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IQBAL ABDUL DHALAIT

Feature Article

Fun With
Chemistry!
peroxide, ammonium hydroxide, Now, open the Coca Cola bottle in
hydrochloric acid, potassium iodide, liquid front of your guests and pour some of the
detergent, Tincture of Iodine, sodium liquid in the empty glass, you will get Coca
thiosulphate, Phenolphthalein pH indicator, Cola. Then pour the remaining liquid from

E
VERY day we come across many ethyl alcohol, water, potassium the same bottle in the other glass
changes in our surroundings. These permanganate, glycerin, ammonium containing crystals of Sodium thiosulphate.
changes may involve one or more thiocyanate, ferric chloride silver nitrate, This time you will get plain water. The crystals
substances. For example, your mother potassium ferrocyanide, ferric chloride, of sodium thiosulphate (hypo) react
may ask you to dissolve sugar in water to sodium hydroxide. chemically and decolourise the liquid when
make a cold drink. You would also be it is poured in the glass. The coloured liquid
familiar with the rusting of iron in which 1. Change Coca Cola into dramatically becomes as clear as water!
oxygen molecules from the atmosphere Water
react with iron atoms in presence of
Let us suppose you have invited two guests
moisture to form a new substance. The
to your place and one of them is interested 2. The Crazy Message
atoms in iron oxide line up differently from Take a blank white paper and write any
to have Coca Cola while the other wants
those in either oxygen molecules or iron. message with phenolphthalein indicator
plain water. Now, your predicament is that
Again, if we look at photosynthesis, using cotton bud and allow it to dry. Fill the
although you have a bottle of Coca Cola,
plants use the energy in sunlight to join spray bottle with ammonium hydroxide
you do not have drinking water. Strange
together six molecules of carbon dioxide solution and spray this solution directly on
situation, but let’s go along with it.
and six molecules of water to produce the watery marks on the paper. The invisible
Now, can you please both of them by
one molecule of glucose and six message written on the paper will begin to
pouring Coca Cola for one from a Coca
molecules of oxygen. We drink potable appear in colour and you will be able to
Cola bottle and plain water for the other
water from the tap or from a bottle. We read it.
from the same bottle? Impossible? Well, just
may also drink it as lemonade or fruit juice, But interestingly, after a few minutes
perform this simple chemical trick not for
tea or coffee. This water has unique the colour message will start to fade away
actually drinking purposes but just to impress
properties because of the way in which and finally completely disappear. Due to
your guests.
its molecules cling to each other. It is an the alkaline nature of ammonium
Prepare Coca Cola chemically by
oxide of hydrogen, just a chemical but hydroxide, phenolphthalein gives a pink
mixing sufficient quantities of Tincture of
remarkably unusual. Just add a single colour when it is allowed to mix with the
Iodine in water so as to get dark colour
oxygen atom to it and it becomes solution. Further, on exposure to room
similar to the Coca Cola drink, store it in a
hydrogen peroxide with absolutely temperature the ammonia evaporates
soft drink bottle and seal it properly well in
different properties. from ammonium hydroxide leaving the
advance. Take two empty glasses, put
Isn’t it all so curious? Chemical water particle behind on the paper which
some crystals of sodium thiosulphate in one
reactions happen naturally or can be is colourless in phenolphthalein indicator.
glass well in hand.
made to happen; they may take years or In this way the message disappears to your
only an instant. Here are some reactions great surprise.
laid down before you. Try them at home
and enjoy the fun.

What will you require?


An empty soft drink bottle, drinking glasses,
jug, conical flask or transparent plastic
bottle, rubber cork, rose flower, plate,
paper cup, handkerchief, metal plate/
ceramic plate, knife, cotton bud, blank
white paper, cotton swab, match box,
pairs of tong, glucose powder, methylene
blue indicator, sulfur powder, hydrogen

