Sol 31 PDF

1
AITS-CRT-I (Paper-2)-PCM(Sol)-JEE(Advanced)/15
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ANSWERS, HINTS & SOLUTIONS

CRT– I
(Paper-2)
ALL INDIA TEST SERIES
Q. No. PHYSICS CHEMISTRY MATHEMATICS
1. D A C
2. B A C
3. B C C
4. B C B
5. D A D
6. C D A
7. C D C
8. D A B
9. D A A
10. C C C
11. D C A
12. B B C
13. B B C
14. C C A
15. D B C
16. C A B
17. A A C
18. C A B
19. D A D
20. B B D
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2
Physics PART – I
SECTION – A
2. 6 = V cos  t ...(1)
1
3 = V sin  t  gt 2 ...(2)
2
V 2 sin2
24 = ...(3)
g
Solving the equation we will get the result
1 2 1
3. kx  mv 2
2 2
mv 2
x
k
4. F = mg use concept of toppling
5. Use concept of conservation of energy Ei = Ef
mg  F v
6. a
m
v  u  at
0 2i
7. Use B  
4 r
 +
8. M  iA B
+
dx 2
A  x2 ,i  ,t +
t 
+ dx
Place the value in M = iA
x
A

h
9. x  distance of final image of bird from x

bird itself
h
 ˆ 2
11. r  i (t  4t)  ˆj( t 3 )

Differentiation twice to get a  ˆi(2)  6t ˆj
  
  r F
12.   F  dr
3
 x x-volt
15. (6  x) i0RA and  6    (3i0 )R A A V
 3
i0
6x 1
 
x 3
6
3 6V
9
 x V
2
3
 after connection = V
2
 3R v  x
16. i0  RV = x and (3i0 )  
 3  Rv  3
3
 i0  A
16
17. (P) Vcm = (R  r)

1 2
 rotational E  m  R  r  2
4
1 2 1 3
(Q) total kinetic energy = mv cm  Icm 2  m(R  r)2 2
2 2 4
 ˆ 2ˆ
(R) acm  (R  r) i  (R  r) j
  
18. Lany point  Lcm, that point  L about CM
3
(P) 
2
mvr kˆ  
(Q)  (1)
1 1
K  mv 2cm  Icm 2
2 2
3
 (R)  mv 2
4
19. Slipping between 2 and 8

14  12
(P) a2 kg  1
2
12  10 1
(Q) a8 kg  
8 4
(R) 0.6  2  10 = 12
20. Basic combination of lenses.
4
Chemistry PART – II
SECTION – A
1. C2H5 H2C CH3 H3C CH2

C2H5
H3C C OH H3C C  H3C C I I C CH3
HI I
  
HC CH3
2H O2 CH CH3 CH CH
CH3 H3C CH3 H3C CH3
CH3
3o Racemic mixture
2. O O O O O
C O C2H5 C OH
H3O  



  CO 2
  ketoacid
3. Br2 KCN 
COOH
H3C COOH   H2C COOH   H2C H2O / H
COOH 
Re d P  H2C
Br CN COOH


 CO
 CH3COOH  CO2 

2
4.
Et2NH / DMF /  Reduction
F NO 2   Et 2N NO 2   Et 2N NH2
HF
NaNO /HCl + dil. HBF


2
 Et 2N N2 Cl 
4
Et 2N F

5. CH3 CH3
H2C C opens as as operating unit
CH2 C
CH3
CH3
6. F
F F
S
C1
C2
F F
F
7. XF4-type molecule have zero dipole moment when it is either tetrahedral or square planar.
5
8. rA  22.5
 0.225   0.225
rB rB
 rB  100 pm
9. Go  2GoZnO  2 GSO

o
2
 2GoZnS
= (–616–408)–(–293) = –731 J
10. Expansion of real gas above its inversion temperature shows heating effect.
11. sp3d2  it involves dx 2  y 2 and dz2 orbitals in hybridisation.
3 3
12. sp d  It involves dxy, dyz, dzx d-orbtials in hybridisation.
13. Go = –nFEo

