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강원도보건환경연구원보 18:60~69, 2007


Rep. Inst. Health & Environ. 18:60~69, 2007

An Estimation and Application of Optimal DO Control


Concentration according to Oxygen Demand in an Aerobic
Process of Wastewater Treatment
Geun-Woo Hyun, Chan-Kee Lee*, Beom-Nyung Huh, In-Ryang Huh, Won-Gu
Jeong, Sang-Yeol Koh, Suk-Jong Lee, Nam-Seong kim, Sung-Bin Park,
Yeong-Jin Kim, Sung-Seok Kim

하수처리를 위한 포기 공정에서 산소요구량에 따른 최적 DO 제어농도의 추정과 적용

현근우, 이찬기*, 허범녕, 허인량, 정원구, 고상열, 이석종, 김남성, 박성빈, 김영진, 김성석

* 강원대학교 환경공학과

Abstract
하수처리시설을 운영함에 있어서 ORP probe의 경우 무산소 혹은 혐기 상태에서 (-)값을 지시하기 때문
에 DO probe보다 많이 이용되고 있으나, 유기물의 유입부하량에 직접적으로 영향을 미치는 DO 농도도
중요한 제어값이다. 유입부하량의 변동에 따라서 산소요구량이 변화되므로, 생물학적 반응조의 산소공급
량을 실시간으로 조정해주어야 한다는 사실을 다단계 DO 농도제어 실험을 통해서 확증하였다. SBR 반
응조에서 DO meter를 사용하여 포기시 DO 농도를 0.5, 1, 2, 3, 4 mg/L로 각각 제어하면서 DO 농도와
산소공급량 간의 관계를 2차방정식으로 유도한 결과, r=0.99로서 아주 높은 상관성을 보여주었다. 이러한
산소공급량은 유입 유기물 부하량에 따라서 변화하는 산소요구량과 같은 단위 개념이므로, 유도된 수식
을 가지고 유입 유기물부하량에 대응하는 산소요구량에 따른 이론적인 적정 DO 제어농도를 추정하였다.
그 수식을 유입 유기물량을 on-line으로 측정하는 계측기나 ORP 혹은 OUR 변화값 등과 연계하여 적용
하면, 하수처리시설의 포기공정을 자동제어하기 위한 인자 중의 하나로서 유용하게 활용될 것이다.

INTRODUCTION than DO probes because it points (-) values in


a anoxic or anaerobic state(4), and also many
The ON/OFF interval of an aerobic device is studies regarding the characteristics of ORP in
very important for efficient removal of nitrogen aerobic/anaerobic state have been conducted
and phosphorus in a wastewater treatment (5-9). Although the DO was frequently
plant. Various control methods using ORP, pH regarded as an auxiliary factor in automatically
and DO have been introduced in order to solve control system, it is also an important control
this issue(1-3). factor because the optimum DO concentration
ORP probe has been used in more cases of an aerobic reactor changes in real-time
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adding to the inflow organic substances. on-line DO monitoring data and oxygen
The DO concentration can be controlled by demand. The equation can be usefully applied
adjusting air flow a continuous aeration as control logic to automatically control the
method. However, automatic control system aerobic process of a wastewater treatment
using DO sensor presents more effective plant.
methods, because the air flow adjusting method In this study applied using multi-step DO
can't actively respond to the change in the control concentration method for estimation of
state of inflow. In recent years, it has been optimal DO control concentration according to
necessary to optimize the aerobic/anaerobic oxygen demand in an aerobic process of
process in a type of SBR or intermittence wastewater treatment.
aerobic process that periodically repeats aerobic
and anaerobic processes in order to remove
nutrients effectively(10). MATRIALS AND METHODS
There are several methods to control the DO,
such as a method using feedback controller,
SBR system
which controls the DO by indicating a set The continuous inflow SBR reactor used in
points of DO meter(11), ON/OFF control this experiment was fabricated using a
method, which controls the DO by calculating transparent acrylic cylinder, which has a radius
respiration rates and estimating OUR(12-13), of 25cm, height of 70cm, and effective volume
and a fuzzy control method, which controls the of 35L as presented in Fig. 1. In addition, a
DO after estimating OUR using respiration steel paddle was installed at a low speed motor
rates(14). in order to obtain a perfect mixing. The
However, these methods neglected the mixing was conducted at 120~130rpm. The
concept which controls the set point of DO wastewater entered continually flowed into the
concentrations in real-time. If wastewater that reactor through a tube, which was connected
has a low organic concentration suddenly at the bottom of the reactor.
enters into a wastewater treatment tank,, the A diffuser was installed at the bottom of the
set point of DO concentrations should be reactor in order to supply air continuously
controlled at a low level in real-time because using an external blower, and the air flow in
oxygen demand has decreased. Conversely, in the aerobic process was maintained at 3L/min
the case of the wastewater inflow having a in which the air flow was controlled using a
high organic concentration, the set point of DO flow regulator. DO and ORP probe were also
concentrations should be controlled at a high installed inside the reactor and monitored the
level in real-time because oxygen demand has values in real-time using a PC. This
increased. This means that the set point of DO monitoring can be performed using automatic
concentrations should be controlled in real-time control software, 'Advantech Drivers Supporting
according to the change in the inflow of for Industrial Automation' by Adventech, which
organic substances. Because oxygen demand includes a control board that changes analog
presents the same unit as oxygen supply, it is signals to digital signals and digital signals to
possible to estimate by relative equation of the analog signals. In addition, the program was
optimal DO control concentration that uses the used to QBasic certain internal logics in order
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to control the response time for sensors, such minutes, respectively. The sludge was removed
as anaerobic/aerobic, settlement, decantation, for 2~5 minutes at the period between the
and wasted sludge. settlement time and decant time.
The reactor applied in this test was operated The reactor temperature was maintained at
in the order of Anaerobic - Aerobic - Settle - 20~22℃. The experiment lasted for 2 months
Decant as presented in Fig. 2, and the in which the MLSS was also maintained at
anaerobic time, aerobic time, settlement time, about 3,800mg/L. HRT was 18~20 hours and
and decantation time were 90, 110, 60 and 30 SRT was 25~28 days.

