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In memory of Leo Szilard, who passed away on May 30,1964, we present

an English translation of his classical paper ober die Enfropieuerminderung


in einem thermodynamischen System bei Eingrifen intelligenter Wesen,
which appeared in the Zeitschrift fur Physik, 1929,53,840-856. The publica-
tion in this journal of this translation was approved by Dr. Szilard before he
died, but he never saw the copy. At Mrs. Szilard’s request, Dr. Carl
Eckart revised the translation.
This is one of the earliest, if not the earliest paper, in which the relations
of physical entropy to information (in the sense of modem mathematical
theory of communication) were rigorously demonstrated and in which Max-
well’s famous demon was successfully exorcised: a milestone in the integra-
tion of physical and cognitive concepts.

ON THE DECREASE OF ENTROPY IN A THERMODYNAMIC SYSTEM


BY THE INTERVENTION OF INTELLIGENT BEINGS
by Leo Szilard
Translated by Anatol Rapoport and Mechthilde Knoller from the original article “Uber die Entropiever-
minderung i n einem thermodynamischen System bei Eingriffen intelligenter Wesen.” Zeitschrift f u r
Physik, 1929, 65,840-866.
0*3
resulting quantity of entropy. We find that
The objective of the investigation is to it is exactly as great as is necessary for full
find the conditions which apparently allow compensation. The actual production of
the construction of a perpetual-motion ma- entropy in connection with the measure-
chine of the second kind, if one permits an ment, therefore, need not be greater than
intelligent being to intervene in a thermo- Equation (1) requires.
dynamic system. When such beings make F(J
measurements, they make the system behave
in a manner distinctly different from the way
a mechanical system behaves when left to
itself. We show that it is a sort of a memory
T HERE is an objection, already historical,
against the universal validity of the
Second Law of Thermodynamics, which in-
faculty, manifested by a system where deed looks rather ominous. The objection is
measurements occur, that might cause a embodied in the notion of Maxwell’s demon,
permanent decrease of entropy and thus a who in a different form appears even nowa-
violation of the Second Law of Thermody- days again and again; perhaps not unreason-
namics, were it not for the fact that the ably, inasmuch as behind the precisely
measurements themselves are necessarily formulated question quantitative connec-
accompanied by a production of entropy. At tions seem to be hidden which to date have
first we calculate this production of entropy not been clarified. The objection in its origi-
quite generally from the postulate that full nal formulation concerns a demon who
compensation is made in the sense of the catches the fast molecules and lets the slow
Second Law (Equation [l]).Second, by ones pass. To be sure, the objection can be
using an inanimate device able to make met with the reply that man cannot in prin-
measurements-however under continual ciple foresee the value of a thermally fluc-
entropy production-we shall calculate the tuating parameter. However, one cannot
Requests for reprints of this paper should be deny that we can very well measure the
sent to: value of such a fluctuating parameter and
Mrs. Leo Szilard
2380 Torrey Pines Road
therefore could certainly gain energy a t the
La Jolla, California 92038 expense of heat by arranging our interven-
301
302 LEO SZILAHI)

