PRESIDENCY GROUP OF SCHOOLS Bangak langatore TCRSE SCHOOLS} ALP VEARLY EXAMINATON. SEPTEMBER 2019 CHEMISTRY Grade: Xt Maw: Marka: 70 sve wutet Cod ns de ss") Vis ow cd | umbers # to 10 are one mark Assertion and Reasoning / ‘dwestions. Choose the correct answer out of the following ehotees =” Question numbers 11 to 20 are also one marker questions. They are to be answered in one word or in one sentence. Question numbers 21 to 27 are two marker questions. They are to be answered in 30 words cach. | + Question numbers28 to 34 are three marker questions. These are to be answered in aboutS0words each, * Question numbers 35t0 37 are S marker questions with internal choice. ‘The empirical formula and molecular mass of a compound are CH;O and180 g respectively. What 1 1 will be the molecular formula of the compound? @ Gyo; (i) CHO (iil) CoHi120 (iv) CoH 2. The first ionisation enthalpies of Na, Mg, Al and Si are in the order: @ —-NaAlMg> Al> (iil) NaMg>AlB>C>D oe (i) B>C>D>A i) D>C>B>A (x) C>B>DSA et In question numbers 8 to 10 a statement of assertion followed by a statement of reason is given. of ‘Choose the correct answer out of the following choices. (Both assertion and reason are wrong. ii) Both assertion and reason are correct statements but reason is not correct explanation of assertion. (iii) Assertion is correct statement but reason is wrong statement. (iv) Both assertion and reason are correct statements and reason is correct explanation of lyfiet assertion. + (v) _ Assertion is wrong statement but reason is correct statement. ad 8. Assertion (A) : It is impossible to determine the exact position and exact momentum of an electron a 1 Reason (R) : The path of an electron in an atom is clearly defined. 9. Assertion (A) : Generally, ionisation enthalpy increases from left to right in a period. 1 Reason (R) : When successive electrons are added to the orbitals in the ‘same principal quantum level, the shielding effect of inner core of electrons does not increase very much to compensate for the increased attraction of the electron to the nucleus. 10. Assertion (A) : Nitration of benzene with nitric acid requires the use of concentrated sulphuric acid. Reason (R) : The mixture of concentrated sulphuric acid and concentrated nitric acid produces the 1 simultaneously. ¢ electrophile, NO2*. 11. If 10 volumes of dihydrogen react with 5 volumes of dioxygen gas, how many volumes of water will be produced? 1 12. Which of the following orbital 1 Ip, 2s, 2p and 3f. 13, What would be the IUPAC name and symbol for the element with atomic number 120? 1 14. Although C-O bond is polar, CO; is a non polar molecule. Why? 1 1 1 1 1 Is are possible? 15. What is the oxidation number of iodine in Kl, rationalise your result. 16. Why does the solubility of alkaline earth metal hydroxides in water increases down the group? 17. How will you convert ethyne to benzene? 18. Predict the shape of AsFs using VSEPR model. 19. Given the standard electrode potentials, K‘/K =~2.93V, Ag'/Ag = 0,80V, Hg”/Hg = 0.79V Mg*/Mg =-2.37 V, Cr"/Cr=—0.74V _ Arrange these metals in their increasing order of reducing power. 20. Why are alkali metals not found in nature? 21. Consider the following species : N* , O*, F”, Na”, Mg** and AP* () What is common in them? (i) Arrange them in the order of increasing ionie radii. Piz? 04 Poe cu:a Give reason for the following: (a) All carbon to oxygen bonds in CO; are equivalent, (b) Be molecule does not exist. (©) PbCl is more covalent than PbCh. oR level diagram for No- Compare the relative stability of the Draw molecular orbital energy 5 following species and indicate their magnetic properties Nz, Na‘, Nx and Nz List the quantum numbers of electrons for 5d. What is the wavelength of light emitted when the electron in a hydrogen atom undergoes transition from an energy level with n = 4 to an energy level n= 2? OR ‘Show that the circumference of bohr orbit for the hydrogen atom is an integral multiple of the de Broglie wavelength associated with the electron revolving around the orbit. A 100 watt bulb emits monochromatic yellow light of wavelength 400 nm. Calculate the number of photons emitted per second by bulb. Draw the shape of p-orbitals. 5 Draw the resonance structures of phenol. Define the term electromeric effects. Explain the givert orders of acidity of carboxylic acids ‘Cls;CCOOH > Cl,CHCOOH > CICH,COOH. Write IUPAC for the following: CH3-~CHj-C=C-CH=CH2. OR ‘Arrange the following in increasing order of stability and give reason for the same: (CHs)3C’, CH”, (CHs)CH’ and CHs-CHp" Ethylamine is more basic than aniline. Justify What are nucleophiles? Pick out the nucleophiles and electrophiles from the following: CN’, SOs, BF3, NO2*