Eepindo deli a Fer peers MATERIAL SAFETY DATA SHEET PRODUCT : HYDROCHLORIC ACID SOLUTION (HCI) - 32% IDENTIFICATION ‘COMMON NAME CHEMICAL NAME Hydrochloric Acid, Aqueous Hydrochloric Acid ‘CHEMICAL FORMULA: HAZARD CLASS HCI faq) ‘Conosive DOTUN DOT LABEL: 1789, Poison gas, corrosive use - Ass laboratory reagent - For pickling and heavy duty cleaning of metal parts: rust and scale remaval Far hydrolyzing starch and proteins in preparations for food = _As“spitts of salts" for clearing of ime and masonry fram new brickwork. ~ As Tix of flux component for soldering: manufacture of “killed spirits” PHYSICAL DESCRIPTION / PROPERTIES APPEARANCE : Clear, colariess to pale yellow SOLUBILITY INWATER: Soluble SPEC. GRAVITY : 1,185 for 32% conc. At 20 CORROSIVITY : highly corrosive to most metals. FLASH POINT = Not combustible ODOUR : Sherp, suffocating odour BOILING POINT : > 120° MELTING PONT: -20°C FLAMMABILITY > Non ftammable VAPOUR PRESSURE - « 2¢.8kpa @ 25°C INGREDIENTS (CHEMICAL ENTITY CAS NO_ PROPORTION ‘Hydrochioric Acid ‘7647-01-0 Min, 22% Free Chiorine - Max. 10 ppm Fe Mer toe Eepindo deli 2 HEALTH HAZARD INFORMATION EFFECTS OF OVEREXPOSURE HEALTH EFFECTS : ACUTE, CHRONIC SWALLOWED; Contidered an unlikely route of entry in commerciallindusttial ‘environments. The liquid is extremely corosive if swallowed and is ‘capabie of causing burns to mouth, throat. esophagus, with extreme discomfert, pain and may be fatal # swallowed in quantiy. Ingestion ‘may result in nausea, abdominal iritation. pain and veriting. EYE CONTACT: Eye contact ts extremely pamtul and may cause rapid comeal sSamage. The liquid is axiremaly corrosive tot he eyes and cacable of ‘causing severe damage with loss of sight. The vapor is highly initating and may be corrosive to the eyes. The vapor from heated material is extremely rating, INHALED “The vapor is Fighiy imitating to the upper respiratory tract. Inhalation hazard ie increased at highor temperatures. ‘The vapor from Nested ‘ateial i extramaly intating ta the upper respiratory tact ad lungs and any contact may cause rapid issue destruction if inhaled SKIN ‘The ‘iquid f= extremely corrosive to the skin and contact may cause rapid tissue destruction with severe bums # exposure is prolonged. ‘The vapor is imitating to the skin. Bare unprotected skin should not be exposed to this material The material may secentuate any pre- existing skin congiten. Highly corasive and considered toxe by al exposure routes. Principal reutes of exposure ave usually by skin contacifeye contect with the liquid. As with any product cantact with unprotected bare skin; inhalation of vapor, mist or dust in work place ‘atmosphere: or ingestion in any form; should be avoided by observing food eccupational ‘work practice, EMERGENCY FIRST AID PROCEDURES SWALLOWED: Rinse mouth out with plenty of water. F poisoning occurs, contact a doctor or poisons SIN: information center. If swallowed, do NOT induce vomiting. Give 8 lass of water. IF this product comes in contact with the skin. immediately fush Body and clothes with large amounts cf water. using safety shower, if avaiable. Quickly ramava all ee arenasXpindo deli 2 contaminated clothing, including footwear. Wash allocted areas with water ( and soap if available ) for atleast 15 minutes. Transport to hospital of doctor. EYES. lihis product comes in contact withthe eyes, imniedialely hold the eyes open and Wash continuously for at least 18 minutes with fresh running water. Ensure irigation under eyelids by occasionally iting the upper and lower ids. Transport to hospital or {doctor without detay. Removal of contact fonses afer an oye