tiori according to the results of the ineasure- as well as the motor nervous systems a
nients. Presently, of course, we do not know degradation of energy is always involved,
whether we commit an error by not includ- quite apart from the fact that the very
ing the intervening man into the system and existence of a nervous system is dependent
by disregarding his biological phenomena. on continual dissipation of energy.
Apart froin this unresolved matter, it is Whether-considering these circuin-
known today that in a system left to itself no stances---real living beings could continually
“perpetuuni mobile’’ (perpetual niotion ma- or at least regularly produce energy a t the
chine) of the second kind (more exactly, no expense of heat of the lowest temperature ap-
“automatic machine of continual finite pears very doubtful, even though our ignor-
work-yield which uses heat a t the lowest ance of the biological phenomena does not
temperature”) can operate in spite of the allow a definite answer. However, the latter
fluctuation phenomena. A perpetuuni mobile questions lead beyond the scope of physics
would have to be a machine which in the in the strict sense.
long run could lift a weight at the expense of It appears that the ignorance of the bio-
thc heat content of a reservoir. In other logical phenomena need not prevent us frorn
words, if we want to use the fluctuation phe- understanding that which seems to us to be
noinena in order to gain energy at the ex- the essential thing. We may be sure that
pense of heat, we are in the same position as intelligent living beings-insofar as we are
playing a ganic of chance, in which we may dealing with their intervention in a ther-
win certain amounts now and then, although niodynaniic systen-can be replaced by non-
the expectation value of the winnings is zero living devices whose “biological phenomena”
or negat>ive.The same applies to a system one could follow and determine whether in
where the intervention from outside is per- fact a compensation of the entropy decrease
formed strictly periodically, say by periodi- takes place as a result of the intervention by
cally moving machines. We consider this as such a device in a system.
established (Szilard, 1925) and intend here I n the first place, we wish to learn what
only to consider the difficulties that occur circumstance conditions the decrease of
when intelligent beings intervene in a sys- entropy which takcs place when intelligent
tem. We shall try to discover the quantita- living beings intervene in a therniodynamic
tive relations having to do with this inter- system. We shall see that this depends on a
vention. certain type of coupling between different
Snioluchowski (1914, p. 89) writes: “As parameters of the system. We shall consider
far as we know today, there is no automatic, an unusually simple type of these ominous
permanently effective perpetual motion ma- coup1ings.l For brevity we shall talk about a
chine, in spite of the molecular fluctuations, “measurement,” if we succeed in coupling
but such a device might, perhaps, function the value of a parameter y (for instance the
regularly if it were appropriately operated by position co-ordinate of a pointer of a meas-
intelligent beings.. . .” uring instrument) at one nioment with the
A perpetual motion machine therefore is simultaneous value of a fluctuating parame-
possible if-according to the general method ter x of the system, in such a way that, from
of physics-we view the experimenting man the value y, we can draw conclusions about
as a sort of deus ex machina, one who is con- the value that x had a t the moment of the
tinuously and exactly informed of the exist- “measurement.” Then let x and y be un-
ing state of nature and who is able to start or coupled after the measurement, so that 5 can
interrupt the macroscopic course of nature change, while y retains its value for some
a t any rnornent without expenditure of work. time. Such measurements are not harmless
Therefore he would definitely not have to interventions. A system in which such
possess the ability to catch single molecules measurements occur shows a sort of memory
like Maxwell’s demon, although he would
’ T h e author evidently uses the word “omi-
definitely be different from real living beings nous” i n the sense that the possibility of realizing
in possessing the above abilities. In eliciting the proposed arrangement threatens the validity
any physical effect by action of the sensory of t h e Second Law.-Translator
ON THE OF ENTROPY
DECREASE 303

