Arendt 2005 Materials and Corrosion

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Materials and Corrosion 2005, 56, No.

4 Impressed current cathodic protection 271

Impressed current cathodic protection


Development of optimum system configurations for ships using scale models
(physical scale modelling)
H. Fr. Arendt*

The purpose of this fundamental study was to establish optimum be applied to the models. The model studies were conducted in a
cathodic corrosion protection system configurations for ship hulls. systematic manner and under defined conditions in German stan-
Comprehensive surveys were conducted in order to develop a better dard (DIN) artificial seawater and in a natural electrolyte.
understanding of the electrochemical processes occurring on a ship The experiments clearly showed the functional correlation be-
hull in a seawater electrolyte. The results obtained show that the tween the geometric configuration of the reference electrodes on
performance of a system can only be evaluated when it is installed the hull and the locations of the anodes. The results reflect the in-
on a real object. However, once installed the location of the im- terrelationships between the electrochemically more positive
pressed current anodes and the reference electrodes cannot be chan- bronze propeller and the steel. The configuration developed in
ged if the potential distribution over the underwater hull is not op- the course of the experiments provided an optimum distribution
timal. Hence, a procedure had to be established that permits the of the protection current over the entire hull model.
development and optimisation of system configurations for future The data from the model study were applied to the design fea-
objects. tures of the Class 123 Frigate. Subsequently, the efficiency of this
A validated, experimental laboratory technique using scale ship procedure was evaluated on a real object in a real electrolyte.
models was established to determine the fundamentals of cathodic The results obtained clearly demonstrate that physical scale mod-
corrosion protection and to develop a theoretical understanding of elling is a rational, scientific method for the evaluation and design
the underlying mechanisms. The findings obtained in practice could of impressed current cathodic protection systems.

1 Introduction – the coated steel surface


– rudders, stabilisers, A-brackets
When planning and designing a ship, the materials must be – uncoated propeller surfaces
adapted to the environmental conditions in such a way that the These components have different free corrosion potentials
authorized life is achieved without requiring corrective repair and thus different polarisation requirements. As these compo-
after construction. nents constitute electrically coupled metals, mixed potentials
If a sufficient life cannot be ensured by using economically develop if the structure is not cathodically protected.
acceptable materials additional corrosion protection means The processes occurring on the underwater hull, especially
must be applied. in the stern section, inevitably lead to corrosion damage.
For various reasons, Impressed Current Cathodic Protection Therefore, a comprehensive understanding of the factors
(ICCP) systems offer the most promising method for effi- immediately affecting the potential profiles along the under-
ciently controlling corrosion on hulls, marine steel construc- water hull is required. ICCP is aimed at a uniform potential
tions and steel surfaces wetted with seawater. Cost analyses profile over the entire hull under all operational conditions. In
for ships revealed that, based on a operating period of 25 practice, however, such a uniform profile is very difficult to
years, impressed current systems are more economical than achieve.
galvanic anodes.
Compared to static structures, the protection of ships re-
quires careful consideration of the specific conditions. For
the design of an impressed current system, characteristics 2 Potential controlled impressed current systems
such as the hull shape, the different materials, the changing
operational conditions and the speed of the ship must be in- With this active corrosion control method, the potential of
cluded in the technical specifications. the material is changed by using a DC power source in such a
The entire underwater hull constitutes a large complex body way as to bring on a cathodic reaction in the material to be
comprising at least the following three components: protected (reduction area). To this end, the metal must be pro-
vided with electrons, i.e. must be connected to the negative
terminal of the power source. The positive terminal is used
for the anodic reaction (oxidation) in the electrolyte. The cur-
rent can be supplied via inert platinised titanium anodes and is
controlled with respect to the potential. For this control pro-
* H. Fr. Arendt,
Bundeswehr Technical Centre for Ships and Naval Weapons, cess, a potential value provided by a reference electrode is
Berliner Str. 115, D-24340 Eckernförde (Germany) used for controlling the current supplied in order to achieve
jetzt: a specified nominal value.
Villenweg 7, 24119 Kronshagen (Germany), The potential profile along the underwater hull is deter-
e-mail: h-f.arendt@webmaster7.de mined by the specific configuration of the system, i.e. by

