PAPER Adva PII Sol PDF

1
AITS-CRT-I(Paper-2)-PCM (Sol)-JEE (Adv)/14
From Classroom/Integrated School Programs 7 in Top 20, 23 in Top 100, 54 in Top 300, 106 in Top 500 All India Ranks & 2314 Students
from Classroom /Integrated School Programs & 3723 Students from All Programs have been Awarded a Rank in JEE (Advanced), 2013
FIITJEE JEE(Advanced)-2014
ANSWERS, HINTS & SOLUTIONS
CRT–I
(Paper-2)
Q. No. PHYSICS CHEMISTRY MATHEMATICS

ALL INDIA TEST SERIES
1. C A, B, D B
2. B A, D A
3. B B, C, D A
4. B A, D D
5. D A, D B, C, D
6. C B, C, D A, B, C
7. A A, B A, D
8. C B, C A, B, C, D
9. B. D C
10. C C A
11. B A C
12. A B A
13. C B A
14. A B A
15. A D A
16. C C A
17. B A C
18. A B D
19. C D B
20. D D D
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
2
Physics PART – I
SECTION – A
2. vmax =   mg/k
mv max 2mg
Fav = 
T 4 
2R
 4S  2 7R3 3R2
3. W= p 
R  0 r 
  4 r dr = 4p0  + (4)(4S) 
3 2
4. Work done by all the forces on the block equal to change in kinetic energy.
6. No effect of ‘a’ and ‘g’ on time period of spring pendulum.
1  1 1  8R
7. = R 2  2  
 3 1 1 3  9
1  1 1  3R
= R 2  2  
 2 1 1 2  4
 3 1 27
 
 2 1 32
  x dx N
8. Work done by friction   F  ds   mgcos  
0
cos 
= mg x = 20 J f

mg dx ds dy
cos   
ds
dx
9. Field inside the conductor is zero
10. Charge distribution is shown in figure. Q
O Q Q O O O
s1 s2
 0
11. 
( 3mg) /(m / ) 2mg /(m /  )
3
  0
2
 m
 2m   g 5
 2
12. v = g
m/ 2
3
13-14. If the bike does not slip, path of both the wheel
must be parallel with its direction as shown in the Front
figure. wheel
R1 = /tan
R2 
2
 2  c.m.
Rcm =    R1 = 4  tan2  
2 2 tan 
Rcm
mv 2 2mv 2 tan  
Net friction force f =  Rear
R cm  4  tan2  R1 wheel
15. p0A = ma  a = p0A/m
16. p0A = ma  m = m/5

 m  m = 4m/5
Chemistry PART – II
SECTION – A
2. H3C H CH3 H Cl CH3
PCl
C C  H C C CH3 
5
 H C C H
H CH3 CH3 Cl
O
 anti conformer 
3. Thermal stability of nitrates of alkali metals increases down the group. MgO is basic; SnO is
amphoteric and B2O3 is acidic oxides.
4. Cell reaction is:



Tl  s   Cu2  aq 
 Tl  aq   Cu  s 

Tl  0 0.0591
Reaction quotient Q  2
and Nernst equation is Ecell  Ecell  logQ; at 298 K
Cu  n
+
To increase Ecell, Q should be decreased. Which is decreased by decreasing [Tl ] and increasing
2+
[Cu ].
5. Statement ‘B’ is true for weak electrolytes only and in case of ‘C’ osmosis never stops so dilution
on solution side continues and no limiting value of equivalent conductance of solution is obtained.
6. Pb3 O 4  4HNO3 
 2Pb NO3  2  PbO2 2H2 O
Before reaction 0.05 mole 2 mole  
After reaction  1.8 mole 0.1 mole 0.05 mole
residue
2
2Pb  8NaOH  2Na 2 Pb OH  4 
HNO3  NaOH  NaNO3  H2 O
Moles of NaOH used to neutralise excess of HNO3 = 1.8 mole
Moles of NaOH used with Pb(NO3)2 = 0.4 mole
Total NaOH used = 2.2 mole.
4
1
7. Coagulation value 
Coagulating power
Less is the gold number, better is the protection power.
8
8. Maximum capacity or volumes of balloon   480  548.57 ml
7
Also, V1 = 480 ml, T1 = 278 K, n = 1 mole
(A) The balloon will burst at a minimum temperature (T2) when volume becomes 548.57 ml.
Using Charle’s law
V V
 1  2
T1 T2
480 548.57