DO ORP
m eter m eter

PC

M D ecant

Effluent
reservoir
C ontrol panel
SBR
Reactor
Feed pum p

P A ir pum p

R aw
W /W

Figure 1. Schematic diagram of SBR system

Anaerobic
/Aerobic

Continuous inflow
raw wastewater

React Settle Decant

Figure 2. Schematics of continuous inflow SBR process


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DO control is required into the reactor. It was possible to


maintain an optimum DO concentration using
A level of the DO control is required as the
only a simple ON/OFF control of an air
indispensable condition for the degradation of
blower. The control was performed by setting
organic substances, nitrification and phosphorus
the air blower to either OFF or ON when the
removal. And certain excessive air flows
DO concentration either increased over or
should be prevented to save energies and
deceased under the set point level, respectively.
maintain an optimum state of microorganisms.
In this control, there was a slight oscillation of
It is known that nitrification bacteria can be
damaged as a result of competition between the range of ±0.1mg/L.
nitrification bacteria and heterotrophic bacteria The DO of an aerobic reactor was
when the DO level is lower than 1.0 mg/L automatically controlled by applying
even though the nitrification is effectively concentrations of 0.5, 1, 2, 3 and 4 mg/L, an
processed at the DO concentration of 1.3~2.0 equation for automatic control was derived by
mg/L(15). On the other, in the case of the calculated a theoretical optimal DO control
biological phosphorus uptake, the poly-P concentration. In addition, this study
composition began at the DO concentration of investigated the cost reduction effect according
0.1mg/L, and the maximum phosphorus to a comparison of the optimum DO control
adoption was performed at 0.5 mg/L(16). concentration with the unoptimized case. Fig. 3
Because the DO concentration in a reactor presents the results of the monitoring of DO
can be significantly changed according to the concentrations using a PC by applying the
inflow load and time, an optimum DO control concentrations of 1, 2, and 3 mg/L.

4
DO Control Conc. : 1 mg/L
3
DO(mg/L)

0
4
DO Control Conc. : 2 mg/L
3
DO(mg/L)

0
4
DO Control Conc. : 3 mg/L
3
DO(mg/L)

0
3 6 9 12 15 18 21 24
Time(hours)

Figure 3. On-line monitoring profiles with controled DO concentration.


