a n fay = 2, oa then 2 Te, aul : (A) (n-Day (B) nen (© nan (D} None of the above If the vertices P, Q, R of a triangle POR are rational points, which of the following points of the triangle POR is/(are) always rational point(s) (A) centroid (B) incentre (©) circumcentre (D) orthocentre (A rational point is a point both of whose co-ordinates are rational numbers) The number of values of ¢ such that the straight line y = 4x + ¢ touches the curve SP alis: a) @1 (2 (D) infinite. 1 1 1 If 1 a: 1 inG. P., then ———» ———— ———__ soe "Tt yx is ny ive” (A) A.P. (B) HP. (Cc) GP. (D) None of the above The number of values of x in the interval [0, 51] satisfying the equation 3 sin’ x -7 sinx +2=Ois: (a) 0 {B) 5 (6 {D) 10 The order of the differential equation whose general solution is given by y= (Cy + Cy) cos (x +C3)-— Cae"! where Cy, C2, C3, C4, Cg are arbitrary constants, is : (ay 5 @4 (3 D) 2 If g (f (x)) = [sin x| and f (g (x)) = (sin-Vx?, then : 1A) f(x) = sin® x, g (x) = ve B) f(x) =sin x, g x) = |x} (Q) f(x) =x*, g 0) = sinvx (D) f and g cannot be determined Let Ag Ay Ap Ag Aq As be a regular hexagon inscribed in a circle of unit radius. Then the product of the lengths of the line segments Ay Ay, AoAz and Ag Aq is = a) 2 (B) 3 (3 (oy) 28 2+> 25. For three vectors u, 0, w which of the following expressions is not equal to any of the remaining three ? a3 5 + (A) u-(v x w) (B) {vy xujou a3 > 3 (C) v-(u xu) ID) (u x v)-w 26. There are four machines and it is known that exactly two of them are faulty. They are tested, one by one, in a random order till both the faulty machines are identified. Then the probability that only two tests are needed is 1 1 (A) 3 Be i 1 © 2 (D) a 27. Let h(x) = min fx, x2}, for every real number of x, Then : (A) his continuous for all x (B) his differentiable for all x (C) @)=1, forallx>1 (D) his not differentiable at two values of x 28. If f (x) = 8x —5, then f4(): lear 1 (A) is given by 5 x45 3 {C) does not exist because f is not one-one (D) does not exist because f is not onto 29. If E and F are the complementary events of events E and F respectively and if0 < P(6 <1, then. B) is given by (A) P(E/F) + PE/F}=1 (B) PIE/F)+PE/P)=1 (Q PIE/A+PE/F)=1 — (D) PE/F) + PUE/F)=1 6i 3: 1 30. If| 4 3i -1| =x + iy, then 20 3 i (A) x =3,y=1 B) x=Ly=3 () x=0,y=3 D) x=0,y=0 31. A fair coin is tossed repeatedly. If tail appears on first four tosses, then the probability of head appearing on fifth toss equals = 1 1 lay L — A> ®) 35 31 1 oO 32 Do 532. 33. 34, 35. 36. 37. 38. 39. An n- digit number is a positive number with exactly ndigits. Nine hundred distinct n-digit numbers are to be formed using only the three digits 2, 5 and 7. The smallest value of n for which this is possible is : (A) 6 B7 (8 (D) 9 Seven white balls and three black balls are randomly placed in a row. The probability that no two black balls are placed adjacently equals : 1 7 (A) 3 ®) ra 2 1 (Cc) 5 () 3 a Letn be an odd integer. fsin nO = by sin’ 0, for every value of, then: {A) by =1,b, =3 B) bp =0,b)=n (CQ) by =-1,by =n (D) bp =0, by =? -3n+3 Which of the following number(s) is/are rational ? (A) sin 15° {B) cos 15° (C) sin 15° cos 15° {D) sin 15° cos 75° . If the circle x? + 42 = a? intersects the hyperbola xy = ¢” in four points P (xq, 94), Q lx2, v2), R (xg, v3), S( xq, vq), then + (A) xy xp + x3 + xq =0 B) y+ + ¥3+y4=0 (©) x1 x0 xg xq = 04 (D) yy v2 va va = c* If E and F are events with P (E) < P (F) and P (EMF) > 0, then : (A) occurrence of E = occurrence of F (B) ocewrence of F = occurrence of E (C) norroceurrence of E => non-occurrence of F (D) none of the above implications holds Which of the following expressions are meaningful question Se +3 (A) u-{v x w) B) (u-v)-w +3 a 3 > {C) (uv) w (D) u x(v -w) HE 00 dt =x [2+ £0 dt, then the value of f (is: 1 (A) a (B) 0 ; 1 Oo -5AO. Let h(x) = f(x) -(/ GF + (F (9) for every real number x. Lhen = (A) his increasing whenever f is increasing (B) his increasing whenever f is decreasing (C) his decreasing whenever f is decreasing {D) nothing can be said in general ANSWERS 1.0) 2.(C) 3.(C) 4. (D) 5.(B) 6. (A) 10 8.10 9.0) 10. (A) 11.8) 12. (A) 13.0) 14.) 15. 0) 16 (B) 17.0) 18. (A) 19.() 20.(B) 21.10) 22. (C) 23. (A) 24.(C) 25.(C) 26. (8) 27.(A), (C.D) 28.8) 29.4), (D) 30.) 31.(A) 32.8) 33. B) 34. (B) 35. (C) 36. (A), (8.0.00) 37.0) 38. (A), (C) 39. 1A) 40. (A), (C) SOLUTIONS 1. (leo - 0) =a? - 07)! =(-202)? ={- 27 02)? =~ 128-0"4 = -12807 , Therefore, (D) is the Ans. a n and Ty zat(n-Ddet m = tmend=}-2m=2 oe aed nom mn mn Again Twn =a+(mn- Id +(mn—nen-d - 2at(n-Dd+imn-nd =T, +ntm—1)-. mn 1yy-le1 ™ Therefore, (C)is the Ans. 3. Let number of newspaper which are read be n. Then 60n = 300 x 5 > n=25 Therefore, (C) is the Ans. 4. Slope of x+8y=4is-13 and slope of 6x = 2y =7is 3.therefore, these two lines are perpendicular which show that beth diagonals are perpendicular. Hence PQRS must be a rhombus. x? + % = 4 (given) centre =cy =(0,0) and Ry =2. Again x? +? — 6x ~ 8y~ 24 = 0 then ep #3, 4 and Rp =7. Again cy eg =5 = Ry - Ry Therefore, the given circles touch in temally such that they can have just one common tangents at the point of contact. Therefore, (B) is the Ans. fi, fide fl be-bide= [! xde— J") daw -0- [i blade [vx is an odd function] fi if -1 20.1 25 16 Here a? =25, b? =16 But bP =@d- A) 16 =25(1- 114 > ¢ , > 25 e =e &a1-6_ 9 25 25 > e=3/5 Now foci of the ellipse are + ae, 0=+3,0 we have 3 = ae > a= Now PF, + PF = focal distance = 2a =2 «5-10 Therefore, (C) is the Ans. PQRSis a parallelogram if and only if the mid-point of PR is same as that if the mid-point of QS. That is, if and only if145_ 44an a 217 bab 2 2 2 = a=2 and b=3 Therefore, (C) is the ‘ane » 9. It is given that a, b, ¢ are linearly dependent =[e.b.cl-0 10. 11. 12, 1 1 1 = 4 3 4 1 a B 1 0 0 => {4 -1 0 | = O Apply Cz + Cz ~ Cy, C3 > Cz - Cr 1 oa-1) B-1 Now expanding along Ry, = -G-)=0> fel Alsot ¢ |= V3 (given) — where ¢ = 7 + aj + BE (given) = 1+ spi= => L+e241=3 3 of =1 = a=sl Therefore, (D) is the correct Ans. P (2 white and 1 black) = P (W; Wb By or Wy Bp Wy or By We Wy) = EO We Ba) oe ee ee /3) = P (WA) P (Wb) P{Ba) + P (Wi) P(By) P(WS) + P(B,) ) (HB) (Wy) “ga4'44 4°44 4 =f0-3+0-8 Therefore, (A) is the Ans 13 13, 13 ae +t he aes =(+9 ay ” re ee ee are [et a} =(1+i)f=-1+i, Therefore, (B} is the Ans.0 The maximum value of f (x) =cos x + cos'\v: /2x) is 2 which occurs at x = 0. Also, there is no value of x for which this value will be attained again. Imp. note : This question can be solved by calculus also. (8) will be minimum when 2a is maximum, i.e., when x” + Lis minimum + Le. atx =0. . Minimum value of f (x) is f Q) = - Therefore, (D) is the Ans.145_ 44an a 217 bab 2 2 2 = a=2 and b=3 Therefore, (C) is the ‘ane » 9. It is given that a, b, ¢ are linearly dependent =[e.b.cl-0 10. 11. 