29 SCIENCE REPORTER, APRIL 2011


Feature Article
the centre of this plate. Arrange some
First ethyl alcohol starts to burn Cut Your Hand
pieces of paper on a metal plate. Put two
since it has a low boiling or three drops of glycerin over potassium Painlessly
temperature as compared to permanganate. The glycerin will slowly start
Moisten your hand with a
water. to react with this black powder by giving
off smoke and very soon the pieces of solution of ammonium
Water acts like an absorber paper will start to burn with violet flame. thiocyanate and apply ferric
This is an example of exothermic
3. The Unburnable reaction in which heat is produced and it chloride solution with cotton
Handkerchief is sufficient to burn the paper pieces. on the knife blade. Now begin
Unscrupulous people often use this trick to
Ask your friend to give
demonstrate their “supernatural” powers.
your demonstration.
you his
handkerchief But now you know it is just a simple
chemical trick.
and get his kind
permission to
burn it. Hardly 5. Cut Your Hand
likely that you Painlessly
will get the Can you dare to cut your hand with a
permission. Well, knife? Well, try this simple chemical trick
you can perform to impress your friends.
this trick with your First, before you begin your trick
handkerchief. moisten your hand with a solution of
Dip it in a mixture ammonium thiocyanate and apply ferric
of ethyl alcohol and water prepared in chloride solution with cotton on the knife
the ratio of 1:1. Squeeze out the excess blade. Now begin your demonstration.
liquid and hold it with pairs of tong and Hold the knife and press the reverse
then put on the candle flame. You will be edge, the blunt edge, of the knife against
Prepare solutions such as ammonium
surprised to notice that the handkerchief your skin where ammonium thiocyanate
thiocyanate, silver nitrate and potassium
catches fire without actually burning. has already been applied. At once a
ferrocyanide by dissolving about a
When you put the handkerchief on blood like liquid will flow out of the mark
spoonful of these chemicals into 50 ml
fire, first ethyl alcohol starts to burn since it made by the blade as ammonium
water respectively. Take about 10 drops
has a low boiling temperature as thiocyanate and ferric chloride react. It
of each solution in three glasses and
compared to water. Water acts like an will seem as if you have actually cut your
arrange them side by side on the table.
absorber and absorbs the heat released hand and the wound is bleeding.
Prepare another solution of ferric chloride
by burning the ethyl alcohol helps to keep
of the same concentration. Mix it with three
the temperature of the cloth down so that
glasses of water in the jug.
it does not catch fire. 6. Tri-Colour Change
Just pour the liquid from the jug into
If your friend has been bold and You must be familiar with the phenomenon
the first glass and you will get red colour
trusting enough to hand over his of a turmeric stain on a white shirt turning
resembling the soft drink. You will get milk
handkerchief, you can now return the red when it is washed with soap. This
in the second glass and blue ink in the
handkerchief without any damage done. happens simply because of the alkaline
third glass. The change of colour to red
nature of the soap solution. This chemical
and blue are familiar tests for ferric ion
4. Create Fire Magically reaction is another example of colour
that was already present in the solution.
Place a metal /ceramic plate on a table. change. If you know how to do it, you can
The white precipitation is a common test
Put a piece of paper with some potassium easily turn water into soft drink, milk or even
for chlorides. Silver nitrate reacts with ferric
permanganate ground in powder form in ink.
chloride to form a thick white precipitate
of silver chloride resembling milk.

7. Shake It to Get Blue


Colour
Oscillating reactions are truly spectacular
because of the visual display exhibited by
these reactions. Here is one of such
reaction that can be performed with
common chemicals.
Fill three fourth of a conical flask or
transparent plastic bottle with water. Add
about 5 grams sodium hydroxide in it. Add
5 grams of glucose powder and then put

SCIENCE REPORTER, APRIL 2011 30


Feature Article
Now take this flower out of the glass.
Fill the glass halfway with hydrogen
peroxide and dip the rose into it. It will start
to gain its original colour. The sulfur dioxide
which is produced by burning sulfur
combines with oxygen from the coloured
part of the flower leaving the flower
bleached white. The bleached flower is
then dipped in hydrogen peroxide which
provides oxygen to the flower restoring its
colour.

9. Create Smoke without


Burning You will be fascinated to see the
a few drops of methylene blue indicator Take a glass, moisten the inside of the glass tiny bubbles that make the
to this solution and shake them to mix the with ammonium hydroxide. Take a few resulting column of foam that
dye. The resulting solution will be blue. drops of concentrated hydrochloric acid
Hold and keep the solution steady on the plate. Invert the glass over the plate.
gushes out look more like
and observe any change in colour. The Fumes will start to accumulate in the glass. toothpaste.
liquid will gradually become colourless as
glucose reduces the methylene blue dye
and the colour of the solution disappears. tiny bubbles that make the resulting
Can you restore this colour again? column of foam that gushes out look
To do this just shake the contents of more like toothpaste.
the conical flask very rapidly by capping
the mouth of the container with cork, 11. Boil Water in Paper
you will be surprised to see blue colour Cup
again. This is due to re-oxidation of What do you think will happen to a paper
methylene blue with oxygen from the cup of water when it is held over a candle
trapped air. The reaction can be flame? You would be surprised to know
performed several times by standing
and shaking alternately to make it
happen again and again.

8. A Rose of Changing The vapors of ammonia combine with


Colour hydrochloric acid to form dense white
fumes of ammonium chloride to give the
Take a fresh rose and moisten it with water.
effect of smoke.
Tape it to the inside of a drinking glass as
shown in the picture. Place a small amount
of sulfur on a metal plate and allow it burn
10. Oxygen Foam
Pour 100 ml of hydrogen peroxide into
by providing heat. When it begins to burn,
a tall glass cylinder. Add some liquid
invert the drinking glass over the burning
detergent to it. Mix them thoroughly.
sulfur. The flower will start to lose its natural
Add about a teaspoonful potassium
colour and will become white.
iodide in this mixture to make the that the paper cup will not burn. Let us see
hydrogen peroxide break down how it is done.
chemically. This rapid decomposition Fill three fourth of a paper cup with
results in lots of oxygen that turns into water. Hold the cup a few centimeters
foam. You will be fascinated to see the above the candle flame. The paper cup
held over an open flame will not burn
because the heat from the flame transfers
A Rose of Changing from the cup to the water. Thus the paper
Colour never gets hot enough to burn. Instead,
the transferred heat causes the water to
Fill the glass halfway with boil!
hydrogen peroxide and dip
the rose into it. It will start to Mr Iqbal Abdul Dhalait is an Education Officer with
gain its original colour. the Goa Science Centre, Miramar, Panaji-Goa; Ph:
(0832) 2463426

31 SCIENCE REPORTER, APRIL 2011

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