(castSim,}-Chemiso 2018 CHEMISTRY — GENERAL Paper : GE/CC-1 Full Marks : 50 Candidates are required to give their answers in their own words as far as practicable. are wee per Fre) 31 arcartat BEB aca Bea me: (3) spre fears ae SoHE ee GTAT| x) fafa were were caret ) crea SHI ag eaftataTs ay Ca) a omer ers a fora we? (8) mre! eons zene Hi carane ©) irs 8.1. cae once (@) rearrel er corns care? oy) fafirars a apace Some framers wrarateram aa cost | @) crmerea coh Frame Bees seat (8) ‘pwn Tre cere | () wees» wale af Rome eA ‘m/e eI SC CHT ‘sy ¢'p' ge GhOA miter oreAtAA crte: a ea] SHPG/ AHI SoRN Sez () ae BTe we RRR CuO SH AT IE (©) (&) F © (@) Li*-ea W5 Hard/Soft ws 1 #14 foes erat (2) Cut (tema wre 29)-08 Remaaa Re GTR (©) PhCH, © CH; CH)~43 30 oath afte wht anette? (CHC Br 6 CH,Brea 345 GF Sy! faften maLe ware? GAGEICO) Please Turn OverM (Ist Sm. )-Chemistry-GGE/CO-1/(CBCS) Q@) al (0) com Te Yer cate afew © (CHy),€ © CE) CHCH, ©) DStorarateeitnee stoargte cst () Rafat oh ace Com RemaeRe wee co Bem Ble ect: © FeCh (2) RNH, @ CN @ 1,0 Ce) faire entre orcas fia’ apie erat | (2) frataite sretatine eutireofitee eros amma eres cepa are ¢ (@) CCLCOOH (1) CH;COOH —@) CBr,COOH @) CF,COOH (©) wee enters Bex axa IRATE To ors, oy Rae ane aes a aT aA) RTA TCANE HS TE AIG S ROE (2) see oF CHET, AR Ty YB oO WlenaTa (T,> T,) aTMETATAA aeTAN ae Frew Ra asl caeiore aI Gree | (3) am at caf TA cm 279C aT 800 mm Bie ee eS HT GAH (Cyyp) 9 at () Ses eREP es ere ATS ‘al oe ORE BEI Fea STAT | (2) crore em wee @ aT ora ara! oo Ble RABE ee (8) Fates ms enefeewre wees ney eee (©) 62 sera Faber 50% at za 30 FARTS rTM, 75% Fie eo KLE eo AAR TOT (3) 2 fafa e-corm cere @ co areas ote | Ce FARR ame cts cnc, £21804 CH, OH (a) frefaitte refs R/S saftroncaes feta eras H CH,CH, a CH, Br (CHOH br (co) 1-REB EE ERT RUB ale UA, © combate ants selfora wrda ceangs Boffecwe cee Flea | aTAHt Scat)@) Rare oxewsa Bea afew Bret creat (©) Fe oak PRCA one aH, ©) Site seas Be aah Breas we 1 ©) finan tora at gm se cA ara (©) FBR aaVbe ca erate wg BoreaAR aT aA (2) Hsp0,-3 raster 1 fy HPO, Fase 2 are wat ©) BF; 2a BCL-a Hn Co afeees fem ABR ae? OT ATI ish Version] The figures in the margin indicate full marks. Answer any twenty questions : 120 (a) Write down the unit of the rate constant of @ zero order reaction, (b) What do you mean by half life period of a reaction? (©) What do you mean by ‘root mean square’ speed of a gas molecule? (A) What is the average velocity of an ideal gas molecule? (e) What do you mean by viscosity coefficient? (Write down the S.1. unit of surface tension, (B) What do you mean by compressibility factor? (h) Write down the Arthenious equation of temperature dependence of rate constant (9) State one limitation of Bohr’s theory. (D_Draw the shape of p, orbital. (k) What are the possible ‘P and ‘m’ values for a principal quantum shell with n= 2? (Give the general electronic configuration of *s* block and ‘p” block elements. (m) Write down the conjugate acid/base of NH, (a) According to Lux-Flood concept whether CaO is an acid or base? (0) Identify hardisoft acid or base (i) F°, Gi) Li* (P) Give the electronic configuration of Cu (atomic number = 29), (q)_ Which one is the more stable carbocation? CH; CH) PhCH, Please Turn Over[M(IstSm.)-Chemistry-GAGE/CO)-1/(CBCS) (4) (8) Which one of the following species undergoes Sy! reaction more easil (CH) ;CBr, CH,Br (3) Which is the more stable free radical between (CH3),C and CH3CHy? (®) Write down the D-configuration of glyceraldehyde. (u) Identify if each of the following species are electrophile or nucleophile @ FeCl (i) RNH, i) CN" (i) H,0 (¥) Succinie acid is optically inactive—Justfy the statement. (w) Arrange the following carboxylic acids as per their decreasing acid strength : (@ CCICOOH i) CH;COOH Gil) CBrSCOOH (iv) CF;COOH. (%) When maleic acid is heated it forms its anhydride but fumaric acid does not form its anhydride— Explain. Answer any fifieen questions : 2x15 (@) Show graphically how Maxwell’s speed distribution curves vary at two different temperatures T, and T, (T,>T)) for the same gas. (b) Calculate the most probable speed (Cyyp) for 1 gram mole of chlorine gas at 27°C and 800 mm pressure. (©) Find out the unit and dimension of Van der Waal’s force constant ‘a (@ How do the viscosity coefficient of gas and liquid depend on temperature? (©) Distinguish between order and molecularity of a reaction. (®) Fora first order reaction, time for completion of 50% reaction is 30 minutes. Calculate the time taken for 75% decomposition. (8) Show the mechanism of E2 reaction with a proper example. (h) Complete the reaction : Cone. HyC—CH—CH—CH z CH; OH (Write the R/S configuration of the following : H CH,CH, a sa oe Br CH, @ 2-butene is more stable than L-butene. Why? (K) Mesotartarie acid is optically inactive, though it contains chiral carbon atoms. — Explain.@) M(IstSm,)-Chemistry-G(GE/CO-H/ (CBC () Write a short note on Inductive Effect. (mn) Distinguish between orbit and orbital (n) What do you mean by diagonal relationship? Give an example. (0) The electron affinity of chlorine is eater than that of fluorine Explain. (p) State Lowty-Bronsted theory of acids and bases with example. (q) HPO, is monobasic acid but HsPO, is dibasie— Explain, (1) Between BF; and BCl;, which one is a stronger Lewis acid ? — Explain.