f JE (Main)- RRB ca CHEMICAL BONDING SECTION : STRAIGHT OBJECTIVE TYPE at. 22 23 24 25 26 27 28 29. Which is correct order for net dipole moment (1) HE> HCI> HBr> HI (2) CH, F> CD, -F (8) SO,>SO, (4) CH, ~ CH = CHOI (cis) > CH, - CH = CHC! (trans) Which ofthe following is not correct (1) Carbon-carbon bond length in Ca, will be more than that in CH,CCH, (2) 0-0 bond length in Na, O, will be more than that in KO, (8) 0-0 bond length in O, (PIF, will be less than that in KO, (4) N-O bond length in NO gaseous molecule willbe smaller than that bond length in NOCI gaseous molecule. Correct order of bond length is (1) 80> S02-> 50, (2) S02->S0,->80, (8) SO, > $0, >s02- (4) None of these. Which ofthe following is paramagnetic? (Mo, (@)cN- (co (4) No Gaseous SO, molecule (1) is planner triangular in shape with three bonds from sp? — p overlap and three x-bonds formed by two px ~px overlap and one px — dr overlap. (1) is planner triangular in shape with three o-bonds from sp? p overlap and three x-bonds formed by one px—pr overlap and two px— dx overlap. (8) is a pyramidal molecule with one double bond and two single bonds. (4) planner triangular in shape with two double bonds between S and O and one single bond ‘Among the following, the pairin which the two species are not isostructural is (1)lOsandXe0, ——(2)ACH,-andPH,* ——(3)AsF,-andSF, (4) SIF, and SeF, The correct order of C-N bond length in the given compounds is : P:CH,CN. Q: NCO R: CH,CONH, ()P>Q>R @P=Q=R (@)R>Q>P (@)R>P>Q ‘The correct order of increasing s character (in percentage) in the hybrid orbitals in below molecules / ions is (assume all hybrid orbitals are exactly equivalent) coe XeF, i Nel, BeC, (9) 1 0 a wv v ()icMH,S>H,Se>H,Te (2)G,H, >C,H,>CH,> NH, (8) SF, < NH, H,0>H,S> SF, The correct order of stability to form ionic compounds among Si‘, AI%*, Mg?* and Nat is (1) Sit > AI" > Mg? > Nat (2) AB? > Sift > Mg2* > Na? (3) Nat > Sift > Mg? > Are (4) Nat > Mg2* > Al sit The correct order of hybridisation of the central atom in the following species NF, BF, PF, and [SiF,)* is: (1) sp®, sp, spd, sp%d (2) sp, sp?, spd, sp3o* (6) sp?, sp®, sp°%, spa? (4) sp°, sp2, sp, sp%a? Which of the following arrangements is correct on the basis of the increasing p-character of the hybrid orbitals of the central atoms in the following (c10,- (cs, (ii) Sac, (1)t> i> >t (3)i>u> um (ila ism Which of the following are isostructural ? Nos co, clos, 80g, X60, ” 0) cy (W) ) (1)() and (vy (2)(l) and (vy (2) (m) and (tv) (4) (vy andy) Which of the following is a planar molecule ? (1)Xe0,F, (2)XeOF, @)XeF, (yxer, Which one of the following represents the INCORRECT decreasing order of bond angles? (1) CO, > BF, > CH, > H,0 (2) NO," >NO, > NO, (8) BCI, > PCl, > ASCl, > BIC, (4) 10," > BrOg- > ClO, ‘The number of P—O—P bonds in tricyclic metaphosphoric acid is (1) zero (2)two (3) three (4) four In which ofthe following molecule /ion all the bonds are equal ? (SIF, QF, (Cr, (Por, Resonance®__ $$ a N Eisai fr bar tomorow2.25 227 228 229 2.30 231 2.92 2.33 2.94 5 JEE (Main) - RRB cx Which ofthe following options with respect to increasing bond order is correct ? ()NOH,O, > HF > H,S. (2) HF>H,O, > H,O>H,S (3) HF >H,O>H,S>H,0, (4) HF >H{O>H,0, >H;S {In which of the following metal to metal bond is present? (1) Cupric chloride (2) Stannous chloride (8) Mercurous chloride (4) Mercurie chloride What is not true about ice? (1) Ithas open cage like structure (2) Ithas less density than water (8) Each O atom is surrounded by 4 H atoms (4) Each O atom has four H-bonds around it Give the correct order of initials T or F for following statements. Use T if statementis true and F if (1) The order of repulsion between different pair of electrons is |, ~1,>1,~b,>b,-b, (il) In general, as the number of lone pair of electrons on central atom increases, vaiue of bond angle from normal bond angle also increases (ltl) The number of tone pair on O in H,0 is 2 while on Nin NH, is 1 (IV) The structures of xenon fluorides and xenon oxyfluorides could not be explained on the basis of VSEPR: theory, () TTF (1) TFTF (TFT (4) FFF false: Consider the following statements : |. Asigma (c) bonds formed when two c-orbitals overlap I. Api(n) bondis formed when two. x-orbitals overlap axially lL —-Ag-bondis weaker than x-bond Which of the above statements is/are correct? (1)Landit (2) land it (8)lalone (4)Ilalone2.48 2.47 2.48 2.49. © JRE (Main) - RRB ca Match list | wth List Il and select the correct answer using the codes given below the lists List | List! (cs, (@)Bent (©) So, (@)Linear (oar, (9 Trigonat planar (NH, (s) Tetrahedral (0) Trigonal pyramidal Codes ® » © © ® » © © M g por t @ ep aor t @ q P t s (4) P q t s Match List-| (Hybridisation) with List-ll (shapes) and select the correct answer using the codes given below the lists List List (a) dsp? (p) Square planar oop (@Tetrehedral (c) dsp (f) Octahedral (sp (@) Tonal bipyramidal Codes: @ (bo) ©) @ @ (o) © .@ ® po a@orios @ s ait @ Pp r q s @ s r q Idently the correct sequence of increasing number of x-bonds inthe structure ofthe following molecules WHS0, dHs.o, (yHs.o, (1) 1, Hand IL (2), Land tt (3) 1, Mand! (4)1, Mand It ‘The hybridization of the central atom will change when : (1) NH, combines with Ht (2) H,80, combines with OH (9) NH, forms NH, (4)H,0 Combines with H* Resonance”. @ 3.2 3.3 3.4. 35 36 37 38,