\._ KENDRIYA VIDYALAYA SANGATHAN, BHUBANESWAR REGION 4) HALF YEARLY EXAMINATION 2019-2020 e class: x1 SUB: CHEMISTRY TIME: 3 HRS MM. MARKS: 70 (2) All question are compulsory (b) Section A: @. No. 2 to 20 are very short answer questions (objective type) and carry 1 mark. {€) Section 8 : Q. No.23 to 27 are short answer questions and carry 2 marks each. (@) Section C: Q. No.28 to 34 are long answer questions and carry 3 marks each. (2) Section d : Q. No.35 to 37 are also long answer questions and carry 5 marks each. (1) There is no overall choice. However an internal choice has been provided in two questions of two marks, ‘two questions of three marks and all the three questions of five marks weightage. You have to attempt only one of the choices In such questions. (g) Use log tables if necessary. Use of calculators is not allowed. SECTION ee Read the given information and answer the questions 1 to 5 that follows: Nitrogen atom can assume sp*,sp* as well as sp-hybrid state in different species. These hybrid states in fact represents different energy states of the atom at the time of bonding. When nitrogen atom is directly linked to H-atom it can also form H-bonds. Nand P atoms both have same number of outer shell electrons, yet phosphorous dees not form a diatomic molecule like Nz. Also phosphorous shows pentavelency but nitrogen does not. Answer the following questions on the basis of above information:- 1. Inwhich of the following molecule N-atom adopts sp-hybrid state. (a) NH3 (b) H2N-NH (c) HCN (d) N20, 2. What is the hybrid state of Nitrogen in Nz molecule? (a) sp? (b) sp? {c)sp (d) sp'd 3. Which of the following molecule does not exist? (a) NFS (b)NEs (c) PFs (4) Noe In the period table electronegativity increases from left to right in a period and decreases from top to bottom in a group. The non-metallic character of an element is directly related to the electronegativity which the metallic character is inversely related to it. 4. The least metallic element of group-13 is; (a) Aluminium {b) Boron {c) Gallium (d) Indium 5. The electronegativity increase with; {a) Decrease with nuclear charge {c) Increase in atomic mass along the group {b) Increase in atomic size {d) Increase in atomic numberLin the blanks: 6 The most electropositive ot wont positive element In fine period t6 where as the most electronesative element Is snnbioniani a 2. Cahas a smaller fonie radius than K° because it has 8. The temperpture above which gas eannot be liquefied 9 Units of VistdElty of liquid ts —— ~ 10. For real gases the value o! Questions 13.to 3: ultiple cholee qu sstions: 11. A thermodynamic state function Is a quantity; o Cen to determine the heat energy _(c) Used to determine pressure volume work . ) Whose value Is Independent of path __(d) whose value depends on temperature only . The enthalpies of all elements in their standard states are; (a) Unity {b) Zero (c) Less than zero (d) Different for each element 13. A solution with pH=2 Is more acidic than one with a pH=6 by a factor of; {a} 4000 (b)2 (e) 10000 (ayaa 14. The solubility of Fe(OH)sis “x’mol L. Its Ksp would be; (a) 9x° (b) 3x* (co) 27%° (a) 9x" 15, The number of sub-shells in the fifth energy level is; (a) 20 (b)15 {10 (as Question 16 to 20 (A) Both assertion and reason are correct statements, and reason is the correct explanation of the assertion. (8) Both assertion and reason are correct statements, but reason is not the correct explanation of the assertion. (c) Assertion is correct, (D) Assertion is wrong, but reason is 16, Assertion (A): CO2 molecule is non-polar in nature. Reason (R): The molecule CO; does not have any polar bond. 17, Assertion (A): Glycol is more viscous than C2H:0H. Reason (R): H-bonding does not occur in ethanol. 18, Assertion (A): The two electrons present in the fir: but reason is wrong statement. correct statement. st energy level cannot have same value of spin quantum number. . Reason (R); There is only one orbital in the first energy level. 29. Assertion (A): Both MH and AU of a reaction very with temperature, Reason (R}: BH and AU of the reaction are always different but definite quantities. 20, Assertion (A): For a reaction at equilibrium, MH is equal to TAS. Reason (R): At equilibrium free energy change is equal to zero. 2|Pager SECTION ~ 8 21. The density ae 'V of 3M solution of NaCl Is 4.25@ml.", Calculate molality of the solution. and explain Law of multiple proportions. 