Tiếp Cận 23 Phương Pháp Giải Nhanh Hiện Đại Hóa Học - Trần Văn Thanh PDF

TRAN VAN THANH Tiép can 23 PHUONG PHAP _ ©) GIAINHANH HIEN BAI HOA HOC + Gap nhat 23 phuong phap méi nhat giai nhanh héa hoc + Gidip hoc sinh luyén thi THPT Quéc Gia 6n tap nhanh mon héa hoc + Gidp Thay C6 cap nhat phuiang phap mdi nhat dé ting dung trong giang day NHA XUAT BAN DAI HOC QUOC GIA HA NOLTU HOC DANH THUC TIEM NANG TRONG BAN Chio céc em hoc sinh than mén, ‘Megabook ra di nhting bé séch cé tinh ty hoc, tui én tap cao, nhim myc dich gidp céc em nang cao kha nang ty hoc va dic biét phat trign tu duy ciia minh vé mon hoc d6. ‘Megabook hiéu duge viéc phat trién tu duy, trf tué con ngudii dé tgo nén su thinh cong nhut Bill Gates, Steve Job hay Mark Zuckerberg... la nh& 80% dua vao viéc ty hoc, tu nghién cttu én say mé chit khOng phai Ia ng6i trén ghé nha trudng, nghe gido hun. Viéc ty hoc khéng han théng qua séch vd, ma théng qua su quan sét cudc sng xung quanh, qua internet, hay don gidn la hoc héi kinh nghiém cia ngudi di truée. ‘Vigc tu hoc sé gittp céc em phat huy tiém nang ciia ban than, nhén théy nhiing kha nang, so ‘trung cia chinh minh cdn dang an gidu dau dé trong tiém thite ma céc em chua nhgn ra. Vigc ty hoc gitip cdc em ting kha nang tu duy, xit ly céc van dé nhanh nhay, thich nghi va dép ‘ing t6t hon véi su thay déi cita méi trudng va x8 hdi. ‘Vigc ty hoc xay dung bin nang sinh tn, phan xa tt hon cho méi con ngudi. Sinh ra 6 trén d0i méi dita tré da biét ty hoc héi nhu vie quan sét, nhin moi vat xung quanh, nghe nhiéu va réi biét néi. Vige ty hoc that ra rat ty nhién, dén trudng la mét phuiong phap gidp ich thich sv ty hoc. Va thay c6 chi c6 thé hudng dan va tao cam hting chit khong thé day chiing ta moi thi, ‘Tom hai viée tu hoc sé gitp mdi ngudi dot phé trong su nghiép va cudc sing. Mot ky sut biét tuthgc sé dot phd cho nhiing c6ng trinh vi dai, mot bac sf say mé nghién citu sé dot phé tré thanh bac sf ti nang citu chia bao nhiéu ngudi, mot gido vién tu nang cao chuyén mon méi ngdy sé bign nhiing gié hoc nhim chan thinh dy chm hiing va thi vi, Boi vay viéc ty hoc sé gitip bat ky ai than cong hon va henh phiic hon trong cudc séng. Biét ty hoc => Nang cao kha nang tu duy, xit ly van dé nhanh Biét ty hoc => Tang kha ning thfch nghi, phan xa nhanh véi moi trueng Biét ty hoc => Tao ra nhiing thién tai gidp dat nude va nhan loai Biét ty hoc => Giip mdi ngudi thanh cong trong cudc s6ng, d6t pha trong sui nghiép Biét ty hoc => Tyo xa h6i voi nhiing cong dan wu ta.arn Danh cho nhiing ai muén thanh cong RCMB racer rence MUC TIEU LA KIM CHi NAM DAN DUONG CHUNG TA BI Khdi d4u cho méi ching duéng cén c6 dong luc dé bude di, dé c6 dong hic bude di thi myc tiéu chinh Ia ngdi né dé thiic day suf chinh phyc day thi vi. Céc em than mén, céc em da ty héi xem minh da cé “ngdi né” ndo cho nim hoc méi chuta? Cho vigc hoc Héa cting nhu chinh phuc cuén sach chuyén dé Héa nay chtia? Va xa hon 18 chang dudng cho cuge séng 5 nam téi nifa chula? Cho dit cé ho§c chuta cé trong tim tri mot myc tiéu thi chi can céc em viét ra, viét ra nhiing muc tiéu cia ban than thi né sé trd nén r6 rang hon rat nhiéu. BGi vi, “Sy rd rang tao nén site manht” Céc em chi dén duge DICH mét khi cdc em biét minh dang muén di dén dau, tré thinh ai, dat dugc diéu gi sau 1 nim, 2 nim, 5 nam nia? Vay nén hay danh 30 phiit dé hinh dung, tuéng tugng vé cai DICH dé réi viet ra em nhé,Ey) Prvonc pHAr cial cHuNG: Ciéch giai chung cia phuong phap 46 thi gém 4 bude sau © Xéc dinh ding eta d6 thi. : © Xéc dinh toa dé cdc diém quan trong [thuding la 3 diém gém: xuat phat, cue dai va cue tiéu] © Xéc dinh tile trong 46 thi (til@ trong dé thi chinh la tiIé trong phan ttng). © Tit dé thi da cho vA gia thiét dé tra ldi cdc yeu cu cha bai todn, cr * XO, PHAN UNG VOI DUNG DICH M(OH), IE Thiét lap hinh dang cdia a6 thi + Khisue CO, vao dung dich chita a mol Ca(OH), thi déu tién x4y ra phan ting CO, + Ca(OH), + Caco, +H,0 Suy raz + Lugng két tia ting dan * S6 mol két tia ludn bing s6 mol CO, * $6 mol két tia max =a (mol) = d6 thi cia phan ting trén li: 0 a + Khi ligng CO, bat dau du thi long két tia tan xa theo phan ting: CaCO, + CO, + H,O > Ca(HCO,),ecg Suy ra: « Lugng két tia giam dén én 0 (mol) D6 thi di xudng mét céch A6i xing Phuong phap giai: = Dang cita d6 thi: Hinh chit V nguigc déi xting = Toa d6 cdc diém quan trong + Digm xudt phat: (0,0) + Dim cuc dai (két tia cuc dai): (a, a)[a la s6 mol cita Ca(OH),] => két tia cue dai la a mol. + Diém cic tigu: (0, 2a) = Tig trong 46 thi: 1:1. Dil eai tap sp dung Suc tit tiv dén du CO, vio dung dich Ca(OH),, Két qua thi nghiém dugc biéu dién trén 46 thi nhu hinh bén. Gid tri chia ava b la A.02va04. B.0.2va0,. €.0,2.va03. D.03 va 0,4, 1 Huéng dan: + Tu tilé cia d6 thi bai toan = a = 0,2 mol. + Tuong ty ta cing 6 b= 2a = 0,4 mol Dap an A (Trich Bé Thi Thit THPT Tri Ditc 2016) Suc tit tit dén du CO, vao mot céc dung dung dich Ca(OH),. Két qua thi nghigém dugc biéu dién trén d6 thi nhu hinh bén. Khi higng CO, da suc vio dung dich 1a 0,85 mol thi lugng. két ta da xudt hign la m gam. Gid tri cia m la “Ty \ aa A.40 gam. B.55 gam. 4 C.45 gam. D.35 gam. Resco, 0 03m Huéng dan: Dita vao dé thi ta c6: Neo, = 0,3 8 = Rep, = Moco, =03 Resco, = 0.3 Neo, = 1 : = gow, = 0,65m01 oo. =e sma os a, =0,85=9 {7% x+y=0,65 or” Meyquco,, = Ymol [x +2y= 0,85 Dap nC (Trich Dé Thi Thit Nam Phit Cit - 2016) Héa tan hoan todn 11,2 gam CaO va H,O thu duoc dung dich Y. Suc khi CO, vio dung dich Y, qua qué trinh Khao sat ngudi ta lip dé thi cia phan ding nhu sau ! Gia tri cia x &: : A,0,025 B.0,050 C..0,020 0,040 x | TYSx! [mol CO. Hung dan: No, rw =89 eae — ES 58x =0,2 > x = 0,025mol Ca(HCO,), :7x CO, PHAN UNG VOI DUNG DICH GOM NaOH; Ca(OH), MB Thiét lap dang cia a6 thi +Khisuc tit tit CO, vao dung dich chifa x mol NaOH va y mol Ca(OH), thi xay ra phan ting: CO, + 20H” —=> CO¥ +H,0 (1) CO} + CO, +H,0 > 2HCO; (2) Ca* + COP — Caco, L (3) + Tathy: S6mol OH” = (x + 2y) = CO} max = (0,5x + y)0 ¥ yhOSK ye x29, + Mit khdc: s6 mol Ca®* = y (mol) = 86 mol CaCO, (max) = y (mol) Suy ra: $6 mol két tia max = y (mol). D6 thi cia phan ding trén I: Phuong phap giai ~ Dang cita dé thi: Hinh thang can * Toa dé céc diém quan trong + Digm xudt phat: (0,0) + Diém cue dai(két tita cuc dai): (Ca ..)[a 18.56 mol cita Ca(OH),] => keét tia cue dai la a mol + Diém cic tiéu: (0, n"OH-) = Tile trong 46 thi: 1:1. Hil 8aitap sp dung [XEEED suc CO, vio dung dich hén hop g6m Ca(OH), va KOH ta quan sét hién tugng theo dé thi hinh bén (sé ligu tinh. theo don vi mol). Gia tri cha x la A.0,12 mol. B.0,11 mol. C.0,13 mol. D.0,10 mol. Lo |m Huéng din: Tide thi ta cé {exon = 0115mol > K*:0,3 X= Megoo, = 4Ca™ :0,15—x —*°2 50,34 0,3-2x = 0,5-x => x= 0,1mol HCO; :0,5-x Ne cop, = 9515mol Mog :0,3m0l Dép én D Deo, = ¥ x=n, Ghinhé: Mego, =¥=9} or Noo, = YF XLY = Deacow, (METED (Trich Dé Thi Thi THPT Hong Linh 2016) Khi suc tii ti dén dui CO, vao dung dich hén , vao dung hgp gém a mol NaOH va b mol Ca(OH), két qua thi nghiém duige biéu din trén d6 thi sau Newco, 05 Tila: bla i A.4s5. B.4:3. C54, Dz2:3. lm Huéng dan: Tacd fn = Neco, =0,5 i. 1,y =8+2b=1,4=9a=0,4.mol Dap an A (Trich Dé Thii THPT Déng D4u 2016) Dung dich A chita a mol Ba(OH),. Thém m gam NaOH vio A sau dé suc CO, du vio ta thay lugng két tia bign di theo dé thi (hinh bén). Gia tri cia (atm) 1: A205 B. 206 C204 D.20,8rad 1 Huéng dan: =b=0,5 ‘ioe =a+m=20,4g Noy =0,54+2a=1,3 9.4 =0,4 Dap anc OH~ PHAN UNG VOI DUNG DICH AI” HE Thiétlap dang cia a6 thi Cho tit tit dung dich chia NaOH vao dung dich chita a mol AICI, ta ¢6: + Phan ting xay ra: AT + 30H” - Al(OH), L AI(OH), + OH” > AIO; +H,0 + Dé thi biéu dién hai phan ting trén nhu sau: s6 mol Al(OH), mol OH o@ BGa) — C(4a) +Taludn cé: BO=3 yy BCL1 yy pMoa 1 BM I [il Phuong phap gidi: = Dang cita d6 thi: Tam gidc khéng can = Toa dé céc dig quan trong + Diém xudt phat: (0,0) + Digm cyc dai (két tita cuc dai): (a, 3a)[a 18 s6 mol cia AI] = két tita cute dai la mol, + Diém atic tiéu: (0, 4a) = Tile trong 46 thi: (1:3) va (1:1). Hl bai tap 4p dung (A_2014): Khi nhé ti tii dén du dung dich NaOH vao dung dich hén hop g6m a mol HCI va b mol AICL,, két qua th nghiém duige biéu dign trén 46 thj sau: al36 mol AU(OH), Tiea:bla A.4:3, B21, Gil D.2:3. ™@ Huéng dan: a=0,8 mol Khi mol n,,, Na’ :2,8mol CY :0,84+3b —“452,8= AlO; :b-0,4 ,8 dung dich thu duge sau phan ting: ,8+3b+b—0,4 => b= 0,6mol => = = 3 ’ 0.6 Dap an A Khi no tit tit dén dit dung dich NaOH vao dung dich AICL,, két qua thi nghiém duigc biéu din trén d6 thj sau (s6 ligu tinh theo don vi mol). Tylexyle A B. C4 D.4:5 @ Hung dan: Tui dé thi ta cb khi mol NaOH bang x thi két tha cuc dai la 2 Day, =8=9 x= 3a Khi mol NaOH bing y thi két tia cyfc dai 8 0,5a dung dich thu duge sau phan ‘ing: Naty = os = x_3a_6 Bycony 1058—A] CF 3a Sy =3 Sa = OFT :0,5a Dap an A Dung dich X chtia a mol AICI, va 2a mol HCL Sé mol Al(OH), Rot ti tt dung dich NaOH vito dung dich X ta c6 46 thj sau: Gid tri coax la 86 mol NaOH A.0,624 B. 0,748 C.0,756 D.0,684Mega book Huéng dan: Khi mol NaOH bang x mol két tia la 0,8a .mol dung dich thu duigc sau phan ting: Na’ :x mol AP*:0,2a mol—®24-5 x +0,6a = Sa => x-4,4a=0 cr :5a Khi mol NaOH bang 0,918 mol két tia Ia 0,6a mol dung dich thu duige san phan ting: Na* 0,918 AIO; :0,4a mol —*2" 0,918 =5,4a > a=0,17 mol Cr :5a .748 mol Dap an B (Trich Dé Thi Tht THPT Luong Thé Vinh 4,01) Quang Binh 2016) Cho tit tit dén dut dung dich NaOH 0,1M vio 300 ml dung dich hn hop gém H,SO, a molfit va Al,(SO,), b mol/it. B6 thi duéi x= day mo ta su phy thudc ctia s6 mol két tha Al(OH), 2a ae Moy vio s6 mol NaOH da ding. Ti s6 a/b gin v6i gid tr) nao sau day A.1,7 B23 C27 D333 Hung din: H,SO, :0,3a i (80,), :0,3b Trudng hop Myo =2,4b dung dich thu duigc sau phan ting 'Na* :2,4 Al(OH), : y.mol => 4 SOP : 0,3 +.0,96—"*-s 2, 4b +1, 8b ~3y = 0,6a+1,8b AP*:0,6b-y 2,4b—0,6a = 3y = 0,8b-0,2a=y Truding hop Mya =1.4a dung dich thu duige sau phan ting (Nat :1,4a Al(OH), : ymol => }SO7 : 0,3a+0,90 > 1, 4a = 0, 6a +1,8b+0,6b-y AIO; :0,60~y y =2,4b—0,8a = 0,8b-0,2a > 1,66 =0,6a => Dap an(Chayén Lao Cai 2016) Khi nhé tit tit dén dit dung dich NaOH vio dung dich hén hop .g6m a mol H,SO, va b mol Al(SO,),,két qua thi nghiém duige biéu din trén 46 thi sav: s6 mol AKOH), 6 mol NaOH Thea bla: A.8:1 B21 Gul D.4:5 & Hudéng dan: H,SO,:a es 2b Tut dé thj ta co: Khi mol nyo Na’ :0,9 SOF" :0,14+3b #90, AIO; :2b-0,1 Dap anC =0,230=0,1 0,9 dung dich thu duige sau phan sing: 2+ 6b+2d-0,1= 8=0,8—9 b=0,1=9 >= (REED (rich Dé Thi Thi THPT Quynh Luu 1 -2016) Panag, Nhé tir tir dung dich dén du Ba(OH), 0,2M vao 100 7 ml dung dich A chtia Al,(SO,), xM. Méi quan hé gitia 699 |. Ahdi ligng két tua va s6 mol OH’ duigc biéu dién bang 6 thi sau: Néu cho 100ml dung dich hén hgp Ba(OH), 0,2M va NaOH 0,3M vio 100ml dung dich A thi Khéi higng két tha thu dugc li bao nhiéu? A.5,44.gam B. 4,66 gam C.5,70 gam D.6,22 gam i Hudng dan: Tit dé thj ta c6: BaSO, : 0,03 mol = Noy = 0,3x = 0,03 x = 0,1 M Ba?*: 0,02 Al: 0,02 BaSO,|: 0,02 =A12(804)3 : 0,01 mol => +4Na":0,03 => mg >m=5,44g SO}: 0,03 | or. 9.07 AN(OH), |: 0,01 Dap én Asores (Chuyén KHTN Lan 5 -2016) Nho V lit dung dich NaOH 1M vao dung dich chtta H,SO, IM va AL(6O,), x M. D6 thi mé ta su phu thudc cia Itigng két tia vio thé tich dung dich NaOH duge biéu dién nhu sau: Gi tri cha X tuong ting la: Sas 036 O58 vi A.0,450 B. 0,350 €.0,375 D.0,425, mt Huéng dan: H,SO, :a { Al, (SO,), :b Ti d6 thj suy ra 2a = 0,24=> a = 0,12 mol = b=0,12.x Na* :0,36 Rysoxt = 0,36 mol => Nioyp, = =F {SOF 20,1243 AP*:2b-¢ 40,36 + 6b—30 = 0,24 + 6b => c= 0,04 mol Na* :0,56 Ryjoa = 0,56 Mol = Nyyow, = C=F SOF :0,12+36 AIO; :2b-c 430,56 = 0,24 +-6b+ 2b-0= 8b—c= 0,32 => b= 0,045 => x = 0,375 Dap nC (Teich Dé Thi Thi THPT Ha Huy Tap Lan 2-2016) Nho ti ti dung dich Ba(OH), dén du vio dung dich hén hgp Na,SO, va AL,(SO,), ta c6 d6 thi biéu din su phu thudc khéi luong két tia theo s6 mol Ba(OH), nt sau Khbi rong kéttia (@) 69,9} 0 x 032 S$ mot BaOEa ‘Duta vio d6 thi hay xc dinh gié tri cia x 8 ‘A.0,28 (mol) B.03 (mol) €.0,2(mol) D.0,25 (mol) 1 Huéng dn: Na,S0,:2 eR BO, 943 =0,3= {a (s0,),:0 2+3b=0,3= Naso,Ba** :0,02 =0,32——»4 Na*:2a —““.52a+0,04= 2b = a-b=0,02 Mayor), NO; :2b ja-b=0,02 _ fa=0,09 Va+3b=0,3> Két tta dat cye dai ‘Truong hop két tia hét ion $02" :0,3.mol suy ra mol: BaSO, :0,3 => m=79,26 gam Al(OH), :0,12 Ba(OH), :0,3=9n,,, ‘Tridng hop két tia hét ion AP :0,18 mol = n,,,. =0,18.3=0,54= ny.coy, =0,27 mol BaSO, :0,27 =m. AN(OH), :0,18 ),6 => AK OH), :0,12 mol => { = m= 76,95 Chon x= 0,3 mol Dap an B (Dign Chau 5 Lén 1 -2016) Khi nhé tit tit dén du dung dich NaOH vao dung dich hén hgp X g6m x mol H,SO, vay mol AL,(SO,), két qua thi nghiém chigc biéu dign trén 46 thi sau. s6 mol AKO), ® 04 10 «14 6 mol NaOH ‘Néu cho dung dich chita 0,7 mol Ba(OH), vio dung dich X, phan ting hoan toan thu ditge m gam két tia. Gid tri m gain gid tri ndo mhat? AMS B.16,7 C.170 D. 151,45 @ Huéng dan: xmol H,SO, fs Al, (SO,), TW d6 thi ta cé: 2x =0,4 = x= 0,2 mol ‘Nat 21,4 => AIO; :2y—0,2 "91,4 = 2y-0,242x + 6y sO: = 8y=1,6-2x =1,2= y=0,15 mol Byuon = 14 Al(OH), :0,2ead —timimioH, , PBaSO, :0,65=3 m=151,45g H,SO, :0,2 Al, (SO, ), :0,15 Dip én D (XEQELD (Trich Dé thi THPT Tién Lang 2016)Cho m gam Al tan hoan toan vao dung dich chita y mol HCI thu duige dung dich Z chita 2 chat tan 6 cling néng 4 mol. Thém ti tit dung dich NaOH vao dung dich Z thi dé thi biéu dién Iuong két tia phu thudc vio lugng OH’ nhu sau: Axvow, o,175y | - 0 5,16 Gia tri cia m la A. 20,25, B.324. 26.1. D.27,0, Huéng dan: na: Na’ :5,16 ra 7 —hacisémel_ 41(OH), :0,175y mol +4 AIO; :0,075y Ale, crey Hho y= 4,8 > m=32,4g Dap an B ( DANG bp Ht PHAN UNG VOI DUNG DICH AlO2 MB Thigt lap dang cia d6 thi 4+ Cho tir titdung dich chia H” vio dung dich chita a mol AIO; ta cé phin ting xy ra: Ht +Al0; + H,0 — AI(OH), 1 26 mol AIOH), AI(OH), + 3H* > Al* + 3H,0 ay + Dé thi bigu dign hai phan ting trén nhu sau: 4) +Taludn c6: BO} yg BC _3 BM 1 BM 1 00) Baa) C(4a) va BM = a=nl max. 8 mol”Phuong phap gi = Dang cita dé thj: Tam gidc khong cin = Toa dé céc diém quan trong + Diém xudt phat: (0,0) + Dim ciic dai(két tita cute dai): (a, a)[a la s6 mol cia Al] => két tia cyte dai la a mol, + Diém cuc tiéu: (0, 4a) * Tile trong d6 thi: (1:1) va (1:3). Bai tgp vidu (Trich Dé Thi Thit THPT Chuyén Son Tay 2016) Khi nhé tit tit dén du dung dich HCl vao dung dich chifa x mol NaOH va y mol NaAlO, két qua thi nghiém duige biéu dign bang d6 thi bén. Xéc dinh tile x: y? s6 mol AKOH), 0 04 06 1,0 s6miol NaOH A.4:3, B.1:3. C.23 Dis. | Huéng dan: Nat :0,4+y NAOH:04 yous! sad] ap :y0,2- ™ 90,44y43y-0, NaAl0, :y mol [Cl :1 mol NaQH:0,4 x4 =y=035 uae NaAlO, :0,3mol y 3 Dép an A (XETED (rich Dé Thi Thi THPT Long Xuyén 2016) Khi nho ti tit dén du dd HCI vo dd hén hop gém x mol Ba(OH), va y mol Ba[Al(OH),}, (hoac Ba(AIO,),), két qua thi nghiém duge biéu dién trén d6 thj sau: ‘86 mol AKOH), a a oor 08 07 s6mol Hcl Gia tr cia x va yn hugt la A, 0,10 v8 0330. B, 0,10 va 015. €.0,05 va 0,15. D.005 va 0,15asd 1 Huéng dan: Ba(OH), :x mol { ator sta —#122_5 AI(OH), :0,2 mol Ba(AlO, ), :ymol => 2x =0,1=> x= 0,05 Ba* :0,05+y dd: 4 AI* ; 2y—0,2 —Y“30,1+2y+6y—0,6=0,7 = 8y=1,2 => y=0,15 mol Cr :0,7 Dap an D (Sé Gido Duc Va Dao Tao Bac Giang 2016) Cho tii tit dd HCI loang vao dd chita x mol NaOH va y mol NaAlO, (hay Na[AI(OH),]). Sut phy thudc cia s6 mol két tia thu duge vao sé mol HCl dugc bigu dign theo 4 th sau: Gis tri cay a AA B18 CLs D.1,7 @ Hudng dan: Na’ :LL+y qlee —Hosso y dd) AP y—1,1 51,1 +y+3y-3,3=3,8 NaAlO, :y mol [cr :3,8mol syeisa [MOH ° NaAl0, :1,5 mol Dap an (ZETED (rich Dé thi Dién Chau 2-2016) Cho tii tit dén du dung dich HC] loang vao dung dich 8 ig 8 chiia 0,1 mol NaOH va 0,1 mol NaAlO,. Méi quan he vé s6 mol gitta HCI cho vio va s6 mol kt tia, duige mé t& ding qua 46 thi no sau day? Dayoens Muyous 01 02 03 04 05 : 01 02 03 04 05 ie.Daxomns m Huéng dan: o 0,1 02 03 04 05 Maa 01 02 0,3 04 06 Khi cho tit tit dén dut dung dich HCI loang vio dung dich chtéa 0,1 mol NaOH va 0,1 mol NalO,, Truiéc tién HCl phan ting NaOH HC1+NaOH—>NaCl+H,0() 0,16e—0,1 ‘Néu mol HCl én hon Ién hon 0,1 mol H* +Al0; +H,O—— AK(OH), J (2) 0,1<0,1 9,1 3H* + Al(OH), —> Al” +3H,0 (2) 0,3-—0,1 Nh{n xét mol HCl én hon 0,1 thi mdi cé két tia loai A va D. ‘Mol HC! bing 0,2 két tia cut dai Mol HCL1én hon 0,5 két tia tan het. Dap an C (Trich Dé thithi/ THPT LongXuyénLén3-2016): avou) Cho tir tit dung dich H,S0, vao dung dich c6 chita déng thai b mol KAIO, va 2b mol KOH, két qua thi nghigm dugc m6 ta bing dé thj sau: Gid tri cha ala A. 0,325. B. 0,375. C.0,400. D.0,350. 1 Huéng d 2b=0,4 = b=0,2 mol =| H2S0.'# Al(OH), :0,15 Dép én B SOP sa 4K" :0,6 AL" :0,05 M4 = 0,375 molad OH" TAC DUNG VOI H' VA Zn Ml Phuong phap gidi + Cho ti tit dung dich chtta OH” vao dung dich chita a mol Zn” ta c6 phan ting xdy ra: Zn* +20H” — Zn(OH), + 56 mol Zn(OH), Zn(OH), + 20H” —»>ZnO7 +H,O + D6 thi biéu dién hai phan ting trén nhu sau: + Tutdng ty khi cho tiy ti” dung dich chtta OH” vao La bidanstial dung dich chtta x mol H* vaa mol Zn™ ta cé dé thi sau: ° 2a 4a s6 mol Zn(OH), 6 mol OH 0 x atx date + Cho tit tit dung dich chia H* vao dung dich chtta a mol ZnO} ta c6 phan ting xay ra: 20} +2H* — Zn(OH)2+ Zn(OH), + 2H* > Zn** + 2H,0 +Dé6 thjbiéudién hai phan ting trén nhutsau: + Tuong ty khi cho tit tlt dung dich chtta H” vao dung dich chifa x mol OH™ va a mol ZnO} ta c6 46 thj sau: $6 mol Z(H), $6 mol 6 mol Zn(OH), x Date datx + Dang cita dé thi: Tam gide cin + Toa dé cde diém quan trong + Diém xuit phat: (0,0) + Digm cue dai (két tia cui dai): (2a, a)[a la 86 mol cita Zn?*] => két ta cuc dai ld a mol.+ Diém cuic tiéu: (0, 4a) » THé trong dé thi: (2:1). Baitap Cho ti tit dung dich NaOH dén dut vao dung dich ZnSO, Két qua thi nghiém duigc biéu din 8 46 thi dui day. Gid tri ctaala A.0336 B.0,24. C.0,48. D. 0,28. $6 mol 2008), Hung dan: Tit d6 thita 6 Nat sa ZnSO, :0,12.mol = } ZnO} :0,12 = 2 =0,48.mol sox :0,12 Dap anC Cho tit ti! dung dich HC] dén dui vao dung dich Na,Zn0,, Két qua thi nghiém duge biéu didn & 6 thi dudi day. Gid tr ca xb 8 mol Z(OH), A.0,06. B.0,24. C.0,12 D. 0,08, @ Huéng dan: Nat :2x Na,ZnO, :x mol = {Zn*:x => x =0,06 mol CP :0,24 Dap an A Khinho ti tit dén du dung dich NaOH vao dung dich gm a mol HCl va b mol ZnSO4. Két qua thi nghiém duge biéu dién trén so 46 sau 56 mol Zn(OH), Tika:bla AL1:2. B.3:2. 36 mol OH C233, D.3:4. o 06 10 3.0 1 Huong dan: jamolHCl yoy oh b mol ZnSO, Tit dé thi ta cé: a = 0,4 molNa’ :1 mol ny, =1 wa Zn rb-x Zn(OH), :x cr :0,4 SOF: —M9142b—2x =0,44+2b > x =0,3 mol Na" :3 mol (ae _4, ZnO> :b-x Zn(OH), :x cr :0,4 SO} :b 93 = 2b—-0,6+.0,4+ 2b = 4b=4,2 > b= Nhé tit tit dén du KOH vao dung dich hén hgp g6m a mol HCI va x mol ZnSO, ta quan sat hign tugng theo 46 thi hinh bén (s6 ligu tinh theo don vi mol). Gid tri cia x (mol) li: A.04. B.06. C07. D.0,65. Hung dan: ‘a mol HCI x mol ZnSO, ‘TW d6 thi ta c6: a = 0,25 mol ‘Na :0,45 mol ny 0,45 yy |Znt:x-y Zn(OF), :y cr :0,25 108 —M,0,45+2x-2y = 0,25+2x = y=0,1 mol SOF :x Na* :2,45 mol peels a 2007 :x- Ol 452 -0,240,25+2x 2n(OH), :0,1 Cr :0,25 SO? :x. = x=0,6 mol Dap in B (Chuyén Vinh lén 3-2015) Dd X chttax mol NaOH va ymol Na,Zn0, (hoc Na,[Zn(OH),]); dd Y chita z mol Ba(OH), va t mol Ba(ALO,), (hogc Ba[AI(OH),],) (trong dé x < 22). Tién hanh hai thi nghiém sau: ‘TNI: Nho tit tit dén dui dd HCI vao dd X. ‘TN2: Nho tit tii én dui dd HCI vao dd Y,oot 03 os s6mol HCL Gid tr chia y vat lin lugt 8 A. 0,075 va 0,10, B. 0,075 va 0,05. C.0,15 va 0,05. D.0,15 va 0,10 1 Huéng dan: i NaOH | [7 mol Ba(OH), ymol Na,Zn0;' "| t mol Ba(AlO,), “TNE: tit d6 thi ta 06 xmol NaOH X: > x=0,1 mol ymol Na,ZnO, wci:0,3mor [NE O142¥ 20,3 mol vet =} Zn :y-0,05—"*-40,14 2y +2y—0,1=0,3=> y = 0,075 mol Hennes mie y+ 2y y Cr :0,3 = TN2: Ba :2+t z mol Ba(OH : Y (08), = BCL O3 => 4 A103 :2t-0,05 tmol Ba(A10,), ~ [AUOH), 0,057] 9 M5 22+ 2t = 2t-0,05+0,3 = 2z = 0,25=9 z= 0,125 1 Ba (OH) HCI:0,5 a zmo : y ates an => {Al :2t-0,05 tmol Ba(Al0,), — [AI(OH); :0,05 ae E5224 2t+6t-0,15 = 0,5 > 22+81 = 0,65 = 1 = 0,05 mol Dap in B (ETE Nhs ti tir dén du KOH vao dung dich hdn hop g6m a mol HCl va x mol ZnSO, ta quan sét hign tugng theo 46 thi hinh bén (s6 ligu tinh theo don vi mol). Gid tri ctia x (mol) la: A004. B.06. c.0,7. D.0,65.eed 1 Huéng din: Ti d6 thi ta cd a=0,25 mol Na” 0,45 Dygos = 0.45 Zn :x— [ome Chios StH 2y=0.25 42x y=041 SOF =x, Na’ :2,45 pete i a tees =2x-0,240,25-+2x = x =0,6 SOF :x Dap dn B (Trich Dé Thi thii THPT Ham Thuan Bac 2016) Cho dd NaOH phan ting véi dung dich CrCl, 06 két qua nhu hinh vé 86 mol Cr(OH)s $6 mol OH" Gid tri cla x a; ALLS B.20 C18 D.16 1 Huéng dan: CrCl, :0,5 mol Hie ‘Nat :x lO : x a3 : 20, =0,34+15=x=1,8 mol (eens 02 dd: 4 CxO; 20,34 4x =0,341,5= x =1,8 mol or ss Dap in C (Trich Dé Thi Thit THPT Lé Xoay Lan 4-2016) Hén hop X gém Cu va ALO, cé ty 1 mol tuang ting la 4: 3. Cho m gam hén hgp X tac dung véi dung dich HCI du thu duge chat rin. Y va dung dich Z chita 2 chat tan c6 cing néng 46 mol. Rét til tit dung dich NaOH vio dung dich Z ta c6 dé thj sau:a 4,254 Cho chit ran ¥ téc dung véi dung dich HNO, du thu duige x mol khi NO, (sin phém khit duy ahit). Gié tri chaxla A042 B.0,48 €.0,36 D.0,40 mt Huéng dan: et ee ALO, :3b HCI: 6b Nat :4,25a =4, Bron = 4258, A105; :6b-a+0,09 AI(OH), :a—0,09 z Cr :24b th» 4,25a = 6b~a+0,09-+24b = 5,25a—30b=0,09 ite —30b=0,09 = {i =0,36 a-6b=0 ,06 Cu:4b—2% NO, : x mol“ 8b = x > x = 0,48 mol Dép an B ‘Cho tit tit dung dich chia a mol Ba(OH), vao dung dich chifa b mol ZnSO, D6 thi biéu ién s6 mol két tita theo gid tri cita a nhui sau: Gid tr} cla bk: A.0,10. B.0,12. C.0,08. D.0,11. Izabees nL @ Hudéng dan: BaSO, :0,0625 = 1 (OB), 10,0605 *= 1250 Ba(OH), :0,0625 mol—22.2 { BaSO,:b =0,125 mol 2n (OR), :< * a Ba(OH), :0,175 | = b+e=0,125 mol Ba™ :0,175-b Zn0% :b-c ie ee eae 2b-c= 0,175 0,025 mol =90,175—b=b-c= 2b-c=0,175 =| Dip an A Cho dé thj biéu dién méi lién hé gitta lugng ion H’* va higng két tita Al(OH), trong phan ting ciia dung dich chita ion H* véi dung dich chtta ion AIO,” nhu sau: Tayo 0,25x 0,85x Dya vao dé thi, cho biét gid tri cla ala A. 0,25. B. 0,23. C. 0,35 D. 0,2. [cr :0,85x ny, =0,85% 4 |, ie 44) Al" :0,4-a—# 91,2304 0,4 =0,85x => 3a+0,85x =1,6 AIH), 22 gee a" :0, 1.25 [3a+0,85x=16 [a= => a=0,25x x Dip dn AX11 dung dich chia NaOH va 0,15 mol Ba(OH),. Suc tit tit CO, vio X, luigng két tia tgo thanh dugc m6 ta trong 46 thi duéi day: one oa eee $6 mol NaOH ban du la A.02 B04 C03 D015 m Huéng dan: 4 = Mgyoyy, = 0415 MOl;tyyog =2a—a =a = 0,15 mol Dap an D [EDD (trich DETHTHYSGDCAMau-2016)Nhotwtit én du dung dich NaOH vio dung dich X chia FeCl, va AICI, thu duoc dé thi sau, Gid tr} n gin Maen) shat v6i gid tri ndo sau dy? sf A. 84 gam B.81 gam. C.83 gam D. 82 gam. 1 Huéng dan: 273438 tow FeCl, : Fe 5 Ch t@ sonar, [PCO '8 97, 78x =88,47g AICI, :b AM(OH), :x Na” :2,7 dd: 4 Al* :b—x —M 5 2,74+3b—3x =3a+3b = 3a+3x =2,7 > a+x=0,9 Cr :3a+3b : Fe(OH), : { 278 won fm D8, 107a+78x =88,47 AIC, :b AI(OH),:x Na’ :3,1 dd:} AlO; :b-—x —“* 53,1 = b-x-+3a+3b > 3a + 4b—x =3,1 Cl :3a+3b 3a+4b-x=3,1 a =0,63 107a+78x =88,47. => }b=0,37 atx=0,9 x=0,27 FeCl, : Fe(OH), : { ©Cls:8 non 200 { (OH), * 1072+ T8y =80,67g AICI, : AIH); :¥ Dap an Bee Rott tit dung dich Ba(OH), 0,2M vao 150 ml dung dich AICI, 0,04M thay lugng két tia phy thudc vio s6 ml dung dich Ba(OH), theo dé thi dudi day. Gia tri cha a va b tuiang ding Id: ‘Vea(on), (ml) 0 a A.45 ml va60ml B.45mlva90ml =. 90 ml va.120ml_~—«dD«. 60 ml va. 90 ml © Huéng dan: Tit d6 thi suy ra 2ax0,2 = 0,006.3 = a x 0,2 = 0,009mol = a = 45ml 2b x0,2 = 0,006.4 => bx 0,2 012mol => a = 60ml Dap an A [XEEELD Cho tii tix dung dich HCl vao dung dich cé chita a mol NaHCO, va b mol Na,CO,, $6 mol ‘hf CO, thu duge phy thud vio s6 mol HCI duge biéu dign trén 46 thi sau: 86 mol COz ‘$6 mol HC! Tile cha ab la: ALB B.3:4 C73 D.43 Hudng dan: Tit d6 thi suy rab = 0,15 mol atb=0,35-0,15=0,2=>a=0,05 mol > 2= = b O15 3 Dap dn A Khi nbo tit tit dung dich NaOH dén du vao dd AICI, két qua thi nghiém duigc biéu dién theo d6 thi sau. 86 m0l M049? ‘Tinh gid tri cha x? A.0,82 B.0,80 €.0,78 D.0,84 1 Huéng din: alTu d6 thj tacé AICI, :0,24 mol Tyyou = 0,42 MO] => N giro, = 0514 mol Na* :xmol Dyson ea = ide 241 10; 0,1 5 x =0,1+0,72 = 0,82 mol {retest De ina aE Dap an A Chom gam Altécdunghoantoin véidung yy dich chia a mol HNO, Sau phan ting théy dung dich cé khéi lugng khéng thay déi va thu duge 6,272 lit (dtc) hn hop Khi Z gém NO va NO, ‘Ty Kh6i cita Z so véi metan la 135/56 Ngudi ta 6 tiv ti dung dich NaOH vio dung dich sau phan ting déng thdi dun néng nhe thy Ivong két tla bign thién theo dé thi hink hinh vé bén dudi (don vi mol): Gié tri cita a gén nhét voi: A.18 BLS C17 D.20 9, mt Huéng dan: NO:0,13 mol [ x0, 0,15 mol Al 225 1 NHNO, :0,0825 AL(NO,), 10.4 HNO, :b ‘NH,NO, :0,0825 ‘Na 21,5825 AI(NO,), :0,4 208 Al(OH), :0,3 —>4 AIO; :0,1 HNO, :b NO; :b+0,0825 — HA 41,5825 = 0,1+b+0,0825 > b=1,4 =a=1,4+0,04.3+0,0825.2+0,28= 1,965 mol Dap an D Khi nho tii tii dén du dung dich NaOH vao dung dich hén hop gém a mol HCl va b mol AICL, két qua thi nghiém duge biéu dign trén d6 thj sau 36 mol AKOH)s. 86 mol NaOHPe ee 0000000000000000000000000000000006 ‘1 Huéng dan: Nhin vio d6 thi ta thay: m,. =a=0,5(mol) Voi Maou =1,8—1,8=0,5+3b + (b-0,3)—9b=0,4 Dap in D ED Khisucti ti dén du CO, vio dung dich cé chita 0,1 mol NaOH, x mol KOH va y mol Ba(OH),, Két qua thi nghiém thu dugc biéu dién trén 46 thj sau: Gia tri cua x, y, z lan lugt la: A.0,6 ; 0,4-va 1.5 3-va 1,2 €.0,250,6 va 1,25 D.0,3 50,6 val4 1 Huéng dan: Tu dé thj suy ra: y=0,6moljn,,, =0,1+x+2y=1,6=9x=0,3 Nat :0,1 No, =Z gy __ JK*20,3 BaCO, :0,2 Ba :0,4 HCO; :z-0,2 HH 0,140,340,8=2-0,2=>2=14 Dap an D Suc khi CO, vao V lit dung dich hén hgp NaOH 0,2 M va Ba(OH), 0,1M. Dé thj bigu dién kh6i higng két tia theo s6 mol CO, nhu sau: Gia tri cha V 1a Meas A. 300 B. 250 C.400 D. 150 @ Hudng dan: (CO, :0,13 mol Na‘ :0,2V 0,03 0,13 Ney, 0.13 mol yy a at #5] Ba :0,1V-0,03 90,4 =0,16 = V=0,41= 400 ml ean 20,03 . i ni HCO; : 0,1 mol Dép én C Bo BAITAP REN LUYEN: (Trich Dé Thi thit THPT Luong Ngoc Quyén 2015) Khi nhé tit tir dén du dung dich ‘NaOH vao dung dich hén hgp g6m a mol H,SO, va bmol Al,(SO,), két qua thinghiém digbiéu dign trén dé thi sau: 86 mol A(OH)s 0.1 0 0,2 05 og Tilea: bla ABI B.2:1 CuL 36 mol NaOH D5 (Trich Dé Thi thii THPT Chiic Dong 2015) Khi suc tit tit dén dut CO, vao dung dich hén gp gém a mol NaOH va b mol Ca(OH),, két qua thi nghiém duge biéu dién trén 46 thi sau: Nexo, Tiga:b li: 1 ve AAS BLS:4 C25 (Trich Dé Thi Thid THPT Phi: Duc - 2016) Dign phan 400 ml dung dich gém NaCl, HCl va a3 CuSO, 0,02M voi dién cyc tro va man ngin xé6p. Citdng dé dong dign 11,93 A. Coi thé tich dung dich khong thay 4éi trong qué trinh dign phan. Chis6 pH 7 theo thdi gian duigc biéu dién bing d6 thi sau day. Gid ‘rj cha x trong hinh vé la 2 A. 1200 B. 3000 C. 3600 D. 1800 (Trich Dé Thi thi THPT Chuyén Bao Léc - 2015) Khi nhé tit tit dén du dung dich HCI ‘vao dung dich hén hgp g6m a mol Ba(OzH), va b mol NaAlO2, két qua thi nghiém duige biéu didn trén 46 thi s Tila: b Min higt 8 AQ B.2:7 C.4:7 D.2:5(Trich Dé Thi thiv THPT Bai Chay 2015) Nho tit tit €én dut KOH vio dung dich hén hgp gma mol HCI va x mol ZnSO, ta quan sét hign tugng theo d6 thi hinh bén (s6 ligu tinh theo don vi 025 045 25 Toye mol). Gia tri cia x (mol) li: A.04. B.0.6. C.0,7. D.0,65. Khi nhé ti tit dén dut dung dich HCl vao dung dich hén hop g6m a mol Ba(OH), vab mol Ba[ Al(OH) ], (hoc Ba(AIO,),), két qua thi nghiém dugc biéu dign trén dé thj sau: S60} AL(OH), oor 03 7 SOmol HCI Vay tila: bla AvL:2, B.2:1. 2:3, Dil:3, Khi nhé ti tit dén dut dung dich HCI vao dung dich hén hop gém x mol Ba(OH), va y ‘mol Ba[AI(OH),], (hoae Ba(AIO,),), két qua thi nghiém dude biéu dién trén dé thi sau: SO mol Al(OH), 0 o1 0,3 07 Sémol HCL Gia tri cla x va y lan higt la A.0,05 va 0,30. B.0,10 va 0,30. C.0,10va0,15, D.0,05 va 0,15. (RETED Khi nho ti tix dén du dung dich KOH vao dung dich hén hgp gm x mol HCl va y mol ZnCl, két qua cia thi nghiém dugc biéu dién trén 46 thj sau: 4 s6 mol Zn(0H), 2 l > 06 10 14 6 mol KOHTong (x+y +2) 1a A. 2,0. B11. C.0,9, D.08. Dung dich A chtia a mol ZnSO, dung dich B chtta b mol AICI,; dung dich C chtta c mol 8 dung ; dung NaOH. Tién hanh 2 thi nghiém sau: ‘Thi nghiém 1: Cho tit tit dung djch C vio dung dich As ‘Thi nghigm 2: Cho tit tit dung dich C vio dung dich B. Luigng két tia 6 2 thi nghigm bign 46i theo dé thi sau day: 9 x da 032 Thao ‘Téng khéi luong két tia 6 2 thi nghiém khi ding x mol NaOH gan nhat véi gid tri nio sau day? A.9,5, B85. C9. D8. [XETELD Neu tahoa tan hoan toan hon hop NaOH va Ba(OH), vao nuiéc du thu duige dung dich X. Suc khi CO, vio dung dich X. Két qua thi nghigm thu duge biéu dién trén 46 thj sau: ‘brat BrCOs Gia tri ctia x la: A325 B.25 oe B.30 D.2,75 o4a a da * ‘Suc CO, vao dung dich Ba(OH), ta quan sat hién tong theo dé thi hinh bén. Gié tri cita x la: A. 5,0 (mol) B, 3,6 (mol) C. 4,0 (mol) D. 4,4 (mol) 1 Hudng dan: 2a=0,2>a=0,1 Nat :0,9 AI(OH),:0,1 |“ 5480} :3b+0,1 }"* 50,9 = 6b +2b+0,2-0,1 NaOH :0,9 10; :2b-0,1 8b =0,8—>b=0,l>a:b=1:1 Dap an Cead b=0,5 a+2b=14>5a=0,4=a: Dép an A Khi ¢=0,pH =2=9[H* ]=0,01= HCI:0,004 mol t=x pH =13 > pOH =1=>[OH™]=0,1=,,, = 0,04 2NaCl+H,O—>2NaOH +Cl, +H, = ny, = 0,02 it_ 1,93t Qng, +2.ny, =0,06=— = , 004+ 2.ng, +2.ny, =0,' Baseso0. 3000 Dap in B 2a=0,8a=0,4 HCI:2,8m01 = AI(OH),:.2—>) cr :2,8 0,8+b+3b~3,6= 2,8 b=1,4=9a:b=2:7 Dap nB 2=0,25 mot [K+ 20,45 KOH:0,45 mol gg JV 0:25 | we 0,454.94 -2y=2x 40,25 Zn(OH), : ymol Zn :x-y SOF 3x > y=01 K* :2,45 : 1 :0,25 a KOH:2,45 mol _ a ,|CT 20, HAs 2,45 = 0,25+2x-0,242x Zn(OH), :0,1 mol ZnOF :x-0,1 SOP :x > x=0,6 Dap AnB0,1 mol => a = 0,05 Ba** :0,05+b, —Aoicr :0,7 H+ 0,1+2b+6b-0,6= 0,7 AP* :2b—0,2 HC1:0,7, AI(OH), :0,2 b=0,15 = a:b=1:3 ap an D 0,1= x =0,05 mol Ba” :0,05+y FHCI:0,7 ol] | bs oe a3 | 50,1429 46y--0,620,7 AI(OH), :0,2 iy ),1+2y + 6y—0,6 = 0, Cr :0,7 y=0,15 Dap an D (xe x =0,6mol contr adl K*:1 mol si mol a 2+ bide Zn sy n= (ena you JA 5142y-22=0,6+2y Cr :0,6+2y 2=0,2 K° :1,4 mol KOH:1,4 mol 2 a ite ZnO% : y~0,2>—“* 41,4 = 2y-0,4+ 0,64 2y Za(OH), :0,2 mol Cr :0,6+2y = y=0,3xtytz=h1 Dép dn B Toy. = 0,32= 4b = b =0,08 mol 4a =0,08.3=0,24 = a =0,06 mol ‘Thi nghiém 1: Cho tit tit dung dich x mol NaOH vao dung dich A Na ix oat $5) 7n0% :0,06—y | *>x =0,12-2y+0,12 #417008 :0,06-y |-#4x =0,12-2y+0, 2008), :y iu u : SO} :0,06 => x+2y =0,24 mol(1) i |w) Mega book ‘Thi nghigm 2: Cho tit tit dung dich x mol NaOH vao dung dich B. Nat ix NaOH = OH =xmol | a.) ap -0,08—y} 4 9x-+0,24—3y =0,24 Al(OH), :y mol : cr :0,24 x=3y=0 aye =0,144 x-3y=0 ap [ETO mm 1=8,496 8,5 x+2y=0,24mol() |y=0,048 Dap én B Ba(OH),:a [tee, = 0,48 (0H), 3 Jeo, = 0,4a =0,5>a=1,25 mol NaOH:a * | pac, = 0. Sites Nat :a oo: 4 Ba% 0,5 | M504 2a-1=x—0,5-9 x =3a-0,5=3,25 Boxeo, = 0,5 : HCO; :x-0,5 Dép an A en Ba(OH), :a mol :3 mol Ba’: CO,:3mol _ yg, JBa":0,5a ws 3-9.5apa=2x=20=4 BaCO, :0,5a HCO; :3-0,5a Dap ancRodi (Rhodium) Rodi, duoc William Hyde Wollaston phat hien sau khi Ong tim ra palladium trong nam 1803, 1a mot kim loai trang bac, cing nhung dé kéo soi. NO c hé so phan xa cao va c6 tinh dan dién/dan nhiét cao nhat trong tat ca cdc kim loai thudc nhom platin (PGM). Rodi khéng bi gi trong hau nhu tat ca cdc dung dich ngam nuoc bao gém ca axit vo co ngay cd 6 nhigt do cao. Cong dung chinh cla Rodi fa dugc str dung nhu mot chat pha ché dé tao hop kim voi bach kim va 6 dang hop kim do thi n6 co mot vai Ung dung trong cong nghiép dién va cong nghiép ché tao thuy tinh.Nhom Ia kim logi cé tinh kkhit rét manh chi ding sau kim loai kiém va kiém thé. Tinh khii cia nhém dugc thé hign qua nhiéu phan ting Phan ting véi nuidc trong moi trudng kiém: AI+OH" + 1,0 —>Al0; +3H, - Khit duigc oxit kim loai diing sau AL: 3M,O, +2yAlI—"> yAL,0, +3xM M hay gip Fe Cr, AL. Thuding gap oxi sat vi dé bai c6 thé két hgp bai tap xac dinh cong thitc oxit sit. Bo PHUONG PHAP GIAI BAITAP NHIET NHOM: Chit y: xéc dinh dé bai cho phan ting xay ra hodn toan hay khOng hoan toan - Dac truing bai todn nhiét nh6m ding NaOH (hay dung dich kiém): - Néu phan ing xay ra hoan hin hép sau phan ting NaOH c6 kkhi bay ra nén Al du suy ra hn hop sau phan ting nhigt nhom [a Al; Al,O,, M=> toan b6 Al chuyén vé mu6i NaAlO,. Ghi nhé: Cr khong phan ting v6i NaOH; Cr,O, phan ‘ing NaQH dic - mot s6 bai toan khai khée thém néu hén hgp phan ting véi HCl va H,SO, loang thi céc em chi can chit y: - Néu hén hgp sau phan ting téc dung HNO, hogc I1,S0, dc hodc hn hop H',NO; tacé $ ty, =2ng +2ty, +2.tho, +4:Mo H10.N yy, +12My, +10My.o + Va sit dung bao toan e la nhanh nat - Bai todn nhigt nhom khi chia hai phén nhuing dé khong cho bing nhau thi nbé xét hai phan khong bang nhau dé gidi3000000 oo BAITAP [XETED thuc hign phan ting nbiét nhém (trong digu kign khong c6 khong khi, hiéu suat 100%) ‘v6i 9,66 gam hén hgp X gém Al va m6t oxit sit, thu digc hon hop rin Y. Hda tan Y bing dung dich NaOH du, sau khi cdc phan ting xdy ra hoan to&n thu dug dung dich Z, chat khong tan ‘Tva 0,03 mol khi, Suc CO, dén du vao dung dich 2, loc ly két tiia nung dén khéi ligng khong d6i duige 5,1 gam mot chat rén, Cong thttc cia oxit sit va khéi ltgng cia né trong hn hop X wen la A. Fe,0,v82,76 gam. B. FeO, vi 6,96 gam. C. FeO vA7,20 gam, D, Be,O, va 8,00 gam. Hung dan: eee H, 10,03 9,66 gam X4Fe—*5 y M085. i - ° Z—%_+ AH), —" > A1,0. AL:O,1 fn 0:02 59,66 gamX/ Fe: 0,09 = Fe,0, = m=6,96g 1,0, :0,04 0:0,12 Dép dn B (XEQED thuchign phan ting nhiét nhém hén hop gém Al va m gam hai oxit sat trong khi tro, thu dutgc hon hop rin X. Cho X vio dd NaOH du, thu duge dd ¥, chat khong tan Z va 0,672 lit khi H, (dktc). Sue khi CO, du vio Y, thu duge 8,58 gam két tia. Cho Z tan hét vio dd H,SO, thu duige dd chita 20,76 gam mudi sunfat va 3,472 lit khi SO, (dktc, sin phd khit duy nhét cia H,SO,). Cac phan ting xdy ra hoan toan. Gia tri cia m la A, 6,80 gam B.8,04 gam C.6,96 gam D.7,28 gam 1 Huéng din: Al f H, :0,03 Fe—5x—san, | Ha ™B}5 y—% > AKOH), :0,11 mol Al: 0,02 Fe 7 > => Z:Fe—%1_ 20,76 gam: . +80," +HLO AIO, :0,045 soe ng... = Ngo, = 0,155 mol => m,, =5,88 g> m=m,, +m =8,04 g Dap én B [XECED Tien hanh phan ting nhiét nhém hin hop X gém Al va FeO dén phan ting hoan toan, thu dulgec chat rin Y, Chia Y thinh 2 phén bing nhau, Phan mét phan ting t6i da véi V lit dung dich NaOH IM. Hoa tan hét phén hai can 3,5V lit dung dich HC] 2M. Hén hgp Y gém A. AL Feva ALO, B. ALO, vi Fe, C. Fe, FeO v2 ALO, D. FeO, Al,0, Fe va AlW) Mega book Huong dan: ~ Phan ting nhiét nhom hoan todn: Dé don gin chon V=11 Phin mot phan ting t6i da véi 1 lit dung dich NaOH 1M dung dich thu dug NaAlO, :1 mol =n, =1mol Hoa tan hét phan hai cén 3,5 lit dung dich HCl 2M: dung dich thu dugc 'AP* :1 mol ‘ALO, ‘Al: 1 mol Fe® :x mol x =2 mol é B25} FeO ie" :x mol“ 5x = 2 mol Suy rahén hop ees cr :7 mol Fe Dap anC Tién hanh phan ting nhiét nhom hén hgp X gém Al va Fe,O, trong digu kién khéng cb héng khi thu duigc 28,92 gam hén hgp Y. Chia hén hgp Y thinh hai phan. Phan mot téc dung ‘v6i dung dich NaOH dui thu duge 1,008 lit H, (dktc) va 3,36 gam_ chat ran kh6ng tan. Phan hai ‘tée dung vita dit v6i 608 ml dung dich HNO, 2,5M thu duige 3,808 lit khi NO (dktc) va dung dich Z chtta m gam hén hgp mudi. Céc phan ting xdy ra hoan toan, Gid tri cha m gan gid tri nao nhat sau day? A.101 B.102 €.100 D.99 1 Huéng dan: Phan ting xdy ra hodn toin Phin 1: tic dyng NaOH cé Khi H, bay ra suy ra hn hgp rin sau nbiét nhom. Al ‘Al: 0,03, {Al va FeO, >. 410, oe ALO, :0,03 mol Fe He Fe:0,06 >m=7,3¢ Phan 2: Alt :0,27 AL: 0,09 Fe: 21,69 4 AL,O, :0,09 mol #22 _5mg}Fe*: +NO:0,17+H,0:emol Fe:0,18 NH :b NO;: jE 5 4b + 20 = 1,52 {Pnrsoonassao:7soe-sneqoseno7 = m=99,75 g Dap anC Hon hgp X gm Alva Fe,O,, Tién hanh phan ting nhiét nhom hoan toan m gam hén hop X trong digu kign khéng cé kh6ng khi thu dugc hén hgp Y. Chia ¥ kim 2 phn. calPhan 1: Cho tc dung véi dung dich NaOH du thu duigc 1,008 lit H,(dktc) va con lai 5,04 gam chat rin, Phan 2: Tic dung v6i HNO, long du thu dutge dung dich A va 8,064 IitNO (dktc la sin phém Ah duy nhét). Cho A tac dung véi dung dich NaOH thi khéi lugng, két ta Idn nhat thu duge la 54,63 gam. Gid tri m 1a A. 38,70 gam. B, 39,72 gam. C. 38,91 gam. D, 36,48 gam. Huéng dan: Phan ting xiy ra hoan toan Phan 1: téc dung NaOH cé Khi H, bay ra suy ra hén hgp ran sau nhigt nhom. Al: (A1:0,03 a ‘ wwon_, [0,045 molH, Fe —"54A1,0, 8 = mg} Al,0, :x mol Fe: 0,09 mol oO Fe Fe:0,09 Phan 2: AL:0,03 k AP* :0,03k +2xk mg4Al,O, : x kmol—""_ 5m g {Fe** :0,09k +NO:0,36+H,O:cmol Fe:0,09k INO; + /AI(OH), :0,03k + 2xk Fe(OH), :0,09k 111, 97k +156kx = 54,63, {ones =0,363 -{ 34,63 gam { Dap énB [XEQED thuc hign phan ting nhiét nhom hén hgp gém Al va.m gam hai oxit rin trong khi tro, thu duoc hon hop ran X. Cho X vio dung dich NaOH du, thu durge dung dich Y, chat khong tan Z ‘va 0,672 lit khi H, (dktc). Suc khi CO, du vao Y, thu duc 7,8 gam két tia. Cho Z tan hét vao dung dich H,SO, , thu duge dung dich chifa 15,6 gam muéi sunfat va 2,464 lit khi SO, (6 dkte, la sin phim khtt duy nhét cia H,SO,). Biét cdc phan ting xay ra hoan toan. Gié tri cla m Ja A. 6,29 B.6,48 C.6.96 1D, 5,04 1 Hudng dan: Phan ting nhiét nhém xay ra hoan toan. Sp thu duigc cho vao dung dich NaOH dut ‘Thu duge khi H, bay ra suy ra Al dut hén hyp X gm ‘Al NaOH oo, Al: 0,02 oe 25 Al(OH), :0,1 X:4AL,0, 4 +¥}]NaAlo, = X:1 A1,0, :0,04 M H, :0,03 M3) Mega book c +80, :0,11+H,0 = my =5,04.g¢=9 m= M—8°:415,6 gam: ‘ SO? 0,11 Dap an C ‘Thuic hign phan wing nhiét nhom hoan toin hon hgp X gém Al va Fe,O, trong chin khéng thu duigc 21,69 gam hén hop Y. Ta nghién nhé va tron déu Y r6i chia lam 2 phan: Cho Phén 1: téc dung véi dung dich NaOH dui thu digc 1,008 lit ki (Aktc) va 3,36 gam chat rn khong tan. Cho Phén 2: tron véi x gam KNO, r6i hoa tan vio 100 gam dung dich HCI, sau phan ting thu duige dung dich T chi chita céc mu6i clorua va 3,36 lit hén hgp khi Z g6m NO va H, (8 dktc), biét ti kh6i cita Z véi He la 6,1. Dung dich T tac dung véi lung dut dung dich AgNO, du thu duige 147,82 gam ket tita Gis tri gn ding cia néng 46 phin trim FeCl, trong dung dich Tla A.9% B. 10%. 11%. D.4% 1 Huéng dan: Phan ting xdy ra hodn toan Phan sau nhigt nhém, 4c dung NaOH cé Khi H, bay ra suy ra hén hgp rén Al A1:0,03 : ‘ won, [0,045 moll, {Al va Fe,0, "+4 Al,0, SH Ot => may Al,0, :0,03 mol ‘¢:0,06 mol Fe Fe: 0,06 => m=7,23g A :0,18 Fe" :x AL:0,06 a ia Sette Fe*:y +46 84 ALLO, :0,06 mol —areeeciar asm MEY 1 94 195 Fe:0,12 eae Kt :b-+0,12 2g +4tyg +10.n uty 2D, = x+y=0,12 => 43x+2y+0,18 = 8b +0,36+0,06 = 13x +2y-8b= 143, 5(0,9+10b)+108y =147,82 [ox +108y +1435b=18,67 mj, = 123,93 > Ymg.c, =10,48% Dap nB (XELED Hin hop X gém Al, FeO, Cr,0,. Nung hén hgp X trong binh kin khong 6 oxi cho én hi phan ting xay ra hoan toan thu duigc 28,7 gam hén hgp rn Y. Cho toan bé Y téc dung véi dung dich NaOH dc néng due thi thu duige 1,68 lit khi H, (4kte), dung dich Y, va m gam chét Lsran Z. Cho toan bd Z tée dung v6i dung dich H,SO, loang du thu dugc 6,16 lit khf H, (dktc). Gia tri m gin véi gid tri ndo sau day? A.15 gam B.l4,4 gan C.14,9 gam D.14,7 gam 1 Huéng dan: x:{Al, FeO:a, Cr,0,.6— 28,7 gam Y—““" 50,075 mol H, ‘Al: 0,05 mol Fe:a 28,7 gam Y4Cr:2b => 3da+102b+56a +104b = 27,35 Al,O, tb 075 et >m=146 2a+4b =0,55 b Dap an D Dun néng 25,5 gam hén hgp X gém bét Al va Be,O, cho dén khi phan ting xay ra ho&n toin thu duigc hn hgp rin Y, Dem hét hén hgp rn ¥ cho vio dung dich NaOH du thu duge 3,36 lit kh H, (dktc). Thanh phén % vé kh6i ligng cita Fe,O, c6 trong hén hop X la A.63,25%, B.31,76%, €.36,75%. D,68,24%, Hung dan: |Al:0,1 Alaa ab 25,5 gam: > ALO, :——-—SoH 20)! gam (ee 1,0," H, 20,15 Fe 27a+232=25,5 48 2503 compa, = 68,24% Bao b=0,075 > Mra. 8 ae 3 Dap én D Dp carta ren woven [XELED Hon hop X gém Al, Fe,©,, Tin hanh phan ting nhiét nhém hoan toan m gam hén hop X trong diéu kign khong 6 khéng khi thu dug hn hgp Y. Chia ¥ thinh 2 phan: - Phan 1: Cho tac dung voi NaOH du thu duge 1,008 lit H, (dktc) va cdn lai 5,04 gam chat ran khong tan. - Phan 2: C6 khéi lugng 29,79 gam cho tac dung véi dung dich HNO, loing du thu duge 8,064 lit NO (dktc, NO Ja san phém khd duy nhit). aec Lraid a Gia tri cha m va cOng thiic cita oxit sat lan lugt 1a A. 39,72 gam va FeO. B. 39,72 gam va Fe,0,. C. 39,91 gam vi FeO. D. 36,48 gam va Fe,0,. Nung néng m gam hén hgp gém Al va Cr,O, (trong diéu kién khong c6 khéng khi) dén khi phan ting xay ra hoan toan, Chia hén hgp thu duge sau phan ting thanh hai phan bing nhau. Phan mét phan ting vita dt voi 600 ml dung dich NaOH IM (long) va thay c6 bot khi thodt ra. Dé hda tan hét phan hai cén vita dit dung dich chtta 2,6 mol HCL. Gia tri ctiam la A. 19,8. B. 83,6, C. 93,2. D. 1000 ‘Tron 2,43 gam Al véi 9,28 gam Fe,O, ri nung néng cho phan ting xdy ra mot thoi gian, lam lanh duigc hén hop X gém Al, Fe, Al,O,, FeO va Fe,O,, Cho toin b6 X phan ting véi dung dich HCl du thu duige 2,352 lit H, (dktc) va dung dich ¥. C6 can ¥ duige a gam mu6i khan. Xée dinh gid tri cha a? A. 27,965 B, 16,605 C. 18,325 D. 28,326 ‘Thyc hién phan ting nhiét nhom m gam hén hgp X gém Al va Fe,O, dén khi phn ting 8 p X gi 0, phan ting hoan toan thu dugc hén hop ¥ (biét Fe,O, chi bj khdt vé Fe). Chia ¥ thanh hai phén: = Phan 1: cho tac dung voi dung dich NaOH du thu duige 0,15 mol H, dung dich Z. vi phan khng tan T: Cho toan bé phan khong tan T tac dung véi dung dich HCI du thu duigc 0,45 mol Hi, - Phin 2: cho tac dung véi dung dich HCI thu duge 1,2 mol H,. Gia tri cla ma A. 164.6. B. 144,9. C1354. Dz 173,8. ED Hon hyp X gm Alva FeO, lfy 42,8g X dun néng dé thyc hién phan ting nhiét nom ‘m6t thi gian thu duigc m gam chat rin Y. Chi Y thanh 2 phan bing nhau, Hoa tan hét Phan 1 trong dung dich KOH du thay thodt ra 1,68 lit khi (dktc). Phdn 2: hda tan hét trong dung dich HCI thay thoat ra 5,04 lit kh (dktc), Tinh 9 kh6i lugng cia Fe trong Y: A. 39,25 B. 58,89 C.19,63 D. 29,44 ‘Thyc hién phan ting nhiét nhém hén hop bot X (g6m Al va mt oxit sat) sau phan ting thu duge 16,38 gam chat rin Y. Cho ¥ tic dung véi dung dich NaOH du, phan ting xong thu dugc phan kh6ng tan Z va 3,36 lit khi (dktc). Cho Z tan hoan toan trong 40,5 gam dung dich H,SO, 98% (néng, vita di). Biét céc phan ting xay ra hodn toan. Khéi ligng Al ban dau va céng, thiic oxit sat la A. 6,12 gam va Fe,0,. B. 5,94 gam va Fe,0, C. 6,12 gam va Fe,O,. D.5,94 gam vi Fe,0,, ED Thc hign phin ting nhi¢t nhom bon hop g6m Al va m gam hai oxit sit trong khi tro, thu duigc hén hop rén X. Cho X vio dung dich NaOH du, thu duge dung dich ¥, chat khong tan Z va 0,672 lit khi H,, (dktc). Suc khi CO, dul vao Y, thu duge 7,8 gam két tia, Cho Z.tan hét viodung dich H,SO, thu duigc dung dich chifa 15,6 gam mu6i sunfat va 2,464 lit SO, (dkte, Ia sin phém Khit duy nhat cia H,SO,), Biét céc phan ting xdy ra hodn toan, Gié tri cia m Ja A. 6,48. B. 6,96. C.6,29. ‘Dz 5,04 Nung m gam hén hop A gém Al va Fe,O, trong méi truéng khéng cé khéng khi, dén phan ting xdy ra hoan todn (gid sit chi cé phan ting khi oxit sit thinh sét) thu duigc hon hop B. Chia B thanh hai phan, Phan mt téc dung v6i dung dich NaOH du thu duige 1,176 lit khi. ‘Tach ly phn kh6ng tan cho tac dung véi dung dich HCI du, thu duige 1,008 It khi. Phén hai tc dung véi dung dich H,SO, loang du thu duigc 6,552 lit khi, Céc khi do & dkte. Gia trj cia mk A. 24,06. B. 25,08. C. 23,04. D. 22,02. ‘Thutc hién phan ting nhiét nhém hén hop gém Al va m gam hai oxit sit trong khi tro, thu dugc hén hgp ran X. Cho X vio dung dich NaOH du, thu dugc dung dich ¥, chat khong tan Z, va 0,672 lit Khi H, (dktc). Suc khi CO, du vao Y, thu deige 8,58 gam két tiia. Cho Z tan hét vio dung dich HSO,, thu duige dung dich chita 20,76 gam mudi sunfat va 3,472 Iit khi SO, (6 dkte, 14 san pham khii duy nhat cia H,SO,). Biét céc phan ting xay ra hoan toan. Gié tr} clia m la A. 8,04 gam B. 6,96 gam C.6,80 gam D.7,28 gam ‘Nung néng m gam hén hop X gm Al va Fe,O, t6i phan ting hoan toan, thu duige chat rin Y, Nghién nhé, tron déu va chia Y lim 2 phan: ~ Phan 1: Cho téc dung véi dung dich NaOH dén du thu duge 1,344 lit H, (dtc) va chat rin Z. Hoa tan chat rin Z trong dung dich HCI du thu duge 5,376 lit khi H, (dkte) - Phén 2: Cho tac dung v6i dung dich HCI du thu duge 6,72 lit khi H, (dktc). Gid tri cia m la: A. 29,04 gam, B.87,12 gam. C. 53,52 gam, D. 26,76 gam, ‘Thy hign phan ving nhigt nhom hdn hgp bot P gdm Al va Fe,O, trong digu kign khong cé khéng khi thu duige 79,44 gam hén hgp H, chia hén hgp H thanh hai phan, Phan mét téc dung v6i dung dich KOH du thu difgc 4,8384 lit H, (ktc) va 24,192 gam chat rin khong tan. Cho phan hai tan hét trong 2,67 lit dung dich hén hgp O gém KHSO, 0,8M va KNO, 0,8M thu duige 4,3008 lit NO (dtc) va dung djch N chit tan chi chtta m gam hén hop muéi G. Céc phin ting xdy ra hoan toan, Gia tri m gan nhat voi A515. B.525. C.535. D. 545. Tién hanb phan ting nhiét nh6m hoan toan 19,32 gam hén hgp X gém b6t Al va Fe,O, trong diéu kign khdng co khong khi thu duigc hn hop Y. Nghién nhé, tron déu hon hop ¥ r6i chia thanh 2 phan (phan mot c6 khéi luong gép 3 lén phan hai) - Phin 1: duigc hda tan hét trong dung dich HNO, loang, du, dun néng thu duige dung dich Z. va V lit NO (sin phém kh duy nbat, dtc). - Phin 2: dem tac dung véi dung dich NaOH dut dun néng thu duigc 0,015 mol khi H, va con Iai 2,52 gam chét ran, Gia tr] ctia V va céng thite cia oxit sit Ia A. 3,696 va Fe,0, B.3,36va FeO, C.3,696vaFe,O, —_D.3,36va Fe,0,.ed Cho 41,4g hén hgp X gém Fe,O,, Cr,0, ALO, tac dung véi dung dich NaOH dic du, sau phan ting cdn chat ran ning 16 g. Dé khit hoan toan 41,4 g X bing phan ting nhigt nom phai dng it nhat 10,8 g Al. Tinh % theo khéi lugng cia Cr,O, trong hén hop X? A36,71% B. 38,65% C.24,64% D.35,51% [XEMELD 6 3,04 ghdn hop X g6m bot Al va Fe,O,(trong dé Al chiém 41,12% vé kh6i lugng) thuc hign phan ting nhigt nhém hoan toin hn hgp X trong chan khéng thu duige hén hop Y. Hoa tan hoan toan Y trong dung dich chita 0,314 mol HNO, thu duigc dung dich Z. chi cé cde mui va 0,021 mol m6tkhi duy nhat la NO. Cé can dung dich Z, r6i thu ly chat rn khan nung trong chan khéng dén khéi higng khéng 46i thu duigc hén hgp khi va hai T. Khéi lugng cia T gin gid tr] nao nhét sau day? A415 g B.15,35g C.15,78 g D.14,58 g ‘Thuc hign céc phan ting nhiét nhom hén hgp gém m gam Al va 4,56 gam Cr,O, (trong diéu kign khong cé O,), sau khi phan ting két thiic, thu dugc hén hgp X. Cho toan bd X vao mot lttgng dut dung dich HCI (loang, néng), sau khi cac phan ting xay ra hodn toan, thu duigc 2,688 lit H, (dktc). Con néu cho toan bd X vao mot ligng du dung dich NaOH (diac, néng), sau kkhi phan ting ket thitc thi s6 mol NaOH 4a phan «ing la? A.0,08 mol. B.0,16 mol C.0,10 mol. D.0,06. [XETELD Nung néng m gam hén hop gém Al va Fe,O, trong diéu kién khong cd khong Khi. Sau ‘khi phan ting xy ra hodn toan, thu dug hn hgp rn X. Cho X tac dung v6i dung dich NaOH (du) thu duigc dung dich Y, chat rin Z va 2,24 lit khi H, (6 dktc). Suc khi CO, (du) vao dung. dich Y, thu duge 62,4 gam két tia. Gid tri chia m la ALSILS. B.93,9. C.85,4, D. 93,0. ‘Tron déu 6,102 gam hén hgp Al, Fe,O, va CuO (céc chat ¢6 cing s6 mol) r6i tién hanh phan ting nhiét nhom thu dugc hon hgp X. Cho X phan ting véi dung dich HNO, du duge V ml (dtc) hén hop khi NO, va NO theo tié mol tung éing ld 1:1. Gi tri cha V 18 A. 806,40. B. 403,20. C. 604,80. D. 645,12. [ED Tr9n 0,54 gam bét Al véi hn hgp bot Fe,O, va CuO r6i tign han phan ting nhiét nhom 6 nhigt dé cao trong diéu kign Khéng c6 khéng khi thu dugc hn hgp rin X. Hoa tan X trong dung dich HNO, thu duigc 0,896 lit (dktc) hén hgp khi Y gm NO, va NO. Ti kh6i cia X so vi H, Ii: A.20 B.2 C.23 D.21 ‘Tron déu bdn hgp b6t Al va Cr,0, r6i nung trong binh kin khdng cé khong khi dén khi phan ding xay ra hoan toan thu duigc hén hgp chat ran X, Chia X lim 2 phan bing nau. Phan 1: téc dung vita di v6i 300 ml dung dich NaOH 1M thay cé khf bay ra, Phan 2: dem tac dung véi litgng dit dung dich HNO, long, néng, thu duigc V lit kh{ NO (sin phém khit duy nhat, dktc). Gia tri cla VA AL 13,44, B. 4,48. C.3,36, D.6,72. EXD on hyp X gm cic chat CuO, Fe,O, Alc6 s6 mol bang nhau.Thyc hign phin ing nhiét nhém 33,9 gam X trong moi tridng khi tro, sau mot thoi gian thu duge hén hgp chat rn Y.Cho Y téc dung hét v6i dung dich HNO, dut thu duige hn hop sin phim khit Z chi gm NO,, NO cé6 téng thé tich 4,48 lit (dktc). Ty khéi cita Z so véi heli A105 B.21,0 C95 D. 19.0 [XETEDD ‘thyic hign phan ting nhigt nhom hén hgp gém Al va m gam hai oxit sit trong kh tro, thu duigc hén hgp rn X. Cho X vio dung dich NaOH dui thu duge dung dich Y, chat kh6ng tan Z, vi 0,896 lit khi H, (dktc). Suc khi CO, du vio ¥, thu duge 7,8 gam két tia. Cho Z tan hét vao dung dich H,SO,, thu dutge dung dich chtéa 20,76 gam mu6i sunfat va 3,472 lit khi SO, (6 dktc, a sin phéim kh! duy nhat cia H,SO,). Biét cdc phan ting xay ra hodn toan, Gié tri cia m ld A. 6,80 gam. B.6,96 gam. C.7,64 gam. D.8,04 gam. Hén hop X g6m 3,92 gam Fe, 16 gam Fe,O, va m gam Al. Nung X 6 nhiét d6 cao trong digu kign khOng cé khéng kh, thu duigchén hgp chat rén Y. Chia Y thanh hai phan bang nhau. Phan mot tc dung véi dang dich H,SO, loang (du), thu duigc 4a mol kh{ H,, Phin hai phan ting v6i dung dich NaOH du, thu duigc a mol khi H,. Biét céc phan ting déu xay ra hoan toan. Gis trj cham A. 7,02. B.4,05. C.5.40. D.3,51. [XEIEED Nung m gam hin hop Alva Fe,O, (trong moi trudng khong cé khong khi) dn khi phin «ing xay ra hoan toan thu duige hén hop rén Y. Chia ¥ thanh 2 phan bang nhau: ~ Phan 1: téc dung véi H,,SO, loang du sinh ra 3,08 lit khi H, (dk) ~ Phan 2:tac dung voi dung dich NaOH du sinh ra 0,84 lit khi H, (dktc). Gia trj ciza m la? A.22,75 B. 21,40 C.29,40 D. 29,43 [XEEED tron déu 6,102 gam hén hop Al, Fe,0, va CuO (céc chat 06 cing s6 mol) r6i tién hanh phan ting nhiét nhém thu duge hén hop X. Cho X téc dung véi x lit dung dich HNO, 1M dui duge V ml (6 dktc) hén hgp khi NO, va NO theo tilé mol tung ding la 1:1. Tinh gid tri cla x (biét ding du 5% so véi lugng phan ting) A. 0,288, B.0,3024. ©.0,1134 D.0,2646 [XEXEED Nung hén hop X gém 0,3 mol Al va 0,1 mol Fe,O, 6 t° cao trong diéu dién khéng cd khéng khi dugc hén hop chat ran Y. Cho Y tac dung lung dich NaOH du thu duge V lit khi H, (dktc). Tinh gi tr} cia V biét cdc phan ting xay ra hoan toan? AL 2,24 B, 3,36 C448 D.5,6 [XETED Nung hin hop bot gdm 15,2 gam Cr,0, va m gam Al 6 nhiét 46 cao. Sau khi phan ung hoan toan, thu dugc 23,3 gam hén hgp rin X. Cho toan bd hén hgp X phan ding véi axit HC] (du) thoat ra V lit khi H, (6 dktc). Gia tri cha V 1a? A448 B.3,36 €.10,08 D.7,84 Thu hign phan ting nhiét nhom hén hop bot X (gém Al va mot oxit sat) sau phan ting thu duige 92,35 gam chat rin ¥. Cho Y téc dung véi dung dich NaOH du, phan ting xong vin con phiin khong tan Z va thu duige 8,4 lit khi E (dtc). Cho Eluang chitZ tan hoan toin trong =aaera dung dich H,SO, dac néng cin vita di 60 gam H,SO, 98%, Biét cdc phan ting xy ra hoan toan. Khéi higng Al,O, tao thanh c6 chita trong chat rin YB: A, 38,08 gam. B. 40,8 gam C.24,48 gam D. 48,96 gam (XETED cho hén hgp A 6 khéi lugng m gam gém bot Al va oxit sét Fe,O,. Tién hanh phan ting P 1g m gam gf 0, phan ting nhiét nhom hén hgp A trong diéu kign khong cé khéng khi dugc hon hop B. Nghién nhé tron déu B ri chia thanh 2 phén. Phan 1: c6 Kh6i luong 14,49 gam duigc hoa tan hét trong dung dich HNO, dun néng, dugc dung dich C va 3,696 lit khi NO (sin phim khit duy nhét & dkc). Cho Phin 2: tic dung véi dung dich NaOH dun néng thay gidi phéng 0,336 lit khi H, (ake) ‘va con lai 2,52 gam chat rin. Céc phan ting déu xay ra hoan toan, Cong thifc oxit sét va gid tri cia m lin lugt a A. FeO va 19,32. B. FeO va 28,98, C. Fe,O, va 19,32, D. Fe,O, va 28,98. [XETEED Co 22,3 gam hén hop X gém bot Fe,O, va Al. Nung X khéng c6 khong khi ti phan ting 8 8 0; ig Kh t6i phan ing hoan toan thu duigc hén hgp Y. Hoa tan ¥ trong HCI du duige 5,6 lit khi (Aktc). Khéi lugng Al 6 trong hh Xl AL93 B.63 C.6,75 D8 1 [XETED Nung hin hgp bot gm Al va Fe,O, (trong diéu kién khong cé oxi), thu duige hén hgp chat rin X. Chia X thanh 2 phan bang nhau: Cho Phin 1 vio dung dich HCI (dui) thu duge 7,84 lit khi H, (dite). Cho Phin 2 vio dung dich NaOH (dui) thu diige 3,36 it khi H, (dktc). Biét ring cc phan ting déu xay ra hoan toan, Phan tram khdi lugng cia Fe trong X13 A46,47%. B.33,61%. C.66,39%. DA2,32%. Hén hgp X gém Al, Fe,O, c6 khéi hing 21,67 gam. Tién hanh phan ting nhiét nhom hon, hop X trong digu kign khong c6 khong Khi (gia thiét chi xiy ra phin Ung Al khit Fe,O, thanh kim ogi). Hoa tan hén hgp chat rén sau phan ting bing dung dich NaOH du thu dugc 2,016 It H, (dktc) va 12,4 gam chat rin khdng tan. Higu suat cha phan Ging nhiét nhém la A. 45%. B,50%. C.71,43%. D,75%. (CXETED Nung 21,4 gam hon hop X gém Al va Fe,O, (phan ting nhiét nhém), thu dugc hén hop Y. Cho Y téc dung hét véi dd HCI du duige dd Z. Cho Z tac dung vai dd NaOH dit duigc két tia ‘T, Nung T trong khéng khi dén khéi lufong khong déi thu duige 16 gam chét rn. Khdi higng Alva Fe,O, trong hén hgp X ln tgt 8 A.54 gam va 16 gam. B64 gam va 1S gam. C.4,4 gama 17 gam. D.7,4 gamvva 14 gam. TEED Tron déu 6,102 gam hén hgp Al, Fe,O, va CuO (céc chat c6 cling 6 mol) r6i tién han phan ting nhiét nhém thu dugc hén hgp X. Cho X tac dung vi x lit dung dich HNO, IM dui dug V ml (4 dktc) hén hgp khi NO, va NO theo ti lé mol tuong ting la 1:1. Tinh gia tri cia'x (biét ding du 5% so véi lugng phan ting) A. 0,288. B.0,3024. C.0,1134 D.0,2646. EaC6 22,3 gam hén hyp X gém bot Fe,O, va Al. Nung X khéng oé khéng khi t6i phan ting hoan toan thu duge hén hgp Y. Hoa tan ¥ trong HCI du duige 5,6 lit khi (dktc). Kh6i higng Al 6 trong hh X18. A93 B. C675 D.81 ‘ung néng m gam hén hop g6m Al va Fe,O, trong diéu kién khong cé khéng khi, Sau khi phan ting ‘xly ra hodn toa, thu duge hn hp ran X. Cho X tic dung v6i dung dich NaOH (du) thu due dug dich Y¥, chat rin Z va 3,36 lit khi H, (6 dite) Suc khi CO, (du) vao dung dich ¥, thu dutge 39 gam két tha, Gié tr] cha m la: A.45,6 gam B.57,0 gam C. 48,3 gam D.36,7 gam [XEZED Nung m gam gém Al va Fe,O, trong diéu kign khong cé khéng khi cho dén khi phan ding hoan toan thu dugc hén hgp X. Tron déu X, chia X thanh 2 phan. Phan 1: (c6 khdilugng 14,49 gam) héa tan hét trong dung dich HNO, dui thu duigc 0,165 mol Khi NO (sin phém khi duy nhat), Phan 2; tac dung hét v6i dung dich NaOH nhiét &6 thy giai phéng 0,015 mol H, va con Iai 2,52 gam chat rin. Cong thite sat oxit va gid tri m Ia A, Fe,0,; 19,32. B. Fe,O,; 28,98, C. Fe,0,; 28,98. D. FeO, ; 19,32. , 0,5 CXETEDD Nung 61,32 gam hin hgp ran gém Al va céc oxit sét trong khi tro 6 nhiét d6 cao dén khi phan ting xy ra hoan toan thu dug hén hgp X. Chia X thinh 2 phan bang nhau. ~ Phin mét cho téc dung voi dung dich NaOH du thu dutge 2,016 lit khi (Akt). - Phén hai hde tan het trong dung dich chita 1,74 mol HINO, thu duige dung dich ¥ chi chiia cdc muéi va 4,032 lit NO (dktc) thoat ra. Cé can dung dich Y, ly ran thu dugc dem nung ngoai Khéng Khi dén kh6i ltgng khong d6i thu dugc hai chat rén c6 s6 mol bing nhau, Néu cho Y tae yng véi dung dich Na,CO, dut thi thu duige a gam két tila. Gid tri cia a li: ‘A. 50,40 gam. B.50,91 gam, 57,98 gam. D. 58,20 gam. Nung hén hop X g6m 0,3 mol Al vi 0,1 mol Fe,O, & nhigt dé cao trong diéu dién khong 66 khong khé dutge hin hop chat rn Y. Cho Y tc dung véi dung dich NaOH du thu dugc V lit khi H, (dktc). Tinh V biét cdc phan ting xay ra hoan toan. A. 2,24, B.5,6, C. 4,48. D. 3,36. [XETED Hon hop X gém 8,1 gam Al va 16 gam Fe,O,. Nung hén hop X 6 nhiét d6 cao trong diéu kign khéng co khéng khi, sau mt thi gian phan ting thu duge hén hgp chit rin Y. Hba tan Y trong dung dich HCl (du), thu duigc dung dich Z va V lit khi H, (dktc). C6 can dung dich Z thi thu dugc 66,87 gam mudi khan. Gid tri cua V 1a. A. 8,288. B. 8,400. C.7,840. D. 6,720. [ZENZD Hon hop X gém m gam Al va 7,2 gam Fe,O,. Nung hén hop X trong diéu kign khong cé khéng khi thu duge hén hop rin Y. Bé tac dung hét vi cac chat trong Y cén ding vita dit 100 ml dung dich NaOH 1M, thu duigc 0,672 lit khi (¢.k.t.c). Higu suét cia phan ting nhiét nhém ka: A, 80%. B.90%. C. 88,9%. D. 85,9%, IzaDa Nung ndng m gam hén hgp gém Al va Fe,O, trong diéu kién khéng c6 khong khi, Sau kkhi phan ting xdy ra hoan toan, thu dugc hén hgp rn X. Cho X téc dung véi dung dich NaOH (du) thu duge dung dich Y, chat ran Z va 2,24 lit khi H, (6 dktc). Suc khi CO, (du) vao dung dich Y, thu dugc 62,4 gam két tila. Gia tri cham 1a ALLS, B. 93,9. C. 85,4. D. 93,0. [XEPEED Nung hén hop bét gém Al va Fe,O, trong binh kin mot théi gian thu dugc hén hgp X B 205 gi g6m Fe, FeO, Fe,O,, Fe,O, va AL. Hoa tan hét X bang dung dich HNO, du thu dugc 1,344 lit (dktc) khi NO la sin phém khit duy ahat, Khét ligng cia Al trong hdn hop ban déu la A.0,81 gam. B. 3,24 gam. €.0,27 gam. D. 1,62 gam. ‘Tron bot Al'véi Fe,O, r6i dun néng thu duigc 24,1 gam hén hop X. Chia X thinh hai phan bang nhau: Phan 1: tac dung véi dung dich NaOH du thu duige 1,68 lit H, 6 (dtc). Phan 2: tac dung véi dung dich H,SO, dc néng du thu duigc 5,04 lit SO, 6 (dktc) sén phém ‘chit duy nit. Onit sit li: Biét tat c& cdc phan ting déu xdy ra hoan toin, A.Fe,O,hoic FeO, B.Fe,O,, CFO. D.Fe,0,. Nung néng m gam hén hgp X gém Al va Fe,O, t6i phan ting hoan toan, thu dugc chat rn Y. Nghién nhé, trn déu va chia Y lam 2 phn: ~ Phan 1: Cho tac dung véi dung dich NaOH dén du thu dug 1,344 lit H, (dktc) va chat ran Z. Ha tan chat rin Z trong dung dich HCI dt thu duige 5,376 lit kht H, (dtc) ~ Phan 2: Cho tac dyng véi dung dich HCI dut thu duge 20,16 lit khi H, (Akt). Gia tri cua m la: A. 29,04 gam. B. 87,12 gam. C. 107,04 gam. D. 26,76 gam. ‘Thyc hién phan ting nhiét nhém hén hgp X gém Al va Cr,O,, thu duigc hdn hop Y. Chia hén hgp Y thinh hai phén bing nhau, Phan 1: phan ting vita di 2,5 lit dung dich H,SO, 0,5M, néng (khéng cé khong khf). Phén 2: phan (ing vita di 3,2 lit dung dich HNO, 1M, thu duige 11,2 lit khi NO (do 6 dktc, sn phdm khit duy nhét). Higu sudt cia phan ting ahigt nhom la A. 50%, B. 80%. C. 75%. D.60%. Nung néng 23,3 gam hén hgp gém Al va Cr,0, (trong diéu kién khong c6 khong khi) Sn, = 0,6 r, ia ALO,> m=93,2g CrCl, 20,4 Cr Hee { ALO, Dap an C ‘Al: 0,09 mol Al, Fe, Al,0,, S. Fe,0, :0,04 FeO va Fe,0, Ny = 2.9 +2.ny, = 0,04,4.2+0,105.2=0,53 mol = 0=0,09.27+0,04.3.56 + 0,53.35.5 = 27,965 g 25H, :0,105 Dap an. A Phén I: Al Al 0,15 mol H, Al:O1 { —toyY-{Al,0, >; NaAlO, = Y:jAl,0, :0,2 Fe,0, iq es Fe Fe—40,45 mol Fe: 0,45 Phan 2: Y: hie tad reuand , [AICI 0.5K M1_wor 59,54 340,45k2=1,2" ae te FeCl, :0,45k 7 ‘ fe Fe:0,45k = k=0,59m=144,9g Dap an B Al /Al:0,05 Al > JALOs sow Al,O, 214 eX: Soy , Y : 1.48% ‘eee Fe 290,075 mol ¥ V5, Fe,0, Fe,0, /A1:0,05 JAL:0,05 ALO; net 1,0; %ra,. = 9) Vy TEEPE 20,225 mol YF 6615 mol? Mtv = 325% Fe,0, Fe,0, Dap an A > ‘Alia Al:0,1 16,38gX{Feb —“sy. ALO, 55 M8 0,15 molH, + Fe Owe Fe:b al27a+56b+16c=16,38 pela 3 27a+56d+16c = 16,38 3a—2c=0,3 O1 Fe*:b +80, +H,0;n,,, SOP :0,2025 i Fe HS ma { ,2025 mol => b= 0,135 2Ta+16c=8,82__ fa=0,22_ [Al:5,94 = => = 3a-2c=0,3 c=0,18 ” |Fe,0, ‘Al Al NaAlO, — Al(OH), :0,1 [Al:0,02 151 Al,0, >) Fe => 4 Al,O, :0,04 Fe,0, a ‘ Fe H, :0,03 Fe:x mol +80, :0,11+H,0 Fe Fe: x mol—#82-515,6 gam { =0,11= m,, =5,04 2 m=6,96g eal Hi, :0,0525 ‘Al:0,035 F0,7 ALO, —82+4 NaAlO, => {Al,0, :0,02 Fe Fe—< 5H, :0,045 mol [Fe:0,045 Phan 2: A1:0,035 k™ AI,0, :0,02 k™ —88 5H, :0,2925 mol —"* +0,195k = 0,585 > k=33 m=22,02¢ Fe:0,045 k™" Dap anD 7 Al H, :0,03, {re 7 "44 A1,0, | NaAlO, 82> AI(OH), :0,11 i Fe Fe Fe 2825 20,76 gam | Md +80, :0,155 mol+H,O SOF :0,155mm) Megabook _ Al:0,02 => jAL,0, :0,045=> m,, =5,88 2 m=8,04g Fe Dap an A Phan 1: Al AL H, :0,06 Al: 0,04 {f a —"5/ 1,0, #5) NaAl0, = 4ALO, :0,12 , 7“ Fe Fe—%50,24 molH, — [Fe:0,24 Phin 2: ‘AL:0,04k => 4AL0, :0,12k— 4H, :0,3 mol => 0,04k 3 +0,24k 2 = 0,6 = k=1> m=53,52g ,24 AL ‘Al Hi, 20,216 /AL:0,144 { fia. £41410, >} KAO, => mg 4 Al,O, :0,192 = 47,664 g ae Fe Fe: 0,432 Fe:0,432 Phan 2: Kt 34,272 SOF :2,136 ‘A1:0,096 NH: 31,776 g 4 ALO, :0,128—SSSseie=" Ny NO; +NO:0,192 mol+H,O Fe:0,288 alt Fe* Fe" By, = 2g +4 yg +10 gs Roy, =0,06—M4 > nyo = 0,948 mol = my, =515,184 => A Dép an A. Phan 2: ia Al H, :0,015 AL:0,01 sane Fe0 144,83 g 4 AlO, 5) NaAlO, = 4,83 g 4 A1,0, :0,02 aoe Fe Fe:0,045 Fe:0,045Phan 1: Al:0,03 ae V =3,6961 14,49 g 4 AL,O, :0,06—™2 5 NO: 0,165 => Fe,0, Fe: 0,135 Dap anc Fe,0, NaCrO, 41,4g:4 Cr,0, >; |NaAlO, Al,O, Fe,0, :0,1 mol Fe,0; :0,1 2 [AL,O, 20,2 41,4g:} Cr,0, 2a aaa Oe =a =0,1> %mMe,o, =36,71% AL,O;:b Tee Dap dn A [Al:0,06 mol attain " HL sora ¥6,04:0,01 mol 0,02 01 NO +O Dye 2g 4 Nyy HOM, PM = 0,015 mol = ny, o = 0,127 mol |AP* :0,06 AP* :0,06 Fe**:x Fe :x Z:4Fe : 0,806; Z:4Fe™ : at {Ai0'008 et atte pee ‘ Fe,0,:0,015" NH; :0,015 NH} :0,015 NO; :0,278 mol NO; :0,278 mol = m, =15,346 g Dap én B Al ‘Al:0,04 mol : oe Al,0, :0,03 "> H, :0,12 mol => 4 ALO, :0,03 F Cr:0,06 Cr: 0,06 ‘Al:0,04 mol ALO, :0,03 —“ > NaAIO, :0,1 mol = ny,o, =0,1 mol Cr:0,06 Dap anc=85,4 > 1Fe,0,:0,275 mol ™ 8 Dap anc AL:0,018 os . 