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    journaal

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    © All Rights Reserved
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    2 views10 pages

    Us 20180133658 A 1

    Uploaded by

    Adhe Martha
    journaal

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
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    of 10
    cu») United States US 2018) BAL 3368 2) Patent Application Publication co) Pub. No.: US 2018/0133658 Al SEO et (34) ADSORPTIVE MEMBRANE (71) Applicant: AMOK Gimporsi (KR) (72) Inventors: In Yong SEO, S JEONG, lachoon (KR) 21) Appl. No. (2) PCT File: (86) PCT No, $371 (X0), (2) Date G0) Sua, 1 May 18, 2016 ENTECH CO, LTD. oul (KR); Ut Young, PCTIKR20161005255 Nov. 9, 2017 Foreign Application Priority Data 2015 (KR) 10-2015-0077321 (43) Pub. Date: May 17, 2018 Publication Classification GI) Ime BID oon (2006.01) BOID 6700 (200501), BOLD 692 2006.01), (2) US. Cl, cr BOLD 69/12 (2013.01); BOLD 67/0093 (2013.01); BOD 69/2 (2013.01); BOID 2323/39 (2013.01); BOID 2325/48 (2013.01): ‘BOLD 2325/13 (2013.01); BOLD 2325/14 (2013.01); BOLD 2325/16 2013.01); BID 232542 2013.01); BOLD 2323/36 (2013.01) on ABSTRACT Provided is an adsorptive membrane, which includes: a support member having a plurality of frst pore; anda first ‘adsorptive member which i sacked on the support member ‘and hs. plurality of second pores forme! therein and whieh js made by accumulating ion exchange nanofibers for adsorbing foreign substances. 120b ~~ 150 ‘ -120a Patent Application Publication May 17,2018 Sheet 1 of 3 US 2018/0133658 Al FIG. 1 Patent Application Publication May 17, 2018 Sheet 2 of 3 ‘US 2018/0133658 AL FIG. 3 210 set 120 +10 FIG. 4 120, 110 1200 FIG. 5 1208 11206 110 FIG. 6 120 110 Patent Application Publication May 17, 2018 Sheet 3 of 3 FIG. 7 ‘US 2018/0133658 AL 4206 +160 FIG. 8 110 US 2018/0133658 Al ADSORPTIVE MEMBRANE, ‘TECHNICAL FIELD [0001] The present disclosure relates to an adsomptive ‘membrane, and more particularly to an adsorpive mem- brane capable of adsorbing ionie foreign substances by an adsomptive member made by accumblating ion exchange nanofibers, and capable of enabling paysical adsomption of reign substances by pores, thereby improving adsorption ‘ellicieney, and obtaining a desired antibacterial propery. BACKGROUND ART [0002] In recent years, industrial developments have ‘caused various environmental problems due to pollutants ‘eaused by rapid economic growth, population growth and urbanization 10003} ‘That is, pollutants such as wastewater, heavy met- ‘ls, dust nd harmful gas are discharged from manufocturing plants and industrial facilites of various industries, living ‘eiliies, automobiles and motoreycles, thereby polluting sie and water quality 0008} These pollutants are interfering. with the life of human being, who wants to live pleasant and healthy life ‘and various solutions © purify the pollutants have been ‘ough andthe research and development for this have beea ‘continously and variously contimied, 10005] An example technique for purifying contaminants fs to filter the contaminated gos of liguid through « mem brane 10006] Membranes can separate and filter only certain ‘components from gases, liquids, solids or mixtures therco, ‘and the mixture is filtered sing the physicochemical prop: crtes of the membrane [0007] | Membranes in a water treatment fed are classified jnto porous membranes, microporous membranes and homogeneous membranes depending on the structure of the ‘membrane, and they are classified into microfiltration mem- branes, ultrafltation membranes, reverse osmosis: mem- branes, gas separation membrane, and pervaporation mem- branes Jepending on their applications 10008] Here, a polymer membrane is prepared by casting «polymer solution into a sheet and then immersing iin 8 solid phase. The polymer membranes have been used a8 & ‘wide range of membranes ranging from mierofiltmation to zs permeation. 0009] Korean Patent Application Publication No. 2011- £85096 proposed a composite iter in which activated carbon fibers and ion exchange fibers are laminated on a side wall ‘of @ housing, However, there was a disadvantage that the ize of the filter is lage i the form of a composite filter. [0010] Korean Patent Registration Publication No. 507969 proposed a technique of producing a web by form= ing a web of ion exchange fiber on an ion exchange nonwoven fabric, sprinkling ion exchange resin on the web, phicing an ion exehange nonwoven Tabrie thereon, and removing ionic gas such as acidic or alkaline present in 2 ‘lean room of Semiconductor manufacturing process, ith 8 non-woven type composite ion exchenge filter using neadle punching. However, since the pores of he nonwoven fabric arc large, the very fine harmful dust cannot be filtered, ‘and the ion exchange resin sprayed on the ion exchange ronwoven fabric may flow to thereby cause an additional source of pollution to occur May 17, 2018 DISCLOSURE Technical Problem [0011] The present disclosure has been made in view of | the above circumstances and has aa object to provide aa ‘adsorptive membrane capable of adsorbing ionie foreign substances and physically filtering foreign substances by pores ta impove the adsorption performance while preser\~ fing the flow rate [0012] It is another object of the present disclosure to provide an adsorptive membrane capable of obtaining. an excellent antibacterial property by including