METODO UNIFAC PARA COEFICIENTES DE ACTIVID

Compuestos Metanol A
Acetona B
PARAMETROS GENERALES PARAMETROS DE LAS SUSTANCIAS PURAS
Temperatura de la Volumen funcional relativo Area funcional relativa
mezcla 500 K (Rx) (Qx)
Composición de la x (A) 1 CH3 0.9011
mezcla X(B) 0 CH3CO 1.6724
R=
Numero de Q=
componentes NC 2 OH 1
Formulas X1 CH3-OH
moleculares X2 CH3CO
Numero de grupos NG 3

EVALUACION
Area parcial de grupo funcional
Volumenes moleculares relativos (ri) Area molecular relativa (qi) (eki)
1.9011 2.048 0.41406 0.36301
r q
2.5735 2.336 0.00000 0.63699
eki
0.58594 0.00000

Coeficiente de actividad Coeficientes de actividad Coeficiente de

residual combinatorio actividad UNIFAC
gamma
Ln gamma1R 0.00000 Ln gamma1C 0.00000 1 1.00000
gamma
Ln gamma2R 0.51450 Ln gamma2C 0.13064 2 1.90625

GAMMA
FRACCION METHA FRACCION AC PHI SK J L R X1
0.4140625 0.8426149476 1 1
0 0.6550117168 1.35368997 1.140625
1 0 0.5859375 0.6435083826 - - 0
0.4083204931 0.8565839053 0.96583924 0.9861325116
0.0716486903 0.6687314791 1.30744688 1.124807396
0.9 0.1 0.5200308166 0.6283648153 - - 0.0056146
0.4027355623 0.8701707334 0.93393529 0.9726443769
0.141337386 0.6820759288 1.26425884 1.1094224924
0.8 0.2 0.4559270517 0.6136355097 - - 0.0219012
0.3973013493 0.8833909005 0.90407168 0.9595202399
0.2091454273 0.6950602584 1.22383276 1.0944527736
0.7 0.3 0.3935532234 0.5993036967 - - 0.0481127
0.3920118343 0.8962590514 0.90407168 0.9467455621
0.275147929 0.7076988514 1.30744688 1.0798816568
0.6 0.4 0.3328402367 0.5853534999 - - 0.0836069
0.3868613139 0.908789061 0.84972958 0.9343065693
0.3394160584 0.7200053354 1.15027042 1.0656934307
0.5 0.5 0.1278308
0.5 0.5 0.2737226277 0.5717698777 - - 0.1278308
0.3818443804 0.9209940848 0.84972958 0.9221902017
0.4020172911 0.7319926311 1.35368997 1.0518731988
0.4 0.6 0.2161383285 0.5585385685 - - 0.180308
0.3769559033 0.6922463276 0.80154989 0.9103840683
0.2091454273 0.4898027774 1.08505005 1.0384068279
0.3 0.7 0.1600284495 0.36295011 - - 0.8083118
0.3721910112 0.9444784705 0.7794524 0.8988764045
0.5224719101 0.7550580735 1.0551369 1.0252808989
0.2 0.8 0.1053370787 0.5330794481 - - 0.3084414
0.3675450763 0.9557809418 0.75854061 0.8876560333
0.580443828 0.7661589175 1.02682882 1.012482663
0.1 0.9 0.0520110957 0.5208265844 - - 0.3834443
0.3630136986 0.9668047221 0.73872159 0.8767123288
0.6369863014 0.7769860421 1 1
0 1 0 0.5088758461 - - 0.465381
S DE ACTIVIDAD

STANCIAS PURAS PARAMETROS DE LAS SUSTANCIAS EN MEZCLA

Area funcional relativa Matriz de frecuencia de grupos
(Qx) secundarios (vx) para cada compuesto Matriz de parametros de energía (amk)
0.848 1 1 CH2 0
1.488 0 1 CH3CO 26.76
v= a=
1.2 1 0 OH 156.4

EVALUACION DE LOS PARAMETROS DE LA MEZCLA

Energia parcial por grupo Area Fraccional por
Energia funcional por interaccion de grupos funcionales funcional en cada especie grupo funcional
1.00000 0.38566 0.13904 0.84261 0.96680
0.94789 1.00000 0.71964 0.65501 0.77699
beta Phi o
0.73140 0.84535 1.00000 0.64351 0.50888
Tau theta

GAMMA C GAMMA
GAMMA R X2 GAMMA C X1 X2 GAMMA X1 X2

0.5144989219 0 0.130638193 1 1.9062484

0.4070789092 0.0016013179 0.099732788 1.007242055 1.6599902

0.3145650084 0.0060477543 0.074393735 1.028343157 1.4754437

0.2358088407 0.0128682057 0.05385594 1.062878619 1.3359796

0.1698121778 0.0058074984 0.188468845 1.093533728 1.4308677

0.1157050136 0.0321068352 0.02467288 1.173437643 1.1507086

0.1157050136 0.0321068352 0.02467288 1.173437643 1.1507086

0.0727274952 0.0208039237 0.354102127 1.222761653 1.5323916

0.7769052907 0.0568253283 0.008017666 2.375331831 2.192238

0.0175854039 0.0706578413 0.003391648 1.460968039 1.0211986

0.0043291585 0.0852298417 0.000807947 1.597874252 1.0051503

0 0.1003923968 0 1.760809082 1
MEZCLA

z de parametros de energía (amk)

476.4 986.5
0 164.5

84 0

Energia fraccional
Area Fraccional por por grupo funcional Volumen fraccional Area fraccional evaluada en
grupo funcional (sk) Evaluado en reparto (Ji) reparto (Li)
0.41406 0.84261 1.00000 1.00000
J L
0.00000 0.65501 1.35369 1.14063
sk
0.58594 0.64351
 ANALISIS DE PRESION

Temperatura (K) 500 K

Constantes de Antoine

COMPUESTO A B C Kpa
CH3-OH 16.5785 3638.27 239.5
CH3CO 14.3145 2756.22 228.06

φi 1 1 1 1 1
°C 226.85 226.85 226.85 226.85 226.85
T
K 500 500 500 500 500

Xac 0.00 0.10 0.20 0.30 0.40

xMetha 1 0.9 0.8 0.7 0.60

KPa 6482.84 6482.84 6482.84 6482.84 6482.84

Pmetha
Bar 64.828 64.828 64.828 64.828 64.828

Kpa 3849.41 3849.41 3849.41 3849.41 3849.41

P Acetona
Bar 38.494 38.494 38.494 38.494 38.494

Gamma de Unifac GamAC 2.57 1.659990198 1.47544368 1.33597957 1.43086767

Gamm Met 0.87 0.8972420553 0.93834316 0.99287862 0.94353373

Kpa 5640.07 5874.00 6002.42 6048.49 5873.26

P0
Bar 56.401 58.740 60.024 60.485 58.733

Yace y1 0 0.1087841212 0.18924337 0.25507532 0.37512345

Ymetha y2 1 0.8912158788 0.81075663 0.74492468 0.62487655

Tc Vc
Para ij ω Pc bar Zc Kjj
K cm3/mol

Acetona 11 0.307 508.2 47.01 0.2330 209 0

Methanol 22 0.564 512.6 80.97 0.2240 118 0
Mezcla 12 0.4355 510.4 60.9 0.2285 159.2 0

par T.reida(K) B0 B1 B^ij Bij d1,2

1.1 0.98386462 -0.35012764 -0.045161992 -0.36399237 -327.149841
2.2 0.97541943 -0.35614325 -0.051952152 -0.38544426 -202.873847
1.2 0.97963292 -0.35312507 -0.048526341 -0.37425829 -260.737677 8.54833447
 PHI ACET 0.87868924 0.861941884 0.85262866 0.84891273 0.85922261
φi
PHI METHA 0.76261192 0.755046573 0.75124732 0.75038725 0.75767768

Kpa 6419.78205 6709.4994843 6837.63114 6850.39479 6474.57607

PR 1
Bar 64.1978205 67.094994843 68.3763114 68.5039479 64.7457607

TOL DIFERENCIA 779.715512 835.49613214 835.214442 801.906996 601.31338

TOL % 13.82458 14.223623686 13.9146361 13.2579749 10.2381489

298 K

GAMMA 1 GAMMA P.BUBLE X acetone

2.57 0.95 16.8083565 0 35
2.2588099768 1.16136347 21.2864154 0.1
30
1.8775642982 1.44480304 24.8194794 0.2
1.6054642697 1.10067965 27.521719 0.3 25
1.6378751841 0.96245279 29.5977345 0.4
1.2645855795 1.33967884 30.4483551 0.5 20
1.6287968744 0.2498171 31.4392699 0.6
2.4202047564 -3.96523743 31.7318253 0.7 15
1.0374230539 1.85934448 31.4952307 0.8 10
1.0092089008 1.67367762 30.4632294 0.9
0.86 0.08726218 26.1971374 1 5

0
0 0.1 0.2 0.3 0.4 0.5

328 K

GAMMA 1 GAMMA P.BUBLE X acetone

2.57 0.999 68.2312271 0 120
2.1119806988 1.02846349 80.0095692 0.1
1.781136455 1.14121574 90.5412406 0.2 100
1.5418907453 1.10241065 97.1731399 0.3
1.5895704105 0.98923791 101.8982 0.4 80
1.2381669123 1.31364194 104.62586 0.5
1.6064539623 0.45936602 105.770035 0.6 60
2.365515104 -2.71991158 104.645957 0.7
1.0336182068 1.77314876 104.146019 0.8 40
1.0082449534 1.72959323 99.5481548 0.9
0.86001 -0.12820911 82.2041449 1 20

0
0 0.1 0.2 0.3 0.4 0

500 K

GAMMA 1 GAMMA P.BUBLE X acetone

2.57 0.87 6419.78205 0 8000
1.659990198 0.89724206 6709.49948 0.1
7000
6000
5000
4000
 8000
7000
1.4754436779 0.93834316 6837.63114 0.2
1.3359795666 0.99287862 6850.39479 0.3 6000
1.4308676708 0.94353373 6474.57607 0.4 5000
1.1507085618 1.02343764 5976.15636 0.5
1.5323915543 0.62276165 5322.89125 0.6 4000
2.1922380366 -0.52466817 4797.64974 0.7 3000
1.0211986168 0.76096804 4151.5562 0.8
1.0051503235 0.59787425 3870.22052 0.9 2000
0.86001 -0.73919092 3310.53112 1 1000
0
0 0.1 0.2 0.3 0.4
DONDE i Acetona 1
j Methanol 2

1 1 1 1 1 1 PASO 1
226.85 226.85 226.85 226.85 226.85 226.85
500 500 500 500 500 500

0.50 0.60 0.70 0.80 0.90 1.00

0.5 0.4 0.3 0.2 0.1 0

6482.84 6482.84 6482.84 6482.84 6482.84 6482.84 PASO 2

64.828 64.828 64.828 64.828 64.828 64.828

3849.41 3849.41 3849.41 3849.41 3849.41 3849.41

38.494 38.494 38.494 38.494 38.494 38.494 PASO 3

1.15070856 1.53239155 2.19223804 1.02119862 1.00515032 0.86001

1.02343764 0.62276165 -0.52466817 0.76096804 0.59787425 -0.73919092 PASO 4

5532.16 5154.19 4886.77 4131.46 3869.90 3310.53 PASO 5

55.322 51.542 48.868 41.315 38.699 33.105

0.40034511 0.68668102 1.20880871 0.76118683 0.89984454 1

0.59965489 0.31331898 -0.20880871 0.23881317 0.10015546 0 PASO 6

R
cm3*bar/m
ol*k

83.14
 0.88196011 0.90541384 0.9196727 0.98003433 0.99918451 1.04332109
0.77071487 0.78566707 0.79540632 0.82576374 0.83628652 0.8535395 PASO 7

5976.15636 5322.89125 4797.64974 4151.5562 3870.22052 3310.53112

59.7615636 53.2289125 47.9764974 41.515562 38.7022052 33.1053112

443.993079 168.704753 89.1252636 20.1003719 0.31633699 0

8.02566838 3.27315965 1.82380535 0.48652031 0.00817428 0

6419.78205 6709.49948 6837.63114 6850.39479 6474.57607 5976.15636 5322.89125 4797.64974

0.87 0.89724206 0.93834316 0.99287862 0.94353373 1.02343764 0.62276165 -0.52466817

P.BUBLE

P.BUBL
E

0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

P.BUBLE

P.BUBL
E

0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

P.BUBLE
00
00
00
00
00 P.BUBL
 P.BUBLE
00
00
00
00
00 P.BUBL
E
00
00
00
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
 4151.5562 3870.22052 3310.53112
0.76096804 0.59787425 -0.73919092
 T 500 500 500 500 500 500
226.85 226.85 226.85 226.85 226.85 226.85
Y AC 0 0.1 0.2 0.3 0.4 0.5
YMT 1 0.9 0.8 0.7 0.6 0.5

