\sueament” SOLID STATE CHEMISTRY Seetion- A; Objecti Ha compound is formed in a FCC lattice 3th M atomns at the corners of the unit cell N ators at the face centers, the formula of the compound will he (a) MN (b) MN, (MN (MN, Which of the parallelograms in the figure below are viable ‘unit cells? type 0) (b) (ii) (o) (iii) (d)Allorthcahove. How mithy atoms are there in ane lement packed in a fee structure taj (b)2 (4 (ays | The coordinates for the atoms in a body cemred cubic unit cell are ee (a) @, 0, 0).and (1/2, 0, 0) (b)(0, 0, 0) and (112, 1/2, 1/2) B (c).(0. 0, 0) and (0, 1/2. 0) (d) (0, 0, 0) anc (0, 0, 1/2) A erystalhas the lattice parameters ab ¢¢and a= (b= 7-90". The crystal system is f a) Veuaconal (b) Monoclinic (c) Cubic (4) Onthorhombic apart metal crystallizes in the face-centered cubie lattice parameter of 4.20A. The shortest atom off gofitact distance in the lattice is * a420A, (b) 2.97A (c)2.42A (4) 2.104 "he inter planar distance (A) for a (100) plane in a cubie structure with the lattice parameter of 4A is: (a) (b)2 (e)4 Ws The packing efficiency for the following cubic structures varies as follows : diamond (D), simple eube (SC) face centered cube(FCC) and body centered cube (BCC). (a) D>FCC>BCC>SCC (b) FCC>BCC>SCC>D (c) BCC>FCC>SCC>D (d) D>SCC>BCC>FCC MnO has 4 NaCl (rocksalt) structure with the unit cell parameter a~4.43A. The Mn--O distance in MnQ i (b) J2X4.43A (6) 4.43/24. (4) 4.43/34 (@) 443/24 The lattice parameters fora monoclinic crystal are (ba=becaspry (a) ax beciasy=90° (Jaxbecaapry Sodium metal crystallizes in the body centered cubic lattice with cell edge a, The radius of the sodium atom is: (by av /2 (© av3/4 (a) a/ 22 (a) a/V272. L Inaclose packed (hcp, ccp) arrangement of a lattice comprising of atoms of akind, the number of ttrahed and octahedral holes present respectively are: {a)2n and 2n (b)nandn (c)nand2n (d)2nandn 13, Calculate the fraction of the volume of Alffec) occupied by its atoms (a) 0.255 (b)0.740 (00.414 (0.875 14 The erystal structure of Pb,O, contains : (a) Octahedral and tetrahedral units (b) Only octahedral units (c) Octahedral and pyramidal units (d) Octahedral and square-planar units. 1S. Cubic close packing of n spheres zenerates the following number of interstitial sites. (a) 2n octahedral and n tetrahedral sites. (b)n octahedral and n tetrahedral sites. (©)2n octahedral and 2n tetrahedral sites (d) noctahedral and 2n tetrahedral sites. 16. Accrystal having lattice parameters a = b + ¢, a= B= y = 90° belongsto the crystal system. (a) monoclinic (b)Orthorhombic ©) Rhombohedral_-—_(d) Tetragonal }7. _ Aerystal system is determined by the lengths (abc) and the angles (acBy) of the unit cell. For Orthorhom system these are (urbe: a=B.y--90° (b)a=bec, a=B=7=90° ik (arbee; a=B=y=90° @azbecq axpey290" ‘The packing factor of a body-centered cubic lattice is (2) 0.59 (b) 0.68 (00.77 (4) 0.46 19K MnO hasa NaCI (rocksalt) structure with the unit cell parameter a=4,43A, The Mn-- Odi ® . (a) 4.43/24 (b) V2 4.434 (©) 443/V2 A (d) 4.43/ BAY | YW ‘The structure obtained when all the tetrahedral holes are occupied in a fec structure is of the type + (@)NeCl (b)CsCh (©) CaF, (ZnS ti 21, ‘The lattice parameter ofan element stabilized in a fee structure is 4.04 A. The atomic radius of the elements? - (0) 286A (b) 143A (429K ()5.RA 22. Ametal crystallizes in fee structure with a unit cell side of 500 pm. Ifthe density of the crystal is 133 g/ee,the ‘molar mass of the metal is close to (a)23 (b)24 (c)25 (d)26 23. Metallic copper and iron have respectively fec and bee structures at room temperature. he coordination numbers of copper and iron in their structure are (a)Cu:12andFe:8 — (b)Cu: 8and Fe: 12 (©) Cu: 6 and Fe: 8 (Cu: 6 and