18 6,102 g }Fe,O, :0,018—-> XK 4 vy ay ME 5a =0,018 => V =806,41 Cu0 0,018 a DépénA Cau 18 aoa NO:b b=0,04 Fe0, —ox—# 50,04 mol Seer NO,:a~ Ja+3b=0,02.3 cuo =M-4159%=21 2 Dap nD ID Al ivi HL, Al: 0,3 mol 2 Jato, —moxosm, [Hy 3 mol _ sa eet eae leaennetey C,0, ean © 3V=6,721 Dép an D (CuO :0,1 mol 33,9 gam X:4 Fe,O,:0,1 mst —2-30,2m{ NO, :a. feast fa=01 Al:0,1 mol = =4 NO:b ~ la+3b=0,4— |b=0,1Hi 20,04 Al wt > ‘Al i NaAlO, — Al(OH), :0,1 i ox:tan 2 201 | apg tL fro, Al,0, Yt. 10s 7555 fe so. Fe:5,88 Fe—¥S2_520,76 gam} +50, :0,155+11,0 SOF :0,155™" >m=7,642 Dap 4nC 22 Fe: 0,07 Al:2x X:4Fe,0, :0,I—"4Y :4 Al,O, :0,.1—> Al Fe:0,27 Phan 1: Al:x ALO, : 0,05—#52-4 H, : 4a mol => 3x + 0,27 = 8a => 8a-3x = 0,27 Fe:0,135 Phin 2: abe 3x-2a=0 = 0,045 Al,0, :0,05 “45 Ha mol => 3x =2a.=3x-2a=0— qn dt a 8a—3x=0,27 |x =0,03 Fe:0,135 =m=35ig Dap an D Al og Fe, 7 PY ANOs Fe Phin 1: Al ‘Al: 0,025 mol Y:) ALO, —4 5H, :0,0375 = Y¥:4AL,0, Fe FeMm Mega book i = FP $000000000000000000000000000000000 Phin 2: ‘Al: 0,025 mol ¥:4AL,0, HS H, 10,1375 = 0,025.3+2a =2.0,1375 3 a=0,1 Feza ‘A1:0,05 mol m:{Al,0,:0,1 => m=22,75g Fe:0,2 Dap in A AL: 0,018 £ ENC NO, va bu 6,102.8 }Fe,0, 30,018 9X2 4V:) ,018, CuO :0,018 ied PnP = 2g +4.tyg +2.tyo, = 0,288 n°% = 0,288.1,05 = 0,3204 Dip an B AL:0,1 (0,3 mol Al ¢ on + + +H, 1 => V, =3,361 [onmats0,— AI,0, :0,1 25H, 20,15 mol = Vy, =3,36 Fe:0,1 Dap én B <=> 15,2 gam Cr,0, peta v4 Ban BOs 8 593.3) AL,0, :0,1 29H m gam Al Cr:0,2 P24 2a = 0,134,223 a=0,35 V=7,841 Dap an D ‘Al Al Al:0,25 mol fr °. 292,35: Y | ALO, “5H, :0,375 = 92,35: Y4 ALO, ¢, ac Fe Fe : 0,2 Al:0,25 mol qa : 9.3780: +H,0= 2: 0,8 mol = 92,35: ¥4Al,O, :40,8 g e Fe:0,8 OoAl o bes 251 A1,0, Fe,0, Fe Phin 2: Al HH, :0,015mol — [Al:0,01 Al,O, “>, NaAlo, => 4Al,0, 2x Fe Fe:0,045 mol [Fe:0,045 Phan 1: ‘AL: 0,01 k 14,49 g 4 ALO, :xk —™25NO:0,165 mol Fe:0,045k =19,32 = 0,01k.3+0,045k.3 = 0,165.3 = k=3=9 x =0,02 => Fe,0, Dap an C Fe,0,:a a 22,3: A PALO, BH, 0,25.mol Fe > Myc; =2My +2My, = 6a+0,5 2a+3b=0,5 AICI, +b > 160a + 27b = 22,3 = 4a+3b=6a+0,5> FeCl, :2a Dap dn B Dé cho phan ting xiy ra hoan toan. Hn hgp sau phin ting nhiét nhém phan ting NaOH (du) thu duge khi H, hén hgp sau phan ting cé Al ALO, : {us Joes 7 Fe,0,: M Phin 1: 1,0, : ‘Al, : Fe MOH, :0,15 mol = 4 Fe AL Al:0,1 molDeca Phin 2: ALO, : ‘AIO; :0,1 Fe 24H, 10,35 mol {Fe:0,2 b= %m,, = 46,47% Al:0,1 mol Al:0,1 mol Dap an A 2Al+Fe,0, + Al,O, + 2Fe Fe Al e Fe,O; NeOH 21,67 5 at m0 ALO, Al 0,075 mol=» 21,67¢am{ 41:21 = x=0,075 mol 21,67gam. Bm £6.04 :0,1 Dap nD A.5,4 gam va 16 gam. zg Fe,0, :16g, ‘Al A ‘ 24 eof 5 | Hoye trl r¢0,:0ino1-92140anf 205 (ern ‘AI(NO,), :0,018 +4 Fe(NO,), :0,054 Cu(NO,), :0,018 6,102: NO, :0,018 NO:0,018 CuO :0,018 =x=0,288.1,05 = 0,3024 = ino, Dép an B 34 ALO, :a Fe,0,:a|_» Ho. 22,3 gam) tp fs] Fe:2a | 29H, :0,25 mol : Al:b=2a O1 7 My =6,38 eaten f = 30 > 2a+1,5b-3a=0,25 b Dap dn BYY —% AK(OH), :0,5 mol {i Jonata Fe,0, H, :0,15 mol Al: 0,1 mol Dap nC a |e AG Fe,0, at Fe Phan 2: Al cosmos, [41091 ALO, a [h mol _, 41,0, Fe:2,52g Fe Fe:0,045 mol Phin 1: A1:0,01k 14,49 gam 4 Al,O, ak EL +0,165 moti NO= f Fe: 0,045 k mol k=3 = a= 0,02 mol ‘Al:0,04 {r 19,32gam_ mgam J AI,0, :0,08 }=> Fe,0, Fe:0,18 mol Dap in D u37 ‘Al: 0,5 Fe,0, :0,15 fomasnae 102ak + 2,79k = 14,49 0,165k = 0,165.3 Al:0,06 mol 30,66 g xX" 5H, :0,09 mol 30,66gX:4Al,0,:a > 102a+56b= Fe:b ‘Al:0,06 mol 30,66gX:4Al,0,:a SS !_, ¥+NO:0,18 mol Fe:b ’ fens ar ase=an— [ys 29,04 Fe,0,:0,56 " —a+0,5b=0,03Seed AE*:0,3 Fe :0,3 Y NO} :1,53 NH} :0,03 sco, [AMO 03 go gg Fe(OH), :0,3 NH} :0,03, Dap an A Aas ‘AL:0,1 ater 25:4 1,0, :0,1 9H, :0,15 mol > Vy, =3,361 0,1 mol Fe,0, : Fe:0,2 Dép an D [ere P:0,3 xf Bee. gf LYE 668 eam Fe:0,1 sisi cl:1,34 $3 yg =134=2iny, +2.Mg = Ny, =0,37 mol => Vy, =8,2881 Dap an A Al # yy_uorzos , [NAAlO, 0,1 y,{Al0.0 Fe,O, :0,045 mol /H, :0,03 ALO, = 212. 100% =88,9% 0,135 Dap anC won . [NaALO, :—£% > A(OH), :0,8 mol H, :0,1 | = m=85,4g ALO, 155 > F404 0,275Fe : Feo et Joo: Fe,0, $—®°5NO:0,06 mola = Fe, 0, Al ,06 = my, =1,62.g Al 7 12,0585, [OX 105 ‘Al: 0,05 Phan 1: X—“# 5H, :0,075—+X::} ALO, : Fe /Al:0,05 — 8 5 $0, : 0,225 12,05 g X:} ALO, :0,05 }—> Fe,O, Fe:0,1 (. } toy FeO, ‘A1:0,04mol ~ Phan 1: YH,» 24 mol = ) Fe: 0,24 mol Pua ALO, :0,12 mol ‘Al: 0,04k Fe:0,24kmol_}|—! 5141, :0,9 mol = 0,04k 3+0, 24k 2 = 0,9.2 => k=3 => m=107,04g AL,O, :0,12 mol Dap an C 7 Al:b ‘Al “ ALO, 78 "oy: Cr0, C10, 26 Phan L Cr:2a Al:b AP :2a4b 1,0, : ae 20578] ysouiasma JOP"28 | 6a 3b 4da460=1,25.2 4,0, :¢ Cr"? :2¢ Cr:2a SO? 1,25 => 10a+3b+ 6c =2,5 (am) Mega book Phin 2: are AP :2a+b eae S| torent _NQ:0,5mol+4Cr* :2a+2¢) 5 6a +3-+6a+60=2,7 Aaa = Cr:2a NO; :2,7 12a+3b+6¢=2,7*93b+6a=0,5.3=1,5 12a-+3b+6¢=2,7 6a+3b+0c=1,5 [—3 10a+3b+4 60=2,5 3}—> H=—*—.100%= 50% ate Dip and > cau 46 ) Ala 11,65 sam |S Phan 1: Ar ] ‘A,0, 10,05 ieee ft 15 i165 g4Cr:0,1 AL:0,05, 1,65g4Cr > _ NaAlO, :0,15 > Al Phan 2: ALO, :0,05 11,65 g 4Cr:0,1 A1:0,05 20,15 fe O15 4 =0,65 CrCl, :0,1 Dap an D Phan 1: Al Cr,0, Phan 2: /AL:0,05 a fea 10,25 —£521,95 g Al,O, |» H, :0,075 = 21,95 g4 Al,0, at=>a=0,1 | AL AL: 0,05 Cr Cr:2a 21,95 g} ALO, :a ;-—#>, => Nyq =1,15 mol CrCl, :0,2 [Cr:2a Dip 4nBte } 2 yx, JAbOs CrO, Cr C10, Phin 2: Al /A1:0,05 ALO. Al,0. 10,975g4 7} “8 5H, 0,075 mol 10,975 g4 7 > cr Cr C10, Cr, Phan 1: Al:0,05 /Al:0,05 Al,0, 0, :0,0375 10,975g4 7 >} 5H, :0,15 mol 10,975 g4 7? Cr Cr:0,075 1,0, Cr,0, :0,0125 0.0375 __ 1 999% = 75% 0,0375+0,0125 Dap anC ‘Al ‘Al 6 gam: 2 9,66 gam ie Jew 9,66 gam: 4 ALO, Fe ‘Al: 0,02 H, :0,03 ©, = 9,66 gam :4 Al,0, :0,04 NaAlO, 2-5 Al(OH), ALO, :0,05 = Fe,0, = m=6,96 Dap 4nB en x. fa! fy sonora, [NAAlO, :0,7 _ Pal 66,9 =mz Fe,0,f7 H, :0,15 Barra eee e:0, Dap én AVang (Gold) Vang la kim loai cé mau vang khi thanh khéi, nhung khi cat nhuyén cling 6 khi co mau den, héng nggc hay tia; mém, dé udn, dé dat mong, va chiéu sang. Vang két hgp voi cdc kim loai khac sé cho ra céc hgp kim cé mau khac nhau, nhu két hop voi déng cho mau dé hon, hgp kim véi sét mau xanh la, hgp kim voi nhom cho mau tia, vai bach kim cho mau trang, Boi vang la mot chat phan xa tot voi butc xa dién tirnén no dugc dung lam lop phd bao vé cho nhiéu vé tinh nhan tao, trong cdc tm bao vé nhiét héng ngoai va mo cla céc nha du hanh vi try. NO cing dugc ding nhu Iép phan xa trén mot sé dia CD cong nghé cao. McLaren sir dyng vang 4 trong khoang dong co model F1 va minh.Dic diém bai toan nay cho s6 chat nhiéu hon s6 phuong trinh: Phutong phép gidi: Tim dac diém chung cita hop chat hiiu co dém dot dé gidm s6 chat ‘+ Dang toan cho hin hgp hidro cac bon 6 cing s6 Chote s6 H6n hop Y gém metan, etylen,va propin 6 ty kh6i so véi H, la 13,2. Dét chay hoan toan 0,15 mol hén hgp ¥ sau 46 din sin phém chay vao dung dich NaOH du thi khéilvgng binh tng thém m gam. Gid tri cha m Ia: A.16,88 gam. B.17,56 gam. C.18,64 gam. D.17,72. gam. 1 Huéng dan: cH, Hén hop ¥ gm }C,H, Nhan xét: Céc chat trong Y déu c6 4 nguyén tit H nén ta dit chung CH, cong thifela: C,H, M, =13,2.2= 26,4 C,gH, EDD 5, e H,0:2.0,15 = Dap an D Bai toan nay nhiéu chat hon gia thiét dé bai cho nhuing ta dya vao dat diém cho quy déi vé mot chat. [XIEIED Hon hop X co ti khéi so voi hidro la 21,2 gdm C,H, C,H, va C,H, Khi dét chy hoan toan 0,1 mol X, thi cn vita di V lit oxi (dktc). Gia tri cha Va (cho C=12, H =1) A. 103,04. B. 18,60. C. 10,304, D. 13,888. 1m Hung din: Nhin xét: Céc chit trong ¥ déu c6 3 nguyen tit C nén ta dit chung cong thiic la: C,H, (CO, :0,1.3=0,3 HO :0,1.3,2 =0,32 My =21,2.2=42,4-> C,H, , Snes No, =Moo, 0,46 = Vo, =10,304 Dap nCLis DANG QUY BGI VE CONG THUC CHUNG. [XRTED bot chéy hodn toin hin hop X gém: metanal, axit axetic, metyl fomat, axit lactic (CH,CH(OH)COOH) va glucozo can V lit O, (dktc). San phém thu duge hap thy hét vao dung dich Ca(OH),. Sau khi két thiic phan ting, thu duge 10 gam két tia va thdy kh6i Iugng dung dich sau phan ting ting thém 2,4 gam so v6i kh6i higng miéc v6i ban du, Gid tr} cha VIA A. 2,24, B. 4,48. C. 3,36. D112. mt Hugng din: HCHO CH,COOH HCOOCH, —> HCHO te a CH,CH(OH) - COOH ae CoHl,0, =2=0,2 mol no, =Nep, = 0,2 Vo, = 4,481 2 62a-10 = 2,4 Dap an B [XIETED 61 chéy hoan toan 4,02 gam hén hgp gém axit acrylic, vinyl axetat va metyl metacrylat 16i cho ton bé san phim chay vao binh 1 dying dung dich H,SO, dic, binh 2 duing dung dich Ba(OH), dui thay kh6i hygng binh 1 tang m gam, binh 2 xudt hién 35,46 gam két ta. Gié tri cama A.2,70. B.3,24, C234. D.3,65. m Huéng dai o, JO. :an $0, 4,02 g C,H, 0, :amol—2-. HH et H,O:aii—a=0,13 Co, M5 BaCO, :an = 0,18 mol ee +30) = 4,02 {r =0,18 > > Myo =0,13.18=2,34 g jan =0,18. a =0,05 2 Dap an C00 DANG QUY 861 DUA VAO TILE MOL Dét chay hoan toan 10,33 gam hén hgp X gém axit acrylic, axit adipic, axit propanoic va ancol etylic (trong dé s6 mol axit acrylic bing s6 mol axit propanoic) thu dugc hn hgp khi va hoi ¥. Dn ¥ vao 3,5 lit dung dich Ca(OH)20,1M thu duge 27 gam két tia va nude loc Z. Dun néng nuéc loc Z lai thu dug két tia, Néu cho 10,33 gam hén hgp X 6 trén tc dung véi 100 ml dung dich KOH 1,2M, sau phan ting c6 can dung dich thi thu duoc khéi lutong chét ran la 13,76 B.1277 €.12,21 D.10,12 & Huéng dan: CH, =CH-COOH:a HOOC ~(CH,),-COOH HOOC-(CH,), ~COOH: cepa (CH), © 510,33 gam [HOOC-(CH,), ~ COOH:a CH, ~CH, -COOH:a H,OH:b C,H,OH ‘CaCO, :0,27 mol Ca(HCO,), :0,08 10,33 gam [HOOC~(CH,), ~ COOH: CO, cxowyoasmot C,H,OH:b H,O 146a+46b = 10,33 ).27+0,08.2= 0,4 = Neo, = 0,27+0,08.2=0, = eee -{ 10,33 gam {HOOC=(CH,), COOH: 0,055 pox szm_, [ROOC~(CH,), ~ COOK :0,055 C,H,OH:b KOH:0,01 m = 222.0,055+0,01.56 =12,77 g Dap én B [XIEIED bit chay hn hgp X gém glixerol, metan, ancol etylic va axit no, don chifc mach ho Y (trong dé s6 mol metan gép 2 lan s6 mol glixerol) cn viia dit 1,525 mol O, thu digc 1,55 mol CO,, Nu cho m gam hén hgp X téc dung v6i 400 ml dung dich NaOH 2,5M, r6i cé can thi thu dugc m gam chat rn khan, Gid tri m gan ahdt v6i gid tri ndo dudi day? A. 76, B. 80. C.62. D.70. 1 Huéng dan: C\H,(OH), : CH, :2a CyHames0 2X rose 0, fls55 mol CO, x —Etsimat Os C,H,OH C,H,,0,:¥ H,O:1,55+x [C,H2,02 = x+2y+3,05 =3,141,55+x = y=0,8 mol Néu cho m gam hén hgp X téc dung véi 400 ml dung dich NaOH 2,5Mecg C,Hag sO, —>mC0, +(m+1)H,0 x———> 1, 5mx——> mx 1,5mx +1,2n-0.8 = 1,525 > = 0,8 < 155 2-2, 1CO, +n#,0 mx +0,8n =1,55 0,8 ——1, 2n -0,8 —>n C,H,,0; + n<1,9375=>n=1 Cy Han420 : eHagnO!% _yanimt yng [HOOONA:O8 6s gg HCOOH :0,8 NaOH: 0,2 Dap anc GD eartar ren vuven Hin hgp khi X gém etilen, metan, propin va vinylaxetilen o6 ti khi so v6i H, 18 17. Bat chay hoan toan 0,05 mol hén hgp X réi hap thy to’n bd sin phém chéy véo binh dung dich Ca(OH), (du) thi khi long binh tang thém m gam. Gia tri cia m la A.66. B.585. C73. D.3,39. H6n hop X g6m vinylaxetilen, eten va propin cé ti khdi so vdi hidro bing 17. Dét chay hoan toan mét ligng X thu duge CO, vi 3,6 gam H,O. Néu din toan bé sin pham chéy qua dung dich Ca(OH), dv thi thu duge m gam két ta, Gid tri cia m 1a A.12,5 gam B.25 gam C. 37,5 gam D.50 gam [XETED Hin hop X g6m: C,H, C,H, C,H, c6 ti khéi so vdi H, [8 14,25. Dét chy hodn toan 11,4 gam X, cho sin phim vio binh dying dd Ca(OH), du théy kh6i higng binh tng m gam. tricha ml: A624 B. 73,12 C. 68,50 D514 Hén hop X g6m propin, propan va propilen cé ti khéi so véi hidro la 21,2. Dot chay hoan toan 15,9 gam X, sau dé hip thy toin bd sin phim vao binh dung 1 Iit dung dich Ba(OH), 0,8M thay kh6i higng binh ting m gam va cé a gam két ta, Gia tri cia m va a lan lugt li: A. 71,1 gam vi 93,575 gam B,71,1 gam va 73,875 gam C. 424 gam vi 63,04 gam D. 42,4 gam va 157,6 gam Hén hgp X gém: CH, C,H, CH, C,H, C,H, Ty khéi cita X so voi H, la 27. Dot chay +hoan toan X, cin ding vita di V lit O, (dktc), thu duigc CO, va 0,03 mol HO. Gid tri cia V la: A. 1,232. B. 2,464. C. 3,696. H6n hop X gém metan, axetilen va propen cé ti khéi so véi H, lA 13,1. Dot ch4y hoan ton 0,2 mol hén hgp X sau dé dan sin phdm chay vao binh chita dung dich Ca(OH), duthi thu duge 38 gam két tha tring va khéi lugng binh ting thém m gam. Gid tri ca m 1a A.21,72.gam B.22,84 gam C.16,72 gam. D. 16,88 gam Hn hgp Y gém metan, etylen.va propin c6 tf khéi so v6i H, la 13,2, Dét chay hoan toan 0,15 mol hn hgp ¥ sau dé din sin phém chay vao dung dich NaOH du thi Khoi Iiong binh tang thém m gam. Gié tri cia m lis A.16,88 gam. B.17,56 gam, C.18,64 gam. D.17,72. gam. [HEED Hin hop X gm metyl acrylat, vinyl axetat, buta-1,3-dien va vinyl axetilen. Dét chay hhoan toan 0,5 mol hn hop X bing 54,88 lit khi O, (dtc, vita di), thu duige khi CO, va 2344 gam H,O. Phan tram khdi higng cita vinyl axetilen trong X IA A.31,52%. B, 30.50%. C.21,55%. D. 33,35%. [XELED dit chay hoan toan m gam hén hop X gém ancol etylic, glixerol, metan va axit cacboxylic no, don chtéc, mach hd ¥ (trong dé s6 mol cita metan gip hai lén s6 mol cia glixerol) cin ding viia dai 0,65 mol O,, thu due 0,7 mol CO, Néu cho m gam X phan ting véi dung dich KOH di thi kh6i lugng mudi thu duige la A.33,6g, B.27,2g. C. 44,88. D.39,2g, LEME Hin hop X gém CH,COOH; C,H,COOH; HOOC-CH,-COOH. Bé trung hoa hoan toan m gam X cn ding 480ml dung dich NaOH 1M. Mat khéc d6t chéy hoan toan m gam X thi thu duigc 43,12 gam CO, va 15,48 gam nutéc. Gid tri cia m Ia: A.20,14 gam B. 26,52 gam C. 12,68 gam D. 28,84 gam Cho m gam hén hop X gém CH,=CH-CHO, HCHO, C,H,CHO va OHC-CHO phan ting véi higng du dung dich AgNO,/NH, thu duge 38,88 gam Ag. Mat khéc, dét chéy hoan toin m gam hén hgp X thu duigc 0,28 mol CO, va 0,22 mol HO. Gis tr) 6 thé c6 cia m fa A.7,32 B.7.64 6.636 D.6,68. ED Hon hop X gémetilen, metan, propin, vinyl axetilen cé ti khéi so vi H, 18 17,6. D6t chay hoan toan 7,04 gam hén hgp X 16i hap thy sin phém chay vio dung dich Ca(OH), du thi kh6i lugng binh ting thém m gam. Gis tri cha m la: A.30,08 B.33,68 C..24,80 D_ 33,60 Cho hén hop X gém C,H,COOH, C,H,(NH,),, HO-CH,-CH=CH-CH,OH. Dét chay hoan toan m gam hén hop X réi dan sin phém chay cho hap thy hoan toan vio dung dich Ca(OH), thay tgo ra 20 gam két tia va dung dich Y. Dun ndng dung dich Y thay xuat hién két tia. CO can dung dich ¥ r6i nung chit rin dén kh6i ligng khng d6i r6i dem can thi thay c&n duige 5,6 gam. Gis tri cia m Ia A.54. B.7,2. C.8,2. D.88. ‘Dét chay hoan toan 29,2 gam hén hgp X gém andehit acrylic, metyl axetat, andehit axetic sak y yt vaetylen glicol thu duigc 1,15 mol CO, va 23,4 gam HO. Mat khdc, khi cho 36,5 gam hén hopX trén téc dung hét véi dung dich AgNO, trong NH, thi thu duigc t6i da m gam Ag. Gid tri gén abit cia mia A435. B. 64,8. €.53,9. D.81,9. Hén hop X gém etanol, propan--ol, butan-1-ol, pentan-1-ol. Oxi héa khong hoan toan mét luigng X bang CuO nung néng, sau mot thoi gian thu dugc H,O va hén hop Y gém_ 4andebit tuang ting va 4 ancol du, Dét chay hodn toda Y cén diing vila di 1,875 mol O,, thu duge thu duge 1,35 mol khi CO, vi H,O. Mat khéc, cho toin b6 lugng ¥ trén phan ting véi lugng dui dung dich AgNO, trong NH, dun néng. Sau khi cde phan ting xay ra hoan toan, thu duige m gam Ag. Gié tri ciia m la: A648 B.27,0 C324 D.43,2 Cho hén hgp X gém HCHO, CH,COOH, HCOOCH,, CH,CH(OH)COOH va glucozo. Dé6t chy hodn to’n m gam hin hgp X cén V Iit O, (dktc). Ton bg sin phim chéy duige hip thy vao binh Ca(OH), du thay khéi lugng dung dich gidm 15,2 gam. Gid tri cia m la: A. 16 gam B,18 gam C.20 gam D.12gam Hén hop X gém axit fomic, axit acrylic, axit oxalic va axit axetic. Cho m gam X phan ting hét véi dung dich NaHCO, thu duige 1,568 lit CO, (dete). Bét chdy hoan toan m gam X cén V lit O, (dict), thu duige 5,72. gam CO, va 1,8 gam H,O. Gié tri cha V la A.2,688 it, B. 2,016 lit. C. 2,464 Lit. D.2912 lt, Dét chay hén hgp X gém glixerol, metan, ancol etylic va axit no, don chttc mach hé Y (trong dé 6 mol glixerol bang % s6 mol metan) cfn vita dit 0,41 mol O, thu duigc 0,54 mol CO, Néu cho m gam hén hgp X téc dung véi 200 ml dung dich KOH 1,5M, r6i c6 can thi thu duge mt gam chat rin khan. Gid tri m’ gan nit voi gid tri nao dudi day? A.25. B.33. C.3L D.29, Dét chay hoan toan 43,1 ghén hop X gém axit axetic, glyxin, alanin va axit glutamic thu duige 32,36 lit CO, & dktc va 26,1g nuvéc. Mit khéc cho 43,1 gam hén hgp X téc dung vita di 300 ml HCI 1M. Néu cho 21,55 gam hén hgp X tac dung véi 350 ml dung dich NaOH 1M thu duge dung dich Y. Cé can dung dich Y thu duge m gam chit rin khan, biét phan ting xy ra hoan toan. Gid tri cba m? A.12,69 B.24,17 C.34,5 D30,15 [XEQZD it chay hoan toan m gam hén hgp X gém CH,OH, CH,CHO va C,H,CHO cn ding viia dit 0,6 mol O,, sinh ra 0,45 mol CO,, Néu cho m gam X trén phan ting véi lugng du dung dich AgNO, trong NH, thi khi két thiic céc phan ting, kh6i luong Ag thu duigc ka A. 43,2 gam. B, 16,2 gam. C.27,0 gam. D.32,4 gam. [ZEDED dit chay hoan toan 24,4 gam hén hop X gém C,H, CH, CH, CH,CHO, CH,=CH- CHO cén vita i 49,28 lit khi O, (dktc), sau phan ting thu duge 28,8 gam H,O. Mat khac, lay al m Mega book TE 2099900000009000000000000000000009toin b6 Ittgng X trén syec vio dung dich AgNO,/NH, du, dun néng thay xudt hién m gam két tita (cée phan ting xay ra hoan toan). Gid tri ctia m la A.32,4 gam. B.21,6 gam. C.54,0 gam, D. 43,2 gam. Hén hgp X gém andehit axetic, axit butiric, etilen glicol va axit axetic trong dé axit axetic chiém 27,13% khéi higng hén hgp. Dét 15,48 gam hn hgp X thu duge V lit CO, (dtktc) va 11,88 gam H,O. Hap thy V lit CO, (dkte) vio 400ml dd NaOH x mol/| thu duge dd Y chtta 54,28 gam chat tan. Gid tri cia x la: A24 B.S C.20 D.18 Hon hgp X gém C,H,OH; HCHO; CH,COOH; HCOOCH, CH,COOCH; CH,OHCH(OH)CHO; CH,CH(OH)COOH. Dét chay hoan toan 19,4g hén hgp X cén vita i 32g oxi, sau phan ting thu duge 0,9 mol HO. Tinh % theo khéi lugng cia CH,COOC,H, trong hén hgp X? A45,36% B, 43,05% C. 46,62% DS52,13% ‘Hon hgp (X) gém ancol metylic, etan, glyxerol (mol cita etan gap 46i mol glyxerol). Hén hop (¥) gém axit axetic, axit metacrylic va axit adipic (mol axit axetic bing mol axit metacrylic). Hen hgp (Z) gdm O, va O, 06 ti khdi so vdi H, la 19,68. Bot chdy hoan toan hén hop (T) gom m gam (X) van gam (¥) cn 1 mol (Z) thu dug 1,02 mol CO,, Mat khéc dem n gam (Y) tée ung hét v6i NaHCO, du thu duige V lit khi CO, do 6 dite, Gid tr} cha Vk A.5,376 lit B. 11,872 lit C.6,73 lit Dz 13,44 lit Hin hop khi va hoi X g6m C,H, CH,CHO, CH,COOH. Tron X véi V lit H, (dkte), r6i cho qua Ni, dét néng thu dugc hén hyp Y (gm Khi va hai), D6t chay hoan toan ¥ thu duge 0,15 mol CO, va 0,2 mol H,O. Gi tri cha V 1a A. 1,12. B. 2,24. C448, D..0,672. ED dn hyp X cé C,H,OH, C,H,COOH, CH,CHO trong dé C,H,OH chiém 50% theo s6 mol. Dét chdy m gam hén hgp X thu duige 3,06g HO va 3,136 lit CO, (dktc. Mat khac 13,2 gam hén hop X thuc hign phan ting trang bac thay cé a gam Ag két tha, Gid tri cia ala A108. B.2,16. 9,72. D.8,64. Dét chay hoan to’n 23,8 gam hén hgp X gém axit acrylic, axit adipic, axit propanoic va alyxerol(trong dé s6 mol axit acrylic bing s6 mol axit propanoic) bing oxi dui thu duigc hin hop Y gom khi-va hoi, Din Y vao dung dich chtta 0,7 mol Ba(OH)2 thu duge 98,5 gam ket tia va dung dich Z. Dun néng Z lai thay xuat hién két tia. Cho 23,8 gam X tc dung véi 300 ml dung dich KOH 1M, sau phan ting xy ra hoan toan, c6 can dung dich thu duige chat ran khan 6 Kh6i long la A.15,8 gam B. 27,8 gam C. 16,6 gam D. 30,8 gam Hon hgp X gm axit fomic, axit acrylic, axit oxalic va axit axetic, Cho m gam X phan ting hét véi dung dich NaHCO, thu duige 1,344 lit CO, (dktc). Dét chay hoan ton m gam X cin 2,016 lit O, (Aktc), thu duige 4,84 gam CO, va a gam H,O. Gid trj cia a lb ALA B. 1,62. C.3,60, D. 1,80,ee ds '9090000000000000000000000000000009 Hén hgp X gém 2 ancol CH,OH, C,H,OH ¢6 cling s6 mol va 2 axit C,H,COOH va HOOC|CHL,],COOH. Dét chay hoan toan 1,86 gam X cn ding vita dit 10,08 lit khéng khi (dktc, 20% O, vi 80% NY, theo thé tich) thu dig hén hgp Y gém khi va hei. Din ¥ qua nuiéc voi trong du, sau khi cc phan ting m gin nat v6i gid tri A. 2,75. B. 2,25, C.3,75 D. 4,25. y ra hoan toan thay khéi lugng dung dich gidm m gam, D6t chéy hoan toan 26,72 gam hén hgp X gém axit metacrylic, axit adipic, axit axetic va glixerol (trong 46 s6 mol axit metacrylic bing s6 mol axit axetic) bing O, du, thu duge hon hgp Y gém khi va hoi. Dan Y yao dung dich chiia 0,76 mol Ba(OH),. thu dugc 98,5 gam két tia va dung dich Z, Dun néng Z lai xudt hign két tia. Cho 26,72 gam hdn hgp X téc dung véi 140 ml dung dich KOH 2M, sau khi cdc phan ting xy ra hoan to’n, c6 can dung dich thu duge chat rn khan c6 khéi lugng gan gid tri nao sau day? A. 26,2 gam B.24,7 gam C.28,9 gam D. 30,1 gam Hén hop X gm etan, propen, benzen va axit propanoic, Dét chdy hoan toan m gam X dn 4,592 lit O, (dktc). Cho toan bd sin phém chay vio 100 ml dung dich Ca(OH), 1M thu dude 5 gam két tia va khéi luigng dung dich ting 4,3 gam, Dun néng dung dich thay xudt hién thém két tia, Phan trim khdi lutgng cia axit propanoic trong X La A. 36,21%. B. 45,99%, C.63,79%. D,54,01%. [XETELD 16+ chay hoan toan m gam hén hgp X gém glixerol, metan, ancol etylic va axit cacboxylic no, dan chtic mach ha ¥ (trong dé s6 mol glixerol bing 1/2 s6 mol metan) cn 0,41 mol O,, thu duigc 0,54 mol CO, Cho m gam X téc dung véi dung dich KOH du thi higng muéi thu diige 1 A.39,2.gam. B.27,2 gam. C.33,6 gam, D. 42,0 gam. ‘Dét chay a gam h6n hgp X gém glixerol, metan, ancol etylic va axit no, don chite mach baY (trong dé s6 mol metan gp 2 Han s6 mol glixerol) can vita dit 1,525 mol O, thu duige 1,55 mol CO, Néu cho a gam hén hgp X téc dung vi 400 ml dung dich NaOH 2,5M, r6i c6 can thi thu dufgc m gam chét rén khan. Gid tri m gén nhét v6i gid tri ndo duidi day? A. 80. B. 64. C.70. D.76. Hon hgp X cé C,H,OH, C,H,COOH, CH,CHO trong 46 C,H,OH chiém 50% theo sé mol. Dét ch4y m gam hén hgp X thu duge 3,06 gam H,0 va 3,136 lit CO, (dktc). Mat khac 13,2 gam hén hgp X thyc hién phan ting trang bac thay c6 p gam Ag két tta, Gia tri cha p la A. 2,16. B. 8,64. C.9,72. D. 10,8. Hon hgp X gém C,H,, CHO, C,H,, COOH, C,H,, ,CH,OH (déu mach hé, n ¢ N*). Cho 2,8 gam X phan (ing vita di 8,8 gam brom trong midc. Mit khéc, cho toin bd Iuigng X trén phan ving v6i luigng du dung dich AgNO, trong NH,, két thic phan ting thu duige 2,16 gam Ag. Phan trim kh6i lugng cia C,H,, ,CHO trong X 18 A. 20,00%. B. 26,63%. C.16,42%. D. 22,2296. alHén hop X g6m propan, etylen glicol va m6t s6 ancol no dan chiic mach hé (trong d6 propan va etylen glicol cé sé mol bang nhau). Dét chay hodn toin 5,444 gam X r6i hap thy toan bé sin phim chdy vio binh dying dung dich Ba(OH), du théy khi luigng binh tang lén 16,58 gam va xuét hign m gam két tiia trong bin, Gié tri ciia m gin véi gid tri nao sau day nhat? A. 45,70. B. 42,15. C. 43,90. D.47,47. Xi hén hgp gém HOOC-COOH, OHC-COOH, OHC-C=C-CHO, OHC-C=C-COOH; Ylaaxit cacboxylic no, dan chitc, mach hd. Dun néng m gam X véi higng du dung dich AgNO, trong NH,, thu duge 23,76 gam Ag. Néu cho m gam X téc dung véi NaHCO, dui thi thu duge 0,07 mol CO,, Dét chay hoan toan hn hgp gdm m gam X vam gam ¥ cén 0,805 mol O,, thu duige 0,785 mol CO, Gié tri ciia m a A88. B46. C.60. D.7,4. Hén hop X gém C,H,OH, HCHO, CH,COOH,HCOOCH, CH,COOGH, (CH,OHCH(OH)CHO va CH,CH(OH)COOH. Dét chay. ‘hoan toan 13,8 gam X cin dung vita ii 12,04 lit O, (dktc), thu duge CO, va 9 gam H,O. Thanh phin phin trim theo khdi ligng cia CH,COOC,H, trong X18 A. 15,58% B. 12,46% C.31,16% D.24,92% H6n hgp M gm 4 axit cacboxylic. Cho m gam M phan ting hét v6i dung dich NaHCO, thu duge 0,1 mol CO,, Dét chay hoan toan m gam M cén diing vita dit 0,09 mol O, sinh ra 0,14 mol CO,. Gid tri ctam I A.5,26. B. 5,80. C348. D.5,08. Hén hgp X gém ancol propylic, ancol metylic, etylen glicol, glixerol, sobitol. Khi cho m(g) X tc dung voi Na du thi thu duige 5,6 kit H, (dktc). Néu dét chy m (g) X cAn viva dit 25,76 lit Kh{ O, (dt), sau phan ting thu duge 21,6g H,O. Phan trim Kh6i ligng cita ancol propylic ¢6 trong hén hop X ki A. 50% BL 45% C. 67.5% D, 30% Chia 10,3g hén hgp gém HCOOCH,CH,OH; HCOOCH,; HOC,H,OH thanh 2 phin bang nhau, Dét chdy Phin 1 can 4,088 lit O,(dkte), dn toan b6 sin phém chay vao 1 lit dung dich Ba(OH), 0,15M théy dung dich giam 14,62g. Cho Phén 2 tic dung véi Cu(OH), 6 diéu kign thuding, Khéi luong Cu(OH), bj hoa tan 6 Phan 2 la: A 4,165g B. 1,225g C.2,450g D.7,105g ‘Dot chdy hoan toin 0,1 mol hén hgp X gm etan , propan , propilen , axetilen thu duge 6 mol H,0 it hon s6 mol CO, 18 0,02 mol. Mat khéc 0,1 mol X c6 thé im mat mau t6i da m gam dung dich Br, 16%. Gid tri cia m la: A. 180 B.120 C. 100 D.60 Hn hgp X gém CH,OH; CH,COOH; HCHO trong dé CH,OH chiém 40% sé mol. Dét chy hoan ton m gam hdn hgp X thu duige 1,512 g H,O va 1,4336 lit CO, (dktc): ChoCu(OH), du tic dung véi 4,9g hdn hgp X 6 diéu Cu(OH), tham gia phan ting géin nhét voi gid tri: A.1,70 B, 2,50 €.9,60 D.17,40 én thuéng.. sau phn ting hoan toan s6 gam, Hén hop X gém metyl fomat, andehit acrylic va axit metacrylic. Dét chéy hoan to’n m gam X 16i hap thy hét sin phim chdy vao 70 ml dung dich Ca(OH), 1M, thu duige 5 gam két tia va khéi higng phan dung dich tang thém 0,22 gam, Gid tri cham la A. 1,54. B. 2,02, C.1,95. D. 1,22. [XEEED Hon hop X chia Shop chat hau co no, mach hé, cé sé mol bang nhau (trong phan tit chi Pp Pp a ng Pl chita nom chite ~CHO hoac COOH). Chia X thanh 4 phan bing nhau: - Phan 1: ic dung vita dit 0,896 lit H, & (dktc) trong Ni, *. - Phan 2: tac dung vita di: 400 ml dung dich NaOH 0,1M. - Dét chay hodn toan phan 3 thu dude 3,52 gam CO,. - Phan 4 tac dung véi AgNO, du trong NH, dun néng én phan ting hoan to’n thu duige m gam Ag. Gid tr) clam i: A. 17,28. B. 8,64. C. 108. D. 12,96. ED Hin hop X gsm HCHO, HCOOCH, va CH,CH(OH)COOH. Dét chay hoan toan m gam X cin V lit O, (dktc), hép thy hét san phém chay vao mudc v6i trong dut thu duige 50 gam két tia. Gid tri cha Va A, 10,08. B. 11,20. C.8,96, D. 13,44. Dét chéy ho’n toan 13,36 gam hén hgp X gém axit metacrylic, axit adipic, axit axetic va glixerol (trong dé s6 mol axit metacrylic bang sé mol axit axetic) bang O, du, thu dugc hin hgp Y gm Khi va hoi. Dan Y vao dung dich chifa 0,38 mol Ba(OH),, thu duge 49,25 gam két tiha va dung dich Z. Dun néng Z lai xudt hign két tia. Cho 13,36 gam hén hop X tic dung vi 140 ml dung dich KOH 1M, sau khi céc phan ting xdy ra hoan toan, o6 can dung dich thu duge chat ran khan c6 khdi luigng la A. 19,04 g B. 18,68 g C14ddg D.1332g Cho 27,1 gam hn hgp X gm axit fomic, axit glutamic, glyxin, axetilen, stiren tac dung, t6i da vdi 150 ml dung dich NaOH 2,0M. Néu dét chéy hoan toan 27,1 gam hén hop X trén ngugi ta cin ding x mol O, thu duigc 15,3 gam HO va y mol khi CO, Tong x+y la: A. 3,275. B. 2,525. C. 2,950. D. 2,775. Hén hgp X gm etilen, metan, propin, vinyl axetilen cé ti khéi so véi H, la 17. Dét chay hoan toin 5,1 gam hon hgp X réi hap thy sin phim chéy vio dung dich Ca(OH), du thi khot Iigng binh tang thém m gam. Gié tri ctia m la: AL 25,5 B.20,1 C.18,3 D.21,9 Ea(XEQED dot chay hon hop X gém etylen glycol, metan, ancol etylic va axit no, don chife mach hg Y (trong dé s6 mol etylen glycol bing s6 mol metan) cén vita dit 0,7625 mol O, thu duige 0,775 mol CO, Néu cho m gam hn hop X tac dung véi 200ml dung dich NaOH 2,5M, ri ¢6 can thi thu duge x gam chat rin khan, Gia tri m gén nhat véi gia tr] nao duidi day? A38, B35 C32, D.40. Cho hén hop X gém C,H,OH, HCHO, CH,COOH, HCOOCH, CH,COOCH, (CH,(OH)CH(OH)-CHO, CH,(OH)CH,COOH. Dét chay hoan toan 13,8 gam X cén 12,04 it kh O, (dktc), thu duige CO, va 9 gam nuiéc. Phin trim theo khéi hing cia CH,COOCH, trong X 1a A. 17,68% B.12,45% C.19,24% D.15,58% [XEDED Hon hop X gémancol metylic, etylen glycol va glixerol. Cho 21,6 gam X phan ting hoan todn v6i Na du, thu duige 7,84 lit khi H2 (dktc) va hén hop muéi X. Dot chay hoan toan 21,6 gam X, r6i théi sin phém chay qua binh chia CuSO, khan du, khi két thc thi nghiém khéi Iugng binh nay tang? A. 30,0 gam. B. 18,0 gam. C. 16,0 gam. D.9,0 gam, Hén hop X gm CH,COOC,H, C,H,COOCH, va C,H,OH. Dét chéy hoan toan m gam hén hgp X thu duigc 0,6 mol CO, va 0,7 mol H,O. Thanh phan phan tram vé khéi long ciia C,H,OH trong X la A, 20,72%. B,50,00%, C. 34.33%, D.51,11%. Hn hgp X gém hai cht hitu co mach hé (déu chuia C, H, ©) trong phan tli mBi chat ¢6 hai nhém trong s6 céc nhém ~CHO, -CH,OH, -COOH, Dét chéy hoan toin 17,1 gam X thu duige 11,2 lit CO, (dktc) va m gam HO. Cho 17,1 gam X téc dung hét véi Na du, thu duge 2,8 lit H, (dktc). Mat khéc, cho 17,1 gam X phan ting hoan toan véi lugng du dung dich AgNO, trong NH, thu dug 54 gam Ag, Gid trj cha m 1a A45. B. 6,3. C.9,0, D. 12,6. D6t chéy hoan toan 26,72 gam hén hgp X g6m axit metacrylic, axit adipic, axit axetic va glixerol (trong d6 s6 mol axit metacrylic bing s6 mol axit axetic) bang O, du, thu dtigc hén hop Y gém khi va hoi. Dan Y vao dung dich chifa 0,76 mol Ba(OH), , thu duge 98,5 gam két tia va dung dich Z. Dun néng Z lai xuat hign két tia, Cho 26,72 gam hén hgp X téc dung voi 140 ml dung dich KOH 2M, sau khi cfc phan ting xay ra hon todn, c6 can dung dich thu duige chat rén khan c6 kkh6i huigng la ‘A. 19,04 gam B, 28,88 gam . 18,68 gam D. 13,32 gam [XEZED Hon hop X gém 2 ancol CH,OH, C,H,OH c6 cing s6 mol va 2 axit C,H,COOH va HOOC[CH,], COOH, Dat chay hoan toan 5,58 gam X can diing vita dit 6,048 lit oxi (dktc) thu dugc hin hgp ¥ gém khi va hai. Dan Y qua nuiéc véi trong du, sau khi céc phan ting xiy ra hoan toan thay khéi liong dung dich gidm m gam. m gin nhit véi gid tri nao duidi day? A.12,75, B.8,25. ©.675, D.11,25.Mega book Hén hgp X gém hidro, propen, axit acrylic, ancol anlylic (C,H,OH). Dét chay hoan toan 0,75mol X thu duige 30,24 lit CO, & dktc. Dun néng X véi Ni sau mét thé gian thu duige hn, hop Y ¢6 ti Khéi so vi X 18 1,25. Cho 0,1 mol ¥ phan ting vita dit véi V lit dung dich Br, 0,1M. Gig tei cha Va A.03. B.06. C04, DOS. Hén hop X gém etan, propen, benzen va axit propanoic, Dét chay hoan to’n m gam X clin 4,592 lit O, (dktc). Cho to’n b@ sin phém chéy vio 100 ml dung djch Ca(OH), 1M thu duigc 5 gam kéttiia va khoi lugng dung dich tang 4,3 gam. Dun néng dung dich thay xust hign them két tia. Phan trim kh6i long cia axit propanoic trong X 1a A, 36,21%. B, 45,99%. C. 63,79%. D.54,01%. [XETEED st chay hoan toan 5,6 lit hén hop khi X gém etilen, propin va vinylaxetilen, thu dug 14,56 lit khi CO, Ciing 5,6 lit hén hop X lam mit mau dung dich chita t6i dam gam brom. Céc thé tich Khi do 6 dktc, Gid tej cia ma A. 104. B72. C64, D.32. Dét chay hoan toan hén hop X gém: metanal, axit axetic, metyl fomat, axit lactic (CH,CH(OH)COOH) va glucozd cén V lit O, (dktc). San phdim thu duigc hap thu hét vao dung dich Ca(OH), Sau khi két thiic phan ting, thu duige 10 gam két tia va thay khéi luong dung dich sau phan ting tang thém 2,4 gam so véi khéi lugng mide v6i ban dau. Gia tri cita VLA A224. B.448. €.3;36, D112. Bp none An: han xét; Céc chat trong Y déu o6 4 nguyén tit H nén ta dit chung cong thie i: C,H, CO, :0,05.2,5 = 0,125 M, =17.2=343 C,H, SMe 2 0, | H,0:0,05.2=0,1 M= Meo, +My =73E Dap anc ED Nhan xét: Céc chat trong Y déu c6 4 nguyén tii H nén ta dat chung cing thitc la: C,H, (CO, :8.2,5 Hy A Neco, = Neo, = 2,58 =0,25= Meco, = 25.8 My =17.2=34 > amol C,H, "> Dap an B E> Chi: Céc chat c6 trong X du c6 2 nguyén tit céc bon. me =0,8.12 = 9,6 > noo, = 0,8 4 ng = 0,8 11,4 gam : oo ma STAgam My = 1,8 > Ny =O! Rx Dap in DDéy thay céc chat trong X déu c6 3 C trong phan tit va My = 42,4 > X:C,Hy, Noo, = 1,125 (mol) 3753 1 — Am T= 1,125.44+1,2.18= 71,1 (gam) yo =1,2(mal) Van, =1,6(mol) >n,... =1,6-1,125 = 0,457 <0,8 > a =0,475.197 =93,575 (gam) Dap an A xe ,25 (mol) 0,2 (mol) Ol, :a( mol) grasare , [712 +320=37, 05-48-81 |O, :b (mol) 2a+4b=0,2.2+0,3.3 ___0,25.71 0,25.71+0,2.32 3 %ma, 100% =73,5% > %m,, =26,5% My =26,2 —>CygHy, EE nyo = 0,34 (mol) — Am = 0,38.44 + 0,34,18 = 22,84 (gam) Dap an B Nh§n xét: Cac cht trong ¥ déu oé 4 nguyén tit Hf nén ta dt chung cong thic Ia: C,H, 28 vy, —somcan_, [60,201535 3 m=17,72 H,0:2.0,15=0,3 Nhén xét: Hén hgp céc chit 6 dac diém chung la 4 C Noo, =4iny, =4.0,5=2 CHO, - dc diém chung thit hai la ba chat | C/H_O, | 06 2 lién két bi ~ C,H, ¢6 ba lien két bi Cie C\H0. HO, oysssna feos:tma c, 0,5 mol X, Heel, H,0:1,3 mol “aH, CH,eels CHO, 0.5 motx/| CosO: pmol [arb=05 _ fa=0.3 _ a ), 5 mol => Yor = % CH, a+2b=0,7 "|b 2 Meat, = 21 C\H,:b Dp an A han xét: Trong hén hgp X s6 mol cia metan gp hai lan s6 mol cita glixerol. Quy 4éi hén hgp thanh ancol no don chifc va axit no don chiic. C,H,(OH), :a xc] CHa228 eo ,JOnHan2O:% oem, [0,7 mol CO, C,H.OH C,H,,0;:¥ H,0:0,7+x CyH;,02 PEO 4 x 42y41,351,44+0,7+x = y=0,4 mol C,H,_,,0+ 20, — m0, + (m+1)H,0 x—— 1, Smx —>mx C\H,,0, +820, no, +nH,O => {mx+0,4n =0,7 0,4 <0,7 0,4 0, 6n -0,4 9, 4n n< 1,759 n=1=9 HCOOK :0,4 = Mycooe =33,6 8 Dap in A at (CH,COOH ‘COOH: 0,48 mol mgX4C,H,COOH motos! ym gX Cx HOOC-CH, -COOH Hey COOH :0,48 mol fee CO, :0,98_ (—%L>x =0,5 mol mgX\C:x ae > = m=28 84 = H,0:0,86 [#5 =1,24 mol . Hey Dap an D ut CH, =CH-CHO| HCHO HCHO Aa Ag :0,36 mol = 0,09 < Neyo < 0,18 0,09 < ng <0,18 OHC-CHOCH, =C HCHO C,H,CHO ‘H-CHO. OHC-—CHO Dap anc C,H, cH, “|CH, CH, x De, = 0s Dap an iu 13 SCH: 2 noi ‘CH,COOH X:4 C,H, (NH,), HO-CH, ~CH = CH-CH,OH Ca(HCO,), “CaCO, — +Ca0:0,1 mol => CO, :0,4 mol CO, :0,52 H,0:0,4 CHO:b > $35,259 X=2,6C,,H, S H,O a 36, 5gamX { ny 41-9 my =88.01=8,8 Dap an D (CH, =CH-CHO CH,COOCH, 29,2gX CH,CHO |C,H,0, H.0 29,2. x1] OHO: [_, [Sots CHO CHO; CH, =CH-CHO 36, seamx ;|CHCOOCH, Seam“ CH,CHO CHO, Dap nC con, (se elon, - Moo, + My,o = 30,08 g 20,2 Ca(HCO,), : C:1,15 mol On eh15 29,2 gX:1H:2,6 mol = H,0:1,3mol ® “ome (00,8 mol {i 0,3 = HO, :0,375 C,H,0:0,25 ‘AgNO, tong Ni 10,44 = 5,24 my = 6,36 Ag:0,5bd ‘C,H,OH CHOW C,H,OH C.H,,OH CyHaas29 22 oy CH; q0:b (C,H,,;CH,OH :a C,Ha,.4CHO:b —>{C,H,,,,CH,OH wf C,H,.20 +1,5n0, —>nCO, +(n+1)H,O a———1,San—an C,H,,0 + (1,5m-0,5)0, —>mCO, +mH,0 b——1, 5bm—0,56 sam 2,4 g ‘an-bam =1,35 1,5an +1,Sam—0,5b=1,875 =>b=03>n,, Dap an HCHO CH,COOH 9, }CO, +8 caiow, HCOOCH, 9H, 0—24{ an, CH,CH (OH)COOH 1,0: CHO. 100a—62a =15,2 > a=0,4 mol => my =a.30=0,4.30=12 6 yg Dap an D ni HCOOH CH2 =CH-COOH (Coon), CH,COOH ‘COOH :0,07 CO, :0,07 mol >| C H ‘COOH :0,07 mg] C:0,06 H:113 1g, =0,11 mol => Vo, 50, :0,13 ° fre , a = H,0:0,1 Dap an ‘Nhan xét: trong hén hop X s6 mol ciia metan gap hai ln s6 mol cita glixerol, quy 46i hn hop thanh ancol no dan chtic va axit no don chite. alC,H,(OH); :@ CH, :2a CHa s20 2X 10,_, [0,54 mol CO, C,H,OH C,H,,0,:¥ HO :0,54+x CoH2,02 BRIO x +2y +0,82 =1,08+0,544+x = y=0,4 mol CyHay20 +820, —>mC0, +(m+1H,0 x—— 1, 5mx —> mx C,H,,0, +2520, —n00, +n,0 = {rmx +0,4n = 0,54 0,40 <0,7 0,4 0, 6n- 0,4 0,4 n<1,35 = n=1={HCOOK :0,3=> Mycoox = 25,28 Dap an A CHO, C14 C,H,NO, CO, :1,4 H:2.9 43,1 wes yg) at 431 *" => 16a+14b = 23,4 Be CH,NO, {oates Ora C.H,NO, Neb C,H,O, CLHSNO; 63 noinct 43,1 HIN 5 = 0,3 =a =1,2 £2") 0.H,NO, re C,H,NO, C.H,O, CyHsNO, a ssmansont 21,55; in a) CH,NO, = C.HNO, - nhan thay tilé 20 : Na(RCOONa) = nf, = 0,39 nyo =0,3— 921,55 +0,35.40 =m + 0,3.18 = m= 30,15 Dap an D D> (CH,OH X:} CH,CHO }—°S2_5{CQ, :0,45 mol C,H,CHO.eed CH,OH +1,50, —+CO, +2H,0 a———>1,5a—ra CaH2n0 +(1,5n-0,5)0, —+nCO, +nH,0 b———1, nb - 0,56 —> bn eee = b=0,15 mol 1,5a-+1,S6n—0,5b=0,6 a4, =0,3 mol => m,, =32,4g Dap én D CH CH, aes exstm , [C0215 mol 24,4gam:) C,Hyy oo H,0:1,6mol CH,CHO CH, = CH-CHO Ete 5g = Ngo = 0,2 mol ny, 10,4 = my, = 43,28 Dap anD [CH,CHO ->C,H,0 C\H,COOH + C,H,O. ico, 15,48 gamX4 >” CHO, ny)? C,H,0, H,0:0,66 mol CH,COOH + C,H,0, :0,07 mol C)HO:a 1548 gamx ICH, 2 |-29[0% _, [40+ 60+0,074= 0,662 Pte eee) eee H,0:0,66 mol [44a +62b+0,07.60 =15,48, C,H,O, :0,07 =0,2 => 1,04 z 0,62 mol CO, #5 54,28 sam DVrco, = 2a+2b+ 2c = 0,62 mol Na,CO, :x NaHCO, : y e =1,8 01 52. mol Myo = Op1.2+0,52= 0,72 x= x+y=0,62 => = 106x +84 =54,28- Ly Dap an DC,H,OH > C,H.O HCHO > CHO CH,COOH + C,H,O, > CH,O 19,4g X41 HCOOCH, > C,H,O, > CH,O CH,COOC,H, —+C,H,0, CH,OHCH(OH)CHO = C,H,O, + CH,O |CH,CH (OH) COOH — C,H,0, > CH,O optmt , [CO :0,8 mol H,0:0,9 mol CHO:a 46a+30b+88C=19,4 fa=0,1 opin , [CO, :0,8 mol 19,4gX:4CH,O:b } Simi, = )datb+4o=08 > 4b=02 H,0:0,9 mol CHO, :¢ , 6a+2b+80=1,8 c=0,1 YM 4,0, = 45,36% Dap én A (X): CHO YY: CHO, 1 mot 2: 402°54 (0, :0,46 mol —{CO, :1,02 mol (C,Hyq,20+3n0 —> nO, +(n +1)H,O a——>3an —an_ a ee > C,H,0, +130 —>6CO, +5H,0 3an +13b=2,46 mol b——13b—> 6b atscos C,H, :0,12 mol CO, :0,24 mol = Veo, = 5,3761 Dép in A CH, .JOHCHO |, [0,15 mol co, te CH,COOH 0,2 mot H,0 7 P= 95 cH,COOH rie Pee = Vy, =0,05.22,4=1,121 Dap dn A an =0,3 b=0,12 molDT cand > (C,H,OW C,H,OH:0,03 C,H,COOH ae ear C,H,COOH: x ayy ices H,0:0,°7 mo | CF Coy 3x+2y+0,03.2=0,14 i. (C,H,OH 0,03 C,H,OH: 177 838] CoH,COOH:0,02 | —»13,2 gam} C,H,COOH: CH,CHO:0,01 CH,CHO: 0,04 —t82_ Ag: 0,08 mol > m,, =8,64g Dap én D 228] a [CO:] erminyoxie_, [BACO, 0.5 ae HO Ba(HCO,), :0,2 oo {1462+92=23,8._, fa=0,1 6a+3b=0,9 b=0,1 H,0,K, :0,1 CygHlygO,y :0,1 22822285 m gy ieeta mmezi8g Dap an B HCOOH page CooH (COOH :0,07 mol coor 2uOs_CO, :0,06 mol = }C (coon), 7 CH,COOH CO, :0,11 mol H,0:0,1 mol a=18 04:00 nt (CH,OH,C,H,OH) > C,,H,O ico, 1,86gamX }C,H,COOH — C,H,0, {aa HOOC[CH, ], COOH > C,H,,0, - C:1,5a CO, :1,5a_ [66a+18b=4,74__ fa=0,05 1,86gamX yH:2b |—»—@nea 5) oo 2 ce a Mose VO: [34a42b=1,86 ~ |b=0,08 075 (r aoe — SDs mi" = 0,075,100 - 0,075.44 —0,08.18 = 2,76 g 20:0,C\H,O, :b 1,0 Ba(HCO,), :0,26 146a +92b = 26,72 { = 6a+3b=1,02 26,72 emt {el ae 20,5 0,12 =0,1 = ¥.CO, :1,02 mol => { CH,O,K, :0,12 CHyq0, :0,12 2492885 mg > m= 28,88 g KOH: 0,04 Dap an C CH, x JOMs o:op0s mm JEO2 | cacon),: omer, [CACO :0,05 CoH H,0 Ca(HCO,), :0,05 C\H,O, :x mol =) mig" =0,15.44+2.18-5 = 4,3 a= 0,15 mol 225 2x +0,205.2=0,15.2+0,15 = x = 0,02 mol = my = 2,74 => %mo,4,0, = 54.01% Dap in D CH,OH:2 (CH, :2 |CH,OH :2 - Tea, = 2Nex,0, -(2 Ho fe HOH 1 2] CHOBE CHogs20 HO, + sHLOH | Cr On C,H... +1,5n0, —»nCO, + (n+1)H,0 a——1,5an——>ran ‘an+bm=Ngo, = 0,54 CH,,0, +(1,5m—1)0, —+mCO, +mH,0 [* bt +1,Sbm—b=0,41 b——1, Sam~b—> bm => b=0,4mol an +0,4m = 0,54 => m<1,25 = HCOOK : 0,4 mol > m= 33,6 g oe Dap an C HH : 2 (CH, :2 |CH,OH :2 (CH! fey, = Nene, = ss =} C\H,OH:1= C,H,,,,0 4 = EReames > 10H, 21 m,n) OT on # “Hs C\H,, ,,0+1,5n0, —onCO, + (n +1)H,0 a———> 1, 5an —>an ‘an+bm=ngo, = 1,55 > : = b=0,8 mol CyHy,0, + (1.5m -DO, —>mCO, +mH,0 |” (1,5an+1,5bm—b=0,1525 b— +l, Sam—b—> bm HCOONa:0,8 mol an+0,8m=1,55= m<1,9375 => BeOS MO" Wy m= 62,48 NaOH :0,2 Dap én Bead C,H,OH (C,H,OH:0,03 20,14 =0, CH,COOH} —2- 5 [0021914 8 | Cu COOH: x fas 249793 H,0:0,17) 2 3x-+2y =0,14—0,03.2 = 0,08 CH,CHO CH,CHO:y oA 0,02 m,, = 2,16 g C,H, ;CHO:a 2,8 gam X4C,H,, ,COOH:b }—"%82" {2a +b+0=0,055 mol C,H, ;CH,OH:¢ C,H, ;CHO:a 2,8 gam X1C,H,, COOH: b |—SM&tE NL. Ag :0,02 mol—>a=0,01 mol C,H, .CH,OH:¢ 2,8=0,045.14n—0,045 +29.0,01+31(b +e) +14b = 1,47 = 0,63 +14b = n <2,33 =) n=2:CH, =CH-CHO:0,01= %mg,, cy-cHo = 20% Dap in A eT 2; CO, :an Ba(0H) 5,444 gam XC,H,,,,0:a—2>. woh, : H,O:an+a 4 =5,444_ fan =0,232 { a 1 0,23: = Maco, = 0,232.197 = 45,704 g = 62an +18a =16,58 a=0,122 Dap in A 37 SatenGE ‘CHO: 0,11 mol ABO. Ag 0,22 mol = {COOH OHC-C=C-CHO c OHC-C=C-COOH tae : on (CHO:0,11 mol = Nato, :0,07 mol COOH: ONC _C=eC_CHO [EP CO 0,07 mol => bet 0,07 mol OHC-C=C-COoH ACHO +30, —>4CO, +2H,0 0,11 0,0825 40,11 2COOH +0,50, —>2C0, +H,00,07 90,0175 0,07 C+0,—>€0, xoxox C,H,,0, + (1,5n-1)0, —>nCO, + nl¥,0 b——>1,5bn-b——> bn x-+bn=0,605 bn =0,4 =| x +1,5bn—b =0,705 3 41d=01 =>m=8,8g 6,344 12x = 14bn+32b > 14bn+32b—-12x=6,34 [x =0,205 Dép an A [XETEDD Bio toan khéi lugng tinh ra khdi htgng CO, My +Mo, = Meg, + My,o =P Moo, =22= Neo, = 0,5 mol ‘C,H,OH—>C,H,0 HCHO—>CH,O CH,COOH——>C,H,0, —+CH,O CHO:a eas HCOOCH, —>C,H,O, —+CH,O => 13,8 g)CH,O:b aa es CH,COOC,H, —>C,H,0, C,H,O, :¢ ete CH,OHCH (OH)CHO—>C,H,0, CH,CH (OH) COOH—>C,H,0, —>CH,O 46a +30b+860=13,8 a= 0,025 = Ja+b+2c=0,5,3-0,5375.2=0,425 > 4b=0,35 = %meyno, eae 5, 58% 6a+2b+6b=1 c= 0,025 » Dap an A COOH ‘COOH :0,1 mol Cho m gam M:4C MH. CO, :0,1 mol => 4C H H (COOH: 0,1 mol (COOH:0,1 mot C:0,04 Sudoree! (extant C:0,04 = m=5,26 H fete H:0,28 Dap an A p (au 40 C\HO CHO a C,H,O: X: ouHho, A ni02smol—ng aay, <0samaix 4S bp fearon os CoH,.0,)Megabook _JCH,O:a CO, :0,5a+0,5b+0,55 dono b H,O:1,2 mol 60a +28b+ by =9+ 22a +22b = 38a +6b-+by =9 Batby=2,4 a=0,15 38a+6b+ by =9 = 4b =0,35 => %ttonyg =30% atb=0,5 by =1,2 HCOOCH,CH,OH > C,H,0, 5,152 1 HCOOCH, > C,H,0, HOC,H,OH > C,H,0, {re 2X _nwiomaus (CHO: + CHO, : MONO 197% — 44x —18y = 14,62g H,O:y 4x +18y =10,99 = 197x = YO, :0,17 CH,O:a __ [30a+62b=5,15 _ fa=0,12 515g = > CHO, :b— ]a+2b=0,17 b= Mo,ow, 225 g Dap an B ce C,H, GH, co, 0,1 mol: a afl 0 C,H, 0,1=2er He, K-1 Dap an B (CH,OH (CH,OH: 0,02 a 0, _ JCO, 10,064 Se CH,COOH }—%94 5 ggg?) CHACOOH: a HCHO, baeeree HCHO: 00382501, fea 099414, 62-9x=0,3m-f =n, = 005 Bowron => 8atby=2,4 H,0 BaCO, :0,13 Ba(HCO,), :0,02 a SMe 30,0125 mol P= k-1=0,2=9k=1,2—9 ng, =0,12=9m,, =19,2g =m =120g ‘a+b=0,03 2a+b=0,044ane ‘CH,OH : 0,02 = 20 ON => m=1,96 g = 4,9 g} CH,COOH :a 2,5 =0,035 b=0,016 HCHO: 2CH,COOH + Cu(OH), —+(CH,COO),Cu+2H,0 Neou, =950175 = Meo, =1715 8 Dap an A C,H,O, 7 Ta cé: X4C,H,O —. Co 10,09 teex = 0,05 (mol) H,0:0,07 CHO, 1.09.12 +0,07.2+0, 05.16: , 02 (gam) HCHO: 0,01 Ny, = 0,04 —> Meg = 0,04 HCOOH: 0,01 Ta cb: 4 Mou: = 0,04 —> monoy = 0,04—> | HOC CHO : 0,01 Ngo, = 0,08 HOC-COOH:0,01 HOOC-COOH:0,01 —n,, =0,01.4+0, 01.2 +0,01.4+0,01.2 = 0,12—> mj, = 12,96 Dap én D eg HCHO aan X:{ HCOOCH, —cH,0—2 ee 10% C400, :0,5 mol CH,CH(OH) COOH 2 No, = Moo, = 0,59 Vo, =11,21 Dap in B 13,36 CHO, 2 CO, oseneine(on), , [BaCO, :0,25 36 gam Sg]? stmt Ber, 2 TCH O.: 1,0 Ba(HCO,), :0,13 = Fito, =0,51.mal—> {228 +466 =13.36._, f= 0,05 7 3a+6b=0,51 b=0,06 (C\H,O, :0,05 H,0,K, :0,06 13,36 gam 49 80> Kono, ag C5H,O.K, :0, cue CHO, :0,06 KOH: 0,02 Dap an CPE oLaad [XEIEDD Vay quy di bh vé a mol HCOOH; b mol NH, - CH, -COOH; ¢ mol C,H, => m(X) = 46a +75b + 26c = 27,1 (1) Accor) = Bowony = 4 +b = 0,3 (2) BINT cho H ta cs: =a + 25b +c = 0,85 (3) b=01;c=04 a) Gidi hé ta cé a= BINT cho Ctacé: Noy = & + 2b+ 2e = y = 1,2 mol BINT cho oxi ta c6 0,3 +x = y +0,85/2 => y = 1325 => x+y = 2,525 Dap an B 1 cH, x C,H, 3 12x+4=34 x= GH, CoH »S= C, Hy (CO, 20,373 exon, “ H,0:0,3 =0,375.4440.3.18=21,9g Dap an D C,H, os —*-of CaCO, :m\st TE} CH, :1 [CH,OH:1 = a CyHy..0 Noy, Pano. feteoys {enor alte C,Hq)0+1,50, —>nC0, +(n+1)H,O a——>15an—an antbm=n, =O775 > = C,Hs,0,+(1,5m-1)0, —>mCO, +mH,0 |” (1,San-+1,sbm—b = 0,7625 b——1,5am-b—> bm 4.0,4m=0,775 = m<1,9375 = [HCOONa: 0.4 mol, 4 31,2 =0,775= m C,H,0 HCHO — CH,O CH,COOH — C,H,0, > CH,O CHO HCOOCH, + C,H,0, > CHO =>4CH,O CH,COOC,H, > C,H,O, CHO CH, (OH) CH(OH)-CHO > C,H,0, CH,O CH, (OH) CH, COOH. — C,H,0, > CH,O CH, 46a+30b+860=13,8 [a =0,025 oy srrsnet [CO, 20,5 13,8 gam X jCHO SSM) A ae yar btde=0,5 = 1b=0,35 CHO, eee 6a+2b+6c=1 025 YIMe 0, =15,58% Dap én D CH,OH [C:0,7 mol Cho 21, 6 gamX | C,H, (OH), } "0,35 mol H, = {OH:0,7 mol C,H.(OH), H:1,3 mol 7 mol ta 0, JOO 0,7 mol p— 9) TO agp? Mao “188 H:1,3 mol arcee Dap an B (CH,COOC,H, a (ry 0,6 eas :0,1 mol %Me 4,0 = 34.33% H,0:0,7 C.H,0:0,1 > “Mex = 0,25 mol 125 mol => Di... ng n,, = 0,5 mol => ng, = 0,25 mol Do N40 = Duy gng => MOI chat du c6 1 CHO va (1 nhém CH,OH hoge COOH) => n, = 0,25 mol => $6 C trung binh = 0,5/0,25 = 2 => 06 1 chat la HOCH,CHO: x mol ; chat cn Jai sé 14 OHC-COOH: y mol =>x + = 0,25 va 60x + 7ay = 17,1gec’ => x= 0,1; y= 0,15 mol => Bao toan H: 2n,,, = 4x + 2y = 0,7 mol =>m=63 Dép an B 26,72 gam) OHH #® 0, JCOr _ arena enon, BaCO, :0,5 : H,0 Ba(HCO,), :0,26 920+1460=26,72__ fa=0,1 = = 3a-+6b=1,02 b=0,12 CSHjOs:0,1 co4s-0 280 CyH,O,K, :0,12 ee eee 012 ™E) KOH: 0,04 |,02.mol => m=28,88g CH,OH :C,H,0 HoH J Ora 5,58 gam X }C,H,COOH > C,H,0, —>C,,H,O = 5,58 gamX4C:1,5 HOOC[CH, ], COOH > C,H,,0, > C,H, 0 Hib ay Uae oxiared ,[CO, #152 _ [66a+9 ore eae |ectte H,0:0,5 |34a+b H:b mf" = 0,225.100~14,22=8,28 g Dap an B CH, CH, = CH-COOH CH, = CH-CH, -OH H, 0,75 mol CHO, ICO, :1,35 mol 0,75 mol — rH H,0 C,H,O, :0,45 mol 75 mol ae \e 0,3 mol C\H,0, :0,45 mol 0,75 if HOO MON ty 5 mm = my => hy My = My My H, :0,3 mol al= My tx M. = 0,Imol Y > ny, =0,05= ng, = 25 = ny =0,6 mol:= n,,, =0,15 mol => n, = 0,3 Peng. ),05 mol => Ve, Dap an D CH, CH | oxsoa0sea_, [O02 _caon,n1m, [CACO, 0,05 CoH H,0 Ca(HCO,), :0,05 CHO, => ¥.CO, :0,1 mol = 0,1.44+b18— 0,25 mol CH, | 29 CH, => ny, = 0.25.1, Dap an 2 HCHO CH,COoH HCOOCH, —rc1i9:a2of CH,CH{OH)COOH C\H.,0, = 62a-10= Dap an B CO, 22 exon 28 exon, CaCO, a Ora 4 => a= 0,2 => Vo, =0,2.22, (a = 4,481 ie4, Ruteni (Ruthenium)] Rutheni dugc nha khoa hoc Nga la Karl Klaus phat hién va co lap nam 1844, Ten goi cé nguén géc tir Ruthenia, mot tir La tinh dé chi Rus, mot khu vuc lich strma ngay nay la mién tay Nga, Ukraina, Belarus, mét phan Slovakia va Ba Lan. Karl Klaus dat ten cho nguyén té nhu vay dé vinh danh qué huong ong. Sau mot qua trinh héa hoc phuc tap. kim loai nay dugc phan lap va sir dung cho nhiéu muc dich khac nhau. Chang han nhu Ruteni dugc thém vao voi hop kim ctia paladi va bach kim dé gia tang do cimg va tang cudng do bén. Ruteni cing dugc sit dung phé bién trong finh vuc dién tir. Nam 2009, gid cla kim loai nay vao khoang 14.500USD/kg. Vé mat sinh hoc Rutheni co thé lam sam mau da ngudi, va c6 thé la chat gay ung thu va tich ly sinh hoc trong xuong.UNG HNO, KHONG XAC |AN PHAM KHU - Van dé bai todn nay khéng biét khi sinh ra la khi gi - Xéc dinh mol nits trong muéi (NO;) - Sti dung phuong phap bio ton nguyén t6 dé xic dinh lugng nite trong HNO, di vio khi, ~ Bao toan nguyén t6 hidro suy ra mol nude ~ Bao toan mol oxi suy ra mol oxi di vio khi [XEDED Hoa tan hét 14,8 gam hdn hgp Fe va Cu vio 126 gam dung dich HNO, 48% thu duge dung dich X (khong chtta muéi amoni). Cho X phan ting véi 400 ml dung NaOH 1M va KOH 0.5 M, déu thu dugc két tia Y vi dung dich Z. Nung Y trong khong khi dén khéi higng khong di thu dugc hdn hgp 20 gam Fe,O, va CuO. Cé can dung digh Z, thu duige hén hgp chat rin khan T. Nung T én khéi higng kh6ng d6i, thu diigc 42,86 gam hén hop chat rin. Nong 4 phan trim cita Fe(NO,), trong X cé gid tri gin nhdt voi gid tri nao sau day A7.6 B79 C.8,2 D.69 m Hung dan: 205 :0,5a Cu: Fe:a 14,8 son f PO Bates, os6nel_, x NOHO 29 gam { eee hau > = 80a+80b=20 ~~ |b=0,1 Fe(NO,), 2x f x+y=0,15 x=0,04 x:4cu(No,), :0,1= = 3x+2y=0,34 |y=011 Fe(NO,),:¥ K*:0,2 Na’ :0,4_ [46a+17b=25,86 [a =0,54 42,86; em NO; eg 6 aie ,96 0,54 = 0,42 => My =14,8+126—0,42.14—0,78.16 = 122,44 0,48 mol => ng = 0,78 mol CHreex0,, = 19% Dap an B4 9900000000000000000000O0OOOOOOGHOK Se a 4 [XETED cho 6,048 gam Mg phan ding hét véi 189 gam dung dich HINO, 40% thu duigc dung dich X (khéng chtta muéi amoni) va hn hgp khi Ia oxit ciia nito. Thém 392 gam dung dich KOH 20% vio dung dich X, ri c6 can va nung sin phém dén khéi ligng kh6ng déi thi thu duoc 118,06 gam hén hgp chat rin. Néng dé % cia Mg(NO,), trong X cb gia tri gin nbit 1. A. 20% B. 25% C.17,2% D. 19.7% 1 Huéng dan: KNO, KNO, :x ‘Mg: 0,252 mo] —2izmsl_, x Koel KOH —*>{KOH:y Mg(OH), :0,252 MgO : 0,252 xt+y=14 =1,02 > > 85x +56y=107,98 |y =0,38 mol ene N:l,2-1,02=0,18 24NO3 :1,02 20,3 eo eae = X:{NO; = thy o 10,342 mol => hh fete He 0,516 My =189,488 = C% yy), =19468% Dép én D Dp bartée ren uven ‘Hoa tan hoan toan 1,28 gam Cu vao 12,6 gam dd HNO, 60% thu duge dd X (khong co ion NH,’). Cho X téc dung hoan toan véi 105 ml dd KOH IM, sau dé loc bd két tia duge dd ¥.Cé can Y duige chat rin Z. Nung Z dén khéi higng khong 46i, thu duige 8,78 gam chat ran, Néng dé phén trim cia Cu(NO,), trong X gin véi gli tr] ndo sau day nhét? A. 28,66%. B. 29,89%. C. 30,08%. D. 27,09%. Ha tan hoan toan 7,68 gam Cu vao dd chtta 0,48 mol HNO, khudy déu thu duge V lit hén hgp khi NO,, NO (dktc) va dd X chia hai chat tan. Cho tiép 200 ml dd NaOH 2M vao dd X, loc bd két tita, c6 can dd r6i nung tiép dén kh6i luong khong déi thu duige 25,28 gam rn, Cac phan ting xy ra hoan toan, Gid tri Va A. 1,792. B. 3,584. C.5,376. D. 2,688. Hea tan hoan toan 11,6 gam hén hgp A gém Fe va Cu vio 87,5 gam HINO, 50,4%, sau khi kim loai tan hét thu dugc dung dich X. Cho 500ml dung dich KOH 1M vao dung dich X thu duigc két tia Y va dung dich Z. Loc ly Y r6i nung trong khong Khi dén khdi hxgng khong 6i thu diigc 16,0 gam chat rin. Co can dung dich Z duige chat ran T. Nung T dén khéi lniong, Khéng di thu duigc 41,05 gam chit rin, Néng d6 % cita mudi Fe(NO,), c6 trong dung dich X gin nit vi gid tri ndo dudi day? ALAdM%, B.15%. C.29%. D. 11%.Ha tan hoan toan 11,6 gam hén hop A gém Fe va Cu vao 87,5 gam HNO, 50,4%, sau khi kim oai tan hét thu duige dung dich X va hén hop khi B . Cho 500ml dung dich KOH 1M vio dung dich X thu duigc két tia ¥ va dung dich Z, Loc léy ¥ r6i nung trong khong khi dén khéi Jugng khong 46i thu dugc 16,0 gam chat rn, C6 can dung dich Z dugc chat rin T, Nung T dén khéi lugng khéng déi thu duigc 41,05 gam chat rin, Biét cdc phan ting xay ra hoan toan. Trong dung dich X chat tan e6 néng 46 % cao nhét cé gié tri gén vdi gid tri ndo sau day: A. 20% B. 30% C.25% D.10% Ha tan hodn toan 1,28 gam Cu vio dung dich chita 0,12 mol HNO, thu duigc dung dich. X va hn hgp khi ¥ g6m NO va NO,, Cho X tic dung hoan toan véi 105 ml dung dich KOH LM, sau dé loc bé két tita duge dung dich Y,. Cé can Y, dtigc chat ran Z. Nung Z dén khéi Ikigng khéng déi, thu dude 8,78 gam chat rn. Ty kh6i cita Khi Y so v6i He la AS. B10. C95. D.8. [XEEED cho m gam hén hop A gém Mg va Al cé t} Ie mol 4: 5 vio dd HNO, 20%. Sau khi céc kim loai tan hét c6 6,72 lit hn hop X gém NO, N,O, N, bay ra (dktc) va duigc dd X,, Thém mot lugng O, vita dit vio X, sau phan ting duige hén hop kf Y. Dn Y tii tit qua dd KOH du, 6 4,48 lit hon hop khf Z di ra (dktc). Ti khéi cia Z déi véi H, bing 20. Néu cho dd NaOH vao dd X, thi luong két tia 16n nhat thu duige la (m + 39,1) gam . Biét HNO, ding dui 20 % so voi ging cdn thiét. Néng dé % ciia AI(NO,), trong X, gin nit véiz A, 9,4% B.9,6% €.9,7% D.9,5%. HUONG DAN: KNO, » in Cu :0,02 mol B28, x_Houueimt_yy, JKNOs_ 3,78 g |SNOu:® KOH KOH:y (ae i" 01 85x+56y=8,78 |y=0,05 mol [Cu** :0,02 X:4NO5 10,1 j,9 =0,03 mot =p |NO127 01-0402 =X: =0, ae - 0:0,12.3~0,1.3-0,03 =0,03 20,06 |, 28 +12, 6 my ~My = 13,12 = Choxio,y, = 28, 66% NaNO, e496 agg [NaNOsix NaOH NaOH: y 01a mt et xis yf x =0,32 ,058 mol xty=04 = = 69x +40y = 25,28Oe aad ieee 'N:0,48-0,32 = 0,16 NO 7 :0,48-0,32=0, : 10,32 ny, =0,. ),16 mol =X a i Dio oa m={ Wiese aaata ae 2 atsnel{ => V=0,16.22,4=3,5841 Dap an B o Fe,0; Y—516 11,6gam Feta oer ,y_Kokscsma Cu0:b ; ne e KNO, :x Z—2T—244,05 gam |? OH: y xty=0,5 ad > 85x +56y = 41,05 80a +801 fe ae 46 (age 1 ener > = > =X: b=0,05 mol Fe" sd 2c+3d =0,45—0,05.2= 0,35 NO; :0,45 foro jd =0,05, 0,7.3-0,45,3~0,35 =0,4 ty, =11,64+87,5~-0,25.14-0,4.16 = 89,2 =? O% yyy, = 13,56% Dap an B 0,5: 1a 50 : uO: 11,6 gam era Otel, yx _KOW: 0Sol [Curb —2-5t—£-41,05 gam [KNO2** KOH: y xt+y=0,5 x=0,45 = = 85x +56y=41,05 |y=0,05 ‘Cu** :0,05 fcc yes Fe*:¢ jee > > x > 80a + 80b =16 b=0,05 mol |Fe* <4 20+3d =0,45-0,05.2=0,35 NO; :0,45 3 [om Ot yp [N:0,25 d=0,05~ |0:0,7.3-0,45.3-0,35=0,4my, =11,6+87,5-0,25.14-0,4.16= 89,2 C%egoo,), =13,56% C%egoy), =20518% 10,53% : tmo,-0:2m8 | Howqittnet_ [KNO, 4 KNO, :x Cu:0,02 mo], x_n oy: 98,78 g i KOH KOH:y 1 x+y =0,105 = = 85x+56y=8,78~ ly 1,05 mol cu :0,02 X:4NO}:0,1 0,03 mot =» {N?12-0.1 0,02 N-385-4-9,5 =X: IL => Myo =0,08 mol => =M=383-=9, : ? }0:0,12.3-0,1.3-0,03= 0,03 He HT :0,06 Dap anc ‘NO Mg:4a axon _ | 003 mol X:| N,O. Al:Sa N; xX NO 0,3 mol X:| N,O |-2» Y—*" 5M =40 eeeeeee [asst eee ere N, :0,05 mol N, NO:0,1 mol =0,03 mol X:] N,0:0,15 mol N, :0,05 mol Al(OH), : 5: x, mae, [AO 58 a3 ong, = 321 = 2,3-50=0,1 mol Mg(OH), :4a 7 ee, =n, =2,3=0,1.348.0,15 +0,05.104+8.0..n5, Mg:0,4 lise = Mynyvo, = 050375 mol Miho, = 4x9 +10.ty,o + 12my, +100, = 2.875 = igo, = 2,875.12 =3,45 = my =1086,75 = my =1094,85 = C% yao, =957% Dap anC SEPoe on Iridi (Iridium) Iridi la mot trong nhang nguyen t6 hiém nhat trén hanh tinh chang ta. NO Ia mot kim loai cing, mau trang bac thudc nhém platin (PCM), [a kim loai khang 4n mon t6t nhat, tham chf la 6 nhigt dQ cao khong 200°C. Iridi dugc Smithson Tennant phat hién nam 1803 6 Anh (cng nam ong phat hign ra Osimi), Mac di la mot trong nding nguyen t6 hiém nhat trong vo Trai Dat. vai san lugng va tiéu thy hang nam chi 3 tdn, no cé nhiéu ting dung trong cac Aganh cong nghiép dac thu va trong y hoc. Voi nhing tinh chat dac biét. Iridi dong vai tro quan trong trong cac nganh y khoa, dién tit 6 t6 cing nhu cac mat hang tiéu ding khac nhu bit bi, déng h6, va la ban.. ‘DIEU CHE Cl, 0, G05 888000000000000000000000000006 EY Pruone PHA cit Bio ton mol nguyén t6 oxi nif end nt? Bao toan nguyén t6 Clo ng +ng Bio toan mol nguyén 16 hidro va céc nguyén t6 con lai Bun néng 48,2 gam hén hgp X gém KMnO, va KCIO,, sau m6t thai gian thu duige 43,4 gam hén hgp chat rin ¥, Cho Y tac dung hoan toin véi dung dich HCI dic, sau phan ting thu duige 15,12 lit Cl, (dktc) va dung dich gém MnCl, KCI va HCl du. $6 mol HCl phan ting 1a: ALLS B24 cis D.21 @ Hung dan: 48,2 gam [RMO%°* 43.4 gam: ¥+0, :0,15 mol — 43,4 gam , ™ VK CIO, :b 7 sbesteiaasit = 158a+122,5b= 48,2 KCl:a+b Mah, sa 1! 