278 T2
 T2 = 317.71 K
or T2 = 44.71oC
Hence (A) is incorrect but (C) is correct.
o
(B) Pressure of the gas at 5 C having 1 mole and V = 480 ml
PV = nRT
480
 P  1 0.0821 278
1000
 P = 47.5 atm
Hence (B) is also correct.
(D) Since V increase with increase in temperature from 5oC to 44.71oC, at which balloon bursts
and therefore pressure remains constant. Thus pressure of gas inside the balloon when it
bursts is 47.5 atm. Hence (D) is incorrect.
Hence (B, C) are correct.
Solution for the Q. No. 9 & 10

B is CO2(g)  the compound A is a ZnCO3 and C is oxide of Zn, as it is white when cold and turn
yellow on heating. D is CaCO3 which form Ca(HCO3)2 which exist in solution only.
Solution for the Q. No. 11 & 12

OH
OH
C
Since ‘A’ react with NaOI, it must be O CH2Cl other side products are
OH OH
OH O OH
OH
O C CH2Cl
and less likely to be ; B is ;
C
H 2C O CH2NHMe
COCl
OH
OH
while ‘C’ is
CH
HO CH2NHMe
5
13. The above paragraph shows that compounds (A to D) are

CH2 Cl COOH COOC2H5
H2 C H 2C CH3COOH H2C
CH2 Cl COOH COOC2H5
(A) (B) (C) (D)
In above problem concerned reaction is:
COOC2H5
 
CH O + H2C i Py, 
  CH CH COOH
ii H3 O
COOC2H5 iii 
Benzaldehyde (D) Cinnamic acid

(E)
Hence (B) is correct.
14. Since compound (C) is CH3COOH. So,

O
O
H3C C
H3C C OH
P4 O10 O(ethanoic anhydride)
O 
 H2 O
H3C C
H3C C OH
O
(F)
Hence (B) is correct.
15. (A) That is path independent e.g. U  q  w; U is state function, while q and w are path
functions.
(B) Work is a type of energy in transit, i.e. which appears only on surface/boundaries.
(C) w & q are not completely interconvertible.
16. (A) Work is path function.

(B) Initially there is no opposing force but opposing force increases gradually due to diffused gas.
(C) W = ab; (area inside the curve)
a = 3 litre, b = 1 atm.
17. Le-chateliers principle is applicable and for (R) Ptotal = PCO2 , which is equal to Kp for the given
reaction.
20. Isodiaphers are those atoms for which (n-p) is equal. Isoesters are those species which contains
equal number of atoms as well as equal number of electrons.
6
Mathematics PART – III
SECTION – A
1. Normal vector to plane P1 3 k̂
Normal vector to plane P2 2iˆ  4ˆj  3kˆ

a    2iˆ  ˆj 

angle between a and vector ˆi  2ˆj  2kˆ is given by
  2iˆ  ˆj    ˆi  2ˆj  2kˆ 
cos = 0
 5 9

= .
2
2. f(x) = f(x)
Integrating log f(x) = x + k
f(x) = ex+k
f(0) = 1
1 = e0.ek
k=0
 f(x) = ex
g(x) = x  f(x) = x  ex
1 1 1
 
0

I  e x x  e x dx  e x x dx  e2x dx

0
0
e2 1 3 e2 3  e2
 e  (e  1)      .
2 2 2 2 2
3. n (S) = 64C3
Let ‘E’ be the even of selecting 3 squares which from the letter ‘L’
No ways of selecting squares consisting of 4 unit squares = 7C1  7C1 = 49
Each square with 4 unit squares forms 4L – shapes consisting of 3 unit squares
 n (E) = 7  7  4 = 196
196
 p (E) = 64
C3
4. x2 + 9y2 + 25z2 = 15yz + 5 zx + 3xy

