1.

Buat diagram T,x,y iso butana dan n-heptana pada tekanan 600 kpa

Titik didih propana 11 Diagram T,x,y

Titik didih n-butana 62
1.200

T Ka Kb 1-Kb Ka - Kb xa ya alfaab=Ka/Kb 1.000

11 1 0.24 0.76 0.76 1.000 1.000 4.167
0.800
20 1.25 0.34 0.66 0.91 0.725 0.907 3.676
30 1.6 0.46 0.54 1.14 0.474 0.758 3.478 0.600

T
40 1.95 0.6 0.4 1.35 0.296 0.578 3.250
0.400
50 2.3 0.78 0.22 1.52 0.145 0.333 2.949
62 2.8 1 0 1.8 0.000 0.000 2.800 0.200

0.000
0 10 20 30 40 50 60 70
x,y
60 70
Coba 1
Metanhol Etanol n-Propanol 1 kPa 7.50062 mmHg
Pc 7353.78 6379.7 5052.11 2 atm 202.65 kpa
A 7.513334 7.4344 6.683944 W/D 0.666667
B 3503.33 3424 3008.31 D/W 1.5
C 237.93 217.43 186.66
T 97 97 97 komponen Zi Pv i Ki = Pvi/Pt
A-(B/(C+T)) -2.9465531406 -3.45368 -3.921393376 A 0.25 386.2236 1.905866
e 0.0525204248 0.031629 0.019813468 B 0.6 201.7834 0.995724
Pv (Pc*e) 386.22364973 201.7834 100.0998193 C 0.15 100.0998 0.493954
Pv (mmHg) 2896.9168316 1513.501 750.8107066 jumlah

Coba 2
Metanhol Etanol n-Propanol 1 kPa 7.50062 mmHg
Pc 7353.78 6379.7 5052.11 2 atm 202.65 kpa
A 7.513334 7.4344 6.683944 W/D 0.666667
B 3503.33 3424 3008.31 D/W 1.5
C 237.93 217.43 186.66
T 92 92 92 komponen Zi Pv i Ki = Pvi/Pt
A-(B/(C+T)) -3.1050699039 -3.62962 -4.111685082 A 0.25 329.6066 1.626482
e 0.0448213853 0.026526 0.016380149 B 0.6 169.2298 0.835084
Pv (Pc*e) 329.60660651 169.2298 82.75431639 C 0.15 82.75432 0.408361
Pv (mmHg) 2472.2539049 1269.329 620.7086806 jumlah

Coba 3
Metanhol Etanol n-Propanol 1 kPa 7.50062 mmHg
Pc 7353.78 6379.7 5052.11 2 atm 202.65 kpa
A 7.513334 7.4344 6.683944 W/D 0.666667
B 3503.33 3424 3008.31 D/W 1.5
C 237.93 217.43 186.66
T 96 96 96 komponen Zi Pv i Ki = Pvi/Pt
A-(B/(C+T)) -2.9778767328 -3.48842 -3.958913143 A 0.25 374.3132 1.847092
e 0.0509007952 0.030549 0.019083844 B 0.6 194.8941 0.961728
Pv (Pc*e) 374.31324971 194.8941 96.41368132 C 0.15 96.41368 0.475765
Pv (mmHg) 2807.5814471 1461.827 723.1623864 jumlah
 Kurva
X (suhu) Y (Zigma)
1.02
92 0.946572
97 1.014058
1

0.98
y*ID X IW
0.308688 0.161968
0.598971 0.601543 0.96

0.106399 0.215402
1.014058 0.978913 0.94

0.92

0.9
91 92 93 94 95 96

y*ID X IW
0.295533 0.181701
0.556074 0.665889
0.094965 0.232552
0.946572 1.080142

y*ID X IW
0.306164 0.165754
0.590599 0.614102
0.104112 0.218832
1.000875 0.998688
94 95 96 97 98
komponen zif pv αiR
benzena 0.33 178.7924 2.4090
toluena 0.33 74.2170 1.0000
orto-xilena 0.34 26.4606 0.3565

Basis: F= 100 mol ITERASI KE- 1

D= 25 mol xRW 0.3
W= 75 mol xBW 0.1749
Xxw 0.3955
xBW=(W/(zif*F))*((zrf*F)/W) 0.31449 total 0.8704
xXW=(W/(zif*F))*((zrf*F)/W) 1.646123

yBW=((xif*F)-(xiW*W)/(F-W)) 0.59452
yTW(yRW)=((xif*F)-(xiW*W)/(F-W)) 0.2904
Yxw=1-yBW-yTW 0.11508
 pc a b c a-(b/(c+T))e e * pc
benzena 4924.22 5.658375 2948.79 228.59 -3.3157 0.036308768 178.7924
toluena 4062.72 5.944251 3242.38 225.97 -4.00262 0.018267801 74.21696
orto-xilena 3654.21 5.922088 3412.02 214.47 -4.92798 0.007241136 26.46063
asumsi suhu rerata (T)= 100 celcius

2 3 4 5
0.5 0.4 0.35 0.3432
0.5987 0.3497 0.2535 0.2418
0.4745 0.4382 0.4178 0.4149
1.5732 1.1879 1.0213 1.000
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