faculty, in the sense that one can recognize However, it is no longer constraincd to the
by the state parameter y what value another upper part of the cylinder but bounces inany
state parameter z had a t an earlier moment, times against the piston which is already
and we shall see that simply because of such moving in the lower part of the cylinder. I n
a memory the Second Law would be vio- this way the molecule does a certain amount
lated, if the measurement could take place of work on the piston. This is the work that
without compensation. We shall realize that corresponds to the isothermal expansion of
the Second Law is not threatened as much an ideal gas--consisting of one single mole-
by this entropy decrease as one would think, cule-from volume V , to the volume
as soon as we see that the entropy decrease +
V1 V2 . After some time, when the piston
resulting from the intervention would be has reached the bottom of the container, the
compensated completely in any event if the molecule has again the full volume V1 + Vz
execution of such a measurement were, for to move about in, and the piston is then re-
instance, always accompanied by produc- moved. The procedure can be repeated as
tion of k log 2 units of entropy. I n that case many times as desired. The man moves the
it will be possible to find a more general piston up or down depending on whether the
entropy law, which applies universally to all molecule is trapped in the upper or lower half
measurements. Finally we shall consider a of the piston. I n more detail, this motion
very simple (of course, not living) device, may be caused by a weight, that is to be
that is able to make measurements con- raised, through a mechanisni that transmits
tinually and whose “biological phenomena” the force from the piston to the weight, in
we can easily follow. By direct calculation, such a way that the latter is always dis-
one finds in fact a continual entropy produc- placed upwards. I n this way the potential
tion of the magnitude required by the above- energy of the weight certainly increases
mentioned more general entropy law de- constantly. (The transmission of force to the
rived from the validity of the Second Law. weight is best arranged so that the force
The first example, which we are going to exerted by the weight on the piston a t any
consider more closely as a typical one, is the position of the latter equals the average
following. A standing hollow cylinder, closed pressure of the gas.) It is clear that in this
at both ends, can be separated into two manner energy is constantly gained at the
possibly unequal sections of volumes V , and expense of heat, insofar as the biological
V , respectively by inserting a partition from phenomena of the intervening nian are ig-
the side at an arbitrarily fixed height. This nored in the calculation.
partition forms a piston that can be moved I n order to understand the essence of the
up and down in the cylinder. An infinitely man’s effect on the system, one best imagines
large heat reservoir of a given temperature T that the movement of the piston is performed
insures that any gas present in the cylinder niechanically and that the man’s activity
undergoes isothermal expansion as the consists only in determining the altitude of
piston moves. This gas shall consist of a the molecule and in pushing a lever (which
single molecule which, as long as the piston steers the piston) to the right or left, depend-
is not inserted into the cylinder, tumbles ing on whether the molecule’s height requires
about in the whole cylinder by virtue of its a down- or upward movement. This nieans
thermal motion. that the intervention of the huniari being
Imagine, specifically, a man who a t a given consists only in the coupling of two position
time inserts the piston into the cylinder and co-ordinates, namely a co-ordinate x, which
somehow notes whether the molecule is determines the altitude of the molecule, with
caught in the upper or lower part of the cyl-
another co-ordinate y, which determines the
inder, that is, in volume V1 or V , . If he
should find that the former is the case, then position of the lever and therefore also
he would move the piston slowly downward whether a n upward or downward motion is
until it reaches the bottom of the cylinder. imparted to the piston. It is best to imagine
During this slow movement of the piston the the mass of the piston as large and its speed
molecule stays, of course, above the piston. sufficiently great, so that the thermal agita-
304 LEO SZILARD

tion of the piston at the temperature in ques- mental amount, but not smaller. To put it
tion can be neglected. precisely: we have to distinguish here be-
In the typical example presented here, we tween two entropy values. One of them, & ,
wish to distinguish two periods, namely: is produced when during t,he measurement y
1. The period of measuTeinent when th e assumes the value 1,and the other, 8, ,when
piston has just been inserted in the middle of y assunies the value - 1. We cannot expect
the cylinder and the niolecule is trapped to get general information about S1 or Sz
either in the upper or lower part; so that if we separately, but we shall see that i f the
choose the origin of co-ordinates appropri- amount of entropy produced by the “meas-
ately, the r-co-ordinate of the molecule is urement” is to compensate the entropy de-
restricted to either the interval x > 0 or crease affected by utilization, the relation
x < 0; must always hold good.
2 . The period of utilization of the measure-
ment, “the period of decrease of entropy,”
during which the piston is moving up or
down. During this period the x-co-ordinate One sees from this formula that one can
of the molecule is certainly not restricted to make one of the values, for instance 81, as
the original interval x > 0 or x < 0. Rather, small as one wishes, but then the other value
if the molecule was in the upper half of the A!?, becomes correspondingly greater. Fur-
cylinder during the period of measurement, thermore, one can notice that the magnitude
i.e., when x > 0, the molecule must bounce of the interval under consideration is of no
on the downward-moving piston in the lower consequence. One can also easily understand
part of the cylinder, if it is to transmit that it cannot be otherwise.
energy to the piston; that is, the co-ordinate Conversely, as long as the entropies 8,and
R: has to enter the interval x < 0. The lever,
, produced by the measurements, satisfy
on the contrary, retains during the whole pe- the inequality (l),we can be sure that the
riod its position toward the right, corre- expected decrease of entropy caused by the
sponding to downward motion. If the posi- later utilization of the measurement will be
tion of the lever toward the right is desig- fully compensated.
nated by y = 1 (and correspondingly the Before we proceed with the proof of in-
position toward the left by y = - 1) we see equality (l), let us see in the light of the
that during the period of measurement, the above mechanical example, how all this fits
position x > 0 corresponds to y = 1; but together. For the entropies & and & pro-
afterwards y = 1 stays on, even though x duced by the measurements, we make the
passes into the other interval x < 0. We see following Ansatz:
that in the utilization of the measurement 8, = 8, = k log 2 (2)
the coupling of the two paraineters x and y
disappears. This ansatz satisfies inequality (1) and
We shall say, quite generally, that a pa- the mean value of the quantity of entropy
rameter y “nieasures” a parameter x (which produced by a measurement is (of course in
varies according to a probability law), if the this special case independent of the fre-
value of y is directed by the value of param- quencies w1 , w2 of the two events) :
eter x a t a given moment. A measurement
procedure underlies the entropy decrease 8 = k log 2 (3)
effected by the intervention of intelligent In this example one achieves a decrease of
beings. entropy by the isothermal expansion?
One may reasonably assuiiie that a meas-
urement procedure is fundamentally asso- - 31 = --klog ____
v1 .
ciated with a certain definite average entropy vl+ v2 ’
production, and that this restores concord- (4)
ance with the Second Law. The amount of
entropy generated by the measurenient may,
of course, always be greater than this funda- The entropy generated is denoted by s,, ss.
ON THE DECREASE
OF ENTROPY 305