10,675:mol+ H,0:4a+36-0,3 43,4 gam v= Nye) =8a+ 6D~0,6 = 8a+6b-0,6+b=at+b+2a+0,675.2 = Sa+6b=1,95 fe taceee iy = yo) = 84+ 6b ~0,6=1,8 mol Sa+6b=1,95 p02 ee ere eee Dap dn C [SEED Nhiet phan 82,9 gam hin hgp X gém KMnO, K,MnO, MnO,, KCIO, va KCIO (trong 46 clo chiém 8,565% Khéi lugng), sau mét thdi gian thu dug chat ran Y va V lit) 0, (dktc), Hoa tan hoan toan Y cn 1 lit dung dich HCl 3M (dun néng), thu dugc 19,04 lit Cl, (dktc) va dung dich Z chita hai chat tan c6 cing néng 46 mol. Gia tricia V1a A336. B.2,24. €.5,60. D.448.De ee : z 1 Huéng din: Pt KC1:0,5 (mol) :0,5(mol sdf Ta cb: sng =0,2. Ageia ng, =0,85 SEL my +3.36,5=0,5.74,5 +0,5.126 + 0,85.71+1,5.18— my = 78,1 =0,1S—>V= BEE no, = ae 36 (lit) ong 5 Dap an A EY Bartar ren woven Nhiét phan hoan toan 30,225 gam hén hop X gém KMnO, va KCIO, thu dutgc O, va 24,625 gam hén hgp chat rn ¥ gém K,MnO, KMnO, KCIO, MnO, KCL Cho toin b6 ¥ téc dung vita dit véi dung dich chtfa 0,8 mol HCI dic, dun néng, Phan trim khéi lugng KMnO, trong X la: A. 39,2% B. 66,7% C, 33,33% D. 60,8% Nhiét phn 30,225 gam hén hgp X gém KMnO, va KCIO,, thu duige O, va 24,625 gam hn hop Y g6m KMnO, K,MnO, KCIO, MnO, va KCI. Toan bé ¥ tac dung vita dit v6i dung dich chita 0,8 mol HCI, dun néng, sau phan ting thu dutge x mol Cl. Gié tricia x gn nat véi gi tri nao sau day? AOL. B.0,2. €.03, D.04. Nung m gam hén hop X gém KMnO, va KCIO, thu duge chat rn ¥ (g6m KCl, K.MnO,, MnO, KMnO,) va O,, Trong ¥ cé 1,49 gam KCI chiém 19,893% vé khéi luong. Tron lugng O, trén véi khong khi (g6m 80% thé tich N,, cdn lai la O,) theo tilé mol 1:4 thu dugc hén hgp khi Z. Dbt chdy hét 0,528 gam cacbon bing Z, thu dugc hdn hgp T gém O,,N, va CO,, trong d6 CO, chiém 22% vé thé tich. Gid trj cha m gin gid tr] ndo nhit sau day? A105. B. 100. 6.95, D.9,0, Nhiét phan 40,3 gam hén hop X gsm KMnO, va KCIO,, sau mét thdi gian thu duge khi , vi 29,9 gam chat rin Y gm KMnO, K,MnO, MnO, vi KCL Dé hoa tan hoan toan Y cin vita dit dung dich chia 0,7 mol HCl, Phén trm khéi higng KMnO, bj nhiét phan la A. 50%. B. 80%, C.75%, D. 60%. Nhiét phn m gam hén hgp X gém KMnO, K,MnO, MnO,, KCIO, va KCIO (trong &6 ‘Mn chiém 24,14% khéi lugng), sau mt théi gian thu duigc chat ran ¥ va 4,48 lit O, (dktc), Hoa tan hoan toan ¥ can 1 lit dung dich HCl 2M (dun néng), thu duigc 17,92 lit Cl, (dtc) va dung dich Z chita hai chat tan ¢6 cling néng dd mol. Gié tr} ctia m gin nhat voi gid tri mao sau day? A.67, B.68. C69. D.70. Nung néng 60,01 gam hén hgp X gom KMnO, KCIO, va MnO,, sau mot thé gian tha aldugc khi O, va 48,81 gam chét rin Y gm K,MnO, MnO, KMnO, KCI. Dé hea tan hoan toan Y cdn vita dat dung dich chtta 1,6 mol HI, thu duige 9,688 lit khi Cl, (dkte). Phan tram khéi higng KMnO, bj nhiét phan 1a A. 70,83%. B.75,00%. C.77,08%. D.72,92%. Hén hgp X gém KCl va KCIO,, Ngudi ta cho thém 10 gam MnO, vao 39,4 gam hén hgp X thu dugc hén hop Y. Nung Y 6 nhi¢t dé cao duige chat rn Z. va khi P. Cho Z vao dung dich AgNO, ly dut thu dutgc 67,4 gam chét rn, Léy 1/3 lutgng kh P suc vao dung dich chita 0,5 mol FeSO, va 0,3mol H,SO, thu duigc dung dich Q. Cho dung dich Ba(OH), lay dui vao dung dich. Q thu duigc m gam ket tia. Biét céc phan ting hodn toan. Gid tr clia m 1k A.238,2 gam. B.185,3 gam. C.212,4 gam, D.197,5 gam. Nung m gam hin hgp X gém KCIO, va KMn0, thu duige chat rin Y va O,, Biét KCIO, phan hay hoan toan, con KMnQ, chi bj phan hity mot phdn. rong Y o6 0,894 gam KCl chiém, 8,132% theo khéi higng. Tron higng O, 6 trén véi khong kh theo ti1¢ thé tich %o,: V, = 13 trong mot binh kin ta thu duige hén hgp khi Z. Cho vao binh 0,528 gam cacbon réi ddt chay het cacbon, phan ting hoan toan, thu dugc hén hgp khi T gém 3 khi O,, N,, CO, trong 46 CO, chigm 22,92% thé tich. Biét khong khi chcta 20% thé tich oxi, con Iai J8. Gia tri m (gam) la AL12,59 B. 12,53 €.12,70 D.12,91 Nhiét phan 15,8g KMnO, thu dugc 14,52g chat rin sau 1 thi gian. Lay toan bé lugng chat rin nay tac dung voi dung dich HCl dc néng du thu duige V lit khi (dtc). Gid tri cia V li: A. 3,808 B. 2,688, C.0,596 D, 2,016 Hén hgp X gém KCIO, Ca(ClO,), CaCl, va KCl c6 téng khéi higng la 83,68 gam. Nhiét phan hoan toan X thu duigc 17,472 lit O, (Akte) va chat rén Y gém CaCl, va KCL. ¥ téc dung vita di 0,36 lit dd K,CO, 0,5M thu dugc dd Z. Lugng KCI trong Z nhiéu gp 22/3 lan lugng KCl trong X. Phan trim khéi lugng KCIO, trong X la A. 23,51%. B.47,62%. C.58,55%. D.81,37%. Nhiét phan hoan toan m gam hén hgp X g6m KCI, KCIO,, CaCl, CaOCl, Ca(CIO,), thu duige chat rin Y va 2,24 lit khi O, (dktc). Ha tan ¥ vao nude duige dung dich Z. Cho dung dich Z tac dung véi dung dich Na,CO, dui thu dude 20 gam két tia. Néu cho dung dich Z téc dung v6i dung dich AgNO, /NH, du thi thu duige 71,75 gam két tha. Gié tri cita ma A. 29,65 gam B. 124,85 gam C. 32,85 gam D.50,6 gam [ETD Niet phan hoan toan 15,8 gam KMnO, toan bé khi oxi thu duige cho tdc dung het véi [XEMEED 6 48,2 gam hin hop X gém KMnO, va KCIO, duige tron theo tik kim loai R. Sau khi oxi phan ting hét thu duge 5,92 gam chat ran X. Cho chat rin X vio dung dich H,SO, loang, du thu dutge 1,792 lit H, (dktc). Hay xéc dinh kim loai R. A.Mg B.Al C.Fe D.Zn 36 mol 3: 4 tung: ting. Nung nong hén hop X mét thai gian thi thu dutge 40,2 gam hén hgp chat rin Y (gém aead 6 chat). Cho toan bé Y tac dung véi dung dich HCI dac (du) dun néng, thu duge V lit khi CL (kc). Gia tri cita V1? A. 10,64 lt. B.21,28 lit. C1201. D. 33,60 it. = Huéng din: K,Mn0, KMnO, :x pes 30,225 gam X. £24,625 eam ¥{ KCIO, }+0, :0,175 mol KCIO, :y MnO, KCl K,Mn0, KMn0, oe 24,625 gam Y} KCIO, |—H2:2880_, +Cl,+H,0:0,4 MnCl, MnO, KCl KMn0,:x]__ [158x+122,3y = 30,225 x 30,225 gam X = = KCIO, :y 4x+3y =0,175.2+0,4=0,75 Ly=0,15 YIM x40, =39,2% Dip an A KMnO, K,Mn0, KCIO, +0, :0,175 mol Mn0, 2083 gen KCI Err KMnO, K,Mn0, “| 0,8 mol SCH KCI ~y KCIO, |= 5. +l; :xmol+H,0:0,4 mol ‘MnCl, MnO, KCl 2S em 1,075 158x-+122,5y =30,225 fx y=0,15 mol => 4x +3y =0,175.2+0,4),2875 mol 22 50,15+0,8= 2x +0,225+0,075.2=9 x = Dap anC KCI: 0,02 fice 57,49 9) Ke | KCIO, f MnO, f Seated KMnO, = O,:a (0, 1,8a-0,044 Ci ‘ane E0048 59,2 mold N, :3,2a 0, :0,8a CO, :0,044 = 1,8a-0,044+3,2a+0,044=0,2 = 5a =0,2 => a= 0,04 m, =7,49+0,04,32=8,77g Dép én D D> KMnO, KMn0,:x_» K,Mn0, 40,3 gam x RMM6°*_* 99.9 gumy:4 K2M« 4 6, .0,325 mol KCIO, :y Mn0, KCl KMn0, KM, yeas, [KCI sae 1, +H,0:0,35 29,9 ga) gn cy, Ch #0203501 KCl 158x +122, 5y = 40,3 4x +3y =0,325.2+0,35= 2KMnO, —"->K,MnO, + MnO, +0, a—_—1, 5a 05a 0,54 KCIO, + KC1+1,50, b——>b— 5b KMn0, :0,1-a K,Mn0, :0,5 29,9 gamY 4 HH * 0,4—4a+0,5a.4+0,5a.2= 0,359 a=0,05 mol Mn0, :0,5a KCl:b Yom sc0, 8.55 100% =50% Dap in A =PS oi casad xr KMn0, K,Mn0, X:{ MnO, }—">¥+0,:0,2 mol KcIO, KCIO MnCl, :a yas 20, : tat fine fear 0,8 mol+H,0:1 mol KMn0, uate K,MnO, ae mo x4 Mino, $—%smgi** 5 %Mn=—__559 _ 1 00% = 24.14% Masa 94a+35,5+22,4 KCIO, a KCIO : 8S 4b +2=32 +1,6— 3a—b=0,4(2) 3a—b=0,4 a=0,3 = 63,35 [paseo gserasuoris™ {pcos 7 Dép an B KMnO, :x K,Mn0, ° MnO, 60,01gam }KCIO, :y —* 448,81 gam¥:) 2, +0, :0,35 mol MnO, :z te KCl K,Mn0, Mn0, KCl 48,81 gamY:4/ 2 —bémattial X*Y 54, :0,4325 mol+H,0:0,8 mol KMnO, MnCl, :x+z KCl 158x+122,5y-+872 = 60,01 158x+122,5y+872=60,01 [x=0,24 4n43y+22=1,5 3 fax+3y+22=15 =4y=0,175 YHLG=xty+224+2x+0,4325.2 [3x+0y+22=0,735 2=0,0075 K,MnO, :0,5a MnO, :0,5a+0,0075 KMn0, :0,24—a KCI 8 =0,175 = YomPbyyo, =72,92% 48,81 gam Y: E25 2a ++0,015+0,96—4a =0,8 Dap an D1000006. KCl: KCIO, :b |} “52 +0, :x mol 10 gam MnO, 39,4gX vporex[ 0,4 718. 67,4 gam {ABCH8.4 mo} MnO, :10g 74,5a+122,56=39,4 a=0,2 mol atb=0,4 b=0,2 mol Fe" :0,4 (0,5mol FeSO, Fe: 0,1 nn F ay. vB mg | Fe(OH), :0,4=9 m=238,2¢ 0,3mot H,SO, SO} :0,8 = x=0,3 mmol 32-01 mol Fe(OH), :0,1 Ht :0,2 Dap an. A \ x.{8ClO, oe Y+0, KMn0, Y¥:{0,894 gam KCl:=» my =10,994 g 0,14 0, :1,6a-0,044 Ny:24a) 4 —Eeetine 9,192 mol N,:2,4a => 1,6a—0,044+2,4a+0,044 3a , :0,6a CO, :0,044 => da = 0,192 = a = 0,048 > m, = 10,994+ 0,048.32 = 12,53 g 15,8g KMnO, :0,1 mol 14, 52g Y+0,, KCI:0,1 MnCl, :0,1 04 sapy sent | +Cl, :a+H,0:0,32 255 0,64=0,34+2a = a =0,17 mol = Va, =3,808 1 Dap an B A, 3,808 KCIO, sy ca(Clo,), 5 KCl:x vy [Cah 83,68 gam X afi *40, :0,78 molMega book 358,72 g{ CAO! #9 xeoporeen, [2 = 0,18 mol EV KCl: Z:KC1:b+0,36 = 0,88 34,5 x 2 =0,88.14,5-9 x=0,12"Soxty=b= y=b-x= Yormyoyo, = 58,55% Dap anC p cau 11 KCl KcIo, cacl, soy fier +0, :0,1 mol cxocl, ca(cl0,), CHCh nao. C4C0, 0,2 -9 {O8Ch 02 kel KCl: > b=0,1>m=m, tmp, =32,85 g Dap an C Ami 5 AgCI:0,4+b = xe 1 2KMnO, —"->K,MnO, + MnO, +0, = np, = 0,05 R—=45,92gam {5 aR = 4,32 > = an = 0,05.4+0,08.2 = 0,36 Dap an A Ti KMn0, :0,15) 9 48,2gam 4 “40,2 Y +0, :0,25 mol ( KCIO, :0,2 it a 40,2.gam yee, [KCL0,35 MnCl, :0,15 =0,35+0,4+42a=>a +amolCl, +H,0:0,7 —#S50,2+1, Dap inA 475 => V =10,641Osimi (Osmium) Osimi la mot trong nhing nguyén té dam dac nhat trén trai dét. dugc Smithson Tennant phat hign vao nam 1803. No la chat chiu nhiét t6t nhdt trong cdc kim loai thudc nhom platin (PGM), 6 trang thai ran chdc, osimi co mot mau tréng hoi xanh tuong ty nhu kem va ving bén voi cac axit. Kim loai nay dugc dung chi yéu trong céc hap kim khong gi dung dé bit déu cc ngdi bit hoc cac try ban 1é dung cu. Moi day, céc nha khoa hoc Anh 4a phat hién rng hop chét gitta Osimi va Rutheni co khé nang chda benh ung thu rudt va ung thu buéng trang.By uvtuvver 1. Két tha thu duge: Ag’ +Cl —>Agcll Fe* +Ag*"—Fe* +Ag 2, Néu trong dung dich cé H*: Dyas = Mpg 0,751, Bo BAITAP Hoa tan hoan toan m gam hén hop Mg, Fe (ti 1é khéi lugng tuong ting la 6: 7) vao dd HCI du, sau phan ting thu duige dd X chita 3 chat tan c6 til mol 18 2:1: 1 va 672 ml khi Hi, (dk). Nhé dd AgNO, du vao dd X., sau khi phén ting hodn ton thu duigc khi NO (san phim khit duy nhét citaN") va a gam ket tia. Gié tr clla m la: A. 10,045, B, 10315, cus D.861 1 Huéng din: MgCl, : 2x AgCl 4: 7x =0,07 ; FeCl, x A825 MB:X go, on MB) ag Lx 2% =0,0025 m=10,315g Fe:y HCI:x 7 H, 10,03 —>nyq = 0,06 = 6x = x=0,01 2x 2 = 2k 2 Soy 1 Dap nB Ghi nhé: sit hai vé sit ba nhudng 1 e, nhan eli: 4H" +NO; *4NO+2H,0 Ag’ +le—>Ag Hoa tan hoan toan hn hop gém 1,12 gam Fe va 1,44 gam FeO bang 300 ml dung dich HCI 0,4 M, thu dutgc dung dich X. Cho dung dich AgNO, dut vio X, thu duige khf NO (sin.pham khit duy nbat cia N°*) va m gam két tila, Biét cic phan ding xdy ra hoan toan. Gid tri cia mit A.20,46 B.21,54 C183 D915 1 Hugng dan: AgCld:0,12 ABs my i Ag L:0,04-3. ne Fe:0,02 —scvos Fe0:0,02 =0,01 = =18,3g Dap nC Hoa tan m gam hén hgp FeCl, FeCl,, CuCl, vao nuéc dugc dung dich X. Suc H,$ du vio thay xudt hign chat rin ¥ nang 1,28 gam va dung dich Z. Cho Z tac dung véi dung dich AgNO, du thay c6 22,25 két tia, Hoa tan Y trong HNO, dui théy thost ra 1,4 gam khi duy nhat. biét céc phan ting xdy ra hoan toan, sin phdm khit N’* la NO. Gis tri m gin nhat v6i gid tri? A.84.gam B.9,4 gam C.7,8 gam D.7,4gam 1 Huéng dan: FeCl, Beh eet FeCl 1 CuCl, Zs 7 AgNO 22, 25gam Age HCl Ag 2FeCl, + H,S—> 2FeCl, +2HC1+S1 CuCl, +H,S——> CuS + 2HCI s 1,28gamY —P2NO:14g Cus sia 32a+646=1,28_ fa=0,02 $:0,01 peer (e ae ain a ee prce he8eam ¥ inal ne FeCl, :x+0,02 AgCl:2x+0,08 => } FeCl, : 0,02 2 7 E 222.250 rete HCI:0,04 Ag:x +0,02-0,03=x-0,01 CuCl, :0,01 FeCl, :0,03, => 395x =11,85 => x =0,03 mol = mg ;FeCl,:0,02 > m=8,41g Cucl, :0,01 Dp én A Cho 27,04 gam hén hgp ran X gém Fe, FeO, Fe,O, Fe,O, va Fe(NO,), vio dd chita 0,88 mol HCI va 0,04 mol HINO,, khudy déu cho céc phin ting xay ra hodn toan, thu duge dd Y (khong clita ion NH,*) va 0,12 mol hén hgp khi Z gm NO, va N,O. Cho dd AgNO, dén du TsMega book vao dd Y, thay thoat ra 0,02 mol kh NO (sin phém kh duy nit); d6ng thoi thu duge 133,84 gam két tia. Biét ty 1g mol cia FeO, Fe,O,, Fe,O, trong X lén lugt fa 3: 2: 1. Phin trim s6 mol iia Fe cé trong han hgp ban du gaa nhat v6i: A. 48% B.58% €.54% D, 46% Huéng din: Fe :0,13 Fe:x Fe :0,18 mol /AgCl 1: 0,88 ae plo ete, 27,04 gamX:4 Fe,0,:28 28888251 |” :0,08 mot ere Fe,0,:0 H,0:0,42 Fe(NO,),:y 0,12 mot NOz*_, foF4d=012 ee MONYN,O:4 |460+44d=5,44 = ¥=0,06 mol n® = 0,84 = 28a +2,0,08+10.0,04 = a=0,01=3 x =0,14 = %np, =53,84% Dap anc Ghi Nhé: Cho khéi lugng két ta A BCT ay ra mol Agsuy ra H? du suy ra mol Fe Agl: - vi phan ting xay ra hoan toan dung dich cé H’ va Fe™ nén khong thé c6 ion NO; Cho 7,84 gam Fe vo 200 ml dd chtia HCI 1,5M va HNO, 0,5M, thay thodt ra khi NO (khi duy nhat) va thu dugc dd X. Cho dd AgNO, dit vio dd X, thu duige m gam chét rin. Biét NO 14 sin phd khit duy nat ctia NO,.. Gié tri cha m la A.48,45, B. 56,01. C. 43,05. D, 53,85. 1 Huéng dan: Fe sa ‘AgCl:0,3 Fe:0,14 mol poy?) Fe" sb AA {i ne cl :0,3 E AgCl: Ag:0,12 = =0,12 Be 0,14 =f OL 3 n= 56,0lgam 2a+36=0,3 home| Dép in B BD 6 6,16 gam Fe trong 2,24 lit (dktc) hon hop khi X gm Cl, va ©, thu dugc 12,09 gam hén hgp Y chi gém oxit va mudi clorua (khong con Kkhi du). Hoa tan Y bing dd HCl (vita di), thu duigc dd Z. Cho AgNO, du vio Z, thu duge m gam két tia, Gi tri cia m 1a A.27,65. B.37,31. C.44,87, D. 36,26,1 Huéng dan: i. Fe" :0,11 ii ta atb= 0,11 mol Fe +0,1 mol] —* [12.0 cr :2b fe cae anf b i‘ i: Poet . OF 128 ol ie Fe" :0,11 AgCl: 0,26 = [or :01g PBs fF POT eo, pug JAB O26 _ sa. s7g 07 lo 10,06 1 :0,26 Ag:0,07 mol Dép inc Hoan tan hét m gam g6m Fe va mét oxit sit (Fe,O,) trong 800ml dd HCl 1M (vita dit) 8 : ie thu duige dd X va 1,792 lit khf H, (@ dktc). Cho dd X téc dung véi dd AgNO, du thu duige 132,08 gam két tia. Gid tri m la: ‘A,21,5472 gam B, 25,6 gam €.27,52 gam D. 23,04 gam 1 Huéng dan: n H, :0,08 mol aa © _wcosmet 5 aq x J Fe M5 139,08 g AEC OF, 5 0,16 mol Fe,0, Agia Cl :0,8 mol Fe* :0,16 mol =0,32 mol =n =0,16 mol => dd X j Fe" :0,16 mol cl afr 2 8 mol = nk = 0,32 mol m=23,04 mol Dap an D Cho m gam bét Fe vao binh kin chita déng théi 0,06 mol O, va 0,03 mol Cl,, r6i dét néng, Sau Ihi céc phan itng xay ra hoan toan chi thu dutgc hén hgp chit rin chita céc oxit sit va musi sat. Hda tan hét hén hop nay trong mét lung dung dich HCI (léy dut 25% so voi lugng cin phan ting) thu duge dung dich X. Cho dung dich AgNO, dut vao X, sau khi két thiic céc phan ‘ang thi thu duigc 53,28 gam ket tha (biét san pham khif clia N**& khi NO duy nit), Gi tri cia m 1a? A.6,72 B. 5,60 C.5,96. D, 6,44. Huéng dan: Eo Fe": O, :0,06 i Cr :0,36 war 8 | 8S oF :012 oe O* 20,12 i H*:0,06 iSe Lad fa /AgCl: 0,36 EEC 882.5 53,28 gam snk, <3. +n,, =0,06 mol Ag:0,015 mol ace 3m, HA, #2ihg += 37H yg =0,36=> ny, = O12 my 6728 Dip én A [XETED bét chay hén hop gém 1,92 gam Mg va 4,48 gam Fe véi hdn hop khi X g6m clo va oxi, sau phan ting chi thu duige hén hop Y gém céc oxit va mu6i clorua (khong cdn Khi dui). Hoa tan Y bing m6t ligng viia ti 120 ml dung djch HCl 2M, tha duige dung dich Z. Cho AgNO, durvao dung dich Z, thu duigc 56,69 gam két tia, Phin tram thé tich cia clo tronghdn hop Xa A.51,72%. B.53,85%. C.56,36%. D.76,70%. Mm Huéng dan: oe Mg** 0,08 20,08 HeL024m!_4) Fe 0,08 ian CF :2a+0,24 2a nen /AgCl:2a+0,24 0,08 28 55,00{ eee CY :2a+0,24 tg= = FHS = 0,12 mol = b= 0,06 mol Dg = 0,08.2 + 0,08.3-2a—0,06.4 = 0,16-2a AgCl:2a+0,24 Ag:0,16~28 = 4,97 = Tla = a =0,07 = %ng, = 53,85% = 560m Dap inB Héa tan 1,12 gam Fe bing 300 ml dung dich HCI 0,2 M, thu dugc dung dich X va khi H, Cho dung dich AgNO, du’vao X, thu duigc khf NO (sin phim khtt duy nhat ctia N*9) vam gam két tia, Biét cic phan ding xdy ra hoan toin. Gi tri cha m la A. 10,23 B.861 C.7,36 D.9,15 Huéng dan: +1, 0,02 AgCl: 0,06 FeCl, :0,02_ sso. fc = m=9,15¢ Fe0,02 Hanon ° HCI: 0,02 Ag: 0,005 Dp an D ‘Tron 8,1 gam Al véi 35,2 gam hén hgp rin X gém Fe, FeO, FeO, Fe,O, va Fe(NO,), thu duge hén hgp Y. Héa tan hoan toan Y vao dung dich chifa 1,9 mol HCl va 0,15 mol HNO,,Khudy déu cho cdc phan ting xay ra hoan toan, thu duige dung dich Z (khong chiia muéi amoni) vi 0,275 mol hén hgp khfT gém NO vi N,O. Cho dung dich AgNO, dén du vao dung dich Z, Sau khi cdc phan ting xy ra hoan toan thu duige dung dich M; 0,025 mol khi NO (sin pham kkhit duy nhat cia N") va 280,75 gam két tia, Phan trm khéi lugng cia Fe(NO,), trong ¥ 1a A.4157%. B.62,35% C.76,7%. D.51,14%. @ Huéng dan: NO 275 mol 0,275 mo! fe te AP*:0,3 35,2 gam X ig sie : 11,9 mol Rr [areeeeeea | aee gt2e1__5) 7.:)Fe™ 20,2 mol 42 >| 2en7s{ 80 ide Fe,0, 0 aes Ag:0,075 Fe(NO,),, A rn NO:0,025 mol Al:0,3 mol a Balt 5H,0:0,975 nZ,, =3.tyg +N, =0,15 mol NO:x _ fxty=0,275 > > N,O:y ” |30x+44y=9,3 YomMeso,), =41457% 0,275 oit| = Ngo, =0,1mol 2 = 0,075 Dap an A Hoa tan hét 20,0 gam hén hop X gém Cu va cdc oxit sét (trong hén hop X oxi chiém 16,8% vé khéi luigng) bing dung dich A chita hdn hop b mol HCl va 0,2 mol HNO, (vita dit) thu dugc 1,344 lit NO (dktc, la san phim khit duy nhat cba N**) va dung dich Y. Cho dung. dich ¥ tac dung v6i mot lugng vita di dung djch AgNO, thu dutgc m gam két ta va dung dich Z. Cho dung dich Z tac dung véi mot lugng dit dung dich NaOH, loc két tha, nung dén khéi luigng khong d6i thu duige 22,4 gam chat rin. Cac phan ting xay ra hoan toan. Gid tri cta m la A.83,29, B.7681. C. 7033. D.7897 Huéng din: NO:0,06 mol 7 ei - eae Jd 2245 29, 4 gam fees a ih ES 205 :0, 8 \Fe Barn | y A ®, 0:3,36g AgCl:b Ag:x 64a +56D=16,64_ fa=0,12 => = [80a + 80b = 22,4 b=0,16ec lead 0,42+0,06.4 = b=0,46 mol Ny +4. = b+0, —¥£40,12.2+0,16.3 = 0,21.2+0,06.3+x = x =0,12 AgCl 0,46 =mg eC Ag 1:0,12 Dap an D 3 m=78,97g [XENEED Cho hin hop chita 20,88 gam Fe,O, va 3,84 gam Cu vao dung dich HCl loang du, tha 204 i 8 duige dung dich X. Cho dung dich AgNO, dui vio dung dich X, thay thoat ra 0,045 mol khiNO. (sin pham khit duy nbét); déng thai thu dugc m gam ket tia, Gi trim li, A. 137,79 gam B. 137,25 gam C.111,42 gam D. 138,78 gam Huéng din: ‘NO :0,045 ee 0,09 sy |CuCl, :0,06 Cu:0,06 Fect,:0,06 | m yas i f se Ag:0,21-3.0,045 = 0,075 HCl: = m=137,258 2=4iny. =0,18 Dép dn B Hoa tan hét m gam hdn hgp g6m Fe va mt oxit sat (Fe,O,) trong 400 ml dung dich HCL IM (viia dia) thu duigc dung dich X va 0,896 lit khi H, (dktc). Cho dung dich X tac dung vita dit voi dung dich AgNO, dui thu duigc 66,04 gam két tita. Gi tri clia m Ja A.17,52 B. 11,55 C. 11,52 Dz 15,62 © Hudng dan: (Fe.0,) ya: eams_ 4p, -0,04 mol = | F6ay = 016 mol Fe Fe: 0,04 Fe elo Fe** :0,08 =| Fe | AS. 5 66,04 gam ABO 5 x] Fe 10,08 : Ag:0,08 Cr :0,4 mol Cl :0,4 mol = m=11,52g Dap an C Cho m gam hén hgp bét X gém Fe,O,, CuO va Cu (x, y nguyén dutong) vao 500 ml dung dich HCI2M, thu dutgc dung dich Y (khéng chia HCl) va cdn lai 3,2 gam kim loai khong tan. Cho ¥ tac dung voi ligng du dung dich AgNO,, thu duigc 175,9 gam két tita. Biét cc phan wing déu xdy ra hodn toan, Gid tri cia m gin nhat véi gid tri nao sau day? A341, B. 27,5. C. 40,7. D. 29,1, eal1 Huéng dan: Fe,0, FeCl, : |AgCl cud ~sustsy| 7 jsf gCl:1 = x=0,3mol CuCl, 2b Ag eee 3 M436,5= Mpg, +Mog, +My +My, => M=40,8 g [ZEQMD Hos tan hoan toan hén hgp g6m 1,12 gam Fe va 1,44 gam FeO bing 300 ml dung dich HC10,4 M, thu duigc dung dich X. Cho dung dich AgNO, du vio X, thu duge khi NO (sin phém Khit duy nhat ctia N"9) va m gam két tha, Biét céc phan ting xy ra hoan toan, Gid tri cba mh A. 20,46 B. 21,54 C. 18,3 D.9,15 ™ Huéng dan: EID Hoa tan hoan toan 31,66 gam hén hgp X g6m Al, Zn, FeCl, va Fe(NO,), trong dé Al cé héi ltigng m gam vao dung dich chifa 0,78 mol HCI chi thu duge dung dich Y va 0,896 lit khi NO (dktc). Cho tié tit AgNO, vao dung dich ¥ dén khi cac phan ting xay ra hodn toan thi thay higng AgNO, phan ting la 0,995 mol, két thie phan ting thu duige 142,25 gam ket tira va 0,112 lit kai NO (kt, sin phim khit duy nat ctia NV) va dung dich Z cha m, gam mudi. "Tg (m + m,) gn nat v6i gid tri ndo sau day: A.80,75 B, 82,99 c.82,90 D.80,70 Hung din: Agia _ fa+b=0,995 a=0,015 = = AgCl:b ~ [108a+143,5b=142,25 [b=0,98 ‘Ag:0,0 n¥, = 4.0,005 = 0,02 yen JAB! OP15 x0 :0,005 1" AgCl:0,98 n¥.,, =0,02.0,75+0,015=0,03 Bao toan mol Clo FeCl, :x mol— 2x +0,78 = 0,98 => x=0,1 Ta lai odcasa’ Nyc, = 0,78 = 4.99 +10.m, $0,029 aye = Bio todn nguyen t6 nito ta lai c6 Fe(NO,), :y —+2y =0,04 +0,06 = y =0,05 mol Alsa Zn:b FeCl, :0,1 Fe(NO,), :0,05 31,66gam: = 27a+65b=9,96 Dung dich Y Fe** :0,03 Fe” :0,12 HY :0,02 NH; : 0,06 Hons g48 | 3a+2b=0,48 0,08 a ft => m=2,16 = 27a+65b=9,96 ” |b=0,12 2 Zn :b AP a Cr :0,98 Fe™* :0,03 Fe" :0,12 Fe™* :0,15 NH; :0,06 NE} :0,06} 85 m,g Z :4Zn™ :0,12 } => m, = 80,82 => m+m, = 82,98g Zn™ :b AL 30,08 AP a NO; :0,99 Cr :0,98 Dap inB Hoa tan hét hén hgp X chita 22,4 gam Fe-va 8 gam Fe,O, trong dung dich HCI loang thu vig 10,08 lit kh H, (dkctc) va dung dich ¥ chi chtia céc musi. Cho dung dich AgNO, dui vio dung dich ¥ thu duge m gam két tita. X4c dinh gid tri cla m: A.204,6 B2145 C.198,2 D. 1724 1 Huéng dan: 05,0 = 0.152 nyq = 1,2 (mol)Eons apc 1,2 —+m,=204,6 (gam) | HE 4g:0,3 ‘ | Dap an A Xlahén hop chtta MgO, CuO va cfc oxit cia sit (Biét trong X phin trim khéi lugng cita oxi 18 26,82%). Hoa tan hét 10,44 gam hén hgp X bing lugng dung dich HCl (dut 20% so vé lugng phan ting) thu duge dung dich Y, Cho KOH du vao Y loc ket tia r6i nung trong khong hi tdi khh6i lugng khong d6i thu duge 10,8 gam hén hgp oxit. Mat khac, cho AgNO, du’ vio Y thay c6 m gam Két tia xuft hign, Céc phan ting hoan to’n. Gia tr) cla m Bs: A. 64,18 B. 68,44 C.72,18 D. 60,27 = Huéng dn: Ta c6: nfo = 1OANO.2682 _ 9.175 tty =0,175.2-+ 0,2.0,175.2 42 (mol) 10,8-10,44 6 V6i oxit khi nung: sy, 2=0,045 Khi cho AgNO, {is nh, = 0,015 045 omy, = Mac, =0,42.143,5 = 60,27 gam Dap nD [XETED cho 6,48 gam hén hgp X gém Fe, FeO, Fe,O, va Fe,O, phan ting hét véi dung dich Y chia HNO, va HCI theo tile tuong ting 14 7:10 vé sé mol thu dutgc 0,672 lit NO va dung dich Z, dung dich Z héa tan t6i da 3,36 gam Fe, sinh ra kh{ NO va dung dich T. Néu cho AgNO, du vao T thi thu duigc m gam két ta, Biét trong céc phan ting NO la sin phém khit duy nhat ciia N®. Gia tri ca m gan nhat voi: A.45 B.46 C47 D.48 1H Hudng dan: Cho Fe vao Z co khi NO bay ra = Z co H” du = mu6i trong Z 14 Fe** Fe: onan dae O:b 3a=2b+0,03.3, b=0,09 nr, =0,09.2 + 0,03.4=0,3(mol) sas Fe:0,15 0:0,09 Fe** : 0,15 Typ = 0,04 —>T{ NO; : 7x 0,04 B2=9x =0,02 Cr 10x a tse3a6-9.84/ E54 0,15.2=0,09.2 +32 ayoSec wo,_, fABC1=0,2 if ase 0,15 —m = 44,9 (gam) Dap an A Hoan tan hét m gam gém Fe va mét oxit sit (Fe,O,) trong 400ml dung dich HCL 1M (vita i) thu dulge dung dich X va 0,896 lit khi H, (6 dktc). Cho dung dich X téc dung voi dung dich AGNO, du thu dugc 66,04 gam két tia, Gid tri cia m la 15,62. B.11,55. C.11,52. D.17,52. 1 Huéng dan: Tyg = 0.4 0,4-0,04.2 Tacé:) en eam a {ir cg Ke 0.16 (mol) Tet ap oad erertitt Ag :0,08-—22 + Fe’ cr :0,4 ‘Vay dung dich X chita: }Fe™* :0.08 | #21 5 Fe* 30,08 ——>m =0,16.56 +0,16.16 = 11,52 (gam) Dap dn C Dé 16,8 gam phdi sit ngodi kh6ng khi mét thi gian, thu duge 21,6 gam hén hgp rin X gém Fe va cdc oxit Fe. Hoa tan hét X trong dung dich HCI loding du, thu duige 1,344 lit khi H, (dlktc) va dung dich Y. Cho dung dich AgNO, dut vio dung dich Y, két thiie phan ting thy thodt ra 0,03 mol khi NO (sin phém khit duy nhét); déng thai thu duigc m gam hén hop két tita, Gid tri cha m la A. 130,26 gam B, 128,84 gam C, 132,12 gam. D, 126,86 gam m Huéng dan: =26-168 45 Nyc, = 0,3.2 + 0,06.2+0,03.4 = 0,84 168 Dy. = =0,3—2290,3.3=0,3.2+0,06.2+0,08.3-+1n, —omy, = 0,09 KBP S2 > AgCI:0,84 —_—) — nm, =130,26: mm fr 0,09 a bieeu Dap an A alHoa tan hét hn hgp X chtta 21,28 gam Fe va 9,28 gam Fe,O, trong dung dich HCl loang thu duigc 9,856 lit kh H, (dtc) va dung djch Y. Cho dung dich AgNO, du vao dung dich Y thu duge 1,34 lit kh NO (kt, sin phim khii duy nbét cia N") vi.m gam hdn hop két tia. Xéc inh gid trj cha m: A.214,6 B. 219.6 C.248,2 D.2024 @ Huéng dan: EMTs tyg =1,44 (mol) a= 0,3 2S eM 20,5—a mires AgCt:1,44 mn, =219.6 (gam) FE +Ag:0,3-0,06.3=0,12 = Dap an B ( eartap ren woven: Cho 30,88 gam hén hgp gém Cu va Fe,O, vao V lit dung dich HCl 2M duigc dung dich X-va con Iai 1,28 gam chit rin khong tan. Cho dung djch AgNO, du t4c dung véi dung dich X duige 0,56 lit khi ¥ (6 dtc) khéng mau hod nau trong khéng kh{-va m gam ket tia, Biét céc phan ting xay ra hoan toan. V va m ln higt fa A, 5,04 lit va 153,45 gam. B. 0,45 lit va 153,45 gam. C. 5,04 lit va 129,15 gam, D. 0,45 lit va 129,15 gam. ‘Cho 5.5 g hén hgp bot Al va Fe (cé ti é mol tuong ting 2:1) vao dung dich chita 0,45 mol HCI, sau dé cho tiép 500ml dung dich AgNO, IM thu dig m gam chat ran. Biét ring cée phan ting xay ra hon toan, sn phim khit duy nhat cia HNO, loang la NO, tinh m? ‘A.65,925 B. 64,575 C. 69,975, D71,75 Hoa tan hét 24,018 gam hén hop chat rin X gm FeCl,, Fe(NO,),, Cu(NO,), va Fe,O, trong dung dich chtfa 0,736 mol HCl, sau phan ting thu duigc dung dich ¥ chi chita 3 muéi va 0,024 mol khi NO. Cho dung dich AgNO, du vio Y thu duige 115,738 gam két tia, Biét NO 18 san phém khit duy nhit cua N°, Phan tram vé s6 mol cia FeCl, trong X cé gid tri gén nhat véi: A. 15% B. 18% C.22% D.25%oka’ Hoa tan hét 17,76g hdn hgp X gém FeCl, ; Mg ; Fe(NO,), ; Al vio dung dich chita 0,408 mol HCI thu duigc dung dich Y va 1,6128 lit khi NO (dkte), Cho ti tit AgNO, vao Y dén phan (ing hoan toan thi thay lugng AgNO, phan ding 1a 0,588 mol, két thiic phan ting thu duge 82,248g két tita va 0,448 lit khi NO, (dktc) va dung dich Z chi cé m gam muéi. Gid tri m gan nhit véi: AA B.41 C43 D.44 [XELED it 6,16 gam Fe trong 2,24 lit (dktc) hn hop khi X gém Cl, va O,, thu duige 12,09 gam hén hgp Y chi gém oxit va muéi clorua (khong con Khi du), Hoa tan Y bang dung ich HCI (vita di), thu duige dung dich Z. Cho AgNO, du vao Z, thu duige m gam két tia. Gié tri cia m la A. 27,65. B. 37,31 C.44,87, D. 36,26. Dt chéy 6,56 gam hén hop Mgva Fe trong khi O,, thu dutgc 9,12 gam hn hgp X chi g6m cac oxit. Hoa tan hoan toan X trong dung dich HCI vita di, thu dugc dung dich Y. Cho dung dich NaOH du vio Y, thu duge két tia Z. Nung Z trong khong khi dn khéi ligng khong di, thu duge 9,6 gam chat rin. Mat khéc cho Y téc dung vi dung dich AgNO, du, thu duge m gam két tha, Gié tri cham A.43,2. B. 32,65. C.45,92. D.52,4. Dét chay hén hp gém 1,92 gam Mg va 4,48 gam Fe véi hén hgp khi X gém clo va xi, sau phan ting chi thu duge hén hgp Y g6m céc oxit vi muéi clorua (khong con Khi du). Hoa tan Y bang m6t higng vita dit 120 ml dung dich HCl 2M, thu duge dung dich Z. Cho AgNO, du vao dung dich Z, thu duige 56,69 gam két tia. Phan trim thé tich cia clo trong hdn hop X la A.51,72%. B.53,85%. C.56,36%. D.76,70%. [XELED Tin banh dign phan 100 gam dung dich chtia 0,2 mol FeCl, 0,1 mol CuCl, va 0,16 mol HCI (dign cyc tra) dén khi bat dau c6 kh thodt ra 6 c hai cyc thi ding dign phan. Dem phén dung dich sau dign phan tac dung hét v6i 150 gam dung dich AgNO, két thiic phan ting thu duige 90,08 gam két tia va dung dich chtta mot musi duy nhit c6 néng 46 a%. Gid tri cla a gan nhdt v6i gid tri ndo sau day ? A. 30,5. B. 35,5. C.34,5. Dz 33,5. [XELED Hoa tan hét 23,76 gam hén hop X gém FeCl,; Cu va Fe(NO,), vio 400 mi dung dich HCI 1M thu duge dung dich Y, Cho tif tit dung dich chifa AgNO, 1M vao Y dén cdc phan ting hoan thay da ding 580ml, két thuic thu duigc m gam két tia va thoat ra 0,448 lit khi (6 dtc). Biét NO la sén phém khit duy nhat cia N* trong cd qué trinh, gid tri cla m gan nhét véi: A. 82. B. 80. C. 84. D. 86. [LXEDED cho 2,8g Fe tic dung hoan toan véi V ml dung dich HNO, 0,5M thu duige sin phim khit NO dluy nhat va dung dich X. X cé thé tac dung vdi t6i da 0,03 mol AgNO,, Gid tri cha'V Ia: A. 240 B. 160 €.320 D.120 alCho 7,84 gam Fe vao 200 ml dung dich cha HCl 1,5M va HNO, 0,5M, théy thodt ra khi NO (Kkhi duy nhit) va thu duigc dung dich X. Cho dung dich AgNO, du vio dung dich X, thu duigc m gam chat ran, Biét NO la sin phdm khit duy nhat cita NO,. Gid tri cla m 1a A.48,45, B. 56,01. C.43,05. 1D. 53,85. D6t chay m gam hén hgp gém Mg va Fe trong oxi mot théi gian thu duge (m + 4,16) ‘gam hén hop X chita cdc oxit. Ha tan hoan toan X trong dung dich HCl vita di thu duige dung dich Y chita (3m + 1,82) gam mudi. Cho AgNO, du vao dung dich Y thu duge (9m + 4,06) gam két tia, Mgt khac hoa tan hét 3,75m gam hdn hop X trong dung dich HNO, long dui thu duge dung dich Z chia m gam mu6i. Gid tri cba ml A. 107,6 B.161,4 C. 158,92 D.173,4 D6t chay m gam hén hgp X g6m Cu va Fe trong 2,912 lit (dktc) hén hgp khi gém Cl, va , thu duige (m + 6,11) gam hén hgp Y gém cdc mudi va oxit (khdng thay khi thoat ra). Hda tan hét Y trong dung dich HCl, dun néng thu ditgc dung dich Z chi chtta 2 muéi. Cho AgNO, du vao dung dich Z thu duigc 73,23 gam két tia. Mat khac héa tan hét m gam hén hgp X trén trong dung dich HNO, 31,5% thu duoc dung dich T va 3,36 lit khf NO (sin phém khit duy nhat; dktc). Nong a C% cia Fe(NO,), cé trong dung dich T gan nbét vdi gia tri nao sau day? A. 8%, B. 7%. C.5%. 1D. 9%. Cho 12(g) hén hgp Fe va Cu t7é mol (1: 1) vao 200ml dung dich chtta HCI 2M va HNO, 0,5M. Sau khi phan ting xay ra hoan toan thu duigc dung dich A , kh NO va mét phn kim loai Khéng tan, Lay toan b6 dung dich A cho téc dung vdi ligng du dung dich AgNO, , thu duge m(g) két tia (biét sin phim khit cia N°S tgo ra NO duy nha). Xéc dink m: A574. BL 55,6. C. 60,1. D. 68,2. ‘Nhigt phan hoan toan 0,1 mol mudi M(NO,), thu duge 5,04 lit hén hop kai (6 dtc) va 8 gam chat ran, X la hén hop gém RBr va MBr, vdi s6 mol bang nhau. Lay 31,9 gam hén hgp X tac dung véi dung dich AgNO, du thu dugc 67,2 gam két tia. Téng s6 proton cé trong nguyén tM vaion RA? A.37. B.35. C38, D.36. Cho hén hgp chita 20,88 gam Fe,O, va 3,84 gam Cu vao dung dich HCI loang du, thu dug dung dich X. Cho dung dich AgNO, du vio dung dich X, thay thoat ra 0,045 mol kh{ NO (san phdm khit duy nhét); déng théi thu dugc m gam két tia. Gid trim lA. A. 137,79 gam B. 137,25 gam C.111,42 gam D. 138,78 gam Hoa tan 1,12 gam Fe bing 300 ml dung dich HC10,2 M, thu duoc dung dich X va khi H,. ‘Cho dung djch AgNO, du vao X, thu duigc khi NO (sin phém khit duy nhét cita N"9) vm gam két tha, Biét cdc phan tng xay ra hoan toan. Gia tri cua m 1a A. 10,23 g B.86lg C.736 8 D.9,15g Dien phan véi dién cyic tro 200g dung dich hén hop chia 0,3 mol FeCl, 0,1 mol CuCl, 0,2 mo! HCI dén khi khi bat dau thoat ra 6 catot thi ngat dong dign. Dé yén binh dign phan r6i thém 250g dung dich AgNO, vita dit vao, phan ting xy ra hoan toin duge 156,65g két tia, V aa La lit khf (dtc) va dung dich ¥ chtia 2 muéi, Néng 46 phan tram ctia mudi cé phan tit khéi lén, hon trong Y 6 gia tri gan nhat vei, A27 B25 G15 D.18 Cho 19,39 gam hén hgp Cu(NO,),, Fe,O,, FeCl, vao 500 ml dung dich HCl 1M duge dung dich X va 0,03 mol NO. Cho AgNO, vita dit vao X duigc 86,1 gam két tita va khong thay hi thoat ra, Mat khdc, X tac dung véi t6i da m gam Fe lai thay xudt hién NO (dktc). Biét NO 18 sin phim khit duy nhét cia N*8, Gid tri cfia m la A. 6,02 B56 C.7,28 D.616 ‘Hoa tan hét m gam hén hgp gdm Fe va mét oxit sat (Fe,0,) trong 400 ml dung dich HCL IM (vita di) thu dug dung dich X va 0,896 lit khi H, (dtc). Cho dung dich X téc dung vita di vi dung dich AgNO, du thu duige 66,04 gam két ta. Gid tri cha m a A.17,52 B. 11,55 C1152 D. 15,62 [ETE Hoa tan hoan toan 1,609 gam hén hop 6 dang bét g6m Fe va Al vio 40 ml dung dich HCI7,3% (D=1,1 g/ml) thu dugc dung dich Y. Thém 700 ml dung dich AgNO, 0,2M vao dung dich Y, khudy ki thi sin phém thu duigc chi c6 két tika va dung dich Z. Loc bé két tia, 06 can phan dung dich Z,léy chat ran thu duige dem nung trong binh kin dén khéi ligng khong déi thu duige m gam chat rén, Gié tri m la, A.5,779 gam. B, 3,294 gam. C.8,101 gam. D. 6,023 gam. Cho 7,84 gam Fe vio 200 ml dung dich chita HCl 1,5M va HNO, 0,5M, thay thodt ra khi NO (khi duy nht) va thu duigc dung dich X. Cho dung dich AgNO, du vao dung dich X, thu duigc m gam chit rén, Biét NO la sin phém khit duy nhat cha NO,.. Gid tri cia m Ba A, 48,45. B. 56,01. C. 43,05. D. 53,85. Hoa tan hét 17,76g hn hop X gém FeCl, ; Mg ; Fe(NO,), ; Al vio dung dich chita 0,408 mol HCI thu dugc dung dich Y va 1,6128 lit khi NO (dktc), Cho tii tit AgNO, vao Y dén phan ‘ing hoan toan thi thdy lugng AgNO, phan ting la 0,588 mol, két thiic phin ting thu duge 82,248g két tha va 0,448 lit khi NO, (dktc) va dung dich Z chi cé m gam muéi, Gid tri m gén nhat véi : A.42 B41 C.43 D444 Hoan tan hét m gam gém Fe va mot oxit sat (Fe,O,) trong 400ml dung dich HCl 1M (vita ii) thu dug dung dich X va 0,896 lit khf H, (& dktc). Cho dung dich X tc dung vi dung dich, AgNO, du thu duige 66,04 gam ‘két tita. Gia tri cha m lA A. 15,62. B.11,55. 11,52. D.17,52. [XETEED Ha tan hét 3,36 gam bot Fe vio 180 ml dung dich HCI 1M, thu duge dung dich X. Cho ga 8 X téc dung véi luigong dit dung dich AgNO, sau khi két thic cdc phan ting thu duige V lit khi NO (san phém Knit duy nhat, dtc) va m gam chat ran, Gid tri cia m va V lén hot la A. 18,3 va 0,336, B, 18,3 va 0,224. €.27,45va0336. 1D. 27,45 vA 0,224. El‘Hoa tan hoan toan hén hop gém 2,8 gam Fe va 1,6 gam Cu trong 500 ml dung dich hén hgp HNO, 0,1M va HC] 0,4M, thu duge khf NO (khi duy nhat) va dung dich X. Cho X téc dung hét véi dung dich AgNO, du, thu duige m gam chat ran, Biét céc phan ting déu xay ra hoan toan, NO li sin phim khit duy nhat cita N* trong céc phan ting. Gid tri cia m 1a A. 28,70. B. 30,05, €.34,10, D.29,24, Héa tan hét 2,24 gam bét Fe vio 120 ml dung dich HCI 1M, thu dugc dung dich X. Cho X tac dung véi lvgng du dung dich AgNO, sau khi két thiic céc phan ting thu duge V lit NO (dktc,la san phdm khit duy nhat cia N) va m gam chat ran. Gié tri cia m va V Han hugt la? A. 18,3 va 0,224. B. 18,3 va 0,448. C.17,22 va 0,224. D, 1,08 va 0,224. [XETED Hoa tan m gam hén hop A gém FeO vao Fe,O, bing luigng vita dit dd HCI, sau phan ting thu duge dd B. Cho %4 da B tae dung véi dd NaOH du, ket tia thu duc dem nung trong khong hi dén khéi lugng khong d6i dugc 40 gam chit rin. Cho % dd A cin lai tac dung vai lugng du dd AgNO, thu duige 208,15 gam chat ran, Gid tr] ofia m la A. 76,8 B. 38,4 C624 D. 1248 Cho hén hop gém 25,6 gam Cu va 23,2 gam Fe,O, téc dung v6i 400 ml dung dich HCl 2M cho dén khi phan (ing hon toan thu duigc dung dich A va chat rin B. Cho dung dich A phan ting véi dung dich AgNO, du tao ra két tita X. Lugng két tia X14 A.32,4.gam. B.114,8 gam. C.125,6 gam. D.147,2 gam Cho 1 loai oxit sit tac dung hét véi dung dich HCI vita di, thu duige dung dich X chita 3,25 gam mudi sit clorua. Cho dung dich X tac dung hét v6i dung dich bac nitat thu duge 8,61 gam AgCl két ta, Vay cong thita ciia oxit sét ban du Ia A.Fe0, B.FeO CFe0, D.Fe0, (XEEED cho 54,04 gam hin hgp g6m Cu, Fe,O, vao dung dich HCI thu dutge dung dich X va con 2,24 gam chat rn khéng tan. Cho dung dich AgNO, du vio dung dich X thu duige 0,98 lit khi Y khong mau hod naungoai khong khi (sin phém khit duy nhat, 6 dtc) vam gam két tia, Biét cfc phan ting déu xy ra hodn toan. Gié tr ciia m la: A. 268,54, B, 226,01. C. 282,71. D.277,99. Cho 12(g) hén hop Fe va Cu t7 18 mol (1: 1) vao 200ml dung dich chifa HC12M va HNO, 0,5M. Sau khi phan ting xay ra hoan toan thu dugc dung dich A, khi NO va mét phén kim loai KhOng tan. Lay ton bo dung dich A cho téc dung véi lugng du dung dich AgNO, , tha dutge m(g) két tia, (biét san phdm khii cia N** tgo ra NO duy nhét), Xée dinh m: A574, B.55,6, C.60,1. D. 68,2. [XETEED Hoa tan hét 2,52 gam bét Fe vio 130 ml dung dich HCl 1M, thu duigc dung dich X. Cho X tac dung véi hiong du dung dich AgNO, sau khi két thi céc phan ting thu duigc V lit khi NO (san pham khit duy nhét, dktc) va m gam chét ran. Gid tri cla m va V lan lugt La A. 20,275 va 0,224. B. 14,535 va 0,224. C. 18,3 va 0,448. D, 18,3 va 0,224.m) Mega book ‘Cho 100 ml dung dich AgNO, a mol/l vao binh chita 100 ml dung dich Fe(NO,), 2a ‘mol/l. Sau khi phan ting két thiic thu duigc 6,48 gam chat ran va dung dich X. Cho dung dich HCI du vio binh thi thu duige V lit khi NO(dktc). Gid tri cia V 1a 0,448 B12 C.0,896 D.0,672 Cho 26,4 gam hén hop gém Fe,O, va Cu (cé til s6 mol tuong ting la 2:1) vao 500 ml dung djch HCl 2M, thu duge dung dich X. Cho dung dich AgNO, dui vao X, thay thoat khi Khong mau hod nau trong khong khi, va con Jai m gam chat rin. Céc phan ting déu xdy rahoan toan. m cé gid tri gin nbét voi ALl47. B.149. C45, D153, ‘Oxi héa 5,6 gam Fe thu dutge 7,04 gam hn hop X gém FeO, Fe,O,, Fe,O, va Fe. Cho toan 6 hén hop X tac dung véi 100 ml dung dich hén hop HNO, 1,6 va HCl aM, thu dugc dung dich ¥ va 0,448 lit NO (dtc) la sin phim khtt duy nhat cita N**, Cho toan b6 Y téc dung véi mit lugng du dung djch AgNO, thu duige m gam két ta, Céc phan ting xdy ra hoan toan. Gié tri cua mia A. 20,83. B. 18,67. €.19,75. D. 22,99. Hoa tan hét m gam Fe,O, vio dung dich HCl vita di thu dugc dung dich X. Chia dung dich X thanb hai phan bang nhau: - Phan 1; Cho téc dung hoan toan véi dung dich AgNO, (du), sau phan ting thu duige 188,4 gam két tia. - Phan 2: Tae dung duge v6i t6i da x mol KMnO, trong dung dich H,SO, (khong tao ra SO.) Gid tri cla x la A. 0,24. B. 0,27. C.0,03. D. 0,48. [XETEDD Cho hin hop gém 0,4 mol Cu va 0,1 mol Fe,O, phan ting hoan toan véi 400 ml dung dich 8 0, ng HCI2M thu dutge dung dich A va chét rin B, Cho dung djch A téc dyng v6i dung dich AgNO, dui thu duige m gam két tha. Gié tri cla ma A443 B.147,2 C1433 D. 146,2 Hon hgp X gm Fe,O, va Cu (til mol ld 1; 2). Cho m gam X téc dung vita di véi dung dich chita 0,08 mol HCI, két thite phan ting thu dutgc dung djch Y va con lai m, gam chat rin Z. Cho dung dich Y téc dung v6i dung dich AgNO, du thu duige m, gam két tia. Gid tri cia my m, lin lugt la A. 0,64 va 11,48. B. 0,64 va 3,24. C.0,64 va 14,72. D.0,32 va 14,72. Hoan tan hét m gam gém Fe va mdt oxit sit (Fe,O,) trong 800ml dung dich HCI 1M (vita m=153,45g¢ HCl:b Ag:x = x+0,025.3=0,3 = x =0,225 mol => 2V =0,2+0,6+0,1= V =0,45 mol Dap an B uz AICI, :0,1 Al:0,1 ‘AgCl:0,45 mol 5,58 1 esses 5 Hoc}, 0,05 ABE 888 5 mg |ABCT=0,45 mol Fe:0,05 ek pias Ag:0,0125=m= 65,925g, Dap in A 24,018 FeCl,:x FeCl, Fe(NO3)):6 orémancr_,| ¥#} FeCl 82-9115, 738 gam —esmelel_ Cu(NO,), :¢ (CuCl, Fe,Q,:4 0,024 mol NO Ry, = 2g +4.ny, > a =0,08 mol Dung dich sau cing usage ‘AgCl:0,736+3x 1185= /Ag:3b4.2¢-0,0167 1,85 = 430,5x +324b+216¢ 85 2b +2e= 0,024 => b+e=0,012 0,02 25162, 5x +1800+188b=5,458 = 4b=0,006 = %ngc, HE 430,5x +32Kb + 2160 = 11,85 ¢=0,006 Dap in B Agia _, fa+b=0,588 _, [2 = 0.06 mol AgCl:b ~ [108a+143,5b=82,248 ” |b = 0,528 mol Ryo, =0,02 mol =n}, =2.0,02 = 0,04 mol = n¥.,, = 0,02+0,06 Dye = 408 = 4.ny +0,04-+10.n,,,, = n,.,, =0,008 mol Bao toan nguyén t6 nito: Fe(NO,),:x=32x= 08 => x= 0,04 Bio Toan mol Clo suy ra FeCl, : y mol = 2y +0,408 = 0,528 => y = 0,06 Bio toan mol Nguyén t6 Fe =0,1-0,08=0,02 AgCl:0,736+3x Ag:d = ty, = 3x +3b+0,72+2c-0,736-3x = 3b + 2c—0, 016 =e 199 =17,86% 0,112 1,08 molad Me" AP :d Mg™ :0,1 NEY : 0,008 SER AI* :0,02 pe wa_,|20430=9, + NHG :0,008 } => m= 43,9, ect a aca” cae tee Fe :0,02 Fe™ 0,1 Cr :0,528 NO; :0,568 H! 0,04 Fe Fe™ :0,07 sxsane+0.on( 54 } 12004 0: 0,06 B25} Fe™ 0,04 2 C1:0,14 CY :0,26 [a =0,03 = b=0,07 Fe:0,11 Omg ABCH:0,26 44,878 Cr 0,26 Ag;0,07 Dép én D xe Mi Mg Mg 6.56ean{ Fe, eet gam} Fe 5 y:) Fe eZ ste 00,16 mol [Cr :0,32 mol Mg**:1,04 7 Mg0:x Fe™ :0,06 AgCl:0,32 ‘ sg, a se{neo, 20,597 Fe" :0,04 Ag: 0,06 Cr :0,32mol 3 m=52,4¢ Dap an D e:0,08 : citolie ‘Mg: 0,08 Fe:0,08 ), (04:4 20,08 | erases! 5] Cy- 09,24 mot [4 Mg:0,08 } (Cl, : 0:28 z CF :2b eae ),06 mol ‘AgCl:2b+0,24 eee {is :0,08,3+0,08.2—0,06.4-2b = 0,16-2b > %Nng, = 53,85% Dap én B El =94,97=71b > b=0,07Dign phn dén khi bit dau c6 khi thoat ra 6 c& hai exc thi ditng dién phan, Nghia la 6 catot ion Cu vita dign phan hét Fe’ Fe)" 0,23 0,2 2c —Cl, +2e )™ Cu —5Cu 0,4—0,2 0,1 0,2 Dung dich sau dign phan Fe :0,2 HY 10,16 80, pen a 10,09 mol Cl 0,56 ae Kh6i lugng dung dich sau dign phan. mdd=100-m,, -mg, = 79,48 Khéi luigng dung dich sau cing m& = 79,4+150-90,08—my)=134,92 => Canon = 92. 100% =35,87% Dap an B (xc Cho tit tt dung dich chita AgNO3 1M vio ¥ dén céc phan ‘ing hoan thay da ding 580ml, két thiéc thu duigc m gam két tta va thoat ra 0,448 lit khi, Suy ra trong Y phai cé H™ suy ra NO; phan Xing hét vay trong Y khéng cé muéi NOS FeCl, :a AgCl:2a+0,4 23,76 gam yCu:b Hostels yy ;_aaOu0.5t001 5) Ag og Fe(NO,), :¢ NO: 0,02 mol 4H* +NO; —>NO+H,0 0,32 0,08 = 2c =0,08—+c = 0,04mol 4H" +NO; —4NO+H,0 => a+2b+0,04 =0,3+d => a+2b-d=0,26 Ag’ —*>Ag d—ad Hae —d=0,24 =0, at2b-d=0,26 [a +2b-d=0,2 a =0,08 erate 2a+0,4+d=0,58 => }2a+d=0,18 => )b=0,1 => mg => m=82,52g 02 127a+64b=16,56 |127a+64b=16,56 |d=0,02 . Dap an AMega book Te Nhan théy cd qué trinh sét vé sét ba 4H" +NO; 2 9NO+2H,0 )" tut © Fe? Fe” +3e 4a—sa—93 0,05 —+0,05 0,15 Ag’ to Ag 0,03 —+0,03 0,15=32+0,03 = a=0,04—>n,. = Nyy, =0,5.V =0,16 = V =0,321=320mnl Dap inc Fe: Hix conf 0,3 Agia 4 5 4a=9a=0,12 mol omg {M83 _, m= 56,018 Ag:0,12 Mg Mg nelle }e me } #2 5(3m + 1,82) mele e 0:4,16 g=0,26 mol [c1:0,52 3m-4+1,82=m-+18,46 m=8,32¢ Mg (3m + 1,82) vee | A825 (9m + 4,06) jae tae a }c1:0,52 iad => 0 =0,04 mol gang( MEX Jag [t86V=832 [x= 0.16 mol Fe:y |~ |2x+3y=0,26.2+0,04~ |y =0,08 mol | swios_, {MB(NO,), :0,6 "= 161,44 = 375meim (TES |Fe(NO,), :0,3 on uae Dap in B cu ™e | Fe ce = =0,05 eff 3 sm + 6,11)] Cl: 20 = {i 0,13 mol =f 0,0: Fe ‘on 2a.35,5+32b=6,11 — |b=0,08Curx mg . ‘AgCl: 0,42 ea) Jt» 7.23 am: ee 1:0,42 CuCl :x __ f2x+2y=0,42__ [x=0,18 (Cu:0,09 > > mg FeCl, ty 0,12 y=0,12 Fe:0,12 ‘Cu? :0,09 Cu:0,09 | imosian_, [Ree se etd =0,12 jo=0,09 mg SL, = > Fe:0,12 Fe™:d 2e+3d=0,27 |d=0,03 NO; :0,45 =5,67% 127,98 > Cau 14 fre ase Cu:0,1 MOH Khi phan ting xay ra hoan toan thu duge dung dich A, khi NO vi mét phén kim logi khong tan nén dung dich A chi chia mudi sit hai Fe™ :0,1 Cur | aio one [hecrn cr :0,4 Ag: H*:0,1 0, 4 549 x =0,025 3 mg ret 8 gate Ag:0,025 = 0,1, Dap an C ren 2M(NO,), —+M,0, +2NO, +0,50, a——0,5a-—9 2a 0,25a =n T=2,25a =0,225mol => a = 0,1mol Mygwoy, =8+0,2.46+ 0,025.32 =18 = M(NO,), =180=> M: Fe:2=26 RBr:a 50 67,29 [ABBE 38 FeBr, :a Ag:a => R:23:Na=9 Z=11=9 Na’ :11 = p=37 feos Dap an A i] 09Deed D> FeCl, 0,21 FeO, :0,09 CuCl, 0,06 aux ‘AgCl:0,9 —>. a =137,25 eae FeCl, :0,06 MB) ag:0,075 7 O5e HCI: 0,18, Dip dn B 1104 20, Fe:0,02 mol —Ha:00 5 {FOC 002] aio, rag [ABCH006 _ og isp HCL: 0,02 Ag:0,005 D.9,15g Ta 0,3 mol FeCl, . H 20, 0,1 mol CuCl, #9] MUFC! _ spo, 156,659 [ABCHO8 0,2 mol HCL Ag:0,3875 0,2 mol HCI Fe(NO,),:0,3 A => m4, = 200+ 250-0, 25.71—-156, 65 —0,05.30 = 274,1 [Cu(NO,), :0,2 %Fe(NO,), =26,48% Dap an A iD Fe: 0,04 Fe Heats 4X 4H, 0,044 ( Fe (Fe0,) 0:0,16 mol Fe :0,04 acta Fe :0,08 X:A( Fe 10 566,04 4ABEE OT x17 Fe 50,08 Ag:0,08 mol Cr :0,4 mol CY :0,4 mol = m=11,52g Dap nC p> Cau 22 ) : 1:0,3 es 04nd aX: A mg [A i 0,14. ouaeacsxaaanome [EEN om Ag: 0,12 Dap én B PTFeCl, My : 17,768: —ssesnei LY + NO: 0,072-+H,0:0,144 mol +H, :0,04 mol Fe(NO,), Al /AgCl: 0,528 Ag:0,06 =17,76 +0,408.36,5~0,072.30—0,144.18—0,04.2 +0, 588.170 -82,248—0, 02.46 -0,02.18 Yu asso _, 32, 280 { +NO, :0,02 mol +0,02 mol H,O 1.16 (mol) Cr 20,4 ‘Vay dung dich X chita: {Fe”* :0,08 EE Fe :0,08 —m = 0,16.56 + 0,16.16 = 11,52 (gam) Dap dn C Fest06m! tastes | FEC, 0.06 4.0, g [ARCHOS HCI: 0,06 Agia 0,06 =a +0,06.0,75 = a = 0,015 = m=27,45 gam Vo = Puc22,4 =0,3361 gam Dap an C {foes jee <.0sma fr Cu:0,025f Br "| NO AgCl:0,2mol xa , M8) Agia 0,05.3 + 0,025.2 = a+0,25.0,75 = a = 0,0125 => m=30,05g. Dép an B iEL’ piven eit | Fo wn AgCl:0,12 Fe:0, ool tani fT saad [Hone Aga NO:0,04:4=0,01 m=18,3 4 =, 7 0,04=a+0,013 a 0.01= (ma Dap an A wo, FeCl, a, , FeCl, i oo 20,5a+0,5b=0,25 poe 08 15gam je Agia => 395a+430.5b = 208,15 => m=2.(0,2.72+0,15.160) = 76,82 fre 395a +430.5b = 208,15 Pleas 0,5a+0,50=0,25 b=0,3 Dap én A Cu:0,4 mol iD °, OA mol | wet: otmal 5 Joy 108 _, m=147,2g Fe,0, :0,1 mol Dap én D AgCl:0,06 mol => m,, =112=9 n,, = 0,02 No Puss = 0,03 = Fe,0, Dép én D> Cue x, 644-2320 =54,04—2,24 = a= 0,175 Fe,0,:0 Cur :0,175 (Cu: 0,175 Fe* :0,525 © peerctett if onost rarjena ae 030,10, cr:14 en HY :0,175 al—**+0,525=a+3.0,04375 = a = 0,39375 => m = 268,5375 Dap én A Fe™* 0,1 FeO acgan [C8 2005] son yg [ABC 0.4 Cu:0,1f PEP) og 4 Ag:0,1-0,1.0,75 = 0,025 => m=60,1g Dap an C ED ‘AgCl:0,13 rooms ss 0S aang fo i! NO:0,01 ae Dip an A AgNO, :0,1a 202222", Ag :0,1a = 0,06 = a = 0,6 Fe(NO, ), :0,06 mol t ®(NOs), 10,06 mol_ ses. 49:0,04 = V=0,8961 Ag Dap an E> FeCl, :0,1 FeO, 20,1 yos-agoi_, |CUCL 0,05 Asch sas Cu:0,05 FeCl, :0,2 Ag:0,05 HC1:0,2 Dap sn B Fe:0,1mol—2 (c to} 180403600 fa Hertel NO: 0,02 0:0,09 Cl :0,1a NO; :0,14 dd =:ee cd x+y=0,1 => 42x+3y=0,14+0,la n, =0,16+0, la =0,09.2+0,02.4=0,26 = a=1 AGCL=OI a on.g3 Ag :0,06 Dap an A Fe,O, :a—#5. ae AN _5188,4 gam: AgCl:8a _ -0,15mol FeCl, :2 Ag:a =x5=>x=0,03 eed me Som. Ag:0,3 Dap énB 2a mol Cu _yossina, [FeCl i003) apo. oy g [ABU WO 14 705 a mol Fe,O, CuCl, :0,01) Ag:0,03 m, =0,01.64=0,64 Dap én00004 HCl:a 8 => Cy, =16 FeCl, :0,35 —Heenowal AgC1:0,7 +a =a=0,1 Ag:0,35-0,75a | Cu:6,4.g FeCl,:a }—#% 3102,3gam CuCl, 26 AgCl:0,6 <=> a=0,15 mol m=0,15.64+0,15.56+6,4+0,3.16= 29,2 ¢ Dap anC Fe:0,02H225 5 ‘AgCl: 0,06 = m=9,15g Ag:0,005 FeCl, :0,02] sg, HCI:0,02 ; | neta 2-4= 9,2 a=0,2 FeCl, 10,6 Fej0, 20.2) pcyanot Cac PEAY OuCh 0,2 a HC1:0,4 eine iCu:0,2 Agcl:0,4 CuCl, :0,2}—2 5 48 da: FeCl, :0,2mol 9] Be = 79g 7 Fe:0,4 ‘ Ag:0,2 HCI:0,4 Dép én B