F 2005 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim DOI: 10.1002/maco.200403834
272 Arendt Materials and Corrosion 2005, 56, No. 4

Fig. 1. Mixed potentials in the stern section with the impressed current system switched off

Fig. 2. Free corrosion potential of the coated steel hull and lowered potential in the desired range of cathodic protection

the number of anodes and their respective locations as well as 3 Surveys of real objects
by the locations of the reference electrodes in relation to the
hull, to the propeller and to each other. In addition, the dis- Comprehensive surveys were carried out on ship hulls to
tances between the reference electrodes and the impressed gain a better understanding of the electrochemical processes
current anodes are to be defined. involved in the cathodic protection provided by galvanic an-
Ship steel can be considered sufficiently protected against odes and impressed currents. Divers were employed to mea-
corrosion if its potential has been lowered by approximately sure potentials on the hulls, the appendages, the shafts and
200 mV below its free corrosion potential. propellers of various ship classes. The values measured pro-
vided very differentiated information about the factors di-
rectly affecting the distribution of the protective current.
While the surveys of ships equipped with galvanic anodes fo-
cussed on the verification of the protection potential, the tests
conducted on the ships equipped with impressed current sys-
Materials and Corrosion 2005, 56, No. 4 Impressed current cathodic protection 273

3.1 Practical trials on ships with impressed current


systems

3.1.1 Fast patrol boats

These boats are made of ship steel. Their propulsion system


consists of four shafts with four aluminium multicompound
bronze propellers, eight spring steel A-brackets made of
high-alloy steel and two rudder blades. It was difficult to gen-
erate a sufficient protection potential in the stern section as the
respective materials possess very different free corrosion po-
tentials and constitute electrically coupled metals (Fig. 3).

3.1.2 Frigates

Part of the information from the surveys conducted on the


fast patrol boats were taken into account in the construction of
the Class 122 Frigates. The anodes and reference electrodes
were configured on the basis of relevant standards and in co-
operation with the Netherlands Navy. At that point in time, the
state of the art suggested that approximately six anodes should
be evenly and symmetrically distributed over the underwater
hull to optimise the potential profile (Fig. 4).
Opinions differed as to the location and number of refer-
ence electrodes. They were finally installed in the midship
section.
Measurements conducted on the underwater hull of this
ship class revealed a very non-uniform potential profile. In
the stern section, the specified lowering of the potential by
Fig. 3. Potential distribution in the stern section of a four propeller U ¼ 200 mV was not achieved. Here, the protection potential
system (measured across the hull) could be corrected slightly by making modifications in the an-
ode circuit and a greater lowering of the potential by
U ¼ 260 mV.
It turned out that, under the conditions of the multi-propel-
tems were far more comprehensive and included measure- ler system, most of the protective current impressed via the
ment engineering surveys conducted over a longer period anodes flows off to the uncoated surfaces of the propellers
of time. In this way, extensive information about the potential which are nobler with respect to their free corrosion potential.
profiles along multipropeller ships could be obtained for the
first time.
3.2 Lessons learned from the practical trials

The results confirm that it is impossible to evaluate the per-


formance of a system before it has been installed and tested
under practical conditions.