depending on whether the molecule was also shall look upon them as chemically dif-
found in volume Vl or VZwhen the piston ferent, if they differ only in that the y co-
was inserted. (The decrease of entropy ordinate is +1 for one and - 1 for the other.
equals the ratio of the quantity of heat taken We should like to give the box in which the
froin the heat reservoir during the isothermal “molecules” are stored the form of a hollow
expansion, to the temperature of the heat cylinder containing four pistons. Pistons A
reservoir in question). Since in the above and A’ are fixed while the other two are inov-
case the frequencies w1 , W P are in the ratio of able, so that the distance BB’ always equals
the volumes Vl , V z, the mean value of the the distance AA’, as is indicated in Figure 1
entropy generated is (a negative number) : by the two brackets. A‘, the bottom, and B,
3 =w1.(+31) + WY(+ s,) =
the cover of the container, are impermeable
for all “molecules,” while A and B’ are semi-
“1
permeable; namely, A is permeable only for
k log ___
v1 + (5) those “molecules” for which the parameter x
v l + VP Vl+VZ
is in the preassigned interval, i.e., (xl ,x2), B’
V2 k log ____V1 is only permeable for the rest.
VI+ vz Vl+VZ
As one can see, we have, indeed
v1
+ v, klog v1+ + vz
~
v1 V2 ___
T’, v2 v1+
Tr (6)

v, + + klog2 2 0
VP
aklog-
v2
and therefore :
S++g-Q. (7)
In the special case considered, we would
A’
actually have a full compensation for the de-
crease of entropy achieved by the utilization FIQ.1
of the measurement.
We shall not examine more special cases, I n the beginning the piston B is at A and
but instead try to clarify the matter by a therefore B’ at A’, and all “molecules” are
general argument, and to derive formula (1). in the space between. A certain fraction of
We shall therefore imagine the whole sys- the molecules have their co-ordinate x in the
tem-in which the co-ordinate x, exposed to preassigned interval. We shall designate by
some kind of thermal fluctuations, can be w1 the probability that this is the case for a
measured by the parameter y in the way just randomly selected molecule and by wP the
explained-as a multitude of particles, all probability that x is outside the interval.
enclosed in one box. Every one of these par- Then w1+ WP = 1.
ticles can move freely, so that they may be Let the distribution of the parameter y be
+
considered as the molecules of an ideal gas, over the values 1 and - 1 in any propor-
which, because of thernml agitation, wander tion but in any event independent of the
about in the common box independently of x-values. We imagine an intervention by an
each other and exert a certain pressure on the intelligent being, who imparts to y the value
walls of the box-the pressure being deter- 1for all “molecules” whose x at that moment
mined by the temperature. We shall now is in the selected interval. Otherwise the
consider two of these molecules as chemi- value -1 is assigned. If then, because of
cally different and, in principle, separable by thermal fluctuation, for any “molecule,” the
semipermeable walls, if the co-ordinate x for parameter x should come out of the preas-
one molecule is in a preassigned interval signed interval or, as we also may put it, if
while the corresponding co-ordinate of the the “molecule” suffers a monomolecular
other molecule falls outside that interval. We chemical reaction with regard to x (by which
306 LEO SZILARD