φi ac 1 1 1 1 1 1
GAMMA AC 1 1 1 1 1 1

COMPUESTOA B C
CH3-OH 16.5785 3638.27 239.5
CH3CO 14.3145 2756.22 228.06

Kpa 3849.41003 3849.41003 3849.41003 3849.41003 3849.41003 3849.41003

Psat Ac Bar 38.4941003 38.4941003 38.4941003 38.4941003 38.4941003 38.4941003
kpa 6482.8351 6482.8351 6482.8351 6482.8351 6482.8351 6482.8351
P sat Met Bar 64.828351 64.828351 64.828351 64.828351 64.828351 64.828351

Kpa 6482.8351 6067.7345 5702.59334 5378.90427 5089.98776 4830.52621

Pinicial Bar 64.828351 60.677345 57.0259334 53.7890427 50.8998776 48.3052621

X ace 0 0.15762765 0.29628402 0.41919964 0.52891095 0.62743721

x xmet 1 0.84237235 0.70371598 0.58080036 0.47108905 0.37256279

Gamma Ac 2.57828055 1.90807228 1.54949946 1.33891216 1.42683251 1.12374403

Gamma
Gamma Met 1 1.92573059 1.09012877 1.18235793 1.26854044 1.4320711

Po Kpa 6482.8351 11667.8013 6815.19052 6687.58559 6859.34164 5901.66737

Bar 64.828351 116.678013 68.1519052 66.8758559 68.5934164 59.0166737

PHI ACET 0.87868924 0.86194188 0.85262866 0.84891273 0.85922261 0.88196011

φi
PHI METHA 0.76261192 0.75504657 0.75124732 0.75038725 0.75767768 0.77071487

X ace 0 0.13692351 0.19484188 0.33045125 0.42922099 0.60163364

x xmet 0.76261192 0.63510389 0.579573 0.45828843 0.37918303 0.24496775

X ace 0 0.17735576 0.25159884 0.4189611 0.53094861 0.7106457

xNormali
xmet 1 0.82264424 0.74840116 0.5810389 0.46905139 0.2893543

Gam Ac 2.57828055 1.84678338 1.6482705 1.33924846 1.40601462 1.07224386

nuevo Gamm Gam Met 0.76 0.75248953 0.77501416 0.83214373 0.79037791 0.97445399

Kpa 6460.63164 6603.95051 6826.18781 6813.42288 6569.26144 5958.04075

P Bar 64.6063164 66.0395051 68.2618781 68.1342288 65.6926144 59.5804075

TOL %< 5% 0.34249605 43.4002145 -0.16136442 -1.88165498 4.22898017 -0.95521095

6460.63164 6603.95051 6826.18781 6813.42288

 0.76 0.75248953 0.77501416 0.83214373
298 K

GMMA 1 GAMMA2 P.ROCIO Y ACETO

2.57828055 1 16.2050494 0 P.ROCIO
2.33975856 1.05231595 18.3703547 0.1 35
2.2725533 1.05398748 19.8641166 0.2
2.05263368 1.0439499 21.63112 0.3 30
1.99925582 1.03683704 23.750628 0.4 25
1.55760435 1.13775927 26.382985 0.5
1.75879866 0.97661407 28.0492605 0.6 20
3.41578779 0.6068577 31.3834365 0.7
1.05566954 1.79635124 31.3168099 0.8 15
1.00929774 2.01124491 30.8568145 0.9 10
0.86 1.37179089 26.1419706 1
5

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7

328 K

GMMA 1 GAMMA2 P.ROCIO Y ACETO

2.57828055 1 67.3494996 0
120
P.ROCIO
2.26751843 1.01413472 73.5756859 0.1
2.17380454 1.0175046 79.4899405 0.2
1.91011018 1.01552621 84.7028329 0.3 100
1.86779283 1.01696909 91.8354949 0.4
1.4016161 1.13707273 98.0818177 0.5 80
1.68477168 0.9836232 104.554807 0.6
3.27836281 0.5485004 106.186213 0.7 60
1.03075627 1.93834929 100 0.8
1.00506781 1.89601774 90.6265233 0.9 40
0.86 1.37179089 82.8116078 1
20

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8

500 K

GMMA 1 GAMMA2 P.ROCIO Y ACETO

2.57828055 0.76 6460.63164 0 P.ROCIO
1.84678338 0.75248953 6603.95051 0.1 8000
1.6482705 0.77501416 6826.18781 0.2
1.33924846 0.83214373 6813.42288 0.3 7000
1.40601462 0.79037791 6569.26144 0.4 6000
1.07224386 0.97445399 5958.04075 0.5
5000
1.59523829 0.47615887 5255.56757 0.6
2.24530294 3.66053645 4728.81872 0.7 4000
1.00307551 0.85212629 4292.83149 0.8 3000
2000
1000
0
 5000
4000
3000
1.00051634 0.4774812 3838.65912 0.9
0.9 2.37179089 3320.6163 1 2000
1000
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8
 500 500 500 500 500
226.85 226.85 226.85 226.85 226.85
0.6 0.7 0.8 0.9 1
0.4 0.3 0.2 0.1 0

1 1 1 1 1
1 1 1 1 1

3849.41003 3849.41003 3849.41003 3849.41003 3849.41003

38.4941003 38.4941003 38.4941003 38.4941003 38.4941003
6482.8351 6482.8351 6482.8351 6482.8351 6482.8351
64.828351 64.828351 64.828351 64.828351 64.828351

4596.23372 4383.61742 4189.80216 4012.39974 3849.41003

45.9623372 43.8361742 41.8980216 40.1239974 38.4941003

0.71640595 0.7971435 0.87074167 0.93810733 1

0.28359405 0.2028565 0.12925833 0.06189267 0

1.5934031 2.01735633 1.01383771 1.00314412 1

1.5479838 2.8719681 1.94470994 2.14988346 2.37179089

7263.21643 9411.43015 8411.70746 4205.46375 3861.51303

72.6321643 94.1143015 84.1170746 42.0546375 38.6151303

0.90541384 0.9196727 0.98003433 0.99918451 1.04332109

0.78566707 0.79540632 0.82576374 0.83628652 0.8535395

0.64329108 0.78020758 1.68986815 0.97936502 1.04660142

0.22745534 0.12062056 0.11019202 0.02523417 0

0.73878119 0.86610037 0.93878426 0.97488135 1

0.26121881 0.13389963 0.06121574 0.02511865 0

1.59523829 2.24530294 1.00307551 1.00051634 0.9

0.47615887 3.66053645 0.85212629 0.4774812 2.37179089

5255.56757 4728.81872 4292.83149 3838.65912 3320.6163

52.5556757 47.2881872 42.9283149 38.3865912 33.206163

27.6413195 49.7545151 48.9659916 8.72209701 14.0073782

6569.26144 5958.04075 5255.56757 4728.81872 4292.83149 3838.65912 3320.6163

 0.79037791 0.97445399 0.47615887 3.66053645 0.85212629 0.4774812 2.37179089

P.ROCIO

0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

P.ROCIO

0.4 0.5 0.6 0.7 0.8 0.9 1

P.ROCIO
0.4 0.5 0.6 0.7 0.8 0.9 1
METODO UNIFAC PARA COEFICIENTES DE ACTIVID
Compuestos Metanol A
Acetona B
PARAMETROS GENERALES PARAMETROS DE LAS SUSTANCIAS PURAS
Temperatura de la Volumen funcional relativo Area funcional relativa
mezcla 328 K (Rx) (Qx)
Composición de la x (A) 1 CH3 0.9011
mezcla X(B) 0 CH3CO 1.6724
R=
Numero de Q=
componentes NC 2 OH 1
Formulas X1 CH3-OH
moleculares X2 CH3CO
Numero de grupos NG 3

EVALUACION
Area parcial de grupo funcional
Volumenes moleculares relativos (ri) Area molecular relativa (qi) (eki)
1.9011 2.048 0.41406 0.36301
r q
2.5735 2.336 0.00000 0.63699
eki
0.58594 0.00000

Coeficiente de actividad Coeficientes de actividad Coeficiente de

residual combinatorio actividad UNIFAC
gamma
Ln gamma1R 0.00000 Ln gamma1C 0.00000 1 1.00000
gamma
Ln gamma2R 0.81648 Ln gamma2C 0.13064 2 2.57828

GAMMA
FRACCION METHA FRACCION AC PHI SK J L R X1
0.4140625 0.7777823252 1 1
0 0.5504447125 1.35368997 1.140625
1 0 0.5859375 0.6063959291 - - 0
0.4050832671 0.8080912219 0.94719276 0.9783143055
0.1120427549 0.5806083229 1.28220533 1.1158897547
0.8423723519 0.1576276481 0.482873978 0.5707426032 - - 0.0215567
0.3975006589 0.8336858903 0.9051472 0.9600015914
0.2066584445 0.6060803027 1.22528868 1.0950018152
0.7037159829 0.2962840171 0.3958408965 0.5406347751 - - 0.0737187
0.3910123425 0.8555868384 0.87087782 0.944331695
0.2876195757 0.6278762682 1.17889856 1.0771283396
0.5808003648 0.4191996352 0.3213680818 0.5148719884 - - 0.143958
0.3853973748 0.8745398466 0.87087782 0.9307710184
0.3576830713 0.6467384247 1.28220533 1.0616606929
0.471089054 0.528910946 0.2569195538 0.4925769579 - - 0.2248425
0.3804905417 0.8911025864 0.81838536 0.9189205536
0.4189104729 0.6632217706 1.10784005 1.0481437565
0.3725627861 0.6274372139 0.3117726
0.3725627861 0.6274372139 0.2005989854 0.4730936767 - - 0.3117726
0.3761658292 0.9057004107 0.81838536 0.9084759649
0.4728741812 0.6777496201 1.35368997 1.0362303975
0.2835940544 0.7164059456 0.1509599896 0.4559217884 - - 0.4018126
0.3723254483 0.7037568796 0.7800667 0.8992010828
0.2876195757 0.4574756421 1.05596847 1.0256512351
0.2028564981 0.7971435019 0.1068801462 0.2994607513 - - 0.9847459
0.3688923518 0.9302516257 0.76454201 0.8909098307
0.5636325412 0.7021831483 1.03495285 1.0161940257
0.1292583289 0.8707416711 0.067475107 0.427041408 - - 0.5842138
0.3658050115 0.9406727695 0.75086397 0.8834536127
0.6021563344 0.7125543381 1.01643703 1.007689277
0.0618926701 0.9381073299 0.0320386541 0.4147826827 - - 0.674468
0.3630136986 0.9500946895 0.73872159 0.8767123288
0.6369863014 0.721931094 1 1
0 1 0 0.4036993765 - - 0.7632529
S DE ACTIVIDAD

STANCIAS PURAS PARAMETROS DE LAS SUSTANCIAS EN MEZCLA

Area funcional relativa Matriz de frecuencia de grupos
(Qx) secundarios (vx) para cada compuesto Matriz de parametros de energía (amk)
0.848 1 1 CH2 0
1.488 0 1 CH3CO 26.76
v= a=
1.2 1 0 OH 156.4

EVALUACION DE LOS PARAMETROS DE LA MEZCLA

Energia parcial por grupo Area Fraccional por
Energia funcional por interaccion de grupos funcionales funcional en cada especie grupo funcional
1.00000 0.23400 0.04941 0.77778 0.95009
0.92165 1.00000 0.60561 0.55044 0.72193
beta Phi o
0.62075 0.77407 1.00000 0.60640 0.40370
Tau theta

GAMMA C GAMMA
GAMMA R X2 GAMMA C X1 X2 GAMMA X1 X2

0.8164845304 0 0.130638193 1 2.5782805

0.5615906593 0.003848416 0.084502798 1.025730589 1.9080723

0.3833907884 0.0125771316 0.054541162 1.090128771 1.5494995

0.2571090865 0.0235527063 0.034748376 1.182357926 1.3389122

0.1672964365 0.0130244989 0.18816052 1.268540438 1.4268325

0.1038399735 0.0473491607 0.012826016 1.4320711 1.123744

0.1038399735 0.0473491607 0.012826016 1.4320711 1.123744

0.0598604029 0.0351406999 0.406011638 1.547983799 1.5934031

0.6982938135 0.0702516898 0.003494094 2.871968101 2.0173563

0.0123738982 0.0808990039 0.001368945 1.944709936 1.0138377

0.0028352409 0.0909455934 0.000303945 2.149883463 1.0031441

0 0.1003923968 0 2.371790886 1
MEZCLA

z de parametros de energía (amk)

