9 11/13/05 19:05 Page 74 74 + Chapter3 | The Structure of Crystalline Soli QUESTIONS AND PROBLEMS D Fundamental Concepts 3A What is the difference between atomic struc- tire and exystal structure? Unit Cells Metallic Crystal Structures 32 If the atomic radius of lead is 0.175 nm, caleu- Tate the volume of iis unit cell in cubie meters. 33 Show for the body-centered cubie crystal structure that the nit cell edge length a and the atomic radius R are related through a= 4R/V3, 34 For the HCP crystal structure, show that the ideal c/a ratio is 1.633. ‘38 Show that the atomic packing factor for BCC is 068. ‘3.6 Show that the atomic packing factor for HCP is 0.74 Density Computations 3.7 Molybdenum has a BCC crystal structure, an atomic radius of 0.1363 nm, and an atomic ‘weight of 05.04 gimol, Compute and compare its theoretical density with the experimental value found inside the front cover. 38 Calculate the radius of a palladium atom, aiven that Pd has an FCC crystal structure, a density of 12.0 gicm’,and an atomic weight of 106.4 g/mol. 39 Calculate the radius of a tantalum atom, given that Ta has a BCC erystal structure, a Gensity of 16.0 giemr’,and an atomie weight oF 180.9 g/mol. 3.10 Some hypothetical metal has the simple cubic crystal structure shown in Figure 3.23. If its atomic weight is 74.5 g/mol and the atomic radius is 0.145 nm, compute its density. 3411 Titaniuo has an HCP erystal structure and a density of 4.51 glem’. (a) What isthe volume ofits unit cel in cubie meters? (b) Ifthe c/a ratios 1.58, compute the values of cand a. 342 Using atomic weight, crystal structure, and atomic radius data tabulated inside the front cover, compute the theoretical densities of aluminum, nickel, magnesium, and tungsten, and then compare these values with the mea- sured densities listed in this same table, The c/a ratio for magnesium is 1.624. 3413 Niobium has an atomic radius of 0.1430nm and a density of 857 glem®. Determine whether it has an FCC of BCC erystal structure. 3414 Below are listed the atomic weight, density, and atomic radius for three hypothetical al- loys, For each determine whether its crystal structure is FCC, BCC, or simple cubic and then justify your determination. A simple cubic unit cell is shown in Figure 3.23. ‘Atomic Atomie Weight Density ‘Radius Alloy —__(gimol) __(glem" (am) A 431 640 B itt 1230 c 9.00 3.5 The unit cell for uranium has orthorhombic symmetry witha, b, and ¢ lattice parameters of 0.286, 0.587, and 0.495 nm, respectively. If its density, atomic weight, and atomie radius are 195 glem’, 238,03 g/mol, and 0.1385 nm, respectively, compute the atomic packing factor. igare S25. Hard-sphere unit cell representation of the simple cub crystal structure, D REVISED PAGES EQA79 12/20/05 7:38 Page 75 3.416 Indium has a tetragonal unit cell for whieh the @ and c lattice parameters are 0.459 and 0495 nm, respectively. (a) Ifthe atomic packing factor and atomic ra- dius are 0.693 and 0.1625 nm, respectively, de- termine the number of atoms in each unit cell. (b) The atomic weight of indium is 114.82 ‘/mol; compute its theoretical density. 3.17 Beryllium has an HCP unit cell for whieh the ratio of the lattice parameters c/a is 1.568. If the radius of the Be atom is 0.1143 nm, (a) determine the unit cell volume, and (b) eal- culate the theoretical density of Be and com- pare it with the literature value. 348 Magnesium has an HCP crystal structure, a ‘fa ratio of 1.624, and a density of 1.74 glem’. ‘Compute the atomie radius for Mg. 349 Cobalt has an HCP crystal structure, an atomic radius of 0.1253 nm, and a ¢/a ratio of 1.623, ‘Compute the volume of the unit cell for Co, Coystal Systems 3.20 Below is a unit cell for a hypothetical metal ) To which crystal system does this unit cell belong? (b) What would this crystal structure be called? (©) Calculate the density of the material, sven that its atomic weight is 141 gimol 0.48 on ee F035 nm 321 Sketch a unit cell for the face-centered or- thorhombie erystal structure, Point Coordinates 3.22 List the point coordinates forall atoms that are associated with the FCC unit eell (Figure 3.1). D D 2nd REVISE PAGES Questions and Problems + 75 323 List the point coordinates of both the sodium and chlorine ions for a unit cell of the sodium chloride crystal structure (Figure 122). 