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RESULTS AND DISCUSSION 4mg/L) improves the nitrification rate, it is


difficult to significantly increase the operational
Calculation of air flow factor performance. This will lead to a significant
increase in cost(10).
Dissolved oxygen is one of the most
In order to operate the reactor effectively and
important factors in the process of biological
economically, a DO meter was used to
nutrients removal. The amount of the oxygen
maintain the DO concentration in an aerobic
supply in an aerobic reactor is theoretically the
process at 0.5, 1, 2, 3 and 4mg/L, and the
same as oxygen demand for microorganisms to
results were monitored. Fig. 4 presents the
oxidize organic substances in an activated
results profile and shows a partially magnified
sludge process. The rate of oxygen transfer
graph of 2 mg/L DO concentration.
from gas phase to liquid phase is relatively
Because an air flow was to be produced first
low, because a small amount of the supplied
in order to calculate the oxygen supply, the air
oxygen is used only by microorganisms. If the
flow time expressed in (Eq. 1) that was added
oxygen is a limitation factor in the growing of
to the aerobic time among the total aerobic
microorganisms, activated sludge settlement
time, which was obtained by summing all 't'
will present poor results due to the abundance
values(values for the power ON), was
of filamentous bacteria.
calculated, and then the air flow factor(Ahr)
The concentration of the dissolved oxygen in
was calculated by dividing it by the total
an aerobic reactor generally should be
aerobic time(1 hour).
maintained at the level of 1.5~2.0mg/L.
Although the high DO concentration(more than t1 + t2 + t3 + t4 + … = total T (eq. 1)

2.3

2.2
DO Control Conc.(mg/L)

2.1

1.9

1.8

1.7 t1 + t2 + t3 + t4 …… / total time

1.6
1 11 21 31 41 51 61 71 81 91 101 111 121 131 141 151 161 171

Time(sec)

Figure 4. A profile for calculation of air flow time in aeration time


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Calculation of oxygen supply DO : Dissolved oxygen, mg/L


Qair : Air flow, L/d
Although a typical DO control method the air
Ahr : Air flow factor per hr
flow generated by an air blower, in case of
control with the use of on-line concept and DO Fig. 5 shows the change in the oxygen
meter can be applied an intermitted ON/OFF supply and DO control concentration of specific
control while an adequate level of air is based unit on the data noted in Table 1. Based
continuously supplied. on these results, a second order equation(Eq. 3)
Oxygen supply was calculated basing on the was derived, which solution resulted in
air flow factor(Ahr), air flow (3L/min=4,320L/d) obtaining the high correlativity r=0.99.
and DO concentrations (see Eq. 2). Table 1
DO control conc.(mg/L) =
presents the results of the oxygen supply
-0.0156Od + 0.489Od + 0.183 (eq. 3)
2
calculation according to the DO control
concentration using this equation. Where, Od = oxygen supply

Os(gO2/d) = DO × Qair × Ahr × g/1000mg This equation can be derived using a


(eq. 2) multi-step DO control and monitoring method
where, Os : Oxygen supply, gO2/d online.

Table 1. Calculated oxygen supply by DO control concentration and air flow rate per hr

DO control conc. Air flow factor Oxygen supply


(mg/L) (Ahr) (gO2/d)
0.5 0.35 0.76
1 0.41 1.77
2 0.47 4.06
3 0.61 7.91
4 0.84 14.52

5
DO Control Conc.(mg/L)

2
y = -0.0156x 2 + 0.489x + 0.183
r = 0.99

1
M L S S : 3900 mg/ L

0
0 2 4 6 8 10 12 14 16
O x y g e n S u p p ly ( g O 2 / d )

Figure 5. Relation between oxygen supply and DO control concentration


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Table 2. Theoretical optimal DO control concentration according to the oxygen supply

Measured oxygen Calculated optimum DO Measured oxygen Calculated optimum DO


supply(mgO2/hr) conc.(mg/L) supply(mgO2/hr) conc.(mg/L)
0.0 0.0 8.0 3.1
0.5 0.4 8.5 3.2
1.0 0.7 9.0 3.3
1.5 0.9 9.5 3.4
2.0 1.1 10.0 3.5
2.5 1.3 10.5 3.6
3.0 1.5 11.0 3.7
3.5 1.7 11.5 3.7
4.0 1.9 12.0 3.8
4.5 2.1 12.5 3.9
5.0 2.2 13.0 3.9
5.5 2.4 13.5 3.9
6.0 2.6 14.0 4.0
6.5 2.7 14.5 4.0
7.0 2.8 15.0 4.0
7.5 3.0 15.5 4.0