476.4 986.5
0 164.5

84 0

Energia fraccional
Area Fraccional por por grupo funcional Volumen fraccional Area fraccional evaluada en
grupo funcional (sk) Evaluado en reparto (Ji) reparto (Li)
0.41406 0.77778 1.00000 1.00000
J L
0.00000 0.55044 1.35369 1.14063
sk
0.58594 0.60640
METODO UNIFAC PARA COEFICIENTES DE ACTIVID
Compuestos Metanol A
Acetona B
PARAMETROS GENERALES PARAMETROS DE LAS SUSTANCIAS PURAS
Temperatura de la Volumen funcional relativo Area funcional relativa
mezcla 328 K (Rx) (Qx)
Composición de la x (A) 1 CH3 0.9011
mezcla X(B) 0 CH3CO 1.6724
R=
Numero de Q=
componentes NC 2 OH 1
Formulas X1 CH3-OH
moleculares X2 CH3CO
Numero de grupos NG 3

EVALUACION
Area parcial de grupo funcional
Volumenes moleculares relativos (ri) Area molecular relativa (qi) (eki)
1.9011 2.048 0.41406 0.36301
r q
2.5735 2.336 0.00000 0.63699
eki
0.58594 0.00000

Coeficiente de actividad Coeficientes de actividad Coeficiente de

residual combinatorio actividad UNIFAC
gamma
Ln gamma1R 0.00000 Ln gamma1C 0.00000 1 1.00000
gamma
Ln gamma2R 0.81648 Ln gamma2C 0.13064 2 2.57828

GAMMA
FRACCION METHA FRACCION AC PHI SK J L R X1
0.4140625 0.7777823252 1 1
0 0.5504447125 1.35368997 1.140625
1 0 0.5859375 0.6063959291 - - 0
0.4039868049 0.8117922686 0.9409737 0.9756662458
0.1257243969 0.5842916286 1.27378666 1.1128693116
0.8226442384 0.1773557616 0.4702887982 0.5663889434 - - 0.0271555
0.3999131387 0.8255427002 0.91828378 0.9658279577
0.1765555519 0.5979761471 1.24307154 1.1016475142
0.7484011642 0.2515988358 0.4235313093 0.5502138705 - - 0.0536909
0.3910247287 0.8555450294 0.87094181 0.9443616089
0.2874650206 0.6278346596 1.17898519 1.0771624602
0.5810388973 0.4189611027 0.3215102507 0.5149211697 - - 0.1438006
0.3852946131 0.8748867131 0.87094181 0.9305228392
0.3589653309 0.6470836285 1.27378666 1.0613776134
0.4690513876 0.5309486124 0.255740056 0.4921689278 - - 0.226504
0.3764428524 0.9047653347 0.79913805 0.9091450019
0.4694174901 0.6768190263 1.08178516 1.0369935178
0.2893543 0.7106457 0.3956508
 0.2893543 0.7106457 0.1541396576 0.4570217482 - - 0.3956508
0.3750936103 0.9093196257 0.79913805 0.905886455
0.4862533159 0.6813514862 1.35368997 1.0332767377
0.2612188074 0.7387811926 0.1386530739 0.4516643899 - - 0.4261854
0.3691069808 0.6774645663 0.76550276 0.89142818
0.2874650206 0.4279727703 1.03625341 1.0167852679
0.1338996315 0.8661003685 0.0699386161 0.2622666003 - - 1.2146573
0.3657742505 0.9407766015 0.75072901 0.883379322
0.6025401696 0.7126576724 1.01625433 1.0076045392
0.0612157446 0.9387842554 0.0316855799 0.4146605418 - - 0.6754085
0.3641413788 0.9462882683 0.74360181 0.8794357828
0.6229151221 0.7181429189 1.00660632 1.0031064398
0.0251186486 0.9748813514 0.0129434991 0.4081769916 - - 0.7265345
0.3630136986 0.9500946895 0.73872159 0.8767123288
0.6369863014 0.721931094 1 1
0 1 0 0.4036993765 - - 0.7632529
S DE ACTIVIDAD

STANCIAS PURAS PARAMETROS DE LAS SUSTANCIAS EN MEZCLA

Area funcional relativa Matriz de frecuencia de grupos
(Qx) secundarios (vx) para cada compuesto Matriz de parametros de energía (amk)
0.848 1 1 CH2 0
1.488 0 1 CH3CO 26.76
v= a=
1.2 1 0 OH 156.4

EVALUACION DE LOS PARAMETROS DE LA MEZCLA

Energia parcial por grupo Area Fraccional por
Energia funcional por interaccion de grupos funcionales funcional en cada especie grupo funcional
1.00000 0.23400 0.04941 0.77778 0.95009
0.92165 1.00000 0.60561 0.55044 0.72193
beta Phi o
0.62075 0.77407 1.00000 0.60640 0.40370
Tau theta

GAMMA C GAMMA
GAMMA R X2 GAMMA C X1 X2 GAMMA X1 X2

0.8164845304 0 0.130638193 1 2.5782805

0.5337597896 0.0048173869 0.079685621 1.032489532 1.8467834

0.4364861027 0.0092971811 0.063240454 1.065014163 1.6482705

0.2573272399 0.0235289064 0.034781367 1.182143729 1.3392485

0.1658225837 0.0128104058 0.174936609 1.270377907 1.4060146

0.0623343088 0.0582577204 0.007419206 1.574453993 1.0722439

0.0623343088 0.0582577204 0.007419206 1.574453993 1.0722439

0.050735198 0.0538668658 0.416287927 1.616158872 1.5952383

0.8073681495 0.0802168584 0.001472302 3.650536449 2.2453029

0.0027735566 0.0910478537 0.000297237 2.152126293 1.0030755

0.0004670043 0.0965355461 4.92016E-05 2.2774812 1.0005163

0 0.1003923968 0 2.371790886 1
MEZCLA

z de parametros de energía (amk)

476.4 986.5
0 164.5

84 0

Energia fraccional
Area Fraccional por por grupo funcional Volumen fraccional Area fraccional evaluada en
grupo funcional (sk) Evaluado en reparto (Ji) reparto (Li)
0.41406 0.77778 1.00000 1.00000
J L
0.00000 0.55044 1.35369 1.14063
sk
0.58594 0.60640
 Kpa 1000 1000 1000 1000 1000 1000
PRESION
Bar 10 10 10 10 10 10

Xi Acet 0 0.1 0.2 0.3 0.4 0.5

x Xj Met 1 0.9 0.8 0.7 0.6 0.5

PHI Acet 1 1 1 1 1 1

A B C
MATH 16.5785 3638.27 239.5
ACET 14.3145 2756.22 228.06

K 417.212991 417.212991 417.212991 417.21299111 417.212991 417.212991

T sat Acet
C 144.062991 144.062991 144.062991 144.06299111 144.062991 144.062991
K 409.864046 409.864046 409.864046 409.86404607 409.864046 409.864046
T sat Meth
C 136.714046 136.714046 136.714046 136.71404607 136.714046 136.714046

K 409.864046 410.598941 411.333835 412.06872958 412.803624 413.538519

T0 C 136.714046 137.448941 138.183835 138.91872958 139.653624 140.388519

Kpa 861.379173 874.565214 887.898972 901.38139143 915.013416 928.795989

Psat Acet
Bar 8.61379173 8.74565214 8.87898972 9.0138139143 9.15013416 9.28795989
Kpa 1000 1019.03281 1038.35168 1057.9596212 1077.85966 1098.05485
P sat Meth
Bar 10 10.1903281 10.3835168 10.579596212 10.7785966 10.9805485

Gam AC 2.167962 1.83737344 1.59584118 1.4170701439 1.49315379 1.18481099

Gamma
Gam MET 1 1.00860392 1.0337305 1.0750753892 1.11535243 1.20937302

ESPECIE J MET

Kpa 1160.92893 1067.52939 1020.32484 996.6335098 930.119679 987.588838

PJ sat
Bar 11.6092893 10.6752939 10.2032484 9.966335098 9.30119679 9.87588838

K 415.760039 412.423488 410.648433 409.7329067 407.06684 409.378829

NUEVA T
C 142.610039 139.273488 137.498433 136.5829067 133.91684 136.228829

Kpa 1160.92893 1067.52939 1020.32484 996.6335098 930.119679 987.588838

P Acet sat
Bar 11.6092893 10.6752939 10.2032484 9.966335098 9.30119679 9.87588838

Y Acet 0 0.19614501 0.32565528 0.4236898773 0.55552469 0.58505306

Y
Y Metha 1.16092893 0.96904289 0.84379272 0.7500193109 0.62244674 0.59718165

R
Tc Vc
Para ij ω Pc bar Zc Kjj cm3*bar/m
K cm3/mol ol*k
Acetona 11 0.307 508.2 47.01 0.2330 209 0
Methanol 22 0.564 512.6 80.97 0.2240 118 0 83.14
Mezcla 12 0.4355 510.4 60.9 0.2285 159.2 0
 TK par T.reida(K) B0 B1 B^ij Bij d1,2
1.1 0.81810319 -0.49886136 -0.26070032 -0.578896356 -520.301701
2.2 0.81108084 -0.50694269 -0.2754375 -0.662289438 -348.587903
415.760039 1.2 0.81458445 -0.50288809 -0.26800221 -0.619603053 -431.664076 5.56145092
1.1 0.81153776 -0.50641133 -0.27445836 -0.590670051 -530.883687
2.2 0.80457177 -0.51459752 -0.28970281 -0.677989909 -356.851653
412.423488 1.2 0.80804726 -0.51049031 -0.28201159 -0.633306363 -441.210877 5.31358611
1.1 0.80804493 -0.51049305 -0.28201669 -0.597072172 -536.637799
2.2 0.80110892 -0.51873593 -0.29753982 -0.686548384 -361.356301
410.648433 1.2 0.80456945 -0.51460028 -0.289708 -0.640768109 -446.409314 5.17547144
1.1 0.80624342 -0.51261628 -0.28598194 -0.600412731 -539.640234
2.2 0.79932288 -0.52088864 -0.30165127 -0.69101996 -363.70986
409.732907 1.2 0.80277569 -0.5167382 -0.29374569 -0.644664445 -449.123807 5.10248022
1.1 0.80099732 -0.51887007 -0.29779532 -0.610293233 -548.520652
2.2 0.79412181 -0.5272293 -0.31390022 -0.704269017 -370.683338
407.06684 1.2 0.79755216 -0.52303527 -0.30577488 -0.65620023 -457.16054 4.88291059
1.1 0.80554669 -0.51344074 -0.28752788 -0.601711802 -540.807816
2.2 0.79863213 -0.52172456 -0.30325422 -0.692759937 -364.625676
409.378829 1.2 0.80208196 -0.51756837 -0.29531988 -0.646180174 -450.179783 5.0739251
1.1 0.79161425 -0.53032503 -0.31995629 -0.628551611 -564.930957
2.2 0.78481927 -0.53884335 -0.33687827 -0.728842697 -383.617393
402.29836 1.2 0.78820944 -0.5345695 -0.32834069 -0.677561877 -472.042738 4.46287283
1.1 0.75882124 -0.57328018 -0.40920456 -0.698905981 -628.164207
2.2 0.75230775 -0.58239509 -0.42941718 -0.824586385 -434.010906
385.632952 1.2 0.75555747 -0.57782192 -0.4192194 -0.760391968 -529.748676 2.67776196
1.1 0.8104597 -0.50766627 -0.27677317 -0.592635628 -532.650313
2.2 0.80350297 -0.51586988 -0.29210296 -0.680615957 -358.233841
411.875621 1.2 0.80697384 -0.51175393 -0.28436869 -0.635596494 -442.806362 5.27143066
1.1 0.81455199 -0.50292544 -0.26807032 -0.585223025 -525.987998
2.2 0.80756013 -0.51106321 -0.28307924 -0.670719902 -353.025174
413.955324 1.2 0.81104853 -0.50698029 -0.27550685 -0.626963528 -436.79196 5.42925153
1.1 0.8209622 -0.4956226 -0.25488656 -0.573872773 -515.786594
2.2 0.81391532 -0.50365895 -0.26940939 -0.655605841 -345.070074
417.212991 1.2 0.81743117 -0.49962692 -0.26208225 -0.613763736 -427.59595 5.66476832
PHI ACET 1.02643469 1.01202881 1.00448381 1.0005902971 0.98962636 0.99891878
φi
PHI METHA 1.01636148 1.00735883 1.00264837 1.0002752289 0.99317104 0.99954267

gamma ACT 2.14628994 1.83279604 1.59701323 1.4197708716 1.49830367 1.18685421

GAMMA
gamma MET 1 1.02857057 0.9937807 1.0954678884 0.96711114 1.16149436

Kpa 1016.36148 909.047701 900.169818 838.71754301 840.434776 851.00421

PJ SAT Bar 10.1636148 9.09047701 9.00169818 8.3871754301 8.40434776 8.5100421

T BUB FI K 410.496455 406.190635 405.816638 403.14407813 403.220846 403.690614

C 137.346455 133.040635 132.666638 129.99407813 130.070846 130.540614

P 1KPa

GAMMA 1 GAMMA T.BUBLE X acetone

T.BUBLE
255

250
3.46823183 1 253.098852 0 T.BUBLE
2.69239974 1.41374992 247.514142 0.1 255
2.16128462 1.92444719 244.463576 0.2
1.79152981 2.82316774 241.538669 0.3 250
1.78085656 3.70498316 239.712225 0.4
1.34171911 5.36276848 238.174058 0.5 245
1.69709101 6.52086184 237.272503 0.6
240
2.60739215 6.80666919 236.540612 0.7
1.04875377 15.1527501 236.537262 0.8 235
3.9920948 2.62748514 236.577252 0.9
3.5 3.28011781 237.679203 1 230

