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OEESAVE BSAPEUEO With Mollier Diagram IN S.I. UNITS ‘Dear Students, Beware of fake/pirated editions. Many of our best selling titles have been unilavsfidlly printed by unscrupulous persons. Your sincere effort in this direction ‘may stop piracy and save intellectuals’ rights. For the genuine book check the 3-D hologram which gives a rainbow effect. {Np S.cHAND ‘AN 180 8001: 2000 COMPANY S. CHAND & COMPANY LTD. RAM NAGAR, NEW DELHI-110 055 .. S. CHAND & COMPANY LTD. HS «An 180 9001 : 2000 company, se Head Orfice : 7361, RAM more NEW DELHI - 110 055 Phones : 23672080-81-82, 9899107446, 9911310888; Fax : 91-11-23677446 Shop at: schandgroup.com; E-mail: schand@vsni.com Branches : * Ist Floor, Heritage, Near Gujarat Vidhyopeeth, Ashram Road, ‘Ahmedabad-3600014 Ph. 27541965, 27542369, chmedabad@schandgroup.com * No.6 “Ahuja Chambers, 1! Cost Kumara Kup Rood, , bangalore@schandgroup.com . Ph : 4274723, bhopal@schandgroup.c * 152, Anno Saial, Chennai-400 002. 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S. CHAND’S Seal of Trust Tnour endeavour to protect you against counterfeil/fake books we have puta Hologram Sticker on the cover of some of our fast moving titles, The hologram displays a unique 3D multi-level, multi-colour effect of our logo from different angles when tilted or properly illuminated under a single source of light. Background artwork seems to be “under” or “behind” the logo, giving the illusion of depth. A fake hologram cloes not give any illusion of depth. First Edition 1984 Subsequent Editions and Reprints 1984, 86. 87, 88, 89, 90, 91, 92, 93, 94, 96 (Twice), 97. 98, 99, 2000, 2001, 2002, 2003, 2004 (Twice), 2005, 2006 (Twice), 2007 (Twice) Reprints 2008 ~ ISBN: 81-219-0654-7 Code : 10044 PRINTED IN INDIA By Rajendra Ravindra Printers (Pvt.) Ltd, 7361, Rom Nagar, New Deihi-110 055 and published by S. Chand & Company Ltd., 7361, Ram Nagar, New Deihi-110 055. PREFACE TO THE EIGHTH EDITION 1 feel happy in presenting the revised edition of this small booklet. The favourable and warm reception, which the previous editions and reprints of this booklet have enjoyed at home and abroad, has been a matter of great satisfaction to me. The mistakes, which had crept in the previous edition, have been eliminated, In short, itis earnestly hoped that this standard booklet will continue to earn appreciation of the teachers and students alike. Although every care has been taken to check mistakes and misprints, in this colossal figure work, yet it is difficult to claim perfection. Any errors, omissions and suggestions for the improvement of this booklet brought to my notice, will be thankfully acknowledged and incorporated in the next edition. R.S. KHURMI PREFACE TO THE FIRST EDITION take an opportunity to present this small booklet entitled as "Steam Tables in S.1. Units” to the students of Degree, Diploma and A.M.LE. (1) classes. The object of this booklet is to present the various properties of water and steam in a most concise, compact, to the point and lucid manner. ‘Although every care has been taken to check mistakes and misprints in the colossal figure work, yet itis difficult to claim perfection. Any errors, omissions and suggestions for the improvement of this booklet, brought to my notice, will be thankfully acknowledged and incorporated in the next edition, RS, KHURMI (iii) RULES FOR S.I. UNITS The International System of Units, abbreviated as S.1. Units, is a unified and systematically constituted system of fundamental and derived units for international use. This system of units isnow being used in many countries, and it is hoped that it will be used throughout the world very soon. In India, the Standard of Weights and Measures Act of 1956 (wide which we switched over to M.K.S. Units) has been revised to recognised all the S.1. Units in Science and Technology as well as Industry and Commerce. Though there are many rules for the style and usage of S.I. Units, yet the following are important from the subject point of view: 1. Foranumber, having 5 or more digits, the digits should be placed in groups of three, separated by space counting both to the left and right of the decimal point. 2 Ina four digit number, the space is not required, unless the four digit number is used in a column of numbers with 5 or more digits (iv) Introduction to Steam Tables and Mollier Diagram 1. Definition Steam is the vapour form of water and is invisible when pure and dry. It does not obey the laws of perfect gases, until it is perfectly dry. When the dry steam is further heated, it behaves more or less like a perfect gas. The steam is, generally, used as a working substance in the operation of steam engines and steam turbines. 