Table 2 presents the estimation values of an of carbonaceous material is determined from a


optimal DO control concentration and oxygen mass balance using the bCOD concentration of
supply using Eq. 3. the wastewater treated and the amount of
Because oxygen supply has the same basic biomass wasted from the system per day. If all
units (gO2/d) as oxygen demand, the optimum of the bCOD were oxidized to CO2, H2O, and
DO control concentration can be reversely NH3, the oxygen demand would be equal to the
calculated in an aerobic process by substituting bCOD concentration. However, bacteria oxidize
oxygen demand for the oxygen supply. This a portion of the bCOD to provide energy and
means that the optimum DO control concentration use the remaining portion of the bCOD for cell
can be calculated according to the inflow load of growth. Oxygen is also consumed for
organic substances using this process. This endogenous respiration, and the amount will
equation is useful as a instrumental control factor depend on the system SRT. For a given SRT,
for automatic control of the aerobic process of a a system mass balance can be derived where
wastewater treatment plant, when the equation is the bCOD removal equals the oxygen used
combined with certain types of equipment, which
plus the biomass VSS remaining in terms of
can measure the inflow of organic substances in
an oxygen equivalent.
real-time online, or the changed value of ORP or
When nitrification is included in the process,
OUR measured in real-time online.
the total oxygen demand will include the
oxygen demand for removal of carbonaceous
Calculation of oxygen demand material plus the oxygen demand for ammonia
The oxygen demand for the biodegradation and nitrite oxidation to nitrate as follows(17):
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Ro = Q(So-S) - 1.42Px,bio + 4.33Q(NOx) (4.33×46×0.005)g/d = 4.87 g/d


(eq. 4)
where, Ro = total oxygen demand, g/d where, Px, bio = 8250 mg/L × 0.6 L/d = 5.0 g/d
Px,bio = biomass as VSS wasted, g/d
NOx = the amount of TKN oxidized to From the results, oxygen demand obtained is
nitrate Ro=4.87g/d.

The average values of the raw wastewater Optimum DO control concentration


treated in this experiment was used to analyze The theoretical DO control concentration,
oxygen demand(Table 3). The values were used which is an optimum value in an aerobic
to estimate oxygen demand by substituting it process, was estimated as 2.2 mg/L by
into Eq. 4. In the SBR reactor, the amount of
substituting the previously determined oxygen
oxidation of ammonium nitrogen to nitrate for 1
demand(4.87g/d) into Eq. 4. Because this value
cycle was assumed to be 5 mg/L.
was similar to the experimental optimal DO
Oxygen demand was calculated by
control concentration of 2.0 mg/L, the economical
substituting the data presented in Table 3 into
efficiency was analyzed using this value. Table 4
Eq. 4. The results are as follows;
presents the analysis results based on the value
Ro = 46(0.152-0.0038)g/d - 1.42×5.0g/d + of 2.0 mg/L as a criterion 1.0.

Table 3. Raw wastewater characteristics for estimation of oxygen demand

Item Values Remarks

Q 46 L/d
Inf. BOD 152 mg/L
Eff. BOD 3.8 mg/L
Inf. bCOD 243 mg/L bCOD ≒ BOD×1.6
Eff. bCOD 6.1 mg/L
NOx 5.0 mg/L 1cycle consumed
Waste sludge MLVSS 8250 mg/L
Waste sludge quantity 0.6L/d

Table 4. Comparison of power cost by the DO control concentration

DO control conc. Air flow factor


Power cost rates
(mg/L) (Ahr)
0.5 0.35 -
1 0.41 -

2 0.47 1.0
3 0.61 1.3
4 0.84 1.8
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By considering the optimal DO concentration J. (1998) Process state evaluation of