225
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9

P 100 Kpa

GAMMA 1 GAMMA T.BUBLE X acetone

2.56192627 1 337.357961 0
2.1133784 1.06047233 333.444978 0.1
1.78650649 1.19142049 330.541584 0.2
1.54716525 1.39310988 328.262304 0.3
1.5964451 1.44943231 327.099571 0.4
1.24098358 1.86644346 326.425694 0.5
1.61193736 1.49932922 326.10647 0.6
2.39775844 -0.46732254 326.233732 0.7
1.03391898 3.77069995 326.020917 0.8
3.98828427 -20.9646129 327.266927 0.9
1.15 -1.63422087 333.758328 1

P 1000KPa

GAMMA 1 GAMMA T.BUBLE X acetone

2.14628994 1 410.496455 0
1.83279604 1.02857057 406.190635 0.1
1.59701323 0.9937807 405.816638 0.2
1.41977087 1.09546789 403.144078 0.3
1.49830367 0.96711114 403.220846 0.4
1.18685421 1.16149436 403.690614 0.5
1.56606656 0.48531545 403.980253 0.6
2.28682367 -1.90513643 404.498739 0.7
1.02613171 1.37855857 406.625132 0.8
3.98633519 -26.2427745 412.446956 0.9
0.7 -3.03025123 425.544474 1
 1000 1000 1000 1000 1000
10 10 10 10 10

0.6 0.7 0.8 0.9 1

0.4 0.3 0.2 0.1 0

1 1 1 1 1

417.212991 417.212991 417.212991 417.212991 417.212991

144.062991 144.062991 144.062991 144.062991 144.062991
409.864046 409.864046 409.864046 409.864046 409.864046
136.714046 136.714046 136.714046 136.714046 136.714046

414.273413 415.008308 415.743202 416.478097 417.212991

141.123413 141.858308 142.593202 143.328097 144.062991

942.730051 956.816543 971.056406 985.450579 1000

9.42730051 9.56816543 9.71056406 9.85450579 10
1118.54824 1139.34291 1160.44194 1181.84843 1203.56549
11.1854824 11.3934291 11.6044194 11.8184843 12.0356549

1.56099934 2.25639301 1.02586594 1.00629245 1

1.27594668 2.45897447 1.57213543 1.75134412 1.96974877

819.983963 513.887862 1052.77907 1109.64115 1203.56549

8.19983963 5.13887862 10.5277907 11.0964115 12.0356549

402.29836 385.632952 411.875621 413.955324 417.212991

129.14836 112.482952 138.725621 140.805324 144.062991

819.983963 513.887862 1052.77907 1109.64115 1203.56549

8.19983963 5.13887862 10.5277907 11.0964115 12.0356549

0.76799666 0.81167309 0.86400815 1.00496116 1.20356549

0.41850232 0.37909114 0.33102226 0.19433635 0
 0.9705942 0.90944139 1.00875741 1.01720958 1.03073236
0.98056928 0.93694922 1.00687502 1.01291449 1.02246504

1.56606656 2.28682367 1.02613171 3.98633519 0.7

0.48531545 -1.90513643 1.37855857 -26.2427745 -3.03025123

857.573459 869.433975 919.449001 1068.16486 1472.4748

8.57573459 8.69433975 9.19449001 10.6816486 14.724748

403.980253 404.498739 406.625132 412.446956 425.544474

130.830253 131.348739 133.475132 139.296956 152.394474

T.BUBLE
T.BUBLE

T.BUBLE

0.5 0.6 0.7 0.8 0.9 1

 Bar 10 10 10 10 10 10
PRESION Kpa 1000 1000 1000 1000 1000 1000
Act 0 0.1 0.2 0.3 0.4 0.5
Y Met 1 0.9 0.8 0.7 0.6 0.5
Gamma Gamma 1 1 1 1 1 1
φi φi 1 1 1 1 1 1

A B C
MATH 16.5785 3638.27 239.5
ACET 14.3145 2756.22 228.06

Acet 144.06299111 144.06299111 144.062991 144.062991 144.062991 144.062991

T.sat
Met 136.71404607 136.71404607 136.714046 136.714046 136.714046 136.714046

K 409.86404607 410.59894057 411.333835 412.06873 412.803624 413.538519

T0
C 136.71404607 137.44894057 138.183835 138.91873 139.653624 140.388519

Kpa 861.37917315 874.56521361 887.898972 901.381391 915.013416 928.795989

P sat ACET
Bar 8.6137917315 8.7456521361 8.87898972 9.01381391 9.15013416 9.28795989

Kpa 1000 1019.0328098 1038.35168 1057.95962 1077.85966 1098.05485

P sat MET
Bar 10 10.190328098 10.3835168 10.5795962 10.7785966 10.9805485

ESPECIE J Methanol

Kpa 1160.9289279 1165.1879059 1169.448 1173.70919 1177.97143 1182.23471

P sat MET
Bar 11.609289279 11.651879059 11.69448 11.7370919 11.7797143 11.8223471

K 415.76003928 415.90705148 416.053678 416.199921 416.345782 416.491261

T
C 142.61003928 142.75705148 142.903678 143.049921 143.195782 143.341261

Kpa 971.38446048 974.2522781 977.118737 979.983825 982.847529 985.709837

P sat ACT Bar 9.7138446048 9.742522781 9.77118737 9.79983825 9.82847529 9.85709837

R
Tc Vc
Para ij ω Pc bar Zc Kjj cm3*bar/m
K cm3/mol ol*k
Acetona 11 0.307 508.2 47.01 0.2330 209 0
Methanol 22 0.564 512.6 80.97 0.2240 118 0 83.14
Mezcla 12 0.4355 510.4 60.9 0.2285 159.2 0

TK par T.reida(K) B0 B1 B^ij Bij d1,2

1.1 0.8181031863 -0.498861358 -0.26070032 -0.57889636 -520.301701
2.2 0.8110808414 -0.506942687 -0.2754375 -0.66228944 -348.587903
415.760039 5.56145092
415.760039 1.2 0.8145844466 -0.502888089 -0.26800221 -0.61960305 -431.664076 5.56145092
1.1 0.8183924665 -0.498532317 -0.26010726 -0.57838525 -519.842325
2.2 0.8113676385 -0.506609076 -0.27482258 -0.66160901 -348.229769
415.907051 1.2 0.8148724826 -0.502556771 -0.26739832 -0.61900874 -431.250032 5.5720297
1.1 0.8186809884 -0.498204439 -0.25951685 -0.57787611 -519.384723
2.2 0.8116536838 -0.506276644 -0.27421039 -0.66093131 -347.873067
416.053678 1.2 0.8151597635 -0.502226624 -0.26679712 -0.61841677 -430.837619 5.58255254
1.1 0.8189687548 -0.497877719 -0.25892905 -0.57736894 -518.928885
2.2 0.8119389801 -0.505945387 -0.27360093 -0.66025631 -347.517791
416.199921 1.2 0.8154462922 -0.501897643 -0.26619859 -0.61782713 -430.426828 5.59301985
1.1 0.8192557686 -0.49755215 -0.25834387 -0.57686372 -518.474802
2.2 0.8122235302 -0.505615296 -0.27299417 -0.65958401 -347.163932
416.345782 1.2 0.8157320715 -0.501569821 -0.26560271 -0.6172398 -430.017651 5.60343201
1.1 0.8195420325 -0.497227728 -0.25776127 -0.57636044 -518.022462
2.2 0.8125073369 -0.505286368 -0.27239009 -0.65891438 -346.811481
416.491261 1.2 0.8160171042 -0.501243154 -0.26500947 -0.61665478 -429.610077 5.6137894
1.1 0.8198275493 -0.496904445 -0.25718125 -0.57585909 -517.571858
2.2 0.812790403 -0.504958595 -0.27178868 -0.65824741 -346.460431
416.636361 1.2 0.816301393 -0.500917634 -0.26441885 -0.61607204 -429.204098 5.62409242
1.1 0.820112322 -0.496582297 -0.25660378 -0.57535966 -517.122979
2.2 0.8130727312 -0.504631973 -0.27118992 -0.65758309 -346.110773
416.781082 1.2 0.8165849408 -0.500593256 -0.26383084 -0.61549158 -428.799705 5.63434145
1.1 0.8203963531 -0.496261277 -0.25602885 -0.57486213 -516.675815
2.2 0.8133543244 -0.504306494 -0.2705938 -0.6569214 -345.7625
416.925427 1.2 0.8168677503 -0.500270014 -0.26324541 -0.61491339 -428.396889 5.64453686
1.1 0.8206796456 -0.495941379 -0.25545645 -0.57436651 -516.230356
2.2 0.8136351851 -0.503982153 -0.27000029 -0.65626232 -345.415603
417.069396 1.2 0.8171498243 -0.499947903 -0.26266255 -0.61433744 -427.99564 5.65467902
1.1 0.8209622021 -0.495622599 -0.25488656 -0.57387277 -515.786594
2.2 0.8139153163 -0.503658945 -0.26940939 -0.65560584 -345.070074
417.212991 1.2 0.8174311655 -0.499626916 -0.26208225 -0.61376374 -427.59595 5.66476832
PHI ACET 0.99570197 0.9962971834 0.99689196 0.9974863 0.99808021 0.99867367
φi
PHI METHA 1.0179980417 1.0182503878 1.01850129 1.01875075 1.01899878 1.01924538

X Acet 0 0.1022627512 0.20404725 0.30535799 0.40619941 0.50657589

X
X Met 0.8768823115 0.7865043435 0.69673985 0.60758281 0.51902724 0.43106727

Gamma Acet 2.0239678994 1.705622367 1.48558886 1.33006103 1.55045382 1.13882145

Gamma
Gamma Met 0.9910191697 1.0088612679 0.03495756 1.09872458 1.13845968 1.25469865

Kpa 1227.6635699 1156.2613835 28064.7623 1046.81625 952.272732 1013.03856

P Met sat
Bar 12.276635699 11.562613835 280.647623 10.4681625 9.52272732 10.1303856

K 418.01630966 415.59843398 607.851068 411.652419 407.971149 410.368673

T C 144.86630966 142.44843398 334.701068 138.502419 134.821149 137.218673

Kpa 1016.0827867 968.23909609 12293.5062 893.725429 828.088973 870.417738

P Ac sat
Bar 10.160827867 9.6823909609 122.935062 8.93725429 8.28088973 8.70417738
 R
Tc Vc
Para ij ω Pc bar Zc Kjj cm3*bar/m
K cm3/mol ol*k
Acetona 11 0.307 508.2 47.01 0.2330 209 0
Methanol 22 0.564 512.6 80.97 0.2240 118 0 83.14
Mezcla 12 0.4355 510.4 60.9 0.2285 159.2 0

