" «veyansec BOSON Classes (Bete noes GRANGER 2019 DYNAMIC DISCUSSION SHEETS. Rela GENERAL ORGANIC CHEMISTRY boat 4. The number of secondary hydrogen in 2,2-dimethyl butane is (ays (B)6 (4 (D2 2. Geometry of methyl free radical is (A) Pyramidal (B) Planar (C)Tetrahedral (O)Linear on ne ban 3 : New Noy oo o « Te corect stabi oder ofthe given cenoical sutures is (A)X>Y>Z (B)X>Z>¥ (C)Z>Y>X (D)Z>X>¥ NO, NO, a fi O och, 0 a ay Which of the following order is correct for dipole moment of the above compounds ? (aye teil (B)I> >I ()i> tt (O)N>1> 5. Which of the following is the correct order of effect. (A)-NO, >-CN > -COOH (8)-F > Cl>-Br>4 8 e 8 8 (©)-NH,>—NH.Me>—NHMe,>NMe, (0) H > — Ph >— CH= 6. Aromatic compounds are: A ° CO ALAN ® (©) e ©) H 7. Which ofthe following is/are correct statementis about inductive effect (A)Itisa permanent effect (B) tis the displacement of electrons through © bonds (C) tis a distance dependent effect (D) tis dominates over resonance effect some times 8. Which of the following is / are resonance structure of diazomethane (CH,N,) ) GN ©) Gu,—¥: Ce g 2, ¥ 9. Which ofthe ions are aromatic? (A) Cyclopropenyl cation (B) Cyclobuteny! dianion (C) Cyclobutenyl dication (D) cyclopenta-1,3-dienyication (oav) 6 = (aoav) 8) (aoav) (aav) 9 W) + @ @) 7 @ + ‘SUaMSNY CHEMISTRY 1 (aay) s[= ALLEN)” «evansec BOSON Classes ‘CAREER INSTITUTE| [Pe sss RONEN Prove Methodseny fr Prepon of KVPY and lens Senos Ohact 2019 DYNAMIC DISCUSSION SHEETS: CHEMISTRY foam ee Nomen LST Prey 4. Which of the following is the weakest acid ? nw » 2 OS i WNT SW a i Which nitrogen is most basic in the above structure ? (A)1 (B)2 (c)3 (05 3. Most stable alkene is CO OO CO 9OO H. H H ©, a oS ox S HH Arrange the (C-H) bonds x, y and z in decreasing order of their bond dissociation energies in homolysis (y>x>z (B)z>x>y (C)z>y>x (D)y>z>x Paragraph for Question No. 5 to7 {fa compound or ion follows following criteria Itis said to be aromatic in nature ‘It must be a cyclic compound or ion ‘All atoms in ring must be in a same plane. ‘It must follow Huckel rule ie. total number of x electrons must be equal to (4n+2). where n=0, 1,2, 3,..,. 5. Which of the following will exhibit least dipole moment o ° ° al ® A © oO ©) ‘ 6. Anon-aromatic compound (A) (C,H,0) can be converted into an aromatic species, on treatment with strong base. The structure of compound (A) can be OH enmol ° ° IL 0 ws oY “on ™ O Z (ALI (B) 1, mV (cyiiiv (OVlLV ° 7. Which of the following reaction is not possible cl on ° “og 14890. eG ms oC) sc, oO Hoe tw) @ 9 (©) @ + @ ¢ O t= @ + SUaMSNY CHEMISTRY 2" «veyansec BOSON Classes => ALLEN ‘CAREER INSTITUTE| Pate oc ECLNGNTSEEON 2019 DYNAMIC DISCUSSION SHEETS: CHEMISTRY foam ee Nomen LST Prey 4. Which of the following o-bonds participate in hyperconjugation ? ir (a) 1. (Bla jan (D) None of these 2. Thecorrect order of C-N bond length of following compound is Nis My Nts (A)L> the lV (B)il>1> > v (Cpil> the tev (D> Ive tet 3. Which of the following radical is most stabilized ? “ Co ®) ODO © CO : ©) Se) 4. Order of acidic strength will be HC E— cH A HYC—-E—E—cHy Ml) Hyo—E—CHs—F—CHy (aay > ay > () (8) (> (> (N) (©y(h> a>) (Oy(> a>) 5. Whatis the acidity order of x, y & z ? Hai ity COOH wo (Ayx>y>z (8)x>z>y (C)y>z>x (D)z>y>x 6. Which of the following carboxylic acids is / are more acidic than benzoic acid ? coon coon 00H Coon CMe on a Oo (8) «© (oy) (Mt; cy 7. Which of the following compounds will give precipitate with AgNO, solution ? 5 ws on “Oo “O oly oO (0) (ao) oz (av) 9 @ § @ » O& t€ Oo @ZMmM + ‘SUaMSNV CHEMISTRY 3