Fe:6 24 as a perovskite crystal structure, The coordination numberof titanium in CaiO. is (b) 6 ©3 (d) 12 25 ‘The arrangement of sulphur in zine blende and wurtzite structures, respectively are : (a) Hexagonal close packing and cubic close packinig (b) Cubic close packing and hexagonal close packing (©) Simple cubic packing in both the structure (@None of theseJ _ @)Ca7i,.0, (Caio, (Caio, (CaO, 2 | AZine selenide crystallizes in 7incblende structure. How many atoms of Zn and Se are present inthe 33. Coordination number of °C” in Be,C, whose structure is correlated with that of CaF is: 35 36. 37. fA The atomic radiu , Calcrun fluonde ystallizes m fluorite stcture. The coordination srber forthe cation and anton isrespectively {a 6,6 (6)6.4 (4,6 @a4 Inthe CSCI structure. the nurnber of ions in a unit cellis: (a2 tb) 6 8” * ‘The stsucture of CsCl transforms to NaC! under high pressure During this process the coontifatign number of Csand Ci-change from % (8B, (b) 66 () 12:12 (0)8:6 ‘The coordination number of the Ba ions in barium flucride is 8. The coordination nurnber of the fuoride-ion is: (a) 8 (b)4 (I (62. Zine selenide crystallizes in zineblende structure. The numbers of atoms of Zn and Se eset in its unit cell are: (a8 (b)6 4 (a) I2 What is the empirical forma for the following unit cel (a8 tb) 6 (4 (a2 (a2 {by 4 ()6 (8 ‘density 3.62 pcm” is (a) 1.510% (b) 1.6x107 (©) 20x10 =. (d) 22x10* Gold crystallizes in face-centrered-cubic lattice. The atomic weight and density of gold are 196 97 and 19.4 af can’ respectively. The length of the unit cell is: (a) 2.563A (b) 3.2304 (©) 4.0704 (8) 8.1404 An element crystallizes both in FCC and BCC lattice. the density ofthe element in the two forms is the same, the ratio of unit cell length of FCC to that of BCC lattice is. 1 s 1p ‘ 1 (@) (23 (3) © (45 w(t} Anelement A(At, Wt. 69.22) crystallizes m the fcc close-packed lattice and has a density of 8 gm/cc, the unit cell lattice parameters of Ais: (2)3.65A (b)2.65A (435A (235A Consider an orthorhombic unit cell of dimensions a=450 pm, b~650 pm, and ¢=400 pm. The perpendicular distance between the (110) planes is (a) 650 pm (b)450pm = + —()370 pm (€)500 pmBw. 40. 42 a 48, 49, "manner. The separation ofthe layers in the crystals is 404 pm. Find he angle along which the first Fora FOC lattice, which of the following statements is correct? (a)h, k, f valves are all odd or all even {byh. k. I valuesare all ever (©)b, k, I values are all odd (dyhs k# fareaileven The second order Brag diffraction trom the: 100 planes of a cubic erystal isequivalent tO a) The second order diffraction from the 200 planes ” {b) First order diffraction from the 200 planes. (€} First order diffraction from the 400 planes. (d) First order diffraction from the 100 planes. ° A plane of spacing “d’ shows first order Brayg diffraction at angle QA plane of spacing 24 6 {a) shows Bragg diffraction at 20 (b) shows Bragg diffraction at 2 (C)shows Bragg diffraction at sin (2°) (d) shows Bragg diffraction at 5" ‘( . 2) Fora fcc lattice the miller indices foethe first bragg’s peak (smallest bragg angle) are: (2) 002 yin (©)001 (a 10 ‘The X-ray powder pattern of NaCl shows an intense cone at @_15,87°. Using X-rays 1.54 10°* cm. The spacing between the planes (in A) of NaCI crystal is. fatal (b) 2.82 (©)4.23 (d) 5.63 ‘The condition for complete distructive interference of monochormatic X-rays of wavelength’ « Suceessivecrystal planes of interplanar spacing dis: am fa) AABdsino (b) A Adsin® () A. 2dcosO (d) i ddcos0 Thevalue of d,,, ina cubic crystal is 325.6 pm. The value of d,,, is 155395 6pm (b) 976.8 pm (©) 108.5 pm (4) 625.6 pm -rays of CuK, (wavelength 154 pm) are diffracted by a set of atomic planes in acrystal in the