TK par T.reida(K) B0 B1 B^ij Bij d1,2

1.1 0.8225429155 -0.493844485 -0.25171715 -0.57112165 -513.313933
2.2 0.8154824613 -0.501856136 -0.26612311 -0.65194957 -343.145642
418.01631 1.2 0.8190050801 -0.497836498 -0.25885493 -0.61056782 -425.369425 5.7207255
1.1 0.8177851908 -0.499223411 -0.2613535 -0.57945894 -520.807338
2.2 0.8107655755 -0.507309769 -0.27611477 -0.6630385 -348.982162
415.598434 1.2 0.8142678189 -0.503252648 -0.26866733 -0.62025727 -432.119855 5.54978928
1.1 1.1960863205 -0.233878237 0.05791774 -0.21609749 -194.224564
2.2 1.1858194851 -0.238279281 0.05492819 -0.20729978 -109.109692
607.851068 1.2 1.1909418394 -0.236071171 0.05643649 -0.21149308 -147.342663 8.64892863
1.1 0.8100205025 -0.508178774 -0.27772082 -0.59343907 -533.372428
2.2 0.8030675368 -0.516389511 -0.29308556 -0.68168977 -358.799027
411.652419 1.2 0.8065365272 -0.512269986 -0.28533365 -0.63653279 -443.45866 5.25413597
1.1 0.8027767586 -0.516736921 -0.29374327 -0.60691611 -545.485352
2.2 0.7958859709 -0.52506652 -0.30969877 -0.69973663 -368.29777
407.971149 1.2 0.7993239393 -0.520887359 -0.30164881 -0.65225542 -454.412273 4.95857517
1.1 0.8074944382 -0.511140541 -0.28322348 -0.59809015 -537.552739
2.2 0.8005631555 -0.519392413 -0.2987911 -0.6879106 -362.073284
410.368673 1.2 0.8040213277 -0.51525225 -0.29093684 -0.64195524 -447.236364 5.15329558
1.1 0.7828210496 -0.541384997 -0.34200099 -0.6463793 -580.954165
2.2 0.7761015556 -0.550056926 -0.35973577 -0.7529479 -396.304871
397.829657 1.2 0.7794540617 -0.54570601 -0.35078812 -0.69847423 -486.611927 4.03518262
1.1 0.7709924503 -0.556782343 -0.37376446 -0.67152803 -603.557398
2.2 0.7643744893 -0.565668123 -0.39267039 -0.78713422 -414.29842
391.818363 1.2 0.7676763383 -0.561209913 -0.38313186 -0.72806384 -507.226366 3.40308696
1.1 0.8125891049 -0.505191655 -0.27221625 -0.58876204 -529.168805
2.2 0.8056140911 -0.513360904 -0.28737803 -0.67544211 -355.510653
412.957783 1.2 0.8090940818 -0.509262195 -0.27972852 -0.63108397 -439.662581 5.35429553
1.1 0.8167750412 -0.500375946 -0.2634372 -0.58125117 -522.418163
2.2 0.8097640967 -0.50847831 -0.2782753 -0.66542558 -350.238572
415.085076 1.2 0.813262014 -0.504413158 -0.2707891 -0.62234181 -433.572109 5.51251615
1.1 0.8210922751 -0.495475946 -0.25462456 -0.57364569 -515.582492
2.2 0.8140442728 -0.503510256 -0.26913773 -0.65530393 -344.911169
417.279094 1.2 0.8175606791 -0.499479249 -0.26181546 -0.61349988 -427.412129 5.66940397
PHI ACET 1.0023782474 0.9953840547 1.54400281 0.98402725 0.9733007 0.92442568
φi
PHI METHA 1.0244179971 1.0173771369 1.79625157 1.00600059 0.99570405 1.0021412

Ace 0 0.0602733294 0.01690845 0.24834344 0.30322932 0.46629272

x Met 0.8420071428 0.7849409973 1.46472033 0.61226154 0.55106461 0.39421534

ACE 0 0.0713112965 0.01141207 0.28856845 0.3549473 0.54188071

X normali
META 1 0.9286887035 0.98858793 0.71143155 0.6450527 0.45811929
 ACE 2.1382050906 1.9071625313 1.69339319 1.43533607 1.56149513 1.15288381
GAMMA
META 1.25 1.204360351 6.50008199 1.31956903 1.24470488 1.54926805

Kpa 990.18754918 970.23418056 920.988584 865.975056 838.664886 843.028905

PMET sat
Bar 9.9018754918 9.7023418056 9.20988584 8.65975056 8.38664886 8.43028905

K 409.48082491 408.69216588 406.689113 404.348116 403.141722 403.336578

T
C 136.33082491 135.54216588 133.539113 131.198116 129.991722 130.186578

TOLE TOL 2.0419023265 1.6617647082 33.0939544 1.77438615 1.18376669 1.71360428

253.04963043 252.45166072 250.184756 249.686834 247.631147 246.019533

0.305 0.2850961894 0.24500073 0.27200952 0.27743611 0.26653303

P 1KPa
T.ROCIO
GAMMA 1 GAMMA T.ROCIO X acetone 255
3.42509952 0.305 253.04963043 0
3.3658843 0.28509619 252.45166072 0.1 250
3.71125861 0.24500073 250.18475577 0.2
3.14116321 0.27200952 249.68683381 0.3 245
2.96669147 0.27743611 247.63114712 0.4
2.64813212 0.26653303 246.01953348 0.5 240
2.54000186 0.23870952 244.83404021 0.6
3.84354721 0.2222728 241.18984772 0.7 235
1.20586874 0.35737336 239.4630237 0.8
1.016629 2.53471581 236.48556757 0.9 230
1 3.28012694 237.63675683 1
225
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

409.480825 408.692166 406.689113

P 100KPa

GAMMA 1 GAMMA T.ROCIO X acetone

2.56553923 0.7 337.77369223 0
2.40783195 0.70110065 335.55328258 0.1
2.20971778 1.12022083 333.76319414 0.2
1.94461564 0.67324479 332.37604018 0.3
1.89824533 0.65163906 330.84236619 0.4
1.43167421 0.737286 328.35036187 0.5
1.65104567 0.69041015 326.38875252 0.6
2.83818603 0.37137476 326.4184803 0.7
1.02352893 0.65192172 338.20670038 0.8
1.00333104 1.24811344 331.02314744 0.9
0.84 2.36583093 333.19225967 1
P 1000KPa

GAMMA 1 GAMMA T.ROCIO X acetone

2.13820509 1.25 409.48082491 0
1.90716253 1.20436035 408.69216588 0.1
1.69339319 6.50008199 406.68911287 0.2
1.43533607 1.31956903 404.34811586 0.3
1.56149513 1.24470488 403.14172213 0.4
1.15288381 1.54926805 403.33657833 0.5
1.58691681 0.78456262 406.98486908 0.6
2.16304106 0.42372202 410.99177268 0.7
1.0076666 0.84008298 417.37648768 0.8
0.80133743 2.36832309 422.89788963 0.9
0.82 1.96953607 425.49988515 1
 10 10 10 10 10 PASO 1
1000 1000 1000 1000 1000
0.6 0.7 0.8 0.9 1
0.4 0.3 0.2 0.1 0
1 1 1 1 1 PASO 2
1 1 1 1 1

PASO 3

144.062991 144.062991 144.0629911 144.0629911 144.062991

136.714046 136.714046 136.7140461 136.7140461 136.714046

414.273413 415.008308 415.7432021 416.4780966 417.212991 PASO 4

141.123413 141.858308 142.5932021 143.3280966 144.062991

942.730051 956.816543 971.0564062 985.4505791 1000 PASO 5

9.42730051 9.56816543 9.710564062 9.854505791 10

1118.54824 1139.34291 1160.441937 1181.848426 1203.56549

11.1854824 11.3934291 11.60441937 11.81848426 12.0356549

PASO 6
1186.49898 1190.76423 1195.030412 1199.297511 1203.56549
11.8649898 11.9076423 11.95030412 11.99297511 12.0356549

416.636361 416.781082 416.9254267 417.0693959 417.212991 PASO 7

143.486361 143.631082 143.7754267 143.9193959 144.062991

988.570736 991.430214 994.2882584 997.1448578 1000 PASO 8

9.88570736 9.91430214 9.942882584 9.971448578 10

PASO 9
 0.9992667 0.99985929 1.000451448 1.001043164 1.00163444
1.01949057 1.01973435 1.019976726 1.02021771 1.02045731

0.60649178 0.70595136 0.804958876 0.903518521 1.00163444

0.34369707 0.2569109 0.170703058 0.085067942 0 PASO 10

2.03601591 2.16885259 1.018064489 1.004054945 0.99999867 PASO 11

1.3120978 1.62055706 1.787165272 1.968906527 1.96890653

726.460136 614.317454 1082.07145 1141.532661 1205.53426

7.26460136 6.14317454 10.8207145 11.41532661 12.0553426 PASO 12

397.829657 391.818363 412.9577831 415.0850759 417.279094 PASO 13

124.679657 118.668363 139.8077831 141.9350759 144.129094

PASO 14
665.639729 581.307638 917.8920808 958.2968737 1001.31635
6.65639729 5.81307638 9.178920808 9.582968737 10.0131635
0.94365319 0.92603504 0.988657379 0.995136432 1.00183149
0.96822864 0.95243095 1.008849066 1.014629654 1.02064427

0.41777578 0.51414947 0.846386811 0.930824026 1.00051579

0.40631226 0.28701036 0.104336325 0.045143384 0

0.50695528 0.64175643 0.890255826 0.953744988 1

0.49304472 0.35824357 0.109744174 0.046255012 0
 1.58691681 2.16304106 1.007666599 0.801337433 0.82
0.78456262 0.42372202 0.840082979 2.368323095 1.96953607

928.132049 1029.32378 1208.439575 1382.401018 1470.92007

9.28132049 10.2932378 12.08439575 13.82401018 14.7092007

406.984869 410.991773 417.3764877 422.8978896 425.499885

133.834869 137.841773 144.2264877 149.7478896 152.349885

-2.30128939 -4.8934433 -1.07001363 -1.882219847 -1.97009413

244.83404 241.189848 239.4630237 236.4855676 237.636757

0.23870952 0.2222728 0.357373356 2.534715814 3.28012694

ROCIO

T.ROCIO

0.6 0.7 0.8 0.9 1

404.348116 403.141722 403.3365783 410.9917727 417.376488 #DIV/0! 422.89789 425.499885

METODO UNIFAC PARA COEFICIENTES DE ACTIVID
Compuestos Metanol A
Acetona B
PARAMETROS GENERALES PARAMETROS DE LAS SUSTANCIAS PURAS
Temperatura de la Volumen funcional relativo Area funcional relativa
mezcla 328 K (Rx) (Qx)
Composición de la x (A) 1 CH3 0.9011
mezcla X(B) 0 CH3CO 1.6724
R=
Numero de Q=
componentes NC 2 OH 1
Formulas X1 CH3-OH
moleculares X2 CH3CO
Numero de grupos NG 3

EVALUACION
Area parcial de grupo funcional
Volumenes moleculares relativos (ri) Area molecular relativa (qi) (eki)
1.9011 2.048 0.41406 0.36301
r q
2.5735 2.336 0.00000 0.63699
eki
0.58594 0.00000

Coeficiente de actividad Coeficientes de actividad Coeficiente de

residual combinatorio actividad UNIFAC
gamma
Ln gamma1R 0.00000 Ln gamma1C 0.00000 1 1.00000
gamma
Ln gamma2R 0.81648 Ln gamma2C 0.13064 2 2.57828

FRACCION METHA FRACCION AC TEMPERATURA(K) TAU TAU TAU BETHA

1.00000 0.31275 0.09009 0.814126
0.93680 1.00000 0.66941 0.6068581
1 0 409.8640460696 0.68277 0.81469 1.00000 0.6232423
1.00000 0.31341 0.09048 0.8143993
0.93691 1.00000 0.66990 0.6073029
0.9 0.1 410.598940574 0.68324 0.81499 1.00000 0.6234033
1.00000 0.31406 0.09087 0.8146718
0.93701 1.00000 0.67037 0.6077468
0.8 0.2 411.3338350784 0.68371 0.81529 1.00000 0.6235645
1.00000 0.31471 0.09126 0.8149436
0.93712 1.00000 0.67085 0.6081897
0.7 0.3 412.0687295828 0.68417 0.81559 1.00000 0.6237258
1.00000 0.31535 0.09165 0.8152145
0.93723 1.00000 0.67133 0.6086316
0.6 0.4 412.8036240872 0.68463 0.81588 1.00000 0.6238872
1.00000 0.31600 0.09204 0.8154847
0.93734 1.00000 0.67181 0.6090726
0.5 0.5 413.5385185916
0.5 0.5 413.5385185916 0.68509 0.81618 1.00000 0.6240487
1.00000 0.31665 0.09243 0.8157541
0.93745 1.00000 0.67228 0.6095126
0.4 0.6 414.273413096 0.68555 0.81647 1.00000 0.6242103
1.00000 0.31729 0.09282 0.8160227
0.93755 1.00000 0.67275 0.6099517
0.3 0.7 415.0083076004 0.68601 0.81676 1.00000 0.624372
1.00000 0.31794 0.09321 0.8162906
0.93766 1.00000 0.67322 0.6103898
0.2 0.8 415.7432021048 0.68647 0.81706 1.00000 0.6245339
1.00000 0.31858 0.09360 0.8165577
0.93777 1.00000 0.67369 0.6108269
0.1 0.9 416.4780966092 0.68693 0.81735 1.00000 0.6246958
1.00000 0.31922 0.09400 0.816824
0.93787 1.00000 0.67416 0.6112632
0 1 417.2129911136 0.68738 0.81764 1.00000 0.6248578
S DE ACTIVIDAD