injury should only be Undertaken by skied personnel INHALED: {fumes or combustion products are inftaled, removed ta fresh sir. Lay patient down. FIRST Keop warm and rested, IF breathing is shallaw or has stopped, ensure clear airway ‘and apply resuscitation, Transpost ta hospital or doctor. AID FACILITIES: Eye//skin wash station. ADVICE FOR DaCTOR For actto or short term repeated exposures to strana acids 1 2 a 4. Ingest z Airway problems shay arise from larmgeal edema and inhalation exposure. Treat with 100 % oxygen inital. Respiratory distress may require cricothyroidotomy if endotracheal intubation is contrainicated by excessive eweling. Intravenous lines should be established immediately in all cases where there Is evidence of circulatory compromise. ‘Strong acids produce 2 coagulation necrosis characterized by fermation of 2 cosguluti (escha) as.a result of the desiccaling action of the acid on proteins in specific issues. lmmediste dilution (milk or water) within 30 minutes post ingestion is recommended Do not attempt to neutralize the acid sinés exothermic reaction may extend the corrosive injury. Be careful to avoid further vomil since re-expasure of the mucosa to the acid is harreful. Limit ‘fluids to one or two glasses in an adult. Charcoal has na place in acid management. ‘Some authers suggest the wee of lavage within 1 hour of ingestion ‘Skin fesions require copious saline irigation. Trest chemical pune ae thermal buene with nen adherent gauze and wrspping, (Deep sectnd degree bums may benefit from topical silver sulfadiazine Eye injuries require retraction ofthe eyolids 1o ensure thorough irigation of the exrjunatival cub de-saes._inigation sheuld Inst at least 20-90 mirtutes. Do fot use neutralizing agenis or any ‘ther additives, Several iters of saline are required ‘Cycloplegéc drops (1% eyclopentolate for short tem use 5% homatropine for langar term use) ‘anuivodc Crops, vasoconstictive agents of artical tears may be indicated dependent or the covesity af the injury. ‘Steroid aye drops should only be acninistered with the approval of s consuting opthalmologist.3 vindo deli pindo deli £7 PRECAUTIONS FOR USE EXPOSURE STANDARD ; Non assigned for mixture: Hydrogen Chiaride Tc ppm, 7.5 mana IDLH Level“ 100 ppm ES posk Spm: 7.5 maim Note : detector tubes for Hycragen Chloride, measuring in excess of 1 ppm, are available commerciaty, ENGINEERING CONTROL Use in well ventisted area and fecal exhaust ventilation required. If risk of inhalation or overexposure exists, wear SAA approved respirator or work in fume hood. Hydrogen Chionde. ‘vapours wl nol be adequately absorbed by orgarsc vapours recpiratare. PERSONAL PROTECTION : EYE ‘Chemical goggies: full face shield, contact lenses pase a epseial hazard: soft lenges may absort irtants and all eises concentrate them. HANDSIFEET Barer cream and neoprene rubber gloves or PVG gloves or butyl rubbar gloves. PVC boots or PVC safety gumboots or safety footwear. OTHER . ‘Operator should be trained in procedures for sale us of this material. Acid resistant overalls or PVC apron or PVC protective clothing. Ensure there is ready access to an emergency shower and eyewash urit, The local ‘concentration of material, quantity and conditions of use determine the type of personal protective equipment roquitod. For furthor information, const site specific CHEMWATCH data (ff available) er your Occupational Health and Safety Advisor. SAFE HANDLING INFORMATION REACTIVITY DATA STABILITY : YES INCOMPATIBILITY : ‘Strong bases. metals. metal oxides, hydroxides, amines, carbonates & other alkaline materials, ‘yanices, suliides, CONDITIONS CONTRIBUTING