2. Formation of steam ‘The formation of steam takes place, when we continuously heat the water from any temperature in the following stages: 1. The volume of water slightly increases with the increase in temperature, But this incfease is, generally, neglected for all types of calculations, On further heating, the temperature of water reaches the boiling point. The boiling tempera- . ture of pure steam at normal atmospheric pressure of 1.013 bar (1.013 x 10° N/m? or 1,013 X 10° kN/m? also known as 1,013 x 10° kPa) is 100°C (373 K). But it increases with the increase in pressure, 3. After boiling point, the temperature remains constant. But the Water starts evaporating and the volume of steam starts increasing. At this stage, the steam has some water particles in suspension and itis called wet steam. This process continues, till the whole water is converted into wet steam. 4. On further heating, the temperature of wet steam remains constant and all the water particles in suspension are converted into steam. At this stage, the steam is called dry saturated steam. 5. On further heating, the temperature of dry saturated steam starts increasing and it obeys the laws of perfect gases. At this stage, the steam is called superheated steam. As a matter fact, the supetheaied steam is used as a working substance in the operation of steam engines and steam turbines. 3. Properties of steam ‘Thel following properties of steam are always needed for the calculations of its various parameters, which are required in the operation of steam engines and steam turbines. re 1. Specific volume of steam. It is the volume occupied by the steam per unit mass at a given temperature and pressure. It is expressed in m’/kg and is the reciprocal of the density of steam, The specific volume of steam increases with the increase in temperature and decreases with the increase in pressure. 2. Specific enthalpy of steam. Itis the total heat absorbed by the steam per unit mass from the freezing point of water (0°C or 273 K) to the saturation temperature (100°C ot 373 K) plus the heat absorbed during evaporation. Itis expressed in kl/kg. The specific enthalpy of steam increases with the increase in temperature and pressure. 7) Introduction to Steam Tables and Mollier Diagram 1. Definition Steam is the vapour form of water and is invisible when pure and dry. It does not obey the laws of perfect gases, until itis perfectly dry. When the dry steam is further heated, it behaves more or less like a perfect gas. The steam is, generally, used as a working substance in the operation of steam engines and steam turbines. 2, Formation of steam ‘The formation of steam takes place, when we continuously heat the water from any temperature in the following stages: 1. ‘The volume of water slightly increases with the increase in temperature, But this increase is, generally, neglected for all types of calculations. 2. On further heating, the temperature of water reaches the boiling point. The boiling tempera ture of pure steam at normal atmospheric pressure of 1.013 bar (1.013 x 10° N/m? of 1.013 10? KN/m? also known as 1.013 x 10° kPa) is 100°C (373 K). But it increases with the increase in pressure. 3. After boiling point, the temperature remains constant, But the water starts evaporating and the volume of steam starts increasing. At this stage, the steam has some water particles in suspension and it is called wet steam. This process continues, till the whole water is converted into wet steam. 4. On further heating, the temperature of wet steam remains constant and all the water particles in suspension are converted into steam. At this stage, the steam is called dry saturated steam. 5. On further heating, the temperature of dry saturated steam starts increasing and it obeys the Jaws of perfect gases. At this stage, the steam is called superheated steam. As a matter fact, the superheated steam is used as a working substance in the operation of steam engines and steam turbines. 3. Properties of steam ‘Thel following properties of steam are always needed for the calculations of its various parameters, which are required in the operation of steam engines and steam turbines. 1. Specific volume of steam. It is the volume occupied by the steam per unit mass at a given temperature and pressure. It is expressed in m’/kg and is the reciprocal of the density of steam. The specific volume of steam increases with the increase in temperature and decreases with the increase in pressure. 