23, Answer the following:- {a} Draw boundary surface diagram of the 3d2” - orbital. {b) Write the electronic configuration of 2n"ion. 24, The ti increasing order of reactivity among group-1 elements is Li< Na Cl> Br > 1, Explain 25, Find the formal charge of all oxygen atoms in ozone molecule. OR Although both CO2 and H,0 are trlatomic molecules, the shape of HO molecule is bent which that of CO; is linear. Explain this on the basis of dipole moment. 26. Aballoon is filled with hydrogen at room temperature. It will burst if pressure exceeds 0.2bar. if at 1 bar pressure the gas occupies 2.27L volume, up to what volume can the balloon be expanded? oR Ona ship sailing in pacific ocean where temperature is 23.4°C, a balloon is filled with 21 air. What will be the Volume of the balloon when the ship reaches Indian ocean, When temperature is 26.1°C? 27. Answer the following: (a) Neither ‘q’ nor ‘w’ are state function but q#w isa state function. Why? (b) When is as =“? OR {a) Write is the relationship between standard free energy and equilibrium constant (K)? (b) Why do all living systems need to be open system? 28. (a) Define limiting reagent. Ina reaction A+ By---—--> AB. ; Identify the limiting reactant, if any, in the following reaction mixture, (i) 300. atoms of A +200 Molecule of B (b)What will be the mass of one C-12 atom in gram? 29, (a)State and explain Pauli Exclusion Principle. (b)What is the all possible quantum number of 19" electron of potassium atom? OR {ii) 2 mole of A +3 Mole of Bz {a)State and explain Hund’s Rule. (b)What is the energy associated with the second orbit of He" injoule, 30. (aWhy, 2d orbital is not possible? {b)What is the significance of the sign wr? {e) How many electron can be filed in all the orbitals with n +1= 5?31 (a) State Mendeleev’s periodic lw. [b)Would you expect the second electron gan enthalpy of oxygen as positive, more negati ij "e88 Negative than the fist? justify your anwer. or {a)state Modern Period Law, (6) On the basis of quantum numbers, justly thatthe sath period of the perodc table shouls have 32 elements, 32. For a reaction; 2A 4 +B jy > 2D) ; AU= -10.5kd and 05% = -44,1)K" Caleulate BH for the reaction and predict whether the reaction ls spontaneous or not at temperature 298K. (Given R = 8.314) K? Mol’) 33. Answer the following: (2}Drop of liquid assumes spherical shape why? (bJOut of CO, and NH, gases, which is expected to show more deviation from the ideal gas behaviour and why? {6)Under what conditions do real gases show maximum deviation from ideal gas behaviour? oR to their critical temperature and why? (c)Define standard boiling point of aliquid, 34. Answer the following; (2)The Pk, of acetic acid and Pk; of ammonium hydrochloride are 4,76 and 4,75 respectively, Calculate the pH of ammonium acetate solution, (6) What is common ion effect Explain with the help of suitable example. 35. (a) Derive Ideal Gas equation. (b) At 25° and 760mm of Hg pressure a gas occupies 600 mL volume. What will be its pressure at a height where temperature is 10°C and volume of the gas is 640 mL. OR {a) State and explain Dalton’s Law of partial pressure (6) Aneon-dioxygen mixture contains 70.6g dioxgen and 167.5g neon. If the pressure of the ‘mixture of gases in the cylinder is 25 bar. What is the partial pressure of dioxygen and neon in this mixture? 36. (a) A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume of the container is suddenly increased; (i) What is the initial effect of the ‘Vapour pressure? (ii)What happens when equilibrium is restored finally and what will be the final vapour pressure? [Page' _,yessel at 1000K contains CO; under ut Some omer On Finion of graphite. Calculate the valves im oe sik [cioheunuamecidacen f of Ky otal pressure of equilibrium mixture is 0.8atm: oR {(a)State Henry's Law. (b) What is the unit of K; for the given reversible reaction. / 2Mig) + 3g) © Xe # 2V i) pressure is 500mm of Hg & total pressure (JABziq) dissociates as: AB2(g)€> ABig) + Big. if the ini at the equilibrium is 700mm of Hg, Calculate K, for the reaction. 37. Answer the following; (a) Write the Lewis dot structure of CO Molecule. (b)Describe the hybridisation in case of PCls. Why are the axial bonds longer as compared to equatorial bonds. (cJWhat is meant by the term bond order? Calculate the bond order of Na, Oy and Oz. OR {a)Arrange the bonds in order of increasing ionic character in the molecule LiF, K20, Nz and CIF3. (b)Draw diagrams showing the formation of a double bond and a triple bond between carbon atoms in CHa and C,H, molecule. (c) Describe the change in hybridisation (if any) of the Al-atom in the following reaction. AlCl + Cl ------> AlCl,