Bindzil CC in waterborne coating applications Silane modified colloidal silica - uses and benefits j . AkzoNobelProduct overview Bindzil CC colloidal silica water dispersions enhance a number of important properties in pigmented and clear coatings, thus providing strategic product benefits for you as a manufacturer. Bindzil CC products are unique water-based epoxy silane modified colloidal silica dispersions. Bindzil CC products are stable and compatible in most waterborne coatings. Application recommendations + Clear coatings ‘Pigment dispersions + Silicate paints + Pigmented coatings Bindzl C0301, Bindail C0302 and Bind CC4O1 are spe aly developed and designed for use in waterborne 2-pack and UV-curable coatings. Bindzll CC products offer good stably and binding properties in most 2-pack and UV- ‘curable coatings and enhance mechanical properties, adhe- sion and ant-blocking with no change in gloss or haze. The Bindzl C0161 HS is speoiically designed for use as a dispersant for inorganic pigments such as ttania when a surfactant-fee pigment paste is desirable, Bindall C0201 is designed for use in sicata paints to reduce dirt pick-up and to improve the water resistance (hence weather resistance). Bindal PC300 can be used to enhance antsol properties! reduce the dit pick-up in waterborne dco paints. Available Bindzil CC products Non-aggregated particles with many surface groups for interaction with resin «*Bindzl OC181 HS: TS: 15%, Dp: Sam + Bindail C6301: TS: 30K, Dp: 7 nm ‘= Bindzl 06302: TS: 30%, Dp: 7 nm ‘= Bindell OC401: TS: 40%, Dp: 12mm + Bindzl PC300: TS: 30%, Dp: 7 nm Bi norganic paints organic feels Bieri) Pets EetaE eed pigment Bol Binds C901, model structureClear coatings Benefits of Bindzil CC Colloidal Silica in waterborne 2-pack and UV-curable lacquers ‘The enhancement of mechanical properties when Bindeil CC products is incorporated into ‘the coating is due fo the formation ofa silica network/structure in a resin matrix which can act as a reinforcing skeleton in such a matrix. Furthermore, the strong interaction between ‘the many surface groups on the slica particles and substrate surfaces improves properties, such as adhesion. Finally since Bindzl CC products can be described as small and very hard olass-ike particles, enhancement of ant-blocking properties is also possible Improved mechanical properties Persoz Hardness. Resin: PU dispersion, TS:35%, pH, 2k system HPof 109% Binds C0901 20 % Binds CO301 gow $0 2 1 7 “ 20 Time (dey) Persoz harness (EN 1522} for coatings containing Bindzil OC301, based on PU-resins Formulation proposal FP 9150, based on Alberdingk°U 9150 Pos._| Raw material Amount | Produet Supplier 1 | Alberingk*¥ 9150 | 60.40 | Polyurethane | Alberdingk Boley ispersion 2 Bindzil C6301 1350 | modified siloa | EKA Akzo 3 Dowanol DPM 950 | co-solvent | Dow Chemical 4 Water (dion) 9.0 5 Tego Foamex 845 0.60 | defoamer Evorik Tego Chemie 6 Tego Airex 904W 0.40 | defoamer Evorik Tego Chemie 7 Ceratlour 920 1.00 | matting agent _| BYK Gera 8 ‘Acematt TS 100 0.50 | matting agent | Evorik 9 Uttralube 816 D 1.00 | wax dispersion | Koim Additec 10) Byk a6 0.30 | substrate BYK Cherie ‘welling agent 11 | heolate 212 050 | rehedlouy Blementis, TOTAL 117.40 (Promix Pos. 344 before uso), Improved scratch resistance Ref, 10% Binge C0301 systems _| Scratch resistance (@) Reference Put Pu2 Pus 10% Bindzil C6301 PUB 2000") Put 1900 PUD 2000) () Maximum load has been applied on the nee dle without cutting through the coating films Typical properties formulation FP 9150 Pendulum hardness after 74 FT: ca. 80s (according to Koenig) ‘Abrasion resistance: ca: 10mg Chem Ethanol 5 (th) ‘Ammonia: 4-5 (th) Fatty acid: 4-5/4 (1h/16H) Wator: 5 (16h) Reed wine: 4 (16h) Coffe: 3 (16h) 5 = best /0= worst 2K clear lacquer based on formulation FP S150 ‘Add 10% Bayhydur 205 (65% in Proglde DMM) al resistance:Pigment dispersions Benefits of Bindzil CC as dispersant of inorganic pigments + Surfactant-free pigment paste + Improved chemical resistance in coatings + Easy to use and not shear-sensitive + Additional benefit in paint: reduced dirt pick-up How it works of colloidal sca particles alo 18a igpereant in some aoplictior lp keep the is particularly tania pigment dispersed by Dspex N40 Tania pigment dapersed by Bind COIS! HS Improved pigment efficiency Reflectance versus wt- % Ti, nan Acryie Coating eo Corsi Hs =O Dispex N-40 Reflectance (%) 0 10 20 0 50 © wt-% TiO, in the filmSilicate paints Benefits of Bindzil CC in silicate paint + Stable 1-pack compositions are possible + Low alkali content: H typically about 14.2 + Good water resistance (depending on molar ratio) + Good dirt pick-up resistance How it works Colloidal slica is used in inorganic paint ie slicate paint and can eas ly be formulatad