Mg Mg 22,47 gam mudi X 7,44 gam rk > 7,44 gam } Fe }-—2A2e 2 > 4 (NO:0,01 +H,0:0,18mol fe ° N, :0,01 Fe,0, I=ols cr :0,4 NH :0,01 NO} :0,01 sou o [MeO:a 24a+56b=6,32__ fa=0,1 POAT EEO ath 7 €,05:0,50” |40a+80b=9,6 ~ ]b=0,07 Fe™: Fe: Mg:a By =2Ro +4.tyg +12By, +10. Mae Mo = 0,07} 2 | => 240+ 56b = 6,32 cr 30,4 NH; :0,01 2 29,4Tgam JNOS:001_, fety=0.07 _, [x= 0,01 Mg” :0,1 2x+3y=0,2~ |y=0,06 Fe ix Fe ry Cr :0,4 NH} :0,01 y 20,4 22,47gam JNOS #001) sgvo, mene 04 m= 58,48g Mg?" :0,1 Ag:0,01 Fe**:0,01 Fe™ :0,06 Fe,0,:0,08| _woretsa ABC O.8 193,449 06 Ag:0,08 HC1:0,16 Cura >} Fe:b }—™: 154,02 gam A { Ore [Cu(no,, [Fe(NO,), = fso.atmao-,0 =>} 2a+3b-2c=0,21.3 p= 188a+242b = 154,02 Ps(Cu :0,24 stant, [F@Cl, 10,44 ae . Saeed eee aC 2 mn = 200,88 Fe,O, :0,15 CuCl, :0,15 Ag: 0,45 Dap dn A FeCl, x Fe** Cu(NO,),:y Fe" 24,018 gam:4 CMNO):¥ | onsnaner, y JFe NO! 4 HOH Fe(NO,),:2 cu Fe,0,:a Cr :3x 40.736 Aci = 8A-+4.ny9 = a=0,08 mol —HLm, = 43,538 g=m,, +m, +m, = 56(x+2+0,08.3) + 64y + (3x +0.736).35,5 Fe™ :(x+z+0,08.3) 7 Ag :3.(x-+2+0,08.3)+2y Z:4Cu"* 115,738 gam : ee nd fa jesus NO; :3.(x +2+0,08.3)+2y 430, 5x4 216y +3242 =11,85 162, 5x + 64y +562 =3,97.g 02 mot = 1162,5x +188y +1802 =5,458 => {y= 0,006 mol = %m;,., =15,53% 430,5x +216y +324z=11,85} — [z=0,006 mol Dap anD iis H, :0,02 m(g) tang ote 62,605 gam Y : +0,17 mol 4CO, +H,0 N,0, 0,18 Cu: MeOH): ?x | pya:0,91 62,605 gam ry, Soe asses, 31,72 gam) Fe(OH), :0,18 { snuaie Na* :0,045 mol SO} 20,455 Cu(OH), :y ISO? :0,455 E NH} :z AgCl:0,91 = BaCl, :0,455 mol —>T—22 5 256, 04 g 4 Ag:0,18 mol BaSO, :0,455 58x +98y =15,52 x=0,2 39 ]2x+2y+2=0,505 = 4y=0,04 $= yo = 2422002540104 _ 9 ag5 2 24x+64y+182=7,81 |2=0,025 yw |ees —m + 0,045.85 + 0,455.98 = 62,605-+0,17.12.32.40,385.18= 27,28 pap an A ete] Mg Fe,0, ect N,0 54, 24gam X Maco apy cossmeiz [Pl 40 Fe(NO,), a= oie AgCl:2,24 11" :0,08 y 15 334,41 08 +NO:0,025Y:40 Ag:0,12 mol Fe* :0,18mol my =111,44+0,08.36,5 =114,36—* 5 m,,. =182 = nyo =Imol Ov =0,16 = aromorz {%2028]_, [R+¥=0. _, [xeon CO,:y[~ [x+2y-+1=1,08+0,04.3 ~ |y=0,04 Bio toan mol Hidro 008 — 0,04 mol Bao todn mol nito suy ra Fe(NO,), :a+0,04 —2a = 0,04+ 0,12.2=9 a=0,12 mol Takei cb Dycy =8.Mye0, +20, +10 yg +10My,9 +0,08=9 Np, o, = 0,06 = YMga, = 25,66% Dap an A (ere Fe Fe FeC,2°™ 16,48 gam :} Fe,O, sp-—“*-+16, 48 gam: } FeO aR +H, :0,08+H,0 Fe,0, Fe,0, h Fe:0,08 | Feciossamt 08. = 16,48 gam:} FeO: 0,1 | tie ee. Ae sens 2 =96938 Fe,0, :0,03 oe Ag Dap én B en Fe :0,16 : }Cu** = 0,08 Fe:0.16 mol | wosuises yy A mg (AB bao |. gy,Jea*:0 Cu:0,08 mol fF 9m AgC1: 0,66 Ht :0,12 NO; :0,76 molDagio, =z = 0,76 = b+ 0,66 =9 b= 0,01mol = m=95,79g NO:0,18mol Dap an B Fe* a Fe*:b CuS:c 24,96 gam X 82 5H, :0,04+4Cu™ :¢ 85 98, 64 gam sie => 16b +96c = 8,64 er H 2Fe™* +H,S— 2Fe™ +2H* +81 Feta Fe':b i cue —5_5NO:0,045 mol +139,04gam {xe ia Sn CY :2a+3b+20+0,18 f H’*:0,18 mol 395a +430, 5b + 2870 = 127,79. ning = 2g +8 +2.my, = 9 TET aa ea 08 _ as abe2e 0,08 (2a+3b+2c—0, 08).8+56a+56b+ 64c = 24,96 => Ta +80b+80c = 25,6 72a +80b+80c = 25,6 'a=0,2 16b+96¢ = 8,64 => 4b=0,06 > %m, =21,15% 395a+430,5b+287¢=127,79.| [c= 0,08 Dap nD ee TE Ag 4:0,045mol AgCl J:1,5 mol ny... = 0,045 + 0,045.3 = 0,18 mol yy: 220,11 wom { Jenoroos mol .72mol3) Mega book x+3y+z=0,18+0,32=0,5mol Bao toan mol oxi Ay +62-+0,12.3=0,16-+0,72 = dy +6z.=0,52 4y +6z.=0,52 x =0,25 SOx-+232y +1802 =37,44}=> }y =0,07 = %Mgyo, = x+3y+z=0,5 mol 3,38% Dap in B > Mg Hy 14,88 gam: Fe,O, -—22 "430,05 gam dd X+0,06:)NO -+H,0°*™ Fe(NO,), NO, AgCl:0,58 mol 30,05 gam dd X 222 484,31 gj A8CH058 mo Ag:0,01 =0,01.3+0,01=0,04 mol; n*, = 0,04 mol Fe™* :0,04 pee 3a+2b=0,46 083 a+ 2b = 24Cl 0,58 4 7 Yom, =17,01% nae oS ane, 010557 HH :0,04 ‘Mg :b Dap én B a> FeCl, :0,08 Fe,0, FeO he 27,2 gam:{ Fe,0,|—>27,2 gam:} Fe,0,,—“#" 5 y ; a ul c © I i i HCL ‘Tién hanh dién phan dung dich Y bang dién cyc tro dén Khi 6 catot bat déu cé khi thodt ra thi ditng dign phan c6 nghia la Fe* 1 5 Fe 0,08 > 0,08, 2cr Cl, +2e Y* Cu +2e—>Cu a a—2a—>a mi, = 64a-+7la+0,04,71=13,64 = a =0,08 mol ElFeCl, :0,08 FeO Fect FeO : 0,04 moll 27,2 gam:} Fe,O, |Et2my eee => 27,2 gam:4 FeO, :0,12 Cu: 0,08) : Cu: 0,08 HCI Cho dung dich AgNO, dit vio dung dich sau ign phan: FeCl, :0,28 mol__gvos _, FABCI:0,66 HCI:0,1 Ag:0,205 0,28 = 0,1.0,75+n4, = 4, = 0,205 => m 1=116,85 g Dap an A > Cau 57 Mg MgO 0 ot FC 4 7.44 gam) pa soy 922,47 2am mudi X-+0,02 mol ° x Fe,0, : ° Fe,0. 22,47 xX L596 eer gam madi XM L—£99,6 gam 1 Bao toan mol hidro ta tinh ra mol NH} x _0,4-0,18.2 Bat 01 Bao toan mol nguyén t6 nito ta tinh ra mol NO; Dig: =0,05—0,01—0,01.2—0,01=0,01 Fe* sa Fe*:b Mg* :c 2a+3b+2c = 0,35 mol X:4CP :0,4mol }—“#+2a+3b+2c =0,35 mol > j 80a +80b+400=9,6 NO; :0,01 mol 56a +56b+24e = 6,32 Na* :0,05Oe cra FeCl, 2a : 23,76 gam:} Cu:b ta yy tats |S 002 Fe(NO,), i Dung dich Y phan ting AgNO, sinh ra NO suy ra trong Y cé H* va Fe” suy ra trong Y khong, thé c6 NO; IT’ :0,02.4=0,08 Fe* Y:4Fe* cu cr Suy ra mol H* phan ting n® =0,4~-0,08=0,32=4:myo = Myo = 0,08 = Nycyo,y, = 0,04 FeCl, sa 23,76 gam:{ Cub = 127a + 64b = 16,56 Fe(NO,), :0,04 Dung dich sau cing Fe” :a+0,04 Cu sb 4 3a +0,12+ 2b = 0,56 = 3a4 26 = 0,44 NO; :0,58-0,02 =0,56 3a+2b=0,44 a= => 127a+64b = 16,56 1,08, 1 FeCl, :0,08 AgCl:0,08.2+0,4 = 0,56 23,76 gam:4 Cu:0,L dees = m=82,52g Ag:0,02 Fe(NO, Dap an A D> (cu 0,025 Fe:0,05 | snvo,-00s_, JH" :0,05 1:0,2 £30.05 |_ mas woe, ,[ASHO2 oso ogg Cu:0,025 bre 20,05 Ag:0,0125 cr :0,2 Dap én B a> Fe ‘AgCl:0,8 Hues! 5H, :0,08mol +X —2 132,08 gam: a {reo} epee gam) ag:0,16 calFe :0,16 X:) Fe :0,16 = m =0,32.56+0,32.16 = 23,04 gam. Cr :0,8 Dap an C F.0, 1:0,6 ss Agcl:0, X24 CuO }—Hesmol_, y__As¥O: 51923 gam: ec _ Ag:0,15 mol Cu Fe :0,15 Y:)Cu®* :0,15 = 0,15.56+0,15.64+6,4+0,3.16 = 29,2 Cr :0,6 Dap inC AL:0,3 Fe N ay aan 7.4.0,275 molt {N° + 4,0 35,2] FeO, al, 10 Fe,0, Fe(NO,), :x mol AgCl:1,9 ZBL 280,75 ‘Ag:0,075 I. NO:0,025 mol Vi dung dich Z phan ting AgNO, thu khi NO nén suy ra trong Z cé chia Fe’, H* nén khong chita NO; Tinh ra mol H* du trong Z nit =4.n =0,1 mol= ny, = 0,975 mol =0,025.3+0,075 = 0,15 mol Al" 30,3 Fe** :0,15 Z:5Fe™ :0,2 H:0,1 Cr :1,9 mol Bao toan khdi hong tinh ra kh6i lvgng hon hop Tae rs 8,1435,2+1,9.36,5+40,15.63 12 +m, $0,975.18 NO:a at+b=0,275 0,2 => m,=9,35 => = - N,O:b 30a+44b=9,3 'b=0,075 Bio toan nguyén t6 nito 2x 40,15 =0,2+0,075.2 = x=0,1=9 %Mpggy,,, =41,57% Dap én A TE Fe(NO,), :8 Feta Leola HCI tow :b+0,2 8825183 gam {e eee a Curb CY ;2a+2b+0,4 a 2b+0,4=10a 10a-2b = 0,4 , = = = =m, =19,2g 395a+287b=125,6 |395a+287b=125,6 ),3 Dap ancPaladi (Palladium) Paladi a mot kim loai hiém mau tring bac va bong, dugc William Hyde Wollaston phat hign nam 1803, va dat tén theo tén goi cua tiéu hanh tinh Pallas. Bac biét, O nhiét do phong va dp sudt khi quyén, paladi co thé hdp thy hidro toi 900 Jan thé tich cua n6, diéu nay lam cho paladi [a chat luu tro hiéu qua va an toan cho hidr6. Paladi cing chéng xin mau tét. dan dién dn dinh va kha nang chéng an mon héa hoc cao, chju nhiét tot. Phan I6n paladi dugc ding trong cac b chuyén didi xiic tac cua cong nghiep san xuat 6 t0. Bu nhéng nam 2000, do e ngai viéc san xudt 6 to co thé bi tri hoan do thiéu hut paladi, nén Ford Motor da tién hanh dy tro mot lugng 1dn kim loai nay bang viéc mua 6 mirc gid gan nhu cao Nhat. Do gid ca sau dé gidm xu6ng nén Ford a thua thiét khoang 1 ty USD.TAP KIM LOAI TAC DUNG ~ Dic diém bai todn nay xay ra khong hoan toan, - Phuong php gidi: Tinh mol cia ion géc axit, Xéc dinh dung dich mudi sau cing chtta mudi cita kim logi nado bio toan dign tich tinh kh6i lugng kim Joai trong mudi Ap dung dinh luat bao toin kh6i ligng kim loai: D¥ETED cho m gam Mg vao dung dich X g6m 0.03 mol Zn(NO,), va 0.05 mol Cu(NO,), , sau mét thdi gian thu dug 5,25 gam kim loai va dung dich Y. Cho dung dich NaOH vao dung dich Y, Khéi hugng két tha thu dugela 6,67 gam. Gid A405 B. 2,86 1 Huéng dan: Dung dich mudi sau cing M(NO,), :0,08 mot Khi cho dung dich ¥ phan ting NaOH ‘M(NO,), +2NaOH —>M(OH), +2NaNO, M(OH), :0,08 mol = myyoep, =Myy + Moy =F My = 6,67—0,08.34 = 3,95 g Bao ton khéi lugng kim loai m+0,03.65+0,05,64=5,25+3,95 = m=4,05g Dap in A a BAITAP REN LUYEN: Cho m gam bot Cu vao 400 ml dung dich AgNO, 0,2M, sau mt théi gian phan ting thu 8 8 , gian phan ting duge7 gam hén hop chat rin X va dung dich Y. Loc tach X, 16i thém 3,9 gam bét Zn vio dung dich Y, sau khi phan ting xay ra hoan toan thu duge 6,14 gam cht rin. Gid tri cla m 1a A.5,76. B. 6,40. C. 3,20. D. 3,84. Cho m gam bt Cu vao 400 ml dung dich AgNO, 1M sau mot théi gian phan ting thu dtigc 42g hén hgp rin X va dung dich ¥ gém hai mu6i. Loc tach X réi them 16,25g bot Zn vao Y, sau khi phan ting xy ra hoan toan thu duge 23,65g chat ran Z gém 3 kim loai. Gia tri cha mii: A19,2 B.12,8 C160 D96 a[XELED cho m gam bét Fe vao 200 ml dung dich chita hai mudi AgNO, 0,15M va Cu(NO,), 0,1M, sau mot thdi gian thu duige 3,84 gam hén hop kim loai va dung dich X. Cho 3,25 gam bét Zn vio dung dich X, sau khi phén ting xdy ra hoan toan, thu dugc 3,895 gam hén hop kim loai va dung dich ¥. Gié tri cia m la A. 2,240, B. 0,560. C.2,800. D. 1,435. [XELED cho m gam bot Cu vio 400 ml dung dich AgNO, 0,2M, sau mot thoi gian phan ting thu duigc7 gam hén hop chat rin X va dung dich Y. Loc tach X, r6i thém 3,9 gam bot Zn vao dung dich Y, sau khi phan ting xy ra hoan toan thu duge 6,14 gam chét rin, Gia tri ciia m la AL5,76. B. 6,40. C. 3,20. D384. Cho m gam bét Fe vio 200 ml dung dich chita hai muéi AgNO, 0,15M va Cu(NO,), 0,1M, sau mét théi gian thu duige 3,84 gam hdn hgp kim loai va dung dich X. Cho 3,25 gam bot Zn vao dung dich X, sau khi phan ting xay ra hoan toin, thu dugc 3,895 gam hén hgp kim Toai va dung dich Y. Gia tri cia m Ta A. 0,560. B. 2,240. C. 2,800. ‘D.1,435, [ED cho m gam Cu vio 500 mi dung dich AgNO, 0,2M, sau mot thai gian thu dugc dung dich X va 18,88 gam chat ran Y. Tach Y, sau dé cho 6,5 gam Zn vao dung dich X dén khi phan ing xy ra hoan toan thi thu dude 7,97 gam chat rin Z. Gié tri cia m LA A64, B, 19,2 C128. D.3,2. ‘Cho m gam bét Cu vao 500ml dung dich AgNO, 0,32M sau mét thi gian phan ting thu ude 15,52 gam hén hop chat rin X vi dung dich Y, Loc téch X r6i them 11,7 gam bét Za vio Y.sau Khi phan ting xty ra hoan toan thu duige 21,06 gam chat rin Z. Gid tri cba m la: A.10,24 B7,68 C128, D.11,52 Cho 3,36 gam bot Fe vio 300 ml dung dich chtta hai muéi AgNO, 0,15M va Cu(NO,), 0,1M, sau mét thai gian thu duige 5,76 gam hén hap kim loai va dung dich X. Cho 1,8 gam bat Mg vao dung dich X, sau khi phan ting xéy ra hoan toan, thu duige m gam hén hgp kim loai vva dung dich Y, Gia tri cha m lt A. 1,45. B. 2,80. C. 4,92. D. 2,24. CXETED Lic 13,14g Cu v6i 250 ml dung dich AgNO, 0,6 M mot théi gian thu duige 22,56g chat rin A va dung dich B. Nhing thanh kim loai M nang 15,45g vao dung dich B khudy déu dén khi phan ting hoan toan thu cigc dung dich chi chéta mét muéi duy nhat va 17,355g chat rin Z. Kim loai M la: A.Zn B.Pb C. Mg. D.Fe Cho m gam bot Cu vio 200 ml dung dich AgNO, 0,2M, phan ting mét thai gian thu duge 3,88g chat ran X va dung dich Y, Cho 2,925g bot Zn vio dung dich Y sau khi két thie phan ting thu duige 5,265g chit ran Z va dung dich A. Gid tri cua m [&: A382. B. 3,17. C.2,56. D.1,92. (iCho m gam bét Cu vio 400ml dung dich AgNO, 0,2M, sau mt thdi gian phan ting thu duigc 7,76 gam hén hgp chat ran X va dung dich Y, Loc tach X, réi thém 5,85 gam bét Zn vio Y, sau hi phan ting xay ra hoan toan thu duige 10,53 gam chét rin Z. Gid tri cia m la: A. 6,40, B.5,76. C.3,84, D.5,12. Cho m g Zn vio dung dich chéta 0,1mol AgNO, va 0,15 mol Cu(NO,),, sau mt théi gian thu duigc 26,9g két tha va dung dich X chita 2 muéi. Tach lay két tia, thém tigp 5,6g bot sit ‘vao dung dich X, sau khi cdc phan ting xay ra hoan toan thu dugc 6g két ta, Gid tri cia m a A. 6,25 B19,5, C.18,25 ‘D.19,45 Cho 8 (g) bot Cu vao 200m! dung dich AgNO,, sau 1 théi gian phan ting loc dugc dung dich A va 9,52 (g) chat rn. Cho tiép 8 (g) bot Pb vao dung dich A, phan ting xong loc tach duige dung dich B chi chtta 1 muéi duy nhét va 6,705 (g) chat ran, Néng 46 mol/l cia AgNO, ban dau la: A.0,25M. B.0,1M C.0,35M. D.0,20M. Huéng dan: Tyg. ,08mol Dung dich sau cing Zn(NO,), :0,04 mol => mz" = 2,6g Bao toin khdi lugng kim loai m+0,08,108+3,9=7+6,14+2,6=3 m=3,2g Dap dn C Dung dich sau cing. Zn(NO,), :0,2mol = mis" =13g Bio toan khéi lugng kim loai m+0,4,108+16,25g = 42+ 23,65+13 = m=19,2g Dap én A A.2,240. ABNO; 008 es gg eae Cu(NO,), :0,02 a X22" 2 5 7n(NO,), :0,035+3,895 gam Bao toan khéi lugng kim loi alm+0,03.108+0,02.64+3, = m=2,24g Dap in A D> 25 = 3,895-+3,84+0,035.64 Tagyo, = 0,08 mol—> Zn(NO,), :0,04 mol — 5m + 0,08.108 +3,9= 74 6,14+0,04.65 > m=3,2g Dap an C ddx {eetne 0,03 mol } myers Nii gamkl Cu(NO,), :0,02 mol 3,895 gam kl dX 22a day Hts m+0,03,108-+0,02.6443, 25 = 3,84+3,895 + 0,035.65 => m=2,24 g Dap dn B AgNO, aes ax —Stmn2 fea EE 0,1.108+m+6,5 Dap an C NO; :0,07 Zn™* :0,035 dax Do a 18,88 gam ‘| 7,97 gam Z =18,88+7,97 +0,05.65 => m=12,8¢ a AgNO, :0,16 mol zener {15:52 gamX day cay titan 2, [206 gam z Zn(NO,); :0,08 85 0,16.108-+m-+11,7 =15,52+21,06+0,08.65 => m=12,82 Dép anc AgNO, :0,045 mol Cu(NO,), :0,03 mol 5,76 gam kt daxa Lid Mg” :0,0525 NO; :0,105 HHL 5 0,045,108 + 0,03.64-+3,36+1,8 = 5,76-+0,0525.24-+m =m=4,92g sxe Dap an C sutgce_, [22,568 A. AgNO, 0,15 mol ef 7 17,355g Z M(NO,), :@ —10,15.108+ 13,14 +14, 45 = 22,56417,355+m,,. wn anef AgNO, 404 ot nef * aay Zn(NO,), :0,02 5,265g Z — HE 5 0,04.108 +m + 2,925 =3,88-+0,02.65 +5,265 = m=3,2g Dap in A ayaae| AgNO, : 0,08 mol 225 ee {ire Zn(NO,), :0,04 10,53 gam Z tL 5 0,08.108 +m +5,85 = 7,76-+10,53+0,04.65 > m=6,4g Dap an A ica wayne f 26,98 1mol AgNO, mgt Zn(NO,), 4 0,15 mol Cu(NO,), ac 1s ‘Cu(NO,), 7b828 5] [Zn(NO,), :2 ey b 3b =0,05 = a=0,15 mol —40,1.108+0,15.64+m +5, Dap an D = 26,9+6+0,15.65+ 0, 05.56 => m=19,45 gam 9,52 AgNO, :0,2a mol 225, (8) ddA 6,705(e) PD(NO,), :0,la ), 52+ 6,705+20,7a => a= 0,25 contin f E50, 20.108 +848 = Dip an APaladi (Palladium) Paladi la mot kim loai hiém mau tréng bac va bong, dugc William Hyde Wollaston phat hién nam 1803, va dat tén theo tén goi cua tiéu hanh tinh Pallas. Dac biét. 6 nhiét 46 phdng va p suat khi quyén. paladi cé thé hp thy hidré toi 900 Jan thé tich cua no, diéu nay lam cho paladi la chat luu tro hiéu qua va an toan cho hidro. Paladi cing chéng xin mau t6t. dan dién dn dinh va kha nang chéng an mon héa hoc cao, chiu nhiét tot. Phan Ion paladi dugc dung trong cdc bo chuyén ddi xic tac cua cong nghiép san xuat 6 t6. Bau nhing nam 2000, do e ngai viéc san xuat 6 t6 6 thé bj tri hoan do thiéu hut paladi, nén Ford Motor da tién hanh dy tra mot lugng I6n kim logi nay bang viéc mua 6 muc gid gan nhu cao nhét. Do gid cd sau d6 gidm xudng nén Ford da thua thiét khoang 1 ty USD.- Bai toan khong cho ancol va axit ~ Xéc dinh cng thiic axit va ancol Hén hgp M g6m ancol no, don chiic X va axit cacboxylic dan chic ¥, déu mach ha va 6 cling s nguyén tit C, téng s6 mol clia hai chét la 0,5 mol (s6 mol cia Y 1én hon s6 mol cia X)..Néu d6t chay hoan toan M thi thu duige 33,6 lit khi CO, (éktc) va 25,2 gam HO. Mat khéc néu dun néng M véi H,SO, dic dé thuc hign phan ting este héa (higu suét 80%) thi s6 gam este thu duge A. 34,20 B.27,36 €.20,80 D. 18,24 m Huéng dan: 45 CO, :Smol)_ }n=F3 H,0:1,4 mol i oo t 6 2145,6-y<245y>3,25y=4 ICH,O:a CHO, :b => Mejy0, = 0.2.0,8.114 = 18,24 g o.sminif Dét chy hon to’n $,4g hn hop X gém 1 axit cacboxylic no don chite va 1 ancol don chiic Y, thu dugc 0,2 mol CO, va 0,3 mol H,O. Thuc hién phan ding este héa 5,4g X voi hiéu suat 80% thu dugc m gam este. Gia tri ctia m la: A.22 B. 185 C.2,04 D295 mt Huéng dan: s4gx (CrtienO#4_o, [0.2:mol CO, C,H,,0, 1b 3 mol HO > 2=0,1 mol 3 18452040,214-=5,4-9 b= 1025 ol 0. 40,025m-=1,2- |Dr eLeas = mC,H,,0, = 0,025.0,8.102=2,04 CH,OH:a = C,H,O, :b Dép én C Hén hgp X gém 1 axit cacboxylic (no,dan chiic) va 1 ancol don chtic. Dét chay hoan toan Ip X 26 oxy! 10,6g X thu dugc 17,6g CO, va 9g H,O. Thyc hién phan ting este héa 10,6g X véi hiéu suat 60% thu duige m gam este. Gid tri cha m la: A312 B, 2,64 C.5,28 D.4,40 @ Huéng dan: (C.Hy,,,0'8 0,4 mol CO. 10,68.X {Cote o,_, 2 a oral jee =a=0,1mol = 18a+32b+0,4.14=10,6 = b=0,1 mol = 0,ln +0,1m=0,4=5n+m=4 = m cyripo, = 01.0, 6.88 =5, 28g Dap an C Hén hop M g6m 2 axit cacboxylic don chite X va Y (Ia déng dang ké tiép, M, < M,). Dot chéy hoan toan 8,2g M cn 10,4g O, thu dugc 5,4g H,O. Dun néng 8,2g M véi etanol (H,SO, 4c) tao thanh 6g hén hop este, Héa hai hoan toan hén hop este trén thu duige thé tich hoi bang thé tich cta 1,82g1N, (trong cing diéu kign nhigt do va 4p suét), Higu suat phan ting tao este cha X va Y ln ligt 1a: A. 60% va 40% B. 50% va 40% C. 50% va 50% D. 60% va 50% ™ Huéng dan: CO, :0,3 H,0:0,3 32a+0,3.14=8,2 a=0,125 9 n=2,4— Nee adostene aoa Neen a (pes fried 8,2¢ M.C,H,,0, :@ af C,H,COOH : 0,05 C,H,COOHC,H,:y— x+y=0,065 y=0,02 Hy = 60% H, = 40% Dap an A [XETED cho hin hop axit fomic va axit axetic tham gia phan ting este héa voi hin hgp P gm 2 ancol don chttc déng ding ké tip. Phan ting xong thu duigc sin phém l4 este trong d6 06 chat X (phan tit khdi lén nhat) va chat ¥ (oxi chiém 53,33% vé kh6i higng). S6 nguyén tit cacbon 6 trong phan tit X Ad. B.6. C3. D.5.1 Huéng dan: 32.100 53,33 0 Y : HCOOCH, = X: CH,COOC,H, Dap an H6n hgp E gém axit cacboxylic don chtic X, axit cacboxylic hai chite ¥ (X va ¥ déu mach hé, cé ciing $6 lién két n) va hai ancol don chiic Z, T thudc ciing day déng ding. Dét chay hoin toan m gam E, thu dugc 1,3 mol CO, va 1,5 mol H,O, Mat khdc, thyc hién phan ting este héa m gam E (gia sif higu suat cac phan ving 1a 100%), thu duige 33,6 gam sin phém hifu co chi chita este. Phin trim kh6i lugng cia X trong hén hop E gén gid tr) nao nhat sau day? A, 15%. B. 16%. C. 17%, D. 20%. Hung din: RCOO, 1 co, :1,3% {rico 2 nt ee H,0:1,5"" C,Hy,20 mol a(1—k)+b=0,2 mol = a+b—ak = 0,2 mol => ak2ak<3 = k=2=b-a=0,2mol Bao toan khéi ligng 1,3.12+1,5.2+b.16+D.32 =33,6-+18b => 30b=15 = b=: 0,3.x+0,5.y=1,3 = x $ 2,6 = HOOC-COOH CH, 203 2% xty=0,3 _ [x=0,1 > = HOOC-COOH:y~ |x+2y=0,5~ |y=0,2 0,1 +0,2.2+0,5.y=1,3=9n<4=5n=3:CH, = CH-COOH:0,1 mol = YIM, c-coon = 16,9% Dip anc ),5 = a =0,3 mol ‘Hén hgp X gém mot axit cacboxylic don chitc, mot axit cacboxylic hai chic (hai axit déu mach hé, cé cing $6 lién két m) va hai ancol don chtic la déng dang lién tiép, Dét chay hoan toan ‘m gam X, thu duigc 0,21 mol CO, va 0,24 mol H,O. Thy hién phan ting este héa m gam X (gi sit higu suat céc phan ting déu bang 100%), sin phdm sau phan ding chi cé nude va 5,4 gam cdc este thudn chitc. Phan trim kh6i luigng ciia ancoi cé phan tit khdi lén trong X gala abt voi A. 5%, B. 7%. C.9%., D.11%.; KOOOOOOOOOOOMOOOOOOOOOOOOOOOOOOO eed A ™ Huéng dan: i fame i 20,21" R (COOH), C,H,.:0:b mol a(l-k)+b H,0:0,24™ 2 mol =a+b—ak mol => ak 30b=15 => b=0,08 = a =0,05 mol 0,05.x+0,08.y =0,21= x $ 2,6= HOOC-COOH (C,Ha,-202 2% x+y=0,05 > = HOOC-COOH:y |x+2y=0,08"~ ly 0,02.n+0,03.2+0,08y=0,21=9 n<4=9n=3:CH, =CH-COOH:0,02 mol jase 2,3+0,03.2+0,08y = 0,213 y =0,02.3+0,03.2+0,08y = 0,21=>y Sheeting =0,07 ee {i 0.46.100 _ 6 99, %a = 246.100 a=0,017 “MoH = 684 Dap an B [XETEDD Hon hop X gém mot ancol va mét axit cacboxylic déu no, don chitc, mach hd, c6 cling 86 nguyén tit cacbon trong phan ti. Dét chay hodn toan 51,24 gam X, thu duigc 101,64 gam CO,, Dun néng 51,24 gam X véi mic tac H,SO, dic, thu duigc m gam este (higu suat phan ting este héa bang 60%). Gia tri m gin nha véi gid tri nao sau day? A.25,1 B.28,5. C.AL8, D.206. 1 Huéng dan: 51,24 gam x {CoHlnn20 CO, :2,31 mol 24 gam Bam 1c ,Ha,0s 1,0: a SUMA2 314 oC SL2-BILI 9 go cy, ¢ SHMAZII-M 4 95 32 18 18 (C,H,O:0,41 = 0,36.116.0,6=25, CHO, 0,36 ea 25,0568 => 2,2n=3= 51,24 amx| Dap an ADét chay hoan toan hén hgp X gém ancol etylic va axit axetic thu ditgc 8,96 lit CO, (dktc) va 9,36g H,O. Néu thém H,SO, (d6ng vai tr xtic téc) vao hén hgp X va dun néng thu dugc 5,28g este thi hiéu sudt phan ting este h6a la bao nhiéu ? A. 75% B, 60% C.50% D. 80% Huéng dan: C,H,0:0,12 C,H,O, :0,08 100 = 75%. Dap in A Dét chay hoan toan 9,44 gam E gém 1 axit cacboxylic X khOng no don chttc c6 1 lien két i (C=C) va mot ancol don chitc ¥ 4a thu diige 8,96 lit CO, (dktc) va 7,2 gam H,0. Mat khéc, tién hamb este héa 9,44 gam hén hop E trong diéu kién thich hgp v6i higu suét bing 60% thi thu duige m gam este B Gia trj cita m la A.60 gam. B. 13,33 gam, C.48 gam. D.80 gam. 1 Huéng din: (C,Hoy 20, 1a (CO, :0,4 9,44 gam B] "or? > - =0,08>n+m=5 hee (cme front eae Me,y,0, = 0,08.100.0,6=4,8 g Dap an C Dét chy hoan toan 9,44 gam hén hp E gém mét axit cacboxylic X khéng no don chiic €6 1 lién két d6i (C=C) va mét ancol don chite ¥ da thu duge 8,96 lit CO, (dktc) va 7,2 gam H,O. Mit khéc, tign hanh este héa 9,44 gam hén hop E trong diéu kién thich hop vai higu sudt bang 60% thi thu duge m gam este F. Gid tri cfta m la A.6,0 gam. B. 13,33 gam. C.48 gam. D.80 gam. 1 Huéng dan: 9,44 gam BY Cets202 #2 (CO, :0,4 ae CoH m4 H,0:0,4 =0,24 : 2ard=0,24 _ [a=0.08 6 95 4.0,08m=0,4-8n-48m=40 30a +18=3,84 [b=0,08 CH, =CH-COOH 1 > Me ecr-coocn, = 488 C,H,OH t Ms ‘CH, ~CH, =CH-COOH CH,OH = Meu, -cH,-cH-coock, Dap an CReni (Rhenium) Nhang kim loai dugc xp hang quy la do ching khé tim va dac biet kho phan tich. Viée khai thac kim loai hiém bao gid cing la quy trinh phuc tap va dat tién. Chang han nhu cén phai xtr ly mot lugng lon khodng thach moi chiét ra dugc 1kg kim loai hiém Rhenium. Bay la kim loai quy c6 ¥ nghfa chién lugc trong nganh co khf ché tao may moc chiu nhiét cao. Voi nhiét do nong chay rat cao (hon 3.000 do Q, cdc hop kim v6i Rhenium dugc ding dé ché tao cdc bO phan trong may bay phan luc. tén lira, va la vat ligu ly tudng trong nganh nang lugng nguyén tir. Hop kim cua Reni vi vonfram ding lam day toc bong den dién, ché tao pin nhiét dién. Reni con dugc ding lam chat xtc tac trong cong nghiép loc - hod dau. Rhenium dugc cdc nha khoa hoc tim ra vao nam 1925. Tén goi cla n6 xuat phat tir tén s6ng Rhein cua Buc (vi ngudi ta tim ra n6 6 Bic). Vao nam 2010, kim loai nay c6 gid khoang 141USD/troy ounce (tuong duang khoang hon 4.500USD/kg.EY wtnuver: DE AP DUNG PHUONG PHAP NAY CAN XACDINH BUGC CONG THUC TONG QUAT CUA HOP CHAT HOU CO mgC,H,,,,0: amol —2-> CO, :b mol => m =a(14n-+ 18a) = Lan +182 = 14.nco, +184 mgC,H,,_,0, :amol—22CO, :b mol a(4n+30)=m= m=14.no, +302 Bo BAITAP Cho X, Y I2 2 chat thudc day déng ding ctia axit acrylic va M, < M, ; Z la ancol 6 cing s6 nguyén tix C vdi X; T Id este 2 chic duige tao bai X, ¥ va Z. Dét chay hoan toan 11,16 gam. hon hgp E g6m X, Y, Z va T cfn vita dii 13,216 lit khi O, (dktc) thu dhige khi CO, va 9,36 gam nuidc, Mat khdc 11,16 gam E tac dung t6i da véi dung dich chtfa 0,04 mol Br, . Khoi htgng mu6i thu duigc Khhi cho cing higng E trén tac dung hét véi dung dich KOH dit gin nhét v6i gid tri nao duéi day? A. 4,68 gam B,5,44 gam C.5,04 gam D.5,80 gam 1 Huéng din: C\Hy.20) 28 - 11,16 gam 1C_H,_.,0, :b—2s2ste0_, [CO2 #047 mol EE read H,0:0,52 mol C,H ap-60y 2 2a+2b+4e=0,28 mol => 130a+34b +580 = 4,588 a+0b+2c=0,04 ees mol |" 50,47.14+30a +34b + 58c = 11,16 02 J => 0,02n+0,1m+0,02n +0,01m = 0,47 = 0,04n+0,11m = 0,47 c=0,01 ansinsm=47->f—*40,04.3+y+0,11.3=0,47 => y=0,02mol > m=4,68g Dap an A (XEMED (THPTQG-2015) Hén hgp X gém 3 este don chic, tgo thanh tit clung mét ancol Y véi3 axit cacboxylic (phan tit chi cé nhém -COOH); trong 46, cé hai axit no la déng ding ké tiép nhau va mot axit khong no (c6 déng phan hinh hoc, chita mOtlién két doi C=C trong phan td). Thity phan hodn toan 5,88 gam X bang dung dich NaOH, thu dulgc hdn hop mudi va m gam ancol Y. Cho m gam ¥ vao binh dying Na du, sau phan ting thu duigc 896 ml Khi (dtc) va khéi Jugng binh ting 2,48 gam. Mat khéc, néu dét chay hoan toan 5,88 gam X thi thu duge CO2 va 3,96 gam HO. Phan tram khéi lugng ca este khéng no trong Xi A. 29,25%. B. 38,76%. C. 40,82%. D. 34,01%. 1 Huéng din: Xéc dinh cong thiic phan tit ancol. Magsot = Mping +My, = 2,56 8 Dp) =0,08 > M=32.CH,OH Qui déi ba este thinh hai este. 5,8 gam x {CeFlnOa:8 co, CyHyy. 203 2b H,0:0,22 mol a+b =0,08 mol ,06.mol = > 14.0.22+32a+ 44b = 5,88 1,02 mol 5,88~-0,22.2 ~32.0,08 12 24 mol m=5 7-9 %tte0, = F} 22100 00 =34,01% maeienean-aata| ap an D X,Y, Z1a 3 este déu don chtic, mach hé (trong dé Y va Z khéng no cé mét lién két C=C). Dét chéy 21,62 gam hén hop E chtia X, ¥, Z vdi oxi vita di, sin phd chéy dn qua dung dich Ca(OH), du thay khoi tng dung dich gidm 34,5 gam so v6i trutéc phan ting. Mat Khdc, dun néng 21,62 gam E v6i 300 ml dung dich NaOH 1M (vita di), thu duigc hén hap F chi chita 2 mu6iva hén hop g6m 2 ancol ké tip thudc cing day déng ding. % kh6i tong cia este cé khéi Jugng phan tit lén nhét trong hon hop E ki: A. 21,09 B. 15,82. C. 26,36. D. 31,64 ™ Huéng dan: 2% CaCO, :2 CO, :a _cuow, H,0:=> 100a ~ 44a ~18b = 34,5 =» S6a—18b = 34, 5(1) C-H,z 0, : a 2162 aml atta a2 X —toHtaeel_, 5 M = 72 = HCOOCH, CyFlamne2-2kO2 [962-18 =34,5 _, fa 0,87 _ [x= 0.08 0 9g opm aoer 12a+2b=12,02 [b=0,79 |y=0,22 CHO, :¢ ford =0,08 = = CHO, :d-~ [4o45d=0,43 n=satsa{ Dap in B X, Yl hai hop chat hitu co ké tigp thudc day déng ding axit acrylic; Z 1a ancol 2 chitc; T lieste tao béi XY, Z. Dét chay hoan toan 22,2 gam hén hop E chita X, Y, Z, T cdn diang 1,04 mol 02, thu duge 17,64 gam nude. Mit khc hidro héa hoin to&n 22,2 gam E cén disng 0,09 mol H2 (xc tac Ni, t? thu duge hn hgp F. Dun néng toan bé F véi dung dich NaOH vita da, 6 can dung dich sau phan ting thu dugc hén hop chita x gam mudi cita X va y gam muéi cia Y (MX ¢ MY). Tile gin nhat ciiax: y la, A.09 BLO Cul D.08 1 Huéng dan: CyHq20, 78 22,28 4 CyHoy.2O2 cbs ee me CH, Oe H,0:0,98 mol Plena = ees 62 0,86.14+30a+34b+58¢=22,2 ” |30a+34b+58e=10,16 C,Hay-20) 24 22,2 g 4C Hage; 1b 4 = a + 2c = 0,09 C,Hop Oy 2€ 2a+2b+ 4c =0,62 a=0,07 30a+34b+580=10,16=9 4b 22-3 6-888 67 a+2c=0,09 jo=0,01 : = C,H,O, = 0,07.n+0,22.2+0,01(2n + 2) = 0,86 = 0,09. = 0,4 aa X:C,H,0; JH,COONa:c — fe+d=0,07 _ fe=0,04 an=445 => = > Y:C,H,O, "H,COONa:d ~~ [de+5d=0,31 |d=0,03 X:C\H,COONA:0,05—>x=6 _ x Y:C,H,COONa :0,04-—>y = 5,66 Dap an C =1119 Hon hgp A gém este dan chitc X va hai este no, hai chife, mach hd Y va Z (M, 2a+4b=0,23 mol {Re (0,385 —Ba + 32a + 62b = 8,85 { a=0,015 = f =0,05 > 8,85 gam A Vee Seema mE 20 PH 8,8540,13.40=m+4,04+0,015.18 => m=9,74 g Dap an A X, ¥, ZI 3 este déu don chit, mach hé (trong dé Y va Z khong no c6 mot lién két C=C vva.cé t6n tai déng phan hinh hoc). Bét chy 21,62 gam hén hgp E chita X, ¥, Z v6i oxi vita di, san phém chdy dan qua dung dich Ca(OH), du thay khéi lt'gng dung djch gidm 34,5 gam so v6i trudc phan ting. Mat khdc, dun néng 21,62 gam E véi 300 ml dung dich NaOH 1M (vita ii), thu duigchdn hgp F chi chtia 2 muéi-va hén hgp gém 2 ancol ké tigp thud ciing day déng dang. Khéi higng cia muéi cé khéi lugng phan td Ién trong hon hop F 1a: A. 8,64 gam. B. 4,68 gam. C.9,72 gam. D. 8,10 gam. 1 Huéng dan: Vieste don chite nén ta cé: Dyan =e = 0,3 mol = M =72,06 => HCOOCH, Cra 31,62 gam lets op {O08 _, f128+20=12,02_ fa=0,87 mol face : H,0:b |56a-18b=34,5 0,79 mol 0:0,6 Hyg 020,08 = 2 ae =0,081+0,22.2=0,87 = n=5,375 HCOOCH,;0,22 Nee —CH = CH-COOCH, BY (ie -CH=CH-COONa:0,08 CH, ~CH=CH-C00C,H, ~ [HCOONa:0,22 Mex, -cricet-coons = 8,64 & Dap an A Hin hgp X g6m 3 este don chitc, tgo thinh tit cing mdt ancol Y véi 3 axit cacboxylic (phan tit chi c6 nhém -COOH). Trong d6, c6 hai axit no li déng ding ké tigp nhauva mot axithdng no (chita mét lién két 46i C=C trong phan ti!). Thy phin hodn to’n 4,40 gam X bing dung djch NaOH, thu duigc hn hop mudi va m gam ancol Y. Cho m gam Y vao binh dying Na du, sau phan ting thu dugc 672 ml khi (Aktc) va kh6i lugng binh ting 1,86 gam. Mat khic, néu d6t chay hodn toan 4,40 gam X thi thu duigc CO, va 2,88 gam H,O. Phan trim kh6i ligng cia este khéng no trong X i A. 33,6496. B.34,01%. C.39,09%. D.27,27%. 1 Huéng dan: C6 ngay ancol CH,OH :0,06 mol CH,,0,:2 4, fCO, CHa, 20) 1 H,0:0,16 mol Tes tae {; 0,04 4.0 gam xf = = 0,16.144+32a+30b=4,4— |32a+44b=2,16 |b=0,02 sat = Hong, = 018 j= [HCOOCH, =35 cH,CoocH, = m= 4 0,04n-+0,02m = 0,18 -{ 9 58 COs = Mateo, = 39-09% Dap an ED X.¥,2.133 este déu no va mach hé (khong chia nhém chite khdc va M,< M, k=2 0.050-+0,02m=0,25 9 3n-4m=25-f m=4 HOCO-CH, ~COOH C,H, (OH), Cho X, ¥ la hai chit thugc day déng ding cia ancol anlylic (M, = 16a + 28b = 8,32 m=3 =1m+20m=113-5{ : 17 CHO, = %meyy0, =58% n= Dap én A TvBac Tirngan xua, kim loai nay da dugc ding trong buén ban va lam co sé cho nhiéu hé théng tién té. Ngay nay, ngoai viéc dugc str dyng lam cac dé trang tri c6 gid tri. bac con dugc str dyng trong nhiéu linh vyc khac nhu lam rang gia, linh kign dign tir hay san xudt guong can do phan xa cao. Bac bigt. cdc mu6i halégen cla no co vai tro quan trong va dugc (mg dung rong rai trong doi sng; chang han, bac nitrat duoc str dung rong rai trong cong nghé Iuu phim anh; hay I6tdua bac co thé lam tu may dé tao mua nhan tao. Bac ty ban than n6 khong doc nhung phan lon cac mudi cua nd Ia doc va co thé gay ung thu. Bac c6 hiéu «mg va kha nang giét chét nhiéu loai vi khudn, vi tring ma khOng dé lai anh hudng 16 rang t6i stic khde va sy s6ng cla cdc dong vat bac cao. Hippocrates - cha dé cua y hoc hién dai, da viét rang bac c6 cdc thudc tinh c6 loi cho strc knoe va phong chdng benh tat. 0 viet Nam, dan ta cing da biét ap dung higu tng nay khi deo bac dé “ky gid”, “phong bénh”. Theo nhtng nghién cou gan day, sira me dé trong binh sda trang bac lau héng hon la dung trong binh nhya thong thudng. Nhiéu nha san xuat thiét bj dién lanh nhu Toshiba, Panasonic, Samsung (mg dung cong nghé nano bac trong tu lanh, diéu hoa nhiét do, may gigt voi myc dich sat khudn.+ Phuong phép giai: Buéc 1: Tinh mol oxi trong hén hop m,—my hn matte ‘Tinh mol nhhém HCOO™ Buéc 4: Xac dinh chat ran: HCOONa RCOONa ‘NaOH : du (XEDED Cho X, ¥ la hai axit cacboxylic don chtic mach hé (M,< M,); Ta este hai chife tgo béi X, Y va mot ancol no mach hé Z. Dét chay hoan toan 6,88g hh E gém X, Y, T bang mot higng vita dit oxi thu dugc 5,6 lit CO, (dktc) va 3,24g mide, Mat khac 6,88g E tac dung véi dd AgNO, /NH, dui thu duigc 12,96g keét tita Ag. Khi cho cing lvgng E trén téc dung véi 150ml dd KOH 1M réi 6 can thi khéi hong chat rin khan thu duge la: A. 12,78, B. 14,04 C.10,54g D.13,66g 1 Huong din: + E.c6 phan ting trang bac nén X phai la HCOOH va. 0,06 (mol) Rea, - = ae sini, part _ 6,88- 0,25.12-0,182 _ 9 99 (mot) Nao = O18 i HCOOH :a Goi {R,COOH: HCOO-R -OOCR, :¢ toa +0=0,06 —. [Spat b+2c=0,11Dee HCOOK : 0,06 nfs = 0,11 (mol) —smj C,H,COOK : 0,05 — 0, 06 + 0,05x + 0,05 < 0,25 KOH:0,04 HCOOK :0,06 => x<2,8—MAM_5 m4 CH,COOK : 0,05 => m =12,78 g KOH :0,04 Dap an A (XEQED x. ¥, Z 18 ba axit cacboxylic dan chite cing day déng dang (M,< M,< M,), T la este tao ai X, ¥, Z v6i mét ancol no, ba chtic, mach hé E, Dét chéy hoan toan 26,6 gam hén hop A gém X, ¥, Z, T (trong dé ¥ va Z 06 cing 6 mol) bing lugng vita dit Khi O,, thu dugc 22,4 lit CO, (kic) va 16,2 gam HO. Néu dun néng 26,6 gam A vi luigng du dung dich AgNO, / NH,, sau khi cdc phan ting xdy ra hoan toan, thu duigc 21,6 gam Ag. Mat khéc, cho 26,6 gam A phan ting hét véi 400 ml dung dich NaOH 1,5M va dun néng, thu dugc dich B. Cé can dung dich B thu duoc m gam chat ran khan, Gid tri ca m la: A424 B. 25,2 C.50,4 D.41,5 mt Huéng dan: }CO, :1 mot H,0:0,9 mol Cé ngay 3 axit Ja no don chife va este no ba chite 26,6 gam A of (C;H,,0, :0,25 mol og, JOO, :1 mol 26,6 gam Ay? nd Cy Haqs0g 10,05 H,0:0,9 mol [RCOONa : 0,3 25600m A 9:25 ou-96m4 5 | HCOONA:0,1 (cooyr’ : 0,05 AoHine 0,3.0+0,3+0,1<1> C<2= C=155R=22 m=415g Dap an D ED X, Y, Z 18 ba axit cacboxylic don chitc ciing day déng dang (M, . beste eee mol Cé ngay 3 axit 1a no don chtic va este no ba chite 26,6 gam a {osHsiOs 10,25 mol og, JCO, 11 mol 9 oa CopHaps-sOg 20,05 H,0:0,9 mol RCOONa : 0,15 att, mg } HCOONa : 0,05 NaOH :0,2 FRCOONa: 13,3 gam A} (RCOO),R 125 025 = m=24,75 Dap in B Cho X, ¥ la hai axit cacboxylic don chtic mach hd (M, < M,); T Ia este hai chiic tao béi X, Y va mét ancol no mach hé Z, Dét chéy hoan todn 10,32 gam hén hop E gém X, Y, T bang mot higng vita dit O,, thu duigc 8,4 lit CO, (dktc) va 4,86 gam nuiéc, Mat kthac 10,32 gam E tic dung véi dung dich AgNO,/NH, dui thu duige 19,44 gam Ag, Khéi lugng rin khan thu duge kkhi cho cling long E trén téc dung véi 150 ml dung dich KOH 1,5M la? A.20,49 gam. B. 15,81 gam, €.19,17 gam. D. 21,06 gam, @ Huong dan: + E.c6 phan ting trang bac nén X phai la HCOOH va nj =0,18—s nie = 0,09(mol) sot _ 10,32~0,375.12~0,27.2 33, Ks 7G (mol) HCOOH:2 , 5a +0=0,09 Gat {R,cooH:b —| area HCOO-R -00CR, : fab ees dee HCOOK.:0,09 — akin" = 0,165 (mol) —»m}C,H,COOK : 0,075 —+0, 06 + 0,075x +0,075 < 0,35 KOH: 0,06 HCOOK :0,09 = x <2,8H 5 m4 C,H,COOK :0,075 = m=19,17g KOH:0,06 Dap an C iIndi Indi (Indium) 1a mot kim loai kha hiém. mém. dé uGn va dé néng chay, 6 dang kim loai tinh khiét dugc nhiéu nguén tai lieu cho la khong doc hai, dugc hai nha hoa hoc ngudi utc la Ferdinand Reich va Hieronymous Theodor Richter phat hien nam 1863. Khi 6 dang kim loai nguyén chat va bi uén cong thi n6 phat ra cac tiéng kéu rang rac, Ung dung chu yéu cua né hién nay 1a dé tao ra cdc dién cuc trong suét ding trong cdc man hinh tinh thé long (LCD). No cang duge st dung rong rai trong céc Mang mong dé tao ra Cac lp bdi tron. Indi dig thir 61 vé dé phé bién trong I6p vo Trai Bat, nghia la nd co nhiéu gap ba lan bac. Indi dugc san xudt chil yéu tir cdc cn ba con lai sau khi tinh ché quang kém. Nhu cau sit dung indi da gia tang nhanh chong trong nhing nam gan day voi su phé bién cda man hinh may tinh/ti vi LOD.+ ¥ tudng phwong phép: RCOOH +R'OH=—RCOOR '+ HO, Vi bai toan cho hén hgp ancol , axit este tao tif ancol va axit trong hn hgp nén ta cé thé qui d6i gidm s6 chat theo huéng thun loi nhat dé giai quyét bai todn tiyy theo yéu céu dé bai cé hai hung qui déi Huéng 1: quy d6i hén hop axit ancol va este thanh este va midc Hung 2: thém nuiéc quy déi hén hop thanh ancol va axit, Hon hgp P gémancol A, axit cacboxylic B (4éu no, don chiic, mach hé) va este C tao ra tit Ava B. Dét chay hoan to’n m gam P cén ding vita di 0,36 mol O,, sinh ra 0,28 mol CO, Cho m gam P trén vio 250 ml dung dich NaOH 0,4 M dun néng, sau khi két thiic cdc phan ting thu duige dung dich Q C6 can dung dich Q cén lai 7,36 gam chét ran khan, Ngudi ta cho thém bét ‘CaO va 0,96 gam NaOH vao 7,36 gam chat rin khan trén réi nung trong binh kin khong 6 Khong khi dn phén ting hoan toan thu duge a gam khi, Gid tri a gén nhét v6i A.29 B21 C25 D.17 ™@ Huéng dan: mgamP }CyHj,0;—29) 7" Seas) Hy.20 CoHaaea fee <0, {a :0,28 mol {CH 02 3m-2 7 —>mCO, +mH,0 C3H,.0, + 0,289? 036m = 0,06m = 0,28 > m=4,67 Tep.z0, = 0406 won 24 RCOONa : 0,06 iH gO, M5 7,36 gam. >R=293C,H,- NaOH: 0,04 IC,H,COONA :0,06 son-osatns 760m in a Soot 0245 C,H, 0,06 mol = Mey, = 1,88 lat , e Dap an Dcas Hén hgp E gém axit cacboxylic X, ancol Y (déu no, don chtic, mach hé) va este Z duge tao bai X, Y. Dét chdy hoan toan m gam E cén 4,032 lit O, (Alte), thu duigt 3,136 lit CO, (dete). Dun néng m gam E véi 100 ml dung dich NaOH 1M, sat khi phan ting ket thitc, cd can dung dich thu dugc 5,68 gam chat rin khan. Cong thiic clia X la A. C,H,COOH. B. HCOOH. C.C,H,COOH. D.CH,COOH. Huéng dan: C,H2a}20 m gam P }C,H,,,0; >. CJHy,02 3m-2 = = CoH,20, + 0, —+mCO, +mH,O =0,18m = 0,03m = 0,14 m=4,67 Doz,0, = 9403 /RCOONa : 0,03 R=29=C,H,COO! NaOH:0,07 = CH,COOH C01 es 68omnf |C,H,COONa : 0,06 Is oe Vo Reo oie C,H, :0,06 mol => = 1,8) 36 som oe eo, aH mol = Mey, = 18g Dét chay hoan toan 2,76 gam hén hgp X gém C,H,COOH, C,H,COOCH,, CH,OH thu 2,76—0,12.12-0,1.2 16 C,H,COOH:: 0,014 7H 0,06 mol C,H,OH " |M=40,4g C,H,COOH +ROH—>C,H,COOR+H,0 = My,coog = 0501.94,4= 0,944 g Dap én D (THPT QG - 2016) Hén hgp X gém mit axit cacboxylic T (hai chtic, mach hd), hai ancol don chiic cing day déng ding vi mét este hai chtic tao béi T va hai ancol dé, D6t chay hoan toan a gam X, thu duge 8,36 gam CO,, Mat khac dun néng a gam X véi 100 ml dung dich NaOH 1M, sau khi phan ting xdy ra hoan todn, thém tiép 20 ml dung dich HCI 1M 4é trung hoa lugng NaOH du, thu duige dung dich Y. Cé can ¥ thu dude m gam mudi khan va 0,05 mol hn hop hai ancol cé phan tit khdi trung binh nhé hon 46, Gia tri cia m Ja A.7,09. B.5,92, C653. D.5,36. 1 Huéng din: Tinh mol khéi higng NaOH phan ting v6i X Bog = 0,1—0,02 = 0,08 mol Ancol don chic cé trung binh nhé hon 46 suy ra ancol no don chtic hai ancolDc CH,OH C,H,OH, Qui déi X thanh } = C,Hyq,0:0,05 mol CaHan- 24-204 20,04 mol C,H,,0:0,05 mol => 0,04m+0,05n =0,19 mol -{ H,0 m=3 n=l4 'NaQOC-CH, -COONa :0,04 =} HOOC-CH, ~ COOH : 0,04 mol => m g =>m=7,09 NaCl :0,02 spirale Dap An A =Antimatter Phan vat chat dugc cau tao tirnhiing hat nho hon nguyén tir va d6i lap voi vat cht binh thudng. V6i mot lugng nhd (khoang mot gram), phan vat chat c6 thé thay thé toan bd nhién ligu hoa hoc ding cho tau con thoi, c6 thé rat ngan thdi gian con ngudi dat chan lén cac hanh tinh khac. Tuy nhién qua trinh san xudt phan hat rat kho khan va tén kém. Trung tam phan hat I6n nhat thé gidi - phong thi nghiém Fermi 6 Illinois (My) chi san xuat duoc mot phan ty gram phan hat méi nam, véi gid 100 triéu USD (tuong duong 2.100 ty VND). Co nghia la, ngudi ta cn mot trigu nam va 100 nghin ty USD dé san xuat ra mot gram phan hat.© Bai todn loai nay ngudi ra dé cho este phan ting kiém thu duge sp r6i dem d6t. Sit dung phuong phap bao toan nguyén t6 mou = 2su,c0, Anol téch nude thu ete 2ROH—“” 5ROR+H,0 Dou = Byo = Tp Mal = Mae + M,0 ‘Thay phan m gam hén hgp X gém mét sé este don chitc, mach hé bang dung dich NaOH viia dit thu duige a gam hén hgp muéi va b gam hén hgp ancol. Dét chay hoan to’n a gam hon hop muéi trong O, vita dit thu duigc hn hgp khf ¥ va 11,13 gam Na,CO,, Din toan bd ¥ qua binh dung dung dich Ca(OH), du, thu duige 34,5 gam két tia, ding thoi thay khoi lutgng binh tng 19,77 gam so véi ban dau. Dun b gam hén hgp ancol véi H,SO, dic 6 140°C thu duge 6,51 gam hén hgp cic ete, Céc phan ting xay ra hoan ton. Gid tri cia ma A. 17,46. B. 11,64. C.19,35. Dz 25,86. ™ Huéng dan: Na,CO, :0,105 mol RCOONa2"™"54 (CO, exon, HOT EAC, :0,345 mol c 90,345.44 + 18y =19,77 = y = 0,255 mol 2R'OH—R'OR'+H,0> yg Tape =0,105 mol Ls mpcoons 217,46 SS Myon = 84 —MHL; m+0,21.40517,46+8,4=17,46 g Dap én A (XETED Dun néng 22,2 gam hn hgp 2este déng phan cé cing cong thie phan tit C,H,O, véi 200 ml dung dich NaOH a M (du). Chuing cat dung dich sau phan ding thu duigc 24 gam chat rn khan va hén hgp ancol (Q). Dun Q véi H,SO, dic, thu duige t6i da 8,3 gam hén hgp ete. Gié tricia a la: AB B24 C32 D.16 Kall1 Huéng dan: Na* :0,2a 22,2g RCOOR' : 0,3 mol + 24g }RCOO™:0,3 +R'OH:0,3 mol OH :0,2a-0,3 39 0,2a,2340,2a.17-0,3.17+16,3 = 24 Myo =8,340,15,18= 11> m,,=5,9> m0... a6 aah Dap nD. Hén hop X gém mét axit cacboxylic Y va mét este Z (¥, Z déu mach hé khong phan nhdnh). Bun néng 0,275 mol X cén diing 200 ml dung dich NaOH 2M thu duige hén hgp 2 mudi va hén hgp 2 ancol. Dun néng toan bd hén hgp 2 ancol nay véi H,SO, dc 140°C thu dugc 7,5 gam hén hgp 3 ete. L4y hn hgp 2 muéi trén nung véi voi t6i xiit chi thu duge mot Kh{ duy nhat, kh{ nay lam mit mau vita di dung dich chita 44 gam Br, thu duige sin phim chita £85,106% brom vé kh6i lugng, Khéi lugng cua Z trong X 1a A. 19,75 gam, B. 18,96 gam. C. 23,70 gam. D. 10,80 gam. 1 Huéng dan: R.COOH R,COONa:0,15 1 = NaOH :0,4mo} R,(COONa) : 0,125 0,275 mol xfo coon Jy rb ats 4Ra(COONa) R,OH::0,25 mol atb=0,275_ [a=0,15 > |a+2b=0,4 ~ [b=0,125 Hatobcas al : SLX :0,275 mol=n,, = X:CH,, R, (COONa) :0,125 160.100 — C,H, +B, —3C,H,,Br, > %Br= =85,106% > n=2 14n +160 CH, = CH-COOH > HOOC-CH =CH-COOH BRow ol =0,125—Somg oy R,OH:0,25 mol— ny, = 9,75¢—m,, =5,58 Mz = Mooe-cn-cu-coo +My, =19,75 8 Dap An A Cho 2,76 gam mét hgp cht hitu co X tac dung véi dung dich NaOH vita du, thu duge 4,44 gam hén hgp 2 musi cia natri, Dét chéy 2 mudi nay trong O, du, sau khi phan ting hoa 13) Mega book toan thu duigc 3,18 gam Na,CO,; 2,464 lit khi CO, (dkte) va 0,9 gam nuéc, Cong thite don gin fing lA cng thite phan tit cia X.Vay cong thife cu tgo thu gon cia X18 ‘A.CH,COOC,H,, B.HCOOG,HOH. C.CH,COOCH, —D. HCOOC,H, = Huéng din: Na,CO, :0,03 mol 4,44 gam {RCOONa :0,06 mol—°>4 CO, 10,11 mol HO :0,05 mol Mg + Myon = 4,444 Myo =F Myo = 0,04 => HCOOCH,OH Dap in B Thiy phan hét m gam hén hgp X gém mét sé este duge tao béi axit don chitc va ancol don chiic bang mét lugng dung dich NaOH vita dit r6i c6 can thu duige a gam mudi va b gam. hén hop ancol, Dét chay a gam hén hgp mu6i thu dugc hén hgp Khi Y va 7,42 gam Na,CO, Cho toan bé hén hgp khf Y sinh ra qua binh dung dung dich Ca(OH), dui thu duige 23 gam két tiia dng thdi thay khéi lugng binh ting 13,18 gam so vdi ban dau, Dun b gam hén hgp ancol sinh ra v6i H,SO, dc 6 140°C thu dugc 4,34 gam hén hop céc ete. Cac phan ting xdy ra hoan toan. Gid trj m gin nhdt v6i gid tr} nao sau day? AL10. B11. C13. D.12, @ Huéng dan: Na,CO, :0,07 mol RCOONa 22254 [1 one COs _aiom Cac, :0,23 mol 1,0 9 0,23.44+ 18y =13,18 y=0,17mol 2R'OH—>R'OR+H,0 > y,0 = "8" =0,07 mol EL mpc = 0,14.67+0,16.12+0,34 = 11,64 BL mg oy = 4,344 0,07.18 = 5,6 Hs m+ 0,14.40 = 12,48+5,6 = m= 11,64 Dap an DCalifornium Californium (CF) dugc biét dén 1a m6t chat phéng xa cuc manh. Phong xa nay khong chi gay hai cho gene cia con nguéi ma ca tat ca céc sinh vat s6ng, gay ra benh ung thu, tn thuang hé théng mién dich, bénh bach céu, di tat. Hon nda, CF con gay thigt hai di truyén tirviec tiép xc bu xa tich lay trong dot sng thé he nay va cdc thé he saQui déi pepti thanh amino axit va nude: ; Peptit bat ky diéu tgo thanh tit qué trinh triang ngting nhiéu aminonoaxit ban dau Pentapeptit: 5.C, HayyiNOy ~4HjO—> Cy, Hog NO Néu dé bai cho pentapetit ta qui déi thanh aminoaxit tri di lutgng muéc thich hgp mol née a 56 am. [C,H,,..NO, :a mol ae fee hese - Sit dung phutong php bio toan nguyén t6 C, H, O,N Qui 46i peptit thinh dipeptit: i C\H,,N,O, m2 {58 Qui d6i thanh dipeptit c6 gitp gid nhanh bai toén peptit vi dc digm cita dipeptit la mol CO, va mol nudc bing nhau. Néu dé bai cho mol nito ta suy ra dude ngay mol dipeptit dua _pp vao bao toin nguyén t6 nito, Quy d6i X thanh g6c aminoaxit va HO. ; Eee & | peptit —> H,0 (y mol) ([XETED x ia pentapeptit, ¥ 1a hexapeptit, déu mach hé va déu dtigc tao thanh tii mét amino axit (no, hé, chi c6 1 nhém NH, va 1 nhém COOH trong phan ti). - Dét chy hoan toan 0,1 mol X, dan toan bé san pham chy (CO,, HO, N,) vio dung dich Ba(OH), du, thu dude 295,5 gam két tita, ~ Cho 0,15 mol ¥ tac dung hoan toan véi dung dich NaOH du, dun néng thu duge dung dich chita m gam mudi. Gié tri ctia m la: A889, B.93,9. C888, D.999. ™ Huéng dan: D.99,9. X la pentapeptit 5.C, Hay: NOy ~4H{O—>C,,Hoy-N.O, XC, Hog sO, ={rcame aECH yysNO, 0,5 mol fore a, a 0,1 mol X Cathy toa ead 10 10,5. aatow ie y _selOH BaCO, 4:0,5n=1,5 > n=3 #H,O C\H,NO, :0,15.6 = HO 9 mol Cho 0,15 mol C.H,N,O; 4 82 5 CH,NO,Na:0,9 mol > Menage 019.111 = 99,9 g Dap an D ‘Thiy phan hoan toan m gam hén hop M g6m tetrapeptit X va pentapeptit ¥ (du mach 1d) bing dung dich KOH vita di, r6i cd can cn thn thi thu duge (m + 11,42) gam hén hop muéi khan ciia Val va Ala. Dét chay hoan toan musi sinh ra bing mot hong oxi vita dit thu duige K,CO,;2,464 litN, (dikte) va 50,96 gam hén hop gém CO, va H,O. Phan trim khéi hiong cia Y trong hén hgp M cé thé la A.55,24%, B, 45,9896. C.54,54%6, D. 64.59%. 1 Huéng dan: Qui d6i hdn hyp M gém mét tetrapeptit X va mot pentapeptit Y X: RON, sa Vy: R'O,N.3b Ls m+ 206a+262b = m + 11,42 => 206a+262b =11,42 206a+262b = 11,42 = 4a+5b =0,22 +(4a+5)KOH —>C,H,,NO,K +(a+6)H,O CO, :0,22n-0,11 H,0:0,22n K,CO,:0,11 N,:0,11 > Mea, + Myo =13,64n— 4,84 = 50,96 = n= 4,1 eee eet ee 22 ={; ymol NH, ~CH(CH,)- COOH ~ \Sx+3y=4,1.0,22=0,9 Ly ene 0,03 fF Val,(Ala), , :0,03 g& ao mg Y:R'O,N, :0,02 ¥:Val,(Ala),,,:0,02 C,H,,NO,K :0,22 mol > n=2 { Val,( Ala), :0,03 & 0,03n-+0,02m =0,12 > 3n-+2m=12 = = {0,03n+0,02m neon =[jen ¥ :Val,(Ala), :0,02 X :Valy(Ala), :10,74 mg = Ym, = 45,98 % ¥ :Valy(Ala), :9,14 Dap anB aMega book Peptit X va peptit Y c6 téng s6 lién két peptit bang 8. Thiy phan hoan toan X cing nhu Y digu thu duge Gly va Val. Dot hoan toan hén E chtia X va ¥ 6 tilé mol 1:3 cén diing 22,1761 Oxi (dktc) sp chay gm CO, H,0 va N,. Dn toan bo sp chdy vio Ca(OH), du thay khéi lugng, binh ting 46,48g khi thoat ra khdi binh c6 thé tich 2,464 I phan trim khéi luong peptit ¥ trong, E gin véi A91% B82,5% C82% DS15% @ Huéng dan: Qui déi peptit X va peptit ¥ thinh aminoaxit eee eee (CO, :0,22n ag E8881) £020,220 40,1 +b H,O:b Ny 10,11 —H250,22.24++0,99.2=0,22.n340,11+b = 1=3,5> CO, :0,77 4 = -0,18 mol = my =17,88 tt ea? 0,18 mol => m, =17,88g CHsNO,:x | [x+y =0,22 x=0,11 = > CHyNO,:y~ [2x+5y=0,77 Ly=0,11 Gia sti hai peptit X va Y tilé mol 1:3, n+m=10 a=0,01 => 4an+3am =0,22 = in=4 an-a+3am—3a=0,18 |m=6 X:RN,:0,01 _ [X (Gly), Val,., :0,01 = Y:R'N,:0,03- |¥:(Gly),Val,., :0,03 = 0,01x+0,03 7 1(Gly),Valy:0,01__ [X :(Gly)_Valy:3,3 sriaystisaxr6yen| sof (Gly),Val, 0, =| (Gly),Val, y=2~ |¥:(Gly),Val,:0,03 ” |¥:(Gly),Val, :14,58 14:58 199% =81,54% 3D 17,88 Dap dn D 3% = [XEZED Thay phn hoan toan m gam hin hop E gém hai peptit mach hé X va Y bing dung dich NaOH thu duige 9,02 gam hén hgp gm céc mudi cita Gly, Ala, Val. Mat khdc néu dot chay hodn toan m gam E thi cn 7,056 lit O,(ktc), thu duige 4,32 gam H,O. Gia tri cia m la: A636. B7,36. C.4,36, D. 3,36, 1 Huéng din: Quy 461 E thanh aminoaxit va H,0.C;H,;,,0,N (x mol) EB) 0 + 0, >CO, + H,O 4N, (1) 11,0 (y mol) estat cam ‘Mui la C-H,;,,0;NNa (x mol) , [BEE 2xn+x+2y=0,48()) BI.CO: 2x+y+0,315.2=2xn+0,24(0) $M gu =X(14+69)=9,02 (ITD) RMD 1=3,125; x=0,08; y=-0,05 > m= m, x Myo = 6,36 gam at) “BBE mca Dun néng 0,14 mol hn hop A gm hai peptit X (C,H,O,N,) va Y (C,H,,O,N)) voi dung dich NaOH vita di chi thu duige dung dich chita 0,28 mol mudi cita glyxin va 0,4. mol mudi cia alanin. Mat khdc dét chay m gam A trong ©, vita dit thu duige hén hgp CO,, H,0 va N,, trong do téng khéi higng cia CO, va nudc li 63,312 gam, Gid tri m gin nhat li: A.28. B34. C32. D.18, @ Hung dan: NH, - CH,COONa :0,28 NH,CH(CH,)-COONa:0,4 X (C,H,ON,):0 oo > > Y (C,H,,O,N,):b [4a+8 =0,68 Bio toan khéi lvong ta tinh ra kh6i lwong cia 0,14 mol hén hop A co 20,14 mol eae { b=0,03 mol IM, +My,041 = Monin * Maton + Miz =? M, = 46,88. Bao toan nguyén t6 C-va H.. suy ra téng mol C va H trong A: fpeseeen =1,76 ={R 21,76 eee H:0,28.4+0,4.6+0,14.2-0,68.1=3,12 |H,0:1,56 Khi dét chay Jomssniate= a 46,88 gA — igo, + myo = 105,52 mgA— eo, + Myo = 63,312 Dap an A ‘Thiy phan hoan toan m gam hén hgp gém peptit X va peptit ¥ bing dung dich NaOH thu duge 151,2 gam hén hgp gém cc mudi natri cla Gly, Ala va Val. Mat khéc, dé dét chay hoan toan m gam hén hop X, Y 6 trén can 107,52 lit khf O, (dktc) va thu duigc 64,8 gam HO. Gia ti cham la A. 102,4. B. 97,0. 92,5. D. 1078. Ts |PO chanaas 1 Huéng dan: Qui déi hén hop gém peptit X va peptit Y thanh, C,Hoyay NO, amol Pe a leach amo | ant ie ran H,0:b H,O:an+0,5a+b=3,6 ‘an+0,Sa+b=3,6 an=3,9 25 C,H,,NO,Na: amol => a(14n+69)=151,2 EL 2a+b44,8.2 = 2an+3,6=> 2an—2a—-b =6 => 4a=1,4 14an-+69a=151,2 b=-1 = m=1,4.(14n+47)-18=102,4.g Dap én A X va Y lin luot la tripeptit va hexapeptit duigc tgo thanh tl ciing m6t aminoaxit no mach hd, c6 mOt nhém -COOH va mét nhém -NH, Dét chéy hoan todn 0,1 mol X bang O, vita di thu dugc san phdm gém CO, H,O va N, cé téng khéi higng la 40,5 gam. Néu cho 0,15 mol Y tc dung hoin toin véi dung dich NaOH (ly dui 20% so véi lugng cn thiét), sau phan ting cO can dung dich thu duge khéi lung chat rin khan 1a: A.98,9 gam. B.87,3 gam, C.945 gam. D.107,1 gam. m Huéng dan: Qui d6i X thanh CO, :0,3) CHana NO 032 6. as ¢ leno. a.an015 0,2 40,5 8 20, ,15~0, H,0:b=-0,2 Peete teaser N, 20,15 => 18,6n+3,3 = 40,5 = 1=2:C,H,NO, = 18,6n+3,3= 40,5 => n =2:C,H,NO, Qui déi¥ than C,H,NO, : 0,15.6 mol C,H,NO,Na:0,9 HNO, mol oH. mg }CHNO? = m=94,5¢ H,0:b=-0,15.5 NaOH :0,18 Dap dn C Hén hop X gém peptit A mach hd cé c6ng thifc C.H,N,O, va hgp chat B cé cong thite phan ti la CH,NO,, Lay 0,09 mol X téc dung vita dit véi 0,21 mol NaOH chi thu duge san pham la dung dich gém ancol etylic va a mol mudi cita glyxin, b mol muéi cia alanin. Néu d6t chéy hoan ton 41,325 gam hén hgp X bing long oxi vita di thi thu dug N, va 96,975 gam hdn hgp CO, va HO. A.0,50. B.0,76. C130. D.2,60.1 Huéng dn: Dé dang suy ra A Ja pentapeptit va Bla H;N~CH, ~COO-C,H, ft 0,03 (mol) + x (mol) y (mol) y=0,06 (mol) C,H.NO, :0,21 C,H,N,O, :0,03 C,H,0:0,06 X peptit C,H,NO, :0,06 CH, :b H,0:-0,18 mol (C,H.NO, :0,21k C,H,0:0,06 k CH, :bk H,0 :-0,18 kmol 15,27k+14bk = 41,325 [k=2,5 Ik = = 6,975 [bk =0,225 mol |b CO, :0,42k +0,06k.2+bk Hee 7 foe sel [0 :0,705k + bk -0,18k 41,325 ¢ 5 09 mol = a=0,12 mol Dap anc Cho a gam hén hgp X.g6m glyxin, alanin va valin phan ting voi 200 ml dung dich HCL 0,1M, thu dutge dung dich Y, Bé phan ting hét v6i céc chat trong dung dich Y cén 100 ml dung dich KOH 0,55M. Dét chay hoan toan a gam hén hgp X, thu dugc hén hén hgp Z gém CO, H,O VAN, Cho Z vio binh duing dung dich Ba(OH), du, thay kh6i luong binh ting 7,445 gam. Biét cdc phan Ung xay ra hoan toan. Gia tri cla ala A. 3,255. B. 2,135. C.2,695. D.2,765. Huéng din: Qui déiX thanh CO, :0,035" ag {C,Hyq.NO, :0,035 mol —2—»40,5g 4 HO :0,035n-+0,0175 2, N, :0,0175 Meo, + Myo = 2,17 n+ 0,315 = 7,445 = 0 = a =0,035(14n+49) = 3,325 Dap an A (XELEDD Thiy phan m gam hin hop X gém mét tetrapeptit A va mét pentapeptit B (A va B chita <éng thai glyxin va alanin trong phan ti) bing mét lugng dung dich NaOH vila dit r6i c6 can thu duige (m + 15,8) gam hén hgp mudi. Dot chay toan bd lnigng mu6i sinh ra bing mot lugng. oxi vita dit thu duigc Na,CO, va hén hgp hoi Y gém CO, H,O vaN,. Dan toan bé hén hop hoi Y di rat chm qua binh dung dung dich NaOH dc du thay khdi luvong binh tang thém 56,04OE olred gam so v6i ban dau va cé 4,928 lit mot khi duy nhdt (dktc) thoat ra khdi binh, Xem nhu N, Ikhéng bj nuiéc hap thy, cde phan ting xay ra hon toan, Thanh phén phan tram khéi ligng cia Atrong hén hop X la A. 53,0656. B. 55,92% C. 30,95% D. 3537%. mt Huéng din: Qui d6i hén hop X g6m mde tetrapeptit A va m6t pentapeptit B APRON 4 44 4 55)N@OH —>CyHla,NONa+(a++8) 1,0 m a+ 5b)Nat a, NOsNa © B:R'O.Ny:b Se 7 ou Ls m+ 142 +182b = m+15,8 => 1420 +182b = 15,8 142a+182b=15,8_ fa=0,06 => = 4a+5b=0,44 />=0,04 CO; :0,44n—0,22 H,0:0,44n Na,CO, :0,22 Ny 10,22 > Mcp, + Myyy = 27,289, 68 = 56,04 => n= 2,4 C,H,NO,Na : 0,44 mol 2 nai ear a fee ymol NH, ~CH(CH,)-COOH |2x+3y=2,74.0,44=1,06 |y=0,18 Ala ‘A: RO,N, :0,06 A:Gly,(Ala),_, 10,06 ne pera teenies m3 og ae 20,06 B:Gly,(Ala), :0,04 = {0.051+0,01m=0.26 9 6+4n=26-{ , m= => %m, 3,06 g A:Gly,(Ala) :15,6 2 1 B:Gly,(Ala)y 13,8 g Dap an A ‘Thity phan hoan toan 0.09 mol hén hop X gém Tripeptit, tetapeptit, pentapetit voi dung dich NaOH via dit thu duge 16.49 gam musi cha Glyxyl, 17.76 gam mudi cia Alanin va 6.95 gam muéi cia Valin, Néu dét chay hoan todn m gam hén hop X thi thu dugc CO,, HO vaN, trong dé téng khéi lugng cia CO, va HO 4 46.5 gam. Gid tri gin ding cia m la: AL24 B21 C.26 D.32 | Huéng dan: (CH,NO,Na:0,17 0.09 mol.X “2 44C,H,NO,Na:0,16 +H,0:0,09 mol C,HyyNO,Na:0,05 mol EM sy o7 = 9,17 + 0,16 + 0,05 = ,38 mol => my = 1,62gBao toan hidro va cacbon khi dét chay 27,62. g.X —*£+CO, :0,17.2+0,16.3+0,05.5 = 1,07 mol 25 H 20,174 +0,16.6+ 0,05.10+ 0,09.2—0,38 = 1,85 = my, = 0,925. > Meo, + Mao = OTE ects +My = 63,738] = m= 20,15 m Xoo Mep, + Myo = 46,5 | : Dap an B TEED Dun néng 0,14 mol hdn hop A gém hai peptit X (C,H,ON,) va Y (C,H,0,N) véi dung dich NaOH vita dit chi thu duigc dung dich chita 0,28 mol mudi cia glyxin va 04 mol mudi cita alanin. Mat khéc dét chay m gam A trong O, vita di thu duige hén hop CO, H,O va Ny, trong dé tng kh6i higng ciia CO, va nutéc ld 63,312 gam. Gié tri gin diing nhit cia m La 32. B18. C34. D.28, 1 Huéng dan: aatnotal | (C.H,0,N,):4 feign a ° ¥ (C,H,0,Ne):6 [4a+66=0,68 X (C,H,O.N,) :0,08 CH,NO,Na:0,28 auanota{ —teatnsbnel , B { a +0,14 mol HO ¥ (C,H,,0,N) :0,06 C\HNO,Na:0,4 YS 4nd = 0,28.24+0,4.3=1,76 = Neo, 94H ong = 0,28.4+ 0,4.6+0,14.2~0,68 1= 3,12 Myo = 1,56 Asm, = my + My,9 — Myson = 46,888 Lapluan: 46,88g4 23 mcg, + Myo = 105,52 — fe Armco, + Myo = 63,3128 | = 46.88.63,312 og og 105,52. Dap én D. [XEEEED Cho 0,7 mol hén hop T gém hai peptit mach hé la X (x mol) va ¥ (y mol), déu tao bai glyxin va alanin. Dun néng 0,7 mol T trong lugng du dung dich NaOH thi cé 3,8 mol NaOH phan ting va thu duoc dung dich chia m gam mudi. Mat khéc, néu dét chay hoan toan x mol X hoc y mol ¥ thi déu thu duge cing s6 mol CO,, Biét tng s6 nguyén tit oxi trong hai phan ti X va Y la 13, trong X va Y déu o6 6 lién két peptit khong nhé hon 4. Gid tri cla m Ia A. 396,6 B.3408 C.409,2 D. 3994ecg i Huéng dan: + Truldc hét ta tim s6 mat xich trong X va Y tong ting La m, n =5 Taod: Y0=13=2n+2m- (n=l) -(m-1) Smtn=11 ofr Owen Owngtio 1-5): (mol) =0, “exe a XC0°5):8(mol)_yrorsy f+b=07 _ fa=04 Y(n=6):b (mol) 5a+6b=3,8 — |b=0,3 X (C,H,ON,):04 CH,,,,NOz 33,8 0,7molA ye Hels CH NO;Na 33,8 : ¥ (CH,ONe):0,3 H,O 04x 20,30 2a 3a 2 7 1OSHO4 _ 9 59 n 416 38 m=396,6g Dap An A Hén hop X gém tripeptit Y, tetrapeptit Z va pentapeptit T (déu mach hd) chi duge tao ra tii Gly, Ala va Val. ét chy hoan toin m gam X, r6i cho toan bé san phém chéy (chi gém CO,, H,O va N,) vio binh dung 140 ml dang dich Ba(OH), 1M, sau khi cic phn ting xy ra hoan toan thay c6 840 ml (dktc) mot khi duy nhét thoat ra va thu dugc dung dich c6 khoi higng tang 11,865 gam so véi khéi lung dung dich Ba(OH), ban déu.Gid tr cita m gin véi gid tr} nao nhit sau day? A.7,26 B.6,26. €.8,25. D.7,25. mt Huéng dan: Qui déi hn hop X gm tripeptit Y, tetrapeptit Z va pentapeptit T (déu mach hé) chi dugc tao ratit Gly, Ala va Val thanh dipeptit bang céch thém mét luigng miéc thich hop As (B), 22> agC,H,,N,0, :0,0375—2> ©), 20,0375: eee ojamat neon), , [BaCO, H,0:0,037 30 HCO) N; :0,0375 if = mis®=11,865 Igo, + Miysg ~Mtgaco, = 2,325 197(0,28-0,0375n) = 11,685 9,7125n = 66,845 = n= 6,88 =) a= (14n-+28+48).0,0375 = 6,46 SMA —Myy = 646 My = M< 6,46 B Dap an B Pos[XEEEBD Den néng 4,63 gam hén hp X gém ba peptit mach hé véi dung dich KOH (vtia di). Khi cac phan ting két thu, c6 can dung dich thu dugc 8,19 gam mu6i khan cia céc amino axit déu 6 dang H.NC,H, COOH. Dat chéy hoan toan 4,63 gam X cn 4,2 lit O, (dktc), hap thu hét sin phm chay (CO,, HO, N,) vao dung dich Ba(OH), dui. Sau phan ting thu duige m gam két tia va khéi lugng phan dung dich gidm bét 21,87 gam, Gia trj ca m gin gia tr] nao nhét sau day? A. 35,0. B.275. C325. D.30,0. @ Huéng dan: Quy di X thanh aminoaxit va H,O. CcH,;,,0;N (x mol) X—94,63g4 9 = 4x +47x+18y =4,63(1) H,0 (y mol) Mu6i la C;H,-O,NK (x mol) = 14nx + 85x = 8,19.g (2) Eu 1 CO, nx 463g {Cota O2N MOD] sues. | 0: yanx40,5¢ H,0 (y mol) Ny& 2 22 4 2x4 y 40,375 = nxt ytnxt0,5x = 3n.x—1,5x =0,375(3) {i =0,16= neo, = Masco, = Manco, = 32,98 = 32,5 Quy d6iX thanh géc aminoaxit va H,O. atta ; CO, sx X—>4,63g) "7 ea + —OistsmelOe 5d HO: y +n.x—0,5x H,0 (y mol) e HD sx 4 y4+0,375 = Inxty+nx—0,5x =3 3nx-1,5x=0,375(1) ‘Mudi la Mui la C,H1,.0,NK (x mol) = 14mx+85x =8,19¢ (2) {rx =0,16= neo, = Ngaco, = Marco, = 3b 52g = 32,5 Quy déi E thanh dipeptit (CO, nx X—#5C,H,,0,N, + 50 0 an reer Nyex 82-4 3x 40,375 = 3nx = 3nx -3x = 0,375pe Leaad Muéila C, ,.H_O,Nk (2x mol) = m,,,., = 2x (7485) = 8,19 (II) ‘oseHl,O7 1Anx+170x = 8,19 =9 mx = fico, = 0,16 = Mg.co, =31,52g = 32,5 Dap an C {ZEXLD hay phan hodn toan m gam hdn hgp gém peptit X va peptit Y bing dung dich NaOH thu duige 151,2 gam hén hp gém cdc mudi natri cita Gly, Ala va Val. Mat khéc, dé dét chay hodn toan m gam hén hgp XY trén cn 107,52 lit khi , va thu duge 64,8 gam HO. Gié tri cha ml A102,4 B.97,0 C.92,5 D.107,8 m@ Huéng din: ‘Ta sé xit ly bai todn bing céch thém mudc va quy 46i vé Dipeptit ! Khi ding phuong phdp quy 46i nay, Céc ban phai nhé rang: no, ding dé dét chéy hdn hop trutéc va Mudi+ H,0. — n& = 2,04 sn, =12,14) CO, :16na-8a 8a N, :10+80 ty = Bys,co, = 48na-24a = 4,08 nna = 0,105 — 16na+0,46+10=12,14 a=0,04 m= (14n + 29)16a+ 18a = 224na+ 482a = 42,8(gam) Dap an C X a dipeptit Val - Ala, Y la tripeptit Gly - Ala - Glu. Dun néng m gam hén hop X va ¥ c6 1118 s6 mol n,:n, = 3: 2 voi dung dich KOH vita di, sau khi phan ting két thitc thu duge dung dich Z. C6 can dung dich Z thu duge 17,72 gam mu6i., Gi tri cha m gdm mhdtvéi ? ‘A,12,0 gam. B. 11,1 gam. C.11,6 gam. D, 11,8 gam. 1 Huéng din: Phan tich hudng giai Gly-K:2a Val—Ala:3a Ala-K:5a Ta cb: 11,2 Gly~ Ala —Glu:2a Val-K:32 Glu-K, 2a oe BERL 517,72 = a(113.2+ 127.5 + 155.3 + 223.2) 9a =0,01 +m = 0,03(89 +117 18) + 0,02(75 +89+147—36) =11,14 Dap an B Peptit X va peptit Y c6 tong lign két peptit bang 8. ‘Thay phan hoan toin X cing nhu Y a =n Y+1,95.2+2.8,4825 =5,85n+y+0,975 Val:b [—*£52a+5b=3,4.1,95=6,63_ fa=1,04 a 8 > = wink Gly:a ~ |—** 5a+b=1,95 b=0,91 b 7 Dap an B ([XELED Hon hop E gém chat X (C,H,,N,O,) va chat ¥ (CH,,N,O,), trong 46 X 14 muéi cita axit da chiic, Y Ia tripeptit. Cho 27,2 gam E tac dung véi dung dich NaOH du, dun néng thu dutge 0,1 mol hén hgp 2 Khi, Mit khéc 27,2 gam E phan ting véi dung dich HCl thu duge m gam chat hatu co. Gid tri cita m 1a A, 44,525 (gam) B. 39,350 (gam) C. 34,850 (gam) D. 42,725 (gam) 1 Huéng dan: X (CH,N,O,): NH, -OCO-CH, ~COONH, CH,NH,OCO-COONH, (C,H,N,O,): NH, - CH, ~ CO-NH-CH, ~ CONHCH(CH,)-COOH Cho 27,2 gam E tac dung véi dung dich NaOH du, dun néng thu duige 0,1 mol hén hgp 2 khi, Suy ra X: (CH,NH,OCO-COONH, + NaOH —>(COONa), +CH,NH, T+NH, T+H,O a 2 para 2a =0,1= a =0,05mol Ng g,940, = ,1mol 27,2 gam E phan ting véi dung dich HCl thu duge m gam chét hitu co CH,NH,OCO-COONH, +2HC1—+2(COOH) + CH,NH,Cl+ NH,CL 0,0s —_____» 0,1 ——_______—+0,05 C,H,,N,O, +3HC1+2H,0—> mudi 0,1 90,3 90,2 Myer = 42,7258 My. = My + Myo, +My, Dap an D eal[XEVEDD Hon hop A gém dipeptit mach hé X (c6 cong thtic phan tif A C,H.N,O,) va mét mudi Y (cé.c6ng thttc phan tit i CH,N,O,). Cho 0,5 mol A phan ting vita dit v6i dung dich NaOH dun néng, thu duigc dung dich Z chia m gam muéi va 4,48 lit khi'T (dktc, lam xanh quy tim 4m). Gia tri cita m gan mbit v6i gid tri ndo sau day? A. 75,55. B.77,54. C. 80,23. D. 88,10 @ Hudng dan: NH,CH,COONa : 2a S245, NaNO, :b CH,NH, ‘NH,CH,CONHCH,COOH :a 0,5mol mol ene. b => m=97.0,6+0,2.85=75,2g Dap in A Hon hgp M gém peptit A mach hé cong thifc C,H N,O, va hgp chat B cé cng thtic phan. ttt la C,H,NO,, Lay 0,06 mol M tic dung vita dit véi dung dich chia 0,14 mol KOH chi thu dugc sin phém gém ancol etylic, a mol muéi cita glyxin va b mol mudi cia alanin. Mat khac, d6t chay hoan to’n 26,85 gam hén hgp M bing lvqng Oxi vita dé r6i cho toan bé san phém chay (CO,, H,O va N,) vao binh dung dung dich muéc v6i trong du thi thy thodt ra mot chat ‘khi duy nhdt déng thdi kh6i lugng binh ting thém 61,55 gam. Biét ring N, khong tan trong nutéc. Tig a: b bing? AL2:5. B32, C.5:2, D.2:3. 