it is transformed from a species that can pass long as we do not use the fact that the molecules
the seniipernieable piston A into a species for in the container BB’, by virtue of their co-
which the piston is imperiiieable), then the ordinate y, “remember” that the r-co-ordinate
parameter y retains its value 1 for the time for the molecules of this container originally
being, so that the “molecule,” because of the was in the preassigned inlerval, full conapensa-
value of the parameter y, “remembers” tion existsfor the calculated decrease of entropy,
during the whole following process that x by virtue of the fact that the partial pres-
originally was in the preassigned interval. sures in the two containers are snialler than
We shall see immediately what part this in the original mixture.
memory may play. After the intervention B u t now we can use the fact that all naole-
just discussed, we niove the piston, so that cules in the container BB‘ hatie the y-co-ordi-
we separate the two kinds of inolecules with- nate I , and in the other accordingly -1, to
out doing work. This results in two con- bring all molecules baclc again to the original
tainers, of which the first contains only the volume. To accomplish this we only need to
one modification and the second only the replace the seniipermeable wall -4by a wall
other. Each modification now occupies the A *, which is seniipermeable not with regard
same volume as the mixture did previously. to x but with regard to y, naniely so that it is
In one of these containers, if considered by permeable for the molecules with the y-co-
itself, there is now no equilibrium with re- ordinate 1 and impermeable for the others.
gard to the two “modifications in x.)’ Of Correspondingly we replace B’ by a piston
course the ratio of the two modifications has B’*, which is impermeable for the molecules
remained w1:wz.If we allow t,his equilibrium with y = -1 and permeable for the others.
to be achieved in both containers independ- Then both containers can be put into each
ently and at constant volume arid tempera- other again without expenditure of energy.
ture, then the entropy of the systeni cer- The distribution of the y-co-ordinate with
tainly has increased. For the total heat regard to 1 and -1 now has become sta-
release is 0, since the ratio of the two “niodifi- tistically independent of the r-values and be-
cations in x’)w1:w2 does not change. If we sides we are able to re-establish the original
acconiplish the equilibrium distribution in distribution over 1 and - 1. Thus we would
both containers in a reversible fashion then have gone through a coniplete cycle. The
the entropy of the rest of the world will de- only change that we have to register is the
crease by the same amount. Thcrefore the resulting decrease of entropy given by (9) :
entropy increases by a negative value, and,
the value of the entropy increase per mole- 3 = Ic(w1 log w1 + wt log wz). (10)
cule is exactly: If we do not wish to admit that the Second
s = Ic(w1 log w1 + w2 log wp). (9)
Law has been violated, we must conclude
that the intervention which establishes the
(The entropy constants that we must as- coupling between y and x, the iiieasurenzent of
sign to the two “modifications in 5’’ do not x by y, must be accompanied by a production
occur here explicitly, as the process leaves the of entropy. If a definite way of achieving this
total number of molecules belonging to the coupling is adopted and if the quantity of
one or the other species unchanged.) entropy that is inevitably produced is desig-
Yow of course we cannot bring the two nated by Sl and S z , where S1 stands for the
gases back to the original volume without mean increase in entropy that occurs when y
expenditure of work by simply moving the acquires the value 1, and accordingly S z for
piston hack, as there are now in the con- the increase that occurs when y acquires the
tainer- which is bounded by the pistons value - 1, we arrive at the equation:
BB’-also niolecules whose x-co-ordinate lies
outside of the preassigned interval and for WlSl i-
w2s2 = s“ (11)
which the piston A is not permeable any I n order for the Second Law to remain in
longer. Thus one can see that the calculated force, this quantity of entropy must be
decrease of entropy (Equation 191) does not greater than the decrease of entropy s, which
mean a contradiction of the Second Law. As according to (9) is produced by the utiliza-
ON THE DECREASE
OF ENTROPY 307