of 2 mg/L in an aerobic process as 1.0, the alternation oxic-anoxic activated sludge
amount of air flows needed were calculated to using ORP, pH and DO, Wat. Sci. Tech.
be 1.3 times of air flow for the DO control 38(3) pp. 299-306
concentration of 3 mg/L, and 1.8 times of air 2. Andreottola, G., Foladori, P., Ragazzi, M.
flow for the DO control concentration of 4 (2001) On-line control of a SBR system
mg/L. This means that the cost of the for nitrogen removal from industrial
operation electricity of air flow can be reduced wastewater. Wat. Sci. Tech. 43(3) pp.
by up to 30~80% if the optimal DO control 93-100
concentration is maintained. 3. Yong Ma, Yongzhen Peng, Zhiguo Yuan,
As a result, it is evident that the oxygen Shuying Wang, Xuelei Wu. (2005)
demand varied according to the inflow of Feasibility of controlling nitrification in
organic substances and has a significant predenitrification plants using DO, pH and
connection to the DO control concentration of ORP sensors. The 2nd IWA Conference,
an aerobic reactor. The results of these
Instrumentation, Control and Automation,
experiments can provide useful information for
Pusan, Korea
the professional operator in a wastewater
4. Holman, J.B., Wareham, D.G. (2003)
treatment plant by comparing them with
Oxidation-reduction potential as a monitoring
experienced control data, if the results of such
tool in a low dissolved oxygen wastewater
analysis are accumulated for every season.
treatment process. J. Environ. Eng. 129(1)
pp. 52-58
CONCLUSION 5. Wareham, D.G., Hall, K.J., Mavinic, D.S. (1993)
Real-time control of aerobic- anaerobic
Because oxygen supply has the same basic sludge digestion using ORP. J. Environ.
unit as oxygen demand, which can vary Eng. 119(1) pp. 120-136
according to the inflow load of organic 6. Plisson S.S., Capdevile, B., Mauret, M.,
substances, it was possible to propose a method Debuin, A., Baptiste, P. (1996) Real-time
that estimates a theoretically optimal DO control control for nitrogen removal using three
concentration by deriving the equation relating ORP bending points : Signification, control
the oxygen supply and the multi-step DO strategy and results. Wat. Sci. Technol.
control concentration. If the derived equation is 33(1) pp. 275-280
applied in an automatic control method in an 7. Caulet, P., Bujon, B., Philippe, J.P., Lefevre,
aerobic process of a wastewater treatment plant F., Audic, J.M. (1998) Upgrading of
in order to maintain the DO concentration at wastewater treatment plants for nitrogen
the optimal level, it will make a contribution removal: Industrial application of an
not only to the prevention of excessive air flow, automated aeration management based on
but also to the achieving of economical and ORP evolution analysis. Water Sci. Tecjnol.
efficient operation. 37(9) pp. 41-47
8. Zhao, W.H., Mavinic, D.S., William, K.O.,
Reference Frederic, A.K. (1999) Controlling factors for
simultaneous nitrification and denitrification
1. Paul, E., Plisson, S.S., Mauret, M., Cantet, in a two stage intermittent aeration
69

process treating domestic sewage. Water small sequencing batch reactor for BOD
Res. 33(4): 961-970 and nitrogen removal based on on-line
9. Chen, K., Chen, C., Peng, J., Houng, J. OUR coaculation. Wat. Sci. Tech. 35(6) pp.
(2002) Real-time control of an immobilized 29-36
cell reactor for wastewater treatment using 14. Rubio M., Ruiz M., Teran M.F., Arroyo F.,
ORP. Water Res. 36 pp. 230-238 Colomer, J., Colprim, J. (2005) Fuzzy control
10. H ao, J.O ., K im , H . (2000) pH and of dissolved oxygen and on-line OUR
oxidation-reduction potential control estimation in a SBR pilot plant. The 2nd
strategy for optimization of nitrogen IWA Conference, Instrumentation, Control
removal in an alternating aerobic-anoxic
and Automation, Pusan, Korea
system. Water Environ. Res. 73(1) pp.
15. Wild Jr, H.E., Sawye, C.N., McMahan, T.C.
95-102
(1971) Factors Affecting Nitrification
11. Olsson, G., Newell, B. (1999) Wastewater
Kinetics J. WPCF. 43 pp. 1845-1854
Treatment System : Modelling, Diagnosis
16. Schon, G., Gfywitz, S., and Mertens, F.
and Control. IWA publishing, UK.
(1993) Influence of DO and ORP on
12. Spanjers H., Vanrolleghem P.A., Olsson, G.,
Dold P.L. (1998) Respirometry in Control phosphate release and uptake by activated
for the A c tiv ate d S ludg e P roc es s: sludge from sewage plants with EBPR.
Principles. IAWQ Scientific and Technical Water Res. 27(3) pp. 343-354
Report No 7, London UK 17. Tchobanoglous G., Burton, F., Stensel, H.D.
13. Johansen, N.H., Andersen, J.S., la Cour (2004) Wastewater Engineering, Treatment
Jansen, J. (1997) Optimum operation of a and Reuse, 4/e By Metcalf & Eddy, Inc.

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