1 Huéng dan: Nhfn thy A/a pentapeptit _P™7._, Cé ancol etylic nén chat B phai la NH,CH,COOC,H, CH,NO:0,14k (C)H, 0 :0,04k H,0:0,02k CH, :0,02.k.n FE k(57.0,14 + 0,04.46 + 0,02.18) +0,02kn.14 = 26,85 — }CO, : k(0,14.2 +0,04.2 +0,02n) in 0:0,21k-+0,12k +0,02k +0,02nk ad +0,28nk = 26,85 ‘V6i 26,85 gam M ta dén thanh 44. (0,36 +0,02n) + 18(0,35k+ 0,02nk) = 61,55 feu “s— [22,14k + 1,24nk = 61,55 = n=2nén A dude tao béi 2Ala va 3Gly im Iead (XETED x. ¥, Z, T la cac peptit déu duge tgo béi cdc a-amino axit no chia m6t nhom -NH, va 1 nhém ~COOH va c6 téng 6 nguyén tit oxi fa 12, Dét chay 13,98 gam hin hgp E chtta X, ¥, Z, T cn diing 14,112 lit O, (dktc) thu duge CO, H,O va N,, Mit khéc dun néng 0,135 mol hén, hop E bang dung dich NaOH (ldy dut 20% so v6i phan ting), cd can dung dich sau phan ting thu duige luigng chat rn khan 1a A.24,51 gam. B.31,5 gam, C.25,84 gam. D. 36,05 gam. 1 Huéng dan: Qui déi X, Y, Z, T thanh aminoaxit cuit ICO, :an 1a 13,98.g.4 °° 29 28m. 51H O:ant+b H,0:b a a —*2 33a +b+0,63.2 =3a.n +b = 3an—3a = 1,26 <> an—a=0,42 13,98-+18b + 20,16 = 62an +18b+28a = 62an + 28a =34,14 fat [oe = =) 07 a=0,09 ~ |n= C\yHy,0,NNa:0,27 Suy ramudi:mg, 7 >m=31,5¢ 20,054 Dip inB ‘NaOH : 0,05: Peptit X va peptit ¥ c6 tong lién két peptit bang 8, Thuy phan hoan toan X ciing nhu Y déu thu duge Gly va Val. Dét chéy hoan to’n hén hgp Z chita X va ¥ c6 t 8 mol tuwong ting 1:3 thi cn ding 22,176 lit O, (dktc). Dan toan bd sin pham chay gém CO, H,O va, vao binh dyng dung dich Ca(OH), du thay khdi ligng binh tng 46,48 gam, khi thost ra khdi binh cé thé tich 2,464 lit (dktc). ‘Thuy phan hoan toan hén hop Z. thu duigc a mol Gly va b mol Val. Ty 1é a:b la AJL B12 C21 D.23 i Huéng dan: aerate Co, :0,22.n (en 2422 M0" oop mWtO, H,0:0,22n+40,11+y wy N,:0,11 mol 40,92n +18y +1,98 = 46,48 40,92n+18y=44,5 _ — a eee 3n=3,5 y+0,22.2+2.0,99=0,66n+y+0,11 — [0,66 Val:b 50,22 = 0,77 Gly 22Dun néng 0,045 mol hén hgp A chia hai peptit X,Y (s6 lién két peptit hon kém nhau 1 lién két peptit) cén vila dit 120 ml dung dich KOH 1 M thu duigc hn hop 2 chifa 3 mudi cita Gly, Ala, Val trong dé muéi Gly chiém 33,832% vé khéi long. Bét chay hoan toan 13,683 A cn 14,3641 khi O, 6 dkte thu dugc hin hgp khi va hoi trong dé tng khéi higng CO, 1a 31,68g phan trin khéi lugng ciia mudi Ala trong Z gin nhét voi A.50% B55% C45% D.60% nuéc | Huéng dan: Bio toan khéi ligng tinh ra khoi lugng nito. 1a68ga Bastiat 21689 [O% tay 2,522.9 ny, =0,09 mol F Qui déi A thinh amino axit ban vA nude CQHyz NO, :0,18mol 4 ocarasemt 31,68g co, 0.18.0 H,0:b mol H,0:0,18n+0,09+b —Y250,18,2+b +1, 2825 = 0,54n +0,09+ b= n = 2,875.mol = b=—0,1125 mol 13.6te—45f Tinh peptit trung binh Ryo _ O12 _ 8 my, 0,045 3 =2,67 suyra A gém dipepti va tripeptit. Sc, ss, ,NO, -3H,0—0, 1 uN ,O,, 354 >M, = SB 0,045 mol A =m, = C,H.NO,K:a 9,12g A—HOH222¢1_5 me {C\H,NO,K :b +0,045 mol H,O C.HyNO,K:¢ _113a.100 15,03 = erie hanes 3 %eypoge 06 127b+155¢=9,945 ” |o=0,015 mol sm 15,08 Dap an A 12g HH 5 m= 15,03 %iNenno.e = 33,832 =3.a=0,045 mol 100 = 50, 69% [XELED bun néng 0,03 mol hén hop E gém hai peptit X (C,H,O,N,) va Y (CH, O,N) can ding 300 ml dung dich NaOH 1,5M chi thu dugc dung dich chtfa a gam mudi cta glyxin va b gam mu6i cia alanin. Mit khac, dt chay 60,90 gam E trong O, vita di thu dugc hon hgp CO, H,O vaN,, trong dé tong khéi lugng cia CO, va nude la 136,14 gam. THe a: b gin nhat véi gid tri nao sau day: A.0,765, B. 0,625. C.0,750. D.0,875, aMega book X (C,H/O,N,):x ¥ (CH,ONs):¥ x+y=0,08 0,05 = = 6x4 5y = 0,45 ,03 Qui d6i E thinh amino axit va nutée. 5,625C;H,;,,NO; — 4,625H,0—C, 5H, sy, DAC. 0,08 mol E { Ns 305.05 INse2sOsaas = My = 78, 75.0 +181,125 H, h.2si1 CO, :5,625n: Amol Cyeas;Hya5-asNsasOes —eonsitel ia H,0:5,625na—1,18125a 152 31375 sn=— 3614 |a=0,16 facet mol {apse > = i 78,75na+181,125a = 60,9 348, 75na —32,625a = = 220,875 24 b 2a+3b=1,14 Dap an D ‘Cho 0,225 mol hén hgp M gém hai peptit mach hé la X (x mol) va Y (y mol), déu tao boi glyxin va alanin. Dun néng 0,225 mol M trong lgng du dung dich NaOH thi c6 0,775mol NaOH phin ting. Mit khdc, néu dét chay hoan toan x mol X hoacy mol ¥ déu thu duge cing 86 mol CO,. Téng s6 nguyén tit oxi cia hai peptit trong hén hgp M la 9. Téng s6 nguyén tit Hidro cita hai peptit trong M la: A.34, B.33, C35, D.36. m Huéng dan: 31 ‘Tinh peptit trung binh “MH ==" =3,4 Tepe 9 Goi m van in lugt li s6 aa tgo thanh hai peptit trén 2m-(m=1)+2n—(n-1)=9 >m+n=7 X:RN,:x _ fxty=0,225 > > Y:R'N,:y [3x4+4y=0,775 Col 8 Cy 0,125 10 X: Ala— Ala -Gly:2.C,H,NO, +C,H,NO, -2H,0 —>C,H,,N,O, Y; Ala Ala ~ Gly ~Gly:2.CH,NO, +2C,H,NO, ~3H,0 —>C,H,N,0, = DA=33 C,.0,125 = Cy.0,1> Dap an B(ELE Hin hyp X gém Gly -- Ala- Ala, Gly- Ala-Gly- Ala, Gly - Ala Ala- Gly - Gly, Ala-Ala. Dét m gam hon hgp X edn vita dit khi O, (Aktc) thu duige 0,825 mol H,O va 0,9 mol CO,. Lay toan bd m gam X trén tac dung véi lugng vita di V lit dung dich chita NaOH 1M va KOH 1M. Sau phan ding c6 can dung dich thu duc m’ gam chat ran. Gid trj cha m + m’ gén nhit véi: A, 63 (gam) B. 64 (gam) C. 65 (gam) D. 66 (gam) @ Huéng dan: C,HNO:a(x+2) Dén Xvé (Ala), Gly), :a(mol) —>{CH, :2a HO:8 Tinh ra awe { Poe 59 nlte* = 0,35 m= 24,55 n+m'=64,lgam m'=39,55 Dap in B [LET 115n hop M gém peptit A mach hé céng thiic C,H,N,O, va hop chat B c6 ong thie phan tit la C.H,NO,, Léy 0,06 mol M téc dung vita dit véi dung dich chia 0,14 mol KOH chi thu duige sin phém gém ancol etylic, a mol muéi cia glyxin va b mol muéi cia alanin. Mit kh, dét chay hoan toan 26,85 gam hén hop M bang lugng Oxi vita dit réi cho toan bd sin pham chy (CO, H,O va N,) vao binh duing dung dich nude voi trong dui thi thay thost ra mot chét hi duy nbat déng thoi khoi Ivgng binh ting thém 61,55 gam, Biét ring N, khong tan trong nuidc, THe a: b bang? AL2:5, B.3:2, C52, Dz2:3, © Huéng dan: : : meng, Ja =0,02mol Nhin thy A 18 pentapeptit ef adel Cé ancol etylic nén chat B phai la NH,CH,COOC,H, [C,H,NO:0,14k }C,H, 0:0,04k H,0:0,02k CH, :0,02.k.n ‘V6i 26,85 gam M ta dén thanh EEL, k(S7.0,14 + 0,04.46 +0,02.18) +0,02kn. 14 = 26,85 —. (CO, :k(0,14.2 +0,04.2-+.0,02n) 10,18k +0,28nk = 26,85 fe (0,36 +0,02n) +18(0,35k+0,02nk) =61,55 10,18k +0,28nk = 26,85 k=2,5 fies +1,24nk = 61,55 f; =2WMega book s BFE $0900000000000000090000000000000K = May ae = 0.02.2 = 0,04 =2né béi 2Ala va 3Gh eee 7 ao. ai eee i 2Ala va 3Gly —5. etna caus ooieats ip an 7 2 EID Hon hop X g6m hai peptit (duidc tao bdi Gly, Ala, Val), metylamin va axit glutamic. Dét chéy hoan toan m gam X (trong €6 s6 mol ctia metylamin vA axit glutamic bing nhau) thu duigc 0,25 mol CO,, 0,045 mol N, va 0,265 mol H,O. Gia tri cia m gan nhat voi: A.7,42 (gam) B.7,18 (gam). C.7,38 (gam). D.7,14 (gam) ® Huéng dan: + Vis6 mol metylamin va axit glutamic bing nhau nén dén X vé: (C,H,,.yNO:a(mol) oe « » ‘ joe «Ta c6 thé c6 thé gidi thich rét “nong dan” nhu sau: ‘Véi 2 peptit mdi chat bd di mot phan tit nuéc la nd bién thanh C,H,,.NO Cén metylamin va axit glutamic ta cOng g6p lai r6i ném di 2 phan tit nude ciing sé bién thanh C,Hy,4NO H + a a (mol) 0,53 0,092.21) +E Sb. : =0,06 (mol) + Vaym=0,09 (4. 2 -1414+16)+0,06.18=7,19(gam) Dap én B ‘Thay phan hoan toan m gam hén hgp gém peptit X va peptit Y bing dung dich NaOH thu dugc 151,2 gam hén hgp gém céc muéi natri cita Gly, Ala va Val. Mat khac, dé dét chy ‘hodn toan m gam hén hgp X, ¥ trén cin 107,52 lit khi O, va thu dutge 64,8 gam HO. Gié tri cia m la: A.102,4 (gam) B. 97,0 (gam) C.92,5 (gam) D. 107,8 (gam) @ Huéng dan: Ta sé xit ly bai toan bing cach thém nude va quy d6i vé Dipeptit! Khi ding phuong phép quy déi nay, Céc ban phai nhé ring: No, ding dé dét chay hdn hop truéc va sau la khong d6i va khi thy phan hén hop trudc va sau thi NaOH ding cting khong d6i! Do vay tacé: rad sug {CO, -(3,6+y)mol { —42_>C,H,,0,N, —*—>}H,0-(3,6+y) mol Y ves xa N, -x(mol) raf) C,H,0,N, 2! > Mui +1,0 Se Gor Gea) enEME 43x 44,8.2=3.3,6+y) x=0,7 ENTS 5 nx =3,6+y > yy=0,3 EEL (14 + 76).x +56.2x =151,2+18% n=32, 7 >m=(14. 7 +76)0,7-18.0,3 =104,218). Dap én A ED Thay phan m gam hén hop X gém tetrapeptit Y va pentapeptit Z bing dung dich NaOH vita dit r6i 6 can thu duige (m+23,7) gam hén hgp mudi cia Gly va Ala, Dét chy toan b> lugng mui sinh ra bang mot lugng oxi vita di thu duige Na,CO, va hén hgp hoi T gém €O,,H,0 va N,, Din toan bé hén hop hoi T di rét cham qua binh dung dung dich NaOH dic dut dit thay khoi Luong binh tng 84,06 gam va c6 7,392 It mot khi duy nhit thoat ra khoi binh, Thanh phén phén trim khéi higng cha Y trong hén hop X cé tri gin nhét vai (Biét thay phan Y hay Z déu thu duige Gly va Ala): A.53% BL 54% C. 55% D.52% 1 Hudng din: Dé thay ta cn xit ly bai todn dét chy truée: EEN, Na,CO, ‘one 'C,H,O,NNa] 9, | JCO, C,H,O,NNa H,0 "sta ws) Na 035m) Noo, = x (mol) 44x +18y = 84,06 ‘x =1,26 (mol) Dit = ° Tyo = (mol) x+y =0,33 y =1,59 (mol) Degnoyma =2] [BEES 4 20436 =1,2640,33] | fa=0,39 Dat: 4 ae Neyo. =D a+b=0,66 b=0,27 m+ 23,7 =0,39.(74 +23) +0,27(88+23) > m= 44,1 gam id quay ngu¢éc lai xi! ly bai toan chinh: 039400) Gly-Na Ala—Na oT) +H,0 eine PH sn = tO 6640 (n423.7. =0,15 (mol)Eee Y,-x(mob)]_ fxty=0,15 | _, [x=0,09(mol) Z,-y(mol)f ~ |4x+Sy=0,66{ ~ |y=0,06 (mol) Goin, m lin ugt la s6 mat xich Gly c6 trong X,, Y, =2 21925 0,09n +0,06m = 0,39 4 {re : } 0,09(75.3+89-18.3) _ 59, 44,1 3 Y:Gly-Gly-Gly-Ala > %my Dap an A [XETEED Dun néng 0,16 mol hon hgp E gém hai peptit X (CH,O.N,) va Y (C,H, O,N)) cfn ding 600 ml dung dich NaOH 1,5M chi thu dugc dung dich chifa a mol musi ciia glyxin va b mol mu6i cia alanin, Mat khéc d6t chéy 30,73 gam E trong O, vita di thu duigc hn hgp CO,, HO VAN, trong 46 t6ng khéi ligng ctia CO, va nuldc la 69,31 gam. Gid tri a: b gn nhat vii A, 0,730. B, 0,810. 0,756. D.0,962 @ Hudéng dan: X (C,H,O,N,):x (mol =0,16 0,1 (mol) ool! 6) XC oe +f (mol) Y (C,H,O,N,):y(mol) |6x+5y=0,9 — [y=0,06(mol) X (C.HON,):0.1¢m09 4g [CANNOHO? —+slcn,: em Y (C,H,,O,Ns):0,06 (mol) 1,0:~0,74 mol C,HsNO, :0,9k 30,73 gam E | CH, :bk 269,31 ef H,0:-0,74k mol (CO, :1,8k-+bk H,O:1,51k+bk k=0,5 = {b=0,52=9 2 =0,73 Wiesel etgs Wek ja =0,38 106,38k + 62bk = 69,31” |bk=0,26 Dép dn APainit dugc phat hién va dat ten boi Arthur C.D. Pain vao nam 1950. Trong vai thap ki sau d6 cing chi 6 2 tinh thé moi dugc phat hién. Day dugc coi la Mot Khoang chat rat cing va cyc ki hiém. Nam 2005, Sach ky luc Guiness thé gidi da cong nhdn Painite la loai khong sin quy hiém nhat, chi cé khoang 25 mau khodng vat nay dugc tim thay trén toan thé Gi6i. Boi sy khan hiém d6 ma Painit co gid thanh “cao ngut” - khoang 300.000 USD (khoding 6.36 ty VND/a).¢ Phuong phap triing nguing héa giip gidi nhanh bai toan hén hgp peptit cho biét ti lés6 mol cita cae peptit trong hén hgp . ¥ tudng cia phitong phép tring ngung héa la chuyén hén hgp peptit thanh mt hn hop méi bing cach gop hén hop peptit thinh mét peptit mdi va nuéc. Phuong phap gidi: B.:dyfa vao gii thuyé dé bai cho ta gop hn hgp peptit thinh 1 peptit méi va nudc. B,tinh mol céc aa. Lap tiI¢ mol peptit tim tile ti gian B,: tinh $6 géc aa $6 géc aa bing téng tilé t6i gidm nhan véi s6 k (k la s6 ty nhién khéc khong) Bign Iuan tim k, $6 gc aa trung binh In hon 2 B, tinh s6 mol miéc thity phan peptit méi bao toan khéi higng tinh ra khéi lugng peptit. Bai toan loai nay khong cn xc dinh peptit 1a tri hay tera hay penta peptit Hén hgp A gém ba peptit mach hé cé ti Jé mol tuong ting 1:1:2. Thy phan hoan toan m gam A thu dugc hén hgp sin phdm 52,5 g Gly va 71,2 gam Ala biét téng s6 lién két peptit trong phan tii X nhigu hon trong Z va tong s6 lign két peptit trong ba phan tit X, ¥, Z nhé hon 10 gid tri ca m 1a 4.967 B.101,74 €.100,3 103.9 @ Hudng dan: Phuong phép g6p chudi peptit X.¥.Z X4¥4Z4Z—9X-¥-Z-Z+3H,0 ‘Thay phin hdn hop A cing nhu thay phin (E+3.H,0) fe :0,7 mol __, Gly Ala:0,8mol Ala ke=1:— 915 me (E+3.H,0)+11.H,0—> 1Gly +84la { 1,1-———0,7- —0,8 = mx = (748) k=15k |. m, =103,9g, Dap an DHén hop T gém ba peptit mach hé X, Y, Z c6 ti 1é mol twong ting 1a 2: 3: 4. Thay phan hoan toan 35,97 gam T thu duge hén hgp san phdm gém 0,29 mol A gam va 0,18 mol B. Biét t6ng 36 lién két peptit trong ba phan ti X, Y, Z bang 16, A vi B déu la aminoaxit no, ¢6 1 nhém -NH, va 1 nhém ~COOH trong phin ti. Néu dét chay 4x mol X hoe 3x mol ¥ déu thu duge 36 mol CO, bang nhau. Dét chay hoan toan m gam hdn hgp T thu duige N,, 0,74 mol CO, va a mol HO. Gid tri a gin mbit li: A.0,65 (mol), B. 0,67 (mol). €. 0,69 (mol) D.0,72 (mol). i Huéng dan: Goi s6 aa trong méi pepetit X, ¥,Z1a NNN, X 22x 94 :3x => 2x.N,+3x.N, +42.N, =0,47mol = 2.N, +3.N, +4.N, = 24" Z:4x =>.1=0,01=2.N, +3.N, +4.N,=47 N,-1+N, -1+N,-1=16 = N,+N, +N, =19 2 et N,+2N,=9=),? "VAN, =5 m=10 | loai. (X),2 0,02 7 A:C,Hyyq10,N 10,29 mol => 35,97gT 4(Y), 20,03 —Pateetihe ‘afl 29410,N :0,: . 7 04 Bi C,Hamsi02N 20,18 mol 4,06n+2,52.m= 20,72 4,06n< 20,72 n<5,1 n=2 m= Bai ton chia hai phn khOng bang nhau . 35,97g T——>CO, :1,48 mol —> H,0 :1,335 mol mgT——~+O, :0,74 mol —> H,0:a mol I ]emsersma Dap én B (KB -2014) hén hop g6m ba peptit déu mach hé cé tilé mol tuong ting ]a 1:1:3. Thy phan hoan toan m gam X, thu duge hén hop sin phém gém 14,24 gam alanin, va 8,19 gam valin. Biét tng sé lién két peptit trong phan tii cita ba peptit nhé hon 13. Gid tri cha m la A. 18,83 (gam) B. 18,29 (gam) €.19,19 (gam) D.18,47 (gam) i Huéng dan: Phuong phép gop chudi peptit A, B, C. A+B+C+C+C—34-B-C-C-C+4H,0 ¥POs alco ‘Thiy phan hén hgp A ciing nbu thiy phan (£+4.1,0) 7 Val:0,07 mol Gy 0.07, mura (7-416) k= 23k Ala:0,16 mol Ala 0,16 k=1:—>23 mx (E+ 4.H,0)+18.H,0—> |6Val +7 Ala 19,19. 0,18¢—— 0,160, 07, hl Dap nC Hén hop M gém mét peptit X va mét peptit Y (ching dugc cu tao ttt 1 loai aminoaxit, t6ng s6 nhém -CO-NH- trong hai phan tit Ia 5) vdi tiIé s6 mol n,: n, = 1: 3. Khi thiy phan hoan toan m gam M thu duigc 81 gam glyxin va 42,72 gam alanin, Gié tri ctia m la A. 104,28 gam, B. 109,50 gam. 1 Huéng dan: C. 116,28 gam, D, 110,28 gam. Phuong php gop chudi peptit X,Y, X+Y4¥4¥— Y-¥+3H,0 Thity phén hén hop M cing nhu thiy phan (£+3.H,0) Moy = 108 _, ray _ 9 Ng = 0,48 = k=1=913.mx S134 Naw (E+3H,0)+9H,O—39Gly + 4Ala % 99 = m=104,28¢ 1,08 1, 08 Dp dn A ‘Hén hop M gém mot peptit X va mot eptit Y (chting cfu tgo tit 1 logi aminoaxit, tng sé nhém ~CO-NH- trong 2 phan tit la 5) mol n, n= 1:2. Khi thiy phan hoan toan m gam M thu duige 12 gam glixin va 5,34 gam alanin, m 6 gi tri: A.14,46 g B. 110,28 g C. 16,548 g D, 15,86 i Huéng dan: Phuong phap gop chudi peptit X,Y, X+¥+Y—3X_ Y+2H,0 aon ‘Thay phan hén hgp M cing nhu thay phin (#+2H,0) Ney = 0516 tay = 9116 _ rey 8 06 ty, 3 k=l 1)lmx El = (8+3)k.mx=11k Pate2H,0)+8H,O—>8Gly +3Ala eer 88 3 m=14,46¢ 0,16<— 0,16 Dip in A ED Hon hop E gdm 3 peptit X, ¥, Z c6 tie mol tuong ting la 2:3:4. Téng 86 lien két peptit trong X, Y, Z nhé hon 8. Thay phan hodn to’n m gam E thu duigc 45 gam Gly 71,2 gam Ala va 117 gam Val. Gié tri cha m la: A. 202,6 (g). B. 227,8 (g). C. 206,2 (g). D, 211,6 (g). 1 Huéng dan: Phuong phép gop chudi peptit X, ¥, Z: 2X +3¥ +4Z—>2X -3Y-42 +8H,0 ‘Thay phén hin hgp E cing nhu thay phan (M+8,,0) Tyg =1 % BP May My May, =1:0,8:0.6=10:8:6=24.K.mn.x = k=1=324mx |(M +8.H,0)+15.H,0—+6Gly +8Ala +10Val = m, = 206;2g 1,5 0,6 0,8 1 Dap inc [XEDED Hon hop A gém ba peptit mach hé X, Y, Z cé tilé mol tuong ting 2: 3: 4. Thity phan hoan toan m gam A thu duige sin phém gm 21,75 gam glyxin va 16,02 gam alanin, Biét téng s6 lién kkét peptit trong phan tit cia ba peptit trong A nhé hon 17, Gia tri cfia m la ‘A.31,29 gam. B. 30,57 gam, . 30,21 gam, D.30,93 gam 1 Huéng dan: Phuong phap gop chudi peptit X, Y, Z: 2X +3Y +42 —2X -3¥ -47 +811,0 ‘Thiyy phan hén hop A cing nhu thuy phan (M +8.17,0) ' My 20,29 May _ 29 18 Re = 47k k=1947.mx 5 H,O—29Gly + 18Al (4 +8.,0)+38.1,0—9 296) +18Alal 39 on 0,380, 29 —0,18 Dap én D [XETED Hn hop X gdm 3 peptit vdi tile s6 mol la 1:2:1. Khi thiy phan hoan toan m gam X thu ip X gm 3 pept yy pl 8 duigc chi thu duige 13,5 gam glixin va 7,12 gam alanin. Gié trj cha m lA A. 17,38 gam, B. 16,30 gam. C. 19,18 gam. D. 18,46 gam,Mega book 1 Hudng din: Phuong phap gp chu6i peptit X, ¥, Z 1X +2¥+1Z—3X-2Y-Z+3H,0 X= 2Y-Z ‘Thay phn hn hgp X cfing nhu thy phan (-+8.61,0) ie FOB Boy 9 oy 136 ng, =0,08 ty, 4 k=1=>13mr ae H,0)+ ume oe 0,18 0,18 0,8 Dap an A [XETED Thiy phan hoan toan m gam hén hop A gém peptit X va peptit ¥ (duige trn theo tile ‘mol 4:1) thu duigc 30 gam glyxin; 71,2 gam alanin va 70,2 gam valin. Biét téng s6 lién két peptit 6 trong 2 phan tit X va Y 1a 7. Gid tri nh nbat cia m 06 thé la: A. 146.8. B.145. C.151,6 D. 148, @ Huéng dan: Phuong php gop chudi peptit X, 4X +¥ —>4X-Y¥+4H,0 ee ‘Thay phan hén hgp A cing nbu thity phan (M +4.H,0) My = 0,6 8 May My !oy = 0,6:0,8:0.4= 18:4 18k k=1= 18x (M +4.H, 13.H,O- Gly +8Al (M+4.H,0)+13HO—>AGly+8Ala+ OVal| age. Dip an D 1,3<-——0,4 [XECED Hidn hop G gém peptit X va peptit Y (ti 1g 6 mol 1:3). X va Y cfu tao tit | ogi aminoaxit, tng s6 nhom -CO-NH- trong 2 phan tit X va ¥ la 5. Khi thy phan hoan toan m gam G thu duige 81 gam glyxin va 42,72 gam alanin. Gid tri cita m 1a ‘A. 104,28 gam. B. 109,5 gam. C. 116,28 gam. D. 110,28 gam. mt Huéng dan: Phuong phép gop chudi peptit X, ¥: LX +3Y —>L¥ —3¥ +3H,0 ‘Thay phan hén hop G cing nhu thay phan (M +3.H1,0) ie +3.H,0)+9.H,0—9Gly + 4Ala =m, =104,28¢ 1,08 ——1, 08 . Dap an. AKim cuong dugc cau tao tir nguyén to carbon vai cu tric tinh thé lap phuong bén ving, c6 do céng cyc cao va dan nhiét kha tot. Trong cong nghiép ngudi ta ding kim cuong dé lam cdc loai dao cat va danh bong cc loai kim loai. Bac biét, kim cuong dugc str dung nhu mot mon dé trang sic va da dugc con ngudi khai thac tir rat lau trong ty nhién.Phuong phép nay cfin xéc dinh tng s6 mol cita cfc aa. * Bign lugn tinh sé mol peptit dy’ vao téng céc géc aa la tich mot sé nguyén 16 Hén hgp T gém ba peptit mach ha X, Y, Z c6 ty 1é mol tong ting 18 2:3:3. Thy phan hoan toan 48,53 gam T trong NaOH (vita di) thu dutgc 0,67 mol hin hop 3 mudi cita Gly, Ala va Val. Biét tng s6 mat xich c6 trong X, Y, Zl 20, NEu dét chy hodn toan 48,53 gam T thi s6 mol CO, thu duige li A. 1,88 (mol) B. 1,68 (mol) C.2,01 (mol) D. 1,95 (mol) Hung dan: i 2a ‘Ta 06: ny, = 0,67 —>4 Y :3a —>a(2n,+3n,+5n,) =0,67 Z:5a 2 Sn.) =0,67—>2n,+3n,+5n, = 057 67k a a,+n,+n,=20 k=i ja=0,01 [C,Ha.4NO:0,67 pons H,0:10a=0,1 —n, +3n; -om-0— as. neo, = 0,67425 = 1,95 (mot) * 7 Dap anD [XETED x. ¥, 218 ba peptit déu mech hd va M, < M, < M,, Dét chéy a mol X hode a mol ¥ hay a mol Z déu thay s6 mol CO, In hon s6 mol H,0 la 1,5a mol. Thay phan hodn ton 56,22 gam hén hgp E chita x mol X, y mol Y vay mol Z trong KOH thu duge 103,38 gam hén hop mudi cia Gly va Ala. Biét 4x - 9y = 0,38. $6 nguyén tit H cé trong Z cé thé l&: A.3l B.23 c.29 D.27 mt Huéng dan: k GVA to, - yo =AE=D (Wi Kl s6 mat xich) VGi bai todn nay: L5a=a—)—oke=5 (C,H,,..NO:5x+10y H,O:x+2y + 103,38 - 56,22 = 56.5(x + 2y)-18(K+2y) Ta dén E vé: sof PTis x +2y=0,18(mol) —} x = 0,14 y=0,02 I Goi [SY 2— —X: Gly, :0,14 Ala:b = 15 Y :Gly,Ala, Y :Gly,Ala:0,02 Z:GlyAla, :0,02 ‘Ala, :0,02 [XETED Hon hop T gém ba peptit mach hé X, Y, Z cd ty 1é mol tuidng ting la 2: 3: 3. Thay phan hoan toan 38,63 gam T trong NaOH (vita dii) thu dugc 0,57 mol hén hop 2 mu6i cia hai aminoaxit no, cé mot nhém - COOH va mot nhém ~ NH, cé tdng khdi lugng f& m gam. Biét téng s6 lién két peptit trong X, Y, Z la 14, Gid tri cla m la: A. 59,63 (g) B. 48,32 (g) €.5281 (g) D. 56,46 (g) “im Huéng dan: X:2a Ta c6: ny, =0,57—94 ¥:3a—a(2n,+3n,+5n,) = 0,57 Z:8a pao 5n,)=0,57 —32n, +3n,+5n, = 22 19k nytn,tn,=17 =3 (CHy_.NO:0,57 of ‘Hlay-.NO:0,5 eae ied H,0:10a=0,1 EEL m= 38,63 -0,1.18+0,57.40 = 59,63 (gam). Dép én A ED x, ¥, Z la ba peptit déu mach hi va M, > M, > M,, Dét chay 0,16 mol peptit X hoac 0,16 mol peptit Y cing nhu 0,16 mol peptit Z déu thu dude CO, c6 sé mol nhiéu hon sé mol cla H,O a 0,16 mol. Néu dun néng 69,8 gam hén hop E chia X, ¥ va 0,16 mol Z (s6 mol cia X nhé hon s6 mol cita Y) vdi dung dich NaOH vita di, thu duge dung dich chi chia 2 mudi cia alanin va valin c6 téng khéi lvong 101,04 gam. Phén trim khéi ligng cita Y c6 trong hén hop E gin véi gia tri nao nhat: A. 12% BL 25% C.37% D.19% ® Huéng dan: DEY voi peptit dugc tgo boi Gly va céc déng ding nat ee ka H,O:a Véi bai toan nay: 0,16 =0, o£) — sk =4 ne =G-) (v6i ka 86 mat xich)cas C,H, ,NO:4x + 4y +0,64 H,O:x+y+016 EEL 5101,04-69,8 = 40(4x-+ dy +0,64)-18(x+ y+ 0,16) Ta dén E vé: wat x4 y= 0,06 m0) — = 76 la+b=0,88 Ala:a + =0,76 Hehe oe ee —Z: Ala, :0,16 ee fecacom2s fice ViM, > M, va s6 mol cita X nh hon s6 mol cita Y IX: Val, :0,02 _ 004.330 fe Val Ala, 0,04 > *VelAls "Gag Hén hop T g6m ba peptit mach hé X, ¥, Z cé ty 1¢ mol tuong ting 1a 1:5:2. Thay phan hoan toan 36,564 gam T thu duigc hon hgp sin phdm gém 0,372 mol A gam va 0,192 mol B. Biét tng s6 lién két peptit trong X, Y, Za 14. A va B thudc day déng dang cita Gly. Phin tram Kh6i hugng cia oxi cé trong T gin nhit: 100% =18,91%- Dap 4n D A.25% B.32% C.28% D.22% mt Huéng din: Xia ra og, fit =0372 nes fcem fn eee Z:2a {i 5n,+2n,) =0,564—on,+5ny+2n, = 2594 = 47k —. a a,tn,+n, =17 [C,H,, NO :0,564 k=1 { sssoale 0,096 ja =0,012 (mol) 50 = 10,0964 0,564) _ 98 904 36,564 ED Hin hop T gém ba peptit mach hé X, ¥, Z c6 tf 1é mol tuong ting la 2: 3: 4. Thy phan hot toan 35,97 gam T thu dugc hén hgp sin phém gém 0,29 mol A gam va 0,18 mol B. Biét t6ng s6 lién két peptit trong X, Y, Za 16, A va B thudc day déng dang cia Gly. Néu dét chay 4x mol X hoc 3x mol ¥ thi s6 mol CO, thu duge li nhu nhau, Dét chay hodn toan m gam hén hgp T thu duge N,, 0,74 mol CO, via mol H,O. Gié trj cia a gén nhat véiz A.0,65 B.0,67 €.0,69 D. @ Huéng dan: Ls Tacé: { eae 3n,+4n, = 27 247k a ny+n+n, =19= 20,47 af 935,97] CoBlnsNO2047_ gpa =0,01 (mol) H,0:0,11 0,74 v =0,74 t= 9% 2,5 ee 0,47.3,0942 2.3,0942 92 =0,509(0,11 + 0,47) = 0,676 (mol), Bap an B Hén hop M gém hai peptit X va Y cé tng s6 mat xich trong 2 phan tit la 13 vdi tilé mol ‘Thy phan hoan toan m gam M thu duige 24,3 gam Gly, 3,204 gam Ala va 21,06 gam ‘Val. Gié tr] nhé nbét cia m la: A.40,14 (g). B.42,46 (g). C. 38,24 (g). D.36,93 (g). | Huéng dan; a Tack: In ee 054 «34 062 $y ya +n, =13 ln, =1,n, =2 —]n, =8,n, =5 Dap ana =5,n, =8—>m,,, = 40,14 (g)- X, ¥, Za ba peptit déu mach hd, c6 téng sé Lién két peptit la 8. Dot chdy hoan toan x mol X hod y mol ¥ ciing nhui z mol Z véi lugng oxi du, déu thu dugc 0,64 mol CO,. Dun néng 55,12 gam hén hop E chia X, ¥, Z v6i s6 mol tuiong ting la x, y,z-v6i NaOH thu duigc dung dich chita hai mu6i cia Gly va Ala, trong d6 Kh6i ligng ciia mudi Gly a 46,56 gam. Biét ring y > 2 va 3x = 4(y+2). Phan trim kh6i lugng cia Z trong hén hop Ela: A. 26,4% B. 32,3% C, 28,6% D.30,19% @ Huéng dan: nt =0,48 Ta dén Evé: Gly,Ala, : (mol) —+}(2n-+3m)t=0,643 - —>t=0,28 [(S7n+7im) t+ 18t= 55,12 16—+X:Gly-Gly fea { 3x =4(y+2) y+2=0,12 a=3 Yoy b=6 2:2 =0,08 7 ay+bz=0,48 Pe 2=0,04 X:Gly-Gly:0,16 —}Y:GlyAl, 0,08 —+%Gly, Ala, =30,19%. Dap an D Z:Gly,Ala, :0,04ech’ tile mol ny Thiy phan hoan toan m gam M thu duige 22,5 gam glixin vi 3,204 gam alanin, Gid tri cia m: [XETED Hon hop M gém hai peptit X va Y c6 téng s6 nhém -CO-NH- trong 2 phan tit la 6 voi A. 26,462 (g). B. 15,562 (g). C. 19,316 (g). D. 20,952 (g). 1 Huéng din: Tacé: fr: a(n,+5n,)=0,336—on,+ Sn = 2996 = 7 Day +n, =8 k=4 0=0,012 goa — m= 22,543,204 —0,012.2.18~0,06.4.18 = 20,952(gam) Dap an D X, ¥, Z la ba peptit mach hd, duc tao tit Gly, Ala hode Val (Biét M, > M,). Khi d6t chéy 1 > M). Ki : X, Y v6i s6 mol bang nhau thi déu thu dugc lugng CO, !& nhut nhau, Dun néng 50,88 gam hén hop M gm X, ¥, Z véi tilé mol tuiang ting la 4 trong dung dich NaOH, thu duige dung dich T chi chia 3 mudi v6i s6 mol la 0,06; 0,225; 0,375. Biét tng s6 mat xich cia X, Y, Z bing 12. Phan trim khdi lugng cita ¥ trong M gan nhdt voi: A.20% B, 25% C.30% D. 35% 1 Huéng dan: Xda Ta C6: Mya, =0666—>4 Y -4a-—.a4n,44n, +3n,)=0,66 Z:3a ee = 966 ink —. nyén+n, =12 —a=0,015 k=4 Sn, = 48-11 ° etna oss Gly:0,375 sof algal BEL = 3,11364—>) Ala: 0,06 Val 0,225 (XY), :0,06 (Ala~ Val, ~ Gly.) :0,06 — — Z,:0,045 ‘Val ~ Gly - Gly - Gly 0,045 Gly, ~ Val-0,06 ‘ 3} Ala - Val—Val 0,06 iy = 206287 50,88 ‘Val - Gly -Gly-Gly 0,045 Dap nD =33,84%[XEDEDD x. ¥, Z la ba peptit mach hé, dugc tao tii Gly, Ala hoc Val. Khi d6t chay X, Y véi sé mol bing nhau thi déu thu duigc ligng CO, la nhu nhau. Dun néng 37,72 gam hén hop M g6m X, Y, Z véi ti lé mol tuong ting 1a 5:5: 1 trong dung dich NaOH, thu duge dung dich T chi chita 0,35 mol muéi A va 0,11 mudi B (M, < M,). Biét t6ng s6 mat xich cita X, ¥, Z bang 14. Phan trim kh6i lugng cia Z. trong M gin nhét vi: A. 1495 B.8% C.12% D,18% ™ Huéng dan: X58 Ta cb: Danser 0,46—9] ¥ :Sa——a(5n,+5n,+n,)= Za a(Sn,+5n,+n,)=0,46—95n,+5n,+ n, = = 23x ey . ny+n,+n, =14 k=2 ——4n, = 70 - 23k — at Ala:0,35 Val :0,11 £aé; : Val- Ala, :0,05 ‘Ta cé thé dén hén hop M thanh. i :0,01 (loai) gene a Val— Ala, :0,05 {yee af “on Nal Als 20,05 Val Ala, :0,01 337,72: C.BayaNO O46 ores 9 23,4783. H,0:0,01.11 472.0,01 37,72 z= 2,51% Dap nC X, ¥, Za ba peptit mach hd, duigc tgo tit cc a-aminoaxit thudc day déng ding cia glyxin, Khi d6t chay X, Y v6i s6 mol bing nhau thi déu thu duigc ligng CO, J& nh nhau. Dun néng 31,12 gam hén hop M gém X, Y, Z v6i til mol tuong ting la 4:4:1 trong dung dich NaOH, thu ] ¥:a —sa(n, +n,+3n,) = 0,525 23a fireneieo-9m arn 2058 aa a nytn,tn, =21 [C,H,, 1NO0,525 a=0,015 2, =1h-21 1 9.0:0,075 PPS_51,575=0,525n—n=3 m= 0,525(14.3 + 29) + 0,075.18 = 38,625 Dp an C ealHON HOP PEPTIT VA ESTE ‘Hén hop E gém peptit X mach hé (cu tao tit Gly, Ala) va este Y (duc tao ra tii phan ting este héa gitia axit cacboxylicno don chitc va metanol), Dét chay hodn toan m gam E can 15,68 lit ©, (dktc). Mgt khdc thity phan m gam B trong dung dich NaOH vita di thu duge 24,2 gam hén hop muéi (trong dé s6 mol mudi natri cia Gly én hén s6 mol mudi natri cia Ala). Dot chay hoan toan khéi lvgng muéi trén cn 20 gam O, thu duige HO, Na,CO,, N, va 18,7 gam CO, THe s6 mol Gly: Ala trong X la (O=16, Na=23, 0=16, H=1, C=12) ALB Bill C13 D.12 1m Huéng din (C,H,,NO,Na C,.Hyp.;0,Na Idan + 54a+15b = 24,2 C,H; 0,Na:a 24,2 gam: 24,2 gam: 4 NH:b 'Na,CO, :0,5a 24.2am:f aires ons, ]CO, :an-0,5a NH:b H,O:an~0,5a+0,5b N, an~0,5a=0,425 HL 2a +:0,625.2 = 0,425.2+ 0,425 + 0,5b+0,5a.3 (0,5a-0, 5b =0,025 ,425 Ian+S4a+15b=24,2 [b= an-0,5a= (C,H;,NO,Na :0,2 C,Hey.-10,Na :0,05 20n+5m=5$= 4n+m=11 m=! __ [C,H,NO, :0,1 = n=2,5 : m=2 C,HJNO, #015 Gly_3 ares n=2,25 |C\H,NO,:0,05 Ala 1 24,2 gam | Jsoansosm- , Dap an A Hén hgp T gém hexapeptit X mach hé (cdu tao ti Gly, Ala, Val) va este Y(duge tgo ra tt. axit cacboxylic no, don chifc va etanol). Thuy phan m gam E trong dung dich NaOH vita dit thu dugc 32,4 gam hén hop mudi, ét chay hoan toan kh6i luong muéi trén cén 1,11 mol O, thu duge HO, Na,CO,,N, vi 33,0 gam CO,. Gid tri cia m Li: A, 26,68 B,22,82 €. 23,88 D.25,28Mega book Huéng dan i C,H,,NO, m: 7 BA OH, O,Na I4an+54a+15b ‘Na,CO, :0,5a 3254 gam: [Catz O2NA!4 oan, }CO, s0t1-0,5a NH:b H,O:an -0,5a +0,5b N. an-0,5a=0,75 B25 2a 111.2 0,5a—0,5b = 0,03 an-0,5a=0,75 > Idan +54a+15b=32,4 ,75.2+0,75 +0,5b+0,5a.3 Bao toan khéi lutgng ta o6 m+0,3.40 = 32,4 + 0,06.46 +0, 04.18 = m= 23,88g 0,24 Dy y= yo Fe = 004ml Mhenapet = Dap an CTritium Tritium trong tu nhién cuc ky hiém trén Trai dat, chi dugc tao thanh 6 dang vét khi cac bite xa va try tuong tac voi khi quyén. La mét déng vi phong xa cua hydro, Tritium duoc sl dung rong rai trong cac ting dyng nhu chiéu sang khan cdp cia déng hé deo tay sit dung vao ban dém hay danh cho the lan; dau higu “thoat hiém’ ty phat sang dat trong nha hat trudng hoc va cac toa nha van phong. Gia thanh cua loai vat chat nay 30.000 USD/g (khoang 636 trigu VND).Néu peptit c6 chéa Glu quy 46i thanh (C,H,,.NO coo —. ie Ae HO Deoo = Dymo — Mx ‘Néu hén hgp chia Lys C,H, .NO NH {ire es H,O Py = Byso — Mcoow Thay phan hoan toan m gam hdn hgp T gém tripeptit X va heptapeptit Y (mach hé, ty 1é mol 1:2) cén vita di 0,48 mol NaOH, sau phan ting thu duige 49,22 gam hén hgp muéi cia Gly, Ala, Val va Glu, Mat khéc, d6t chdy hoan toan m gam X thu duge 1,32 mol khi CO2. Néu thiy phan m gam X bing HCI (ita di) thi dung dich saw phan ting 06 chita 51,07 gam mudi Gié tri cia m La: 4.33.62 B.31,18 C.36,24 D.34,16 1 Huéng dan: Xéc dinh mol HCl suy ra mol nite 49,220, 48.22 + 36,5x = 51,07 = x = 0,34mol ny = 0,34 mol =a3+2a.7 = a= 0,02 Chi ¥ nh6m COOH trong Glu vin chuyén thanh nhom COONa Nén ta 66 Myufi=M+NEFoy.22 Un tin tang gidm khéi lugng kh6ng ap dung bao toan khéi lugng duigc vi khéng xac dinh duige mol nude. Qui déi T thanh C,H, .NO:0,34 COO; 0,48-0,34= 0,14 mol = 0,34n+0,14=1,32 > 0 00,06 mol m= 04 2+29), 0,34+0,14.44+0,06.18 = 33,62 ¢ Dap an AE la hén hgp chtia 3 peptit A, B, C dugc tao bai Gly, Ala, Val va Lys. Thay phan m gam peptit E trong NaOH thi thay s6 mol NaOH phan ting la 0,69 mol, Sau phan ving thu duige 93,74 gam mudi khan. Mat khdc, thity phn m gam E trong HCl (vita di) thi thu duge 111,41 gam muéi khan. D6t chay ho’n toan higng pepit trén thu duigc téng khéi lugng cia CO, va HO la 187,64 gam. Biét s6 mol E ting v6i m gam [a 0,09 mol. Gid tr} ciia m Ja: A.67,76 B. 65,56 78,87 D.78,78 Hung din: (C,H), NO :0,69 mol NH H,0 Tinh mol HCL 93,74-0,69.22+36,5x=111,41 = x=0,9mol JH, ,NO :0, 65 oh CHa eae ie :0,69n NH:0,9-0,69= 0,21 mol—%->187, 64. ft H,0:0,69n-0,15 [1,0 :0,09 mol _307 n=, m= 67,768 -Dép an A BAIA REN LUYEN Oligopeptit mach hd X duigc tao nén tit cdc a-amino axit déu cé cong thttc dang H.NC,H,COOH. Dét chay hoan toan 0,05 mol X cén ding vita dit 1,875 mol O,, chi thu dige N; 1,5 mol CO, vi 1,3 mol H,O. Mat khéc, thiy phan hoan toan 0,025 mol X bing 300 ml dung dich NaOH 1M va dun néng, thu dutgc dung dich Y, C6 can céin thn toan bé dung dich Y thu duigc m gam chat rn khan, S6 lign két peptit trong X va gid tri cha m lan ligt 1a A.9'va 29,75, B, 10 va 33,75. . 10 va 29,75, D.9va 33,75. [XEZED Thiy phan hoan toin 8,68 g tripeptit mach hé X (duigc tao nén tit a-amino axit cé cing céng thitc dang H,NC,H,COOH) bing dung dich NaOH du thu duge 12,76 g muéi. Mat khéc thiy phén hoan toan 4,34 g chat X bing dung dich HCI du thu duge m (g) mudi, Gia tri cia m la: A725 B.6,53 5,06 Dz 8,25 Hén hgp X gém 1s6 amino axit no, mach hé (chi c6 nhém chit -COOH, -NH,) 6 ti lé Kh6i lugng m,: m,, = 48: 19. Dé téc dung vita dit v6i 39,9 g hn hop X cn 380ml HCl 1M. Mat hdc dét chy 39,9 g hén hop X cdn 41,776 lit O, (dktc) thu duige m (g) CO,, m o6 gid tri I&: A.61,60g B.59,84g C.63,36 g D. 66g Hén hgp A chtia 2 peptit X, Y (co sé lign két peptit hon kém nhau 1 lién két). Dét chay hoan toan 10,74g A cén ding 11,088 lit O,(dktc), dn sin phim chdy vio binh dying nude voi trong dut. Khéi lugng binh ting lén 24,64 g, Mat khac dun néng 0,03 mol A cén dit 70 ml NaOH 1M thu dugc hén hgp gém 3 muéi cia Gly, Ala, Val trong 46 mudi cha Gly chiém 38,14% vé khi lugng, Phin trim khéi ligng mudi cia Val trong Z gan voi: A, 20,0% B.25,3% C.24,3% D.31,4% 2 |aa Cho 0,35 mol hén hgp T gém hai peptit mach hé la X (x mol) va ¥ (y mol), déu tao béi ¢glyxin va alanin, Dun néng 0,35 mol 'T trong hong dui dung dich NaOH thi c6 1,9 mol NaOH phan ting va thu duige dung dich chita m gam muéi. Mat khéc, néu dt chy hoan toan x mol X hoc y mol ¥ thi déu thu dugc cling s6 mol CO, Biét tng s6 nguyén tit oxi trong hai phan ta Xva Y la 13, trong X va ¥ déu c6 s6 lién két peptit khong nhé hon 4. Gia tri cla m la A. 1983 B. 1704 C2944 D,396,6 Hén hgp X gém tripeptit A va tetrapeptit B déu duidc cu tao béi glyxin va alanin. Thanh phén phan trim khéi luong nite trong A va B theo thtt ty 18 19,36% va 19,44%. Thy phan hoan 0,1 mol hén hgp X bang mot ligng dung dich NaOH vita dit, thu duge dung dich Y. C6 ‘can dung dich ¥ thu dude 36,34 gam hén hop mudi. T1é mol gitia A va B trong hén hop X la A.37. B. 3:2. C73. D.233, Hén hop X gém cdc aminoaxit no, mach hé (trong phan tit chi cé nhém chtte -COOH va -NH,) ¢6 t1@ mol ng: n= 2:1. Dé tc dung vita di véi 35,85 gam hn hop X cén 300 ml dung dich HCI 1,5M. Dét chdy hoan toan 11,95 gam hén hgp X edn vita dit 9,24 lit khi O, (dktc), Dan toan bé sin pham chay vio dung dich Ca(OH), du, thu dugc m gam két tha, Gid tricia m la A. 25,00, B. 33,00. C.20,00. D. 35,00, [XETED Cho hin hop X gém hai peptit Y va Z déu mach hé chi tao thanh tit Gly va Ala. Cho m gam hén hgp X tac dung vila di véi 0,1 mol NaOH trong dung dich thu dugc (m + 3,46) gam hén hop muéi. Biét phan trim cia oxi trong hén hgp X 1a 30,59%. Gid tri cia m la A816 g B.6,80 g C7548 D.7,08 g [XETED Dun néng 0,045 mol hén hop A chia hai peptit X, Y (cé s6 lién két peptit hon k m nhau 1 lign két) can vita di 120ml KOH 1M, thu duige hén hgp Z chita 3 mudi cia ly, Ala, al trong dé muéi cia ly chiém 33,832 vé khéi higng. Mat khéc, dét chay hoan toan 13,68 gam A cén ding 14,364 Ift_khi O, (dtc) thu duoc hon hop khi va hoi trong dé téng khéi lugng cia CO, va HO la 31,68 gam, Phan tram kh6i lugng muéi cia Ala trong Z gn nhét vdi: A.50% B.55% C.45% D.60% Hén hop X gém cdc peptit mach hé, déu duige tao thanh ti cdc amino axit cé dang HNC, HCOOH. Dun néng 4,63 gam X vi dung dich KOH dui, thu duigc dung dich chia 8,19 gam mudi, Néu dét chy hoan toan 4,63 gam X cn 4,2 lit O, (dktc). Dan toan bd san pham chdy (CO, H,O, N,) vao dung dich Ba(OH), du, sau phan ting thu duigc m gam két tia va khéi lvgng dung dich gidm 21,87 gam. Gié tri cia m gén gid tri nao nhét sau day? A. 350, B. 300. C.325. D.275. Khi thiy phan khéng hoan toan mét peptit X (M,, = 293) thu duc hai peptit Y va Z. Biét 0,472 gam Y phan ting vita dit voi 18 ml dung dich HCI 0,222 M dun néng va 0,666 gam Z phan ting vita di: véi 14,7 ml dung dich NaOH 1,6% (d= 1,022 gam/ml) dun néng. Biét ring kkhi thay phén hodn toan X thu dugc hén hgp 3 amino axit lt glyxin, alanin va phenyl alanin, Céng thtic cdu tao cta Xa A. Ala-Phe-Gly. B.Gly-Phe-Ala-Gly, C. Ala-Phe-Gly-Ala. _D, Gly- Ala-Phe.Dun néng 0,4 mol hdn hgp E gém dipeptit X, tripeptit Y va tetrapeptit Z déu mach hd bang lugng vita dt dung djch NaOH, thu dutgc dung dich chifa 0,5 mol musi ciia glyxin va 0,4 mol muéi cia alanin va 0,2 mol mu6i cia valin. Mat khéc dét ch4y m gam E trong O, vita di thu dugc hn hgp CO,, H,O va N,, trong dé t6ng khéi lygng ciia CO, va nuéc 1A 78,28 gam. Gia tri m gin gié tri ndo mbét sau day? A.50 B.40 C45 D.35 Hn hop X gém mot 36 amino axit (chi chtfa nhém chifc -COOH va -NH, trong phan tit), trong dé ti lé m4: m, = 16:7. Dé téc dung vita di véi 10,36 gam hén hgp X can vita ding 120 ml dung dich HCl 1M. Mat khdc cho 10,36 gam hén hgp X tac dung v6i 150 ml dung dich ‘NaOH IM r6i 6 can thu duge m gam rin, Gid tri cham 18 A.14,20. B. 16,36. C.14,56. D. 13,84. ‘Thity phan m gam hén hgp X gém mot tetrapeptit A va mot pentapeptit B bang dung dich NaOH vita dit 16i cd can thu duigc (m + 23,7) gam hén hgp muéi cia Glyxin va Alanin, Dét chéy toan bé Iktong mudi sinh ra bang mot ligng oxi vita dui thu duigc Na,CO, va hén hgp hoi Y g6m CO,, H,0 va N,, Dn toan bd hén hop hoi ¥ di rat cham qua binh dung dung dich NaOH dic dit thy khéi higng binh ting 84,06 gam va c6 7,392 lit mot khi duy nhat (dktc) thodt ra khéi binb. Thinh phin phén trim khdi lugng cba A trong hén hgp X la A.53,06% B.35,37%, €.30,95%, D.55,92%. (XELED dun néng 0,14 mol hén hop A gém hai peptit X (CH,O.N,) va ¥ (C,H, O,N) véi dung dich NaOH vita dit chi thu dugc dung dich chita 0,28 mol mudi cla glyxin va 0,4mol mudi cia alanin, Mat khéc dét chy m gam A trong O, vta di thu duigc hén hop CO, H,0-vaN, trong 446 tng kh6i lugng cia CO, va nuiéc a 63,312 gam. Gi tri m gin nt la: Ad B.28 C32 D.18 H6n hop X gém 3 peptit déu mach hé c6 ti 1 mol tuong ting la 1:1:3. Thay phan hoan toan m gam X, thu duge hén hgp sin phém g6m 6,23 gam alanin; 6,00 gam glyxin va 9,36 gam valin. Biét t6ng s6 lién két peptit trong phan tii cia ba peptit trong X Ién hon 8. Gié trj cha m Ia A, 18,89 B. 18,80 C. 18,35 D, 19,07 Hén hop M gém mét peptit mach hé X va mét peptit mach hé Y voi ti lé s6 mol n,n, 3. Khi thily phan hodn toan m gam M chi thu duige 81,0 gam glyxin va 42,72 gam alanin, Biét ring mi peptit X, Y chi dugc edu tgo tit mét logi a-aminoaxit duy nhat va téng s6 lign két peptit -CO-NH- trong 2 phan tw X, ¥ la 5. Gid trj ca m la A. 104,28. B, 110,28, C. 116,28. D, 109,5. [EDEL Hon hop X gm céc chat Y (C,H,,N,O,) va chit 2 (C,H,N,O,)s trong dé Y la mudi cia axit da chit, z la dipeptit mach hé, Cho 28,08 gam X tac dung véi dung dich NaOH du, dun néng, thu duige 0,12 mol hén hgp khi déu lam xanh qu tim am. Mat khdc 28,08 gam X tac dung véi dung dich HC1 du thu duge m gam chat hau co. Gié tri cia m li: A. 37,65 B.39,15 C. 38,85 D.42,9 >]3) Mega book Dét chay mot higng peptit X dug tao béi tl mot loai a-aminoaxit no chifa 1 nhém - NH, va I nhém~COOH cfn ding 0,675 mol O,, thu dugc N,; H,O vi 0,5 mol CO, Dun néng m gam hén hgp E chita 3 peptit X, ¥, Z déu mach hé 06 ti 1é mol tuiong ting 1:4:2 véi 450 mi dung dich NaOH 1M (vita dii), c6 can dung dich sau phan ting thu dugc 48,27 gam hén hop chi chtfa 2 mu6i, Biét t6ng s6 lién két peptit trong E 1A 16. Gid tr) ma ‘A. 30,63 gam B. 31,53 gam C.32,12 gam D. 36,03 gam [XETEID Dun nong 0,15 mol hén hop X gém hai peptit mach hé (déu tgo boi glyxin vA axit P glutamic) véi 850 ml dung dich KOH 1M (vtia ei). Két thiic cfc phan ting, c6 can dung dich thu ditge 95,15 gam mudi khan, Khéi luigng cia 0,1 mol X Ia A. 35,3 gam, B.31,7 gam. C.37,1 gam. D. 33,5 gam [XETEID ‘Thiy phan hoan toan 0,1 mol mot peptit X duige cA tao béi glyxin va alanin bing dung dich NaOH r6i cé can thu duge 57,6 gam chit rin, Biét s6 mol NaOH da diing gp doi so voi uigng edn thiét, C6 bao nhigu céng thiic céu tgo théa man X? AG. BA C8. D.10. ‘Thiy phan hoan toan m gam hén hgp gém peptit X va peptit ¥ bang dung dich NaOH thu dugc 151,2 gam hén hop gém cdc mudi natri cita Gly, Ala va Val. Mat khac, dé dt chéy hoan toan m gam hén hgp X, Y 6 trén cn 107,52 lit khi O, (dktc) va thu duge 64,8 gam H,0. Gid ui cham a A.107,8. B.97,0. C925. D,102,4. Hén hgp A gém dipeptit mach hd X (cé cong thifc phan tit la C,H,N,O,) va mét mudi Y (cé céng thite phan tit]& CH,N,O,). Cho 0,5 mol A phan ting vita du véi dung dich NaOH dun néng, thu duge dung dich Z chta m gam mudi va 4,48 lit Kh{ T (dktc, lam xanh quy tim 4m). Gia tri cia m gin nhit véi gid tri ndo sau day? AL7754. B.75,55. C. 88,10. D.80,23. Peptit X va peptit Y déu mach hé cé téng s6 lién két peptit bang 8. Thay phan hoan toan X ciing nhu Y déu thu duge Gly va Val. Dét chay hoan toan hén hgp E chtfa X va ¥ 06 tile mol tuiong ting 1:3 cin ding 22,176 lit O, (dktc). Dan toan b6 sin phém chdy gm CO,, H,O va N, qua binh dung dung dich Ca(OH), dut thay khéi lvgng binh ting 46,48 gam, khi thoat ra khdi binh cé thé tich 2,464 lit (dktc), Phan trim kh6i lugng cita X trong hén hgp E cé gid tr gin nhat voi AL 14, B.29. C.19. D. 24. ‘X la tetrapeptit Ala-gly-val-ala, Y la tripeptitVal-gly-val. Dun néng m gam hén hop chita X, Y cé ty mol cia X va Y twong ting 18 1:3 véi dung dich NaOH vita di. Phin ting hodn toan thu duigc dung dich T. Cé can cén thin dung dich T thu dutge 23,745 gam chat rin khan. Gié tri ctia mii: A.17,025 B.68,1 €.19,455 D784 22 1]EID Cho 0,3 mol hin hgp axitglutamic va glyxin vao dung dich 400 ml HCI 1M thu duc dung dich Y. Y tac dung vita dé 800 ml dung dich NaOH 1M thu duoc dung Z. Lam bay hoi Z thu diigc m (g) rin khan? A.61,9 gam B.55,2 gam €.31,8 gam D. 28,8 gam Thay phan hoan toan m gam hén hgp hai peptit X va Y bang dung dich NaOH vita dit thu duige 9,02 gam hén hgp cic mudi natri ciia gly, ala va Val. Mat khéc, néu d6t chy hoan toan m gam hén hgp trén thu thi cn hét 7,056 lit khi O, (dktc) thu duge 4,32 gam nudc. Gid tri m 1 A636 gam BA,56 gam 7,86 gam D9,16 gam Hén hop T gém tetrapeptit X va pentapeptit ¥ (déu mach hé, tao béi glyxin va alanin). Dun néng m gam T trong dung dich NaOH vita di thu dugc (m + 11,85) gam mu6i Z. Dt chéy hoan toan Z thu dutge Na,CO, va hén hgp Q gém CO,, H,O,N,. Dan toan bé Q vio binh duing dung dich nutéc voi trong dut thay kh6i lugng binh ting 42,03 (gam) va con Iai 3,696 lit (dktc) mt Ichi duy nhat, Phan trim khéi lugng ciia X trong T gan nhit véi gid tr] nio sau day? A.54 B52 C55 D.53 Ela hén hop gém 3 peptit X, Y, Z. Thay phan hoan toan 18,6 gam E can vita dit 225 ml dung dich KOH 1M. Cé can can than dung dich sau phan tng thu duge m gam hén hgp M g6m 3 mudi kali cla Gly, Ala , Lys véi s6 mol tuong ting la x, ¥,z. Néu dot chay hoan toan mot ugng E thay s6 mol CO, va nuiéc thu duge la nhu nhau, Mat khéc, néu dét chéy hoan toin hin hop gm a mol muéi kali cia Gly va b mol mu6i kali ciia Ala (a,y =b.x) duigc 99 gam CO, va 49,5 gam nude, Phan trim khéi lugng mudi cia Ala trong M gan nhat véi gid tri nio sau diy A.70. B48 C64 D.32. [XETEDD £ 1a hén hop chtia 3 peptit A, B, C duigc tao béi Gly, Ala, Val va Lys. Dét chay hoan toan 0,18 mol hén hgp E san phim chay thu duige o6 chuita 21,056 lit khi N,, 142,912 lit khi CO, (cdc Khi do 6 dtc), Mat khdc, thay phn wong E trén bing dung dich chita KOH du thi thu duige 216,92 gam mudi. Khdi lugng E tuong ting véi 0,18 mol 13: A. 146,28 B. 140,64 C. 138,44 D. 152,82 EID Dun néng 0,14 mol hin hop X gém hai peptit Y (C.HON,) va Z (C,H,O,N)) véi dung dich NaOH vita dit chi thu duge dung dich chiia 0,28 mol muéi cia glyxin va 0,4 mol muéi cia alanin. Mat khac d6t chay m gam X trong O, vita di thu dugc hn hop CO, H,O vaN,, trong dé t6ng khéi lugng chia CO, va H,O la 63,312 gam. Gia tri cia m gn nhat véi gid tr nto sau day? A.28 B34 C32 D.I8 [XETEED x 12 1 pentapeptit cau tao tit 1 amino axit no mach hé cé 1 nhém -COOH va I nhém -NH, (A), A cé téng phan tram khéi lvgng oxi va nito 1 51,685%. Khi thay phan hét m gam X trong mdi trusng axit thu duigc 30,2 gam tetrapeptit; 34,65 gam tripeptit; 28,8 gam dipeptit ‘va 88,11 gam A. m cé gia tri la: A. 195,8 gam B, 167,85 gam C. 156,66 gam D. 164,12 gamLs Thuy phan hoan toan 14,6 gam mét dipeptit X c6 céu tao béi 1 @-amino axit c6 1 nhém. NH, va 1 nhém- COOH bang dung dich NaOH thu sin pham trong dé cé 11,1 gam mot muéi cé chita 20,72% Na vé khéi higng. Thanh phén phan tram vé kh6i lugng ca N trong X la A, 16,96%. B. 14,89%. €.17,5%. D.19,18%. (XETELD Tripeptit X va tetrapeptit Y déu mach hé. Khi thy phan hoan toan hén hgp gém X va Y chi tao ra m6t amino axit duy nhat c6 cong thitc dang H,.NC,H, COOH. Dét chay 0.05 mol Y trong oxi du, thu dugc N, vi 36,3 gam hén hgp gdm CO,, H,O. Dét chy 0,01 mol X trong oxi du, cho san phim chy vio dung dich Ba(OH), du, thu dugc m gam két tia. Biét céc phan ting déu xay ra hoan toan, Gié tri chia ml: A591. B.17,73. C.23,64. D, 11,82. [XEZELD Cho hén hop A chiia hai peptit X va Y tao bai cdc amino axit no mach hé, phan tii chifa L nhém -COOH, I nhém -NH, ,biét ring téng s6 nguyén tit O trong 2 phan ti X, Y Ia 13. Trong Xhofe ¥ déu cé sé lién két peptit khong nhé hon 4. Dun néng 0,7 mol A trong KOH thi thay 3,9 mol KOH phan ting va thu dug m gam musi, Mat khéc dét chayhoan toan 66,075 gam A 16i cho sin phdm hdp thy vao binh chtta Ca(OH), du thay kh6i lugng binh tang 147,825 gam. Gid tri cia ma A. 490,6 B.560,1 C.470,1 D.520,2 Oligopeptit mach hé X duge tao nén ti c4c oF - amino axit déu cé cong thitc dang H.NC,H,COOH. Dét chy hoan toan 0,05 mol X can diing vila di 1,875 mol O,, chi thu duc Nj 1.5 mol CO, va 1,3 mol H,O. Mit khéc, thiiy phan hoan toan 0,025 mol X bang 400 ml dung dich NaOH 1M va dun néng, thu duigc dung dich Y. C6 can cén thén toan bo dung dich Y thu dug m gam chat ran khan. $6 lién két peptit trong X va gid tri cia m lan luot a A. 9 va 33,75, B.9 va 27,75, C. 10 va 33,75. D. 10 va 27,75. Cho hén hop X g6m A (C,H,,O,N,) va B(C,H,,O.N,) téc dung voi mot hiong dung dich Ay NaOH vita da, dun néng dn khi phan ting xdy r2 hodn todn réi cé can thu duigc m gam hén hgp Y gém hai muéi D va E (M,, < M,) va 448 lit (ktc) hén hop Z gdm hai amin no, dan chite dong dang ké tigp 6 ti kh6i hoi d6i voi H, la 18,3. Khoi lugng cia mudi E trong hn hgp ¥ la: A.4.24 gam. B. 3,18 gam. €.5,36 gam, D, 8,04 gam. EED Hn hop X gém valin va dipeptit glyxylalanin. Cho m gam X vio 100 ml dung dich H,SO, 0,5M (loang), thu duge dung dich ¥. Cho toan bo Y phan ting vita dit véi 100 ml dung dich gém NaOH 1M va KOH 1,75M dun néng, thu duge dung dich chia 30,725 gam muéi, Phan trim khdi lugng cia valin trong X li A.65,179. B, 54,588. C.45,412. D, 34,821, [XEDESD Hin hop X gém peptit A mach hd cé céng thifc CH.N,O, va hop chat B cé cong thite phan tia C,H,NO,. Lay 0,09 mol X téc dung vita di véi 0,21 mol NaOH chi thu duge sin phém la dung dich g6m ancol etylic va a mol muéi cia glyxin, b mol mudi cia alanin. Néa 6t chay hoan toan 41,325 gam hén hop X bing lvgng oxi vita di thi thu duge N, va 96,975 gam hén hop CO, va H,O. Gié tri a: b gin nbét véi A.2,60. B.0,76. 1,30. D.0,50, En[XEXZID thiy phan hoan toin m gam hexapetit X mach hé thu dutgc (m + 4,68) gam hén hop Y ‘g6m alanin va valin. Oxi héa hoan toin hon hgp Y cn ding vita dia mol khi O,, thu duge hén hgp Z gém CO,, hoi H,0 vaN,, Dan hén hgp Z qua binh H,SO, dic du, théy khéi lugng hi thoat ra khoi binh giém 18b gam so véi hén hgp Z, tilé a: b = 51: 46. Dé oxi héa hoan toan 27,612 gam X cfn t6i thigu V lit O,(dktc). Gid tri cha VIA A. 33,4152 It B, 30,1392 It, C.29,7024 lit. D. 33,0239 lit Hén hop X gém dipeptit Y, tripeptit Z va tetrapeptit T (déu mach hd) chi duge tgo ra ti Gly, Ala va Val. Dét chdy hoan toan m gam X, réi cho todn bd sin phdm chéy (chi gm CO,, HO vaN,) vio binh dying 150 ml dung dich Ba(OH), 1M, sau Iki cdc phan ting xay ra hoan toan thay c6 1,12 (dktc) mét khi duy nhét thot ra va thu dufge dung dich 6 khéi luigng tang 15,83 gam so vi khéi higng dung dich Ba(OH), ban dau. Gié tri cita m gin véi gia tri nao nat sau day? A.7,38 B.7,85. €.8,05. D,6,66. [XE v6t chay hoan toan 0,1 mol peptit X (X duge tao thanh cic amino axit chi chifa 1 nhém -NH, vi | nhém ~COOH) cfn 58,8 lit O, (dktc) thu duge 2,2 mol CO, va 1,85 mol H,O, Néu cho 0,1 mol X thay phan hoan toin trong 500 ml dung dich NaOH 2M thu duoc dung dich Y¥, c6 can ¥ thu duige m gam chat rin, Cong thiic chung cia peptit va gié tri cia m lén lugt la A.CHON, va 96,9 gam B.CHO,N, va 969 gam C.CHO,N, va 92,9 gam D.C.H,O,N,va 92,9 gam HO, “HON, EED Cho 0,05 mol amino axit X 06 cbng thite H,NC,H,, (COOH), vao 100ml dung dich HCL 1,0M thu duigc dung dich Y. Cho Y tac dung vita dit véi dung dich Z c6 chita déng thdi NaOH 1M va KOH 1M, thi thu duge dung dich T, c6 can T thu duigc 16,3 gam muéi, biét céc phan {ing xay ra hoan toan. Phan trim vé kh6i higng ciia C cé trong phan tii X la? A. 32,65 B. 44,72 €.40,81 D. 36,09 Mét oligopeptit dug tao thanh ti glyxin, alanin, valin. Thiy phan X trong 500ml dung dich H,SO, 1M thi thu duge dung dich Y, c6 can dung dich Y thi tha duge hén hop Z 6 chita céc dipeptit, tripeptit, tetrapeptit, pentapeptit va céc aminoaxit tuong ting, Dét mot nia hén hop Z bang mét lugng khdng Khi vila dit, hap thy sin phdm chay vao binh Ba(OH), du thi thay khéi lugng binh ting 74,225 gam, khdi luong dung dich gidm 161,19 gam d6ng thai thoat ra 139,608 lit khi tro. Cho dung dich Y téc dung hét vai V it dung dich KOH 2M dun néng (ding du 20% so véi lugng cén thiét), c6 can dung dich sau phan ting thi kh6i ltgng chat rn 6 gia tri gin dung la: A184 B. 106 Cll D.198 [XENEED Hon E chita hai peptit X, Y. Ngudi ta thiy phan hoan toan X cling nhu Y déu thu ditge Gly va Val. Bét chy hoan toan m gam E cén 190,008 lit khi O, (dktc). Dn toan bd sin phim chay qua binh duing dung dich Ca(OH), dui thay 6 21,84 lit khi (dktc) thoat ra, Mat khéc, thiy phan hodn toan m gam E trong NaOH (du) thu duge a mol musi cia Gly va b mol mudi cia Val, Ty 18a: b a: A B.&:7. C21 D.1:3.Deas Hén E chita hai peptit X, ¥. Nguidi ta thity phan hoan toan X cing nhu Y déu thu dugc Gly va Val. D6t chy hoan todn m gam E cén 190,008 lit Khi O, (dtc). Dan toan bé sin phém chay qua binh dying dung dich Ca(OH), du thay cé 21,84 lit khi (dktc) thoat ra. Mat khéc, thity phan hoan toan m gam E trong NaOH (dui) thu duge t gam hén hop mui, Gié tri cia tla: A.227,37 B. 242,28, C. 198,84 D, 212,46 Hén E chtta hai peptit X, ¥. Ngudi ta thay phan hoan toan X ciing nhu Y déu thu diige Gly va Val. Dét chay hoan toan m gam E cin 190,008 lit khi O, (dktc), Din toan bé san phém chay qua binh dying dung dich Ca(OH), dut thy kh6i lugng binh ting 400,53 gam va cé 21,84 lit khi (dktc) thodt ra. Gid trj cia m la: 127,37 B. 142,28 C. 156,93 D, 112,46 ([XELZED Peptit X va peptit ¥ cé téng lién két peptit bing 8 va ty 1é mol tuong ting la 1:3. Néu thay phan hodn toan m gam hén hgp chita peptit X va Y thu dugc 6,75 gam Gly va 4,45 gam Ala. Gia tri cia m la: A.9,2 B94 C.96 D.98 HUONG DAN N, 0,05 molX :C,H,O,N, “3251 1,5 mol CO, 13 mol HO. YL 0052+1,875.2=1,5.2+13=2=11 20, ~(n—I)H,O—>X:0,,, = n+ 1=11=9 0 =10=9 n-1=9 lkpeptit, = XiCyHyO Nig NaOH 0,3 mat 0,025 molXCygHy,0, Nyy. 8222 9 m-+H,0 :0,025 mol = m = 29,75 g. Dap an A A, +3NaOH—12,76g mudi +H,0 a—>3a—________»a E58, 68 + 40.3a =12,76 +18a = a = 0,04 mol A, +3HC1+2H,0—>m 0,02 + 0,06 —> 0,04 = m=4,34+0,06.36,5+0,04.18=7, 25g. Dap dn A 39,9 X —Hosestat (0:13,44 Me 48 213,44g=939,98K 0 | a g12b= 2114 {z= gO NR BAT 5,32 ? iu CibCO, :b S185 510: 0,52 => 9a +44b = 94, 26 Cib 2b=21,14 = ine 11 of oe ae 9a+44b = 94,26 b=1L5 co, o,:eassna_, }24,648] 0 6 ee ae 10,74g A280, H,0 }} = you = my = 0,14 =2.0,07 N, :0,07 mol = 0,03mol A—# 4m, “85 5,37+0,07.40=m-+0,03.18 = m=7,63 (C,H,NO,Na:x C\H,NO,Na: y = %ite.1,x0,Na C,H,NO,Na:z fa fe 27 100 =38,14% => x =0,03 7,63 = Ye, n0;44 =18,22% = Illy +139z=4,72 [z=0,01 Dap an A FRO | ag temel=13sa¢m=ti” Y:R'O qui! m=6 X:RO,N, 3x x+y=0,35 _ fx=0,2 — = Y:R'O,Ng:y sx+6y=19 ly=0,15 X:C,HLO,N, :0,2 X: AlaGly, :0,2 CoOWNS 10.2 | og on = 0,159 2-915 3-12 aiGly, 20, Y :C,H,O,N,:0,15 m 0,2 4 16 |Y:Ala,Gly,:0,15 X:Ala,Gly,:0,2 | yanisuon _ [C:H,NO,Na :0,9mol 2H = m=198,3g Y: Ala Gly, :0,15 C\H,NO,Na :1mol Dap an A D> cau6 C,H,NO,Na:a+b A:RN,O, M, :217:Ala,Gly:a +. C,H,NO,Na :2a+3b B:R'NO, M, :288: AlaGly: [a+b=0,1 mol [a= 0,06 — = 2a+3b=0,24 mol b=0,04b 2 Dap an B stata {£00000000000000000000000000000000H% Mega book 35,85 g X —HeLossont 0:14,4 H: 2 yng =0,9 mol=335,85¢X4 0° | ya 4126=15,15 1 N:6,3 Crb # CO, : wis 0,5a 11,95gX bs, HO: = 98+ 44b = 69,15 z= 5 Bb wis 1 lc: a+12b=15,15 ja =2,55 = aml=35¢ 9a +44 = 69,15] [b=1,05 Dap an D wie C,H,NO, :0,1 Ximalthorb —sesosma , {CSHNO.Na:0,1 perce CH, :emol CH, :emol [eee | => b -0,07 mol m+3,46=9,7+14e 0413.16 m Dap in B 13,68 gam A—%28125_, %0 = 100 = 30,59% =» m= 6,8 31,68 gam| ~~? HO }=> ny = Mog = 0,18 0,045 mol A—3m, N, :0,09 mol 3,68: 0,045 mol A—&%2:2_5 muéi+0,045 mol H,O ,12+0,12.56-0,045.18 =15,03 Vee = 3tO0 NOK 15,03 een jaf =f =0,0525 C.HyNO,K: yf [127x +155y=9,38 ” |y=0,0175 0525 =m, = 33,832 > a =0,05 mol = Men vo.x = Dap an C El 100 = 44, 36% 15,03pau C,H,NO,K 75a +14b +180 = 4,63 4,63 gam X4CH,:b — —#2#98,19 gam:4 7 SNS aL, J at lab + 18e=4, 7 CH, :b 113a+14b =8,19 H,0:¢ C,H.NO, :a CO, :2a+b 4,63 gam X{CH, :b —Suaisiseml 5S H0:2,5a+b+e H,O:¢ N, 2a+0,375-+0=4a+2b+2,5a+b-+0= 4,5a+3b=0,375 (ere 0,375 { 07 = ep, = 0416= Myco, =31,528, Dap An C = 113a+14b=8,19 ~ |b=0, CD (MX = 293) = 75+89+165—2.18 = 293 =x ‘Ala -Ph 0,472.gam Y B29 5 => My = 236 =165+89-18 => Y: FF Phe~Ala 0,666 gam Z—S2H:2005 5 4, 200. =» 7] Phe“ Gly Gly -Phe =X: Ala-Phe-Gly Dap an. A p> Cau t2 dipeptit x C,H,NO,Na :0,5 mol 0,4 mol:E4 tripeptit Y }—“! 54C,H,NO,Na:0,4 mol }+H,0:0,4 mol tetrapeptit Z C,H,.NO,Na :0,2 mol => 0,4 mol:E—>m, = 83,9 g—%-». oar H,0:3,05 mg = 83,9 g—9 Meo, 4459 = 19557 > . eet > m=33,56g mmo, 440 = 78,28 Dap an D TH 10,36—X —HO=2s2001 (0::0,24 mol H:a N:0,12 mol Cb {ze 16 ny =3,84 = 10,36 2X. myesc cad (0:0,24 mol COONa:0,12 HH: HH : 0,03 10,36 gx) ** sat asimt oy g {NAOH 0,03 19 ot HO N:0,12 mol c cb H m=10,36+0,15.40-0,12.18=14,22 Dép an A. ‘A:RN,O,:0 (p RIN,O, :b EL m+142a+182b = m+23,7 = 142a +1826 = 23,7 eee oy 09 4a+5b=0,66 = 0,06 St 5m +23,7-+ Hy! ra+b ICO, :0,99+b jane 0,66 _o H,0:1,32+b CH, :b Na,CO, :0,33 N, > b=0275 Ala:0,27 Gly:0,39 =1 = 0,09m +0,06n =0,27 => 3m+2n =9 => t frean 0,09 n=3 Ala, Gly.) 10,06 AlaGly, :0,09 = = Ala,Gly, :0,06 Dap an 0,14mol: A ( ¥ (C,H,0,Ns) 0,14 mol: A>, = 46,88 —> Meo, 41,0 = 77,4-+ 28,08 = 105,52 mgA— co, 1,9 = 63,312 gam = m=28,128g CHON,) ——sronsos , [CsH4NO,Na:0,28 7 Melos +H,0:0,14 C\H,NO,Na:0,4 077 Dap an B mG Ara X:{Bra }-—3A~B~3C+4H,0 C:3a EAra ‘Ala:0,07 X:4Bia -—%2 54 Gly :0,08}—a(n, +n, +3n,) = 0,23 C:3a Val:0,08 ny +n +3n, = 23 = a=0,01 ‘Thiy phan X Ia thity phan E A-B-3C+4H,0+18H,O—>7Ala + 8Gly +8Val feceeeceeeceey My = My,,oy,ya1 ~My,o = 6523 +6 +9,36~0, 01.18.18 = 18,358 Dap an > Cau 17 48 fan=0,48 = = Gly:1,08 ~~ [3am=1,08 X: Ala, :0,12 > Y:Gly, :0,36 => m=104,28g Y:(CyHyyN20,) 2: (CiH,N,O) Nee en Te eticalics } na fea 28,08 gam x{ Z: NH, ~CH, -CONH CH, ~COOH:b NH, :a = d=0,15 = Nyc, =2a+2b= 0,42 mol = m=28,08+0,42.36,5 +0,15.18-0,06.53,5 = 42,9¢ =) 2a =0,12=9 a =0,06 Dap an D en (CO, :0,5 |CoHanatNOz 0,075 xX: ES 4H, H,O 7 N, C,H,,,,NO, +(1,5n-0,75)0, —>nCO, +(0+0,5)H,0+2N, = (1,5n—0,75)0,5 = n.0,675 = 0,075n = 0,75.0,5 > n=5 = ValXx Bs) Y:dx } Mou 048m an + dam + Zap =0,45 =9 x(n+4m-+2p) = 0,45 NOH 0.4591 Z:2x we. 4827 Moy = 28 we 045 Ni 7 48,27 gam [CHWNONaa _ farb=0.45 _ fa=0,11_ val CH,NO,Na:b ~ |139a+97b=48,27- |b=0,34- Gly 45> x =0,01 07,26 = (nt4m+2p)=45.x Xx Bs} Y:4x So xs4v1azs,0+98840—9f NI Maa 86 ‘al 0, Z:2x x Dap in B D> IC,H.NO, :a 0,15 mol X : NH, ~C,H, (COOH), :b 222854 H,O 95,15 sam nee a NH, ~C;H,(COOK), :b a+ 2b=0,85 = nosis” —H#50,15 mol X44 m = 0,45.18+95,15—0,85,56 = 55,65 = 0,1 mol X—“>m=37,1g Dap nC H,,,NO, : 0,1 0,1 mol C,H, NO, a 1,0 +(0,15+b)"" H,O 25, 1,0:0,45 mol ‘NaOH :0,1m moe, 57 ee Jee oN 0.1m 0,1m.40 +0, lm(14n +69) = 57,6 = 40m +m(14n +69) = 576 8 sm=43n=2,5 2 97a+14b=151,2 [C,H.NO, :a (CO, :2a+b mg {CH,:b Su htnel 5 H0:2,5a+b+e=3,6 H,O:¢ N, #2524 49,640=4a+2b+3,6 => 2a+2b-c=6 2a+2b-c=6 a=14 2,5atb+0=3,6 = 1b=1,1 = m=102,4g 97a+l4b=151,2 [e=-1 0,05 mol f X:C,H,N,O, : NH, ~CH, ~CONH-CH-COOH?6| soon so, Y:CH,N,O, —+(NH,),CO, :a 7 ,NO,Na 0, Z-+NH, :0,2mol+H,0 = {7872 [8-1 Lg [oHANO.Na 0.8 a+b=0,5~ |b=0,4 Na,CO, :0,1 =m =88,2¢ Dap an C 1 pf Peptit X:RN, “| peptit Y:R'N, xn+3xm= co, N, :0,11 mol calor, on:099001 1 0, (co i E Me X:RN, 3x tit Y:R'N,, 3 pepti in 3X 7 H,0 IC,H,NO, +0,22 (CO, :0,44+8 Nz :0,L1 mol E:CH,:a om 111.0 :0,55+04b— 22 ae ie H,0:b N, H,0:0,55+2 +b } 2Ue brad 62a+186=17,22 g ja = 0,33 =1%, b=-0,18 me 17 888 "0.44501 98=0,88+204055e020-| a JCHsNO, :0,22-=0,11 [reve X:RN, :Gly,Val,, .) :0,01 et "| peptit Y:R'N, : Gly,, Vale.) 10,03 =0,11 0.01n40,03m=0,1— 3-2 XiGly, Val = Ym, = 18 45% a Dép an C (ers Céch 1 Ala :2a ‘Ala—Gly—Val— Ala: NaNO, :13 la—Gly—Val—Alaza| bya: —MO! 93,745 gam) NNO ‘178 Val —Gly~Val:3a CH, :49a Gyl4a m+13.0,015.40=23,745+4.0,015.18 > m=17,025g Cach2 ‘Ala -Gly-Val-Ala:a ® | val—Gly-Val:32 C)H,NO, :13a CH, :2a +3a+3a.2.3=23a H,0:-9a (CJH,NO,Na :13a — 23,745 gam: CH, :23a > =0,015> m=17,025¢ Dap an A (CH,NO, a (CH,NO,N: mepeptit:| *L—Jon,:b M2 99,02 gam: fore eNe?# Y CH, :b H,O:¢ = 97a +14b=9,02 ‘CH,NO, :a] (CO, :2a+b ‘CH, :b 2025 5 1H0:2,5at¢b +e H,O:¢ N, —*L 52a +0+0,63 = 4a +2b +0, 24 = 2a+2b—c = 0,39 2,Satb+e=0,24 [a=0,08 2a+2b—c=0,39 = }b=0,09 = m=6,36g 97a+14b = ~0,05 Dap an A eal = a=0,015X:RN,:2 yy ef a op (m + 11,85) gam Z+H,0:a +b mol {ie +182b=11,85 { 0,045 = = 4a +5b=0,33 b=0,03 X:RN, ca ene ee C,H,NO,Na:0,33 of a aaa oN ett H,O:¢ cuaabic aes Na,CO, :0,165 mol fe EEE 42,038 (Rovneess JO*05 H,0:0,66+x X:RN,:a ‘Ala : 0,135 X RN, :Ala,Gly,_,) 0,045 ig — => mg Y:RIN,: Gly :0,195 Y:RIN, : Ala, Gly... 10,03 n X: AlaGly, : 0,045 0.045 +0,01m=0135-91,5nm=4.5-9f { laGlly, : 0,04: m = YY: Ala,Gly, :0,03 C,H.NO, C.H,.N,O, C\H,NO, H,O =) xty+z=0,225 mol C,H,NO,K:x tot tatnd 51 C,H,NO,K:y +H,O:tmol C,H,N,O,K :2. 18,6gam E: CH, :2x+3y+6z ea LR gm Es On ante Nixt+y+2z = 4x + 6y +1224 0,225 =x + 6y +1324 2t = 2t = 0,225-z= t=0,1125-0,52 —*2 4040, 225 = 2x + 2y + 2z+0,1125—0,5z = 0,3375-0,5z = 18,6 =(0,3375 -0,52).16+42x + 56y+112z 42x +56y+104z=13,2 [x =0,05 = 4xty+z=0,225 mol => 4y=0,15 = YoMeyoge =. 