TO INSTABILITY ‘Containers may burst when heated. HAZARDOUS DECOMPOSITION PRODUCT ‘Toxic gases and vapors such as chlorine may be released in a fire involving hysrochioric acid.Apindo deli 2 CONDITIONS CONTRIBUTING TO HAZARDOUS POLYMERIZATION: Material is nel known to palymerize. STORAGE & TRANSPORT ‘SUITABLE CONTAINER Packaging ac recommended by manufackrar, Chack that containers are clearly labeled. Packs oF 25 res or less require 2 chid-resistant ciosure. Glass. container or plaste carbay or Polyined drum are normally used. ‘STORAGE INCOMPATIBILITY Segragata fram sikalies, ondeing agents and chemical readily decomposed by acid. ie cyanides, sulfides, carbonates. Avoid storage with metals, motal oxides. hydraxides. amines, Carbonates, alkaline materials, acetic anhydride, cyanides, sulfides, suMites, phocphides, acctylides, borides. carbides, siicates, vinyl acsiate, formaldetyde and potassium permanganate. STORAGE REQUIREMENT Floor should be covered or coated with acid resistant material, Store in original containers, Keep container securely sealed. Store in a cool, dry, welhwentilated sree. Store away from incompatible materials and foodstuff containers, Protect containers against physical damage and direct sunlight Check regularly for leaks. Observe manufactures storing and handling recommendations, TRANSPORTATION Class § | Corasive shall not be loaded in the same vehicle or packed in the same freight ‘container with Class 1 - explosives ‘Class 4,3. — Dangarcus when wet substances Glass 5.1. — Oxidizing agents Glass 5,2. = Organic peroxides Class 7 — Radiosetive eubetances Cass 8 — Asidoniy Foodstuff and empty foodstuff containers SPILLS AND DISPOSAL MINOR SPILLS DO NOT touch the spi material clean up all spillage immediately. Wear fuly protective PYG ¢fothing and breathing apparatus. Gortain and absorb spiloge witn sand, earth inert material OFBpins vermiculite. Use sada ash or sleked lime 1g neutralize, Collect residues and place in labeled plastic comainers with vented! lis MAJOR SPILLS BO NOT touch the spill material clear ares of personnel and move upwind. Alert Fire Brigage and tel! them ihe location ang nature of hazard. Shut off all possible sources oF ignition and omese vention. Wear tl body protective citing with Breathing spparatus, Proven, by result of the ebowe actions, advice emergency services. Collect residue and place in labeled plastic containers wn verog ls, vrater 5 Feeoverable product into labeled containers DISPOSAL pray or fog may be used to disperse vapeur. Collect for recyciing, Recycle wherever possible. Cengult manufacturer for recyciing options. Consult State Land Masta Menagement Authorty for Disposal. Treat and neutralize at an efluent treatment plant, Bury residue in an authorized incl Decontaminate empty containers with a lene Surry. Rietum ematy containers to supplier or bury emply containers al an authorized land, EIRE/EXPLOSION HAZARD Non sembustible liquid. Witt not bum. but heat ‘Szuse excension ar docompoation leading to vi ‘and produces taxic fumse of Hydrogen Chloride. FLASH POINT ‘SPECIAL PROTECTION PROCEDURES UNUSUAL FIRE AND EXPLOSION HAZARDS - EXTINGUISHING MEDIA : EXPLOSIVE LIMITS: AUTOIGNITION TEMPERATURE ‘REVISION of DATE OF ISSUE — : April 1, 2016 produces highly toxic fumes/vepours. Heating may iolent ruplure af containers. Decompeses on heating Decomposition may produce toxic fumes af chiorne. None ‘Wear full protective clothing and NIOSH ‘Approved Seif Breathing Apparatus with full face piece operated in the positive pressure ‘mods. NA FF inwolved in 2 fre, use water spray. UPPER ; Unknown / LOWER: Unknown Nonflammable