12, 1 1 1 = 4 3 4 1 a B 1 0 0 => {4 -1 0 | = O Apply Cz + Cz ~ Cy, C3 > Cz - Cr 1 oa-1) B-1 Now expanding along Ry, = -G-)=0> fel Alsot ¢ |= V3 (given) — where ¢ = 7 + aj + BE (given) = 1+ spi= => L+e241=3 3 of =1 = a=sl Therefore, (D) is the correct Ans. P (2 white and 1 black) = P (W; Wb By or Wy Bp Wy or By We Wy) = EO We Ba) oe ee ee /3) = P (WA) P (Wb) P{Ba) + P (Wi) P(By) P(WS) + P(B,) ) (HB) (Wy) “ga4'44 4°44 4 =f0-3+0-8 Therefore, (A) is the Ans 13 13, 13 ae +t he aes =(+9 ay ” re ee ee are [et a} =(1+i)f=-1+i, Therefore, (B} is the Ans.0 The maximum value of f (x) =cos x + cos'\v: /2x) is 2 which occurs at x = 0. Also, there is no value of x for which this value will be attained again. Imp. note : This question can be solved by calculus also. (8) will be minimum when 2a is maximum, i.e., when x” + Lis minimum + Le. atx =0. . Minimum value of f (x) is f Q) = - Therefore, (D) is the Ans.19. 20. 21. 22. For ellipse condition of tangeney is ? = am? + b? = &=4x4+1=17 > ¢ =+ 717 therefore, (C) is the Ans. Let the common ratio of the GP, ber. Then yexr and z=xr’ = Inysinx+Inr anding=Inx+2Inr Putting A =1+Inx,D=Inr 1 1 1 1 Then et = 1 T+inx A’l+Iny l+inxr l+iInx+inr A+D 1 et lelinz 1l+inx+2Inr A+2D 1 1 1 + —i 1 _t HP. ivinx’Ivinyg' Tene So (B) is the Ans. 3sin?x -7sinx +2=0 (given) > 3sin® x - 6 sinx -sinx+2=0 => 3sinx(sinx - 2 -1(sinx -Q=0 > (3 sin x ~ ) (sinx -9=0 > > and Therefore, sin x = 1/3 orsin x = 2 (sin x = 2 is rejected), 4 " sin” 3 nef x=nn +(-1! ForOsns5, x €[0,57] :. There are six values of x €[0, 5 =] which satisfy the equation 3 sin® x -7sinx +2= Therefore, (Cis the Ans y = (cy + ¢g) cos (x + eg) - cg e* * {given} (1) => yale +2) cos (x + eg) — cq eX +e Now lete; +c =A, cg =B, cg e% =C = y =Acos (x + B) ~ Ce wd) differentiate war-t. x > SY 2 - A sin (x + B) Ce* 13) dx differentiate again wart. x = pes Acos (x +B) ~ Ce (4) > Sy a-y-2ce8" from (2) (6) &y = +y=-2Ce% ee 9m 2 Cee, differentiate again wrt. x Hy WL sce ade de23. 24. 25. 26. fy, dy _ by a f de" oe at oe) which is a differential equation of order 3. Therefore, (C) is the Ans. Let f (x) = sin? x and g (x) = vx Now fog (x)= f(g (xl) = f (x) = sin? Vx and gof (x) = 9 (f (x) = g (sin® x) = sin? x =Isin x again, f (x) = sin x, g(x) =I x! fog (x) = fig Gl = f (1x I) = sin x1 «(sin vx)? When f(x) = x®, g(x} = sin vk fog (x) = f lg (ll = f (sir. vx) = (sin Vx? and (gof) (x) = gf Odl= g(x?) = sin LE = sin Ix | #1 sin x! Therefore, (A) is the Ans aga? =(1-2) +(0~ = ApAy=1 Next, Ag? = a -1? +(o- -2R_s 4 = Apr =¥3 Next ApAg = (a + uy + (0 + 8) = ApAy = v3 Thus, (AgAy) (ApAg) (AgAq) = 3. [ep g)-=lonal=(n ag ‘Therefore, (C) is the Ans. The probability that only two tests are needed = probability that the first machine tested is faulty x (probability that the second machine tested is faulty given that the first machine tested is faulty = : x $ = zt ‘Therefore, (B) is the Ans.27. 28. 29. h(x) = min Lx, x} (given) We will trace h (x) = x and h (x) = x* separately From fig it is clear that {x if x <0 hij=4x?, if Osxsl x if wel From the graph it is clear that h is continuous for all x € R and h' (x) = 1 for all) x > Land his not differentiable at x = O and x = 1. Therefore, (A), (C) and (D) are the answers. f(x)=3x-5 (given) Let ps f(x)=3x-5 = y+5=3e => a2’ a and y= f(x) = x= fy) (2) From {1} and (2} . ye -iyy Xt 2 oplyye—e => fi w= 3 Therefore, (B) is the Ans. : : 2p PIEOA , PEND AL P P(E/FR)= + B/D PED Bi De _ PENN +P(ENA . PA = PAP 1 therefore, Ais the Ans. P(F) B. P(IE/A+PE/F) =P EDA, PENA PF P(F) PIENF) PEMA a “P(R 1-P Therefore, (B) is not the Ans. c. PE/R+Pe/F =P EDS, Pean PENF Penni: © “PF * 1 PF; Therefore, (C) is not the Ans. Lk D. PIE/F)+PE/R-2 EOP PENA OPED Bt Pe _PIENA+PENA PA = 1, Therefore, (D) is true. P(A) PH So (A), (D) are the Ans.30. 