100=65,01 -3x+y+02=0 z=0,025 meSO cers K,CO, :0,5 mol janes or, JCO, :2,25 Pia! 8. C,H.NO,K:b H,0:2,75 N, 2a+3b= 0,25 y=0,75.x => L=3—> y=3x y-3x=0 x 7 reece H,0:0,18 mol en oe a =1,42 C,H,,NO,K :a— 14an + 85a +15b = 216,92 => freee m=140,64 g ap an B TH +0,14 mol H,O fu max tena ae eistyy Z(C,H,0,N,) C,H,NO,Na:0,4 —0,14 molX —>m, = 46,88 —> fetes =1,76.44 +1,56.18=105,52 => m=28,128g m® 25 meo,¢4,9 = 63,312 gam Dap én A en = 4*22 199 =51,685% > M=89: Ala Ala, 20,1 X:Ala,:a—> i nis 5a = 2,2 = a =0,4d > my = 164,12 g Ala:0,99 Dap an D TEE (C,H,,NO,Na 14,6 gam X :a—#* 51,1 gam: 4%Na = 20,72% +H,O:a = ny, =0,1 mol 28.100 146 wn =111=9 1 =3 => CH,NO,Na => X: AlaGly = Yom = =19,17% Dép an DC,HaguaNO, 10,054 CO, 10,21 0,05 mol)" ete 2-5 36,3gam } 2” = ist feo } {rovean-qos|>* : (C,H,NO, :0,03 HO = Myo, =17,73 0,01 olf |.00, 10,0924 5 BacO, : 0,09 | Hest ote. no.k :3,9mol} C,H,,_,NO:3,9 kmol . 66,075 gan af ‘aH 5, aa a ie 3,9kn H,0:0,7k H,0:3,9kn-1,25k 54, 6kn +125,7k = 66,075 | _ n= 3 a hs 241,8kn~22,5k = 147,825] ~ |, _ 995 eis eee rere Dap an C TE IN, 0,05molX —A22#%_5 41,5 mol CO, = X:CygH,,0,,N,) = 10-1 = 91k peptit 1,3 mol H,O X:CygH,,0, Nyy 10,025 S224 ™_5 ran + HO: 0,025 mol My =33,75 2 Dép an A aa JCH, -NH, :0,12 >,H,NH, :0,08 mol 8 (CHO.N) 80,2 mol Z B (C.H,0.N, A (C,H,0,N,)(C,H,NH,),CO, swoa_, [Na,CO, :0,04 : s B (C,H,,0,N,):CH,NH, -OCO-COONH,CH, (COONa), :0,06 m, = 804g. Dap én Daad Val:a HyS04: 0,05, NoOH : O41 X: —is0u:0es 4 y___ Mott, 30,725 gam +H,0:a+b+0,05 [Gly Ala:b we ja-+2b=0,175 mol > > 116a+162b=16,8 Dap én B D> H,O11:0,06 A CHHN,O, ba 0,21 mol NOH bake : 0901 Noy cy MY CHANO-Ne 0 40,06 ena C\H,NO,Na:b x+y=0,09 |__ [x=0,03 = = sxt+y=0,21{~ |y=0,06 C,H,NO, :0,15 = 0,09mol X: C,HNO, :0,15k 1H, :bk CO, :0,54k+bk 41,325 gam X: CH, 496,975 gam = NH, —CH, -COO-C,H, :0,06k H,0:0,525k+ bk H,0:-0,12 kmol 5, 1.32 k=2,5 5 [15:27 1A =41.325] _ fkK=25 sg 99 5 a=0,06 33, 21k +62bk =96,975[ [bk =0,225 CH,NO:0,1 H,NO]n.H,0:b oa : \s LNO]nHy [ots CH, :a ease H,0:b (CO, :0,2+a ot o.01sea+b}—Bomhseimn i. ose AEH IN, :0,05 eee eee eee 62a +18b-+11,5~0,1.197 +197a =15,83 = 259a+18b = 24,03 lb=0,025 = a=0,091 lb=0,05 = a= 0,089 mao fpcncd-o2<%c4-oomsch<0.05-|=> 7,424 Y_S5# 45 16,3 gam+H,0:0,2 Mut, coon, =133=9 H,NC,H, (COOH), = %C = 36,09% Dap an D C,H,NO, :@ (CO, £1,195 Z:)CH,:b 2254 H,0:1,2025 H,O:¢ Ny 16,2325 C,H,NO, +2,250, —>2CO, +2,5H,0+0,5N, a—>2, 25a 92a 92, 5a 90, 5 CH, +1,50, —CO, +H,0 b—31,5b—>b—>> Day, =4.no, =9a+6b+0,5a=9.5a+6b = [9.5a+6b=6,2325 [a=0,375 = = 2a+b=1,195 b=0,445 oy, = 2,25a+1,5b 2325 = ¢=-0,18 mol Trong dung dich Y cé C,H,NO, :0,75 CH, :0,89 Z: Keine! 5 rin +H,0:1,75 H,SO, :0,5 H,0:-0,36 mol m,, =197,33 Dap an Dec Lad Cach 1: Qui déi E thanh: C,H.NO, sa C,H,,NO, :b estat yy, 20.9750 { H,0:0 a=104_ a8 = aset b=0,91 6 7 a+b=1,95 2,25a+6,75b =8,4825 Céch 2: Qui d6i E thinh CH.NO, :1,95 CH, :36 StS 5 1,95,2,25 +4, 5b =8,4825 => b= 0,91 H,O:¢ ee £1,95~0,91=1,04 C\H,,NO, :0,91 Dap én B C,H,NO, :1,95 CH, :3b 2 SAtisoel 195.2, 254 4, 5b =8,4825 => b=0,91 H,0:¢ (CH,NO,Na:1,95 fea 2,73 => m=227,37g Dap dn A ‘C,HNO, :1,95 CH, :3b —tisnel 5 195.2, 25 +4,5b =8,4825 = b=0,91 H,0:¢ C,H,NO, :1,95 CO, 16,63 127: 44 =-1,56 = m= 156,39, => CH, :2,73 00,5 sac’ 36 = m= 156,39g =k=1 Gly 0,09 Gly _9_ 4 jAla:0,05" Ala 5 |, dk : 2s Gly, Ala, +3H,0:0,01 mol = m=9,4g Dap in BTaaffeite Taaffeite dugc cho 1a loai da quy khan hiém hon kim cuong mot triéu lan. Néu g6p toan bd lugng da Taaffeite quy hiém ma con ngudi phat hién tir truoc t6i nay, chting chi choan day mot chiéc coc nho. Bay chinh la ly do d6 khién cho gia thanh cla mot vién da quy Taaffeite khong hé nho.+ Phuong phap: B1: Xéc dinh dung djch sau phan ting chifa ion nao B2: Tinh tng mol dign tich duong, mol dién tich am B3: Bao toan dign tich cho mol dién tich dong bing mol dign tich am WD PrvoncPrée: (XETED Cho tii ti 0,7 mol NaOH vao dung dich chita 0,1 mol AL(SO,),, $6 mol két tia thu dug? B a A.0,2 B.0,15, C.0,1 D.0,05 Huéng dan: Két tia thu duge la Al(OH), : mol Dung dich thu duge sau phan ting: Na* :0,7 mol AIO; :x —“45x=0,1 mol SO} :0,3 mol EMEA 5 ¢=0,3-0,1=0,2 mol Dap nA han xét: phuiong php bio toin dign tich giép céc em hoc sinh giai nhanh bai ton cho muéi cia nhém phan ting ion OH” . Giai phutong php nay cdc em khong cén lap hé phuong trinh hong viét phan ing (Trich Dé thi thit Chuyén Phan Ngoc Hién lan 1 -2016) Hoa tan hét 3,87 gam hén hgp Na, Cava ALO, (trong dé ALO, chiém 52,713% khdi higng) vao muéc, thu durge dung dich X va 1,008 lit khi Hf, (dktc). Cho 135 ml dung djch HCl 1M vao X dén khi céc phan ting két thitc, ‘thu duce m gam két tia. Gié tri cia m li A312 B.195. C.2,34, D.LI?, 1 Huéng dan: Naza 3,87g}Ca:b —E2 5H, :0,045 mol+X ALO, :0,02 mol Ea‘Na* :0,01 _ [238+40b=183_, [a=0,01_, . /Ca™:0,04 a+2b=0,09 b= 0,04 "| Al0; :0,04 OH :0,05 ‘Na* :0,01 26 Ca 20,04 ct:ou3sa01 AI(OH), :xmol Al; :0,04 OHT-0,05 Dung dich thu duigc sau phan ting: Na’ 0,01 ba 0,08 _goiras 5 x = 0,02.2-0,015 = 0,025=9 Myon, =1,95g AP*:0,015 » Cr 20,135 Dap an B [XEIED Hin hop X gém Al, Ca, AL,C, va CaC,. Cho 15,15 gam X vao nude du, chi thu duge dung dich Y va hén hgp khi Z (C,H, CH, H,). Dét chdy hét Z, thu duige 4,48 lit CO, (dtc) va 9,45 gam H,O. Nhé tit tit 200 ml dung dich HC] 2M vao Y, duige m gam két tia. Gia trj cha m la A273. B.19,5, 169. D156. 1 Huéng dan: Ca: ee see ao CO, :0,2 15,15 gam X {Al, Ca, Al,C,va CaC, —¥> Alry SY + a C:0,2 mol ~ 40x+27y=12,75 _ fx =0,15 mol = > 2x+3y =1,05 y=0,25 mol 2 Ca" 0,15 Ca® 0,15 Y:4 AIO; :0,25 U2 4021_5 4 apt ot + Al(OH), :0, OFT :0,05 cr :04 =? Maxon, Dap an C Cho ti tit dung dich Ba(OH), 0,5M vao 200ml dung dich X gém K,SO, 0,2 M va AICI, O,1M. Khi thé tich dung dich Ba(OH), cho vao la V, tht luoing ket tia thu duigc la 7,695g Xi thé tich dich Ba(OH), cho vao la V, thi huomg két tia thu dug la 9,012g tong V, +V, 6 gid wile A. 122 BL 124 C126 D128 aSeed i : * POMPOM OOOH OOH OHIO OOM i Hudng dan: ‘Trudng hop két tia 7,695g. x; {E504 :0,04 mol _asvjeoi neon, 17,6958 BaSO, 1:0,5.V, AICI, :0,02 mol AI(OH), 1:x mol = 116,5.V, + 78x = 7,695 (1) Khi cho 0,5.V1 mol Ba(OH), thi dung dich thu dugc xét trudng hgp két nhom chua két tia hét, K*:0,08 Tr: frien M4 0,08+ 0,06-3x = 0,06+0,08-V1 = 3x-V, =0(2) Al” :0,02—x SOF :0,04-0,5.V, iaesuyma tates ‘Truding két ita 9,012 [E280 :0,04 mol osm mon 7 gos [B89 105.¥s _116,5:y,+70=9,012 0) AICI, :0,02 mol Al(OH), J:a mol Khi cho 0,5V,mol Ba(OH), thi dung djch thu duigc xét tring hgp két nhém tan mot phén K" :0,08, oe —%+0,08 = 0,06+0,06—a +0,08-V, = a+V, =0,08(2) lO; :0,02—a SOF :0,04-0,5.V, = Vv, = a+ Va = 0,08(2) a {M007 yy, =0,1261=126ml 116,5.V, +78a=9,012 (1) ]a=0,008 mol Dap an C 150 ml NaOH 2M vao cdc dying 100 ml AICI, x mol/l. Khudy déu téi phan ting hoan toan duige 0,1 mol két tia. Thém tiép 100 ml NaOH 2M vao céc, khudy déu tdi phan ting hoan toan trong c6 cé 0,14 mol két tia, x mol/I cé gia tri la: AIM B.L6M €.0,8M D.2M ‘@ Huéng dan: Ta tinh duge téng s6 mol NaOH phan ting: nfo, = 0,5mol Xée dinh Na di vé dau? Dung dich sau phan ting li: Na’ :0,5 mol OIxt+y=0,5 _ fOlx+y=0,5 _ fx=3,2 1 :0,1x = = y+0,14=0,1x [Q1x-y=0,14 ” |y=0,18 mol AIO; : y mol Ea[ENED Cho 12,6 gam hén hop X gém Al va AL,C, vao dung dich KOH du, sau khi cic phan ting xy ra hoan toan thu dutge x mol hén hgp khi ¥ va dung dich Z, Suc kh{ CO, dut vo dung dich Z thu duge 31,2 gam két tia. Gid tri cha x 1a A, 0,25. B.0,35. C.03. D.0,45. Huéng din: Aly neem po KAO, :+4b—S> AI(OH), : + 4b =0,4 LC 27a+144b=12,6 fa=0,2 See oP an aoa 0s Dap anD ‘Cho 240 ml dung dich Ba(OH), 1M vio 200 ml dung dich gm AICI, a mol/lit va Al(SO,), 2a mol/It; sau khi céc phan ting két thiic thu dugc 51,3 gam két tia. Gi tri ota ala A.0,16. B.0,18. C012. D.0,15. 1 Huéng dan: Ba(OH), soasimale{ an jis om:| Al, (SO,), :0,4a mol cita BaSO, theo mol cia SO} vi néu tinh theo Ba** thi ta cé Mygo, = 0, 24.233 = 55,92.g > 51,3 BaSO, :1,2a = {279,6a+ 78x =51,3 Al(OH), :x.mol 9513 esne| Xéc dinh ion co trong dung dich sau phan ting: THI: AK(OH), tan 1 phan Ba” :0,24~-1,2a Cr :0,68 "5 0,48-2,4a=0,6ata—x = da—x AIO; :a—x 4a—x=0,48 a=0,15 > 279,6a+78x=51,3 |x ‘THI: Al” chia két tha hét Ba” :0,24—1,2a Cl :0,6a H+ 0,48-2, 4a +3a—3x = 0,6a => x = 0,16 a= 0,166 Al :a-x Dap in Aa ced Cho 200 ml dd X gém Ba(OH), 0,5M va NaAlO, (hay Na{AI(OH),]) 1,5M. Thém tit dung dich H,SO, 0,5M vao X cho dén khi két tia tan trd lai mot phan, thu duige két tia Y. Dem nung Y dén khéi ligng khong d6i duigc 24,32 g chat rin Z. Thé tich dd H,SO, 0,5M da ding la A.0,55 lit B, 1,34 lit C.0,67 lit D.LI0lit. 1 Huéng dan: Ba(OH), :0,1 BaSO, :0,1 fee +(OH), #0 net dd: 4Na :0,3 Nal, :0,3 mol Al(OH), :x mol a AP ry BaSO, :0,1 A BaSO, :0,1 o —1524,32¢ | = x=0,02 mol= y=0,28 mol Al(OH), :x mol 1,0, :0,5x mol SO} :zmol Na’ :0,3 #45 22 = 0,34 0,28.3=1,14 > 2 =0,57mol > Ny, 5o,= 0,57+0,1= 0,67 AP*:0,28 mol Vaso, = 434 Dap an B ho V lit dung dich NaOH 2M vio dung dich chia 0,1 mol Al,(SO,), va 0,1 mol H,SO, én Khi phan ting hodn todn, thu dugc 7,8 gam két tia. Gid tri Idn nhat cla V dé thu duoc hugng két ta tén 1a A045. B.0,35. €.0,05, D025. Huéng dan: ‘Nat :2V foanenan(eors) emis 2viel_5 Al(OH), :0,1 mol-+4$O7 :0,4—"> V =0,451 0,1moLH,SO, A105 :0,1 Dap an A ETELD Hoa tan hét 3,79 gam hon hgp X gém Al va Zn (cé ti lé mol tuong ting la 2:5vao dung p X ge 8 ‘dich chita 0,394 mol HINO, thu duigc dung dich ¥ va V mi khiN, (dktc). Dung dich ¥ tac dung vita dis vdi 1,94 it dung dich NaOH 0,25M dé thu duige dung dich trong suét. Gi tri cla V gin nhat v6i gid tr} ndo sau day? A 2464, B.268,7. C.672,0. D. 8960. Huong dan: Na’ :0,495 A1:0,02 _ aren, yy_ostsmivon , |290% 10.05 _ pax Zn: 0,05 AIO; :0,02 NO; :x molNy ia 10a +8b = 0,16 => => NH,NO,:b — |2a+b=0,029 Dap in B ‘Cho 300 ml dung dich Ba(OH), 1M vao 200 ml dung dich chifa AICI, 0,75M va HC10,5M. Sau khi céc phan ting xdy ra hoan toin, thu duge m gam két tia, Gia trj cha m la A.7,80. B.3,90, 11,70. D585. Hugin dan: AICI, 0,15 pica {is : | ses avom, :xmol+4Cl :0,55 50,6 Z AlO;:y =0,55+y= y=0,05 = x= 01 Myoow, =7.88 Dap én A [XEQRBD Hin hop X gém Al, Ca, Al,C, va CaC,, Cho 15,15 gam X vo nuiéc du, chi thu duge dung a khi Z. Dét chay hoan toan Z, thu duigc 4,48 lit CO, (dtc) va 9,45 gam HO. Thém tit tit dung dich HCI 1M vao Y, khi hét V Iit hoc 3V lit thi déu thu duigc m gam két tia. Gid tr} cha m gin nhat véi gid tri nao sau day? A130, B14. C15, D.12. Al ‘AL 1a Ci 0, =12, x) c aeleaie (00, :0,2 _, [270+400=12,75 _ fa ALC, H,0:0,525 |3a+2b=1,05 b=0,15 C:0,2 Cac, Khi thém V mol HCl vao dung dich Y thi thu dugc x mol Al(OH), 1 (ca** 20,15 Al; :0,25~x—30,05 +x = VQ) Cr :0,05+x Khi thém 3V mol HCl vao dung djch ¥ thi thu duige x mol AI(OH), Ca :0,15 i x=015 AD*:0,25-x— 91 05-3x=3V(2)— 4°") > m=I1,7=128 CP :1,05-3x Dp an DSe cid Cho 12,9 gam hn hgp X g6m Al va Al,O, vao 400 ml dung dich NaOH 1M, dun néng. Sau phan ting hoan toan thu duigc dung dich Y va thay thodt ra 3,36 lit H, (dete). Thém 150 ml dung dich H,SO, 1M vao dung dich Y, thu duge két tia c6 khhéi lugng 18 A.7,8 gam. B. 23,4 gam. C.19,5 gam. D.15,6 gam. lt Hudng dan: H, :0,15 mol Ala NaOH =D4met_ 12,9 gam: notin 5 |/NaalO, Al,0, :b NaOH ‘Al:0,1 NaAlO, :0,3 mol) 50,038 : |_rsoustsset AIO, :0,1 NaQH:0,1 mol => AIOH), :0,2 mol = myjou, =15,68 ap énD 2129 ssn [XENED Cho V lit dung dich NaOH 1M vao dung dich chia 0,14 mol AICI, thu dugc m gam két tila, Mat khac, cho 1,5V lit dung dich NaOH 1M vao dung dich chifa 0,14 mol AICL,, thu duge 0,75m gam két tia. Gia tri cia V la A.0332, B.040, €.0336. D.0,28. 1 Huéng dan: TH Khi mol NaOH: V mol AICI, chuia keét tia het. Al(OH), :x mol Nat: V mol = J AP* :0,14—x $—™ 5 V4+0,42-3x = 0,42 = V-3x =0(1) CY :0,42 mot Khi mol NaOH: 1,5V mol Al(OH); :0,75x mol Na’ :1,5V mol => J AlO; :0,14—0,75x } 91, SV =0,14~0,75x + 0,42 = 1,5V +0, 75x = 0,56 (2) Cr :0,42 mol ane V=0,32 V-3x=0() 1067 Dap An ABAI TAP REN LUYEN: ‘ho tit tit 200 mi dung dich X gém NaOH 1M va Ba(OH), 1,5M vao 100ml dung dich Y gém H,SO, 1M va ZnSO, 2,5M, sau khi phan ting xay ra hoan toan thu duigc m gam két ta, Gia tri m la: A.78,05, B, 89,70. €.79,80. D. 19,80 ‘Cho m gam Ba vio 600ml dung dich chtta KOH 0,1M va NaOH 0,1M thu dugc dung dich X. Cho ti tit dung dich X vao 200ml dung dich Al,(SO,), 0,1M duge két tia ¥. Dé thu duige két tla Y Idn nhat thi gid tri m t6i thiéu va kh6i lugng két tia Y lin luot la: A. 8,22 gam va 13,98 gam, B. 0,00 gam va 3,12 gam. C. 8,22 gam va 19,38 gam. D, 2,74 gam va 4,66 gam. Dung dich X g6m Al,(SO,), 0,75M va H,SO, 0,75M. Cho V1 ml dung dich KOH 1M vao 100 ml dung dich X, thu dugc 3,9 gam két tia, Mat khic, khi cho V2 ml dung dich KOH IM vao 100 ml dung dich X cting thu duigc 3,9 gam két tiia, Biét cic phan ting xay ra hoan toan, Te V2: V1 A4:3, B.25: 9, C139, D.7:3, ‘Cho mét higng hén hgp X gém Ba va Na vio 200 ml dung dich Y g6m HCl 0,04M va AICI, 0,1M. Két thiic céc phan ting, thu duigc 0,896 lit khi (dktc) va m gam két tia. Gid trj cla mia AL1,248 B.1,56 C.0,936 D.0,624 Hoa tan m gam mét hén hgp gém AICI, va ZnCl, c6 ty1é mol tuong ting la 2: 3 vao nude du thu duigc dd X. Cho 960 ml dd NaOH IM vio X thay xudt hién 2a mol hén hop két tia, Mat hdc, cho 2080 ml dd NaOH 1M vao X thay xust hign a mol két tia, Cho ring t6c d céc phan ting la nhu nhau, Gid tr} cha m la: A.97,2 B.81,0 C1215 D.648 [XELLD Cho 150 ml dung dich KOH 1,2M tac dung véi 100 ml dung dich AICI, xM thu duge dung dich Y va 4,68 gam két tia. Loc két tia, thém 175 ml dung dich KOH 1,2M vao ¥ thi thu dugc 2,34 gam két tia niia. Gid tri cia xa ALB, B.06. C24. DA2 TED Cho 150 ml dung dich Ba(O¥), 1M vao 250 ml dung dich Al,(SO,), x(M) thu duge 42,75 gam két tia. Thém tiép 200 ml dung dich Ba(OH), 1M vao hén hgp phan ting thi long két tia thu duige la 94,2375 gam. Gié tri cia x la: A.0,15, B.0,25. €.03. D.0,45. ETED Cho 94,8 gam phén chua (KAI(SO,),.12H,0) tac dung v6i 350 ml dung dich chtia Ba(OH), gampl ,),AZH, 4 8 0,5M va NaOH 1M, sau khi céc phan ting xay ra hoan toan thi thu dvgc m gam két tita, Gia trimla A. 56,375 gam B. 48,575 gam C. 101,115 gam D. 111,425 gam aCaras ED Dung dich X chita 0,02 mol AP*; 0,04 mol Mg’; 0,04 mol NO, x mol CI vay mol Cu. Cho X tac dung hét voi dung dich AgNO, du, thu duigc 17,22 gam ket tita, Mat khéc, cho 170 mi dung dich NaOH 1M vaio X, thu duige m gam két tia, Biét céc phan ting déu xy ra hoan toan. Gi tri cha ma A486. B.5,06. ©. 4008. D.3,30. [LE{HDD Hin hop X gm Na, K, Ba trong X c6 s6 mol ciia Ba bing mot néfa s6 mol cia hén hop. ‘Cho m gam hén hop X tan hét trong nuidc, thu durgc dung dich Y va khi H,. Cho toan b6 khi H, taora di qua m6t dng chita 0,3 mol CuO va 0,2 mol FeO nung néng, sau phan ving thu duge 33,6 gam chat rn trong éng. Dem toan b dung dich Y cho vio mét dung dich chtia 0,2 mol HCL, 0,02 mol AICI, va 0,05 mo! Al,(SO,), thu duigc y gam két tia. Biét cdc phan ding xay ra hoan toan. Gid tri cla y la: A.58,22 B. 52,30 37,58 D.41,19 Cho a gam AICI, vao 200 ml dung dich HCl 1M, thu duige dung dich X. Cho 650 ml dung dich NaOH IM vao X thu duge 2m gam két tita, Mat khéc cho 925 ml dung dich NaOH 1M vio dung dich X thu duge m gam két tia. Gié trj cia a la: (Biét cdc phan ting hoan toan) A. 26,7 gam. B. 13,35 gam. C.40,05, 1D. 53,4 gam. Hén hop X gém Na, Ba, Na,O va BaO. Hoa tan hoan toan 21,9 gam X vao nude, thu diigc 1,12 lit khi H, (digu kign tiéu chudn) va dung dich Y, trong 46 6 20,52 gam Ba(OH),. Cho toan bé dung dich Y tac dung véi 100 ml dung dich AL,(SO,), 0,5M, thu duige m gam két tia. Gid tri cham Ra: A.27,96. B. 3651, C.29,52, D.1,56. Hoa tan hoan toam m gam hén hyp gém AI,C, va Al trong dung dich NaOH dut thu duigc dang dich X va hén hop kh 6 ti khéi d6i v6t H, la 4,5. Cho khi CO, dut qua dung dich X thu duige két tia ¥. Loc ¥ nung dén kh6i lvgng khéng d6i thu duige chat rin c6 kh6i lung 1a (m+10,8) gam. Gié tri cua m la: A.20,8 gam B.19,8 gam 31,5 gam D. 288 gam [XEDEED Cho 46,6 gam hén hop (X) gém Na, K, Ba va ALO, (trong dé oxi chiém 30,9% vé khéi ‘higng) tan hét vao nuiéc, thu duige dung dich Y va 8,96 lit H, (4ktc), Cho 3,1 lit dung dich axit HCL 0,5M vao dung dich ¥ dén phan ting hoan toan thu duoc m gam két tia. Gi tri ciia m gan v6i gid tri nado sau day? A.160. B.21,0. C80. D, 280. ‘Hoa tan hoan toan m gam ZnSO, vio nuidc duigc dung dich X. Néu cho 110 ml dung dich KOH 2M vio X thi thu duige 3a gam két tia. Mit khéc, néu cho 140 ml dung dich KOH 2M vao X thi thu duge 2a gam két tia, Gié tri ctia m la: A771. B. 32,20. €.16,10. D. 24,15. Hoa tan hét 4,667 gam hén hgp Na, K, Ba va ZnO (trong dé oxi chiém 5,14% khéi lugng) vao nuéc, thu duge dung dich X vi 0,032 mol khi H,. Cho 88 ml dung djch HCI1M vao X dén khi céc phan ting két thiic, thu dugc m gam két tia. Gid tri cha m 1a: A.0,990. B.0,198. €.0,297, D. 0,495. (XETEED Cho 200 ml dung dich gsm KOH 1M va NaOH 0,75M vao 100 ml dung dich AICI, 1M. Sau khi két thitc céc phan ting thu duige m gam két tia. Gi tri cia m la: A. 3,90. B. 11,70, C.7,80. 1D, 5,85. [XEDEED Nong nong m gam hén hgp gém Al va Fe,O, trong diéu kin kkhéng cé kh6ng khi, Sau khi cc phan ting xy ra hoan toan thu dugc hén hgp rin X. Cho X tic dung voi dung dich NaOH du thu dugc dung dich Y, chat ran Z, va cé 3,36 lit khi H, dkte. Suc khi CO, dit vio dung dich Y thu duigc 39 gam két tha. Gid tri ca m li: A. 36,7. B45. C4833. D.57,0. Hoa tan hoan toan m gam bét Al vao 150 ml dung dich HCI 2M thu duigc dung dich X. Cho dung dich X téc dung véi 320 ml dung dich NaOH 1M thu duge 4,68 gam ket tia. Gid tri cia mli: A. 1,89 gam B.27 gam C.1,62 gam D.2,16 gam Cho 12,9 gam hén hgp X gém Al va ALO, vao 400 ml dung dich KOH 1M, dun néng. Sau phan {ing hoan toan thu duigc dung dich Y va thay thodt ra 3,36 lit H, (dktc). Thém 300 ml dung dich HC! 1M vio dung dich Y, thu duige két tia o6 khéi luigng la: A.23,4 gam B.7,8 gam C.19,15 D.15.6 [XETEDD Cho tis tis V ml dung dich NaOH 1M vao 300 ml dung dich AICI, 1M, dén khi thu duge 7,8 gam két tha thi diing lai. Tinh gid tri V cuc dai dé duge két tha trén? A.1100 B. 300 C.900 D.100 (Chuyén Vinh Lan 3-2014) Cho 300 ml dung dich gém Ba(OH), 0,5M va KOH x mol/lit, ‘vaio 50 ml dung dich Al,(SO,), IM. Sau khi két thtic céc phan iing thu dugc 36,9 gam két tia Gié tri cia xl: A.0,75. B.0,25. C.0,50. D.1,0. Héa tan hét 4,35 gam hén hop gém Al va hai kim loai kiém 6 2 chu ki lién tiép vao nuéc dui thu duge dung dich X va 3,92 lit H, (dktc). Cho ti tit dung dich HCl vao dung dich X dén khi kh6i lugng két tua lén nhat thi thu duge 3,9 gam két tia, Hai kim loai kiém trong hén hop ban dau la ALK,Rb. B.Na, K. C.Li,Na, D.Rb, Cs. Cho 200 ml dung dich Al,(SO,), 0,5M téc dung vi 200 gam dung dich NaOH thu duge 11,7 gam két tia tring. Néng dé dung dich NaOH da ding li: A.9% B.12% 13% D. Phuong én khdc ([XETESD Hoa tan hoan toan m gam hén hop X gém Na va K vao dung dich HCl du thu duge dung dich Y. C6 can dung dich Y thu duge (m+31,95) gam hén hgp chat rin khan, Hoa tan hoan toan 2m gam hén hgp X vio nuiéc thu duige dung dich Z. Cho tit tir dén hét dung dich Z vo, 0,5 lit dung dich CrCl, 1M dén phan ting hoan toan thu duigc ket tia o6 kh6i Iuigng la A.5L,5gam. B. 30,9gam C.54,0gam, D.20,6gam. eman Hoa tan hoan toan 3,79 gam hén hgp X gém Al va Zn (cé ti 1é mol tuong ting 1a 2: 5) vao dung dich chifa 0,394 mol HNO, thu dugc dung dich ¥ va V ml (dktc) khé N, duy nhét. Dé phan ting hét véi céc chat trong Y thu duigc dung dich trong suét cén 3,88 lit dung dich NaOH 0,125M. Gi trj cia VA AMZ B. 268,8 C3584 D. 3528 Cho 500 ml dung dich Ba(OH), 0,1M vao Vl dung dich Al,(SO,), 0,1M, sau kkhi két thie phan ding thu duge 12,045 gam két tha. Gia tri ca V la: A. 200. B.75. C150. D.300. [XELED Cho miu kim loai Ba vao 500ml dung dich Al, (SO,),0,1M . Sau phan ting thu duge dung dich X,, két tia Y va khi Z. Khéi higng dung dich X gidm di so véi Khéi higng dung dich ban iu 14 19,59 gam. Syc ti tit dn du kh CO, vio dung dich X thi thay xudt hign m gam két tia Gia tri cha ma: A156. B.1,17. C234. D.1,95, (Chuyén Khoa Hoc Ty Nhién Ha Noi lin 4-2014) Hoa tan hoan toan m gam AL(SO,), ‘yao muiéc duige dung dich X. Néu cho 500 ml dung dich NaOH 2M vio X thi thu dutgc 2a gam ‘két tia, Mat khdc néu cho 550 ml dung dich NaOH 2M vao X thi thu dug a gam két tha. Gia tricia ml: A.51,30, B. 59,85, C. 34,20. D.684 Hoa tan hét m gam Al,(SO,), vio nude thu duoc dung dich X. Cho 360 ml dung dich ‘NaOH IM vio X, sau khi két thtic phan ting thu duge 2a gam két tia. Mit khéc, néu cho 400 mi dung dich NaOH 1M vao X, sau khi két thite phan ting thi thu duige a gam két ta. Gid tr} cha m Li: A.15,39. B. 19,665 2052 D. 18,81 [XETED them 150 ml dung dich NaOH 1,0M vao dung dich chtta a mol AICI, thi thu duge m gam két tia. Trong mt thi nghiém khéc, cho 250 ml dung dich NaOH 1,0M vao dung dich chita a mol AICI, thi cfing thu duge m gam két tia. Gia tr cia a va m tuong ting li: A.0,125 va 5,2. B.0,050 vA 3,9. €.0,100 vi 26. D.0,075 va 3,9. ‘Cho 300 ml dung dich Ba(OH), 0,1M vao 250 ml dung dich Al,(SO,), x(M) thu duge 8,55 ‘gam két tia, Thém tiép 400 ml dung dich Ba(OH), 0,1M vio hn hgp phan ting thi lvgng két tiia thu duge la 18,8475 gam. Gia tri ctia x: AOL B.O,12 €.0,06 D.0,09 [XEQEED Hoa tan hét 14,6 gam hén hop gém Zn va ZnO c6 t¥ 1é mol 1:1 trong 250 gam dung dich HINO, 12,6% thu duige dung dich X va 0,336 lit khf Y (dtc). Cho tit ti’ 740 ml dung dich KOH IM vio dung djch X thu duigc 5,94 gam két tita. Néng d6 phan trim cla Zn(NO,), trong dung dich X A. 28,02% B, 14,29% C.12,37% D. 14,32%‘Cho 5,6 gam hén hgp NaOH va KOH (cé thanh phan thay déi) héa tan vo nude diidc dung dich Z. Cho dung dich Z phan ting v6i dung dich chita 0,04 mol AICI,, khdi lugng két tia thu dugelén nhét va nhé nbat li: A.3,12.gva2,6g B3i2gvalssg C.156gva3i2g dD. 26 gval 56g Hoa tan hoan toan 0,15mol phén chua KAI(SO,),.12H,O vao niéc, thu dtige dung dich X. Cho toan bd X tac dung véi 200 ml dung dich (Ba(OH), IM + NaOH 0,75M), sau phan ting, hoan toan thu duge m gam két tia, Gia tri cfia m Ja: A.5055 8. B544g, C583 g, D. 46,6 g. (XELED Hoa tan hoan toan m gam hén hgp gém Na,O va ALO, vio nudc thu duge dung dich X trong suét. Thém ti tii dung dich HCI 1M vao X, ki hét 100ml thi bat ngg xuét hién két tia, hi hét 300ml hoc 700m! thi déu thu dugc a gam két tha. Gid trj cia a vA ciia m lan lugt la: A. 15,6 va 54. B, 14,04 va 26,68. C.23,4-va 35,9. D. 15,6 va 27,7. Hoa tan hoan toan m gam hén hgp X gém Na va K vao dung dich HCI du thu duge dung dich Y. Cé can dung dich Y thu duige (m + 31,95) gam hon hop chat rn khan, Ha tan hoan toan 2m gam hén hgp X vao nudc thu duge dung dich Z. Cho tit tit dén hét dung dich Z vio 500 ml dung dich AICI, 1M dén phan ting hoan toan thu duigc két tita cé kh6i lugng la A.23,4 gam B, 39.0 gam C. 15,6 gam D. 31,2 gam (XELED Dung dich X gém 0,1 mol H", z mol Al**, t mol NO, va 0,02 mol SO,”. Cho 120 ml dung ich Y g6m KOH 1,2M va Ba(OH), 0,1M vio X, sau khi céc phan ting két thuic, thu duge 3,732 gam két tia. Gid trj chia z, tld lugt la: A.0,020 va 0,120. B.0,012 va0,096. C.0,120v8 0,020, 0,020 va 0,012. [XETEED Cho 86,3 gam hin hyp X g6m Na, K, Ba va Al,O, (trong dé Oxi chiém 19,46697567% vé kkhéi luigng) tan hét vao nude thu duige dung dich ¥ va 13,44 lit H, (kte). Cho 3,2 lit dung dich HC10,75M vio dung dich Y thu duigc m gam két tia. Gié tri cita m la: A546, B.104 234 D273. Dung dich X gém 0,25 mol Ba®; 1,3 mol Na‘; a mol OH’ va b mol Cl. Cho 400 ml dung dich ¥ (gém H,SO, 0,25M; HCl 0,25M va ZnSO, 1M) vio dung dich X. Sau khi cdc phan ting két thu, thu dugc két tita G. Nung toin bd G én khéi higng khéng 4éi thu duigc 69,59 gam chat rin H. Gia tri cita bla: A. 0,18 hog 0,58. B.1,52hoic0,48, C.0,58hofc 1,62. —_D. 0,18 hofic 1,22. [XEEZD Hoa tan hoan toan 0,15 mol phen chua KAI(SO,),.12H,O vao nuéc, duge dd X. Cho toan X tac dung vii 200 ml dd (Ba(OH), 1M + NaOH IM), sau phan ting hoan toan duigem gam két tha. Gid tri cia m la: A233, B. 466. C544, D.58,3, Xl dd AICI, ¥ la dd NaOH 2 M. Thém 150 ml dd Y yao céc chifa 100ml dd X, khudy éu dén phan ting hoan toan thay trong céc c6 7,8 gam ket tia, Thém tiép vio céc 100 ml dd |cas Y, khudy déu dén phan ding hoan toan thay trong céc cb 10,92 gam ket tia. Néng d$ mol/| cia dd X bing A.16M. B.2,0M. C.1,0M. D.3,2M. Hoa tan hoan toan 0,3 mol hén hop gém Al va Al,C, vao dung dich KOH (du), thu duge ‘a mol hin hop khi va dung dich X. Suc khi CO, (du) vao dung dich X, luigng keét tia thu duge 14.46,8 gam. Gid tri cla a la: A.0,45. B.0,40. C.0,60. D.055. EXD Cho 200 ml dung dich E gm AICI, x mol/it va Al(SO,), y mol/lit téc dung véi 700 ml ‘dung dich NaOH 1M, sau khi cdc phan ting két thiic thu duigc 7,8 gam két tha, Mat khéc, khi cho 200 ml E téc dung vi dung dich BaCl, (dui) thi thu duge 27,96 gam két tha. Gid tri cia x,, ylan lugt la: A.0,2va04 B.0,6 va0,2 C.0,3 va0,4 D.0,3 vA06 TrOn 100 ml dung dich Al,(SO,), 1M véi 700 ml dung dich NaOH 1M thu duoc két tia E. Loc tich két tia E dem nung tdi kh6i ligng khéng d6i ta thu duigc chat rin c6 khéi Luong la: A.102g B.20,4g 6.2558 D.5,10g Cho m gam kim loai Na vao 200 gam dung dich Al,(SO,), 1,71%, sau khi phan ting xong thu duige 0,78 gam két tia. m c6 gid tril: A.120g B.082ghoic 120g C.0,69ghoic1,61g D.0,69g ‘Dung dich X chifa a mol NaAlO,. Cho 100ml HCI 1M tac dung véi dung dich X thu duge ‘m gam két tita. Cho 300 ml HCl 1M tac dung véi dung dich X thu duige m gam két tita. Gid tri ita a las AL 0,2 B. 0,15 C.0,L D. 0,25 [XETZED Cho 150 ml dung dich Ba(OH), IM vio 250 ml dung dich Al,(SO, ), x(M) thu duige 42,75 igam két tia. Thém tip 200 ml dung dich Ba(OH), IM vao hin hgp phan ting thi lugng két tha thu dugc la 94,2375 gam. Gié tri cita x la: A.0,15. B.0,25. C.03. D.0,45, EXD Hoa tan hoan toin m gam AICI, vio nude duige dung dich X. Néu cho 130 ml dung dich ‘NaOH 1M vio X thi duge m, gam két tia. Mit khdc, néu cho 150 ml dung dich NaOH 1M vao X thi thu duge m, gam két tia, Biét m, = 3m,, Gié tri cia m la: A534 B.549 C.10,65 D. 12,84 [XETEDD cho a gam Ba vio 160 ml dung dich g6m Fe,(SO,), 0,125M va Al,(SO,), 0,25 M thu dugc két tia X. Nung két tia X dén khoi ligng khong d6i thi thu durgc 47,18 gam chat ran. Gia trj cla ala: A. 28,77g B.13,70g C.27,4g D.20,55 [ELE Cho m gam Na vao 160 ml dung dich gém Fe,(SO,), 0,125M va AL(SO,), 0.25M, sau khi ccc phan ting két thitc, loc két tiia r6i nung dén khdi lugng khéng déi, thu duigc 4,73 gam chat ran. Gid tri lén nat cia m 1a: A.10,35, B.9,43, C.11,50. D.9,20 eal[XEEEBD Cho 12,9 gam hén hop X gém Al va Al,O, vao 400 ml dung dich NaOH 1M, dun néng. Sau phan ing hoan toan thu duigc dung dich Y va thay thoat ra 3,36 lit H, (dktc). Thém 150 ml dung dich H,SO, 1M vao dung dich Y, thu duigc két tiia c6 kh6i Iiong la: A.7.8 gam. B. 23,4 gam. C. 19,5 gam. D. 15,6 gam. [XETEBD ho V lit dung dich NaOH 1M vao dung dich chtfa 0,14 mol AICL,, thu duge m gam két ‘tia, Mat khac, cho 1,5V lit dung dich NaOH 1M vio dung dich chtta 0,14 mol AICI, thu duge 0,75m gam két tia. Gid tri cia V 1a: A.0,32. B. 0,40. C.0,36. D.0,28. Cho 0,5 gam hén hgp X gém Li, Na, K vao nude thu duge 2 lit dung dich cé pH = 12. ‘Tron 8 gam hin hgp X va 54 gam bot Al r6i cho vio nudc dén phan ting hoan toan c6 V lit khi thost ra(dktc). Gia tri cha V Bi: A. 11,648 B, 10,304 C.8,160 D.8,064 [XETEED Cho dung dich X chita 0,1 mol Al’, 0,2 mol Mg”*, 0,2 mol NO,, x mol CI, y mol Cu?* - Néu cho dung dich X tac dung véi dung dich AgNO, du thi thu dugc 86,1 gam két tia - Néu cho 850 ml dung dich NaOH 1M vao dung dich X thi kh6i hvgng keét tia thu duige 1 A. 25,3 gam B. 26,4 gam C.20,4 gam D.21,05 gam ‘Cho 100ml dung dich chtta NaOH 1M, KOH 1M va Ba(OH), 1,2M vao 100ml dung dich AICI, xM thi thu duige 9,36 gam két tia, Vay néu cho 200 ml dung dich NaOH 1,2M vao 100 ml dung dich AICI, xM thi khéi Iuong ket tha thu duge va gid tri cita x la (biét céc phan ting xy ra hoan toin) A.LL70gamval6. —B.9,36gamva24. C.7,80gamvA10. —-D.6,24 gam va 4. [XETERD Thé tich dung dich NaOH 0,25M cén cho vao 15 ml dung dich Al,(SO,), 0,5M dé thu duge lugng két tia ln nat A.90ml B, 180 ml €.210 ml D.60 ml [XETEED Dei X gém 0,1 mol H’, z mol AP*, t mol NO, va 0,02 mol $O,. Cho 120 ml dd Y gém KOH 1,2M va Ba(OH), 0,1M vio X, sau khi cdc phan ting két thic, thu duigc 3,732 gam két ta, Gid tri chia z, tin lugt li: A.0,012-va 0,096 B. 0,020 va 0,120 C. 0,020 va 0,012 D, 0,120 va 0,020 Hoa tan hét m gam AL,(SO,), vao nudc duigc dung dich X. Cho 320 ml dung dich KOH 1M vao X, thu duge 3a gam két tiia. Mac khac, néu cho 400 ml dung dich KOH 1M vio X, thu duc a gam két tia, Cac phan ting xay ra hoan toan, gia tri ctia m la 37,62 B.15,39 €.18,81 D. 20,52 (XEDISD x la dung dich AL(SO,),, ¥ la dung dich Ba(OH),. Tron 200ml X véi 300ml Y dug 8,55 gam két tha. Trn 200ml X v6i 500ml Y dutgc 12,045 gam két tila. Nong d6 mol/ cita dung dich Xva Y lan ligt la: A.0,1MvA005M —_B.O,IMvA0,2M C.0,05M va 0,07SM —_D, 0,075M-va JIMpeas [LETTE Cho 300 ml dung dich g6m Ba(OH), 0,5M va KOH x mol/lit vao 50 ml dung dich ALSO), 1M, Sau khi két thiic céc phan ding thu duigc 36,9 gam két tia. Gid tri cha x la A075. B.0,25. €.0,50. D.1,0. Mét hén hgp gém Al,(SO,), va K,SO, trong dé s6 nguyén ttt oxi chiém 20/31 téng sé nguyén tit c6 trong hén hgp. Hoa tan hén hgp trén vio nuidc r6i cho tic dung vai dung dich BaCl, du, hdi khdi Iuong két tia thu duge gap bao nhiéu lan khéi lung hén hgp ban déu: A.1,788 lin B, 1,488 lan C. 1,688 lin D. 1,588 lan. (Cho 94,8 gam phén chua (KAL(SO,),.12H,O) tac dung voi 350 ml dung dich cha Ba(OH), 05M va NaOH IM, sau khi céc phan ting xdy ra hoan toan thi thu dug m gam két tita, Gié trim: A.1L14 gam B. 48,575 gam C. 56,375 gam D. 101 gam 100 ml dung dich A chtfa NaOH 0,1M va NaAlO, 0,3M. Thém ti tit HC] 0,1M vao dung. dich A cho dén khi két tita tan mt phan, loc két tia, nung 6 nhiét 49 cao dén khdi lugng Khong 461 thu duige 1,02 g chit ran. Thé tich dung dich HCl da ding la A038 lit B.0,6 lit C05 lit D.0,7 it [XETED Nho tis tz 3V, ml dung djch Ba(OH), (dd X) vio V, ml dung dich Al(SO,), (dd Y) thi \ 2 1 (SO), phan ting vita di va ta thu duigc két tia ldn nhat la m gam, Néu tron V, ml dung dich X 6 trén, vao V, mil dung dich Y thi ket tia thu diige 06 khdi higng bang 0,9m gam. So sinh tiIé V, / V, thay A.V, V, =2,5 hoac V,/ V, =3,25 B.V,/V, =2,5 hode V/V, =3,55 C.V,/V,=2,7 hode V,/V,=3,55 D.V,/ V,=2,7 hoc V, / V, = 3,75 (XETEED Cho 400 ml dung dich E gém AICI, x mol/it va Al,(SO,), y mol/lit tac dung véi 612 ml dung dich NaOH 1M, sau khi céc phan ting két thie thu dutgc 8,424 gam két ta. Mat khac, Khi cho 400 ml E tac dung véi dung dich BaCl, (du) thi thu duige 33,552 gam ket tia, Tié x: ya AL 4:3 B34 C74 D.3:2 Cho V lit dung dich NaOH 2M vao dung dich chtfa 0,1 mol AL(SO,), va 0,1 mol H,SO, én khi phan ding xay ra_hoan ton thu duge 7,8 gam két tha, Gid tri ln nhat cia V dé thu dugc lugng két tia trén 1a A.0,05. B.0,45. €.0,25. D, 0,035. [XETEDD Cho V lit dung dich hin hgp HCl 0,5M va H,SO, 0,25M vao 500ml dung dich hén hgp NaAlO, 1M va NaOH 1M, dén phan ting hoan toan thu dugc dung dich A va 15,6 gam két tira. Gid tr) 16 nhat cita V la: AAA B.2,5. cs. D.07, Cho m gam Al tic dung véi dung dich HCI 18,25% vita di thu duge dung dich A va khi H2. ‘Thém m gam Na vio dung dich A thu duige 3,51 gam két ta. Kh6i long cita dung dich A la: A.71,76 gam B. 70,84 gam C.74,86 gam. D.72,105 gam callKhi cho 200 ml dung dich NaOH aM vao 500 ml dung dich AICI, bM thu duge 15,6 gam kkét tia, Mat khdc, néu cho 400 ml dung dich NaOH aM vio 500 ml dung dich AICI, bM thi thu duigc 23,4 gam két tha. Cac phan ting déu xy ra hoan toan, Gif tr) etiaa va b lan lugt lb A.3,00-va 0,50. B. 3,00 va 2,50. C.3,00¥a 0,75. D. 2,00 va 3,00. Cho m gam kali vao 300 ml dung dich ZnSO, 0,5M thay khéi liigng dung dich sau phan ‘ing tang 5,3 gam, Gia tri cha m la: 11,70 B.17.55 C.5,46 D. 15,60 ‘Tron 100 ml dung dich Al,(SO,), 0,1M véi 100 ml dung dich HCl xM thu duge dung dich Y. Cho 6,85 g Bari vao dung dich Y, loc lay két tita nung dén khéi lugng khong déi thu duge 7,50 g chat rén, Gid tri nhé nbat cla x la: A030 B.0,15 C.0,10 D.0,70 XETEED Tron 100 ml dung dich Al,(SO,), 1M véi 700 ml dung dich NaOH 1M thu duoc két tua E, ig dich Al,(SO,), 8 Loc tach két tia E dem nung t6i khi long khOng d6i ta thu duigc chat rin c6 khéi lugng la: A.204g B.102g C.510g D.2,55g Cho 200 ml dung dich KOH 0,9M; Ba(OH), 0,2M vao 100 ml dung dich H,SO, 0,3M va Al,(SO,), 0,3M. Sau khi céc phan ting xy ra hoan toan, khéi lugng ket tia thu dugc la: A.9,32 gam B. 10,88 gam C. 14 gam D, 12,44 gam Cho V lit dung dich hén hgp HCl 0,5M va H,SO, 0,25M vao 500ml dung dich hén hop ‘NaAlO, 1M va NaOH 1M, dén phan ting hoari toan thu dugc dung dich A va 15,6 gam két tia. Gia tri lén nat céta V Ia AL19. B.07. C25. D4. [XETELD Cho 16,9 gam hdn hop Na va Al hoa tan hét vao nude du thu duge dung dich X. Cho X phin 8 > ng. Pl tig hét véi 0,8 mol HCi thu dugc 7,8 gam két tha. Tinh khdi lugng Al trong hén hop ban dau. A.3,95 gam B.2,7 gam C.12,4 gam D.S4gam Cho 260 ml dung dich AICI, 1M vao céc chita 350 ml dung dich NaOH 2M. Sau phan ‘ing thu dude két tia loc ly két tia nung trong khong khi dén khéi luigng khong déi thu duge chat rin 06 khéi lugng A10,2 gam B.7.8 gam C5,] gam D.15,6 gam [XETELD Hoa tan hoan toan 37,8 gam Zn(NO, ), vao muéc dutge dung dich X, Néu cho 220 ml dung dich NaOH xM vao X thi thu dugc m, gam két ta. Mat khac néu cho 280 ml dung dich NaOH XM vao X thi thu duge m, gam két tua. Biét m,/m, = 2/3. Gid tri cha xa ALLS B.2 C26 D.LS [XEEEBD Cho a gam Na vio 160 ml dung dich gm Fe,(SO,), 0,125M va AL,(SO,), 0,25M. Tach két tila r6i nung dén khoi long kh6ng d6i thi thu dugc 5,24 gam chat rin. Gid tria nao sau day 1a phit hgp? A943, B.LLS. €.9,2, D. 10,35™) Mega hook [XEQED Cho 38,775 gam hén hgp bét Al va AICI, vao luigng vita dit dung dich NaOH thu duge dung dich A (két tia viia tan het) va 6,72 lit H, (4ktc). Thém 250ml dung dich HCl vao dung dich A thu duge 21,84 gam két tia. Nong dd M cia dung dich HCLI2: A. 1,12M hode 2,48M B. 2,24M hoc 2,48M C.2,24M hoi 3,84M D.1,12M hodc 3,84M Hoa tan 0,54 gam Al vao 1 lit dung dich HCI 0,1M, dugc dung dich Y. Thém tif tit V lit dung dich NaOH 0,1M vao dung dich Y thu dugc 0,78 gam ket tia. Gia tri cia V la: A.0,3lithoge0,7 lit. B.O,31ithode L,1]it, C.0,7 lit. D.0,7 lit hogc 1,1 lit. Hoa tan 19,5 gam hén hop gém Na,O va ALO, trong nudc thu dug 500 ml dung dich A trong suét. Thém dan dung dich HCl 1M vao dung dich A dén khi xuat hién ket tha thi ditng Jai thay thé tich dung djch HCl can ding 1a 100 ml. Phan trim s6 mol mbi chét trong A lin lugtla A. 45% va 55% B. 25% va 75% C. 30% va 70% D. 60% va 40% [XETESD Cho Na téc dung véi 100 ml dd AICI, thu duge 5,6 lit H,(dktc) va két tia. Loc két tia r6i dem nung dén khéi higng khéng déi thu dugc 5,1 gam chat ran. Néng d6 mol/l cia dd AICI, la ALLSM. B.10M. 25M. D.2,0M. X la dung dich Al,(SO,),, Y 1a dung dich Ba(OH),, Tron 200mi dung dich X véi 300ml dung dich ¥ thu dugc 8,55 gam két tla. Tron 200ml dung dich X véi 500m! dung dich ¥ thu duc 12,045 gam két tia, Néng dé mol/l cta dung dich X la A.0,075M. B.0,100M C.0,150M D.0,050M (Trich Dé thi Thét THPT Doan Thugng 2014) Hoa tan hoan toan m gam Al vao dung dich NaOH vita dit thu dug dung dich X. Chia X than 2 phén bang nhau. Phan 1: Nhd 200 ml HC! 1,3M vao thu duge 1,8a gam chat rin, Phin 2Nhd 200 ml HC12,5M vao thu duge a gam chat rn. Gid tr] ctia ma AL27 B54 C108 D.8,1 ‘Thém 240ml dung dich NaOH 1M vao mét céc thuy tinh ding 100ml dung dich AICI, néng dQ x mol/L, khudy déu dén phan ting hodn toin thay trong cBc c6 0,08 mol chét két tia. ‘Thém tiép 100ml dung dich NaOH 1M vao cdc, khudy déu dén phan ting hoan toan thay trong Bc 06 0,06 mol chat két tia. Tinh x, A.05M B.0,8M C.0,75M D. IM [XENESD Cho 10,8 gam hin hgp 2 kim loai Na va K vio 100 mL dung dich AICI, 1M. Sau khi két thiic phan ting khong thu dugc két tia, Kh6i lugng K t6i da c6 trong hén hop 18 A.78 gam B.3,9 gam €.1,95 gam D.0,975 gam (rich Dé thi thi THPT Dinh Chong Duong 2014) Thém m gam kali vio 300ml dung dich chiia Ba(OH), 0,1M va NaOH 0,1M thu ditgc dung dich X. Cho tit tii dung dich X vio 200 ml dung dich AL,(SO,), 0,1M thu dugc két tia Y. Dé thu duige higng két tia Y 1én abt thi gid tr cia m li: A.L71 gam, B. 1,95 gam. C117 gam. D. 1,59 gam, el(Trich dé Thi thi Chuyén Hing Vuong Phi Tho 2012) Cho 200 ml dung dich Y gém Ba(AIO,), 0,1M va NaOH 0,1M tic dung véi dung dich HNO, thu duge 0,78 gam két tha, S6 mol HNO, t6i da cin ding la: A.0,15 B.0,13 C.0,18 D007 (Chuyén Nguyén Hué Lan 1-201) Cho 240 mi dung dich KOH 1,5M vao V lit dung dich AICI, aM thu duge 7,8 gam két tira. Néu cho 100 ml dung dich KOH 1,5M vao V lit dung dich AICI, aM thi sé gam ket tiia thu dugc la: A.5,85 gam B.3,9 gam C.2,6 gam D.7,8 gam (Chuyén Nguyén Hué Lan 3-201) Cho 200 ml dung dich KOH 0,9M; Ba(OH), 0,2M vio 100 ml dung dich H,SO, 0,3M va Al,(SO,), 0,3M. Sau khi céc phan ting xay ra hoan toan, khéi Ihigng két tia thu dhige li: A.12,44 gam B.9,32 gam C. 14 gam D. 10,88 gam (Chuyén Nguyén Hué Lan 3-2012) Dung dich X gsm KOH 1M, Ba(OH), 0,75M. Cho tit titdung dich X vio 100 ml dung dich Zn(NO,), IM thu duge 7,425 g két tha, Thé tich cha dung dich X da ding la: A. 50 ml hoc 100 ml B. 60 ml hogc 120 ml C. 600 ml hog 1200 ml D. 60 ml hog 100 ml (rich Bé Thi thit Bing Thtic Hita Lin 2-2016) Cho m gam Na vao 200 ml dung dich én hgp NaOH 1M va Ba(OH), 0,5M, dén phan ting hoan toan thu duge dung dich X. Cho dung dich X vao 200 ml dung dich hn hgp Al,(SO,), 0,5M va HCl 1M, dén phan ding hoan toan thu duge 31,1 gam ket tia. Gia tri lén nbit cia m la: A.46. B23, C.23. D.ILS, [XELED Tron 10,17 gam hin hyp X gém Fe(NO,), va Al vdi 4,64 gam FeCO, dugc hén hgp Y. Cho ¥ vao lugng vita di dung dich chta 0,56 mol KHSO, dugc dung dich Z cha 83,41 gam mudi sunfat trung hda vi m gam hén hop khi T trong d6 c6 chifa 0,01 mol H,, Thém NaOH vao Z dén khi toan bo mudi sit chuyén hét thinh hidroxit va ngiing khi thot ra thi cn 0,57 mol NaOH, loc két tia nung trong khéng khi dén khéi lugng khong d6i thu duge 11,5 gam chit rin, Gid tri ma A342, B.2,52. €.2,70, D322. C6 100 ml dung dich A chtta hin hop HCl x mol/lit va H,SO, y mol/lit. Cho 100 ml dung dich A tdc dung véi 100 ml dung dich Na[AI(OH),] (hay NaAlO,) 2M thu duge 11,7 gam két tha, Mat Khéc, cho 100 ml dung dich A tac dung voi dung djch BaCl, (du) thu duge 17,475 gam két tha. TY yla A83, B.34, 63:5. D. [XELED Cho m gam hén hop A gém Al,C, va CaC, vao nuidc du thu duge dung dich X; a gam két tila Y va khi hén hop khi Z, Loc bé két tia. Dot chay hoan toan khi Z r6i din sin pham chay vao dung dich X thu duigc thém a gam két tia nia. Héi trong hén hgp X, Al,C, va CaC, duge trn vdi tile mol thé nao: AA3 Bai C12 D.21 eaPe cid Cho hén hgp X gém x mol NaOH vay mol Ba(OH), tif tif vao dung dich chtta z mol AICI, théy két tia xuat hign, két ta ting dan va tan di mét phan, Loc thu duoc m gam ket tita. Gid tri cia m la: A.78(2z-x-2y) B.78(4z-x-y) C.78(4z-x-2y) D.78(2z-x-y) [XETELD Hoa tan mét migng Al vao dung dich chita 0,05 mol NaOH, thay c6 0,672 (dktc) H, bay ig 8 + Day én va con Iai dung dich A. Cho vao dung dich A dung dich chita 0,065 mol HCI thi lugng két tha sinh rala AL1,56g B.234g C.L17g D.0,78g [XETEED Cho m gam NaOH vao 300ml NaAlO, 0,5M duge dd A Cho ti tit dd chia 500 ml HCL 1,0M vao dd A, thu dugc dd B va 7,8 gam chat két tila Suc CO, vao dd B thay xudt hién két ‘ta Gia tri cia m 1a: ‘A. 12,0 gam B. 8,0 gam C.16,0 gam D. 4,0 gam [LEED Hoa tan a mol Al trong 500ml NaOH 1M thu duge dung dich A va V lit H,. Cho tit tit 300 ml dung dich HCI 1M vao dung dich A thu duigc b mol két tha. Néu cho ti tit 650 ml dung, dich HCl 1M vio dung dich A thi thu duge 2,5b mol ket tia. Gi tri cita a va b lan lugt la. A. 0.2 va 0,2. B.0,3 va 0,1. C.02va0] D.0,3va0,2. en 10 600 ml dd NaOH 1M vao 1M thu duigc 10,92 gam ket tita. Gia ETE ch: Il dd NaOH 1M vao V ml dd AL(SO,),1M thu dt gam két tricia V la: AL 185 B.70 : C.140 D.92,5 |Cho V lit dung dich Ba(OH), 0,01. M vao 100 ml dung dich Al,(SO,), 0,1M, sau khi phan ting hoan toan thu dugc 4,275 gam két tka. Gid tri cia Vila A175. B.1,5. C.08. D.25. [XETELED Cho 100 ml dung dich chita NaOH LM, KOH 1M va Ba(OH), 0,9M vao 100 ml dung dich AICI, xM thi thu duigc 7,8 gam keét tia. Vay néu cho 150 ml dung dich NaOH 1M vio 100 ml dung dich AICI, xM thi khéi lugng két ta thu duge va gid tri cita x la (biét céc phan ting xdy ra hoan toan) A.11,70gamvalé. B.9,36gamva24. C.3,90 gamvil,2. _D. 7,80 gam va 1,0. [XETHLED Khi cho 200 mi dung dich X gém AICI, a mol/l va NaCl b mol/l (a: b = 4:3) tac dung véi ig dich X gf 1 325 ml dung dich KOH 2M, sau khi cdc phan ting két thic thu duige 11,7 gam két tia, Néu cho 80 ml dung dich X tac dung v6i dung dich AgNO, du thi thu duge két tia c6 khéi lvgng a A. 43,05 gam. B. 45,92 gam. C. 107,625 gam. D, 50,225 gam. [XEEELD Hoa tan hoan toan 30 gam hén hop X gém Na, K va Ba vio dung dich HCl du thu duge dung dich Y. C6 can dung dich ¥ thu duge 54,85 gam hén hop chat rin khan, Hoa tan hoan toin 45 gam hén hgp X vio miéc thu duigc dung dich Z. Cho ti ti dén hét dung dich Z vio 0,4 lit dung dich ZnCl, 1M dén phan ting hoan toan thu duigc két tia cd khéi Itong 1a ‘A. 25,9875 gam. B. 27,225 gam. C. 34,65 gam, D.396 gam.[XEMEED Them 150 ml NaOH 2M vao céc dung 100 ml AICI, x mol/l. Khudy déu t6i phan ting hoan toan dugc 0,1 mol két tia. Thém tiép 100 ml NaOH 2M vao céc, khudy déu t6i phan ting hoan toan trong cé cé 0,14 mol két tia, x mol/l cé gia tri la: AIM B,1,6M C.0,8M D.2M ‘Cho 300 ml dung dich gém Ba(OH), 0,5M va KOH x mol/lit vao 50 ml dung dich ALSO), 1M, Sau khi két thiic céc phan (ing thu dugc 36,9 gam két tita. Gid tri cia x la: A10, B.025. €.0,50. D075. [XEDELD cho m gam bt kali vio 300m! dung dich chtia Ba(OH),0,1M va NaOH 0,1M thu duge dung dich X. Cho tit tit dung dich X vio 200ml dung dich hén hgp gém H,SO, 0,05M va Al(SO,), 0,1M thu dutgc két tia Y. Dé thu dutgc két tita ¥ lén nhét thi gid trj cla m la: ALI7 B.L7i C.1,95 D.159 [XETEID Hoi tan hoan toin m gam hén hop gém Na,O va Al,O, vio miéc thu dugc dung dich X trong suét. Thém ti! tit dung dich HCl 1,0M vio dung dich X, khi hét 100 ml thi bat dau xudt ign két tia; khi hét 300 ml hoc 700 ml thi déu thu duge a gam két tia. Gia trj cha m vaa ln lugt li: A.56,3 va 23,4 B.35,9 va 23,4 C.27,7 v4 15,6 D.55,4 va 15,6 [XEEEED Dung dich A gém NaOH 1M va Ba(OH), 0,5 M. Dung dich B gém AICI, IM va Al,(SO,), 0,5M. Cho V, lit dung dich A vio V, lit dung dich B thu duge 427,5V,, gam két tha. Tis6 V,:V, =? ABS B. 2,537 va3,5 C.3,5va3 D.3 HUONG DAN: = ‘NaOH ; 0,2 mol tus0,:01me _, J 20(OH), Lx Ba(OH), :0,3 molf °°"! "| Baso, 1:0,3 mol +dd:4 Na :0,2 | SOF :0,05 ZnO} :0,05 > x=0,2 mJ=89,7g. Dap én B KOH: 0,06 NaOH : 0,06 penton Bas, J: 0,06 => m, Ba:amol Dap an A 1 =13,98 m=8,22g‘Al, (SO,), :0,075 L { 260.) ] sean, e5amte SOF 30,3 V, H,SO, :0,075 Are 280, 10,1 1,($0,)5 :0,075]| xo 5 . Al 20, 2(S0,), £2-¥1_ 5 AI(OH), :0,05 mol-+4SOF H,SO, :0,075 lO; :0,1 ,04 mol = n,,,. =0,08 mol— Al(OH), :x mol ‘Na’ :0,08 —34CF :0,068 => x =0,008 => m=0,624 g Na‘ :0,96 AIC :2% | swon-asian, [AIOH), :2y , [AL :2x~0,80 ZnCl, 23x Zn(OH), :3y- | Zn" :3x=1,2a Cl :12x M5 0,96-+6x—2,4a+ 6x —2, 4a =12x = a =0,2 mol | Al(OH), :0,8a 2 =2: =0,4a beeeeeeeearaitie el Na* :2,08 ALCL, : 2 ‘AM(OH), :22 _ |Al0; :2x 0,08 fase} Seats tina 32" | 200% :3x-0,12 cr 12x 4 2x-0,08 + 6x—0,24+ 12x =2,08=9 x = 0.12 mol m=81g AI(OR), :0,4a =0,08 San: 0,6a =0,12 22+3z=52= Dap én B calK":0,39 KOH : 0,39 mol -22#2"|_4 Al(OH), :0,09 dd: ) AIO; :0,1x—0,09 CI :0,3x 0,4x - 0,09 = 0,39 = x=1,2 Dap an D oe BaSO, :0,75 Ba(OF), :0,35 mol 222292" 94, 9375 gam * 2 AIOE), :y 2 59,351 {BAT 20,35-0,75% 9 7 5x =0,5x—y= 2x-y=0,7 Al0; :0,5x~y 2x-y=0,7 a [= 0.45 mol 174,75x + 78y =94,2375 |y=0,2 mol Dép én D > K*:0,2 sa(on), 07s, |AL(OH), :x SOF :0,225 KAI(SO,), .12H,0: 0,2 mol 2222, 7 +dd: (S0,), mol —Sror33 | Bas, :0,175 nat olss AIO; :0,1 => x=0,1=> m=48,575g Dép in B 0,02 mol Al* 0,04 mol Mg”* 0,04 mol NO,” }-—"* 9x +0,04 = 0,08 +0,06-+2y = x-2y=0,1 x mol Cv y mol Cu** 0,02 mol AI" 0,04 mol Mg” ao :40,04 mol NO,” }—* 5 AgCl o.2me1—f aft y=0, x mol Cl y mol Cu"ed 0,02 mol AP* > /Na* :0,17 mol 0,04 mol Mg” ‘Cu(OH), :0,01 foe opt X:) 0,04 mol NO, -p—%8.%imel_5 J Mg(OH), : 0,04 }-+dd: i ay =>a=0,01 0,12 mot Cr Al(OH), :a i : INO; :0,04 0,01 mol Cu’ m=4,08g Dap in C K:b 22 5H, 32 S° 51,0: 0,3 mol = n,,. =2.ny, =0,6mol Ba:e Na* :0,2 Ba"*:0, 0,2 mol HCI eats sos ais .02mol AICI, | —*94C 20.22 =) sop, >m=4119¢ 0,05 mot Al, (SO,), SOF :0,15 ae AIO; :0,08 Dap in D. D> AICI. 1 Bee HOO EK MO _wotestm 5 41H), :y mol-+dd:4CI" :3x+0,2 HCI: 0,2 mol Z AL™ rx-y 85 0,65 + 3x —3y = 3x +0,2 y=0,15 mol ic i Na* :0,925 Xf EEO E® MO’ _suoit-asseol_, (OH), 10,075 mol-+dd:4 CT" :3x+0,2 HCI: 0,2 mol AO; :x-0,075 "£40,925 = 3x +0,2+x-0,075 = x= 0,2 mol = a= 26,7 Dap an A 7 TTBa :0,12 Ba 21,9 gam XG: 21,9 gam X4Na:a_ —22 511, :0,05 mol Na,O BaO Ree f =0,14 = O:b 71, 2be-014 b= 0.147? Bow = 0412.24 0,14 = 0,38 mol Na*:0,14 fae: SOF :0,03 yy —Ahlsond ies {nie 0,12 AIO; : 0,08 AI(OH), :x > x=0,02= m=29,52g ALC, NaAk CH, : 3: : (s LCs _rwon_, ee 4 tea one NaOH ”|H,:32 ~~ |Al:2a NaAlO, :4a+2a=6a oo : a, : = = fees Al(OH), > Al,0, :3a = m+10,8=306a = a =0,1 m=19,8¢ Dap in B ju 14 Na K 46,6 gam X Bi 5H, :0,4 mol + ¥ —"_, AIH), :x mol a Al,O, —— Wb M’:0,8 Noy = 24, = 0,8 mol a a " = dd:} AP" :0,6—x |" 50,841,8-3x =1,55 Al,0, :0,3 mol a Cl :1,55 mol = x=0,35 mol = m=27,3 g Dap an D. 2) Mega book iD K*:0,22 mol ZnSO, : x mol —“<242™_; Zn(OH), :3y mol +dd: 4SO% :x ZnOF :x-3y 4x—6y =0,22 K*:0,28 mol ZnSO, :x mol —2#-22##*_5 Zn(OH), :2y mol + dd} SOF :x Zn0% :x-2y 4x—4y=0,28 4x-4y=0,28_ fe=O1 oo igig 4x~6y=0,22” |y=0,03 Dap in C Na,K,Ba 4,667gam:) 2 5H, 10,032 mol+dd: X—#-"9"_5 Zn(OH), :x mol Zn0:0,015 mol M" :0,064 dd:} Zn :0,015—x }—"*9 0, 064+0,015.2—2x = 0,088 = x = 0,003 = m= 0,297 Cr :0,088 Dap an C Ti eoeie —AichiGimel_, (OH), : x mol-+dd : NaOH:0,15 x= 0,053 m=3,9g Dap an A aD AL Al ft 3, Je ALO, } “#4 H, :0,15mol+ NaAlO, > Al(OH), :0,5mol 0, Fe /A1:0,1 mol = {A1,0, :0,2 mol} m=48,3 g Fe:0,45 mol Dap an C ‘alNat :0,32 Al—Boitanel_, x __MoH 022001, 41(QH), :0,06 mol+dd:4 CI" :0,3 Al; :0,02 = my =0,08.27 =2,16g Al KOH : 0.4mol 4 ‘10, fen, 20,15 mol+ddY Al: 0,1 mol = 12,9 gamX: Al,O, :0,1 mol ‘NaAlO, : ad 10, :0,3 mol NaOH :0,1 mol Dap én D ] sss anon, 20,2 mol = myiogp, =15,6 8 u21 Na* :amol AICI, :0,3 mol 2% Al(OH), :0,1 mol +dd:4 AIO; :0,2. “5a =1,1 Cr :0,9 V=11001 Dap an A (eren Ba(OH), :0,15 mol KOH: 0,3 x => x=0,25 Als al BaSO, 0,15 mol, Kt Aaah 886 36,9 gam met dd: AI(OH), J:0,025 lO; :0,075 Dap an B M_ 4, f 4,35 com 88, 30,175 mol + ddX —* 5 Al(OH), : 0,05 mol M:0,1 mol = 4,35 gam. = 05 mol =M-305/™* K Dap An Aacs Nat :a mol Al, (SO, ), :0,1 mol —S2###""-» Al(OH), :0,15 mol + dd: 4 AlO; :0,05 = a =0,65 C¥%paou =13% Dap nC Na fr |me m gamX fe #41 |K = Ny, = 0,9 mol C1:31,95g ‘Nat N 2m gam X [Boeo2 Kt OH" :0,9.2=1,8 mol M" :1,8:mol CrCl, 10,529 Cr(OB), :x mol + dd: CrO; :0,3 mol => x =0,2 mol CI :1,5 mol Meoup, =103.0,2 = 20,6 Dap dn D NaAlO, :0,02 } gamma, 99s qgy—deawasting_, Ia 70, 20,05 NaNO, :0,365 mol a=0,012 = 4b=0,005 V=268,81 Al 3,79 gamX: fa ia 20,05 a, [Netamol _ [2a+b=0,394-0,365 = 0,029 NH} :bmol ~ [10a +8b=0,02.3+0,05.2=0,16 as mot BaSO, J: 3% Ba” :0,05- Bs(o), 90s A 13,055 | SO, “fowl 0,05-3a AI(OH), Lb AIO; :2a—b => V=150ml GOR Ae e a=0,015 = 1 sa-b=0,1 b=0,02 Bap nCw_, [BaS0, 20,15 Al, (SO, ), :0,05 mol +H, :amol Al(OH), :b * a0, 4:1 P8819, 29 0,3=0,1-b=9 2a+b=0,4 Al0; :0,1—b 0,15.233-+78b-+2a—137a =19,59 «9 135a—78b=15,36 2a+b=0,4 = 135a-78b=15,36 Ba” :0,1 aa _ —£22_5 Al(OH), :0,02 > m=1,56g Na’ :1 mol Al, (SO,), :x mol #825 Al(OH), 1: 2y mol + dd: {SO} :3x mol AIO; :2x~2y Ph o8x-2y=1 Na* :11 mol Al, (SO, ), :x mol—S2#:##_5 Al(OH), J: y mol +dd:} SOF : 3x mol AIO} :2x-y Mo kx-y=11 8x-y=L1_ fx=0,15 Bx—2y=1 7 ]y=o1 Mason, =5ESB Dép an A ED Na” :0,36 mol Al, (SO,), :x mol #2882", Al(OH), J: 2y mol-+dd : 4SO}" :3x mol AIO; :2x -2y ML 8x -2y = 0,36 /Na* :0,4 mol Al, (SO, ), :x moi #4" AIH), U: y mol + dd: }SO7 :3x mol 48x ~y = 0,4 AIO; :2x-y [8x-y=0,4 x= 0,055 pa 3 My 480,), 8x-2y=0,36 Ly =0,04 (604), Dap an D 88igeed ‘Na* :0,15 NaOH : 0,15 mol 22-5 A\(OH), :x mol+dd:4 AP? :a—x CF :3a 0,15+3a—3x =3a = x =0,05 mol = m=3,9g Na® :0,25 ‘NaOH :0,25 mol 224"; Al(OH), :0,05 mol + dd: 4 AIO; :a—0,05 cr :3a 4a—0,05 = 0,25 => a=0,075 Dép dn D ‘Ay(0y:0.25¢0a BaSO, :0,75 Ba (OH), :0,07 mol 282225 18,8475 gam} . AI(OH),:¥ =9 174, 75x + 78y = 18,8475 Ba** :0,07—0,75 dd { = * <5 0,14-1,5x =0,5x—y=> 2x-y=0,14 aa +78y =18,8475 {: =0,09 > 2x-y=0,14 y= 0,04 Dap an D Zn:0,1 mol MO _3NOy 08061 5 ¥ 49,015 mol Y Zn0:0,1 mol K*:0,74 XE nt9_> 7Zn(OH), :0,06 mol +dd:4 ZnO; :0,14 mol NO; :0,46 mot n(NO,),:0,2 eae me :0,06 Snes een eee —¥2 5m =0,44.3+0,1-0,2.6-0,22=O0=9 ¥:N, my, =14,6+250—0,015.28 = 264,18 =3 C%puguo,), =14,3% Dap an DNéu trong hén hop chi cé NaOH: ‘Nat :0,14 NaOH : 0,14 mol—°#4_5 4\(OH), : x mol+dd:4 Cl" 0,12 = x=0,02 AIO; : 0,02 Marom, =1,56 8 Néu trong hén hgp chi cé KOH: KOH:0,1 mol —%=“*_; Al(OH), a Macow, = 268 Dap nD a : a(OH) 0.2m : KAI(SO, ), .12H,0:0,15 mot 2% *2%_5{BaSO, :0,2 => m=46,6g Dap an D TFG N : a, sag, [NAAIO, 228 yoo |, 5 =0,1 mol ALO, 1 NaOH: capa Na’ :22-+0,1 AIO +78 _yoi-03m 5 AOE), :xmol+dd:4Cr:0,3 |B» NaOH :0,1 AIO; :2a—x 2a-+0,1=0,3+2a—x = x =0,2 mol Nat :2a+0,1 NaAlO,:2a e927 . sat 1208. AI(OHD), :0,2mol+dd:4 CT :0,7 |B NaOH :0,1 Al :2a-0,2 2a+0,1+6a-0,6=0,7-4 a=0,15 mola {7277 =15,68 Dap nD2) Mega book Na N main { a Hee fe ce =ng =0,9 mol K C1:31,95 Na N: 2 2 2m gam { “| ese oe {? [eee K OH: M?:1,8mol Z—Moadémel_» AO), x mol+dd:4Cl:1,5mol => x=0,2=>m=15,6g AIO; :0,3 mol Dap AnC (ere 0,1 mol LAL? eee 285324 0,1= 1+ 0,04 =9 1-32 =0,06 t mol NO,” 0,02 mol $0.2" 0,1 mol H* zmol AI ‘BaSO, :0,012 =0, 6, nono, pet, eon? 3+732 gam lias 20,012 t mol NO, 0,02 mol S02" K' :0,144 soy: 450,144 = 0,016 +t+2-0,012 > t+2=0,14 AlO; :z~0,012 t42=0,14 — [t=0,12 > 1-32=0,06 |z=0,02 Dap anc ‘Na, K,Ba : #2 5H, :0,6mol+ Y #24 > Al(OH) 1 86,3 gam aie Rash mol+Y¥ "24 5 Al(OH), : xmol Mt :1.2 mol dd:{Cl:2,4 }=x=0,3=>m=23,4g AD :0,4 Dap an C(0,25 mol Ba®* 1,3 mol Na* a mol OH bmol Cl. ee 4:0,25 ° BaSO,1:0,25 269,59 g Zn(OH), + x mol ZnO 4x mol x=0,14 mol Nat :1,3 re aa-Jor Ot SOF :0,25 Zn’ :0,26 —E1,3+0,26. =0,1+b+0,5 = b=1,22->a=0,58 Nat 31,3 Cr :0,1+b “)sor :0,25 ZnO; :0,26 HA 1,3=0,1+b+0,25.2+0,26.2 > b= 0,18 Dap an D Tinh s6 mol KAI(SO, ), .12H,0:0,15 mol Ba(OH), :0,2 mol NaOH :0,2 mot Fy 6 15 ‘Nén khong co két tiia ACOH), suy ra két tira 1a: Nhin thay : n BaSO, :0,2 mol = Maso, = 46,68 Dap in BcL Baitodn may lugng két tia thu duge la keét tia cudi clang thu duigc mol NaOH La téng s6 mol AI(OH), 4: 0,14 mol ‘NaOH : 0,5 mol“ Al(OH), 1:0,14 mol Dung dich thu duige sau phan ting Na* 0,5 Cl :0,3x 0,5 =0,3x+0,12-0,14 = x=1,6 AIO; :0,1x-0,14 Dap an A oama:f re af He xa, a00m, 0,6 mol he = x=1,50430=0,6 mol AICI, :0,2x Al, (SO, ), :0,2y | 2 sasso.012miany- 9-02 flee ot one! A1(OH), :0,1 mol Al, (SO, ), :0,2y = 0,04 mol Na" :0,7 -0,1 2x +008-O1] ws 50,7 0,2x-0,02+0,6x+0,24 > =0,6 Nat :0,7 AI, (SO, ), :0,1 ““™""_5 AKOH), :x mol +dd: SO} :0,3=> x=0,1 AIO; :0,1 2AK(OH), —-+Al,0, +3H,0 > m=5,1g Dap dn D 2 |Na‘ :amol Al, (SO,), :0,01 mol—*#2"-5 Al(OH), :0,01 mol + dd: }SO;" : 0,03 por Al, :0,01 m=16lg Na’ :a mol dd:{SO? :0,03 = a=0,03 = m= Al* 0,01 Nasa NaAlO, :a mol—2™_ Al(OH), :b+dd:4 AIO; :a—b}—"* 5a =a—b+0,1 Cl 20,1 = b=0,1 mol Na’ :a NaAlO, :a mol—#2%2#!_ Al(OH), :0,1+dd: 4 Al* :a—0,1}-—“-5a 43a -0,. cr :0,3 = a=0,15 mol Dép anB a BaSO, :0,75 Al, (SO,), :0,25x 24 5 94,2375. cy . AKOH), : 9174, 45x + TBy = 94,2375 Ba” :0,35-0,75x = 0,7-1,5x =0,5x- y= 2x-y =0,7 AIO; :0,5x-y 174, 45x + 78y = 94,2375 _, [x= 0,45 2x-y=0,7 y =0,2 Dap an D. eaNa’ :0,13 AICI, :a #988 5 Al(OH), :b+dd:4 CF :3a 50,13 =4a—-b AIO; :a—b 50,15 =4a-2 Fe, (80,),:0,02 Beso, ] ‘BaSO, :0,18 mol +4 Al(OH), } > 47,18 g 4 AI,O, :0,02 Al, (SO,), :0,04 Fe(OH), Fe,0, :0,02 => 2a—-0,36 = 0,04 => a=0,2=9 m= 27,4 a Ba™ :a-0,18 lO; :0,04 be {80,), :0, A a {eae ° ‘AI,0, 10,015 [Hoare art } Al, (SO, ), :0,04 Fe(OH), Fe,0, :0,02 ‘AIO; :0,05 dd:4SO2" :0,18 }=>a=0,41= m=9,43 g. Dap an B Nat sa ALO, : 041 sets, 01smimgganx:{ 20! } /Na* 20,4 [Hs avom, x mol+dd: {SO} :0,15 =) x =0,2 = m=15,6 AI; :0,1 3 aay [NON0, 20. NaOH: 0,1 Dap an D Ea‘Na*: Viol 0,14 mol AIC, —“°#:¥2"_, 4i(OH), :x mol+dd:4 CI" :0,42 mol Al :0,14—x —“#V+0,42—3x =0,42 = V-3x=0 Na": V mol 0,14 mol AICI, —“%#--¥20_, A1(OH), :0,75x mol +dd:4 CI :0,42 mol AIO; :0,14-0,75x E51, SV =0,4240,14-0,75x > 1,5V +0, 75x = 0,56 mol eset =0,56 = V=0,32 V-3x=0 Bai toén nay cdn truéng hgp khi thém V mol NaOH vio 0,14mol AICI, dung dich thu dug a mudi A/Oy Dap an A H=12 = pOH=2 0,5 gam X25 aa: Pn v=2 7 => 8 gam X—E2 on, = Al:0,2 mol—22"_5 H, :0,3 mol => Dap in B iy, = 0,48 mol = V=10,3041 TE (0,1 mol AP* 0,2 mol Mg”* X:4 0,2 mol NO, } “25 AgCl:0,6 mol > x = 0,6 mol > y = 0,05 mol x mol Cr y mol Cu* 0,1 mol AI* 2 Na* :0,85 0,2 mol Mg’ Mg(OH), : 0,2 ee ae X:} 0,2 mol NO, }-—22#2#*™_ {Cu(OH), :0,05 b+dd: oe ae 0,6 mol Cv Al(OH), :x mol te AIO; :0,05 0,05 mol Cu** = x=0,05=9 m= 20,4 Dap an ADae Na* :0,1 ‘NaOH : 0,1 mot K:0,1 KOH:0,1 mol |—"2:8. Al(OH), :0,12 mol +dd :} Ba* :0,12 Cr :0,3x Ba(OH), :0,12 mol AIO; :0,1x-0,12 —**.0,44=0,3x +0,1x-0,12 = x=1,4 AICI, :0,14 mol "224 5 Al(OH), :0,08 = myo, = 6,248. Dap an D Al, (SO, ), :0,0075M#*2"_5 ACOH), :0,015 = 0,25V = 0,015.3 V =0,181=180 ml Dap an B P cau 58 ) 0,1 mol H* fe BaSO, J: 0,012 Releree Rete 43,732 gam i t mol NO; ao AICO), 1:0,012 0,02 mol SO,” K’ 0,144 Hee 250,144 =0,008-+ t+2~0,012 t mol NO,” z mol-0,012: AIO; t+2=0,14 _, [t= 0.12 32-+0,1=t+0,04 > t-32= 0,06 |2=0,02 Dap an B Al, (SO, ), :a mol #2, 41(OH), :b mol K? :0,32 dd:{SOF:3a |S 0,32=6a+2a—b > 8a—b= 0,32 AO; :2a—b Al, (SO, ), :a mol—S2#*4™4_5 AI(OH), 4 mol1900000000000000000000000000000000 “Tb 5 K':0,32 dd:{80> :3a 40,4 6a+2a- 2980-2 + b AIO; :2a-2 3 b Sa-=0,4 = pete ama I881-Bipanc 0,12 BaSO, :0,3b ANOH),: = 69,9b-+ 78x = 8,55 Al, (SO,), :0,2a PO" 58,55 gam t SO? :0,6a-0,3b 69,9b+ 78x =8,55 a b=0,1 x =0,02 mol 1 :0,4a— a’ Pan | strtan-ant.29-06h-034-066-0 3x -0,66=0 salons BaSO, :0,6a Al, (SO,), :0, 222% 519,045 gam 139,88 +78y =12,045 AI(OH), 2 arin dd :{B2"'0,05-0,68 wa 911 20 =0,4a-y—91,60-y=0,1 AIO; :0,4a—y 139,8a+78y=12,045] Ja =0,075 = ae 1,6a—y=0,1 y=0,02 - Dap an D DP cau st Ba(OH),:0,15] auts0.),:005 A\(OH), :0,025 BaSO, :0,15 AS00085 36,9 gam: KOH :0,3x K* :0,3x a dd: —M40,3x = 0,075 x =0,25 Dap an B Al; :0,075 ere = 52 = 3400 +1400 = 3720+ 124b = 16b = 32a K,SO,:b Al, (S0,),:a| _, 12a+4b _ 20 1Ja+7b 31 a_l6_1 = 2 1165 688. Masso, Mjso,), *Mxs0, 690 | aso, :S.mol=>Pe eared WOH OS 7 BaSO, :0,175 sa(o), 045 4 20, : BHO), 0475 (KAI(SO,), .12H,0):0,2 mol mg Nor ah mol => m= 48,575¢ Dap in B AICI, :0,4x EE 4+ BaSO, : 1, 2y => 1, 2y = 0,144 = y =0,12 mol Al, (SO,), :0,4y AICI, :0,4x —Hctstsl2_ A1(OH), :0,108 mol Al, (SO,), :0,048 Na* :0,612 dd: A 50,612 = 0,144.2 +1,2x +0,4x-0,012 = x =0,21 AIO; :0,4x-0,012 . Dap én C u65 Na’:2V O.1 mol Als(SO,),| yon ave ai(op), :0,1 mol +dd: {802 :0,4 0,1 mol H,S0, 20,01 teas 0,03 Na" :0,04 dd:} AL’ 20,01 ea cra je AH), x mol—"> Al, :0,01=> x = 0,02 ,07 mol = 0,1 V = V = Dap an D Ene000 o(, oye sas BaSO, AI(OH), Dé dat két tha cyte dai ta cb: Noy =3iMy. © OVA =3.2VIb 3 b=a=1 Al, (S0,), a, = {20802 '3¥8 =855V, 220 0)5 =) s(n), :2av, PP ‘Treéng hyp AL(SO,), dit BaSO, :V, v. Ba(OH), : V;.mol—S280e2*_,, {= 285V, =0,9.855V1 => —2 =2,7 (OH), : V,.mol ene mom h ayn ‘Truong Hop 2 Ba(OH), du hda tan mét phan két tia Al(OH), BaSO, :3Y, Ba(OH), : V, mol 28%, ee > A1(OH), :0,904V, Ba** : V, -3V, id 272. 