an adsorptive ‘member made by acctimolating nanofibers containing an antibacterial substan or by performing a silver yarn stiteh- ‘ng process on @ membrane. Technical Solution [0013] According to an aspect of the present disclosure there is provided an adsomptive membrane comprising: support ember having a plurality of first pore; anda fist adsorptive member whieh i stacked on the suppor member ‘nd has a plurality of second pores formes therein and which js made by accumulating ion exchange nanofibers. for ‘adsorbing foreign substances. [0014] In addition, in the adsorptive membrane seconling {o an embodiment of the present disclosure, the support member may be a nonwoven fabric ar a woven fabric. [0015] In addition, in the adsorptive membrane seconing to an embodiment of the present disclosure, the fist pore size may be large than the second pore ize. [0016} In addition, inthe adsorptive membrane eeconding {fo an embodiment of the present disclosure, the ion exchange nanofibers may be cation exchange nanofibers or anion exchange nanofibers. [0017] In addition, inthe adsorptive membrane seconding oan embodiment of the presen disclosure the fist adsorp- tive member is laminated on an upper surface of the support ‘member, and the adsorptive membrane may further com- prise a second adsorptive member which is stacked on a lower surface of the support member and has a plurality of third pores formed therein, and which is made by aecunm- Jating jon exeliange nanofibers for adsorbing foreign sub- [0018] In addition, inthe adsorptive membrane seconling fo an embodiment of the present disclosure, the ion ‘exchange nanofibers may be cation exchange nanofibers oF anion exchange nanofibers, and the adsompive membrane ‘may further include a third adsompive member which is stacked on the first adsorptive member and has a plurality of ‘hind pores formed therein, and which is made By acura. Jating other fon exchange nanofibers that exchange ions of ‘opposite polarity with those ofthe ion exchange nanofibers for the fist adsorptive member [0019] In addition, the adsorptive membrane acconling to ‘an embodiment ofthe present disclosure may furler com- prise a nanofiber web that i laminated onthe frst adsomptive ‘member and has plurality of pores formed therein and that js made by accumulating nanofibers containing dopamine, ‘whieh funetional groups for adsorbing foreign substances are attached [0020] Ter, the sanofiber web may have the Functional groups attached to the dopamine by a UV iemadiation, 2 plasma treatment, an seid treatment, or a base treatment on US 2018/0133658 Al 4 web prepared by electrospinning a spinning soluto formed by mixing the dopamine with a solvent and a polymer substance. Here, eeh ofthe functional groups may be a negative charge futional group of & positive change funetional group. [0021] In addition, in the adsorptive membrane according to an embodiment of the present disclosure, the ion ‘exchange nanofiners may be costed with cl 10022] In alton, inthe adsorptive membrane according to an embodiment ofthe present disclosure, the first adsorp- tive member may be designed tobe thinner than the support rember, 0023) In addition, inthe adsorptive membrane according to an embodiment of the present disclosure, one or both of the support member and the frst adsorptive member may further comprise stitched silver yan 10024] According to another aspoct of the present disclo- sure, there is provided an adsorptive membrane comprising: 8 support member having a plurality’ of fst pores: a first ‘adsorptive member stacked on an upper surface oF the suppor member and having a plurality of second pores Tormed therein and made by accumulating ion exchange nanofibers for adsorbing foreign substances; and a second ‘adsomptive member stacked on an upper surface of the fist adsorptive member and having a plrality of second pores ormed therein and made by accumulating nanofibers con taining an antibacterial substance 10025) Here, the second and third pore sizes may be smaller than the fist pore size, and the antibacterial sub- Stance may bea silver tanomateral, and the secand adsorp- five member may have a nanofiber web stractre formed by ‘elecicospinning a spinning solution prepared by dissolving the silver nanomteril in an onganic solvent together with 2 fiber formability polymer material Advantageous Effects 10026) According to some embodiments of the present disclosure, there are advantages that itis possible to adsorb onic foreign substances by the ion exchaage nanofibers of the adsorptive member and to physically filter the foreign substances having a size lager than the pore sizes of the pores ofthe support member and the pores of the adsomptive ‘ember fo improve the adsorption eficieney of the Foreign substances. 10027] According to some embodiments of the present disclosure, the adsorptive member having the plurality of pores formed by the nanoibers is laminated on the support rember having the plunliy of pores to realize a membrane, thereby making it possible to improve the adsorption per ormance while preserving the passing low rate 10028] According to some embodiments of the present disclosure, it is possible (0 realize an adsorptive member ‘capable of being manufactured at low cost with excellent handling properties and strength by laminating the adsorp- tion member and the support member. 10029] According to same embodiments of the present

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