3.24 List the point coordinates of both the zinc and ‘sulfur atoms for a unit cell of the zinc blende ‘crystal structure (Figure 12.4). 325 Sketch a tetragonal unit cell, and within that cell indicate locations of the 114 and + 3 + point coordinates. 3.26 Using the Molecule Definition Utility found both “Metallic Crystal Structures and Crys- Sy slcgrpty” 0d “Ceramic Cystal rue Lek tures” modules of VMSE, located on the book's web site [www.wiley.com/college/cal- lister (Student Companion Site)], gencrate (and print out) a three-dimensional unit cell for f tin given the following: (1) the unit cell is tetragonal with a = 0.583 nmande = 0.318 rm, and (2) Sn atoms are located at the fol- owing point coordinates: 000 ont 100 408 1100 41d oro 18h oor ost tor a ut Crptallogrophiec Directions 327 Draw an orthorhombic unit cell, and within that cell a [211] direction, 3.28 Sketch a monoclinic unit cell, and within that cla [101] direction. 329 What are the indices for the directions indi- cated by the two vectors in the sketch below? EQAs4g6n_c02_26-79 12/20/05 7:28 page 76 5 2nd REVISE PAGES o QA 16 + Chapter3 | The Structure of Crystalline Soli 330 Within a cubie unit cell, sketch the following 3.38 Determine the indies forthe directions shown directions: inthe following hexagonal unit cell (@) (101), (© (ii), © Pu) © B12), (© [102], @ [T2}, @ (313, () [301] 331. Determine the indices for the directions shown in the following cubie unit cet 3.36 Using Equations 3.61, 3.68, 3.66, 0d 36d, d= rive expressions for each of the three primed indices set (u’, and w') in terms ofthe four unprimed indices (u,v, t and wo). Crystallographic Planes 337 (a) Drawanorthorhombie unit ell, and within that cell (021) plane. 3.32 Determine the indies for the directions shown & in the following eubte unt eet () Draw a monostinie unit call, and within that cell (200) plane ® 3388 What are the indices forthe two planes drawn t in the sketch below? a 3:33 For tetragonal crystals, cite the indices of directions that are equivalent to each of the following directions 39 Sth wii cabie uk he ftovng (a) [OL] 4 — a ©) [100] pS) @ cuoT) te) (itd). 334 Convert the [110]and 00T|dircetionsintothe ©) GE, 40) 212), fourindex Miller-Bravais scheme for hexag- (©) (O12), (g) (3T2), ‘onal unit cells, (@) (313), (h) (301), D79 11/aa/os 19:05 page 77 D 3.40 Determine the Miller indices for the planes shown in the following unit cell a 341 Determine the Miller indices for the planes shown in the following unit cell: — 342 Determine the Miller indices for the planes shown in the following unit cell: 343 Cite the indices of the direction that results from the intersection of each of the following pair of planes within a cubic erystal: (a) (110) D REVISED PAGES Questions and Problems + 77 aand (111) planes, (b) (110) and (170) planes, and (6) (11T) and (001) planes, 344 Sketch the atomic packing of (a) the (100) plane for the FCC erystal structure, and (b) the (111) plane for the BCC crystal structure (similar to Figures 3.106 and 3.116), 35 Consider the reduced-sphere unit cell shown in Problem 3.20, having an origin of the co- ordinate system positioned at the atom la- beled with an U. For the following sets ot planes, determine which are equivale a) (100), (070), and (001) 4b) (110), (101), (O11), and (To1) (©) (111), (171), (11), and (TAT) 346 Here are three different crystallographic planes for a unit cell of a hypothetical metal. ‘The circles represent atoms: i ii Modem! “os nme (a) To what erystal system does the unit cell belong? (b) What would this erystal structure be called”? AAT Relow are shown three different erystallo- graphic planes for a unit cell of some hypo- thetical metal. The circles represent atoms: Losznns| f-0360n-+4 1.0.30 om 25am con) oy (a) “To what crystal system does the unit cell belong? (b) What would thiserystal structure be called”? (©) If the density of this metal is 18.91 g/cm’, determine its atomic weight 348 Convert the (111) and (012) planes into the four-index Miller-Bravais scheme for hexag- ‘onal unit cells. EQA79 12/20/05 7:38 Page 78 78 + Chapter3 | The Structure of Crystalline Soli 349 Determine the indices for the planes shown in the hexagonal unit cells below: Cf Te rT NL fe yr @ s. D 3.50 Sketch the (01T1) and (2770) planes in a hexagonal unit cell Linear and Planar Densities 351 (a) Derive linear density expressions for FCC [100] and [111] directions in terms of the atomic radius 2. () Compute and compare linear density val ues for these same to planes for copper. 