fol reflection will occur, Bh Se (2) 79° (b)4s° ue (d) None of the above ‘A crystal plane is parallel to the x-and y-axes and makes intercept if, on the z-axis. The Miller indieesof the plane are (a1i2 (b) 220 (©)001 (a) 002 The angle beeen the wo planes represented bythe Miler nies ( 10)and(11 Dinasome ie ae i a 30° (b) 45° (c) 60° (d) None of these The structure ane 0,1) plane ina simple cubic lattice is: fa)1 (b)2 ()3 (da50 woo ante hie amount of L,O.in air at 1200°C: anen-stoichiometric compound Li,Ni,, 0 (a) An metype semiconductor containing only Ni'* (b) An n-type semiconductor containing Ni* and Ni* (©) p-type semiconduetor containing Ni® and Ni* (4) A p-type semiconductor containing only NP* NaClis crystallised by slow o -vaporation of iis aquen (a) Theerystals willbe non-soichiometnc (b) The crystals should have Frenkel defects (c)’The percentage of defects in the crystals will depend on the concentration ofthe solution and its rate solution at room temperature: The correct statement is: of evaporation (4) The nature of defects will depend upon the concentration of the solution and its rate of ‘evaporation 52. Which of the fptlowing, when doped into a crystal of ultra purified Germanium, will conven it into p-type semiconductor? > aC (b)As (c)In (d)Na ing.10 band theory of bonding, conduction occurs in very good conductors because : -e band is full (b) Valence band and conduction band overlap (& Band gap is smal | resistivity of'a semiconductor 's with temperature ) Decretses with emperature Inereases. at low temperature and then decreases at high temperature : Does not change with temperature ae following has the largest band gap energy? ff) Ge (b) Silicon (0) Tellurium. (d) Diamond ic crystal lattice in place of an anion fa)Frenkel detect. (b) Schottky defect _(c) F-Center (@) Dislocations Among the following elements, the one that acts as the major component ina semiconductor is (ac (b)Si ()Ga (As 58. ‘The crystal systems having the highest and the lowest symmetrices respectively. are (a) Cubic and rhombohedral (b) Cubic and trielinie (c) Rhombohedral and monoclinic (4)Cubie and monoetinie. 59. The incorrect statement for solid sodium chloride is that (a) Both sodium and chloride ions adopt inert gas configuration (b) The conduction band is full (©) The conduction band isempty (a) The valence band is full. 60. ‘The electrical conductivity of a crystalline solid increases with temperature. The solid isa (a)Superconductor —_(b) Metal (c) Semiconductor (d) Semimetal 61. Thenumber of electrons (per second) that pass through a cross section of copper wire carrying acurrentof _ 10° Ais: (a) 62.5x10 c/s (b) 120s () 12000 e/s (A) 0.625%10" e/sG2. Whichof ne following statements is always tue regarding conductors and semiconductors? (4) Semi-conductorsarehalfs good as conductors when comparing their electron mobility (b) Conductors have large band gaps and semi-conductors have small band gaPs- (c) Conductors and sems-conductors do not conduct electricity at high temperatures. (d) None of the above statements are true. 3 1.98eV. The correct statement 63. Consider a n-type semiconductor whose E, = 0,12, = 2.0eV and Ey among the following is {a) E, eV and isindependent of (b) E, = 1.99 eV and remains independent of T {c) E, =1.99 eV and increases towards 2.0 eV with increase of T (4) F, =1.99 eV and decreases with increase of T. 64, ‘The wavelength and the spectral egion for a single electron transfer across the band gap (E, -1.98%10") are [h = 6.626%10""Js, ¢=3%10° ms" | (@)10000m. UV (b) 1000nm,1R ——_(€)500nm, visible (a) 500mm, FAR IR Amon the following isostructural compounds, identify the compound which has the highest (a LiF | (b) LiCl (©) NaC} (d)MgO in asemi¢