2 2V, -6V, =1,906V, 2, =7,096V, > 2 =3,55 AIO; :1,906V, v Dép inc 0,1 mol Al, (SO, Bata }1 mol Al, (SO,), SoH?" 5 (OH), :0,1 mol:dd: {SO} :0,4 0,1 mol H,SO, i ALO; :0,1 = V=0,45 Dap én B Na*:1 HCI:0,5V Nano, 05 0,5V. Al(OH), :0,2 {rs oasy| ae (OD. 20.2 mol d6) Oe co a5y AIO; :0,3 EG I= V40,3 V=0,7 Dap nDLas Al:amol—# AICI, :a mol 2» Al(OH), : 0,045 3a,36,5.100 18,25 ),045 => a = 0,115 => mj, =27a + —3a = 624a = 71,76 8 ‘NaOH : 0,2a S292 Al(OH), :0,2 = 0,2a = 0,6 = a=3 ‘AIO; :0,56—0,3 NaOH :1,2—“S% 5 Al(OH), :0,3 = dd: 4 Na* :1,2 Cr :1,5b => 1,2=0,5b-0,3+1,5b => 2b =1,5=> b=0,75 Dap an C ‘Thi: KOH dui hda tan mot phan két tia. Bice | fst samet ZnSO, osm fm +dd:480% :0,15 fie ZnO} :0,15—x Ma =0,340,3-2x x=03-0,5a Khéi hong dung dich tang. 39a ~99(0,3—-0,5a)—1a =5,3 <> 87,5a=35 => a=0,4 mol m=15,6¢ ‘Th2: KOH hét Zn(OH), :0,5a H, :0,5a 39a-99.0,5a—a=5,3 9 -11,5a=5,3. loa Dép anD [er Ba’ :0,02 0,01 Al, (80.), #01] seosson 57 sg ee 0.03 | aator:oix }+x=0,3 HCL: 0,1x Al(OH), :0,01 on ZnSO, :0,15 mio Dap indena {Al,(SO,), :0,1 mol M2%"_ 41(OH), :0,1 mol Al,0, =m=5,lg Dap nC rena K":0,] KOH :0,18 mol nsoo_, [BAS0,:0,04) | a Ba(OH), :0,04 mol {#5 ”) aoup, dex! eee AO; :0,02 x =0,04— m=12,44g Dap anD [xen HCI:0,5V AAO, 303 Hes a eo 20,2 THI: AlO;.du Na*:1 Vv dd: eee =V=0,7 SO} :0,25V. AlO; :0,3 TH2: Al(OH),.tan mét phan. Na*:1 da Lo yiiy SOF :0,25V, Al*:0,3 tile 5 Al(OH), :0,1 mol 0,76 aa:4 410; :b-0,1| "* 5a—p=0,7 |27 P= 07 0,016 > 23a+27b=16,9Dc eerass Nav: da:Jar bo} 5ar3pan 1a [erent og 18H 88 i eis ‘ ae =) 939427b=16,9” |b=0,2 ICL, :0,2 mol S227. Al(OH), :0,1 mol—*> Al,O, :0,05 >m=5)g Dap an C Zn(NO,), 0,2 M9222 5 7n(OH), : 1, Sy mol Na’ :0,22x dd: ZnO" :0,2-1,5y p90, 22x = 0,4~3y+0,4 NO; :0,4 0,22x+3y=0,8 Zn(NO,), :0,2 #45 Zn(OH), : y mol so 2 Nat :0,2x dd: }ZnO% :0,2—y |" +0, 28x = 0,4—2y +0,4 = 0, 28x +2y = 0,8 NO} :0,4 0,22x4+3y=0,8]_ fx=2 1. - Dap an B eee pe oe boa Fe, (SO,), :0,02 Fe(OH), :0, : Fe,0, :0,02 %2(804), COD 0.04] 9g [Fe208 20.0? 50,04 Al, (SO,), :0,04 AN(OH), :x AI,0, :0,5x ‘Nat sa dd:4SOF :0,18 |= a=0,4=9m=9,2g AIO; :0,04 Dap dn C38,775 Alia | wot 5, :0,3 mol 38,775 ania 775 gam: 20,3 mol => 38,775 gam Bem") AlCl, :b f BAM) AICI, :0,25 NaAlO, :0,45 mol dd: A: See BoE A 10,28 A eee } feces THI AIO; du Nat :1,2 dd:4CI :0,75+0,25a}—“*\ 5a =1,12 |AlO; :0,17 ‘TH2: Al(OH), tan mot phin Na’ :1,2 dd:) CI :0,75+0,25a ;-—“# 9a = 3,84 AL* 0,17 Dap an D oD THI Al(OH), tan mot phan Al: 0,02 B21, y—M0H Ou AL(OH), :0,01 ‘AIO; :0,01 dd:4Cr:01 |“ 50,1V=0,11> V=11 Nat :0,1V TH2:AI* du Al:0,02 424 y Mole. A](OH), :0,01 AP*:0,01 dd:4Cl:0,1 }—“*50,1V +0,03=0,1> V=0,7 Na’ :0,1V Dap in D 1m 19,5gam:[N&0:amol | wo, 4 woes, a [NAAlO, :2b ALO, :bmol NaOH :2a-2b 2a—2b=0,1 a=0,15 _ ]%Mxao = 60% = = 62a +102b=19,5 " [b=0,1 ~ |%np,0, = 40% Dap an DPeer ‘ Ti AICI, :0,la—*H,, :0,25 mol + Al(OH), "+ Al,O, :0,05 => AI(OH), :0,1 Na" :0,5 dd:}Cl :0,3a = 0,5=0,4a-0,1=a=1,5. Dap dn A AO; :0,1a-0,1 a(t, 0. BaSO, :0,3b At(S0,) 0,28 E28, s5pf a AIH), 0,26? = Ba(oH), 005 BaSO, :0,6a Al, (SO, 3 :0,2a 24% 5 12, 045gam: een vg 139,804 78x = 12,045 a MER soi-taeaatenni6e-n=0h AIO; :0,4a~x eae baPanA 1,6a-x=0,1 x=0,02 p> cau85 Phan 1: Al:a mol Sts), x Het: 026ml_, 41(QH), 21,8 y mol Nat sa dd:}Cr 20,26 }—™ 5a43a-5,4y=0,26 = 4a—5,4y = 0,26 mol AI* :a-1,8y Phan 2: Al:a mo] —S0#+80_, x_—Ho'0Sn01_, A1(OH), : y mol Nat sa dd:{CP:0,5 p—Y*5a+3a—3y =0,5 => 4a—3y =0,5 mol Al :a-y 4a—3y=0,5. a=0,2 (eee act png tm 22427-1088 Dipanc NaOH : 0,34 mol 22" Al(OH), :0,06 Na* :0,34 dd:}Cl :0,3x —H 0,34 =0,3x + 0,1x -0,06 = x =1, Dap an D AIO; :0,1x-0,06|Naza atb= ja=0,3 n,=4.n,,, =0,4mol = => =F ~ [K:b 23a +39b=10,8 b=0,1 m=39 Dap an B Ba(OH), :0,03 NaOH :0,03 A,(80,),000 , [BaSO, :0,03 (804) { K:amol AI(OH), :0,04 =a+0,09=0,12 = a=0,03 > m=117g. Dap anC Ba(AIO,), :0,02] so, 7 2.5 AI(OH), :0,01 ‘NaOH : 0,02 Ba” :0,02 _JNa* 20,02 “| AP*:0,03 0,15 mol Dap in A D> KOH: 0,36 mol "5 Al(OH), :0,1 mol K*:0,36 dd:4Cr :3x 240,36 = 4x —0,1 = x =0,0925 mol Al; :x-0,1 KOH :0,15 mo|—Ss*5et_, 41H) Dap an B p> cau 91 KOH:0,18mol] 4.60, oss — Beenie [BaSO, :0,04 > m=9,32g Ba(OH), :0,04[ S600 Dap én B aect DI KOH: V mol niet —2(NOh8t!_, 79(OH), :0,075 mol Ba(OH), :0,75V mol THI Zn(OH), KV °*:0,75V aa: JB" *075V | wee 9 5y=0,25-5 V=0,11=100 ml NO; :0,2 ZnO :0,025 ‘TH2 Zn du KV 2.9.75 dd: BR" O75V_ wt 59, 5 40,05 =0,2 =) V=0,061=60 ml NaOH:0,2 mo! : sou404 [BaSO, :0,1 Ba(OH), £01 mol) — "ry 9311 BAM Yo, gt Na:amol Na’ :a+0,1 - ag: {S08 9? | at 9 40,140,3= 0,440,294 =0,4=9 m=4,6g cr 10,2 AP*:041 Dap in A Fe(NO,), :@ 10,17 gam:X 5 Alb 4,64 gam FeCO, :0,04 mol H, :0,01 Pm MSO. 83,41 gam Z+T T 4CO, :0,04)+H,0 N,0, = {1802 +27b = 10,17a> 3000000000000000000000000000000000 Fil chin 23, K* :0,56 93,41 gam ZNHE= | woos, ye 514.5 gam {P20 Fe™: Al,O, Fe™: Art Dung dich sau cing K* 20,56 SO} +0,56 set a Na” :0,37 mol AIO; :xmol Fe,0, :0,5a+0,02 : 80a+51b=8,81 115 am ot ens sae ” 80a+51b=881 _, [a= 0,04 180a+27b=10,17 ” [b=0,11 K' :0,56 SO? :0,56 ae x+y=0,08 83,41 gam Z:)_* = 42x+3y+z=0,23 ade 56x +56y+182=4,84 |z=0,02 Fe* sy AP*:0,11 Bio toin mol nguyén ti hidro suy ra mol nuidéc 0,56=0,02.4+ 2.1946 = Mp,o = 0524 Bio ton khéi lugng suy ram m=10,17+4,64—83, 41-0,24.18=3,24 Dap in A HCI: 0,1x hess: :0,ly TH HCI: 0,1x he 20,075 | t2-spes0,:017=0015-99=0.5 [ous S20! 5 A\(OH), :0,15Pred ‘Na* :0,2 aa JOO | SOF :0,075 AL" :0,05 TH2: HCL: 0,1x. NAO, :02651 5 AIOH), :0,15 H,SO, :0,075 D204 Nat :0,2 aa: IO |e yo. papa SO} :0,075 AIO; :0,05 a ‘ALC: Ca: CH, :3 mg) * two gax JY AOH), 2x Cac, :y, AIO; : 2x Hy cH, c 4 Oy. 2_ux AVOH), 2x CH, H,0 2 aax:{081Y 8 yoy -2y-ax-y. DépénB AIO; : 2x er Nat :x NaOH :x Bay —imisth 5 Al(OH), :bmol+dd aa KOH), cr 332 AIO; :2—b Ma x + 2y=3z+z—b=> b= 4z—x-2y => m=78(4z-x-y). Dap anc NaOH : 0,03 ‘Al mNOH_5 Hy -0,03 mol+ 403 soise Hel, A1(OH), xmol RSH 10,08 mol + 8821 aio, 0,00 MOHD RIO Na’ :0,05 dd:}CI 20,065 => x =0,015 = m=1,17g Al :0,005 Dap An Casa NaAlO, :0, ssf ta aon, 20,1 Na*:a+0,15 dd:}AlO;:0,05 }—“*>a=0,4>m=16. Cr :0,5 Dap dn > amo! A]—S#2580'_, 4 _HCIO3_ 41(OH), :b mol Na” :0,5 dd:4Cr:0,3 }—*5a—b=0,2 AIO} :a—b a mol Al “0H: ses'_, 4 HCO Al(OH), :2,5bmol ‘Na’ : dd:5Cr BE 3a-7,5b=0,15 AP 3a-7,5b=0,15 3 = a—b=0,2 =01 Dap an BPlutonium Plutonium la mot nguyén té phéng xa néi tiéng véi vai trd tao ra nang lugng hat nhan thong qua phan ung nhiét hach. Plutonium rat doc hai va dé chay nhung sé lugng trong ty nhién kha ft dan toi viec gid thanh cla chat nay rat cao, dugc cdc quéc gia dua vao danh sach nhong chat dugc bao quan va st dung theo nhiing ché do hét strc nghiém ngat. Gia thanh tia loai vat chat nay 6 khoang 4.000 USD/g (tuong duong 84.8 triéu VND/a).(XELED Cho m gam hin hgp X gém MgO, CuO, MgS va Cu,$ (oxi chiém 30% kh6i lugng) tan hét trong dung djch H,SO, va NaNO,, thu duge dung dich Y chi chita 4m gam mudi trung hda va 0,672 lit (dtc) hn hgp khi gém NO,, SO, (khéng cin sin phdm khit khdc). Cho Y téc dung vita di véi dung dich Ba(NO, ), duigc dung dich Z.va 9,32 gam két tdia. C6 can Z duge chét ran T. Nung T dén khéi ligng khéng déi, thu duige 2,688 Itt (dktc) hn hgp kht (cé ti Kh6i so véi H, bang 19,5). Gi trj cha m gan gid tri nao nhat sau day? 30. B25. 6.3.5. D.4,0. Huéng din: MgO Mg. aed ae omg. ni o smgy-co onal. ti0 Cu,S, 0:0,3m y—202) 5 BaSO, :0,04.mol Dung dich chtia Ma M(NO,), "4M +2NO, +0,50, ——— Z:1Na* e294" Pee ae No; NaNO, —"> NaNO, +0,50, ee, 5c 2,5a+0,5¢ 2, a=0,03 108a +16 =4,68 — |b=0,09 a oe ie NO, :0,02 Z:{Na® :0,09 = Y:4 00 *"” bs NaNO, :0,09 = 0,03.mol40 2" e NO; :0,07 $0, 10,01 NO; :0,15 SOF :0,04 = H,SO, :0,04.mol Bio toan mol hidro suy ra mol nude: ny. = 0,025. Bao toan Khéi lugng ta c6: m+0,04.98 +0,09.85 = 4m + 0,02.46 + 0,01.64+0,04.18 1,09 = 3, m Dap an A, Ts]DS ae Hén hgp X gém Fe,O, CuO va Al, trong 46 khéi lugng oxi bing 25% khdi lugng hén hop. Cho 0,06 mol khi CO qua m gam X nung néng, sau mt thdi gian thu duge chat rin Y va hén hgp khi Z gém 2 khi cé s6 mol bing nhau, Hoa tan hoan toan Y trong dung dich HNO, loang du, thu dugc dung dich chéia 3,08m gam mudi va 0,04 mol khi NO (san phim khit duy nat). Gid tri cita m gin bing A948 g B.OSlg C9778 D.9,02g 1 Huéng din: Fe,0, re Cu}:0,75m| gacmnaico {CO:0,03 mg4 Cud |—>mg. a 7 Al CO, :0,03 (0:0,25m Fe Sub :0,75: (0,75m:k1 ting.d] CPi 75™ | ane, og 17M +NO :0,04.mol Al NO; :2,33mg 0:0,25m-0,03.16 Bao toane 0,25m ~0,03.16 2,33.m, 8 62 +0,12= 15,Sm-29,76+59,52=18,64m = m=9,477 Dap an A a, yg +2g =Nyy, Khi cho 39,2 gam hén hgp M gém Fe, FeO, Fe,O,, Fe,O,, CuO va Cu (trong dé oxi chiém 18,367% vé khdi luong) téc dung véi lugng du dung dich HNO, néng 46 a mol/! thi thé tich dung dich HNO, tham gia phan ting 18 850 ml, Sau phan ting thu duigc 0,2 mol NO (san phim kit duy nhat cta N“), Gid tri cia ala A.20. B.1,0, C15. D.3,0. | Hudng dan: Fe, FeO, Fe,0,, Fe,0;, CuO Cu baie 39,2 on eee jus gam.) Cu:b 0:0,45.mol S6a+64b=31,2.g Nypo, = 0,858 = 4M +2.y = 4.0,2+2.0,45=1,7 = a=2, Dap an A Hén hop X g6m Al, Fe,O,, Fe,O,, CuO trong dé oxi chiém 25,39% kh6i lung hén hop. Cho m gam hén hgp X tac dung véi 8,96 lit CO (diéu kién tiéu chudn) sau mot thai gian thu duige chat rin Y va hin hgp khi Z 6 ti kh6i so vi hidro la 19. Cho chat rin Y tée dung véi dung dich HNO, loang dui thu duigc dung dich T va 7,168 lit NO (diéu kign tiéu chun, sin Poephim khit duy nhat). C6 can dung dich T thu duige 3,436m gam mu6i khan. Gia tri cita m gin v6i gid tri ndo sau day nhat? A425 B.350 6.385 D.405 Huéng dan: Fe ‘Al, Fe,0,, Fe,O,, CuO :0,7641m| copema , [CO:0,15 ——>mg.4| Al S00, %60 = 25,39 CO, :0,25 (0:0,2539m Fe :0,7641m Al 0:0,2539m—0,25.16 Fe e +0, 7641 :0,7461m (x) a 0.53, 456m: (i) +NO:0,32.mol 0:0,2539m—0,25.16 NO; :2,7099m, 2 TGP 9.32.34 22MO ISIS 5,9374m= 228,16 m=38,42.8 Dap an C I BAI TAP REN LUYEN Hén hop X gém Cu, Fe,O, va CuO trong dé oxi chiém 12,5% khéi vgng hén hgp. Cho 11,2 lit kh CO (dktc) di qua m gam X dun néng, sau mét théi gian thu duge chat rin Y vahdn hgp khi Z cé ti kh6i so vi H2 bing 18,8, Héa tan hoan toin Y trong dung djch HNO3 dic, rong du thu duige dung dich chtta 2,8125 m gam mudi va 35,84 lit khi NO2 (dkte, la sin pham. Khit duy nhat). Gié tri m gin gia tr] ndo nhét sau day: A 64,1 B.57,6 C.768 D512 Hén hop M gém Al, ALO,, Fe,O,, CuO, Fe va Cu, trong dé oxi chiém 20,4255% khéi higng hén hgp. Cho 6,72 lit khi CO (dktc) di qua 35,25 gam M nung néng, sau mt théi gian thu duigc hén hgp ran N va hén hop khi X c6 ti kh6i so véi H, bang 18. Hoa tan hét toan bo N trong lugng du dd HINO, loang. Sau khi céc phan ting xdy ra hoan toan, thu duigc dung dich chifa m gam mudi (khong c6 muéi NH,NO, sinh ra) va 4,48 lit (Aktc) hon hop khf Z.gém NO va N,O. Ti khéi cia Z so v6i H, 14 16,75. Gid tri cha m gin nhit véis A118, B81. c.140, D.9%. (REZED Hon hop X gém Mg, Fe, Fe,O, va CuO, trong dé oxi chiém 20% khdi long. Cho m gam X tan hoan toan vio dung dich Y gm H,SO, 1,65M vi NaNO, 1M, thu dugc dung dich Z.cl chita 3,66m gam mu6i trung héa va 1,792 lit khi NO (dktc). Dung dich Z phin ding t6i da véi 1,22 mol KOH, Gis tri cha m a? AL24, B.28. C.36. D.32,Oe Nung m gam hén hop A gém Mg, FeCO,, FeS, Cu(NO,), (trong A % khéi ligng oxi 18 47,818%) mot thoi gian (mudi nitrat bj nhiét phan hoan todn) thi thu duge chit rén B va 11,144 lit hn hgp khi gm CO,, NO,, O,, SO, B phan ting hoan toan véi HNO, dc néng dut (thay c6 0,67 mol HNO, phan ting) thu duge dung dich C va 3,136 lit hn hgp X gém NO, va C0,(dy, 321), Cie dung hon to’n véi BaCl, du thay xudt hign 2,33 gam két tia Bit cic ki do 6 dtc, Gia tri gén nhat cita m la? AL 48 B. 33 C.40 D.42 ED 1én hop X gém Cu, FeO, va Fe,O, trong dé oxi chiém 52/305 vé khéi igng. Cho m gam han hgp X téc dung voi dd HCI du thu duge dung dich Y cé téng khoi higng chét tan la 39,42 gam va con 5,12 gam chét ran khong tan, Loc bd chat rén t6i cho dd ¥ tac dung voi dd AgNO, du thu duige m, gam hén hgp két tia va c6 0,896 lit khf NO (dktc, sin phém khit duy nhat cia N*) thoat ra. Gia tri cla m, gin nhat voi: AOS B.15 C. 108 D. 105 [SEL Hoa tan 54,24 gam hén bgp X gém Mg, Fe,O,, MgCO, va Fe(NO,), (trong dé oxi chiém 31,858% vé khéi lugng hn hgp) vio dung dich chtta 0,04 mol NaNO, va 2,24 mol HCL. Sau khi cdc phin ting xy ra hoan to&n, thu duc dung dich Y va 0,16 mol hén hop khi Z gém 2 hi cé ti khdi so véi He bing 11. Cho dung dich AgNO, dut vio dung dich Y, két thic phin ling, thay thodt ra 0,02 mol kh{ NO (san pham khit duy nhat); déng thai thu duge 334,4 gam két tia, Néu c6 can dung dich ¥ thu duge 111,44 gam muéi, Phén trim kh6i ligng cita Fe,O, trong X gin nhat véir A.50%. B. 40%. C.60%, D. 70%, (Trich Dé Thi Thii Chuyén Ly tu trong 2015) Hoa tan hoan toan 17,44 gam hén hop gom. Fe, Fe,O, Fe,O,, CuO, Cu, Mg, MgO (trong 6 oxi chiém 18,35% vé khoi lugng) trong dung dich cha 0,804 mol HNO, loang (dui 20% so vai luigng cén cho phan ting), két thic cdc phan ting thu dude dung dich ¥ va V lit (dktc) hén hgp khi Z g6m N, va N,O (t71é sé mol tuong ting 42:3). Cho dung djch NaOH t6i du vao réi dun néng, khong cé khi thoat ra. Gid tri cla V 1a? A.0,56. B. 0,448. C.1,39. D.1,12. ED (Trich bé thi Thi: Chuyén Nguyén Hug Lan 4-2015) Hon hgp X g6m Al, Fe,O,, Fe,0, ‘CuO trong dé oxi chiém 22,74% khdi higng hén hgp. Cho m gam hén hop X tc dung voi 13,44 lit CO (digu kign tiéu chuén) sau 1 théi gian thu duge chat rin Y va hén hop kht Z c6 tikhdi so véi hidro 14 20. Cho chat ran Y tic dung v6i dung dich HNO, lodng du thu dugc dung dich T va 10,416 lit NO (diéu kign tiéu chudn, sin phém khtt duy nhét). C6 can dung dich T thu dude 3,186m gam mudi khan, m cé gié tri gin nhét la: A.40 B48 C47 D.46 [XELED (Thich Dé Thi This Chuyén Bén Tre 2015) Hén hop X gém Al, Mg,, FeO, Fe,O, trong 46 ‘oxi chiém 20,22% khdi lugng hén hgp. Cho 25,32 gam hén hop X tac dung véi dung dich HINO, du thu duge 3,584 lit hén hgp khi NO va N,O (Aktc) c6 ti kh6i so véi hidro la 15,875 va dung dich ¥. Cé can dung dich Y thu duge m gam mudi khan. Nung mudi khan néy trong. khéng khi dén khoi iuigng khong di 30,92 gam chat rin khan. Gié tri gin nhét ciia‘m la A.107 B. 106 C105 D. 103Hoa tan hét 17,92 gam hn hop X gém Fe,O, FeO, Fe, CuO, Cu, Al va ALO, (trong 45 ‘Oxi chiém 25,446% vé khdi luiong) vao dung dich HNO, loang dui, két thtic cdc phan ting thu due dung dich Y va 1,736 lit (dkc) hén hgp Khi Z g6m N, va N,O, ti kh6i cia Z so voi H, la 15,29, Cho dung dich NaOH téi du vao Y r6i dun néng, khong c6 khi thoat ra. $6 mol HNO, da phan ting v6i X 1a A075. B. 1,392. €.1,215, D.1,475. [XEEEDD #0. tan hét m gam hén hop X gém Mg va cdc oxit sét (trong dé oxi chiém 18% vé khéi Iugng) trong 300 ml dung dich HINO, 2M (diing dut 20% so vai luong cn phan ting) thu duge 0,672 lit NO (dlktc) va dung dich ¥. Co can cfn than dung dich ¥ thu duige 34,82 gam hén hop mui, Céc phan ting xdy ra hodn todn. Gia tri cia m gin nhat véi AL9. B.10, C12, De. (Trich Dé thi Thit Chuyén Lé Khiét 2016) Hn hop X gém Al, Fe,O, va CuO, trong dé oxi chigm 25% khdi htgng hn hgp. Cho 1,344 lit khi CO (dete) di qua m gam X nung néng, sau mét thdi gian thu dugc chat rin ¥ va hén hop Khi Z c6 ti kh6i so v6i H, bang 18, Héa tan hoan toan Y trong dung dich HNO, loang (du), thu duigc dung dich chtta 3,08m gam mu6i va 0,896 lit khi NO (6 dietc, la sin phém Khit duy nhét). % khdi higng ciia Fe,O, trong hén hop X gan gid tr} nao nhit sau day? A 49,2, B. 68,7. C386. D.73,5, (Trich Dé thi The THPT Thj Xé 2015) Hén hop X gém Mg, Fe,O, va CuO trong 46 oxi chiém 20% vé khéi lugng. Cho m gam hén hop X tc dung véi 0,1 mol khi CO, dun néng, sau mot thi gian thu duge chit rin Y va hén hgp khi Z gém 2 khi cé ti khéi hoi so v6i H, 8 18. Cho chat ran Y phan ting hoan to&n véi dung dich HNO, du, thu dutge dung dich D va 24,64 Iitkhi NO, (san phém khit duy nbat & dtc). C6 can dang dich D thu duige 3,9m gam hén hop mu6i khan, Gia tri cla m la A48. B.60. C.40. D.35. Hoa tan hoan toan m gam hén hop X gém FeO, Fe,O,, Fe(OH), FeCO, (trong dé Fe,O, chiém 25% s6 mol hén hgp) bing dung dich HNO, dui, khi phan ting hoan toan thu duige dung dich ¥ chtta (m + 284,4) gam mudi va 15,68 lit (dtc) hén hop khi Z gém NO va CO,. ‘fi kh6i cia Z so véi H, bang 18. Biét N Ola sin phNm khit duy nhat clia N +5. Gid tri cha m Ia AL151,2. B. 1028. 6.786. D. 1996 HUGNG DAN: c re 9, Fe 0,875 :0,875.m mg4o 2? >} cu cud 5 %O =0,125m peterccd coos 10 0,2 |CO, :0,3 Fe Fe 0,875. :0,875.m Y: () 7 BS 52,8125 m. (a) +NO, :1,6.mol O=0,125m—0,3.16 NO; :1,9375m 5 025m=0,3.16 |g _ 49375 8 62 97, 75m = 496 => m=64 Dap in A 45,25 gam. {Ab ALOn Fe,Oy, CuO, Fe , Cu 5,25 gam, Ba) 960 = 20,4255% Fe Cu |:28,85 | coos, [C0:0,15 — , Al CO, :0,15 (O=0,45.nol) 2 =0,15.3+0,05.8+0,3.2=1,45 = m=117,95 Dép an A (0:0,2m (Mg, Fe, Fe,0,,CuO Mg %0 = 20% Fe |[:0,8m Cu —ERosv > 3:66m.Z + NO: 0, 08.mol+H,0 bao ton kh6i lugng tinh ra khéi Ivgng nude m+161,7V +85V = 3,66m+0,08.30+ my, > myo = 2,66m+2,4~246,7V Dung dich sau cing chita Kt 31,22 Nat :V a BAM yn... = V—122+2,3V+0,08=3,3V—1,3 SOF :1,65V teas! 1,22-2,3VPhan chia nhiém vu H* 0,2m 3,3V =2- 161 01 084-+108,37 —1,3) = 29,7F + 0,025m = 12,68) ‘Trong dung dich Z 06 chita (Fe, Cu, Mg): 0,8 Nat :V 3,66m :4SO% :1,65V = 3,66m NO} :1,22-2,3V NH} :3,3V-13 => 3,66m = 0,8m +98, 2V +52.24 = 2,86m—98, 2V = 52,24 B6m~98,2V=52,24 | }0,025m+29,7V =12,68(1) V=0,4. Dap énD co, Mg, FeCO,, FeS, Cu(NO, e NC mgd’ 3» FeS, Cu(NOs),| + 40,4975 mot} NO: %O = 47,818%) oO, SO. = nf =0,955.mol = mp =15,92 0,14.mol *{ 321 giao ( Ye 14 ) C téc dung hoan toan véi BaCl, du thay xuét hién 2,33 gam keét tia. NO, :0,13.mol ) CO, :0,01.mol Bef Beem oy f mol C--*2-+BaSO, :0,01.mol = n§,,. =0,01.mol Néu trong C khong c6 NH; ta cé 0,6; => Dim, =3,12+15,92=19,04 15,92 33,29 127a+135b=33,58 HCI:0,16 56a + 64b— 25> ae - 017m = }16a+16b-=—m =0 athe 05 a 127a +1356 =33,58 AgCl: 0,68 FeCl, :0,19 Ho = 105,144 (e :0,07 7 ™ 8 39,42 gam:4 CuCl, :0,07 HCL:0,16 17,44gam :}Cu, Mg, MgO Bat mal ENO yy Fe, Fe,O,, Fe,0,,Cu0 >, Cu, Mg) :14, 24. {cs Cu,Mg) g YO = 18,35% 0:0,2.mol _JNs:28 “|N,0:3a Phan chia nhiém vy HI": 0,804 :1,2 = 0,2.2+ 2a.12 +3a.10 = a = 0,005 ny, =5a=0,025 => V =0,561. Dap an A mex JF FEO, CO] consan yy 4 2, fOO:MS * (260 = 22,74 CO, :0,45 Fe \ 0.7726. a: y:}feu 779" 5 3,186m:4{ Cu (0:0,2274m -0,45.16 NO} :2,4134m |: 0,7726.m +NO: 0,465Bao toan mol ¢ 0,2274m=0,45.16 | 9 ges 5 _ 24134m 8 62 © 5,2084m = 245,52 = m=47,14, Dap an 25,32 gamX { 0:0,32.mol :0,32.mol dung dich Y Al,Mg, Fe): 20, 2.4 if I, Mg, Fe}: 20,2. (ALMg.Fe):20,26 y [(ALMg.Fe):20,28 NO; (0:0,67.mol ‘Al, Mg , FeO, ees) {amen 20,2. NO :0, mo, vf 0,14 tho, =h34 Ryo, = 134 = 2.0,32+3.0,14+8.0,02 + 8.25, n0, = Byayyo, = 05015 0, 2+1, 34.62 + 0,015.80 = 104,48, Dap an C rng2{EncwadeT3Ke a ht; ,065 }0:4,56.g N,0:0,0125" Dyyyo, =2My H12ny, +10.ny,o =1,475.mol. Dap an D > Cau tT ig :0,82.m. [ mg: (r } ML wvos98 NO :0,03.mol-+34,82 gam: 0:0,18.m ‘Tu duy phan chia nhién ve H 0,18m_ 0,6:1,2= 240,03.4+10.24,n0, 0,18m 0,38 10 M ( 8 } 0,82.m. Fe es :0,0045m +0,394 } = Dynx0, = 38-0,00225m 34,82 gam NH,NO, :0,038-0,00225m _0,18m 240,03.34 8.0.0, = eign 2+0,03.3+8- =0,0225m + 0,09 +0,304—0,018m = 0,0045m+0,394 0,38- Mg 0,82. Fe ] ™ No; NH,NO, = 0,919m +27, 468 = 34,82 => m=8 0,18m_ . Dap an AMega book 7 Al, FeO, im J(ALCuFe):0,75.m| coo, m, — ey *1 cao, 0:0,25m CO, :0, (AL,Cu,Fe):0,75.m) NO} :2,33.m Cu, Fe) :0,75. Z (Al,Cu, Fe):0,75.m 8253, 08m. 0:0,25m~0,03.16 025m O86 4 0,043= 233 o> 3,14m=29, 76m = 9,477 |-so-oa 8 Alia 21a+2320+ 640 =9,477 9,477.4 Fe,0, ib} {0a+4b-+0=0,148 Cud:c | [3a+9b+20=0,356 046 = |b =0,016= %mgzo, =39,16%. Bap an C © =0,083, Mg X:1 Fe,0, oe sen pies i per ae 0:0,2.m 04 Mg,Fe,Cu):0,8. /Mg,Fe,Cu) :0,8:m (Me.Fe.Cu):0,82| ae om gam: | MEF) +NO:1,Lmol 0:0,2m-0,05.16 NO} :3,1m 2.2m 0005.16 41) AE 12,4m = 496 m= 0g. Bap an C FeO Ea Fe(OH), |" €,0, NO:0,4 —]Fe0,:b | 5(m + 284,4 ¥+0,7mol) 00" Fe(OH), 2,0, (m ) gama. + 0,70 {ees FeCO, :0,3 FeCO, El 03 i225 (m + 284,4) gana +0,1m01{ EEE atb+0,3 a+b+0,3=0,4.3=9a+b=0,9 = 0,25 =>a+b+0,3= 4b => a—3b=0,3 =3b=0,3_ [a=0,75 fe erent + 284,4):{Fe(NO,), :a+3b+0,3=1,5=9 m= 78,68 Dap an C(Trich Dé Thi Thi SGD Quang Nam -2016) Hoa tan hét 3,264 gam hén hop X gém FeS,, FeS, Fe, CuS va Cu trong 600 ml dung dich HNO, 1M dun néng, sau khi két thiic cdc phan ting thu duge dung dich Y va 1,816 lit (dktc) mét cht khi thoat ra. Cho Y téc dung v6i lugng du dung dich BaCl, thu duge 5,592 gam két tila, Mat khdc, dung dich Y cé thé héa tan t6i da m ‘gam Fe. Biét trong céc qua trinh trén, sin phim khit duy nhét cita N** la NO. Gié tri cha m la A. 11,256. B.1L712, €.9,760, D.9,120. Mm Huéngdn: 7 én X vé 3,264) Cub Sa tna a a 286 ),024 oe 3a+2b+0,024,6=0,084.3 0,018 Fe :0,024 Cu* 20,018 NO; :0,402 Dung dich ¥ chifa | 8™"_ NO; :0,516 — 3} SOF :0,024 SOF 0,024 Fe™ :0,225 PPL HT :0,456—S on}, = 0,114 BEE m=56(0,225—0,024) = 11,256, Dap an A (Irich Dé Thi Thit THPT Chuyén Tuyén Quang 2016) Héa tan hoan toin 30,4 g chat ran X gém Cu, CuS, Cu,$ va $ bing dd HNO, dut, thay thoat ra 20,16 lit khi NO (sin phéim khit duy nhat, 6 dkte) va dd ¥. Thém dd Ba(OH), du vao Y dug m gam két tita. Gia tri m gn nhat Vi gid tri nao sau day? A119 BLS cal D2 m Huéng dan: cu ca. a 30,4.gX:4 CuS Hansel’ 7 [mono 0,9.mol Cu,s ae 4 { = > |20-+6b=0,93 Cu 20,3 SO} :0,35| saa mor, 7 NO; b=0,35 BaSO, :0,35 > Cu(OH), :0,3 m=110,95.g. Dap nCcasa’ Hoa tan hét m gam FeS bang mot lugng tdi thiéu dung dich HNO, (dung dich X), thu duige dung dich Y va khf NO. Dung dich Y hda tan t6i da 3,84 gam Cu. Biét trong céc qué trinh trén, sin pham khit duy nhat cba N +5 déu la NO. $6 mol HINO, trong X la A.0,48. B.0,12. €.0,36, D.0,24. 1 Huéng dan: FeS +4H" +3NO; +> Fe” +SO{ +3NO+2H,0 a—>4a Cu+2Fe*——> 2Fe* + Cu 0,06 0,12 12 = Nyyo, = 0,48.mn01 Dap an A Hoa tan hét 2,72 gam hén hop X gém FeS,, FeS, Fe, CuS va Cu trong 500 ml dung dich HNO, 1M, sau khi két thite cdc phan ting thu duige dung dich Y vi 0,07 mol mét chat khi thoat ra. Cho ¥ tac dung véi ligng du dung dich BaCl, thu duge 4,66 gam két tha. Mat khéc, dung dich ¥ o6 thé hda tan t6i da m gam Cu. Biét trong céc qué trinh trén, san phém khét duy nbat cba “S14 NO. Gid tri cha m 1a A.9,12 B. 4,96 C.5,92 D.9,76 1 Huéng dan: Fes, Fes Feza 2,72 gam.yFe |>{Cu:b} 5 ¥ +0,07.molNO cus. S:c Cu yY—"“_,BaSO, :0,02.mol = c= 0,02.mol fe isa = 0,02 3a+2b =0,09 b=0,015 Dung dich Y chita Fe™* :0,02.mol Cu** :0,015.mol Y:)SOF :0,02 SE 150) NO; :0,5-0,07 =0,43 H" :0,38.:mol SEL 50,04+0,03+2x = 0,04+0,335 => x =0,1525 = m=9,76g Dap an D[XETED Hoa tan hét m gam hén hgp FeS, va Cu,S trong dung dich HNO,, sau khi cdc phan ting hoan toan thu duge dung dich X chi c6 2 chét tan, véi tng kh6i higng cfc chat tan la 72. gam. Gid tr] ciia m la: A.20 B.60 C40 D.80 1 Huéng dan: Fes, ee 3a+4b=4a+2b S228 | wo. 579 gamicu:2b $__4 98 F4P= 40420 89 Ls a d0.g Cu,S. 248a+224b = 72 01 ISO? :2at+b Dip an C [ENED Hos tan hét 8,0 gam hin hop X gém Fe, FeS, FeS, va FeO, vao dung dich chtta 0,48 mol HINO, dén khi cdc phan ttng xay ra hoan toin thu duigc 10,32 gam hén hgp khi NO va NO, (14 cic sin phém khit duy nbat cia N“*) va dung dich Y chi gém cc muéi va HNO, con du. C6 ccan dung dich ¥ thu duge 22,52 gam mui, Mit Khéc, khi cho dung dich Ba(OH), du vao dung, dich Y, loc két tia nung trong khong khi dén kh6i vgn khong doi thi thu dug 21,98 gam chat rn, Dung dich Y hoa tan duige t6i da m gam Cu tao khf NO duy nit. Gid tri ctia m la: A.3,68 gam B. 1,28 gam C.1,96 gam D.3,2 gam i Huéng dan: Fe Fe: Fes Se te (NO 8,0 gamX I—34S:b }—* ma ENO, 510,32 gam: +¥ Fes, . NO, se Fe,0, = 56a+32b+16c=8 Fe* sa SO; : ‘| {80} =| _ nue, , [Ba0.:b Ww Fe(OH), :a NO; BaSO, :b —£921,98 } won, 20,50 i 80a +233b= 21,98 Fe" 22,52 gam.Y :}SO} :b NO} :x.mol 56a +96b + 62.3a— 62.2 = 22,52 = 242a~28b = 22,52 [242a-28b=22,52__ fa=0,1 =0,03.mol = > 80a +233b=21,98 |b=0,06 [x =0,18.mol ‘NO:n 30n +46m =10,32 — > NO, :m 3n+m=0,1.3+0,6.6-0,03.2=0,6 Bao toan nguyén t6 nito suy ra mol NO; trong dung dich Y [562+ 96b-+ 62x = 22,52 3a-2b=x 10,32 gam {aca’ AX, =0,48-0,16-0,12=0,2 Fe :0,1 Fe™ :0,1 sor :0,05| ...,, [S02 806 1H :0,02 ont NO; 0,2 NO; :0,2-282 =m=3,68.g, Dap én A 'Héa tan hoan toan 0,10 mol FeS, vao dung dich HNO, dic, néng du thu duge khi NO, va dung dich X. Xéc djnh s6 mol HNO, da phan ting, Biét ring Fe va S trong FeS, bj oxi héa dén s6 oxi ha cao nha. A.14 mol B.1,6 mol C.1,8 mol D.1,5 mol @ Huéng dan: Bao toan mol e ta cé 0,1.3+0,2.6= Myo, =1,5.nol Dung dich thi dugc sau phan ting Fe*:0,1 SOF :0,2 => Myo, =Myo, = 155 Ht :0,1 Dap inD [XELED Hoa tan hét m (g) chat rin A gém Fe, FeS, FeS, bing dung dich HNO, dc, ndng. Sau phan ‘ing thu duigc 13,44 lit kh mau nau duy nat va dung dich Y. Cé can dung dich Y, ly mot phan chat khan hoa tan trong dung dich HCl thu dugc dung dich Z. Cho it bot déng vao dung dich Z, dun néng, khOng cé khi thot ra, Gid tr} gén nhét cfia m la A622. B.3.24. C612, D.5,22. Huong dan: Fe Fe:a] iw, A:tFeS: —{s | 25.0, oma FeS, 7 => 3at6b=0,6 3 aa JF __439-2b=0 SO? :b 3a+6b=0,6 _ [a=0,05 = >m=5,2 3a-2 b=0,075 Dap 4n D Ps J]Hoa tan hét 14,88 gam hn hgp X gém Fe, Fe,O, FeS va FeS, (biét trong X huu hujnh chiém 23,656% vé kh6i htgng) trong dung dich chtta 0,8 mol H,,SO, (4c, dun néng), thu duige V lit SO, la sin phém khit duy nhit (dktc) va dung dich Y. Cho 0.48 lit dung dich NaOH 1M vio dung dich Y thu duige 8,56 gam két tia. Biét cdc phan ting hon toan, Cho thém nuéc dit vio Y 16i cho Fe vao thi khéi Iiiong Fe phén ting ti da la AL1L2 B.11,76 C1344 D. 14,56 Wt Huéng dan: Fe:x+y Fe, FeO, Fe,O,, Fe,0,, FeS , FeS, 14,88. gam. * 514,88 gam:40:2 %S=23,656% )LLmol 56x + S6y +162=11,36.8 Két tha la Fe(OH), :x.mol > x = 0,08.mol Dung dich sau Cing la [Na* :0,48.mol Fe™: Mt 0, 48+ 3y = 1,82—2a = 3y +2a = 1,34 so (so, = Bao toane ta cd 3.0,08+3y+0,11.6=22+2a=>~3y+22+2a=0,9 ~3y +22+2a=0,9 O1 3y+2a=1,34 => 4z=0,08 S6y +162 = 6,88 a=0,52 Dung dich ¥ chifa Fe’ :0,18 mol ters SOF :0,39molh}—Besa5 JFE”FOISFP MOM Lo ig 0,39 SOF :0,39 HY :0,24 mol b=0,21> m=11,76g Dap 4nB BAI TAP RENLUYEN Hoa tan hoan toan 8,0 gam hh X gém FeS va FeS, trong 290 mi dd HNO, a mol/l, thu dug khi NO duy nhdt va dd ¥. Dé téc dung hét vdi céc chat trong dd Y cin 250 ml dd Ba(OH), 1M. Két tia tao thanh dem nung trong khong khi dén khéi ligng khong déi dug 32,08 gam chat rin Z. Gid tri cliaa ls A120 B.162 C103 D.2,00cra’ Cho 18,4g hén hgp X gém Cu, Cu,$, CuS, Fe, FeS, $ tac dung hét vi HNO, dac néng, dit thu duge V lit khi NO, (chat khi duy nhat thost ra, san phdm khii duy nhat, dktc) va dd Y. Cho Y tac dung voi dd BaCl, du thu duige 46,6 gam két tia, con khi cho ¥ tic dung voi dd NH, thi thu duge 10,7g ket ta. Gia tri cita V Ia: A. 24,64 B.11,2 C.168 D. 38,08 [XETED Nung hin hop gém 5,6 gam Fe va 3,2 gam Cu véi 5,76 gam S dén khi phan ting hoan toan, thu duige chat rin X. Cho toan b6 X téc dung hét voi dd HCI du, thu duge khi ¥. Thé tich dd Pb(NO,), IM t6i thigu cin diing dé hap thy hét kh ¥ 1a A.120ml. B. 180 ml. C. 150 ml. D, 100 ml. H6n hop ran A gém FeS,, Cu,$ va FeCO, c6 khéi lugng 20,48 gam. Dét chay hén hop A ‘mot thai gian bang oxi thu duge hén hgp ran B va 2,24 Itt (dktc) hén hgp khf X (khong cé ©, du). Toan bé B héa tan trong dung dich HNO, dic, néng, dui. Két thc phan ding thu duge dung dich ¥ va 13,44 Itt (dktc) hén hgp khi Z g6m 2 khi (khong o6 khi $O,) va dung dich Y. Cho Ba(OH), du vio dung dich ¥ thu duige 34,66 gam két tia, L4y két tia nung ngoai khong. khi dén khdi ligng khéng d6i thu dude 29,98 gam ran khan. Biét ring ti khi cia Z so voi X bang 86/105.Phin trim khéi lugng FeS, trong AR? A. 35,16% B.23,44% C.17,58% D. 29,30% Hoa tan hét 50 gam hén hop X g6m Fe, FeO, Fe,O,, Fe,O,, FeS va FeS, (biét trong X lvu hujnh chiém 19,2% vé khéi lurgng) trong 105 ml dung dich H,SO, 20M (dic, dun néng), thu duigc a mol khi SO, la sin phdm khit duy nat va dung dich Y. Cho 0,947 lit dung dich NaOH, 1M yao dung dich Y thu dutgc 16,05 gam két tita. Biét céc phan ting hoan toan. Gid tri cia ala: A128 B.1,26 C132 D134 Cho m gam hén hop X g6m MgO, CuO, MgS va Cu,S (oxi chiém 30% khéi ligng) tan hét trong dung dich H,SO, va NaNO, thu duigc dung dich Y chi chtfa 4m gam muéi trung hoa va 0,672 lit (4ktc) hén hgp Khi gém NO,, SO, (khéng cin sén phém khit khéc). Cho Y tée dung vita dii véi dung dich Ba(NO,), dug dung dich Z.va 9,32 gam két tha. Cé can Z duige chat ran ‘TT. Nung T dén khéi lugng khong d6i, thu dugc 2,688 lit (dktc) hn hgp khi (c6 ti khéi so véi H, bing 19,5). Gié tri cita m gan gid tri ndo nhat sau day? A30. B.2.5. C35, D.40. ‘Hoa tan hoan toan hén hgp gém 0,1 mol FeS, va x mol Cu, vao axit HNO, vita dit, thu duge dung dich X (chi chita 2 mu6i sunfat) va khi duy nbét NO. Gid tri ctia x8 A.0.04 mol B.0.05 mol €.0.12 mal D.0.06 mol Hoa tan hoan toan 30,4 gam chit rin X gém Cu, CuS, Cu,S va S bang dung dich HNO, du, thay thodt ra 20,16 lit NO (dktc) va dung dich Y. Cho dung dich ¥ téc dung véi dung dich. Ba(OH), du thu duge m gam két tia. Gid tri cia m la A. 110,95 B.81,55 C.89,54 D,94,23ED Hon hop X gém FeS, va MS (ti Ig mol 1:2; M la kim loai o6 s6 oxi héa khong déi trong cac hgp chat). Cho 71,76 gam X tac dung hoan toin véi dung dich HNO, dic, néng thu diige 83,328 lit NO, (kte,san pham khit duy nhat). Thém BaCl, dui vao dung dich sau phan ding trén thay tach ra m gam két tia, Gid tri céia m la: A.178,56 gam B. 173,64 gam . 55,92 gam D. 111,84 gam Cho 18,4 gam hén hop X g6m Cu,S, CuS, FeS, va FeS tac dung hét voi HNO, dac néng, dui thu duge V lit khi chi c6 NO, (6 dktc, sin pham Khit duy nhét) va dung dich ¥. Cho toan b6 Y vao mot luong dui dung dich BaCl,, thu dutgc 46,6 gam két tia; con khi cho toin bd Y tic dung véi dung dich NH, du thu duge 10,7 gam két tia. Gi tri ola V8 A112 B. 38,08. C.168. D. 24,64, EID 1 éy 5,2 gam hin hgp FeS, va Cu, téc dung hoan toin v6i dung dich HNO, thi thu duge dung dich chi chia 2 muéi va 12,208 lit hén hgp NO, va SO, (dktc). X4c dinh % vé khdi lugng, iia FeS, trong hén hop ban déu A.71,53% hoe 81,39% B, 93,23% hoc 71,53% C. 69,23% hoc 81,39% D, 69,23% hose 93,23% Hoa tan bén hgp chia (Fe,O,, a mol FeS, va b mol CuS) bing axit HNO, dic, néng. Sau phan ting hoan toan thu duige dung dich A (chi chita 2 musi sunfat) va V lit (NO, NO, tilé mol 1:1) do & dktc. Hay tim méi ign hé gitta V va a, b? i y= SPB Des S08.4b 7 y = 12 2a B08.4b c y= ASA2a 1612.8 D v= SO Aa 606 4 [XEDEED 2 6t chay hoan toan m gam FeS, bing mt lugng oxi vita di, thu duge khi X. Hap thy hat X vio 1 lit dung dich chita Ba(OH), 0,15M va KOH 0,1M, thu duoc dung dich ¥ va 21,7 gam két tia, Cho Y vao dung dich NaOH, thay xudt hién thém két tita, Gid tri cdia m la A.23.2g B.126¢ C18 g D.24g [XEDEED Ho! tan hoan toan 8,0 gam hh X gém FeS va FeS, trong 290 ml dd HNO, a mol/l, thu duige khi NO duy nbit va dd Y, Dé téc dung hét vdi céc chat trong dd Y cén 250 ml dd Ba(OH), 1M. Két tia tao thanh dem nung trong khong khi dén khéi lugng khong d6i duge 32,03 gam chat ran Z. Gid tri ctiaa li: A120 B. 1,62 C.1,03 D.2,00 [ED Cho 4,368 gam bét Fe tic dung vdi m gam bét S, Sau phan ting duge rin X. Toan bo X tan hét trong dung dich HINO, loang du: duigc sin phdm khti duy nhat la 0,12 mol NO. Gid tri ma A. 0,672 gam B.0.72 gam C. 1,6gam D.1,44 gam Hoa tan hoan toan hén hop gém FeS, va Fe,O, bang 100 gam dung dich HNO, a% (vita ii) thu duige 15,344 lit hn hop Khi gdm NO va NO, (dkte) c6 khéi hugng 31,35 gam va dung dich chi chita 30,15 gam hén hgp mudi (khong c6 mudi amoni). Gia tri cla a gin nit voi? A.57 B.43 C.46 D.63Mega book Hén hgp X g6m FeS, FeS,, CuS tan viia hét trong dung dich chtta 0,33 mol H,SO, dac sinh ra 0,325 mol khi SO, va dung dich Y, Nhiing thanh Fe ning 50 gam vao Y, phan ting xong thay thanh Fe nang 49,48 gam va thu duige dung dich Z. Cho Z phan itng véi HNO, dic, vita dit sinh ra khi NO, duy nhét va con lai dung dich E (khong chtia NH,"). Khéi higng mui dang Khan ¢6 trong E la m gam, Gia trj cia m li: A. 20,57. B. 18,19. €.21,33. D.21,41. [XELELD Cho m gam FeS, tac dung voi dung dich H,SO, dac néng dui thu duge V lit SO, (dlc). Hap thy V lit SO, nay vao 400ml dung dich hn hop NeOH 1M va Na,SO, 0,25M thu duce dung dich Y chita 2 muéi cé tilé 6 mol NaHSO,:Na,SO,=2:1. Gid tri cita m la AAS B.56 C.21,0 D.84 ‘Nung m gam hén hgp A gém FeS va FeS, trong binh kin chtta 1 mol khéng khé (trong Khéng khi cé 20% O, vi 80% N, theo thé tich), 3én khi phan ting xay ra hoan toan thu duge chit rin B vi hén hop khi C (84,74% N,, 10,6% SO, va 4,66% O, theo thé tich). Gié tri m gén gid tr] nio dudi day nhat? A800 B.75. 6.990. D835. Hoa tan m gam hén hgp X gém Fe, FeS, FeS, va S vao dung dich HNO, dac, néng thu ‘ui dung dich Y (chong chita muéi amoni) va 49,28 lit hén hgp khi NO, NO, nang 85,2 gam. Cho Ba(OH), du vao Y, ly két tia nung trong kh6ng khi dén khéi higng khong di thu diige 148,5 gam chat rin khan. Gid tri ciia m la A384. B. 24,8. C274. D.9,36. Hén hgp X gém a mol Fe, b mol FeCO, va c mol FeS,. Cho X vao binh dung tich khong cau FeS: Feta soos n(or),025_, [BaSO,:b ]Fe8_ moo yy _mion).0as Fes, S:b Fe(OH), : é BaSO, :b [56a +32b=8 a =0,08 532,03 gam = Fe,0, :0,5a 80a +233b=32,03 |b=0,11ead Ba” :0,14 mol ,28 mol Dung dich cusi coal a ys: Bao toan mol e suy ra mol NO 3.tyo = 0,08.3+0,11.6 = Nyy = 0,3 Bao toan mol nguyén t6 nito suy ra mol HNO3 ),29a = a=2 cu head Fe:a 18,4g:{ CUS 518,49 1 Cub} 4 Y => 56a464b+320= 18,4 Fe ae FeS q 8 y—5BaS0, 0,2 > ¢ Y—“5> Fe(OH), :0,13 a=0,1 Hoc sinh cén biét két tia Cu(OH), tan trong NH, du ‘Cu(OH), +4NH, —3[Cu(NH,),](OH), ,1.3+0,1.240,2.6=1,7 > V=38,081 Dap én D. Khi phan ting v6i dung dich Pb(NO,), la khi HS H,S+Pb(NO,), —>PbS+HNO, Nuys = Nese,» Xéc dinh mol H,S Khi nung hén hgp Fe:0,1 mol (CuS: 0,05 mol ‘Cu:0,05 mol} >} FeS:0,1 mol. —#4H,S:0,1 mol [S:0,18 mol 'S:0,03 mol Hoc sinh cén cha ¥ CuS_khoong tan trong HCl = V=0,11=100 ml, Dap an DFeS, :x 20,48 gam A:{ Cu,S:y }-—29B+X FeCO,:z Xéc dinh dude hén hop khi X gém SO, va CO, Oa: fOr Sabb Odea 1-6 My —A4G.1=) + 64b _ 4.44206 Ol OL Bla hén hop rén gém B:{FeS,, Cu,S ,FeCO,,CuO, Fe,0, }—®"-5 TZ :0,6 mol Dung dich ¥ gém BaSO, 4 BaSO, YY: BE, 34,66 g } Fe(OH), Lx +z}—"529,98 gam Fe,O, :0,5x+0,5z Cu(OH), L:2y CuO: 2y => 51x+51z-+68y—24x—24z—32y = 34, 66-29,98 = 4, 68 ena = h120041162-+160y = 20,487? 27 08 3x4 4y =0,28 mol Xéc dinh duge Z gm NO, vi CO, 0,6 mol Z:©02#,08-O.14B=b-0,02 _ yy _ Moo, Ho, _ Ab —0,88:428,52— 46 NO, :0,6-b+0,02 =0,62—b 06 0.6 Ab +27,64 0,6 Ti Khoi cita Z so véi X bang 86/105 M, _-20+27,64 0,186. Mx, 0,6 4,4+20b 105 =2b+27,64 _ 86 = OTRO =. € 10530b = 631,8 => b = 0,06 = a = 0,04 26,4+120b 105 eg x= 0,04 28.mol = Ym, = 23,44% 107x-+196y =34,66~0,06,233~0,08.107 =12,12” |y=0,04 Dap an B 50 gam {F® P60, Fe,0s, Fe.O,, FeS,FeS, oo Be fee %S=19,2 eee) e $:0,3 mol 56x + 56y +16z.= 40,4 gKét tia la Fe(OH), : x mol => x =0,15 mol Dung dich sau cing 1a Nat :0,947 mol Fe* :ymol Bt 0,947 +3y = SO}: => 3y +20 =3,853 4-3 Bao toan e ta c6: 3.0,15+3y+0,3. -3y+2z+2a=2,25 [y=0,431 22a => ~3y+ 22+ 2a = 2,25 By+2a=3,853 > 42=0,4915 Sy +162 =32 a=1,28 Dap én A xr ‘MgO, CuO, MgS Cu,S|_ NO. ig0, CuO, Mgs | e-em gm s005m0f 2 fe ota: y BOO), BaSO, :0,04 mol Xéc dinh ran T: so, /M(NO,), —->MO +2NO, +0,50, fo oe. |a—_ >a 2a 0,5 ty 7 NaNO, NaNO, —> NaNO, +0,50, b——+b —0,,5b 2,5a+0,56=0,12 0,03 = = 108a+16b=4,68 ~ |b=0,09 Xéc dinh céc chat 6 trong ¥: SOF :0,04 NO; :0,07 [MgO, CuO, MgS, Cu,S mgX: 240 = 30% m+98x+7,65=4m+1,56+18x = 3m-80x = 6,09 —¥250,3m + 4x.16 +0, 09.3.16 = 0,04.4.16+ 0,07.3.16+0,03.32 +16x 0,3m+48x =2,56 feciuceer fala = ‘NO, | Hise am gam Y +0,03 mol { 50, +H,0:x mol 3m—80x = 6,09 Dap an AFe :0,1 0,1 mol F molFeS: ne, lou+:2n LM 50,34+4x=0,442x = x= 0,05 x mol Cu,S : SO} :0,24x Dap én B 30,4 gam {° CuS, Cu,S —4530,4 gam {oy} ee veno:09 1,3 =0,35 4y_tions_, [B280, :0,35 mol |Cu(OH), :0,3 —, [48-4320 =30,4 2a+ 6b =0,9.3 = m=110,95 g, Dap in A aud Fe:a Fes, 8281 71,76 gam X 4M:2a$—™ NO, :3,72 MS:2a a a =) 3a+2a.2+406=3,72= a=0,12=M:Pb BaSO, :0,48 mol = = PCI, :0,24 mol m=178,56g. Dap nA 7m Fea 18,4 gam {Cu:b}—™2 5 NO, :x mol+¥ IS: y—*4+BaSO, :¢ => c=0,2 mol Y—4.4 Fe(OH), :0,1 mol a=0,1 b=0,1 mol Bao toan e ta c6: 0,1.3+0,1.2+0,2.6=x = x=1,7=9 V=38,081 Dap én B Fes Fe" sa 5,2. gam {°2** | twos Foye 25 0,545 moi | NO: Cu,S:b : $0, :¢ SO? :2a+b-e 120a +160b; 120a +160! => y-a+2b42c => j-a+2b+2¢ 15a+10b=2c+0,545—c| [152 +10-c=0,545 Ymy.s, = 69,23%Se chia Fea FeS; : 5,2 oom | eee JH Cn :2b +545 mol ‘NO, :0,545-2a—b SO, :2a+b NO; : = [1208+ 1606 =5,2 = J1208+160b=5,2] _, [a= 0.0404 15a+10b = 4a +2b+0,545-2a~b] ~ |13a+9b=0,545 b =0,0022 Yorngys, =93,23% Cu,8:b Dap dn D Fe Fe" :a+3; 0,2 ef L oy amol FeS;~—M25)Cwsb Fy b mol CuS) SO? :2a+b fn 3a+9x+2b=da+ 2b x=5 a 8a 84 15a48b =4y = 2y= 28 4 4p = gtisa y= 2y= 7) _1523,2a +806,4b v 9 Ap an B FeS, —2->Fe,0, +SO, sO, “#3 5 BaSO, 0,1 mol Ba** :0,05 dd:}K':0,1 =n, =0,3 > ay, =0,15 = m=18g, HSO, :0,2 Dap an C FeS:x 8,0 gamgX: 00 NO+Y ae ft a sy OH 2s BaSO, Fe(OH), 88x+120y=8 x=0,05 = > 313x+546y=32,03 |y=0,03 BaSO,:x+2y Fe,0, :0,5x+0,5y [tom gam { oaSOF :0,11 HH’ :0,26 NO; :b mol = Nao, = Bayo; + Byo = 0,28 + 0,3 = 0,58 = 0,292 a =2 +b = 0,28 mol Dap an D ie :0,078 mol 250,12 mol NO S:amol 0,078.3+6a = 0,12.3 = a=0,021 = m=0,672g Dap an A 16 [FeS, : 7 = = 8.10 | wo. s,655moi NOX _, [R+Y= 0.685, [x =0,01 Fe,O,:b NO, :y 30x + 46y =31,35 y = 0,675 mol 15a+b=0,705 Fe™ :a+3b 30,15 gam jSOf:2a }—9x+4a=3a+9b=x=-a+9b NO}: x. 56a +56.3b+ 28.96 — 62a +9b.62= 30,15 186a +726b = 30,15 045 eae 705 -{ 0,03 0,225+0,685 = 0,91 = n= 57,33 io, Dap an A FeS Fe:a X:f FeS, }-—>{ Cu: b—2 #21 48_ 9, 325 mol khi SO, + ¥ Cus S:0 Xéc dinh dung dich Y gém ion nao Fe* sa Cu :b tt 3a + 2b = 2¢+0,01 SO} :¢+0,33—0,325= +0, 005 3a+2b-2c=0,01 Khi cho Y phan ting Feeed Fe+2Fe™* —>3Fe™* O5aca ae a: f=P56.0,5a-+56b—64b = 0,52 = 28a-8b= 0,52 Fe+Cu —>Fe™ +Cu* be—b HL 3a+2b+6e=0,65 a=0,03 Fe™ 0,085 Dung dich E chtta } SO? : 0,085} => m=18,19 g. Dap an D NO; :0,085 Xit ly mol SO, bay ra ‘NaHSO, :2: SO, :a mol SOBs FAX ane 4x = 0,69 x =0,15 80:01” 1 Na,SO, :x HS at0,1=3x=0,45 > a=0,1 m=2ig Dap anC oe [84,74%N, 84,74 mol N,, | Hib sreo,:amatses 10,6%SO, => 100 mol C: 10,6 mol SO, 4,66%0, 4,66 molO, 221,185 On #21, M2 521,185.2 = 3x +10,6.2+4,66.2 => x = 3,95 mol IN, 84,74 FeS: b=3,95.2 514 . cape oe eerie ere > m=7,8352 g, Dap an A FeS, :b[ ]a+2b=10,66 [b=2,76 x {Fes FeS, Fes, Fe: wo ,y, [NO:1 mol s sib NO, :1,2 mol 3a+6b=4,2 [BaSO, :b yy sioin_, [BaSO, Fe,0, :0,5a —24148,5 gam Fe(OH), | st0.s230-1455 {e +233b=148,5 fe > = 4 = 38,4 a 3a+6b=4,2 ib som faeeeeee aaja mol Fe b mol FeCO, }—*>{Fe,0, osas0.sbs0.seef c mol FeS, iSO, :¢ CO, :b Dé 4p sudt khong thay 46i thi mol oxi phan ting bing mol khi sinh ra 3b+n% =1,5a+1,5b+1,5c+2b+20— n?" =1,5a+0,5b+2,5¢ 9 1,5a+0,5b+2,5c=b+e = 1,5a=0,5b—-1,5¢ ), 5b = 4a+4e=3b s X:{FeS, Cu,$, Cu, CuS, FeS, —>] Fe —*%*5 50,035 mol khi NO+Y cu Y—*2-» BaSO, :0,01 mol => ng =n... = 0,01 $:0,01 Fe:x =956x+64y=1.04 Cury PAS 3x 42y4+0,01.6 oorsa—f < y=0,0075 mol Dung dich ¥ chita (Cu** :0,0075 Fe™ :0,01 SOF :0,01 S25, +019 3 -0,07625 = m=4,88 ¢ NO} :0,215 H*:0,19 Dap an C FeCO,:1 9 SO, :2 —25Fe,0, :1 mol + FeS, 1 CO, :1 In! $1.3=1342241.2=n" =3=Mg, +N,clad d 20,82 {FeS, FeS,, S—>20,8g {eB an0, :2,4 mol _» [362-+320=20,8_ fa=0.2_ 3a+6b=2,4 b=0,3 A—Y®!, Fe(OH), :0,2—> Fe,0, :0,1 mol = m=16g Dap én A i A:{Fe, FeS, FeS, {keno 20,6 mol "Tit gid thiét dé cho trong ¥ Khéng c6 NO; 3 {5 * = 3a-2b=0 SOF :b Fe:a 29,2 gam X {Sib -—ASMN 5 38,7 gam. fhe +77,98 gam mudi Y+H,O Ore ‘ 56a+32b+16c=29,2 y Biot, [BAO 95,99 gam |BASO1* _, gq 4.2336=83,92 Fe(OH), Fe,0,:0,58 Xéc dink cic ion trong dung dich Y Fe sa 77,98 180? = 56a-+96b-+186a—124b = 77,98 => 2428 ~286 = 77,98 NO; :3a~-2b '56a+32b+16c=29,2] [a = 0,35 mol 80a +233b=83,92 }=> }b=0,24 mol 242a-28b = 77,98 0,12 mol ‘NO: 30x +46y=38,7_ [x =0,6 mol 38,7 gam = as NO,:y |3x+y=2,25 y=0,45 mol Bao toan nguyén t6 nite suy ra mol NO; trong Y424 5 2d=0,3725 = d=0,18625 NO} :0,5925 Cu* sd 0,9.gam FeS, —2->Fe,0, +O, :0,0075 mol SO, :0,0075 mol—g#22 BaSO, :0,004 mol —> m=0,868g BHO) 07 Dap anB > Cau 28 Fe :0,1 0,10 mol FeS, —*2-+}SOf :0,2 +NO, :1,5 mol = nyo, =1,5 mol Dip an D H*:0,1 mol Fes, : eS, 2a : NO, 5,76 gam:4CuS:b B29 0,24 mol Y 4 6 +Z Fe(NO,), :¢ 4 120a +96b+180¢ = 5,76(1) BaSO, BaSO, :x mol ZMH 8,85 gam: 4 Fe(OH), :a+c}—"-»7,86 gam 4 Fe,0, :0,5a+0,5¢ Cu(OH), :b Cu0:b 27a +270 +18b=0,99 = 3a +2b+3c = 0,11 %O= re 100 =27,481% => m, = 2,16 = 4x +1,5a+b+1, 5c =0,135 mol atb+e=0,04 a =0,01 x=0,02 mol => }3a+2b+3c=0,11 = 4b=0,01 120a+96b+1800=5,76 [e=0,02 PMpwo, = 62.5% INO, :0,23 0,24 mol Y => My = 46,75 => dy /H, = 23,375 SO, :0,01 ‘Trong T BaSO, khéng bi nhiét phan Dap an AJeremejevite Jeremejevite von la mot khoang chat borat nhém, la mot loai da quy hiém va ft ngudi biét dén, khong mau hoac co mau xanh da trdi hogc vang nhat ch yéu xudt hién 6 Siberia, Buc, Namibia, néi Parmir 6 Tajikistan, 2 dja diém mai nhdt phat hién co khong vat nay la Myanmar va Srilanka, Jeremejevite duc phat hien béi nha nghién cuu khodng vat hoc nguéi Phap Augustin Alexism Damour va dugc dat theo tén nha khodng vat hoc ngudsi Nga Pavel Vladimirovich Ereemeev khi Ong nay tim rané tai Namibia vao nam 1883. Jeremejevite c6 thé dugc cdt va danh bong ma khong gap bat ky van dé gi, khong chiu tac dong cla nhiét a6 cao.+ Phuong phép gid: ¥ Tuong moi : Gid sit cho 0,45.mol 5 * ta khong tinh dug mol tiing khi nh ta tinh dugc tng s6 mol 2 oxi trong hén hop no, = 0,45 mol Nung n6ng hén hop chat ran A gém a mol Mg va 0,25 mol Cu(NO,),, sau mot théi gian thu dugc chat rn X va 0,45 mol hén hgp khi NO, va O,.X tan hoan toan trong dung dich chuta vita dit 1,3 mol HCI, thu duge dung dich ¥ chita m gam hdn hgp muéi clorua, va thoat ra 0,05 mol hén hgp khi Z g6m N, va H, tikh6i cia Z so v6i H, J4 11,4. Gid tri m gin nbét véi: A? B.76. ©.70. D.74, 1 Huéng din: ee > X +0,45 mol{ NO,va O, 0,25 mol Cu(NO,), +0,45 mol{NO,v’ 0, Me™ ae a 25 foe Xm 5m g aie +0,05 mol Z4 H,:0,01 +H,O:y mol tt IM, = 22,8 mol CI :1,3 mol =) a= 0,39 mol => m=71,87 g ae 6=0,45.2+ y= y=0,6 MH 4h+2y-+0,02 =1,3=9 b= 0,02 mol Dap an A Lay hén hop X gém Zn va 0,3 mol Cu(NO,), nhiét phan trong mét thei gian thu duigc hén hop chat ran Y va 10,08 Lit hén hgp khi Z gém NO, va O,, Y tdc dung via di véi dung dich chita 2,3 mol HCI thu dugc dung dich A chi chita céc mui clorua va 2,24 lit hén hgp khi B gém H, va N, c6 ti kh6i so véi H, 18 7,5. Biét cdc khi déu do & dktc. Téng khéi lung mudi trong dung dich A li: A. 154,65 gam. B. 156,10 gam, C. 152,85 gam. D. 150,30 gam. Huéng dan: fet 540,45 mal] N 0,3 mol Cu(NO,), ae oO,PO EL iad ’ L Cu(NO,), —+Cu0 +2NO, +0, icu(NO,), a———sa—sm basy,{Cv0 2 ZnO Zn440,—+Zn0 Zn Cu(NO,), CF :2,3 mol 70, H, :0,05 cud arent y pg AJOH 103 [Hs:0,05 ZnO Zn sa N, :0,05 Zo NH; :b —2a+b=1,7 mol — nf = 0,3.6-0,45.2 = 0,9 mol => nyo = 0,9 => 4b+0,9.2+0,05.2 = 2,3 => b=0,1 mol => a=0,8=) m=154,65 g, Dap dn: A ‘Nung m gam hén hop gém Mg va Cu(NO,), trong diéu kién khong co khéng khi, sau mot thai gian thu duge chit rin X va 10,08 lit (dktc) hn hop khf g6m NO, va O,, Hda tan hoan toan X bing 650 ml dung dich HCI 2M, thu duigc dung dich Y chi chifa 71,87 gam muéi clorua vA 0,05 mol hén hgp khi Z g6m N, va H,, i khéi cita Z. so véi He bing 5,7. Gid tri ciia m gin gid tr] nao nat sau day? A.50. B55. cas, D.60. © Huéng dan: Mg:amol : NO, —£5X+0,45 mol ey eee iC Hy uh sb 1 og X82 @ 571,87 g )MgCl, a+ +H,0:d H, :0,01 NH,Cl:c 2a+2b+0=1,3 Se eeeceeh 95a +135b+53,5¢ =71,87 a =f e a = {95a+135b+53,5.0= 71,87 g 4c+2d+0,02=13— 4042d=1,28. "| a3 og, 6b=0,9+d= 6b-d=0,9 a a =0,39 mol = {b =0,25 mol => m=56,36g ¢=0,02 mol Dap dn: B [XELED Cho 29,64 gam hin hyp X gém FeO, Fe(NO,),, Al, Zn trong dé sé mol Al bang s6 mol Zn tan hoan toan trong dung dich hén hgp chtia 1,16 mol KHSO,, Sau khi céc phan ting xay ra, hoan toan thu duge dung djch ¥ chi chtta 179,72 gam muéi sunfat trung héa va 6,72 lit (dkte) alKhi Z g6m 2 khi trong d6 c6 mot khi héa nau ngoai khong khi. Biét ti kh6i cla Z so vai He la 1,9. Phin trim khéi lugng cia Al trong hon hgp Xa A. 16,334%, B, 15,112%. . 13,664%. D. 14,2289. § Huéng dan: [so kK a ee NO: 0,06 mol 29,64gam {PEN ©_ emits 5179.72 90m JAP 42,28 g vm +HO:x Absa Bl H,:0,24 mol” Inia ne e Fe* Bao toan khéi ligng tinh x= 0,3 mol Bao todn mol nguyén ti hidro Ay+0,24.2+0,3.2=1,16 = y=0,02 mol Bio toin mol nguyén tit nite: 2c= y+ 0,06 = ¢=0,04 mol Bio toin nguyén tit oxi b+6c=0,06+0,3= b =0,12= a=0,15 mol omg =13,664% Dap an: C Cho 66,2 gam hén hop X gém Fe,O,, Fe(NO,),, Al tan hoan toan trong dung dich chita 3,1 mol KHSO, loang, Sau khi cic phan ting xay ra hoan toan thu duigc dung dich Y chi chita 466,6 gam mu6i sunfat trung hda va 10,08 lit (dktc) khi Z gém 2 khi trong d6 c6 mét khi héa ndu ngoai khéng khi. Biét ti khéi ciia Z so véi H, la 23. Phin tram khdi luigng cha nguyén t6 Fe trong hén hgp X gan véi gid tri nao sau day nhat? ? A, 45%, B, 40%. C.55%, D.65%. 1 Huéng dan: SO? :3,1 mol 2 eee oH 'NO:0,05 66,2 g 4 Fe(NO,), : y— SH.» 466,6 gam co { Al:z 7 NH 3b K33 Mega book —a=1,05 = b=0,05 mol = y = 0,05 mol ,05-41,05 = x=, = 224 199=54,9896~ 55%. ES 4xt+ by = pate 66,2" Dap an C Cho 7,65 gam hén hop X gm Al va Al,O, (trong 46 Al chiém 60% khéi lugng) tan hoan toan trong dung dich Y gém H,SO, va NaNO,, thu dugc dung dich Z chi chila 3 mudi trung hda va m gam hén hgp khiT (trong T'c6 0,015 mol H,). Cho dung dich BaCl, du vio Z dén khi cic phan ting xdy ra hodn toan, thu duge 93,2 gam két tha. Con néu cho Z phan ting véi NaOH thi lugng NaOH phan ting t6i da 1A 0,935 mol. Gié tri clia m gin gia tri nao nhit sau day? AL25. B.3,0. C10. D.1,5. 1 Huéng dan: __ fit = 0,17 (mol) > n, = 0,51 (mol) ae Ny,o, = 0,03 (mol) EET sn aye = 0523 BET sab =0,11 ETS 5n, =ny. =0,4(mol) AIO; : 0,23 +Z06 * Fy on anor, f2=0,095 in... =a (mol) S580 04 Fo Tg, =b (mol) Na* :a+0,935 BL 5m, = 0,23.27+0,4.96 + 0,095.23 + 0,015.18 = 47,065 0,4.2-0,015.2-0,015.4 ML nyo = : = 0,355 —2EL_47,65+0,4.98+0,095.85 = 47, 065+ m+ 0,355.18 > m=1,47(gam). Dap an: D 1, we, (Trich Dé Thi Tha Triéng THPT Dé Luong kin 1 -2016) Tron 58,75 gam hén hop X gm Fe(NO,), va kim loai M véi 46,4 gam FeCO, dugc hén hgp Y. Cho toan bé ¥ vao higng vita dit dung dich KHSO, thu duigc dung dich Z chi chita bén ion(khéng ké H* va OH’ cia HO) va 168 lit (dktc) hén hgp T gém ba khi, trong d6 cé hai kh{ cé ciing phan tit Khéi va mot khi héa nau trong khéng khi. TLkh6i cita T so vi H, ld 19,2. CO can 1/10 dung dich Z thu duigc m gam rin khan, Gid tri gin ding cfia m la A. 37,95. B.39,39. C.39,71. D. 39,84, © Hugng din: |CO,,N,0: JCO,,N,0:0,45 feet Tacé: ny nsf 2 of * __51N,0:0,05 7 NO:0,3 on, = 0,4.2+0,05.10+0,3.4=2,5 (mol) —rnquo, = 2,5 (mol)Fe+M:58,75+46,4 ~0,4.62~0,4.60 = 56,35 Vay Z chita: 1k*:2,5 —>m= BSS 39.085 SOF :2,5 Dap énB ETED Cho hén hop X gom Fe, Fe,O, va Fe(NO,), tan hét trong 400 ml dung dich KHSO, 0,4M. Bt 34 a 6 ’a Sau phan ting thu duge dung dich Y chi chtta 29,52 gam muci trang hda va 0,448 lit NO (dktc, sin pham khit duy nhét). Cho dung dich NaOH dut vio Y thi c6 8,8 gam NaOH phan ting, Dung dich Y héa tan t6i dam gam b6t Cu. Biét céc phan ting xy ra hoan to’n. Gi trj cia m la: A096. B.192. C224, D.24. 1 Huéng dan: 16 010.4 9,04 $n j.0, =0,01 Vay Y chtta 29,52: 016 arm 75 (mol) Et SO* :0,16 : INO; 0,06 Fe** :0,075 K* 0,16 ‘Cho Cu vao ¥ thi thu duge dung dich chia: ta = 0,035 Ss m = 2,24 (gam) ~ Muéi trung hda nhé cé hai mudi suanfat va muéi nitrat - Sin phéim khti duy nbét thi khong 6 NH Dap nC [XEXED Hoa tan m gam hén hop ran gém Al, Mg, Fe,O, va Fe(NO,), trong dung dich chtta 0,178 mol H,,SO, thu dugc dung dich X chi chita 22,456 gam mudi sunfat trung héa va 1,2096 lit khi NO 4 dkte, Dung dich X hda tan t6i da 0,96 gam Cu. Mat khdc, cho NaOH du vao X thi thay £6 0,376 mol NaOH tham gia phan ting, Biét cdc phan ting hoan toan. Gia tri m la: A914 B.8,240 C.8,54 D.9,62 1 Huéng dan: NO:0,054 Gok: Meio, =2A—F OF Paso, eee Va Miao, =>—290,178.2 = 0,054.4 + 103a-0,054) + 8b(1)Pe + Fe™ 20,03 HERE, Fe" 1 + 3b -0,03 Vay dung dich X chia 22,456) 7A” 10:02 @ NH; :3a-0,054 SOF :0,178 |S, Me”* :0,16—2,5a—3b [820 =0,006(mot) b=0,01 my am _0,178.2-0,006.4 0 = 0,166 ns 2 — Lym +-0,178,98 = 22,456 + 0,054.30 +0,166,18 —>m = 9,62. Dap an: D Hoa tan m gam hén bgp rin gém Zn, Mg, Fe,O, va Fe(NO,), trong dung dich chtta 0,648 mol HCI thu duge dung dich X chi chifa 36,708 gam mugi clorua va 1,1648 lit khi NO é dktc, Dung dich X ha tan t6i da 1,92 gam Cu. Mit khéc, cho KOH du vio X (dun néng nhe) thi théy 6 0,6272 lit khi mii khai (dtc) thot ra. Biét cdc phan Ying hoan toan. Phén trim khéi Iigng cia Zn trong hon hgp rin ban déu gén nbét voi: A. 19,049 B.18,24% C.26,75% D,29,32% 1 Huéng dan: yo = 0,052 EBEN Deano, =0,04mo1) ited fe = 0,028 OO Sy = 0,648. 2 028.4 EEL m + 0,648.36,5 = 36, 708 + 0,052.30 + 0,268.18 —+m = 19,44 ‘Tu duy phan chia nhiém vu cita Ht ta c6: 0,648 =0,052.4 + 0,028.10 + 8g, ——P Mya, = 0,02 (mol) = 0,268 24 Fe :0,06 EBT 5 Fe™* 0,04 NH; :0,028 [cr :0,648 Zo a Mg*:b __, f2=0.08__ 7, 0.08.65 1 2a +2b=0,36 Vay X chtia: relnnuee =26,75% . Dip an 19,44 Cho 30,24 gam hén hgp rin X gém Mg, MgCO, va Mg(NO, ), (trong dé oxi chiém 28,57% vé khéi lugng hén hop) vao dung dich chita 0,12 mo! HNO, va 1,64 mol NaHSO, khudy déu cho cée phan ting xiy ra hodn toan thu duge dung dich Y chtta cic muéi trung hoa c6 Kh6i lugng 215,08 gam va hn hgp khi Z gm N,O, N,, CO, va H, (trong dé s6 mol eta N,O bang s6 mol cia CO,). Ti kh6i hoi cia Z so v6i He bing A. Gia tri gin mhét cia a la: A68 B.7.8 C75 D.82 El1 Hudng dan: + Dung dich Y chita Mg sa Na’ :1,64 — PT 5 2a+b=1,64 | — — NHj:b EL 24a + 18b =19,92 SOF 31,64 215,08: CO, :0,06 Mg :0,68 + D8 suy ra 30,24)MgCO, :0,06 —>z: Mg(NO, ),:0,06 Hy 27 +0,68.2=0,04.8-+0,06.8 + 10x +2y fe ey 0,06.44 + 0,06.44 +-0,04.28 + 0,08.2 My My @ 4 = es He 4 Dap an a y=0,08 Cho 38,55 gam hén hgp X gém Mg, Al, ZnO va Fe(NO,), tan hoan toan trong dung dich chiia 0,725 mol H,SO, long, Sau khi cdc phan ting xy ra hoan toan, thu duigc dung dich Y chi chifa 96,55 gam muéi sunfat trung hoa va 3,92 lit (aktc) khi Z gém hai khi trong 46 6 mot khi héa nau ngoai khong khi. Bist ti khéi cia Z so véi H, 18 9. Biét Y khong chia ion Fe, Phan trim s6 mol ciia Mg trong hén hop X gin nhat véi gid tri nao sau day? A.25. BIS. C.40. D,30. Mm Hudng dan: Tacd: n, =0,175{NO™ H, :0,075 EEE 5 38,55 +.0,725.98 = 96,55 +0,175.18 + Myo Ny, = 0.55 —BEtn, Mise O02 2 = 0,05 (mol) a 4 Eso, =0,075(mol) ‘Tu duy phan bé nhiém vu cia H* ta c6: 0,725.2 =0,1.4 + 0,075.2 +0,05.10+ 2144 —Myuo = 0,2 (mol) Mg:a Alb 2da +27 =8,85 38.55 20 :0,2 S528 +3b=0,1.3+0,075.2+0,05.8 Fe(NO, ), :0,075 0,2. 