352 (a) Derive linear density expressions. for BCC [110] and [111] directions in terms ofthe atomic radius 2. (@) Compute and compare linear density vale ues for these same two planes for iron. 353 (a) Derive planar density expressions for FCC (100) and (111) planes in terms of the atomic radius 2 (@) Compute and compare planar density val- ues for these same two planes for aluminum. 354 (a) Derive planar density expressions. for BCC (100) and (110) planes in terms of the atomic radius R (b) Compute and compare planar density val- ‘ues for these same two planes for molybdenum. 35 (a) Derive the planar density expression for the HCP (0001) plane in terms ofthe atomic radius R. () Compute the planar density value for this same plane for titanium. Polycrystalline Materials 3.56 Explain why the properties of polyerystalline ‘materials are most often isotropic. X-Ray Diffraction: Determination of Crystal Structures 357 Using the data for aluminum in Table 3.1, compute the interplanar spacing for the (110) set of planes 358 Determine the expected diffraction angle for the first-order reflection from the (310) set of planes for BCC chromium when monochro- ‘matic radiation of wavelength 0.0711 am is used, 3.59 Using the data for a-iron in Table 3.1, com- pute the interplanar spacings for the (111) and (211) sets of planes D 2nd REVISE PAGES EQA9 11/13/05 19:05 Page 79 D REVISED PAGES Questions and Problems + 79 Figure 324 Diffraction pattern for powdered tungsten. (Courtesy ‘of Wesley L. Holman.) Ditoetin are 27 3.60 The metal rhodium has an FCC erystal struc- ture. If the angle of diffraction for the (311) set of planes occurs at 36.12° (fistorder reflec- tion) when monochromatic x-adiation having aa wavelength of Q0711 nm is used, compute (4) the interplanar spacing for this set of planes, and (b the atomic radius for @ rhodium atom. 361 ‘The metal niobium has a BCC crystal structure If the angle of diffraction for the (211) set of planes occurs at 75:99 (firstorder reflection) ‘when monochromatic x-adiation having. a wavelength of 0.1659 nm is used, compute {@) the interplanar spacing for thi eat of planes and (b) the atomic radius forthe niobium atom. 362 For which set of crystallographic planes will firstorder diffraction peak occur ata diffrac- tion angle of 44.53° for FCC nickel when monochromatic radiation having a wave- length of 0.1542 nm is used? 363 Figure 3.21 shows an x-ray diffraction pattern for lead taken using a diffractometer and ‘monochromaule x-radiavion having a wave- length of 0.1542 nm; each difraction peak on the pattern has been indexed. Compute the interplanar spacing for each set of planes indexed; also determine the lattice parameter ‘of Ph for each of the peaks. D 3.64 The diffraction peaks shown in Figure 3.21 are indexed according to the reflection rules for FCC (ice, fi, k, and I must all be either odd or even). Cite the / k.and 1 indices of the first four diffraction peaks for BCC erystals con- sistent with h + & + [being even. 3465 Figure 3.24 shows the first five peaks of the x-ray diffraction pattern for tungsten, which has a BCC erystal structure; monochromatic x-radiation having a wavelength of 0.1542 am was used. (a) Index (ie, give h, k, and 1 indices) for cach of Une peaka (b) Determine the interplanar spacing for each of the peaks. (©) For each peak, determine the atomic ra- dius for W and compare these with the value presented in Table 3.1. Noncrystalline Solids 3.00 Would you expect a matertal In which the atomic bonding is predominantly ionic in nature to be more or less likely to form nonerystalline solid upon solidification than a covalent material? Why? (See Sec- tion 2.6.) EQA