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Arendt 2005 Materials and Corrosion
Arendt 2005 Materials and Corrosion
Arendt 2005 Materials and Corrosion
The purpose of this fundamental study was to establish optimum be applied to the models. The model studies were conducted in a
cathodic corrosion protection system configurations for ship hulls. systematic manner and under defined conditions in German stan-
Comprehensive surveys were conducted in order to develop a better dard (DIN) artificial seawater and in a natural electrolyte.
understanding of the electrochemical processes occurring on a ship The experiments clearly showed the functional correlation be-
hull in a seawater electrolyte. The results obtained show that the tween the geometric configuration of the reference electrodes on
performance of a system can only be evaluated when it is installed the hull and the locations of the anodes. The results reflect the in-
on a real object. However, once installed the location of the im- terrelationships between the electrochemically more positive
pressed current anodes and the reference electrodes cannot be chan- bronze propeller and the steel. The configuration developed in
ged if the potential distribution over the underwater hull is not op- the course of the experiments provided an optimum distribution
timal. Hence, a procedure had to be established that permits the of the protection current over the entire hull model.
development and optimisation of system configurations for future The data from the model study were applied to the design fea-
objects. tures of the Class 123 Frigate. Subsequently, the efficiency of this
A validated, experimental laboratory technique using scale ship procedure was evaluated on a real object in a real electrolyte.
models was established to determine the fundamentals of cathodic The results obtained clearly demonstrate that physical scale mod-
corrosion protection and to develop a theoretical understanding of elling is a rational, scientific method for the evaluation and design
the underlying mechanisms. The findings obtained in practice could of impressed current cathodic protection systems.
F 2005 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim DOI: 10.1002/maco.200403834
272 Arendt Materials and Corrosion 2005, 56, No. 4
Fig. 1. Mixed potentials in the stern section with the impressed current system switched off
Fig. 2. Free corrosion potential of the coated steel hull and lowered potential in the desired range of cathodic protection
the number of anodes and their respective locations as well as 3 Surveys of real objects
by the locations of the reference electrodes in relation to the
hull, to the propeller and to each other. In addition, the dis- Comprehensive surveys were carried out on ship hulls to
tances between the reference electrodes and the impressed gain a better understanding of the electrochemical processes
current anodes are to be defined. involved in the cathodic protection provided by galvanic an-
Ship steel can be considered sufficiently protected against odes and impressed currents. Divers were employed to mea-
corrosion if its potential has been lowered by approximately sure potentials on the hulls, the appendages, the shafts and
200 mV below its free corrosion potential. propellers of various ship classes. The values measured pro-
vided very differentiated information about the factors di-
rectly affecting the distribution of the protective current.
While the surveys of ships equipped with galvanic anodes fo-
cussed on the verification of the protection potential, the tests
conducted on the ships equipped with impressed current sys-
Materials and Corrosion 2005, 56, No. 4 Impressed current cathodic protection 273
3.1.2 Frigates
Systems permanently installed onboard a ship provide only A validated experimental laboratory technique employing
little scope for experimental surveys. Sea trials are time con- scale ship models was established to develop the fundamen-
suming and often very difficult to conduct. tals and a better understanding of the mechanisms of cathodic
It is not possible to correct the location of the anodes and the corrosion protection.
reference electrodes once the system is installed onboard the Studies were conducted to evaluate the performance of ex-
frigates. isting and newly developed configurations and focussed on
the number and locations of the anodes and reference electro-
des [1, 2].
4 Optimising system configurations by means of
physical scale modelling
4.1 Experimental laboratory technique
Therefore it was necessary to find a method for developing
or optimising system configurations. Neither catalogued nor 4.1.1 Models
computer-aided methods were available for a theoretical de-
termination of the best technical solution. Models of the hull are generally built to a scale of 1:19
(Fig. 6). Consequently, the frigate models are about 6.5 m
long. As a prerequisite for the fundamental model studies,
the model must be made of materials whose polarisation char-
acteristics are identical to those of the original objects. Silver/
silver chloride monitoring electrodes are used to measure the
potentials on the hull shell. The shell is punctured at some 50
representative test points to accommodate the monitoring