1. @ pts each, 15 pts total) Provide a systematic name or the chemical formula for the following pure substances: (a) potassium permanganate k M, 0 0 $ (o)_Zoppew T) Acetate CuCH302)2 (©) sodium bicarbonate Nal Ws p (@ perchloric acid Hu Du © ninco Ave? vat NHiNOs 2. (3 pts each for a-h, 12 pts for i, 36 pts total) (a) Circle the atom with the smallest radius (b) Circle the ion with the smallest ionic radius (0) Circle the most electronegative atom (d) Circle the species with the highest ionization energy KI Cgo> (©) Circle the strongest bond (® Circle the compound with the highest (absolute value) ionic lattice energy (g) Circle the compound with the highest AHvap ethanol methane (water > (h) Circle the binary acidg with the strongest acidity HF HCL HBr (i Classifying salt solutions as acidic, basic, or neutral: circle one choice for FeCls ‘acidic neutral basic circle one choice for NHsBr acidic neutral basic circle one choice for KBr acidic Cneutral basic cirele one choice for KNO> acidie neutral 3. (4 pts each, 12 pts total) Provide the electron configurations (using noble gas as the inner electron configuration) and the magnetic properties (paramagnetic or diamagnetic) of following elements or ions: Electron Configuration Magnetic Property a) Zn" DA a4s°3d’? diamugnetic bo UMN da gyorg Mo _ckylss 4a proasnagnetie4G pts each, 10 pts total) Draw a Lewis strcturey foreach ion, a) NH b) Clo” Caen 5. (10 pts total) Consider the following Lewis structure for formamide: H 4) (6 pts) For this structure calculate the formal charge for the following atoms: (show Un your work): 4 oe FCN) = S-o- 3 (8)= | \y F.CO)= £ (2) F.C(C)= ¢ ¥) =D b) (4 pts) Draw one better or an equivalent resonance structure for formamide: Pal Geo: eo | Wu 6. (3 pts each, 15 pts total) Indicate the hybridization of the valence orbitals of the central atom in the following species: a) COCh (carbon is the central atom) _S P ~ b) BrFs spd i oHN P d) H30* sf a oly sp7. @pts each, 12 pts total) Write the net ionic equations for the following reactions that occur (if any) when you mix: (a) solutions of ammonium nitrate and calcium hydroxide N/A (b) solutions of ammonium and sulfuric acid Het Oleg 2 H,0¢2) (©) solutions of lead({I) nitrate and iron(II) iodide Pb eg) pe) ) a pb I(9 (@) solutions of magnesium sulfate and lithium nitrate wilh 8 (3 pts each, 9 pts total) Determine whether each reaction is a redox reaction, Circle the correct answer and, if “yes”, identify the oxidizing agent and the reducing agent. (a) 2Mg(s) + O2xg) — 2MgO(s) Ges) no); the oxidizing agent:__ UJ) the reducing agent: My (2 (b) SOsx(g) + HOW) — HSO«(aq) (yes &): the oxi (©) Pb(NOs)(ag) + 2LiCKag) —> PbClA(s) + 2LiNOs(aq) (yes @: the oxidizing agent: the reducing agent: ing agent: the reducing agent: 9. (10 pts) The decomposition of SO2Ch2 is first order and has a rate constant of 2.90 x 10“ S"!. If the initial concentration of SOzClzs 0.0225M, what will the SO2Clz concentration be after 14.41 min? Show meme [0b I 2 hd t InLsb LD naz, = (290 KE". BESS) # [Cho 225M] Cb}: oo aro10. G pts each, 12 pts total) Label the lines shown in the figure using (a), (b), (c), and (4) for the corresponding gases of: (a) 1 g Ozat 3.29 atm, (b) 0.5 g SO» at 1.97 atm, (c) 1 g O2 at 1.97 atm, and (4) 0.5 g pat 1.97 atm. ‘Temperature, °C 11. (10 pts) Consider the reaction: Ig) + Ch(g) €> 2ICK(g) Ky = 81.9at25°C A reaction mixture at 25 °C initially contains Pj, = 0.010 atm, Pc: = 0.01 atm, and Pict = 0.100 atm. Find the “a Peril we of