STANCIAS PURAS PARAMETROS DE LAS SUSTANCIAS EN MEZCLA

Area funcional relativa Matriz de frecuencia de grupos
(Qx) secundarios (vx) para cada compuesto Matriz de parametros de energía (amk)
0.848 1 1 CH2 0
1.488 0 1 CH3CO 26.76
v= a=
1.2 1 0 OH 156.4

EVALUACION DE LOS PARAMETROS DE LA MEZCLA

Energia parcial por grupo Area Fraccional por
Energia funcional por interaccion de grupos funcionales funcional en cada especie grupo funcional
1.00000 0.23400 0.04941 0.77778 0.95009
0.92165 1.00000 0.60561 0.55044 0.72193
beta Phi o
0.62075 0.77407 1.00000 0.60640 0.40370
Tau theta

GAMMA R GAMMA R GAMMA C GAMMA C

BETHA PHI SK J L X1 X2 X1 X2
0.9597397949 0.4140625 0.814125958 1 1
0.7505204802 0 0.606858108 1.353689969 1.140625
0.4591130918 0.5859375 0.623242272 - - 0 0.64314936 0 0.130638193
0.9598095304 0.4083204931 0.830755137 0.965839235 0.9861325
0.7507569183 0.0716486903 0.62343874 1.307446884 1.1248074
0.4595607055 0.5200308166 0.604974185 - - 0.0069658 0.50860428 0.0016013 0.099732788
0.9598790248 0.4027355623 0.846891048 0.933935291 0.9726444
0.7509930014 0.141337386 0.639530899 1.264258835 1.1094225
0.4600075451 0.4559270517 0.58727374 - - 0.0271263 0.39300725 0.0060478 0.074393735
0.9599482794 0.3973013493 0.86255381 0.904071675 0.9595202
0.7512287296 0.2091454273 0.655154521 1.223832758 1.0944528
0.460453613 0.3935532234 0.570117673 - - 0.0595226 0.29473552 0.0128682 0.05385594
0.9600172954 0.3920118343 0.877762471 0.904071675 0.9467456
0.7514641034 0.275147929 0.670328482 1.307446884 1.0798817
0.4608989118 0.3328402367 0.553483957 - - 0.1033629 0.21242167 0.0058075 0.188468845
0.9600860741 0.3868613139 0.892535074 0.849729585 0.9343066
0.7516991229 0.3394160584 0.685070663 1.150270415 1.0656934
0.1579952 0.14491038 0.0321068 0.02467288
0.4613434439 0.2737226277 0.537351728 - - 0.1579952 0.14491038 0.0321068 0.02467288
0.9601546166 0.3818443804 0.906888727 0.849729585 0.9221902
0.7519337886 0.4020172911 0.699398016 1.353689969 1.0518732
0.4617872116 0.2161383285 0.521701202 - - 0.2228845 0.09122409 0.0208039 0.354102127
0.9602229242 0.3769559033 0.682822554 0.801549891 0.9103841
0.7521681006 0.2091454273 0.459456405 1.085050047 1.0384068
0.4622302176 0.1600284495 0.335721759 - - 0.8429191 0.80574986 0.0568253 0.008017666
0.960290998 0.3721910112 0.934403288 0.779452403 0.8988764
0.7524020594 0.5224719101 0.726871761 1.055136899 1.0252809
0.462672464 0.1053370787 0.491771142 - - 0.381777 0.02214543 0.0706578 0.003391648
0.9603588394 0.3675450763 0.947594245 0.758540614 0.887656
0.7526356652 0.580443828 0.740047928 1.026828821 1.0124827
0.4631139535 0.0520110957 0.477456864 - - 0.4751537 0.00546479 0.0852298 0.000807947
0.9604264494 0.3630136986 0.960426449 0.738721585 0.8767123
0.7528689184 0.6369863014 0.752868918 1 1
0.4635546882 0 0.463554688 - - 0.5775136 0 0.1003924 0
MEZCLA

z de parametros de energía (amk)

476.4 986.5
0 164.5

84 0

Energia fraccional
Area Fraccional por por grupo funcional Volumen fraccional Area fraccional evaluada en
grupo funcional (sk) Evaluado en reparto (Ji) reparto (Li)
0.41406 0.77778 1.00000 1.00000
J L
0.00000 0.55044 1.35369 1.14063
sk
0.58594 0.60640

GAMMA
X1 GAMMA X2

1 2.167961999

1.008604 1.837373436

1.03373 1.595841183

1.075075 1.417070144

1.115352 1.493153787

1.209373 1.184810995
1.209373 1.184810995

1.275947 1.560999343

2.458974 2.256393009

1.572135 1.02586594

1.751344 1.006292452

1.969749 1
METODO UNIFAC PARA COEFICIENTES DE ACTIVID
Compuestos Metanol A
Acetona B
PARAMETROS GENERALES PARAMETROS DE LAS SUSTANCIAS PURAS
Temperatura de la Volumen funcional relativo Area funcional relativa
mezcla 328 K (Rx) (Qx)
Composición de la x (A) 1 CH3 0.9011
mezcla X(B) 0 CH3CO 1.6724
R=
Numero de Q=
componentes NC 2 OH 1
Formulas X1 CH3-OH
moleculares X2 CH3CO
Numero de grupos NG 3

EVALUACION
Area parcial de grupo funcional
Volumenes moleculares relativos (ri) Area molecular relativa (qi) (eki)
1.9011 2.048 0.41406 0.36301
r q
2.5735 2.336 0.00000 0.63699
eki
0.58594 0.00000

Coeficiente de actividad Coeficientes de actividad Coeficiente de

residual combinatorio actividad UNIFAC
gamma
Ln gamma1R 0.00000 Ln gamma1C 0.00000 1 1.00000
gamma
Ln gamma2R 0.81648 Ln gamma2C 0.13064 2 2.57828

FRACCION METHA FRACCION AC TEMPERATURA(K) TAU TAU TAU BETHA

1.00000 0.31795 0.09322 0.8162967
0.93766 1.00000 0.67323 0.6103998
1 0 415.7600392802 0.68648 0.81706 1.00000 0.6245376
1.00000 0.31502 0.09145 0.8150745
0.93718 1.00000 0.67108 0.6084031
0.9 0.1 412.4234880951 0.68439 0.81573 1.00000 0.6238037
1.00000 0.31345 0.09051 0.8144177
0.93691 1.00000 0.66993 0.6073329
0.8 0.2 410.6484327282 0.68327 0.81501 1.00000 0.6234142
1.00000 0.31264 0.09003 0.8140771
0.93678 1.00000 0.66933 0.6067786
0.7 0.3 409.732906703 0.68269 0.81464 1.00000 0.6232135
1.00000 0.31027 0.08862 0.8130783
0.93638 1.00000 0.66757 0.6051561
0.6 0.4 407.066839782 0.68099 0.81354 1.00000 0.6226304
1.00000 0.31232 0.08984 0.8139451
0.93672 1.00000 0.66910 0.6065639
0.5 0.5 409.3788289217
0.5 0.5 409.3788289217 0.68247 0.81449 1.00000 0.623136
1.00000 0.30599 0.08611 0.8112653
0.93565 1.00000 0.66438 0.6022218
0.4 0.6 402.298359539 0.67789 0.81156 1.00000 0.6215913
1.00000 0.29073 0.07745 0.8046477
0.93296 1.00000 0.65274 0.5916293
0.3 0.7 385.6329522614 0.66660 0.80427 1.00000 0.6180063
1.00000 0.31454 0.09116 0.8148722
0.93709 1.00000 0.67073 0.6080734
0.2 0.8 411.8756213593 0.68405 0.81551 1.00000 0.6236834
1.00000 0.31637 0.09226 0.8156376
0.93740 1.00000 0.67207 0.6093223
0.1 0.9 413.9553236176 0.68535 0.81634 1.00000 0.6241403
1.00000 0.31922 0.09400 0.816824
0.93787 1.00000 0.67416 0.6112632
0 1 417.2129911136 0.68738 0.81764 1.00000 0.6248578
S DE ACTIVIDAD

STANCIAS PURAS PARAMETROS DE LAS SUSTANCIAS EN MEZCLA

Area funcional relativa Matriz de frecuencia de grupos
(Qx) secundarios (vx) para cada compuesto Matriz de parametros de energía (amk)
0.848 1 1 CH2 0
1.488 0 1 CH3CO 26.76
v= a=
1.2 1 0 OH 156.4

EVALUACION DE LOS PARAMETROS DE LA MEZCLA

Energia parcial por grupo Area Fraccional por
Energia funcional por interaccion de grupos funcionales funcional en cada especie grupo funcional
1.00000 0.23400 0.04941 0.77778 0.95009
0.92165 1.00000 0.60561 0.55044 0.72193
beta Phi o
0.62075 0.77407 1.00000 0.60640 0.40370
Tau theta

GAMMA R GAMMA R GAMMA C GAMMA C

BETHA PHI SK J L X1 X2 X1 X2
0.9602925549 0.4140625 0.816296738 1 1
0.7524074155 0 0.6103998 1.353689969 1.140625
0.4626825875 0.5859375 0.624537567 - - 0 0.63310255 0 0.130638193
0.9599816255 0.4083204931 0.831373733 0.965839235 0.9861325
0.7513423968 0.0716486903 0.624481043 1.307446884 1.1248074
0.4606686697 0.5200308166 0.605454125 - - 0.0069327 0.5061099 0.0016013 0.099732788
0.9598142181 0.4027355623 0.846678905 0.933935291 0.9726444
0.7507728287 0.141337386 0.639159959 1.264258835 1.1094225
0.4595908226 0.4559270517 0.587064312 - - 0.0271749 0.39374142 0.0060478 0.074393735
0.9597273254 0.3973013493 0.861899289 0.904071675 0.9595202
0.7504782512 0.2091454273 0.653960364 1.223832758 1.0944528
0.4590331352 0.3935532234 0.569307234 - - 0.0598876 0.29663956 0.0128682 0.05385594
0.9594721354 0.3920118343 0.876313513 0.904071675 0.9467456
0.7496172798 0.275147929 0.667556491 1.307446884 1.0798817
0.4574022286 0.3328402367 0.551259625 - - 0.1049385 0.21586473 0.0058075 0.188468845
0.959693619 0.3868613139 0.8916067 0.849729585 0.9343066
0.7503641761 0.3394160584 0.683187396 1.150270415 1.0656934
0.1597478 0.14663341 0.0321068 0.02467288
0.4588171276 0.2737226277 0.535579229 - - 0.1597478 0.14663341 0.0321068 0.02467288
0.9590075526 0.3818443804 0.904508963 0.849729585 0.9221902
0.7480656546 0.4020172911 0.694267329 1.353689969 1.0518732
0.4544593318 0.2161383285 0.516110331 - - 0.2302003 0.09446497 0.0208039 0.354102127
0.9572967601 0.3769559033 0.67875509 0.801549891 0.9103841
0.7425240783 0.2091454273 0.447442211 1.085050047 1.0384068
0.4439036506 0.1600284495 0.325741676 - - 0.8574087 0.81914615 0.0568253 0.008017666
0.9599301046 0.3721910112 0.933852286 0.779452403 0.8988764
0.7511668217 0.5224719101 0.72544216 1.055136899 1.0252809
0.4603364744 0.1053370787 0.489702211 - - 0.3858543 0.02240446 0.0706578 0.003391648
0.9601249777 0.3675450763 0.947299469 0.758540614 0.887656
0.75183226 0.580443828 0.739182273 1.026828821 1.0124827
0.4615952262 0.0520110957 0.47602364 - - 0.4785063 0.00550726 0.0852298 0.000807947
0.9604264494 0.3630136986 0.960426449 0.738721585 0.8767123
0.7528689184 0.6369863014 0.752868918 1 1
0.4635546882 0 0.463554688 - - 0.5775136 0 0.1003924 0
MEZCLA

z de parametros de energía (amk)

476.4 986.5
0 164.5

84 0

Energia fraccional
Area Fraccional por por grupo funcional Volumen fraccional Area fraccional evaluada en
grupo funcional (sk) Evaluado en reparto (Ji) reparto (Li)
0.41406 0.77778 1.00000 1.00000
J L
0.00000 0.55044 1.35369 1.14063
sk
0.58594 0.60640