= – 2  96500  1.10 = – 212.3 KJ
 dE  S
14.   
 dT P nF
S
 1.5  10–4 =  S = 28.95 JK–1 mol–1
2  96500
15. COOH COOH

COOH
NH2 N2 Cl NMe2
NaNO HCl

2

 
 N N NMe2
16. NHAc NHAc NHAc

NH2 CH3
3 CH COCl 2H SO
4 MeCl/ AlCl KMnO
4

   
3
  
SO3H SO3H
NHAc NH2
COOH COOH

H

SO 3H
17. Fact.
19. Read the text.
20. –COOH, –NO2 groups are deactivating groups and –CH3, –NMe2 are activating group. Friedel

Craft’s acylation not take place with the deactivated benzene compound NH2 is nucleophile.
6
Mathematics PART – III
SECTION – A
1. At x = 0, , 2
LHS = RHS
Now let f(x) = tan–1(sin x) and g(x) = sin–1(tan x)
2
f 'x 
cos x
and g'  x   sec x  cos x 
cos x
 f ' x 
2
1  sin x 2
1  tan x 2
1  tan x 1  sin2 x
Hence, f(x)  g(x)  x  domain. So f(x) and g(x) are equal only at x = n
g(x)

2 3
f(x) 4
 3
4 2    5
–
4 4 4
  
 –
– 2 2
4
2. P(x) – 2008 + x = x(x – 1)(x – 2)(x – 3) ….. (x – 2008)

Put x = 2009
3.  f(x) = 3x2 + 2x + 100 + 7 cos x

= 3x2 + 2x + 93 + 7(1 + cos x)
2
 1   278
= 3  x      7 1  cos x   0
 3   3
 f(x) is increasing function  f(1) < f(2) < f(3)
(Let a < b < c)
Now g(y) = (y – b)(y – c) + 2(y – c)(y – a) + 3(y – a)(y – b) = 0
 g(a) > 0, g(b) < 0 and g(c) > 0
C0 C C C n Cn n!
4.   1  2  3  .....   1 
x x 1 x  2 x  3 x  n x  x  1 x  2  .....  x  n 
C0 C1 C 2 C3 1 1 1
 At x = 2, un      .....   
2 3 4 5  
n  1 n  2  n  1 n  2
1 1 
Hence, sn = u1 + u2 + u3 + ….. + un =  
 2 n  2 
5. (1) ad = 1, bc = 4 (2) ad = 1, bc = 2
(3) ad = 2, bc = 1 (4) ad = 2, bc = 4
(5) ad = 4, bc = 1 (6) ad = 4, bc = 2
  a cos   b sin  
6. Centroid = circumcentre =  x1, y1    , 
 3 3 
 9x12 9y12 
 2  2  3   2   cos  cos    sin  sin  
 a b 
7
7.  = 1 + 2 C
1 C C
 = ab sin c = ab sin cos
2 2 2
1 C 1 C
1 + 2 = 6b sin  6a sin b a
2 2 2 2
 = 1 + 2
1 1 1 ab 1 2
   9
a b 9 ab D B
A
8. M x   

e x e2x  2  dx
4x 2x
e  8e 4
x
Put e = t
x x x
f  x   x 2   e t f  x  t  dt = x 2   e   f  t  dt  x 2  e x  e t f  t  dt
 x t
9.
0 0 0
x
 ex f(x) = x2e x + t
 e f  t  dt
0
Differentiating both sides w.r.t. x
ex f(x) + e x f1(x) = 2xe x + x2e x + e x f(x)
 f1(x) = 2x + x2
x3
 f  x   x2  c
3
10. Given differential equation can be written as

xdy  ydx dx
 2
(xy  1)2 x
Integrating both sides
1 1 1 1
   c  c
(xy  1) x xy  1 x
11.-12. Shown in figure