31. 32. 33. 34. 6i — 3 1} |: 3 -ll=x+iy (given) (20 8 i | 6 1 | => -3)/4 -1 -1)=0 [ Co and C3 are proportional] | 20 i i] => xtiy=0 > x=0,y=0. Therefore, (D) is the Ans. The event that the fifth toss results in a head is independent of the event that the first four tosses result in tails. <. Probability of the required event = 1/2 Therefore, (A) is the Ans. Distinct n digit numbers which can be formed using digits 2, 5 and 7 are 3". We have to find n so that 37 > 900 =3"~* 2100 > n-225 => — n27so the least value of nis 7. Therefore, (B) is the Ans. The no. of ways of placing 3 black balls without any restriction is10 C3. Since we have total 10 places of putting 10 balls in a row and firstly we will put 3 black balls. Now the no. of ways in which no two black balls put together is equal to the no. of ways of choosing 3 palaces marked—out of eight places, —W—W-—W-Ww—-Ww—Ww—Ww— This can be done in 8c3 ways. Thus, probability of the required event 8 _ 8c _ 8x7x6 7 , We tipsos8 8 Therefore, (B) is the Ans. Now put@=0,we get 0=bp sinn8= L_ b, sin” Ois tue L = b, Gina’? rel sin n0 S - sin taking limit as @ > 0 = im 228 _ jim xb, (sing? 6+0 sind 830 ral no 539.70 = lim — 8-6) +0+0+0. oop ane 6 Other values becomes zero for higher powers of sin 8. > "oh > by = n. Therefore, (B) is the Ans.36. 37. 38. sin 15° = ; 2-8 (formula) and cos 15° = 3 2B (formula) and sin 15° cos 75° = sin 15°. sin 15° = 3 (2 8) Therefore, all these values are irrational and sin 15° cos 15° = 2.2 sin 15° cos 15° =}. sin 30° = ; which is rational therefore, (C) is the Ans. Itisgiven that x? +7 = AL) and xy=e? (2) We obtain x? + ¢4/x2 =o? > xt dx? 4c =0 --(3) Now x1, x2, x3) x4 will be roots of (3) Therefore Exp =x +xp +x5 + x4q=0 and product of the roots x1 xp x3 xq =c4 . Similarly, yy + y2 + 93 + ¥q =Oand yy yo v3 Yq Therefore, (a), (b), (c) and (d) are the answers It is given that P (E) < P (F) = EcF (1) and P(ENF>0 => EF (2) (A) occurrence of E => occurrence of F from (2) (B) occurrence of F = occurrence of E from (2) (C) non-occurrence of E = non-occurrence of F from (1) Therefore, (D) is the Ans. + 3 A. u -(u x w) is a meaningful operation, therefore, (A) is the Ans. > 3 3 B. u -(v - w) is not meaningful since u . w is a scalar quantity and for dot product both quantities should be vector. Therefore, (B) is not the Ans. oo C.(u - v) wis meaningful since it is a simple multiplication of vector and scalar quantity. Therefore, (C) is not the Ans. > o> ++ D. u x(v - w) is not meaningful since v . w is a scalar quantity and for cross product, both.quantity should be vector. Therefore, (D) is the Ans Hence (A)? Sand (C) are the Ans.39, 40. fi@deaxsfesoar, (given) Differentiating both sides w.r.t. x, we get FPLa1 =x f(x)-1 > +x fi) =1 > f= +x) > Mars ‘Therefore, (A) is the Ans. Let h (x) = f (x) - (F (xl)® + (F Go) Differentiate the whole equation w.r.t. x Wx) = f(x) ~ 2flx)- fx) 4 3 Pld - fbx) = FO) 1-2 foo +309] = 3709 [pea -2 9 + 5] 7 ait =3f(0) [(w» -4) 3] rs 1 3-1 = 5719 (19 - 3) +35 oa, “1Y¥ 2 = 3f0) (1 -4)- 3| Note that h(x) < Oif f(x) < Oand hs) > O if fle) >0 Therefore, h(x) is increasing function if f (x) is increasing function, and h{x) is decreasing function if f (x) is decreasing function, Therefore, (A) and (C) are the Ans.