2. Specific enthalpy of steam. Itis the total heat absorbed by the steam per unit mass from the freezing point of water (0°C or 273 K) to the saturation temperature (100°C or 373 K) plus the heat absorbed during evaporation. Itis expressed in kI/kg. The specific enthalpy of steam increases with the increase in temperature and pressure. (vy) 3. Specific entropy of steam, It is a theoretical value of heat energy, which can not be transformed into mechanical work under the given conditions of temperature or pressure. It is also called degree of disorder of the system. The most common term used is the change of entropy, which is mathematically given as : Ag Heat supplied = Ap 7 Temperature of the system It is expressed in ki/kg K. The specific entropy of steam decreases with an increase in temperature and pressure. 4, Steam tables ‘The various properties of steam (such as specific volume, specific enthalpy and specific entropy) of dry saturated steam and superheated steam vary with the variations of temperature and pressure. ‘These values were carefully determined by observations and calculations first in F.P.S. system and were made available in a tabular form known as steam tables. Later on, these values were converted into M.K.S. units and then into S.1. units, Due to conversion and rounding off the figures, there is a slight difference in the figures quoted in different books. Even some of the authors have changed these values in different editions of the same book. However, in this steam tables the author has quoted standard figures, which are widely accepted and internationally recognised. ‘There are two important steam tables. One of them is based in terms of temperature and the other in terms of pressure. It is a general practice to give the following tables for some important values: |. Saturated water and steam (temperature) table 2. Saturated water and steam (pressure) table 3. Superheated steam table 4, Supercritical steam table 5, Saturated water and steam (temperature) table It contains values of absolute pressure (in bar), specific volume (in m’/kg), specific enthalpy (in kJ/kg) and specific entropy (in kJ/kg K) from 0°C to 374.15°C (critical temperature). A sample of this table is given below: Specific volume Specific enthalpy Specitic entropy Tempe- | Absolute in mi/kg in kiikg in kitke K rature in | Pressure sc | imbar | Water | Steam | Water | Evapo- | Steam | Water | Evapora- © ® (hy ration (hg)} (2) | (5) | tion (5) 0 0.00611 0.0 | 2501.6 | 2501.6 | 0.000 | 9.158 | 9.158 5 |0.008 72 21.0 | 2489.7 | 2510.7 | 0.076 | 8951 | 9.027 10 |0.01227 420 | 24779 | 25199 | 0.151 | 8751 | 8902 ‘The use of this table is given in the following example, Example 1. Calculate the specific enthalpy and specific entropy of 1 kg of steam at 10°C when its dryness fraction is 0.8. (vi) Solution. Given: Mass of steam (m)= 1 kg; Temperature of steam (t)= 10°C and dryness fraction of steam (x) = 0.8. From steam tables, corresponding to a temperature of 10°C, we find that h,=42.0 ki/kg; Igy = 2477.9 ki/kg; 5,= 0.151 kI/kg K and sp, = 8.751 kJ/kg K. Specific enthalpy of the steam We know that specific enthalpy of the steam, h=m [hy+x hy | = 1% [42.0 + (0.8 x 2477.9)] = 2024.32 kJ Ans. Specific entropy of the steam We also know that specific entropy of the steam, 5 =m [s+ 5 1=1 X10.151 + (0.8 x8.751)] = 7.1518 ki/kg K Ans. 6. Staturated water and steam (pressure) tables Itcontains the values of temperature (in °C), specific volume (in m’/kg), specific enthalpy (in ki/kg) and specific entropy (in kI / kg K) from 0.0061 bar to 221.2 bar (critical pressure). A sample of this table is given below: Specific volume Specific enthalpy Specific entropy ‘Absolute | Tempe- inm/kg in ki/kg, in ki/kg K Pressure | rature in bar in°C Water | Steam | Water | Evapo- | Steam | Water | Evapora- | Steam 0) @ We) | Op | Gp |ration (iy)| Hy) | GP | Hon (sy) | (S,) 0.010 6.98 | 0.001 000) 129.21 29.3 2485.0 | 2514.4 | 0.106 8.871 8.977 0.020 17.51 |0.001 001| 67.012 | 73.5 2460.2 | 2533.6 | 0.261 8.464 8.725 0.030 24.10 {0.001 003) 45.670 | 101.0 | 2444.6 | 2545.6 | 0.354 8.224 8.578 ‘The use of this table is given in the following example. Example 2. What is the specific enthalpy and specific entropy of 1.5 kg of steam at a pressure of 0.030 bar, when its dryness fraction is 0.6? Solution. Given: Mass of steam (m)= 1.5 kg; Pressure of steam = 0,030 bar and dryness fraction of steam (x) = 0.6. From