P1(–2, –1) C3(2, 2)
P2(–4, –1) S2 S1
P3(–1, –4)  1 P1
C 2  3,   C1(0, –2)
 2 P P3
2
T(–3, –3)
13. f(c1) > f(c2)

f(c1) > 0 and f(c2) < 0
 at x = c1, f has local minimum and at x = c2, f has local maximum
14. See above solution

2
15. (8n + 4) = (4(2n + 1)) = (4) (2n + 1) = (2 ) (2n + 1) = 2(2n + 1)
16. (pn) is odd  pn – 1(p – 1) is odd
8
 p is prime, the only value p can take is p = 2

 (2n) is odd
17. (P) f(x) = 2x + g(1), f(x) = 2

g(x) = 2x + f(2), g(x) = 2
at x = 1, f(1) = 2 + g(1) and g(1) = 2 + f(2)
 f(1) = 4 + f(2)
(Q)  2f(x) f(y) = f(x – y) + f(x + y) ….. (1)
Replacing x by y and y by x, then
2f(y) f(x) = f(y – x) + f(y + x) ….. (2)
From equation (1) and (2), we get f(x – y) = f(y – x)
Put y = 0, then differentiate
2
(R) f(x) = 3x + 2xf(1) + f(2)
 f(1) = 3 + 2f(1) + f(2)
 f(1) + f(2) = –3
 and f(x) = 6x + 2f(1)
 f(2) = 12 + 2f(1)
 –2f(1) + f(2) = 12
(S) n(a + b)n – 1 = nan – 1 + nbn – 1
18. (P) Put t + 2 = z

(Q) Put 3t = z
(R) Integrate by part
1
(S) Put  z
t
1
1
A  4 1
19. (P) P  4 
 1 1 1 3 1 6 1 
 B        1
2
4 10 4 10 4 10 4
3  5 C3  53 31
(Q) Required probability = 15

C3 91
3!  2  3
(R) Required probability = 
4 44 16
3
A 1 1 1 1 1 5
(S) P  A    P  Ei   P     1     
i 1 E
 i 3 3 2 3 6 9
1 1 1 1 1
1  
 E1  3 3  E2  3 2 3  E3  3 6 1
Thus, P     , P    and P    
A 5 5  A  5 10  A  5 10
9 9 9
10 10
20. (P)  r   r  2    r 2  r  1  1
r 1 r 1
4 4 –1 –1 4 8 –1 –2 2
(Q)  +  +   = + +  =+ +1=0
T    
(R) N = 1 + cos  + i sin  = 2cos cos  isin   2cos  ei/2
2 2 2 2
r 2 r 
D = –i sin  + i(1 + cos ) = i [conjugate of N ] = i2cos  e i /2
2
   
(S)    .....  
3 3 2 33 2

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ANSWERS, HINTS & SOLUTIONS

Q. No. PHYSICS CHEMISTRY MATHEMATICS

4. F = mg use concept of toppling

5. Use concept of conservation of energy Ei = Ef

17. (P) Vcm = (R  r)

19. Slipping between 2 and 8

20. Basic combination of lenses.

1. C2H5 H2C CH3 H3C CH2

NaNO /HCl + dil. HBF

9. Go  2GoZnO  2 GSO

11. sp3d2  it involves dx 2  y 2 and dz2 orbitals in hybridisation.

13. Go = –nFEo

15. COOH COOH

16. NHAc NHAc NHAc

19. Read the text.

Mathematics PART – III

2. P(x) – 2008 + x = x(x – 1)(x – 2)(x – 3) ….. (x – 2008)

3.  f(x) = 3x2 + 2x + 100 + 7 cos x

10. Given differential equation can be written as

11.-12. Shown in figure

13. f(c1) > f(c2)

14. See above solution

16. (pn) is odd  pn – 1(p – 1) is odd

 p is prime, the only value p can take is p = 2

17. (P) f(x) = 2x + g(1), f(x) = 2

18. (P) Put t + 2 = z

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