tioii of the measurement. Therefore the fol- not possible. But we can try to describe sini-
lowing unequality must be valid : ple nonliving devices that effect such cou-
pling, and see if indeed entropy is generated
S+SlO and in what quantity. Having already recog-
WlSl -I- WZS‘B (12) nized that the only important factor is a
certain characteristic type of coupling, a
+ k(w, log w1 + w2 log WB) 2 0
“measurement,” we need not construct any
This equation must be valid for any values complicated models which imitate the inter-
of w1 and w2,3 and of course the constraint vention of living beings in detail. We can be
w2 + wz= 1 cannot be violated. We ask, in satisfied with t,he construction of this par-
ticular type of coupling which is accoin-
particular, for which w1 and w2 and given
8-values the expression becomes a minimum. panied by memory.
For the two minimizing values w1 and wz the In our next example, the position co-or-
inequality (12) must still be valid. Under the dinate of an oscillating pointer is “measured”
above constraint, the minimum occurs when by the energy content of a body K. The
the following equation holds : pointer is supposed to connect, in a purely
mechanical way, the body K-by whose
energy content the position of the pointer is
to be measured--by heat conduction with
one of two intermediate pieces, A or B. The
body is connected with A as long as the co-
ordinate-which determines the position of
the pointer-falls into a certain preassigned,
This is easily seen if one introduces the no- but otherwise arbitrarily large or small inter-
tation val a, and ot,herwise if the co-ordinate is in
the interval b, with B. Up to a certain mo-
8
1
-
k
+ log w1 = SkZ + log
- ~2 = X; (15) ment, namely the moment of the “measure-
ment,” both intermediate pieces will be
then : thermally connected with a heat reservoir a t
w1 = eA .e - S i l k ; w2 = eA.e--s2’k. (16) temperature To. At this moment the inser-
tion A will be cooled reversibly to the tem-
If one substitutes these values into the in- perature T A, e.g., by a periodically function-
equality (12) one gets: ing mechanical device. That is, after
e-Sl’k + e--szik ) 20.
(17) successive contacts with heat reservoirs of
intermediate temperatures, A will be brought
Therefore the following also holds: into contact with a heat reservoir of the
temperature Ta .At the same time the inser-
X 2 0. (18) tion B will be heated in the same way to
If one puts the values w1 and wz from (16) temperature T g . Then the intermediate
+
into the equation w1 w2 = 1,one gets pieces will again be isolated from the corre-
+ e--Ss/k - sponding heat reservoirs.
e-S1/k
- e-A . (19) We assume that the position of the pointer
And because X 2 0, the following holds: changes so slowly that all the operations
that we have sketched take place while the
e-Sl/k
- 1.
+ e-‘Zik 5 (20) position of the pointer remains unchanged.
This equation must be universally valid, if If the position co-ordinate of the pointer fell
thermodynamics is not to be violated. in the preassigned interval, then the body
As long as we allow intelligent beings to was connected with the insertion A during
perforni the intervention, a direct test is the above-mentioned operation, and conse-
quently is now cooled to temperature Ta .
3 The increase in entropy can depend only on I n the opposite case, the body is now
t h e types of measurement and their results but
not on how many systems of one or the other type heated to temperature T , . Its energy con-
were present. tent becomes-according to the position of
308 LEO SZILARD