steam tables, corresponding to a pressure of 0.030 bar, we find that y= 101 ki/kg; Ing, = 2444.6 ilk: s,= 0.354 kifkg K and sy, = 8.224 ki/kg K. Specific enthalpy of the steam We know that specific enthalpy of the steam, =m [hy +X hy ]=1 [101 + (0.6 x 2444.6)] = 1567.76 kJ Ans. Specific entropy of the steam We also know that specific entropy of the steam, sm [sy +2 5p = 15 [0.354 + (0.6 x 8,224)] = 7.9326 ki/kg K Ans. (vii) 7. Superheated steam tables These tables contain the values of specific volume, specific enthalpy and specific entropy of superheated steam from an absolute pressure of 0.02 bar to 221.2 bar (critical pressure) at various temperatures from 100°C to 800°C. In these tables, the values of specific volume, specific enthalpy and specific entropy of steam are directly read from the concerned tables. However, the value at any other pressure or temperature, not mentioned in the tables, is obtained by interpolation. 8. Supercritical steam tables ‘These tables also contain the values of specific volume, specific enthalpy and specific entropy of supercritical steam from an absolute pressure of 250 bar to 1000 bar at various temperatures from 400°C to 800°C. In these tables also, the values of specific volume, specific enthalpy and specific ‘entropy of steam are directly read from the concerned tables. However, the value at any other pressure or temperature, not mentioned in the table, is obtained by interpolation. 9, Mollier diagram It is a graphical representation of steam tables, in which specific entropy is plotted along the ordinate (X-axis) and specific enthalpy along the abscissa (Y-axis). The diagram is divided into two portions by a somewhat horizontal line termed as saturation curve. The lower portion (i.e., wet steam region) contains the values of wet steam, whereas the upper portion (i.e., superheated steam region) contains the values of superheated steam, A Mollier diagram has the following lines. 1. Dryness fraction lines 2. Constant specific volume lines 3. Constant pressure lines 4. Constant temperature lines 10, Dryness fraction lines ‘These lines are drawn in the wet steam region. ive., only below the saturation curve (which represents dryness fraction equal to unity). These lines represent the condition of wet steam between various values of enthalpy and entropy. The dryness fraction lines are slightly curved in horizontal direction, 11. Constant specific volume lines ‘These lines are drawn in both the wet steam region and superheated steam region. These lines represent the specific volume of steam between the various values of enthalpy and entropy. The lines are straight in the wet steam region, i., below the saturation curve, but are curved upwards in the superheated region i.e., above the saturation curve. 12. Constant pressure lines These lines are also drawn in botl the wet steam region and superheated steam region, These lines represent the pressure of steam between the various values of enthalpy and entropy. The pressure lines are also straight in the wet steam region, i.e., below the saturation curve, but are curved slightly upwards in the superheated region ie., above the saturation curve. 13. Constant temperature lines ‘These lines are drawn only in the superheated steam region i.e., above the saturation curve. ‘These lines represent the temperature of steam between the various values of enthalpy and entropy ‘The temperature lines are slightly curved in the horizontal direction. (viii) CONTENTS Preface Rules for S.I. Units Introduction to Steam Tables and Mollier Diagram Saturated Water and Steam (Temperature) Tables Saturated Water and Steam (Pressure) Tables Specific Volume of Superheated Steam Specific Enthalpy of Superheated Steam Specific Entropy of Superheated Steam 1-14 1S—17 18—20 21-23 6t 1698 60r'8 pose LOShT L6L Ir€19 700 1000 or 8I vIL8 OFFS SvEsz OeShZ = SSL | L80'S9 100 1000 81 ut SELB srs Lest PI9PT el $6069 100 1000 at or 6SL8 —O7SR 60ST REPT 119 | HEEL 1001000 or st €8L8 SSR Vest T99PT «= -6TD | SLELL 1001000 st +r 908°8 LOSS TLEST S89rT Les 00678 100 100°0 +1 er O€8'8 seo's VStST SOLbT ors OLT'88 100 100°0 ca4 a S88 £198 VECST Tele vos SE8"E6 000 1000 a I $L8'°8 als LIST CSLeT Tor 606°66 000 100°0 aus or 268 © ISLB 66ST GLLeT Ot | F901 000 1000 ol 6 M68 16L'B vest cosrz size | Pret! 0001000 6 8 1s68 Of8'8 TOISZ «—9TBPZ «NEE | LOO! 000 1000 8 L 9168 OLR yrIStT OSBPZ «Vee | «906ZI 000 1000 t 9 2006 = «1168 9TIStT Perc «TST | «BLLET © 0001000 9 s L006 1668 LOST L687 Olt OVlrl = =—000 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