Fig. 4. Symmetric distribu-


tion of anodes and reference
electrodes over the hull
274 Arendt Materials and Corrosion 2005, 56, No. 4

Fig. 5. Insufficient cathodic protec-


tion in the stern section

Systems permanently installed onboard a ship provide only A validated experimental laboratory technique employing
little scope for experimental surveys. Sea trials are time con- scale ship models was established to develop the fundamen-
suming and often very difficult to conduct. tals and a better understanding of the mechanisms of cathodic
It is not possible to correct the location of the anodes and the corrosion protection.
reference electrodes once the system is installed onboard the Studies were conducted to evaluate the performance of ex-
frigates. isting and newly developed configurations and focussed on
the number and locations of the anodes and reference electro-
des [1, 2].
4 Optimising system configurations by means of
physical scale modelling
4.1 Experimental laboratory technique
Therefore it was necessary to find a method for developing
or optimising system configurations. Neither catalogued nor 4.1.1 Models
computer-aided methods were available for a theoretical de-
termination of the best technical solution. Models of the hull are generally built to a scale of 1:19
(Fig. 6). Consequently, the frigate models are about 6.5 m
long. As a prerequisite for the fundamental model studies,
the model must be made of materials whose polarisation char-
acteristics are identical to those of the original objects. Silver/
silver chloride monitoring electrodes are used to measure the
potentials on the hull shell. The shell is punctured at some 50
representative test points to accommodate the monitoring

Fig. 7. Locating holes for the silver/silver chloride electrodes


Fig. 6. Hull model, front view (stern section)
Materials and Corrosion 2005, 56, No. 4 Impressed current cathodic protection 275

dard (DIN) artificial seawater and natural seawater from the


Baltic Sea (Kieler Förde) are used for the static tests con-
ducted in the tank. During the individual test series the elec-
trolyte is slightly circulated. This circulation causes the elec-
trolyte to flow slowly past the shell of the hull whereby a con-
stant ion exchange on the coated steel surface is achieved.
During the tests, this procedure ensures a comparatively quick
polarisation of the potentials and thus stable potential values.

4.1.4 Control units

Special “electrical corrosion protection systems” have been


developed to control the currents impressed on the models.
These systems are potential controlled units that permit the
implementation of all conceivable circuit configurations in-
cluding multichannel systems. As with the real objects, the
lowering of the potential is effected by means of zinc refer-
Fig. 8. Test laboratory with the model hull and the electrolyte tank ence electrodes. The anodes consist of platinised titanium
wire embedded in scale plastic casings. The anode shields
are true to scale and comply with the specifications of the re-
electrodes. The silver/silver chloride glass electrodes are in- levant standards.
serted into these boreholes along with purpose-made water-
tight seal liners (Fig. 7). Thus, this measuring system can
be used to constantly record and monitor the potential distri- 4.2 Theoretical considerations and laboratory tests
bution over the entire underwater hull of the model.
The studies described in this paper employed scale models
of the Cl. 122 and Cl. 124 Frigate. The different test config-
4.1.2 Test tank urations were established on these models in a systematic
manner.
The test tank is about 10 m long and approximately 2 m The theoretical considerations of the relationship between
wide (Fig. 8). When filled, the tank is regularly checked the model and the electrolyte did not require the scale of the
for freedom from potentials. model to be applied to the conductivity of the electrolyte, i.e.
the conductivity of the electrolyte was not reduced by the
same factor as that employed for the models.
4.1.3 Electrolyte Artificial seawater as specified in DIN 50907 was used for
the tests to be conducted within the scope of these basic sur-
As a matter of principle, the characteristics of the electro- veys.
lyte in the tank that affect corrosion are kept constant. Thus, Normally, the results of model tests are applied to real ob-
the functional relationship between the electrochemical data jects. With these studies, however, the results obtained in prac-
and the main influencing parameters is defined. German stan- tice were first applied to the model.

Fig. 9. Model test configuration: Loca-


tion of system different from real ship –
anodes and reference electrodes closer
to the stern
276 Arendt Materials and Corrosion 2005, 56, No. 4

tial distribution determined on the model actually correlated


with the potential profile of the Cl. 122 Frigate. Thus the basis
for the fundamental studies was established. It was possible to
create potential fields on a physical model that are identical to
those on real objects in real electrolytes.