the pointer at the time of “measurement”- However, following this, the entropy with-
small a t temperature Ta or great a t tempera- drawn from the reservoir T o by direct con-
ture TB and will retain its value, even if the tact with it was
pointer eventually leaves the preassigned
interval or enters into it. After some time, $To) - G(TA)
(22)
while the pointer is still oscillating, one can TO
no longer draw any definite conclusion from
the energy content of the body K with re- All in all the entropy was increased by
gard to the momentary position of the the amount
pointer but one can draw a definite conclu-
sion with regard to the position of the pointer
at the time of the measurement. Then the
measurement is completed. Analogously, the entropy will increase by
After the measurement has been ac- the following amount, if the body was in con-
complished, the above-mentioned periodic- tact with the intermediate piece B a t the
ally functioning mechanical device should time of the “measurenient”:
connect the thermally isolated insertions A
and R with the heat reservoir To. This has
the purpose of bringing the body K-which
is now also connected with one of the two
intermediate pieces-back into its original We shall now evaluate Ihese expressions
state. The direct connection of the intermedi- for the very simple case, where the body
ate pieces and hence of the body K-which which we use has only two energy states, a
has been either cooled to TA or heated to lower and a higher state. If such a body is in
TB-to the reservoir To consequently causes thermal contact with a heat reservoir at any
an increase of entropy. This cannot possibly temperature T , the probability that it is in
be avoided, because it would make no sense the lower or upper state is given by re-
to heat the insertion A reversibly to the spectively:
temperature To by successive contacts with
the reservoirs of intermediate temperatures
and to cool B in the same manner. After the
measurement we do not know with which of
the two insertions the body K is in contact
at that moment; nor do we know whether it
had been in connection with TA or TB in the Here u stands for the difference of energy
end. Therefore neither do we know whether of the two states and g for the statistical
we should use intermediate temperatures be- weight. We can set the energy of the
tween TA and To or between To and Te. lower state equal to zero without loss of
The mean value of the quantity of en- generality. Therefore :4
tropy S1 and Sz, per measurement, can be
calculated, if the heat capacity as a function
of the temperature a ( T ) is known for the
body I(,since the entropy can be calculated
from the heat capacity. We have, of course,
neglected the heat capacities of the inter-
mediate pieces. If the position co-ordinate
of the pointer was in the preassigned inter-
val at the time of the “measurement,” and
accordingly the body in connection with in-
sertion A , then the entropy conveyed to the
heat reservoirs during successive cooling was
Here p and p are the functions of T given
(21)
See the Appendix.
ON THE DECREASE
OF ENTROPY 309
hy equation ( 2 5 ) ,which are here to be taken and the mean energy of the body is given by:
for the argu1iient.sT O, T A , or T B .
If (as is necessitated by the above concept
of a “measurement”) we wish to draw a
dependable conclusion from the energy con-
tent of the body K as to the position co-or- the following identity is valid:
dinate of the pointer, we have to see to it
that the body surely gets into the lower
energy state when it gets into contact with
T B. I n other words: Therefore we can also write the equat’ion:

B A =
a ( T A ) - “(To)
TO
+lT I dii
- -dT
TdT
(33)

as
This of course cannot be achieved, but may
be arbitrarily approximated by allowing T A
to approach absolute zero and the statis-
tical weight g to approach infinity. (In
this limiting process, T o is also changed, in
such a way that TO) and q(To) remain
constant.) The equation (26) then becomes: and by substituting the limits we obtain:

If we write the latter equation according to


and if we form the expression e--sAJk + (25) :
e - S B l k , we find:
1
1 + ge-tdkT = __
e - - S ~ / k + e--SB/k - 1.
- PO‘)
(36)
(29)
Our foregoing considerations have thus for T A and T O ,then we obtain:
just realized the smallest permissible limiting
care. The use of semipermeable walls ae-
cording to Figure 1 allows a complete
utilization of the measurement: inequality and if we then write according to (31):
(1) certainly cannot be sharpened.
As we have seen in this example, a simple ~ ( T A )= u d T A ) (38)
inanimate device can achieve the same we obtain:
essential result as would be achieved by the
intervention of intelligent beings. We have
examined the “biological phenomena” of a
nonliving device and have seen that it gen- If we finally write according to ( 2 5 ) :
erates exactly that quantity of entropy
which is required by thermodynamics.
(40)
APPENDIX
for T A and TO, then we obtain:
In the case considered, when the frequency of
the two states depends on the temperature ac-
cording to the equations:
3 10 LEO SZILARD

We obtain the corresponding equation for S B , expand and collect terms, then we get

Formula (41) is identical with (26), given, for REFERENCES


SA,in the text.
We can bring the formula for S Binto a some- Smoluchowski, F. Vortraye UbeT die k i n e l k h e
what different form, if we write: Theorie der Materie u. Elektrizitat. Leipzig:
1814.
dTe) = 1- PVd, (43) Szilard, L. Zeitschrift fur Physik, 1925, 32, 753.

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