(x)2 + (3y)2 + (5z)2  (x) (3y)  (3y) (5z)  (x) (5z) = 0
1
2(x)2  2(3y)2  2(5z)2  2(x)(3y)  2(3y)(5z)  2(x)(5z)
2 
1
= (x  3y)2  (3y  5z)2  (x  5z)2   0
2 
x  3y = 0, 3y  5z = 0, x  5z = 0
1 1 5 1 1 1
 and  and 
x 3y 3y z 5z x
1 1 1 5 2
   
x z 3y 3y y
1 1 1
 , , are in A.P. and x, y, z are in H.P.
x y z
7
5. When z = n + 1 we can choose x, y from {1, 2, …, n}

 when z = n + 1, x, y can be chosen in n2 ways and z = n, x, y can be chosen in (n – 1)2 ways
and so on
2 2 2 1
 n + (n – 1) + … + 1 = n(n + 1)(2n + 1)
6
ways of choosing triplets
Alternatively triplets with x = y < z, x < y < z, y < x < z can be chosen in
n+1 n+1 n+1
C2, C3, C3 ways.
There are
n+1
C2 + 2(n + 1C3) = n + 2C2 + n + 1C3 = 2(n + 2C3) – n + 1C2.
6. z = zei … (1)
z = zei … (2)
2
 zz = z  z, z, z are in G.P.
2 2
 z   z 
      2cos2
z  z
 z2 + z2 = 2z2 cos 2
z + z = 2z cos .
c
7. 3 = c  c = 6, 1.
1 1
2
 2
3 4
1 1 1 1
8. cos =  x   and cos =  y  
2 x 2 y
1
since xy > 0  x +  2 or  – 2
x
1
y+  2 or  – 2
y
 cos = 1, cos = 1 …(1)
or
cos = –1, cos = –1 …(2)
 cos cos = 1
(cos + cos)2 = 4
  +  is an even multiple of .
 sin( +  + ) = sin(2n + ) = sin
Also, sin = sin = 0
  C (z3
9. IAB = , IAC =
2 2
i
z 2  z1 z  z1  2
 4 e
| z 2  z1 | | z 4  z1 | I (z4)
i
z3  z1 z  z1  2
 4 e
| z3  z1 | | z2  z1 | (z1) A B (z2)
 z  z2 
2 D  1 
 z2  z1   z3  z1   z 4  z1   2 
 e
| z2  z1 || z3  z1 | | z 4  z1 |2
8
2
 z2  z1   z3  z1  AB  AC  AB   AC 
  =    
 z 4  z1 2 IA 2  IA   AB 
 z2  z1   z3  z1   AD 2  AC 
10.  2    (Since AB = 2AD)
 z4  z1 2  IA   AD 
 z4  z1  2 (1 + cos ) sec  =  z2  z1   z3  z1 
11. Equation of the tangent is
x y
sec   tan   1
a b
2 2
Normal is ax cos  + by cot  = a + b
 2 2   2 2 
The normal at P meets the co-ordinate axes at G  a  b sec , 0  and g  0, a  b tan  
 a   a 
2
 2 2 
 PG2 =  a  b sec   a sec     b tan   0 2
 a 
b2
PG2 = b2 sec 2   a2 tan2  
a2
12. When tan  = 0