4.3 Results of the model tests

One main purpose of the tests was to determine the loca-


tions and numbers of anodes and reference electrodes re-
quired. A large number of test configurations was set up on
the model (Fig. 9). The test layout as well as the special mea-
suring system permitted the constant plotting of all potential
characteristics over the entire wetted surface of the shell. The
tests clearly showed the functional relationship between the
geometric configuration of the reference electrodes on the
Fig. 10. Reduction from six to four anodes Electrodes moved to- hull and the location of the anodes. The location of the refer-
wards the stern
ence electrodes determined the strength and efficiency of the
protection profile [2].
The location of the anodes and their active surfaces affect
the potential profile over the entire surface of the underwater
hull. The results reflect the interrelationships between the
electrochemically more positive surfaces of the bronze pro-
pellers and the steel. One factor that had a decisive effect
on the experimentally determined configurations was the re-
location of the reference electrodes towards the stern section.
In this way, the increased protection current required in this
area could be provided. It is evident that potential profiles and
current outputs are determined by the location of the anodes
and reference electrodes relative to the propellers and the ex-
posed steel surfaces. Non-ferrous propellers dominate the
cathodic processes in the stern section [1, 2].
Further more, a reduction of the number of anodes could be
achieved.
Six anodes were required for the system configuration on
the real ship while the number of anodes required for the mod-
Fig. 11. Changes to active anodic surface area el could be reduced to four (Fig. 10). The geometric config-
uration of the anodes was also modified.
Another step taken to optimise the protective current dis-
During the first test, the configuration of the system in- tribution in the stern section was to modify the size of the ac-
stalled onboard the Cl. 122 Frigate was modelled. The objec- tive anodic surface areas (Fig. 11).
tive of this test was to find out if the potential profile on the
model matched the one measured on the real ship. The poten-

Fig. 12. Results from


the model studies ap-
plied to the design char-
acteristics of a real
frigate
Materials and Corrosion 2005, 56, No. 4 Impressed current cathodic protection 277

Fig. 13. Optimised system configuration on the real ship

The performance characteristics established demonstrate an 6 Conclusions


optimum distribution of the protective current over the entire
underwater body of the hull model. The laboratory and the scale models provide a validated ex-
Upon completion of the these fundamental studies, the perimental technique that produces unique and reproducible
question arose as to what extent the relationships established results for the design of impressed current corrosion protec-
on the model can be applied to a real ship. tion systems at an early stage of the design process.
The data obtained are indispensable for the development
and optimisation of specialised naval systems. These data
5 Application of the relationships established on the are not commercially available.
model to a real frigate The system configurations experimentally developed for
the frigates are significantly more efficient and economical
First, the results from the model studies could be validated than existing systems.
against data from the Class 123 Frigate. It is evident from the results that scale models represent a
The data established on the model were applied to the de- rational scientific approach to the evaluation and design of
sign characteristics of this ship class (Fig. 12). impressed current corrosion protection systems.
After the data had been applied, the efficiency of this meth- The development of a theoretical understanding of the me-
od was evaluated on a real object in a real electrolyte (North chanisms of impressed current cathodic protection formed an
Sea water). The potentials on the underwater hull of the Fri- essential part of theses fundamental studies.
gate “Brandenburg” were measured at about 100 test points.
The tests also included measurements with the impressed cur-
rent system switched off to determine the free corrosion po- 7 References
tential of the coated surface (Fig. 13). The measurements re-
quired to determine the protection potential were conducted [1] D. Tighe-Ford, J. McGrath, CORROSION ’91, NACE Interna-
after an appropriate polarisation period. tional 1991, paper no. 308.
The protection potential was ideal, i.e. it showed a uniform [2] P. Khambhaita, D. Tighe-Ford, CORROSION ’95, NACE Inter-
potential distribution. The uniformity of the protection poten- national 1995, paper no. 308.
tial over the entire hull exceeded the results of the model stu-
dies. (Received: August 20, 2004) W 3834
Thus, the suitability of this experimental modelling tech-
nique (physical scale modelling) has been demonstrated.

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