with potassium slicate as the main binder. In si cate paints, colcidalslica reduces the alkalinity and water absorption and improves the ant-soling prop: ties, It also hsips reduce internal stress by reducing the strinkage in the coating, Surfaces that can benefit from these coatings include all forms of natural stone and ma sony, Improved water resistance fof 100 parts paint formulation System 1 (reference — potassium silicate) System 2 @ parts GC301 + 1 part sifcate) System 3 (1 part C301 + 1 part silicate) System 4 (1 part C301 + 2 parts silicate) Absorbed water volume (ml) after 6 hours >20 2641.08 2741.40 272097 Improved dirt pick-up resistance (DPU) ‘The slica particles in colloidal slica dispersions have fully hycroxylated surfaces (mary surface hydrony-sianol groups) and are very hycrophifc When such materials are deposited onto or incorporated inta a surface, the results that it inherits the hydrophilic nature and thus making it hard for the dirt to adhere to the surface, An additional benefit fs that the surface is easiy maintained by either rainfall or simple cleaning as the drt rinses away from the surface. System (ret) System 2 system system d ‘Systems Yinitid | Yfinal | r= Yfinal/Yinitial System 1 (of) | 77.52 30.19 039 System 2 3555 e122 095 System 3 34.00 4458 058 System 4 8233 aro 058 ‘The DPU has been estimated by applying an aqueous stury of carbon blackPigmented coatings acrylic paints Benefits of Bindzil CC in acrylic paints + Dirt pick-up resistance + Increased hiding power Reduced dirtpick-up, acrylic paints with Adhesion and reduced dirt pick-up Bindzil CC30' Bindi CO3O1 post added 700 0 00 2 200 100 0.00 0% cca | 1s% ccs07 tl "oc301 | The coledalsiica particles are enviched at the interfaces enhancing adhesion tia steol property atars oth Coding nade yop. oh mo wr 125 oss jos | edly cr aiunt and ci wlan cho mao etc oo Sait nal hs ppc hence eascng tho fl Sea mco | ens 270 280 14s | ert Hiding power, acrylic paint with BindzilCC301__Exterior wall paint formulation with different Binds CC204 added amount of Bindzil CC301 wo Post adction Pram (esoran| | wanpart mt | Retna | 0m = [ae Hiding power (2) oa «sins | : cs ¢ | ee : “ [J |semagscae| atm [as [ae [am] a beat coor | : : iPigmented coatings alkyd paints Benefits of Bindzil CC in alkyd paints + Dirt pick-up resistance + Increased hiding power + Combined flexibility with hardness Reduced dirt pick-up, alkyd paint with Bindzil CC301 Paint Bt wth 10% Fference inal C0201 postackod ister iar oe von Y ater Yeenp Surface aspects after washing PPaints have bean applied by means of brush on pine wood substratsin two layers (24 hours between the two layers). After 14 days of drying at room femnperature, the surfaces have beon contarrinated with a water- ‘based solution wthrediron oxide. Thecontarination hasbeenappliedby ‘msansa spray. The contaminatedsystamshavabeenletto cry 24hoursat room temperature. The contarinated surfaces have been washed with water only and with seaped water Paint 8 Paint 81 Reference system 90 g paint B + 10 g Bindzl CC301 Hardness and flexibility “he colloidal silica particles rnforco the coating system an make a tougher, ‘mors dre costing it) a harder mons hyaroiesrtace whe ating ‘ety Th rp a coating syste Sons agd mane wee at ‘Etihunce belgimpolstte te rmove in acon aairg wes good text Sd low de pk Up proportisn,troughout te svi it the rosa. Products Weight (g) Grinding paste 1 | Water 202.60 2 | Coadis BRAS 76.00 3 | CoapurxS22 22.50 4 | Bykooe 6.00 5 | _ KRONOS 2190 300.00 8 | _ OMYACOAI 85006 196.00 Letdown 7 | Water 72.00 8 | Aqvatow nfs 350 30.00 9 | Coapur ¥S22 16.00 10 | SorAdFA170 450 11 | SYNAQUA 4804 590.50Head office Europe ka. Chernioale AB ‘AlzoNobel Chenicals GmbH rusia Speciatios Ines Specatos| E445 80 Bohus reuzaver St 48 ‘Sweden DE-52355 Diron, Gmary Phone: 1460) 58 7000 Phone: +49 (92421 595404 Fac +46 (31 58 7859 Fax +49 (02821 S969 Bind2iP, Levasi® Combinder® and Bevasi® are registered trademarks of AkzoNobel and Eka Chemicals in some counties world-wide. Tomorow’s Answers Today isa trademerk of, ‘Akzo Nobel NV. Information herein is given in good faith and is acourate to the best of our knowledge, Information and suggestions are made without warranty or quarantee of results. Before using, ser should determine the suitabilty ofthe produc forts intended use and user assumes the rik and lability in connection therewith ‘The application, use and processing of our [products and the products manufactured by you on the basis of cur technical acvice are ‘beyond our control and, therefore, entirely your ‘own responsibitty. We do not suggest violation Cf any existing patents or give permission topractce any patented invention without a Toanse. 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