GAMMA
X1 GAMMA X2

1 2.146289936

1.008571 1.832796037

1.033781 1.597013233

1.075468 1.419770872

1.117111 1.498303665

1.211494 1.186854214
1.211494 1.186854214

1.285315 1.566066559

2.494864 2.286823673

1.578559 1.026131706

1.757225 1.006335189

1.969749 1
METODO UNIFAC PARA COEFICIENTES DE ACTIVID
Compuestos Metanol A
Acetona B
PARAMETROS GENERALES PARAMETROS DE LAS SUSTANCIAS PURAS
Temperatura de la Volumen funcional relativo Area funcional relativa
mezcla 328 K (Rx) (Qx)
Composición de la x (A) 1 CH3 0.9011
mezcla X(B) 0 CH3CO 1.6724
R=
Numero de Q=
componentes NC 2 OH 1
Formulas X1 CH3-OH
moleculares X2 CH3CO
Numero de grupos NG 3

EVALUACION
Area parcial de grupo funcional
Volumenes moleculares relativos (ri) Area molecular relativa (qi) (eki)
1.9011 2.048 0.41406 0.36301
r q
2.5735 2.336 0.00000 0.63699
eki
0.58594 0.00000

Coeficiente de actividad Coeficientes de actividad Coeficiente de

residual combinatorio actividad UNIFAC
gamma
Ln gamma1R 0.00000 Ln gamma1C 0.00000 1 1.00000
gamma
Ln gamma2R 0.81648 Ln gamma2C 0.13064 2 2.57828

FRACCION METHA FRACCION AC TEMPERATURA(K) TAU TAU TAU BETHA

1.00000 0.31795 0.09322 0.8162967
0.93766 1.00000 0.67323 0.6103998
0.8768823115 0 415.7600392802 0.68648 0.81706 1.00000 0.6245376
1.00000 0.31808 0.09330 0.8163502
0.93768 1.00000 0.67333 0.6104873
0.7865043435 0.1022627512 415.907051482 0.68657 0.81712 1.00000 0.62457
1.00000 0.31821 0.09338 0.8164035
0.93771 1.00000 0.67342 0.6105746
0.6967398531 0.2040472509 416.0536783039 0.68666 0.81718 1.00000 0.6246023
1.00000 0.31834 0.09346 0.8164567
0.93773 1.00000 0.67352 0.6106616
0.6075828068 0.3053579895 416.1999211899 0.68675 0.81724 1.00000 0.6246345
1.00000 0.31847 0.09353 0.8165097
0.93775 1.00000 0.67361 0.6107483
0.5190272433 0.4061994059 416.3457815774 0.68684 0.81729 1.00000 0.6246666
1.00000 0.31859 0.09361 0.8165625
0.93777 1.00000 0.67370 0.6108348
0.4310672723 0.5065758887 416.4912608974
0.4310672723 0.5065758887 416.4912608974 0.68693 0.81735 1.00000 0.6246987
1.00000 0.31872 0.09369 0.8166151
0.93779 1.00000 0.67380 0.610921
0.3436970736 0.6064917765 416.6363605744 0.68702 0.81741 1.00000 0.6247307
1.00000 0.31885 0.09377 0.8166676
0.93781 1.00000 0.67389 0.6110069
0.2569108964 0.7059513586 416.7810820262 0.68711 0.81747 1.00000 0.6247626
1.00000 0.31897 0.09384 0.8167199
0.93783 1.00000 0.67398 0.6110926
0.1707030576 0.8049588759 416.9254266643 0.68720 0.81752 1.00000 0.6247944
1.00000 0.31910 0.09392 0.8167721
0.93785 1.00000 0.67407 0.611178
0.0833821459 0.9025811806 417.0693958939 0.68729 0.81758 1.00000 0.6248262
1.00000 0.31922 0.09400 0.816824
0.93787 1.00000 0.67416 0.6112632
0 1.00163444 417.2129911136 0.68738 0.81764 1.00000 0.6248578
S DE ACTIVIDAD

STANCIAS PURAS PARAMETROS DE LAS SUSTANCIAS EN MEZCLA

Area funcional relativa Matriz de frecuencia de grupos
(Qx) secundarios (vx) para cada compuesto Matriz de parametros de energía (amk)
0.848 1 1 CH2 0
1.488 0 1 CH3CO 26.76
v= a=
1.2 1 0 OH 156.4

EVALUACION DE LOS PARAMETROS DE LA MEZCLA

Energia parcial por grupo Area Fraccional por
Energia funcional por interaccion de grupos funcionales funcional en cada especie grupo funcional
1.00000 0.23400 0.04941 0.77778 0.95009
0.92165 1.00000 0.60561 0.55044 0.72193
beta Phi o
0.62075 0.77407 1.00000 0.60640 0.40370
Tau theta

GAMMA R GAMMA R GAMMA C GAMMA C

BETHA PHI SK J L X1 X2 X1 X2
0.9602925549 0.4140625 0.816296738 1.140403891 1.1404039
0.7524074155 0 0.6103998 1.543753308 1.3007732
0.4626825875 0.5859375 0.624537567 - - 0 0.63310255 -0.0090214 0.071957344
0.9603061438 0.4074694392 0.834942438 1.081155413 1.1072385
0.7524541739 0.0822681301 0.628822644 1.463549238 1.2629439
0.4627709624 0.5102624308 0.603673272 - - 0.0090607 0.48322431 -0.0002385 0.050705761
0.9603196877 0.4012799191 0.852440036 1.027795105 1.0758689
0.7525007956 0.1595008839 0.646112798 1.391315924 1.227163
0.4628590755 0.439219197 0.584101892 - - 0.0341574 0.36085368 0.0101586 0.034957557
0.960333187 0.3954616176 0.86888162 0.979486752 1.0461545
0.7525472813 0.2321015764 0.662361111 1.325921391 1.19327
0.4629469279 0.3724368059 0.565719662 - - 0.0726429 0.26180716 0.0215072 0.023417663
0.9603466419 0.3899855118 0.884349873 0.979486752 1.0179687
0.7525936314 0.3004323554 0.677649154 1.463549238 1.1611206
0.4630345207 0.3095821328 0.548433415 - - 0.122383 0.18270128 0.0072932 0.255846393
0.9603600525 0.384825469 0.898919244 0.895404271 0.9911978
0.7526398466 0.3648193045 0.692050376 1.21209978 1.130585
0.1816351 0.12076564 0.0452603 0.009228272
0.4631218551 0.2503552265 0.532159266 - - 0.1816351 0.12076564 0.0452603 0.009228272
0.9603734191 0.3799578971 0.912656939 0.895404271 0.9657387
0.7526859275 0.4255568063 0.705631079 1.543753308 1.1015457
0.463208932 0.1944852966 0.516821488 - - 0.2489591 0.07370633 0.0226681 0.637288584
0.9603867419 0.3753614442 0.690411565 0.824708144 0.9414984
0.7527318746 0.2321015764 0.467641558 1.116399142 1.0738966
0.4632957528 0.1417272686 0.333333938 - - 0.869873 0.77157558 0.0685399 0.002622693
0.960400021 0.3710167406 0.937874948 0.793419182 0.9183923
0.7527776884 0.5371244443 0.730565378 1.074043588 1.0475412
0.4633823183 0.0918588151 0.488687278 - - 0.4031978 0.01684015 0.0795722 0.001063117
0.9604132568 0.366838482 0.949651075 0.766167727 0.8985624
0.7528233695 0.5892607025 0.742210724 1.037153567 1.0249227
0.4634686298 0.0439008155 0.475558192 - - 0.4897146 0.00389521 0.0909161 0.00015154
0.9604264494 0.3630136986 0.960426449 0.737516159 0.8752817
0.7528689184 0.6369863014 0.752868918 0.998368227 0.9983682
0.4635546882 0 0.463554688 - - 0.5775136 0 0.0999647 -1.3328E-06
MEZCLA

z de parametros de energía (amk)

476.4 986.5
0 164.5

84 0

Energia fraccional
Area Fraccional por por grupo funcional Volumen fraccional Area fraccional evaluada en
grupo funcional (sk) Evaluado en reparto (Ji) reparto (Li)
0.41406 0.77778 1.00000 1.00000
J L
0.00000 0.55044 1.35369 1.14063
sk
0.58594 0.60640

GAMMA
X1 GAMMA X2

0.991019 2.023967899

1.008861 1.705622367

1.045313 1.485588861

1.098725 1.330061027

1.13846 1.55045382

1.254699 1.138821445
1.254699 1.138821445

1.312098 2.036015906

2.555922 2.168852594

1.620557 1.018064489

1.787165 1.004054945

1.968907 0.999998667
METODO UNIFAC PARA COEFICIENTES DE ACTIVID
Compuestos Metanol A
Acetona B
PARAMETROS GENERALES PARAMETROS DE LAS SUSTANCIAS PURAS
Temperatura de la Volumen funcional relativo Area funcional relativa
mezcla 328 K (Rx) (Qx)
Composición de la x (A) 1 CH3 0.9011
mezcla X(B) 0 CH3CO 1.6724
R=
Numero de Q=
componentes NC 2 OH 1
Formulas X1 CH3-OH
moleculares X2 CH3CO
Numero de grupos NG 3

EVALUACION
Area parcial de grupo funcional
Volumenes moleculares relativos (ri) Area molecular relativa (qi) (eki)
1.9011 2.048 0.41406 0.36301
r q
2.5735 2.336 0.00000 0.63699
eki
0.58594 0.00000

Coeficiente de actividad Coeficientes de actividad Coeficiente de

residual combinatorio actividad UNIFAC
gamma
Ln gamma1R 0.00000 Ln gamma1C 0.00000 1 1.00000
gamma
Ln gamma2R 0.81648 Ln gamma2C 0.13064 2 2.57828

FRACCION METHA FRACCION AC TEMPERATURA(K) TAU TAU TAU BETHA

1.00000 0.31993 0.09442 0.8171143
0.93799 1.00000 0.67467 0.6117389
1 0 418.0163096619 0.68788 0.81795 1.00000 0.6250351
1.00000 0.31781 0.09314 0.8162379
0.93764 1.00000 0.67313 0.6103035
0.9286887035 0.0713112965 415.5984339821 0.68638 0.81700 1.00000 0.624502
1.00000 0.45669 0.19732 0.8670721
0.95693 1.00000 0.76290 0.6994108
0.9885879338 0.0114120662 607.8510680844 0.77314 0.87093 1.00000 0.6676402
1.00000 0.31434 0.09104 0.8147897
0.93706 1.00000 0.67058 0.6079389
0.7114315543 0.2885684457 411.6524193671 0.68391 0.81542 1.00000 0.6236344
1.00000 0.31107 0.08909 0.8134183
0.93651 1.00000 0.66817 0.6057079
0.6450527046 0.3549472954 407.9711487067 0.68157 0.81392 1.00000 0.622828
1.00000 0.31320 0.09036 0.8143137
0.93687 1.00000 0.66974 0.6071637
0.4581192852 0.5418807148 410.3686734924
0.4581192852 0.5418807148 410.3686734924 0.68310 0.81490 1.00000 0.6233528
1.00000 0.30195 0.08377 0.8095345
0.93495 1.00000 0.66134 0.5994336
0.4930447205 0.5069552795 397.8296573924 0.67494 0.80966 1.00000 0.6206227
1.00000 0.29645 0.08064 0.8071564
0.93398 1.00000 0.65715 0.5956233
0.3582435704 0.6417564296 391.8183632304 0.67088 0.80704 1.00000 0.6193279
1.00000 0.31549 0.09173 0.8152713
0.93725 1.00000 0.67143 0.6087242
0.1097441739 0.8902558261 412.957783105 0.68473 0.81594 1.00000 0.623921
1.00000 0.31736 0.09286 0.8160508
0.93757 1.00000 0.67280 0.6099975
0.0462550117 0.9537449883 415.0850759431 0.68606 0.81679 1.00000 0.6243889
1.00000 0.31928 0.09403 0.8168479
0.93788 1.00000 0.67421 0.6113024
0 1 417.2790942253 0.68742 0.81766 1.00000 0.6248724
S DE ACTIVIDAD

STANCIAS PURAS PARAMETROS DE LAS SUSTANCIAS EN MEZCLA

Area funcional relativa Matriz de frecuencia de grupos
(Qx) secundarios (vx) para cada compuesto Matriz de parametros de energía (amk)
0.848 1 1 CH2 0
1.488 0 1 CH3CO 26.76
v= a=
1.2 1 0 OH 156.4