Ia, Ch, and ICI at this temperature. Show your work. * Gaaycay “lee 7 Kemeny, gees lett (esl -2% > + = 217A, LG eee bw bq = 3 i) 44 (Onl any (TD 02 one 7 | 2x oeltX ltX a why = a tA Aree ce im crete mm X= peers ADCS be a aole7h aha Th: al. OF PLT ath 12, @ pts each, 10 pts total) Ths reactions exothermic: CeHlisOc(s) + 60x(g) €-> 6COx() + 6H20(8) Hd Predict the direction in which the equilibrium above shifts upon disturbing the system and circle the following answer: (a) increase of reactor volume left no change Cate) —_ (b) removal of COr(g) left no change right_/ (©) addition of CoHi20«(s) left right (d) decrease of temperature left no change Crit (c) Predict the effect of decreasing the reactian temperature on the value of the equilibrium constant Ceres) no change decrease 513. (10 pts) Calculate AHew for the reaction: Fe20x(s) + 3CO(g) > 2Fe(s) + 3COxg) Use the following reactions and given AH’s. Show your work, 2Fe(s) + 3/20x(g) > FexOx(s) AH = -824.2kI CO(e) + 1/202(g) > COx(g) AH = -282.7kI Fads o> 2 fe Gt 244) aH = + MET 3604) 42 On) > 3c0.4) oH = 282s) FIx 3 -23.4 ¥T SE 14. (9 pts) The pH of an acetic acd solution is measured to be 4.74. Ks of acetic aid is given as 1.8 ~10%. Calculate the percent of ionization of acetic acid. Show your work. Thus 1 fash aT KE 7 Aca Pka- pH = —of ee AHH = O= log Cretly > aw] Cad ep pala c+ Perey Tova - Acid Jet / DY h toe THAcdduntiay 2 _ # 15, (2 pts each, 8 pts total) Determine whether or not the mixing of the two solutions will result in a buffer. Circle the correct answer. (@) 100.0 mL of 0.1 MNEs; 100.0 ml of 0.15 MNHCI_ (es? no) (b) 50.0 mL of 0.1 M HCI; 35.0 ml of 0.15 MNaOH —_—_( yes (ho (c) 50.0 mL of 0.1 M HF; 20.0 ml of 0.15 M NaOH (yes (foo, (@ 100.0 mL of 0.1 M HC2H302; 100.0 ml of 0.1 M NaC2H302 Cc no ) 16. (2 pts each, 12 pts total) Provide formula of the conjugate acid for each of the following species: @cr_ HU _,@)Hcos 1d, , (NH Mbe Provide formula of the conjugate base for each of the following species: (a) H20_ OH.) HSOr lg (©) HCIOz a 17. (6 pts each, 10 pts total) (a) Balance the following redox reaction occurring in acidic aqueous solution: ES so(aq) + 2-_Mn0¢(aq) + bitty) — £ SOe(ag) + 2 Mn®*(ag) + spl)(b) Balance the following redox reaction occurring in basic aqueous solution: [| 0xaq) + _2_ct0x(ag) + 2 Orley) 2 costar) + | ong) + 2D (L) 18, (8 pts each, 16 pts total) Calculate the pH of the following aqueous solutions at 25 °C. (a) 4 0.015 M aqueous solution of NaClO (Ks = 3.5108). Show your work: Digit POD = Mg) , _ Lined] CH] 201s 9 wT by ooisM-x x Ke kw Le" Kys29K1 0" wow X BONE = Cot 2 40K107 aoe" Aiea oe 4 : Fm aChbpns J -418 : nme PHE I4- em RB Thep:_7i Fe (b) a mixture containing 0.20 M NHs (Kp = 1.76%10°) and 0.15 M NH4Cl ale a ‘Show your work: . [pit p y, fey pel Pe ery ces I I rah Joy Corea) +/4 piace “rad to + loyeas) The pH: F737 met ease 13 19. (14 pts total) Consider a voltaic cell cbmposed of two half-cells with the following standard reduction a potentials: @) PbO2(s) + 4H"(ag) + SOs*(aq) + 2e” > PbSO«(s) + 2H20(1) ) PbSO«(s) + 2e° > Pb(s) + SOs*(aq) (i) (2 pts) Which of the reactions, (a) or (b), will occur at the eathode of the voltaic cell (circle one). b) (ii) (6 pts) Write balanced equation of the spontaneous redox reaction occurring in this voltaic cell: PADv (9) + weg) 4250 p+ Plus) > 2 PLEAD 7 201.8) (iii) (6 pts) Calculate the standard cell potential, E°c1, for the voltaic cell above. Show your work. Eoay = E cathode - Ennode Prt _20sy = ogy — (-a>dv) coe = f2es V Z