b2
PG =
a
13. When 1 all rounder and 10 players from bowlers and batsman play number of ways
= 4C1  14C10
when 1 wicket keeper and 10 players from bowlers and batsman play number of ways
= 2C1  14C10
when 1 all rounder 1 wicket keeper and 9 from batsmen and bowlers play number of ways
= 4C1  2C1  14C9
when all eleven players play from bowlers and batsmen then the number of ways
= 14C11
 Total number of selections = 4C1  14C10 + 2C1  14C10 + 4C1  2C1  14C9 +14C11.
14. If 2 batsmen don’t want to play then the rest of 10 players can be selected from 17 other players
17
number of selection = C10
19
If the particular bowler doesn’t play then number of selection = C11
17 19
 Total number of selection = C10 + C11
dy
15. Slope of tangent at any point P(x, y) is y
dx
dy
 = ky  y = ek(x – 1)
dx
Since a(y – 1) + (x – 1) = 0 is normal at (1, 1)  k = 1
Hence f(x) = y = ea(x – 1)
1
1 x a x 1  1 1 a 
16. Area bounded =   a  a  1  e
0
 dx =  a   e  sq. units.
 a 2 
9
 k2  k2
17. (P) Limit is easily reducible to cos ec 1   by L’Hospital rule which exist if  1.
 2 2
2
(Q) kx + (3 – 2k)x – 6 = (kx + 3)(kx – 2)
3 3 3
4  5– k– .
k 4 5
(R) (2k + 1, k – 1) is an interior point
2 2
(2k + 1) + (k – 1) – 2(2k + 1) – 4(k – 1) – 4 < 0
6
0<k< ….. (1)
5
Centre (1, 2) and point (2k + 1, k – 1) must lie on opposite side of chord x + y – z = 0
2
k< ….. (2)
3
2
0<k<
3
5  5 
(T) x > – , – 4 < x < 4  x    , 4 
2  2 
 16  x 2 
log5   1
 2x  5 
16  x 2
  51
2x  5
 x  (– , – 9)  [– 1, )
 x  [– 1, 4]

 tx 2
18. I=
e
0
dt
du
x t = u, then dx =
t
 
2 du 1 2 
 e u eu du 
t
I= =
0
t 0
2 t
 
 x2 2
e dx = 2 e x dx   .

 0
r1r2r3
19. r1r2 + r2r3 + r3r1 =  s2  144
r
4(r2 + r3) + r2r3 = 2r2r3 = 144
 r2r3 = 72, r2 + r3 = 18  r2= 6, r3 = 12
r sa 1
  a6
r1 s 2
Similarly b = 8, c = 10
 ABC is right angle triangle.
3
Smallest angle is sin1
4
1
=  6  8 = 24 sq. units
2
R=5
|r2 – r3| = 6
10
20. (P) Equation of normal is y = tx + 2at+ at3 at P(t)

It intersect the curve again at point Q(t1) on the parabola such that
2
t2  t 
t
2
Again slope of OP is  MOP
t
2
Also, slope of OQ is  MOQ
t1
4
Since MOP  MOQ  1 
tt1
 tt1 = 4
 2
t   t    4
 t
 t2 = 2
(Q) P(1, 2), Q(4, 4), R(16, 8)
Now, ar(PQR) = 6 sq. units
(R) Equation of normal from any point P(am 2, 2m) is
y = mx  2am  am3
 11 1 
It passes through  , 
 4 4
3
 4m + 8m  11m + 1 = 0
 4m3  3m + 1 = 0
Now, f(m) = 4m3  3m
 f(m) = 12m2  3 = 0
1
 m
2
 1  1
Since f   f     0 has 3 normals are possible.
 2  2
(T) Since, normal at P(t1) if meets the curve again at (t2), then
2
t 2  t1 
t1
Such that here normal at P(1) meets the curve again at Q(t)
1
 t = 1   3
2

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AITS-CRT-I(Paper-2)-PCM (Sol)-JEE (Adv)/14

Q. No. PHYSICS CHEMISTRY MATHEMATICS

6. No effect of ‘a’ and ‘g’ on time period of spring pendulum.

9. Field inside the conductor is zero

10. Charge distribution is shown in figure. Q

15. p0A = ma  a = p0A/m

16. p0A = ma  m = m/5

4. Cell reaction is:

Solution for the Q. No. 9 & 10

Solution for the Q. No. 11 & 12

13. The above paragraph shows that compounds (A to D) are

Benzaldehyde (D) Cinnamic acid

14. Since compound (C) is CH3COOH. So,

16. (A) Work is path function.

Mathematics PART – III

4. x2 + 9y2 + 25z2 = 15yz + 5 zx + 3xy

5. When z = n + 1 we can choose x, y from {1, 2, …, n}

12. When tan  = 0

20. (P) Equation of normal is y = tx + 2at+ at3 at P(t)

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