EVALUACION DE LOS PARAMETROS DE LA MEZCLA

Energia parcial por grupo Area Fraccional por
Energia funcional por interaccion de grupos funcionales funcional en cada especie grupo funcional
1.00000 0.23400 0.04941 0.77778 0.95009
0.92165 1.00000 0.60561 0.55044 0.72193
beta Phi o
0.62075 0.77407 1.00000 0.60640 0.40370
Tau theta

GAMMA R GAMMA R GAMMA C GAMMA C

BETHA PHI SK J L X1 X2 X1 X2
0.9605000911 0.4140625 0.817114283 1 1
0.7531234862 0 0.611738937 1.353689969 1.140625
0.4640355981 0.5859375 0.625035103 - - 0 0.62932854 0 0.130638193
0.9602776065 0.409951445 0.82783769 0.975398413 0.9900714
0.7523559994 0.0512976928 0.621743292 1.320387048 1.1293002
0.4625854051 0.5387508622 0.611462527 - - 0.0035228 0.53762358 0.0008281 0.107992973
0.9725656667 0.4133990682 0.868443072 0.995979893 0.9983977
0.802771996 0.0082782942 0.700754123 1.348247991 1.1387974
0.5575879425 0.5783226377 0.666209912 - - 6.0015E-05 0.39993176 2.1974E-05 0.126802559
0.9599090768 0.3979151289 0.86069278 0.907388512 0.9610026
0.7510952355 0.2014866938 0.65322103 1.228322727 1.0961436
0.4602010147 0.4005981773 0.571938383 - - 0.0552742 0.30541671 0.0119815 0.055982304
0.9595590554 0.3943773654 0.869772212 0.907388512 0.9524585
0.7499098396 0.2456308616 0.661314186 1.320387048 1.086398
0.4579565729 0.3599917729 0.559251256 - - 0.0832184 0.25072959 0.0072664 0.194914187
0.9597877059 0.3847442296 0.897862123 0.839167102 0.9291936
0.7506828725 0.3658330089 0.689589395 1.135972088 1.0598615
0.1856598 0.12200163 0.036898 0.02026484
0.4594205365 0.2494227615 0.529203491 - - 0.1856598 0.12200163 0.036898 0.02026484
0.9585624075 0.3865081103 0.889974657 0.839167102 0.9334535
0.7465978919 0.3438233286 0.678867836 1.353689969 1.0647205
0.4516707643 0.2696685611 0.529428237 - - 0.1691841 0.14727245 0.0415327 0.314520572
0.9579481289 0.3797877919 0.69713944 0.815007342 0.9172233
0.7446024874 0.2014866938 0.469456825 1.103267263 1.0462079
0.4478716675 0.1925328319 0.355567014 - - 0.7272633 0.75974198 0.0491776 0.011773149
0.9600317428 0.3679926777 0.945912717 0.760528824 0.888737
0.7515134328 0.5748586632 0.737586668 1.029520241 1.0137157
0.4609922249 0.0571486591 0.476883277 - - 0.4701511 0.00665974 0.0837817 0.000977616
0.9602300462 0.36509572 0.954349706 0.747758574 0.8817406
0.7521925569 0.6110068647 0.746393141 1.012233281 1.0057354
0.4622764509 0.0238974153 0.468888195 - - 0.5317272 0.00116803 0.0933141 0.00016851
0.9604325195 0.3630136986 0.96043252 0.738721585 0.8767123
0.7528898821 0.6369863014 0.752889882 1 1
0.463594295 0 0.463594295 - - 0.5774056 0 0.1003924 0
MEZCLA

z de parametros de energía (amk)

476.4 986.5
0 164.5

84 0

Energia fraccional
Area Fraccional por por grupo funcional Volumen fraccional Area fraccional evaluada en
grupo funcional (sk) Evaluado en reparto (Ji) reparto (Li)
0.41406 0.77778 1.00000 1.00000
J L
0.00000 0.55044 1.35369 1.14063
sk
0.58594 0.60640

GAMMA
X1 GAMMA X2

1 2.138205091

1.00436 1.907162531

1.000082 1.693393194

1.069569 1.435336069

1.094705 1.56149513

1.249268 1.152883813
1.249268 1.152883813

1.234563 1.586916814

2.173722 2.163041055

1.740083 1.007666599

1.868323 1.001337433

1.969536 1
 GRAFICAS PXY
298 K 298 K

GAMMA 1 GAMMA P.BUBLE X acetone GMMA 1 GAMMA2 P.ROCIO

2.57 0.95 16.8083565 0 2.57828055 1 16.2050494
2.25880998 1.16136347 21.2864154 0.1 2.33975856 1.05231595 18.3703547
1.8775643 1.44480304 24.8194794 0.2 2.2725533 1.05398748 19.8641166
1.60546427 1.10067965 27.521719 0.3 2.05263368 1.0439499 21.63112
1.63787518 0.96245279 29.5977345 0.4 1.99925582 1.03683704 23.750628
1.26458558 1.33967884 30.4483551 0.5 1.55760435 1.13775927 26.382985
1.62879687 0.2498171 31.4392699 0.6 1.75879866 0.97661407 28.0492605
2.42020476 -3.96523743 31.7318253 0.7 3.41578779 0.6068577 31.3834365
1.03742305 1.85934448 31.4952307 0.8 1.05566954 1.79635124 31.3168099
1.0092089 1.67367762 30.4632294 0.9 1.00929774 2.01124491 30.8568145
0.86 0.08726218 26.1971374 1 0.86 1.37179089 26.1419706

328 K 328 K

GAMMA 1 GAMMA P.BUBLE X acetone GMMA 1 GAMMA2 P.ROCIO

2.57 0.999 68.2312271 0 2.57828055 1 67.3494996
2.1119807 1.02846349 80.0095692 0.1 2.26751843 1.01413472 73.5756859
1.78113646 1.14121574 90.5412406 0.2 2.17380454 1.0175046 79.4899405
1.54189075 1.10241065 97.1731399 0.3 1.91011018 1.01552621 84.7028329
1.58957041 0.98923791 101.8982 0.4 1.86779283 1.01696909 91.8354949
1.23816691 1.31364194 104.62586 0.5 1.4016161 1.13707273 98.0818177
1.60645396 0.45936602 105.770035 0.6 1.68477168 0.9836232 104.554807
2.3655151 -2.71991158 104.645957 0.7 3.27836281 0.5485004 106.186213
1.03361821 1.77314876 104.146019 0.8 1.03075627 1.93834929 100
1.00824495 1.72959323 99.5481548 0.9 1.00506781 1.89601774 90.6265233
0.86001 -0.12820911 82.2041449 1 0.86 1.37179089 82.8116078

500 K 500 K

GAMMA 1 GAMMA P.BUBLE X acetone GMMA 1 GAMMA2 P.ROCIO

2.57 0.87 6419.78205 0 2.57828055 0.76 6419.78205
1.6599902 0.89724206 6709.49948 0.1 1.84678338 0.75248953 6603.95051
1.47544368 0.93834316 6837.63114 0.2 1.6482705 0.77501416 6826.18781
1.33597957 0.99287862 6850.39479 0.3 1.33924846 0.83214373 6813.42288
1.43086767 0.94353373 6474.57607 0.4 1.40601462 0.79037791 6569.26144
1.15070856 1.02343764 5976.15636 0.5 1.07224386 0.97445399 5958.04075
1.53239155 0.62276165 5322.89125 0.6 1.59523829 0.47615887 5255.56757
2.19223804 -0.52466817 4797.64974 0.7 2.24530294 3.66053645 4728.81872
1.02119862 0.76096804 4151.5562 0.8 1.00307551 0.85212629 4292.83149
1.00515032 0.59787425 3870.22052 0.9 1.00051634 0.4774812 3838.65912
0.86001 -0.73919092 3310.53112 1 0.9 2.37179089 3310.53112

P 1KPa P 1KPa

GAMMA 1 GAMMA T.BUBLE X acetone GAMMA 1 GAMMA T.ROCIO

3.46823183 1 253.098852 0 3.42509952 0.305 253.04963
2.69239974 1.41374992 247.514142 0.1 3.3658843 0.28509619 252.451661
2.16128462 1.92444719 244.463576 0.2 3.71125861 0.24500073 250.184756
1.79152981 2.82316774 241.538669 0.3 3.14116321 0.27200952 249.686834
1.78085656 3.70498316 239.712225 0.4 2.96669147 0.27743611 247.631147
1.34171911 5.36276848 238.174058 0.5 2.64813212 0.26653303 246.019533
1.69709101 6.52086184 237.272503 0.6 2.54000186 0.23870952 244.83404
2.60739215 6.80666919 236.540612 0.7 3.84354721 0.2222728 241.189848
1.04875377 15.1527501 236.537262 0.8 1.20586874 0.35737336 239.463024
3.9920948 2.62748514 236.577252 0.9 1.016629 2.53471581 236.485568
3.5 3.28011781 237.679203 1 1 3.28012694 237.636757

P 100KPa
P 100 Kpa
GAMMA 1 GAMMA T.ROCIO
GAMMA 1 GAMMA T.BUBLE X acetone 2.56553923 0.7 337.773692
2.56192627 1 337.357961 0 2.40783195 0.70110065 335.553283
2.1133784 1.06047233 333.444978 0.1 2.20971778 1.12022083 333.763194
1.78650649 1.19142049 330.541584 0.2 1.94461564 0.67324479 332.37604
1.54716525 1.39310988 328.262304 0.3 1.89824533 0.65163906 330.842366
1.5964451 1.44943231 327.099571 0.4 1.43167421 0.737286 328.350362
1.24098358 1.86644346 326.425694 0.5 1.65104567 0.69041015 326.388753
1.61193736 1.49932922 326.10647 0.6 2.83818603 0.37137476 326.41848
2.39775844 -0.46732254 326.233732 0.7 1.02352893 0.65192172 328.2067
1.03391898 3.77069995 326.020917 0.8 1.00333104 1.24811344 331.023147
3.98828427 -20.9646129 327.266927 0.9 0.84 2.36583093 333.19226
1.15 -1.63422087 333.758328 1

P 1000KPa
P 1000KPa
GAMMA 1 GAMMA T.ROCIO
2.13820509 1.25 409.480825
GAMMA 1 GAMMA T.BUBLE X acetone 1.90716253 1.20436035 408.692166
2.14628994 1 410.496455 0 1.69339319 6.50008199 406.689113
1.83279604 1.02857057 406.190635 0.1 1.43533607 1.31956903 404.348116
1.59701323 0.9937807 405.816638 0.2 1.56149513 1.24470488 403.141722
1.41977087 1.09546789 403.144078 0.3 1.15288381 1.54926805 403.336578
1.49830367 0.96711114 403.220846 0.4 1.58691681 0.78456262 406.984869
1.18685421 1.16149436 403.690614 0.5 2.16304106 0.42372202 410.991773
1.56606656 0.48531545 403.980253 0.6 1.0076666 0.84008298 417.376488
2.28682367 -1.90513643 404.498739 0.7 0.80133743 2.36832309 422.89789
1.02613171 1.37855857 406.625132 0.8 0.82 1.96953607 425.499885
3.98633519 -26.2427745 412.446956 0.9
0.7 -3.03025123 425.544474 1
 GRAFICAS

35
Y ACETO
0 30
0.1
0.2 25
P.BUBLE
0.3 20 P.ROCI
0.4 O
0.5 15 P.BUBLE
0.6 P.ROCI
0.7 10 O
0.8 5
0.9
1 0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

120

Y ACETO 100
0
0.1 80
0.2
0.3 P.BUBLE
60 P.ROCI
0.4
O
0.5
40
0.6
0.7
20
0.8
0.9
0
1
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

8000
Y ACETO 7000
0
0.1 6000
0.2
5000
0.3
P.BUBLE
0.4 4000 P.ROCI
0.5 O
0.6 3000
0.7 2000
0.8
1000

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
 P.ROCI
O
3000

2000

0.9 1000
1 0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

255

250
X acetone
0 245
0.1
0.2 T.BUBLE
240
0.3 T.ROCIO
0.4
0.5 235
0.6
0.7 230
0.8
0.9
225
1
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

340
338
X acetone 336
0
334
0.1
0.2 332
0.3 330 T.BUBLE
0.4 T.ROCIO
328
0.5
0.6 326
0.7 324
0.8 322
0.9
320
1
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

430

X acetone 425
0 420
0.1
0.2 415
0.3 T.BUBLE
410
T.ROCIO
405

400
 420

415

410 T.BUBLE
0.4
T.ROCIO
0.5 405
0.6
0.7 400
0.8
395
0.9
1 390
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
ENERGIA DE GIBS