39% 12+ 0,15+0,2 + 0,075es ‘Cho 20,96 gam hén hgp X gém Mg, MgO, Mg(NO,), va Al tan hoan toan trong dung dich chita KHSO, va 0,9 mol ICI loang. Sau khi cc phan ting xay ra hoan toan, thu duige dung dich Y chi chiia m gam hén hgp cdc muéi trung héa va hon hgp 2,016 lit khi Z gém HN, vi NO 6 t9 1g mol tung ting 1a 6: 1: 2. Cho NaOH dui vao Y thi thay o6 1,52 mol NaOH phan ting Hoa tan hét 16,88 gam hén hgp rin A gém Cu, Mg, Fe,O, va Fe(NO,), trong dung dich chita 0,49 mol HCl oang, dun néng: Két thite phan ting thu duigc dung dich B chi chtta 30,055 ‘gam mudi trung hoa va 1,008 lit hn hgp khi C gém NO va H, c6 téng khéi lugng la 0,93 gam & dktc. Biét trong B khong chia mu6i Fe*. Cho NaOH du vao X thi thy m gam két tla xudt hign. Gia tri ciia m la: A.20,64 B. 24,26 C.22,18 D, 26,32 @ Huéng dan: EEL 5 16,88 + 0,49.36,5= 30,055 +0,93+ my. —tty,o =0,21 (mol) NO:0.03 gece 0,49-0,015.2-0,21.2 a Hi, :0,015 Ta cé: n, = 0,01 BEL spo, =0,02 (mol) Tu duy phan bé nhigm vu cia H* ta o6:1 Huéng dan: + Dung dich Y chia Mg :a Na’ 1,64 aL. =, = 21s,os)N* 32a +b= 1,64 a=0,8 NH} :b |_PRK_ 24a +18b=19,92 b=0,04 SOF :1,64 (CO, :0,06 Mg:0,68 RE aa + Dé suy ra 30,24)MgCO, 10,06 —>Z) 7°” Mg(NO,), :0,06 22+ 0,68.2=0,04.8 + 0,06.8-+10x+2y | 22" 0,06.2 + 0,12 =0,06.2 +0,04 + 2x 0,06.44 + 0,06.44 + 0,04.28 + 0,08.2 Mz 0,24 He 4 4 Dap an A Cho 38,55 gam hén hgp X gém Mg, Al, ZnO va Fe(NO,), tan hoan toan trong dung dich chifa 0,725 mol H,SO, loang. Sau khi cdc phan ting xy ra hoan toan, thu dugc dung dich Y chi chita 96,55 gam mudi sunfat trung hda va 3,92 lit (dktc) khi Z g6m hai khi trong dé c6 mot khi hoa nau ngoai khong khi. Biét ti kh6i cita Z so véi H, la 9. Biét Y khong chiia ion Fe. Phan trim s6 mol cita Mg trong hén hgp X gén nhat v6i gid tri ndo sau day? A.25. B.I5. C.40. D.30. —| i Huéng din: Ta c6: a, BEL 4 38, 55+ 0,725.98 = 96,55 + 0175.18-+ mM, —PMy, =0,5 0,725.2 -0,075.2~0,55.2 4 05 (mol) BN np gop, = 0,075(mol) ‘Tu duy phan bé nhiém vy cia H* ta co: 0,725.2 =0,1.4+ 0,075.2 +0,05.10+ 24 —PNz40 = 0-2 (mol) Meza Al:b 2da+27b=8,85 38,55 — i Zn :0,2 PE 5204 3b =0,1.3+ 0,075.2 + 0.05.8 Fe(NO,), sy |ea [ETE cho 20,96 gam hén hyp X gom Mg, MgO, Mg(NO,), va Al tan hoan toan trong dung dich chita KHSO, vi 0,9 mol HCL Jong, Sau khi céc phan ting xy ra hodn toan, thu duigc dung dich Y chi cha m gam hén hgp céc mu6i trung hda va hdn hgp 2,016 lit khi Z gm H., N, va NO 6 t) 1g mol tuong ting 1a 6: 1: 2, Cho NaOH dit vao Y thi thy o6 1,52 mol NaOH phan ving déng thoi xudt hién 13,92 gam két tia. Gid tt ctia'm la: A,94,16 B. 88,12 €.82,79 D.96,93, Hudng dan: HL, :0,06 Ta.c6: nz =0,1)N; :0,01 —om,=1,0(gam) oy, =amol |NO:0,02 Me? : 8 Na" 21,52 AL :b i NH}: Pitt Lai c6: mygioup, =924— 94 * E841 Al; :b cr :0,9 b+e=0,62 | Ja+3b—c=0,42 HL sm =18a+27b +1380 437,71 EEL 20,96 +1360 +0,9.36,5=my +1, 0402-00624 18 a=0,08 08—+} b=0,24>m = 96,93. Dap én D e=0,38 ‘ 3-184 + 27b+8e ELD Hoa tan hét 16,88 gam hén hgp rin A gém Cu, Mg, Fe,O, va Fe(NO,), trong dung dich chita 0,49 mol HCI loding, dun néng, Két thtic phan ting thu! dtigc dung dich B chi chita 30,055 {gam muéi trung hda va 1,008 lit hon hop khf C gém NO va H, cé téng khéi htong la 0,93 gam. 6 dktc. Biét trong B khéng chtia muéi Fe. Cho NaOH du vio X thi thay m gam két tia xust hign. Gid trj céta m la: 5 A. 20,64 B. 24,26 C.22,18 D. 26,32 1 Huéng din: | E+ 16,88 + 0,49,36,5 = 30,055 -+0,93 + my My, =0,21 (mol) i Ta 06: ng =0,045)NO:003 _ ann, - 049-0.015.2-0.21.2 _ 9 } H, :0,015 se 4 i BTA nso y, =0402 (mol) . ‘Tu duy phan 6 nhiém vu cia H* ta c6: El0,49 =0,03.4+0,015.2 +0,01.10+8n.,, —?Mpyo, =0,03(mol) => Khéi higng két tia chinh 1a kim loai va OH (trong hidroxit) jK 7s ma, sengg = 16,88 -0,03.4.16 —0,02.2,62 = 12,48 PE ong = 0,49-0,01 = 0,48 ——>m, = 12,48 + 0,48.17 = 20,64 (gam), Dap dn A. Hoa tan hét m gam hin hgp gém Al, Mg, MgO trong dung dich hdn hgp chita 0,34 mol HNO, va KHSO,, Sau phan ting thu duigc 8,064 lit hn hgp khi X & dktc gém NO, H, va NO, v6i ty 1é mol tuong ting la 10: 5: 3 va dung dich Y chi chiia muéi. Cho NaOH du vio Y thi thay 6 2,28 mol NaOH tham gia phan ting, déng thai c6 17,4 gam két tia xuét hién, Phan trim ‘kh6i lugng cita MgO trong hén hp ban déu la: , A.29,41% B. 26,28% C.32,14% D.28,36% BIEN 4p, =0,34—0,26=0,08 Mg*:0,3 —. ‘NEY :0,08 bs a Lai cé: n, =0,3—9YjAP ra MO” x, ‘lO; :a eee sor b SOF :b +e 2,28+b=a+2 ,88 E35 0,4.3+0,3.2=2n, +0,2.3+0,1.2 +0,06-+0,08.8—sn, = 0,15 ae eee fos HL —>%MgO =29,41% 0,4.27 +0,3.24+0,15.16 Dép dnd [ENED Hoe tan hét 3,54 gam hén hop Al va Mg c6 tf 1é mol tuong ting la 3: 4 trong dung dich X chiia hén hgp axit HNO, va HCI, Sau khi céc phan ting xéy ra hoan toin thu duigc dung dich Y chi chtfa muéi va 2,24 lit hén hop khi gém H,, NO, va NO véi tj 1é mol tuong ting Ia 2: 1:7. Cé can dung dich ¥ thu duge m gam muéi khan. Gid tri cia m la: 17,285 B.14,792 C.18,316 D.16,145 1 Huéng din: ny, =0,02 Ta c6:3,54] 0 o.tdage, =0,01 35 oop Mae =H} M0, = yy =0,07 fone o6sen.082— 00 0,073 0,022 6 91 oy imEL aee AL :0,06 Mg?" :0,08 7 . EL, mn, =16,145 (gam), Dép an D NH} :0,01 HPT SCY : 0,35 [XETEED Cho m gam hin hop X gém Fe, Fe,O, va Fe(NO, , tan hét trong 160 ml dung dich NaHSO, 1IM. Sau phan ting thu duge dung dich Y chi chita 26,96 gam mudi trang hda va 0,448 lit NO (dite, sin phdm khii duy nhét). Cho dung dich KOH dut vao ¥ thi ¢6 0,22 mol KOH phan ting. Biét cic phan ting xdy ra hodn todn, Thanh phan phan trim vé kh Ing chia Fe trong X gin gid trj nao nhit sau day? \ \ A, 2,59%, B.3,5%. C.3,0%. ,2,0%. = Huéng din: Tacé: en : sone =e 1,06 $0, =0,01 =) VA Nyaa = 0522 EE tty, +0,16.2= 0,16 + 0,22——> 9, = 0,06 Fe Na’ :0,16 SOF :0,16 Vay ¥ chita 26,96; Fitts, = 0,075 (mol) SO EBLE 5 n,, =0,075-0,01.3-0,04 0,005 (mol) — Fe ; =2,86% Dap dn C 0,005.56 +0,01.232 + 0,04.180 Hoa tan hét 12,6 gam hén hgp Al va Mg c6 ty 1é mol tuong ting la 2: 3 trong.dung dich X chtia hn hop axit HNO, va HCL, Sau khi cic phan ting xy ra hoan toan thu dug dung dich Y chi chita muéi va 6,72 lit hin hop hai khi (trong €6 c6 m6t khi héa nau ngoai khong khi) c6 tng khéi hong la 6,2 gam. C6 can dung dich Y thu duge m gam muéi khan. Gid tri cia m I A. 57,875 B. 58,792 C.48,316 D, 52,928 Bt Huéng dan: 5 yp gf taro? Typ = 0,2 Ta c6:12,6- rg =033 By = 0, 0,05 (mol) KL my = 57,875 (gam) Y NH! 0,05 [Bt > Cr 1,25 Dap an A eal[XETHED 1362 tan hét 7,52 gam hin hgp X gém Fe, FeO, Fe,O, va Fe,O, bang dung dich chita 0,12 mol H,SO, va 0,18 mol HNO,, thu duigc dung dich Y va 0,896 lit hn hop khi Z. gsm NO va NO, ty Ié mol tung ting 1:3 (dtc, khong cdn san pham khii nao khdc). Cho Cu (du) vao dung dich ¥ thi thay 6 a mol khi NO (duy nhét) thoat ra, Gia tri ctiaa la: A.0,015, B.0,02 C.0,03 D.0,01 @ Huéng dan: —EEN_$NO; :0,14 NO:0,01 SOF :0,12 NO, :0,03 Hex Fe* :y Ta cé: o,-004{ PPL 4 x4+3y =0,38 alt 156 4160-752 —SE 5 3y = 22 +0,01.3 + 0,03 — 3y — 22 = 0,06 1,08 —sa =n. = 0,02(mol) M1 Dap nB 12 Hoa tan hét 40,4 gam hén hgp X g6m Fe va Fe,O, bang dung dich chita 0,7 mol H,SO, va 0,7 mol HNO,, thu duigc dung dich ¥ va hén hgp gém 0,1 mol NO va ¢ mol NO, (khéng con sin phém khit ndo khic). Cho Y tac dung v6i 500 ml dung dich KOH 1M, thu dtige 10,7 gam mot chat két tia, Mat Khdc, cho Y tac dung véi dung dich Ba(OH), du, thu duge m gam két tiia. Biét cdc phan ting xdy ra hoan toin. Gid tri m gn nhit véi: A.210 B.215 C.222 D.240 @ Hudng dan: han thay 56x + L6nj"™* = 40,4 —£40,7.2+0,7-0,2 = 14420420" Sx ta=18 x=0,55 +} 56x + 16n3"** = 40,4 —> 4a =0,15 ng" a =0,75 ager = 0,6 Fe(OH), :0.55 Bas, 20.7 +m, = 221,95 Dap an C Hoa tan hét m gam hin hgp T gm Al, Mg, MgO trong dung dich hén hgp chtia 0,19 mol HINO, va HCL Sau phan ting thu duige 5,824 lit hn hgp khiX é dkte gm NO, H, va N, voit?ead Jé mol tuiong ting la 10: 13: 3 va dung dich Y chi chita mudi. Cho NaOH du vao Y thi thay co 1,63 mol NaOH tham gia phan ting, déng théi cé 11,6 gam két tia xudt hign. Gi tr} chia ma: AL17,6 B. 16,4 C.14,5 D. 18,16 1 Huéng dan: xy = 0,1 Ta cé: my =0,264m, a, = 0,13 gn, = 019-016 = Lai cd: n, =0,2-—ong = AP 20,3, Dung dich ¥ chia moet _ 133+0,19-0,26-0,03.4 Ao 7 2 ES" 40,193 =0,1 40,57 on" =0,1 SEL, m =0,1.16 + 0,3.27+0,2.24 = 14,5 (gam). Bap an C [XEDED cho 23,88 gam hén hop X gém Mg, MgO, Mg(NO,), va Al tan hoan toan trong dung dich chia KHSO, va 1,12 mol HC! loang. Sau khi cdc phan ting xdy ra hoan toan, thu duigc dung dich Y chi chita m gam hén hgp céc mu6i trung hoa va hn hgp 5,152 lit khi Z gm H,, N, vi NO 6 t7 Ie mol tuong ting ld 20: 1: 2. Cho NaOH du vio ¥ thi thay cé 1,72 mol NaOH phan. ‘ing déng théi xudt hign 24,36 gam két tia. Gié tri cia m La: A. 104,26 B. 110,68 C.104,24 D,98,83 ‘@ Huéng dan: 1, :0.2 Ta cb: n, =0,234N, :0,01 NO:0,02 Mg” 20,42 Dung dich Y chia EM my = 49,84 +274 +135b+18¢ MiB#b-04~4e yg SEL, 23,88 + 136b + 40,88 = my +1,28 + eaa=0,2 27a +8b-180=7,16-—> 4 d= 0,4 c= 0,08 > = 49,84 +27.0,2 + 135.0,4 +18.0,08 = 110,68 (gam), Dap an B FED Hoa tan hét 17,6 gam hén hgp rin A gém Cu, Mg, Fe,O, va Fe(NO,), trong dung dich chiia 0,55 mol KHSO, loang, dun néng. Két thiic phan ting thu duge dung dich B chi chia 87,63 gam mu6i trung hoe va 1,68 lit hén hgp khi C g6m NO va H, 6 dkte, o6 ty kh6i hoi so v6i H, JA 6,6. Biét trong B khong chia mudi Fe*. Cho Ba(OH), dut vao X thi thay m gam két tha xuit hign. Gid tri cia m Ii: A. 120,84 B. 150,53 C.122,78 D. 146,36 mt Huéng dan: EE 417,6 + 0,55.136=87,63-+ 0,99 + Myyg —PNy,o =0,21 (mol) Ta cd: 01s Oe mnt 0,55-0,045.2-0,21.2 _9 oy H, 0,045 “ 4 FEEL apap, =0,02 (mol) Tu duy phan bé nhiém vu cia HT ta cé: 0,55=0,08.4 +0,045.2+0,01.10+ 8p, —Mp,0, 03 (mol) => Khdi lugng két tia chinh 1A kim loai va OH’ (trong hidroxit) va BaSO, — HH mg, peay 17,6 -0,03.4.16 -0,02.2.62 =13,2(gam) oj SE ng" = 0,55.2 -0,55-0,01 = 0,54 (mol) — #525; BaS0, :0,55(mol) —>m, 2+ 0,54.17 +0,55.233 = 150,53 (gam), Dap an B (XETED cho 4,08 gam Mg tac dung voi dung dich hén hop Cu(NO,), va H,SO, dun néng, khudy déu dén khi phan ting xy ra hodn toan thu duige dung dich X va 0,896 lit hén hop khi ¥ (dktc) gm hai khi khéng mau, trong dé cé mt khi héa nau ngoai khéng khi va 1,76 gam hén hop hai kim loai cé cling s6 mol, Biét ti khéi cia Y déi véi H, la 8. Khéi lvgng muéi tao thanh trong dung dich X gan nhat véi gi tr] ndo sau day? ‘A. 24,0 gam, B. 39,0 gam. €.19,5 gam, D. 24,5 gam. 1 Huéng dan: Tacb:yy =017 1,76 (gam) MB+0.02 a cb yg = 0, 176 (00) oo ——njy, = 9,15 (mol)—n, = 0,3 (mol) — ny = 0,04 haeaiaste My =@— PN, = 0,02.2 +0,02.4 +108 H, :0,02 Net .eras Mg** :0,15 Dung dich X chia: |NH; SOF :0,06-+5a PL 5a=0,02—>m, =19,32 (gam) Dép an C Héa tan hét 20,36 gam hén hgp ran A gém Cu, Mg, Fe,O, va Fe(NO,), trong dung dich chita 0,66 mol KHSO, loang, dun néng. Ket thie phan ting thu duigc dung dich B chi chita 104,18 gam mu6i trung héa va 1,568 lit hén hop khi C gém NO va H, dkte, 6 ty khéi hei so véi H, JA 9,0. Biét trong B khéng chita muéi Fe™. Phin trim kh6i lugng cia Cu cé trong A gan nhat voi: A. 25% B. 28% C.30% D.32% mt Huéng dan: EL 20,36 + 0,66.136 = 104,18 +0,07.18 +m, —eNy,o =0,26 (mol) NO:0,04 ee 1 Ta ¢6: ng =0,07 104 eon, - 0,667 0,082 0,262 _ 9 oy H 10,03 4 Bn, ge, =0,03 (mol) ‘Tu duy phan bé nhiém vy cia H* ta cé: 0,66 =0,04.4 + 0,03.2 + 0,02.10+ 8g, —>Myqo, =0,03 (mol) Cura Mg:b [64a+24b=8 20,3640 a Fe, O, :0,03 F520 + 2b = 0,04.3 +0,03.2 + 0,02.8 + 0,03.2 Fe(NO,), 0,03 a=0,08 0,08.64 soe — %Cu =. 25,15%. { =0,12 20,36 oat Dét chéy 10,08 gam Mg trong oxi mét thdi gian, thu duge m gam hin hgp ran X. Hoa tan hét X trong dung dich gém HC10,9M va H,SO, 0,6M, thu dugc dung dich Y chi chita céc mudi cé khéi higng 3,825m gam, Mat khac, hoa tan hét 1,25m gam X trong dung dich HNO, Joang du, thu duge dung dich Z chita 82,5 gam mudi va hén hop Khi T g6m N, va 0,015 mol khiN,O. S6 mol HNO, phan ting a A.1,23 mol B. 1,32 mol. C.1,42 mol D.1,28 mol. 1m Huéng dan giai a, =0,9%. BTDT: 0,9x+2.0,6x =2.0,42 +Trong Y jn, .. =0,6x=> 0 BTKL: 35,5.0,9x +-96.0,6x = 3,825m ~10,08 a, 1,42 Me | _1,25.42-10,08) 4 | gg me 2G210.08), => Trong 1,25m gam X 6} 16 7 ny, =1,25.0,42-0,15 = 0,375 =0,15 Egil0,375.2 ~0,06.8~0,015.8 BT E:ny, " 10 = 0,015 Fyyo, =Myge +2My, + 2g +290, Dap an A ‘Hoa tan hét 30 gam ran gém Mg, MgO, MgCO, trong HNO, thay cé 2,15 mol HNO, phan ting, Sau phan ting thu duge 4,48 It (dktc) hén hgp khi NO, CO, c6 ti so véi H, 18 185 va dung dich X chtia m gam mudi. Gié tri cia mA A. 134,80 B. 143,20 C, 153,84 D. 149,84 1,23 mol] @ Hudng dan giai ae =0,2 ent a , = = Mygco, =O 30m +44Mg, =0,2.18,5.2=7,4 — |Mgo, =O1 "MP + So dé phan dng: Mg”; NH, Me, MaOl | xo, —s (ME MeO, | Sma Wate 7 = .=x Pua 28, Pay Duo => [BTN Mo, yg y = 2005" BT E:2a=8x+01.3 fa =0,65 + {BIBT trong ¥: 2(a+6+0,1)+x=2,05-x= b=0,15 m, =24a+40b+0,1.84=30 x=0,125 Mg. oe Dap in B Cho 9,6 gam hén hop X gém Mg va Fe,O, vao 300 ml dung dich HNO, 2M, thu duge dung dich Y va 0,896 lit (4ktc) hén hop N,O va NO cé ti kh6i so v6i hidro la 16,75. Trung ha Y cin ding 40 ml NaOH IM thu duige dung dich Z, c6 can Z thu duige m gam mudi khan. Biét ring phan ting xy ra hodn toan va Khi cé can muéi kh6ng bi nbiét phan. Gié tri m la A, 42,26 B. 19,76 ©. 28,46 D. 72,45, 1 Huéng dan gidi + Y chifa HINO, du nén ¥ khong chita Fe’*. Tay +My, = 0,04 aa = 7 30nyo +44, 9 =0,04.16,75.2=1,34 |My. = 0,01 aeed + So 46 phin ing: Teer Mg", Fe St |NH.NO, Net im, =24x+232y =9,6 + {BT E:2x+y=0,03.3+0,018+82 BTDT trong Z: 2x+9y +2+0,04=0,55-2 my +m. = [42,26 gam Hoa tan m gam hén hgp A gém Mg, Al, MgO va Al,O, bing dung dich HCl vita da thi dulgic dung dich chita (m + 70,295) gam mudi. Cho m gam hén hop A tc dung véi dung dich, H,SO, dic néng du thu duge 13,328 lit SO, (dktc, sn phdm khii duy nhat). Néu cho m gam hén hp A tic dung vi dung dich HNO, loang du thu duigc 3,808 lit hn hgp kh NO va N,O (Akt) 6 ti khéi so vai hidro 1a 318, dung dich ¥. C6 can dung dich Y thu duige 162,15 gam muéikhan. Giétriciamla 17 A. 30,99, B. 40,08. C.29,88, D. 36,18. 1 Hudng dan giai Thy # ggg =0,17 7 + > 30g + 44m, = 73182 6,36 i ‘ 7 + So dé phan dng Mg", Al* © ao ‘Al, Mg. |Al, Al,O, aia 0 [wa Mg, Meo. 130, eekera 80, 0, ‘AUNO,), NO M 1e(NO,), {rot NH,NO,BTDT cho (1): n., + BT E cho (2): n, Hg +2Mhyg, Mey “2 + Theo (1) va sy! ting gidm khdi Iugng, 2 c6:35,5n,. —16n,, tescea ma Me, Al hop ee 1. 21 + Tit (*) va (**) suy wf =0,51 BT E cho (3): Macaca mn ns. ataoas = 380 + 8My,9 8,0, +2No Mat, x4g) = 6 ta ~80Ma x0, ~62n, acon a Mg AL bg Boo, = 0.02875 =22,83 =m =22,83+ 0,51.16 = [30,99 gam| Mena) Dap an A [XIE Cho 4,32 gam Mg vao dung dich hén hgp NaNO, va H,SO,, dun nhe dén khi phan ting xdy ra hodn toan thu duige dung dich X; 0,896 lit (dtc) hén hgp khi Y cé kh6i higng 0,92 gam g6m 2 khi khong mau cé mot khihéa nau trong kh6ng khi va con Iai 2,04 gam chét rin khong tan. Cé can c&n than dung dich X, thu duge m gam muéi khan. Gié tri cha m 1A A.18,27. B. 14,90. C1486, D.15,75. 1 Hudng dan giai H, :0,01 => X khong c6NO,”. 03 Maw =23 |cé m6t khi la NO (héa nau) +86 a6 phan ting NaNO, Mg*;Nat | [H, Mg + — + Sin [| H,SO, so, NH," | [NO aaiain BIE: 2m 5,7 20g, #3 +80, +{BT Ning, BIDT: ny, Bho * Py wong Ying. =0,12 my tm, +m,,. +m, =[14,9 gam| neon X nai FM go, EXD Cho 5,6 gam hén hop X gm Mg via MgO c6 ti lé mol tung ting la 5: 4 tan vita dit trong dung dich hén hgp chia HCI va KNO,, Sau khi két thiic phan ting, thu duigc 0,224 lit kh N,O duy nhit (dktc) va dung dich Y chi chifa muéi clorua. Biét cdc phan ting hoan toan. Cé can cin than Y thu duge m gam muéi. Gié tri cha m la: A.2051 B.18,25. 23,24, D.24,17,aad 1 Huéng dan gidi + So d6 phn ing Mg Teel HCL + — mgo:| * [KNO, BT E:0,1.2=0,01.8+8y +) BT N:x=y+0,01.2 = /BYDT trong ¥:0,18.2+x-+: [mary = 20,51 gam, EDD Cho 7,65 gam hin hop X gm Al va Al,O, (trong dé Al chiém 60% khéi luigng) tan hoan toan trong dung dich Y g6m H,SO, va NaNO, thu dugc dung dich Z chi chfa 3 mudi trung hoa va m gam hén hgp khiT (trong'T 6 0,015 mol H,). Cho dung dich BaCl, dui vio Z dén Khi ccéc phan ting xay ra hoan ton, thu duige 93,2 gam két tia. Com néu cho Z phan ting voi NaOH, thi lu;ong NaOH phan ting t6i da 14 0,935 mol, Gid trj cha m gin gid tr] ndo nhat sau day? A255. B.3,0. C10. D.LS. mt Huéng dan gidi + Ta c6:ny =0,17 mol; ny,., =0,03 mol; Nyco, = 0,4 Mol; Nyy, = 0,935 mol, + So d6 phan ting: Al H,SO, INH,’ A | fH, + —: + A1,0,|” [NaNo, Na’, SO, NO, |A10,~ BaSO, _ 10°, Na’ BT Al:n,,.=0,23 [BTBT trong W: ny, + Trong W 7 = : BT Sin... =04 [BINA M4. yy Moar ange = ie trong Zin, 7 5 0,015; BTN: ty, =0,08_ [x=0,25 3 = BT E:3.0,17=0,08(5-2x) +0,015.2+0,015.8 m, =1,47~[],5 gam| Dap an: D [XEZEED Cho 66,2 gam hén hgp X gém Fe,O, Fe(NO,),. Al tan hoan toan trong dung dich chia 3,1 mol KHSO, loang. Sau khi céc phan ting xy ra hodn toan thu duige dung dich Y chi chita 46,6 gam muéi sunfat trung hda va 10,08 lit (Aktc) khi Z g6m 2 khi trong dé cé mot Khi hoa nau ngoai khéng khi, Biét ti kh6i ctia Z so véi He la 23/18. Phan tram khéi lugng cita Al trong hon hop X gin nhat véi gid tri nao sau day? ALIS. B.20. C25. D.30.MH Huéng dan gidi = 234 Mz ===" =5) -{ eo =>Zg6m {re Z g6m 2 khi trong 46 c6 NO (héa nau) a ny, + yo = 0545 = = 045.234 4 5 { 2n,, +301 05 1, +30 = EE + So d8 phan ting: Fe,0, Fe, Fe" AP*) fit Fe(NO,), }+KHSO, fF FEAT LIT Lng —— INH,”, SO? NO] Al Tes) NO _ ‘akon ae BIKL:n, , = 96:22 31:136= 466,6-2.3 | o5 BTH:n,,. = 2 , BIN: tpg), 0,05 1,05 +-0,05~0,05.6 BT :ny.0, = 7 fm, =10,8 Pom , =16,3% Dap an A Cho m, gam hén hgp X chia Al, Fe(NO, ), va 0,1 mol Fe,O, tan hét trong dung dich chia 1,025 mol H,SO,, Sau phan ting thu duge 5,04 lit (dktc) hn hgp Khi ¥ gém hai khi c6 ti khéi so v6i H, a 31/3, trong dé cé mét khi héa nau ngoai khong khi va dung dich Z chi chifa céc muéi sunfat trung hda. Cho Z phan ting voi dung dich NaOH du, khong théy tgo két tha nau 8. Cho BaCl, vao Z dé két tia vita hét ion SO,” sau dé cho tigp dung dich AgNO, du vio thi thu duigc m, gam két tha. Biét céc phan ting hoan to’n. Gid trj cha tng (m, + m,) 1a A. 389,175. B.585,0. C.406,8. 1 Huéng dan giai 'Y gém 2 khi, m6t khi hda nau _ [8,:0,075 mol *1y, 312 = Y gém My 272m =0,225 INO: 0,15 mol +Z+ NaOH du: khéng tao két tha nau 46 = Z khéng 06 Fe™*,eee Lad + So 46 phan tng: AL Fe(NO,), 2x Fe,0, :0,1 Bap + BT H:2n,, 66, =2y, +40), +2n, 130 2 Mayo =0.875~2n,,,. BTN: 2209, = Bo Pre + BIKL: 62n,,,. +16n,.. +m, =m, oo.) +18 Myo 18M. or as ey is = 04 =m, =52 gam BIBT: n,,.=0,4 1 => Trong Z 05 i { im, +m, =628,2], Dap an D Maer, = Mpyso, = 4025; Mage, = 2 4 tee, . +m, mM, = My.s0, + Mayes +M,, =576,2 gam ‘Hoda tan hét 13,52 gam hén hyp X gm Mg(NO,),, ALO, Mg va Al vao dung dich chita hai chat tan NaNO, va 1,08 mol HCI. Sau khi két thttc phan ting, thu dug dung dich Y chi chita cdc miuéi va 3,136 lit (dktc) hn hap khi Z gém N,O va H,, c6 ti khéi so véi He bang 5. Dung dich Y tdc dung t6i da v6i dung dich chifa 1,14 mol NaOH, lay két tia nung ngoai khéng ki t6i kh6i Tugng khéng 4éi thu duige 9,6 gam rin, Phén tram khéi lugng cita Al cé trong hén hgp X la: A,31,95%. B. 19,97%. C.23,96%. 1D. 27,96%. ™ Huéng dan + $a d8 phan tng: N,0:0,06 mot fe 0,08 mot } mo Mso tate Max= Dap nC 02 => a = 0,39.mol => m=71,87gNe karat Fe(NO,), ‘NO :0,3 mol 58,75 gan eas IM M8257 +0,75 mol (CO, :0,4 +H,0:x |:0,45 mol 46,4 gam FeCO, N,0:0,05 Xéedinh duge trong Z khong 6 mudi NH; ‘Tu duy phan chia nhiém vu H* Ny, = 2g, +4.2NOH10.ny,9 =2,5:mol => x =1,25 mol Bao toan khéi luong ta tinh ra khéi lugng Z 58,754+46,4+2,5.39+1+97) =m, +19,2.2.0,75+1,25.18 =m, =393,85g > 19273933858 Dip an A xD Fe,0, :a mol 3 mol KH90, [NO :0,05 66,2 gam | Fe(NO,), }—H™4X#82_5 466,6 gam Y+Z: +H,0:1,05 mol aH HH, :0,4.mol| bao ton mol nguyén tit hdro ta tinh ra mol NH NHY x =9 4x +1,05,2+0,4.2=3,1=9 x=0,05.mol Bio toan mol nguyén t6 ni to suy ra mol Fe(NO,), Fe(NO,), : y.nol = 2y=0,05+0,05= y=0,05 mol Tu duy phan chia nhiém vy H* Hi =3,1=240+4.ny9+2ny, +10n,,, a=0,2 -100.56 = 54,98%. Dap an B Alb 1 38,55 gam: 8S nol 85 5 96,55 gam. vf fetro:xt Zn0 Fe(NO,), Bao Toan khéi lugng tinh ra mol nuéc 38,55+0,725.98 = 96, 55+0,175.2.9+18x => x = 0,55 mol Bio toin mol nguyén tithidro suy mol NHI : y mol 4y +0,075,2+0,55.2 = 0,725.2 > y = 0,05 molBao toan mol ni td Fe(NO, ), :zmol => 2z=0,05+0,1=> z=0,075.mol Phan chia nhiém va H* H’ =0,725. =o +4.yo +100 gy, +2y, Nzyq = 0,2 mol Mg:a Alb 38,55 gam: => 24a+27b=8,85 ,2 Fe(NO,), :0,075 Bao toan mole ta cd 2a+3b=0,85 ja =0,2 0S => => 24a+27b=8,85 " |b=0,15 = 2a+3b= > Yny, =32%. Dap an D emt ‘Mg cin du la 2,04 gam suy ra Mg Phan ting NO: 0,03 Mg:0,095 mnt. { ooo Bio toan mol e suy ra mol NH; Boy +0,03.3+0,01.2 = 0,095.2 thy, Bio toan mol nguyén t6 ni to suy ra mol NaNO3 Dyno, = 0,01+0,03 = 0,04 mol Xée dinh céc ion c6 trong A Mg**:0,095 NH}:0,01 sw A: Mo y=0,12m=14,9g Na*:0,04 SO}: y.mol Dap 4nB Zi { je aK. 58.11 gamdd X 4 NO:0,01 HY, :0,03 Bao toin mol nguyén t6 nito suy ramol NH; => ,,,, =0,015—0,01 = 0,005 ‘Tu duy phan chia nhigm vu ,15 mol yg) + 2M, +1020, Dung dich X chita ion ntoDevas Zn sa ani M4 2a+3b=013 faa 8,11 gam.}K’ :0,015 —| a i ={ NEI 0,005 Hs 65a+27b = 2,11 Cr :0,15 Dap én C 31s gams{ nem | a Pa - ‘Mg:0,35mol[ ™#®° “| H, :0,1 mol. Bao toin e suy ra mol NHj => NH} :x => 8x+0,1.8+0,1.2=0,7.2 = x =0,05 Bao toin mol nguyén t6 ni to suy ra mol *sN0, = Myyyo, = 0,05-+0,1.2= 0,25 mol Bao toan mol hidro suy ra mol NaHSO, as =10.ny,9 +100, +2.my, =1,7.m0l ‘Zn* 30,35 Mg” :0,35. Cc ion 06 trong dung dich A :} Na” :1,95 mol => m =240,1 NH; :0,05 SO} 31,7 mol FeO:a : NO: 0,06 29,64gam:]FeNOs)2 | stems. 4179, 7290 :¥ + +H,0:xmol Alze H, :0,24 Znze ML 29, 64 +157, 76=179, 72+ 2, 28 +18x => x =0,3 mol Bio nguyén tit hidro suy ra: s6 mol NH} n,,,, ==> 4y+0,3.2+0,24.2=1,16= y=0,02 mol Bao toan mol nguyén tit nite suy ra Fe(NO,), :b =3 2b =0,06+0,02 => b=0,04 ‘Tu duy phan chia nhiém vy H’ H? =1,16= 2a +0,06.4+0,24.2+0,02.10= a= 0,12 molFeO: 0,12 Fe(NO,), :0,04 29,64gam:: = c=0,15.mol = %m,, =13,664% Al:c Zn:¢ Dap in A [AL Zn 0,06 mol NO 1.30.04 ot , 21,5 gam) poG, HSA ely ie oat 1H, 755.9 gem Z+H,0 xmol Ca(NO,), 21,5+0,43.98 = 56,9+2,06-+18x = x = 0,26 mol Bao toan mol Hidro suy ra mol NH; 0,43.2=4n,,,. +0,13.2+0,26.2 = n,,,, =0,02 mol Bao toan nguyén t6 ni td suy ra mol Cu(NO,), Ang), = 0008 Neyvo,), = 0404.01 Tu duy phan chia nhiém vu I Hé =0,86 = 0,06.4+0,13.2 +0,02.10+ 2.ttag =9 pay = 0,08 mol Alra 21,5 gam: Zn:b = Fe tte FeO: 0,08 3a-+2b=0,06.3+0,13.2+0,02.8 = 0,6 Cu(NO,}, 10,04 = Yommg, = 20,09%, Dap an C TH Fe—#82. 5 NO :0,05 mol +X; X 88% NO :0,02 mol+¥ Dung dich Y phan ting 2,08 gam Cu (kh6ng tao thinh san phdm khit clia N*8)_nén chi ¢6 phan ting Cu + 2Fe* —+Cu** +2Fe* 0,0325—+0, 065 2x +0,065.3=0,07.3 => x = 0,0075 ng, = 0,0725 = m= 4,06g. Dap an Cm gam Fe—¥82+» NO: 0,1 mol-+ X 5° 5 NO: 0,04 mol + ¥ #288285 Fe :0,13 mol >m=812¢ Fe? :x——+ 2x +0,13.3= 0,14.3=9 x =0,015 Dap an B > Cau 13 Fe m gam:4 Fe,O, —Ksoutii2wel_5 61,4 gam +NO:0,04 mol +H,O: 0,16 mol Fe(NO,), m=61,4+0,04.30+0,16.18-0,32.136 = 21,96 g K* :0,32 2. y 2st, Dung dich sau cing /S0¢ 132 Na‘ :0,46 mol NO; :0,14 mol Béo toan nguyén 6 ni to suy ra mol Fe(NO,), Mpa), = 0404+ ,14 = Nya, =0509 mol ‘Tu duy phan chia nhigm vy H* H =8.nj.o, +4.yo = 0,329 nyo, = 0,02 m;, =1,12=9 %m,, = 5,1%, Dap an A te i. 20,01 20,05 mol A+: Zn:0,05 mol Hy:0,01 Bao toan mol e ta cé: 0,05.2=8:,,,, +0,01.3+0,01.2 = n,,,, =0,00625 Bao toan mol ni to ta cé: NaNO, =0,00625 +0,01=0,01625 mol ‘Zn** 0,05 Dung dich A chifa cdc ion. Neola — Ly y= 0,06125 = m=9,61265 NH; :0,00625 SOF :a Dap anCx gam Fe—Zi5*->0,2 mol khi NO+ X—#82+0,08 mol NO+ Y 2220 a vf 10,26 — 99-+0,263=0,28.3 > a =0,03-3 x =16,24 2 Ny :0,05 Zn ’ NO, —£40,45.mol. H, :0,05 ey asi 0,3 mol Cu(NO,), an asf Ng =0,3.6~0,45.2 =0,9=9 nyo = 0,9 mol _2:3-0,9.2-0,05.2 ae 4 =0,1 mol 20,1 9.377 22089 m= 154,65. Dép dn A Mg NO:0,05 38,36g:{ Fe,O, ttt mol dd F804 111, 6g +H,0:x Fe(NO,),. 38,36+0,87.98=111,46+1,9+18x > x =0,57 mol 05 = Fe(NO, ), =0,05 mol 1, :0, = 0,87.2=8.1;,0, +0,05.4+0,2.2+0,05.10= tp,o, = 0,08 => my, =10,8 g Dap an D. ite Tm Mg, Al, Fe,0,, FeCO,| (CO, :0,02 45,55 gam #5 0,05 mol Z:} NO:0,02 +H,O+Y Fe(NO,), N, :0, a1 ; Yy—**_; BaSO, : 0,485 mol = H,SO, :0,485 mol Bao toan khéi lugng tinh ra _khdi lugng nude 45,55 + 0,485.98 = 83,49 + 0,02.44 + 0,02.30+0,01.28 +18x =>x=0,435 Bao toan mol Hidro suy mol NH => NH; = 0,025 molKhi cho Y phan ting 1,255 mol mol NaOH dung dich sau cing la: Na* :1,255 mol S02" :0,485 mol AIO; : x mol NO}: y ‘Trong dung dich Y 21,91 gam SO?" :0,485 mol 83,49 gam Y: > y= 0,235 mol => x = 0,05 mol NO}: NH :0,025 mol tax ty =0,285 Tu duy phan chia nhigm vy Ht H*=8.g,0, +2Mpco, +4:2yo +12.my, +10.0,,,, = Bya,o, = 0,06 mol Bio toan mol nguyén tif ni to suy ra mol Fe(NO,), 2 tency, =94025+0,235+0,02+0,01.2 = yyy, #0415 mol ‘AL: 0,05 21,91 gam::}Fe:0,15+0,06.3+0,02} => %my, =2,11% Mg:0,96 gam Dap an A ne H, :b mol beta 8 | ravoyamet , :b mol 86: wl oy: +43,25 gam:4SO} :2a+H,0 a ra a=0,15.mol 8,6+44,55 = 43,25 + 50b+ (0,3~b).18 = b = 0,140625 > m, = 7,03125 Mg =8,6+100~7,03125 = 101, 56875 ‘Vi Cho mét lugng KOH vao X, thu dugc dung dich chi chtta mét chat tan va két ta Z (khong 6 khf thoat ra), Nén suy ra X khéng chtta NH}. dung dich chiia 1 chét tan la K,SO,. suy ra trong X chi chita mudi sunfat. Néu trong X kh6ng c Fe thi ta cé ee . 1 SO* :0,3 mol—*2 M™ :8,6¢ yz M™ :8,6 ¢ ee ‘ ie OFT :0,45 mol 0% :0,225 mol Elm, =12,2<12,6= FeO: 0,05 mol = FeSO, :0,05 mol 2FeO+O—>Fe,0, YIMy so, = 7.48% Dap an B er ag Zn:0,3:mol | ayo, , {NzO:0,15 mol 9 gam: £m") Mg:0,6mol[ "| H, :0,05 mol Bio toan mol e ta c6 s6 mol NH Bg, +I +2, =0,9.2=1,8n,,,, = 0,0625 mol Bao toan mol nguyén t6 ni to suy ra mol NaNO, NaNO, =0,15.2+0,0625 = 0,3625 mol Tut day phn chia nhigm vy H* H? =10.ny, +10ny,0 + 2:4, =2,225.m01 = Myurso, Me?* 0,6 Zn 20,3 Xéc dinh ion 6 trong A: NH :0,0625 = m=308,1375. Dap én D 2,225 Na* :2,5875 CXEDED D. 54,350. Fe, FeO, Fe,0,, Fe,0,, er, JOO, :0,06 : + Fe(OH), . Fe(OH), FeCO, HH, :0,06 *™ Fe, FeO, Fe,0,, Fe0., 0, [O02 :0,06 - ‘NO,), :0,4 mol ee Fe(OH),, FeCO, NO:0,14 *FENOs) 0.4 mol+ELO = Mano, = 0,4.3 + 0,14 = 1,34 mol Fe:0,06 a =0,4 A: (Fe0,Fe(OH),, FeCO, —>Fe"):a = (ios e = 3.0,06+a =0,14.3 (Fe,0,, Fe(OH), —>Fe™): Fe:0,06 A:} (FeO,Fe(OH), , FeCO, —+Fe™):0,24 af OH =54, FeCl, 10,377 75358 (Fe,0,, Fe(OH), —>Fe™):0,1 Dap an Deed Mg,Fe Fe,0,,FeCO, 212 mx Z—**4_4Ba8O, : 0,605.mol =» H,SO, : 0,605 mol Higa mol (CO,, NO, NO,, H,)+mgZ+H,0 op Khi cho NaOH dut vio Z thi thay c6 1,085 mol NaOH phan ting déng théi xudt hign 42,9 gam kkéttita va 0,56 lit khi (dkte) thoat ra. Suy ra khi thodt ra la NH, .Vi khi thu duige cé hidro nén trong Z khong 6 NO; Dung dich sau cing Khi cho NaOH vio Z ‘Na’ :1,085 mol SOF :0,605 =>n=0,125 mol K* :nmol Xéc dinh céc ion c6 trong Z NHj :0,025 mol K* :0,125 Fe sa SO :0,605 Laem dHOH_, 42,9 gam.4Mg™ :b ={ Fe* sa |OH™ :1,06.mol Mg”* :b eis b=0,1625 => m=88,285—* >ny,, = 0,495 mol CO, :x NO:y NO, :z H, :0,06 Weisea x+y+z=0,14mol x=0,04 > 44x +30 + 462=5,72 = }y=0,04 Ox-+y+z=0,125-0,025=0,1 [2=0,06 0,2 mol Tu duy phan chia nhiém vy Ht Hi =0,605.2=2:mep, +4.Myq +2Myo, +2ty, +8.tg.0, +10 9, Dye, = 0,06 mol (0,06 mol NO 0,13 mol H, H,50.049n_,y Bio toan mol hidro suy ra mol NH eal /2a+2b=1,06 [S6a+24b = 24,48 +56,9 gam Z+H,0°*"Bao toan mol nguyén tif ni to suy ra mol Cu(NO,), 04 2Deevoy), ae ae Pexiso,), iss Tu duy phan chia nhigm vu H* H* =0,43.2 = 0,02.10+0,06.4+0,13.2+2n,.9 = Nyy = 0,08 mol a +65b = 8,22 = 3a+2b=0,6 Dap nC Fe,0, eines INO :0,05 66,2 gam X:4 Fe(NO,), - =H 5.466,6 gam¥ +) 75 ')+H,0:1,05 mol "| 1:0, = n¥,, =0,05 mol Bio toin mol ni ta suy ra mol Fe(NO,), 2My4yo,), =0:05+0,05 —F Myo, = 0,05 mol ‘Tu duy phan chia nhiém vy H* HY =3,1=0,05.4+0,05.10+0,4.2+8.n:., = Myo, =02 mol => my =10,8.g => %m,, =16,31 Dap an A ey Mg :0,17 mot £68 [NO:0.02, [Mg:0,02 150. TH, 0,02" [Cu0,02 ony =0,02,2-0,02 = 0,02 mol IMg** :0,15 mol Cac ion 6 trong X:|NH; :0,02 8 5a =0,16=> m=19,32g SO} :a Dap én CBO eared Fe(NO,), 244» Fe(NO,), :0,06 mol cu 22 el. 5X 4NO:0,18 mol => 4 Cu Fe,0, |—+Fe,0, :0,04 mol Fe* :0,16 mol Fe™ :0,18-0,16=0,02| gran at 3X; eat, x] PO x =0,26 mol Cu* : x mol SO¥ :0,52 21% Fe(NO,), :0,06 mol Cu:0,26 mol => m=40,44 g —Fe,0, :0,04 mol Dap an C K? :0,07 ae Cu? :0,03 mol Cu : emote, x} ig? -0,0914+0,05 mol. SOF :0,16 NH; : 0,01 Ne r S 0,06 mol 1 0:0,14 mol =) ng = 0,07.3-0,14 = 0,07 = Mx =39,2 = x =19,6 30 gam:{ MgO:b | 5 NO:0,2 mol => Mg(NO,), :0,1 mol Mg(NO,), Mg” :a+b+0,1 => {2da+40b=15,2=9 242% OF sat b+0,1 = H,SO,:a+b+0,1 =0,3 aravso2erbeoad— [i 37? HSO, =0,6mol Dap én B EqFe FeO, —eso.ai6nel 29, 52 gam ¥ +NO:0,02 mol+H,O Fe(NO,), 29,52 gam ¥ —Sulaa2=0! Dung dich sau ciing la K*:0,16 mol Na* :0,22 mol SOF :0,16 mol NO} : x mol + x = 0,06 mol => Fe(NO,), :0,04 mol ‘Tu duy phan chia nhigm va Hi? =0,16 =0,02.4+8.n.0, = Dpo, Dung dich Y K* :0,16 mol Fe™ :ymol 29,52 gam. —>y=0,075 mol SO} :0,16 mol NO; :0,06 mol Z K* :0,16 mol K* :0,16 mol s a Fe® :0,075 mol Fe" :0,075mol| sana 29,52 gam 4° 22 5/sO} :0,16mol = a=0,035 > m=2,24g SO :0,16 mol NO; :0,06 mol NO; : 0,06 mol Cu* :amol Fe:a 5,36 gam {3 —Tineiisc? NO :0,01 mol b z enone tees = = 3a-2b=0,03 ~” |b=0,09 Xéc dinh céc chat trong Y Fe" 0,07 Fe" :0,07 SOF 3012 crooe , [SOF 0,12 => m=18,465 g NO; :0,02 NO} :0,0075 He 0,05 Cu* :0,04 Dap anccad : Fe:zmol X:4 FeO, sos! 59.04 gam Y+0,04 mol NO+H,O Fe(NO,), 59,04 gam Y 20H Dung dich sau cing la K*:0,32 SO} : 0,32 4 Tt 885 x = 0,12 mol Nat :0,44 NO} :x Bao to’n nguyén t6 ni to suy ra mol Fe(NO,), Fe(NO,), :0,08 mol Tw duy phan chia nhiém vu H* H! =0,32=8inp,0, +0,04.4> nyo, = 0,02 )K* 0,32, SOF :0,32 59,04 gam: = 2+0,02.340,08=0,15 > z=0,01 NO; 0,12 Fe’ :0,15 mol Yom,, = 2.86% Dap anC TE (n°) 915,44 gam:|FO29) = 27x +56y=12,24 Fe,0,, Fe 15,44 gam: Al wae 00,2 mol =) Fe sot 80,280 Oe 15,44 gam: —BamolIINOnBH = 5 293,96 gam dd X+ Bees Pat fai 0:0,2.mol ‘a+b=0,04 ja=0,02 > = 30a+44b=1,48- |b =0,02 ealXée djnh céc ion trong X AI(NO,), :x Fe(NO,);:y NH,NO, :z HINO, :0,9-3x -3y-2z-0,06 xorg at Nat :0,9 NO; :0,84-z=5 0,84-z+x=0,9=9x-z AIO; :x dung djch sau cing Phuong trinh bio toin e 3x +3y =0,2.2+0,02.3+0,02.8+8z = 3x + 3y —82z = 0,62 27x+56y =12,24 => }y= x-2=0,06 mol AL(NO, ), 10,08 AN(NO,), :0,08 Fe(NO,),:0,18 « JALO, :0,04 x: —£9Z:) Fe(NO,), :0,18 >. => m=43,72 gam NH,NO, :0,02 Soo FeO, :0,09 HINO, :0,02 : te akon Dap an C 19,2 gam Mg a 19,2 gam etm ca —aaocnav>(3m-+ 20,8) gam Mg** :0,8 a SEL V = 0,64 m=22,4 => a=0,2 mol SOF :0,75V N N,O0:0,04 Mg(N¢ m{28mol ME yo, ,[NO:004 | |MIBINO,) 8 ge sy 0:0,2 mol N, :0,04” | NH,NO, :0,06 > Dap in A Eg Fe—%%_5 x +0,03 mol NO Na" :0,13, dd:4CI° :0,05 NO; :0,08 XM MIB NO) 4 y NOHO olDO a Dung dich ¥ chita Fea Jr :0,05 : = 3a+b=0,13 mol NO; : 0,08 Ht:b 34=0,0334 20522 354 =0,03+ 20598 4axd=0,17 3a+b=0,13 _ fa=0,04 = 4a+b=0,17— |b=0,01 Fe* 0,04 Fel :0,04 er 1 :0,08 YE 05 _ copes JCC 20,05 0.003759 m=1,528 NO; :0,08 NO; :0,0775 H*:0,01 Cu* sy Dap in A N, Mg NO Cu(NO, N.0 7 a ds rte? 62,605 gam Y +T: NO, fen! H, :0,02 mol BaSO, :0,455 YESS 256,04 gam Z} AgCl: 0,91 Ag:0,18 mol Mg(OH), y 00888 wol_5 34,78 gam: Cu(OH), Fe(OH), Dung dich sau clang khi cho Y phan ting NaOH fa* 20,91 ( 07" :0,455 mol Vay trong Y khéng cé mudi NO; ol2a+2b+c=0,505 =>} 6da+24b+18c = 7,81 => 98a+58b = 15,52 62,605 gam Y ,025 Bao toan khéi higng tinh ra khdi lugng X My +My,s0, +My, =62, 605 gam+m, + Myo 2g +2My, +4. =2Mys0, — My,o =0,455—0,02—2.0,025 = 0,385 my =27,2 ‘Mg:0,2 Cu(NO,), :0,04 oe ie S6x +1 16y =14,88 Fe:x FeCO, : x=01 > y=0,08 Dap an ED {he mol Cu pk ma 80, : 0,06 mol | Hee ,06.3-0,12 = 0,06 Dy Myo == 0.12.01 = N Dung dich sau phan ting \ ‘SOF :0,24 mol NO; :0,06 re -p9g SP YTOTIM=4.568 I=3) Mega book = 0,06 [b= 0,06 _, [©48+2320=17,76 2a+6b=8b (6u:0,16 ‘ . 2 ge an ie 0,919 12 yy 24,16 gam fies “ost y_metaa_, [Fe(OH :0.18 Cu(OH), :0,16 Phan nuéc Ipc chia ‘NaNO, :a ‘NaOH:b NaNO, : = NaOH:b fees 2 {tate 7a gam:f 69a+40b=78,16 [b=0,16 mol Fe :0,18 mol Cu :0,16 NO; :1,04 mol H’ :0,18 mol nko, =1,2-0,18=1,02= ny,g =0,51 mol Bao toan nguyén tit oxi va ni to ny" =0,16 mol {e = 0,06.4+1,02.3-0,86.3—0,51.= = mE! = 24,16+240-—0,16.14-0,21.16 = 258, 56 %Couroyy, =114634% },21 mol Dap énB D> NO:01 Zn — Hh 5 ma: ; 1 savin et Zn EA way y peliy gas ceeea sees ooo! Zn" :0,375 K*:0,1 Nat :0,05 = m=64.05 g Cr :0,95 Dip dn BMg:0,145 mol ya m+ —*£NH}:0,01 N, :0,02 005 Mg”* :0,145 _ JN; :0,01 ")K' 0,05 Cr :0,35 => m=18,035g nel 180s 975,42 gam ¥ ee ett H, :0,08 Bao toan khéi ugng tinh ra khéi ligng nude Myo = 50,82 +1,8.136-275, 42-0,28.2.11=14,04 g = Nyy = 0,78 mol Bao toan mol hidro suy ra mol NH hag = 1,8-0,08.2 -0,78.2 =0,02 mol < 4 Tu duy phan chia nhigm vy ion H* Myo, +4tyo +2My, +10. 5, = Myo, = 0,08 mol K*:1,8 mol NaNO, :a SOF :1,8 mol Fe,O, :0,08 Ps 50,82 gam}! tama. 275,42 gam {Fo +b + 0.24 mol Fe(NO,), :b Ne Mg:c Mg” :¢ NH; :0,02 85a +180b-+24c = 32,26 1 => }a+2b+20=1,3 = 1b =0,06 = %my, = 25,5% 23a+S6b+24c=18,62 [c= 0,54 Dap an AMega book APY: 2,15 ALLIS Nat 2,05 E RC: 82,05 gam {ico.ost ms") et so C—#1_ 5 BaSO, :3,6.mol = SOZ :3,6 mol AL’ :2,15 c.f Nery NHS 3x, mit 17x +782-23+0,52=31 NH} x Al(OH), :z SO? :3,6 mol =17x +78z=25,1 Dung dich thu duge AP? 2,152 Ci{Natiyt] = y+1+6,45-32=7,2— 32-y=0,25 mol SOF :3,6 mol Bzt17x=25,1 32z-y=0,25 mol => }x= \75mol [y= 0,65 xty Bao toan mol nguyén ttt hdro suy ra mol muéc aes =3620022-014 3,2mol AL :2,15 Na® :0,65 cm, =4204g NH; :0,1 SO} :3,6 mol Bee ee mg = 408,05 NaNO, 0,65 Bao toan khéi htong 82,05 +408,05 =420,4+ m, +3,2.18 => m, =12,1 g, Dap an CBao toan e hién dai ta cd Dino, =HO.My,o +12.ny, +10. ,9,n, = Maro, = 0403 mol Al iH 25,24 gam: 4M; - ery 25,24 gam:/Mg agy: cul ff“sbg cu NO; : 2,04 NH,NO, :0.03 mot a~b=2,04.62+0,03.80-1, 02.16 = 112,56 g, Dap an D OF :1,02 Meg, Fe,0,, MgCo co. Peyune s ates 880. 4 ¥ 40,16 mol: {C2 Ban Fe(NO,), 22 EL a fore %O = 31,858% Fe :0,18 HY :0,02.4=0,08 Cr :2,24 mol Agcl + YAN 5 3344 gam +NO:0,02=5 ¥:{Na* :0,04 Ag:0,12 mol : Mg” Fe NH; Kh6i lugng dung dich Y gém mu6i va axit HCI du 11,44 +0,08.36,5 =114,36 Bao toin khéi lugng tinh ra khéi lugng nuiéc: myo =18.g = nyo =1 2,24-0,08—-| Bio toin mol hidro suy ra mol NH: NHS = ,04 mol Fe™ :0,18 Cr :2,16 mol Na* :0,04 2x+3y=1,72 x Mg*:x Ei asp naire Fe*:y NH; :0,04 Mg::0,68 Fe:0,3 34,24 gam X:40:1,08 Cia Nib ,68 mol 111,44 gam Y },12 mol 12a +14b =3,84 a=0,04 = > b+0,04=0,04+2(0,16-a) " |b=0,24 Dap in A iaPc raad Fe,0. 60,24’ mafre || ee rs cu NO: 0,26 mol NO: 0,04 se — 6,04 et x (m — 6,04) gam r of rye Xéc dinh céc chat trong X Fe :x Cu ry CY :1,8mol =n = NO; :0,04 mol H*:0,28 mol a jee eetit 3x+2y =1,56. .8+0,3-0,28=0,26.4+2ng => ny = 0,39 mol Xac dinh duge (m - 6,04) chat ran la Cu, Fe,Mg du. Suy ra dung dich sau cung: (ad 0.9 = 21,8 Dap dn C cr:,8 ea Fe 1336 ef g 13,36 gam } Cu >—5*-> 95,0 gam Y + 0,06 mol NO +H,02 mol Oy 0 — HL 5 13,36 + 98a +101a = 55-+0,06,30+18a => 181a = 43,44 a =0,24 mol ‘Vikhi NO (san phém khit duy nhat), nén trong ¥ khéng c6 mudi amoni. Bao toan mol ¢ hign dai: ny. = 0,06.4+2.n, =n, = 0,12 mol Fe:b+e 13,36 gam 4Cu:d = 56b+56e+64d=11,44 g (0:0,12 mol Xéc dinh cic chat trong Y K* :0,24 mol SOF :0,24 NO; :0,24—-0,06 = 0,18 cu :d Fe*:b Fe :¢ 2b+3e+2d = 0,42 = 156b + 560 +64d = 11,44 g =nBaSO4: 0,24 mol Fe(OH), :b vy: Bao, | FeCOH), = m=0,24.233+11,44+0,42.17=74,5 g Fe(OH), :¢ CuO), Dap an D NO:0,03 Mg(NO,), :0,125 mol 3 gam Mg—2250,05.moLY a dd.X a eee ae Real (ree M, =35,6 : NO: Mg(NO,), :0,125 mol dd X pgp Steer 0,28 mot JNO'* 5, gx, MBCNOS): 10,125 mol 80,25 at ay HNO, :0,03 mol +y=0,2 : eee 0,28 mot {NO!9?1 sy 234 4x4 2y = 0,03+0,475.2 NO, : 35,6 ——=1,047 A Pio = 1,047. Bap dn D Tie Fe(NO,),:a+b+3¢ (CO, :b 22.¢.X:4FeCO, :b | gy pert M42 4O08* HINO, :0,16 NO:0,84—3a—3b—9e Fe,0,:¢ Dyno, = Araico, = 0,16.mol = nfo, =1—0,16 = 0,84 mol 3atb-+e=2,52—9a—9b—27e = 12a +10b+ 280 = 2,52 CO, :b 35( 9.98 zo” Hl 24 mol NO:0,84~3a-36—9e n, =b+0,84—3a-3b-9e = 0,24—0,12 = 0,12 mol => 3a+2b+9¢=0,72 mol 12a+10b+28¢=2,52 {a =0,02 3a+2b+90=0,72 => 1b=0,06> %m,.o, = 63,27% 56a+1166+232e=22 [c= 0,06 Dap an C xp cu Mg eam to 39,95 NO:0,03 16,88 gam Fe,0, etna HO 530,055 gam B+ a Fe(NO,), Bao toan kh6i higng tinh ra khéi lugng nude3) Mega book aie Myo =3,78.8 = My, = 0,21 mol Bio to’n mol hidro suy ra mol n,,,, Dag = Bao toan mol ni to suy ra mol Fe(NO,), : Bao toan e hién dai 0,49 =0,03.4+0,015.2+10.0,0148.n.,0, ,03 mol 02 mol Deo, Cuca Mg:b 16,88 gam) p69, 9,03 [> Ott t24b= 6.22 Fe(NO,), :0,02 Cu sa Mg** :b 30,055 gam B:4 Fe™ : 0,11 ={ NH; :0,01 Cr 20,49 2a+2b=0,26 _, fa=0,08 64a +24b=6,32 ~ [b=0,05 Cu(OH), :0,08 => {Mg(OH), :0,05 =» m= 20,64. Fe(OH), :0,11 Dap an A Ep H, :0,02 ‘A1:0,06 vo, s 3,54 gam: 4) og REY ty NO, :0,01 Gan NO:0,07 —EEon,,, =0,01 mol=> tig, = 0,09 mol Nyc + 0,09 = 0,02.2-+0,01.2 +0,07.4 +0,01.10 => nyc, = 0,35 mol At :0,06 2 PERE Me 08 , m=16,145 2 NH! :0,01 Cr 0,35 Dap an DFe,0, ae F,S0454 mat 86 gamgX: Fe(NO,), fe Y +004 mal N, Mg Pe ae ae Dung dich sau ciing la K* :3,15 mol SOF :1,54 =x =0,07 mol NO} :x Bao toin mol e hign dai ta c6: 1.54.2 = 1,05.2+12.0,04+102,,,. = n,,, =0,05 mol (6 Fe(NO,)," Fe(NO,), :0,1mol Bio toan mol nguyén tii Fe:xty Mg:z 0:1,65 N:0,2 86 gamgX: => 56x + 56y +247 = 56,8 g Cac ion o6 trong Y Soe :1,54 NO; :0,07 209,88 8. 5181,88 g | NH :0,05 Mg": oe 2k43y Fey ap Boe = 112x +168y—18x-27y =28 18x-+27y-+242= 28,8 =005 aos 2x43y+22=3,1 = 4y=0,9 of OB og m=82 20, 10,475 S6x+S6y+24z=56,8g |z=0,15 Dap an C 1 m: {O27 _ 0, 59, 75my {OHO reco, ), 225 40,125 mot] NO Fe:0,3m Fe:0,05m 36 NO, 0.25m 9 40,125 = 22295 «0,35 m=25,2¢ 36 6 Dép an B aLd Fe* 0,03 Cu :0,045 Fe: 0,03 SOF :0,25 POP _ns0,asnat_yy JP fe 10,045 NOH HH" 20,26 Na 0,1 NO; 0,04 +0,06 mol NO+H,O. SO} :0,25 X—MOHEO dd | Na* :0,1+b => 0,146 =0,25.2+0,04 NO; :0,04 = b=0,44 mol => V=440 ml Dap in A Fe:a X:4 FeCl, :b} 4° 9Z:Fe+¥: FeCl, :0,42 mol FeCl, :¢ Wena = > c=0,2=a=0,325 = 0,18605,(0,42+0,225) =0,12 Fe—™:_; Fe(NO,), +NO+H,O:0,15.mol — Fe: 0,225 mol Yom;, =27,6% Dap an A TH 14 gam Fe —BS2etszet_y X—ENOs_y_S NO:h? =0,3 mol FRO, Dot 4 = NaNO, :0,1 mol Dung dich sau cing Fe* :0,25 mol Cu :b SOF :0,5 Na’ :0,1 Dap dn C .0,25.2+26+0,1=1=9 b=0,2 mol =aFe™ :0,02 Cu" :0,03 Fe:0,02 SOF :0,2 60.02 | gonnams 5x. +NO:0,04 mol+H,0 Cu:0,03 s Na’ :0,08 Ht :0,24 0,04 F 20,2 0H ma 08+ V => V = 0,36 = 360 ml NO; :0,04 [Ca :0,28 mol (Ca: 11,2. 11,2 gan: om + 21,14) gam:4CI:a SO} :0,5a => 2a =0,28.2 > a=0,28 > m= 13,44 => b=0,14 mol Ca:0,28mol yo, _ [Ca(NO,), :0,28 820,28 mol ano, {CA0NO3)2 £0.28. 5 0,04 mol 0:0,14 mol NH,NO, :x 0,28.2 = 0,14.2 +0,04.3+8x = x =0,02 => my, = 47,528. Dap dn A Mg Me N,0 5,22 gam:) Mg(OH), mmx pa +H,0 MgCo, - Mg(NO;), Myo =5,22+0, 26.63 =m, +0,02.44+ my. su0H0.25 mo X—S2E =, Mg(OH), 0,12 mol =n, =0,25-0,12.2=0,01 mol Dung dich sau cing la NeNO, :0,25 mol Xéc dinh céc ion c6 trong XDE Lad Mg™ :0,12 mol X:{NHI:0,01 =m, =18,56=9 my, =5,22+0,26.63 =m, +0,02.44+ my, NO; 20,25 =0,12 mol Bo Bao toan mol hidro suy ra mol Mg(OH), Mg(OH), :y mol = 2y +0,26=0,01.4+0,12.2 = y=0,01 mol YIM yoxp, = 111% Dap an A en Mg:a FeCl, :¢ m:} MgCO, :b} =" 51 MgCl, :a+b¢+CO, +H,0:2a mol FeCO, :< HCl: Mg:a Mg:x atb=c=m:{ MgCO,:b }=m:} Fe:x }-—>m=80x+60y FeCO, :a+b COy:y Mg:x as m:] Fe:x }—H2=t#2._50,25 mol J? N,0:0,25-y COs: y, Fe*:x Mg* : (160x+120y + 17,8) gamy}V 2 °* NH,NO, :emol NO; :5x 390 || = 80x +800-+310x = 160x +120y+17,8 =2 230x-120y + 80c =17,8 1,02 = 2y+2,5—-10y+10c = 8y—10c=1, 48 HL 2¢ + 5x +0,5-2y =1,02 = Sx—2y +20 = 0,52 230x-120y+80c=17,8 [x =0,18 Ox+8y-10e=1,48 9 =>) y=0,21—>m=27 Sx-2y+2c=0,52 0,02 Dap an C +(2m + 17,8) gam¥+H,0Mg, a1] 92,4 gam })Fe RAT mol _, 319 gam ¥ +3,44 gam Z+H,O 0:28,8g = Mayo = 2,095 mol = Dyno, ABE ee 015 mol 63,6gkl = 319 gam | NH,NO, :0,015 mol = a=4,1 => %N =18,125% NO; :a mol Dap an B er Le (Fe,Al,Mg)"“" ty ied . NO: 0,1 Al |-2526,2 gam{{ mig | 8222 mg {{ NOs 44,49) 0° +10 NH,NO,:a N, :0,05 Mg ae uNOs er 0:4,82 HNO, :0,185 Nyjg, =8a+0,1.3+0,05.10+0,3.2 =8a+,4 = 1,85 =8a+1,4+2a+0,2 => a =0,025 = m=134,255 Dap in BGrandidierite Dugc phat hién dau tién vao nam 1902, Grandidierite 1a mot loai ngoc cyc ky hiém gan nhu chi c6 6 vung nam Madagascar. NO dugc dat theo ten nha tham hiém ngudi Phap Alfred Grandidier (1836-1912) chuyén nghién ctu vé ctu lich sur ty nhién cla Madagascar. Grandidierite 6 mau luc nga lam va thé déi ti: mau xanh Jam sang xanh lyc va sang trang. Ngudi ta cing da tim thay mét lugng nhé loai da nay 6 Sri Lanka, Na Uy va My.(py THvvET bIEN PHAN: 1. Bign cue Anot dién cyc duong (anh duong) Catot Bign Cc am (Chi am) 2. Céc Qua Trinh xéy ra trén bé mat dign cue + anot xay ra qué trinh oxi héa (a, o nguyén am) 2Cr —Cl, +2€ H,O—30, +41 +4e San phdm thu duge 6 anot la khi Clo va oxi + Catot xay ra qué trinh khit M" +ne—+M 2H,0+2e—>H, +200" San phéim thu duge 6 catot la Kim loai va hidro. 3, Viét phuong trinh dign phan dung dich Dign phin dung dich muéi sunt ~ mu6i sunfat kim logi truéc nhOm khéng bi din phan dung dich nuéc dign phan - mudi sunfat kim Jogi sau nhém dign phan dung dich thu duige kim loai oxi va H,SO, MSO, +H,0—*“4M+0, +1,80, Dign phin dung dich muéi nitrat: - mudi nitrat kim loai trudc nhém khéng bj dign phan dung dich mudic dign phan - mu6i nitrat kim logi sau nhOm dién phan dung dich thu dugc kim logi oxi va HNO3 MNO, +H,0—*>M +0, +HNO, Dién phan dung dich mudi Clorua kim loai tii nhom vé truéc sin phém thu duigc bazo hidro vado MCI+H,O—#4 MOH+Cl, +H,ign phan dung dich mu6i Clorua kim logi sau nhém sn phém thu Kim Logi va kh{ Clo MCl, —@5M+Cl, 4: Phuong trinh Faraday 1: cutting d6 dong dign don vi Ampe ‘T thai gian don vi gidy F hing s6 faraday F = 96500 5. Thittydign phan & dign cuc catot ion nao cé tinh oxi héa manh dién phan trudc Ghi nhé: Khi thu duige & anot chi o6 thé clo va oxi Khi thu duge 6 catot la hidro nD DIEN PHAN DUNG DICH MUOI KIM LOAI BUNG SAU AL Bai todn dign phan amol dung dich CuSO, dung dich sau khi dign phn cho phan ting voi kim Jogi Fe. Phuong trinh dign phan: CuSO, + H,0—*3Cu440, 1 +H,SO, Dung dich sau dign phan gém cé CuSO, dut va H,SO, tgo thanh nén khi cho dung dich sau Khi dign phin phan ting Fe 06 phan ting xay ra la: Fe+CuSO, — FeSO, +Cu(1) Fe+H,SO, — FeSO, +H,(2) Hoc sinh hay nhm chi viét 1 trong 2 phan ting thi gidi ra két qua sai. Khii lugng chat ran tang lén bang khéi ligng Cu sinh ra phan ting 1 trit Iugng Fe phan ting (1) va 2) - Bai toan dign phan amol dung dich Cu(NO,), dung dich sau khi dign phan cho phan ting voi kim loai Fe. Phuong trinh dién phan: Cu(NO,), +H,0—* 50x40, 7 +2HNO, Dung dich sau dién phan gém cé CuSO, du va HNO, tao thanh nén khi cho dung dich sat khi dign phin phan ting Fe cé phan ting xay ra la:Fe +Cu(NO,), -> Fe(NO,), +Cu(1) Fe+HNO, ~ Fe(NO,), +H,0+NO(2) Hoe sinh hay nhdm chi viét | trong 2 phan ting thi gidi ra két qua sai. Khoi higng chit rén ting lén bing kh6i lugng Cu sinh ra phan ding 1 trit higng Fe phan ting (1) va 2) - Hoc sinh cha ¥ vi chat ran kim logi con dui nén Fe vé sat hai - Logi bai tap ny dung dich sau dign phan thudng gém muGi con du vi axit, - Chui y kim logi phan ting 6 hai phuong trinh. (THPT Ha Huy Tép lan 1 -2016) Dién phan 150 ml dd AgNO, 1M véi dién cuc tro trong t gid, cudng dO dong dién khOng 46 2,68A (higu suat qué trinh dién phan la 100%), tha duge chat rin X, dung dich Y va khi Z. Cho 12,6 gam Fe vao Y, sau khi céc phan ting két thiic thu duige 14,5g hon hgp kim logi va khi NO (sin pham khit duy nhdt cia N“*). Gi tri cia tla A.08. B.0,3. ci. D.1,2. ™ Hudéng dan: 2AgNO, +H1,0—?2Ag+3.0,+2HNO, AgNt AgNO, 10,1525 18 10528 a6 pun te Fe(NO,),: 2,28 HNO, :b 8 519,640,108 = E+) s6414, 5 12,64 108a = 28a +21b+14,5 => 80a~21b=1,9 a+b=0,15 80a-21b=1,9_ fa=0,05 2,681 = =n, =0,1= a+b=0,15 b=0,1 96500 Dap an C (HEED (Nguyén Tat Thanh lin 2 - 2014) Dién phan 200 ml dung dich AgNO, 1M véi dién cyc ‘nc trong t gid, cuting dé dong dign khéng di 2,68A (higu suat qué trinh dign phan 14 100%), thu dugc chat rin X, dung dich Y va khi Z. Cho 16,8 gam Fe vio Y, sau khi cde phan ting két thiic thu duge 22,7 gam hén hgp kim logi va khi NO (sin phd khit duy nhat ciia N'), Gid tricia tla: AOS Bal €.0,25, D2 =3600s=1h Huong dan: 2AgNO, + H,0—24¢+40, +2HNO, AgNO, :a a 3b AgNO, :0,2—#>. EEBBE SS Fe(NO)) SA HNO, :bPE LLad HH 516,8-4a, 108= +32) 564422,7 16,8+108a = 28a+21b+22,7 = 80a~21b=5,9 a+b=0,5 eS eareti =| at+b=0,2 Dap an: B (THPT Chuyén Thai Binh 2016) Dién phan dién cyc tro dd cé a mol Cu(NO,), v6i théi gian 2 git cudng d6 dong dign 1,93A thu duge dd X cé mau xanh, Thém 10,4g Fe vio X, phan ting hoan toin thu duige kh NO (sin phdm khit duy nhat) va 8g hén hgp 2 kim logi. Xéc din gid tri cha a: A015 B.0,125, C.03 D.0,2 1 Huéng din: =0,1 Tn, 20,1 = 298 2360082 1h 1 96500 Cu(NO,), +H0—0u+40, +2HNO, 0,072, 072 — 0,036 —+0,144 n, =0,144 x: [BNO OM oats pe(NNO,), =b+0,05448 a = :b+0, + a Cu(NO,), :b e(NO.), 7 SHE 410,44 64b = 8 +566 +3,024 > b = 0,078 = a= b+x =0,15.mol Dap an: A (THPT Ham Thuan Bac 2016) Dién phan véi dién cuc tro dd chia 0,1 mol Cu(NO,),, cuding dd dong dign 2,68A, trong that gian t (gid), thu duge dd X. Cho 7,2 gam bdt Fe vio X, thu duge kh NO (sin phém khit duy nhat ctia N) va 6,75 gam chét rén. Biét cdc phan ting xy ra hodn ton va higu suat cha qua trinh dign phan la 100%. Gid tri ctia 18 A. 1,00. B. 0,60. €.050. D.1,20. Mt Hudng dan: Cu(NO,), + H,O—>Cu +70 +2HNO, a aa 95928 _JHNO, :2 “|cu(No,), 26 HHL 7,2 + 64b = 6,75 +56b + 42a => 42a —8b = 0,45 ‘a= 0,025 2,68. = 0,05 = 28 b=0,075 96500 —4t% 4 Fe(NO,), :b+0,75a +6, 75g avoaa-| =1800s=0,5h Dap an C($8 GD Quang Nam lin 1 -2016) C6 hai binh dign phan, trong d6 binh (1) dying 20ml dd NaOH 1,73M; binh (2) dung dd g6m 0,225 mol Cu(NO,), va 0,2 mol HCl. Mac néi tiép binh (1) va binh (2). Dign phan céc dd bing dong dién mét chién véi cutdng d6 ding dién khong 446i trong mét thai gian. Khi dting din phan, tho ngay catot & cac binh, Sau phan ting, thy néng 4 NaOH @ binh (1) la 2M. Cho tiép 14 gam bot Fe vio binh (2) dén khi phan ting xay rahoan toan thu duige m gam chat rin kh6ng tan. Biét NO la sin phém khit duy abit ctia N*. Gid tri ma A104. B, C83. D.94 Huéng dan: Binh 1 NaOH khong bi dién phan nén mol NaOH khong d6i V,2=20.1,73=9 V, = 20473 17,3 ‘Thé tich gidm chinh la do H,0 bi dign phan Vso = 20-17,3=2,7 > H,O—>H, +40, yo =0,15:mol = n, =0,3.mol Binh 2 Cu* +2e—Cu 0,15< 0,3 fame af AOA ce Fe+Cu(NO,), —>Fe(NO,), +Cu 0,075 — 0,075.0, 075 3Fe+ HNO, —>3Fe(NO,), +2NO+4H,O 0,30, 1125 DY Fe(NO,), :0,075+0,1125 = 0,1875 HL 0,075.64 +14 = m+0,1875.56 => m=8,3 Dap an: C (Chuyén Vinh Phiic - 2013)Dién phan véi dign cyc tro 500ml dung dich CuSO, dén khi thu dugc 1,12 lit khf (dtc) & anot thi diing lai. Ngém mot Ié sit vao dung dich sau dign phan ‘én khi phan ting hoan toan thi thay la sat tang 0,8 gam. Nong d6 mol cita dung dich CuSO, ban dau la: A. 3,6M. B. 18M. C.0,4M D.1,5M. ™ Huéng dan |Cuso, : du: cuso, 4. a 0, :0,05 f] 397PO alcaad CuSO, + H,O—* Cut 40, 1 +H,S0, 0,1 0,05 0,1 Fe+CuSO, — FeSO, +Cu aca———a Fe+H,SO, ~ FeSO, +H, OLE 01 mer" — mf! = 64a -56a~56.0,1= 0,8 = a =0,8 mol Esso, = NBiso, tnt, =0,840,1=0,9=9C, Dap in B (Chuyén Lé Khiét - 2015)Dign phan (véi dién cuc tro) 500ml dung dich CuSO, néng 4¢ x(M), sau mét théi gian thu dugc dung dich Y c6 khéi lugng gidm 4,0 gam so véi khéi lugng dung dich ban déu, Cho 36,4 gam bt sit vao dung dich ¥ dén Khi phan ting hoan toan, thu duige 38,2 gam kim logi, Gid tri cita x la: A125. B.1,65. €.0,55, D.140, m Huéng dan CuSO, :dv:a_y, ES Cuso, —“4{]H,SO0, 0. Cuso, + H0—*3Cu+40, T +H,SO, bp 98 op mi, =m, +m, = 64b +166 =80b =4— b=0,05 mol =? Dy,so, = 0505 mol poe FeSO, +Cu aca——————a 0,05 0,05 mYt"°—m® = 64a —56a ~56.0,05 = 38,2-36,4 = 1,8 =9 a = 0,575 mol fe +H,SO, + FeSO, +H, = ndigg, =MBso, Nfs, =0,575-+0,05 = 0,625 => C Mewtog 05 Dap nA (Chuyén Quéc Hoc Hué - 2015)Sau mét thai gian dién phan 200ml dung dich CuSO, véi dign cyc graphit, khéi lugng dung dich gidm 8,0 gam. Dé loai bé hét ion Cu** con Iai trong Eadung dich sau dign phan cén phai diung vita hét 8,4 gam bot sat (phan ting véi higu suat 100%). Néng a9 mol/I ban dau cia dung dich CuSO, li: A.1,0M B.1,25M Huéng din CuSO, :du:a_, cuso, “4+, ]H,SO, 0, CuSO, +H,O—24Cu+ " O, T +H,SO, = Mhy.s0, “Mago, = 80X=8=> x= 0,1 Fe+CuSO, + FeSO, +Cu aca =a=0,05 Fe+H,SO,—>FeSO, +H, 0,120,1 (XEDED (PH KHOI A - 2012): Dign phan 150 ml dung dich AgNO, 1M véi dién cyc tro trong t gid, cutting 46 dong dign khong 46i 2,684 (higu suat qué trinh phan 18 100%), thu duge chat rin X, dung dich Y va khi Z. Cho 12,6 gam Fe vio Y, sau khi cdc phan ting ket thitc thu duge 14,5 gam hén hap kim loai va khé NO (san phém khit duy nhat ctia N*). Gi tri cia tla 4.08. B.03. Huéng din AgNO, :0,15mol 2AgNO; +H,O+2Ag+ ; 0; +2HNO, rT AgN( 12, y.JA8NOs 6a. 14 5 {48 HNO; Fe Tacé Fano, _ @ 4° °4 Bio toan nguyén t6 nito suy ra mol NO} 0,25a Byo Tyo; = 0415-Myo =0,15~0,25a Dung dich mu6i sau cing laPO lead Bio todn khéi ligng kim loai ta c6 0,15.108+12,6 = 14,5 + 56(0,075—0,125a)+108a => a=0,1 mo ie tye 5 Hom oy Ok mol =n, =0.1= f= t= 36005 = th Dap an C (Nguyén Tat Thanh lin 2 - 2014) Dién phan 200 ml dung dich AgNO, 1M véi dign cyc tro trong t gid, cudng do dong dign khong d6i 2,68A (higu suat qua trinh dign phan la 100%), thu duigc chat ran X, dung dich Y va khi Z. Cho 16,8 gam Fe vao Y, sau khi cic phan ting két thiic thu duge 22,7 gam hén hgp kim loai va khé NO (san phdm khit duy nhét cia N's). Gia trj chat: AOS BAL €.0,25. D.12 @ Huéng dan AgNO; :0,2 mol 2AgNO; +H,0 > aas+Lo; 4+2HNO; — y eo 126gFe v4 HNO, Tacd Ty = : Bio toin nguyén t6 nito suy ra mol NO; .2— Nyy =0,2-0,25a ee Dung dich musi sau cing la Fe a > n,,,. =0,1-0,1250 NO; :0,2-0,25a Bao toan khéi luigng kim loai ta cé 0,2.108-+16,8= 22,7 + 56(0,1-0,125)+108a = a =0,1 Fal oy =0,1 mol =n, =0,1= "= 1=36008=1h Dap an B (Chuyén Bac Giang - 2014) Dign phan 300 ml dung dich AgNO, 1M véi dién cyte tro trong t gid, cuding do ding dign khong déi 2,68A (hiéu sudt qua trinh ign phan 1a 100%), thu duige chat rn X, dung dich Y va kh{ Z. Cho 22,4 gam Fe vao Y, sau khi céc phan ting két thite thu duigc 34,28 gam hén hop kim loai va khi NO (sin phém Khit duy nhét ciia N*), Gid cha ta ALL2 B. 0,25. C10. D.06,Hyéng din AgNO, :0,3 mol 2AgNO, +H,0 > 2Ag +40; +2HNO, a¢—________4 i freon BARK 434.28 g {ts HINO; Tacd Dyno, _ @ a 0,250 pelea tered: Bio to’n nguyén t6 nite suy ra mol NO; Dy, = 0,3—Myy =0,3-0,25a Dung dich muéi sau cing a Fe? = =, =0,15-0,125a NO; :0,2-0,5a Bao toan khi lugng kim loai ta c6 0,3.108+22,4 = 34, 28 + 56(0,15—0,125a)+108a = a=! an. = 012mol =n, ~012mol— E9128 ‘AgNO3 Dap dn A , cudng d6 ding dign khng adi 1,34A (higu suét qué trinh dign phan la 100%), thu duigc chat rin X, dung dich Y va khi Z. Cho 13 gam Fe vio Y, sau khi céc phan ting két thiic thu dugc 14,9 gam hén hop kim logi va khf NO (sin phim khit duy nhat cha N's). Gid tri cla tla: ALL B.3 1 Hudng din AgNO; :0,15 mol 2080, 10-22-10, +2880, a—___________4 ARNO; _i3gre Ag Zz. SE 14,94 fas Slr. Tacé Bao toan nguyén t6 nito suy ra mol NO} Tyg, = 0,15—Myg = 0,150,254 |> Dung dich musi saw cing la Fe* Sry. =0,075-0,125a NO; :0,15-0,25a 9" Bao to&n khdi higng kim loai ta c6 0,15.108 +13 = 14,9+56(0,075—0,125a) +108a = a= 0,1 = Magog 2x 6 15 59 x, [BNOs 2 CuNO,}2:¥ _ RENO: No =0,5x Bao toan nguyén t6 nits suy ra mol NO; Ryo, =0,4-0,5x Dung dich sau cing chita 2 ty =9 3. =0,2-0,25x NO; :0,4-0,5x 9 © Bio toan khéi lugng kim loa 0,2.64+ 14,4 =13,5+56(0,2-0,25x) + 64x => x =0,05 n, = 2x=0,, 2,68 = 36008=1h 96500 Dép in B Lalu y: Hoc sinh thuiéing sai khi cho sit vé sat III vi sét con du sé vé sit IL cal( DANG B SIEN PHAN CHEO - Dién djch chita hn hop {ACh JAC, BNO,), [B,(SO,), ~ A: ti nhém vé trudc, - B: sau nhom. (CuSO, +2NaCl - Cu+Cl, +Na,SO, 2 = pH<7 CuSO, +1,0—"5Cu +40, T+H,80, (CuSO, a 7 (CuSO, +2NaCl— Cu +Cl, +Na,SO, tJ ants e NaCl:b NaCI +H,O—* > NaOH+ Cl, T +H, T |—*=" 5 {CuSO, +2NaCl > Cu + Cl, +Na,SO, > pH =7 = pH>7 ign phan dung dich gém 11,7 gam NaCl va 28,2 gam Cu(NO,), (dién cic tro, mang ngan x6p) dén khi khéi htgng dung dich giam di 15,1 gam thi ngiing dién phan (gid thiéthigng nuéc bay hoi khong ding ké). Khéi ligng kim loai thost ra 6 cactot la: 7,68. B64. C.96. D.15,1. 1 Huéng dan jane mol CuNO,), :0,15 mol [Cu(NO5), + 2NaCI > CuCl; +2NeNOS or — 02 (CuO, )> + 1,09 6u+40, + 2HINOs =9 my =0,1,135+80x =15,1=9 x =0,02 x mig, “(0.1 +0).64=7,68 g Dap an A. (Doan Thuong - 2014) Dién phan co mang ngin dign cuic tro 100 ml dung dich chia CuSO, NaCl déu c6 néng 46 mol/l la 0,1M véi cuting dé I = 0,5A sau mot thoi gian thu dude dung dich cé pH = 2. Thi gian tign hanh dign phan li: A, 193s B. 19308 C.2123s D. 1737s @ Huéng dan 1, = 0,001 = ny,69, = 5.10% Icad (CuSO, +2NaCl—> Cu+ Cl, +Na,SO, }0,005<—0,01 (CuSO, :0,01 mol apaa tar aay « 1 NaCI: 0,01 mol CuSO, +0 40u+ 302 T+H,SO, 5.104 Ge 2° cy ; Sn, =00l= 21-2123 5,510? 0,011 Dap an C (Dai hoc khéi A - 2013): Tign hanh dign phan dung dich chita m gam hén hgp CuSO, va NaCl (higu sudt 100%, dign cy tra, mang ngin xp), dén khi nuiéc bat dau bi dign phan 6 ca hai dign cic thi ngiing din phan, thu dugc dung dich X va 6,72 li ki (dktc) 6 anot. Dung dich X hoa tan t6i da 204 gam AL,O,, Gié tr cba m Bi: A256. B.235 C511. D.50,4. @ Huéng dan ‘Trudng hop 1: ‘CuSO, + 2NaCl > Cu+Cl, +Na;80, CuSO, 28 aoe 1 eae CuSO, +H,O—#@ Cu +302 T+H,80, 3H,SO, +Al0; — Al; (SO4)3 +3H,0 = Dyzysog = 3Malg05 = 046 mol Cl, :a 043. =0loai foros Goa!) ‘Truong hop 2: (CuSO, +2NaCl—> Cu + Cl; +NazSO, (CuSO, :a gpa, 2928 ae, jee b 2NaCl + H,O—® > 2Na0H + Cl, T HH T x ‘Al,03 +2NaQH ~> 2NaAIO, +H,0 0,2 30,4 x=0,497 anot : Cl, :0,2+2=0,3 = a=0,1 => b=2a+x =0,6mol =m=5i1g Dap anC (REPED (1c Ninh - 2015) Hoda tan 5,11 gam hén hop X gém NaCl va CuSO, vao nude duge dung dich Y. Dign phan dung dich Y véi dign cufc tro, mang ngin x6p dén khi nude bat dau bj digo phan 6 2 din cyc thi ngiing. Thé tich khi 6 anot sinh ra gép 1,5 ln thé tich khi do catot sink cal1a, (cdc khi do cing diéu kign nhiét 46 va 4p suat), Phén tram cia CuSO, vé khéi long trong hon hgp Xk: A. 94,25% B.73,22% C. 68,69% D.31,31% © Huéng dan (CuSO, :2 5,11 gNaCl: 2a +x 160a+117a+58,5x =5,11(1) CuSO, +2NaCl > Cu+ Ch, +Na,SO, guu_|@ 9 2a——+a—a 2NaCl+H,0—252NaOH + Cl, T+H, T x 9, Sx 9 0, 5x, anot:Ch,:a+= 2 catot: Hy! vik ja=0,01 ioe 4X21 5.4 -0,25x-03 a+ 5-155 Q)—a-0,25x=0 { 0,04 = Yomeysoy 7 31,31% Dap én D (Ha Huy Tap - 2014) Khi dign phn 500ml dung dich gém NaCl 0.2M va CuSO, 0,05M ‘v6idign cu tro khi két thuic dign phan thu duge dd X. Phat biéu nao sau day ding: A. Dung dich X hod tan duige kim logi Fe. B. Khi thu duige 8 anot cia binh dign phan la: C. G catot xdy ra sti oxi hod Cu”. D. Dung dich X hoa tan duigc ALO, ™ Huéng dan ae Sb NaCl: 0,1 [CuSO 4 20,025 god rach, [CUSO4+2NaCI > Cu+Chy +NaySO, /NaCl+H,O—22-» NaOH +Cl, T +H, T =pH>7 Loai A. Logi B vi khi 8 anot O,.Cl,. Logi C catot xay ra sui kh, Dap an D [XELLD Dien phan (vdi dign cyc tro) dung dich hén hgp chita 0,1 mol CuSO, vi 0,1 mol KCI dén kkhi dung dich mat mau xanh thi diing lai. Thé tich Khi (dktc) thu duige 6 anot la: A. 1,68 lit. B. 2,8 lit. C. 2,24 lit D112 Hit.oe Lead & Huéng dan NaCl:0,1 080,301 gas sy [CuSO4 +2NeCl > Cu “a +Na,SO4 [480s +H,0—2®>cu +502 7 +H,80, Cl, :0,05 ane 7 => V = 1,68 iit JO, :0,025 Dap an A (Dinh Chuong Duong lin 1 - 2914)Tién hanh dién phan (dién cyc tro, mang ngan xdp) ‘mot dung dich chita m gam hén hgp CuSO, va NaCl cho tdi khi nude bat dau bi dign phan & 2 dign cuc thi diing lai, thu duigc 0,448 lit khi (dktc). Dung dich sau dign phan cé méi truéng axit va cb thé hod tan ti da 0,68 gam Al,O,, Gia tri cia m la: A. 4,955 gam. B.5,385 gam. C.4,370 gam. D.5,970 gam. @ Huéng din (cus0, +2NaCl > Cu+ Cl, +Na,SO. 2 Al,(SO,)5 +3420 => X=Miy50, =3Mqo, = 0,02 mol chy: b 0,02 mol ~7"2 => b= 0,02=9a=—+0,02=0,03 0, :0,01 a fee 0,03 mol = =>m=5,97g NaCl:0.02 mol Dép nD (Hoang Hoa Tham - 2013) Dién phan 200ml dung dich Y gém KCl 0,1M va Cu(NO,), 0,2M véi cuding d6 dong dign 5A trong thoi gian 1158 giay, dién cue tro, mang ngin x6p. Gia sit nutéc bay hoi khong dang ké. DO giim kh6i ligng ciia dung dich sau khi dign phan la: A.3,59 gam. B. 2,31 gam. €. 1,67 gam. D.2,95 gam. 1 Hudng din KC1:0,02mol |Cu(NO,), :0,04mol Cu(NO;); + 2KC1> Cu + Cl, +KNO; 0,01 <——0,02 2b |Ca(NO3), + H,0—23Cu+ to, 7 42HNO 0,02> my =0,01.135+0,02.80= 2,952 1, = 0,06 mol Cut +2e 3 Cu 0,03 > 0,06 Dap an D. (Nguyén Trung Thién - Ha Tinh - 2015) Dign phan 500 ml dung dich hén hgp CuSO, b mol/l va NaCl 1 mol/l véi dign cuic tro, mang ngin x6p, cuding d6 dong dign khong d6i SA trong thdi gian 96,5 phiit (hieu sudt qué trinh dign phan la 100%, nuéc bay hoi khong dang ké) thu dutoc dung dich co kh6i luong gidm so véi ban dau la 17,15 gam. Gis trj cha b la A.O,1, B02. C04. D.03. Hudng din ‘Teudng hop I: CuSO, :a ol NaCl:1 => m= 67,5 >17,15 (loai). ‘Trudng hop 2: (CuSO, +2NaCl—> Cu+Cl, +NaySO, CuSO, +H,0—2 Cu + 702 7 4HLS0, (CuSO, +2NaCl > Cu+Cl; +NazSO, fee a gag [2 2a NaCl: 2NaCl + H,O—2 52NaOH +Cl, T+H, T x => my =135a +36,5x=17,15(1) 2a +x =0,3(2) n= 0,3 mol = n, 135a+36,5x=17,15_ [a=0,1 mol sionals : b=0,2M lee =0,3@) f =0,1 mol Dap an B [XENEDD Dien phan cd mang ngén voi din cyc tro 400 ml dung dich hdn hop gém CuSO, y.M va NaCl 1M véi cuding d6 dong dién 5A trong 3860 giay. Sau khi ngting dign phan thay khéi igng dung dich tao thanh bi gidm so véi ban déu la 10,4 gam. Gia tri cia y la A032 BO. C.0,129 D.0,125, m Huéng dan Truong hop 1: CuSO, 8 pea dart [NaCl:1 (CuSO, + 2NaCI—> Cu + Cl; +Na,SO, Cuso, +H,0 2. Cu+ 30; T+H,80, = my =67,5> 10,4 (loai). 1mae Trung hgp 2: (CuSO, +2NaCl > CuCl; +NaySO, 0, asa [cus est : NaCl:1 2NaCl+ H,O—2->2NaOH +Cl, T +H, = my =135a+36,5x=10,4(1) ,2=9 n= 2a+x=0,2(2) me ee +36,5x=10,4 " = 0,05 mol > = => y=0,125M 2at+x=0,2(2) x=0,1 mol Dép an D (CD KHOI A - 2010): Dién phan (dién cyc tro) dung dich X chtta 0,2 mol CuSO, va 0,12 mol NaCl bing dong dién cé cudng 4} 2A. ‘Thé tich khi (dktc) thoat ra 6 anot sau 9650 gidy ign phan Ri: ALL 344 lit B. 2,240 it. C1792 lit. = Huéng din eect svg. [08804 =2NACL+ C+ Cla +N 80g NaCl: 0,12 mol CuSO, +102 900450, 7 HS0, 2Cl Cl, +2e ig = 0,2 mol—2-5 4 0,12 0,06 > 0,12 2H,0 +0, +4H' +4e = No, =0,02 mol n T=no, + Ne}, = 0,08 mol = V = 1,792 lit Dap an C (Sao Nam - 2015) Dién phan 200 ml dung dich hén hgp CuSO, a (M)va NaCl 0,5 (M) bang dong dign c6 cudmg d6 khong d6i 4A (dign cv tro, mang ngin xp). Sau thai gian t gidy thi ngiing dign phan, thu duigc dung dich Y cé pH =1 (Biét higu suét dign phn 100%, céc ki sinh ra khong tan trong dung dich; V dung dich thay déi khéng dang ké). Gid tr) cba t A. 2895, B. 5790. C.3377,5. D. 4825. = Huéng din pH=l=n .1.0,2 = 0,02 mol 2cr +l, + 26 0,1 9 0,050,1 It =n, =0,12= T= t= 2895 5 2H,0—30, +4H* +4 F 0,02¢ 0,02 + 0,02 > 0,02 Dap an A[XETRED (Cam Thay - 2015) Tién hanh dién phan V lit dung dich NaCl 1M va CuSO, 1,8M (bing dign cx tro mang ngin x6p) tdi khi nudc bat dau dién phan 4 cd 2 dign cue thi diing dién phan, thay khéi ligng dung dich giém m gam. Dung dich sau dién phan hoa tan t6i da 8,84 gam ALO, Gid tri cia m Ri: AL 34,6 B. 34,5 C348 D343 @ Huéng dan Cach 1: 3 mol Bao; = 150 2A1,03 + 6H,S04 — Al, (S04); +3H,0Pny,50, ~3.taiz05 ~ 0.26 mol [CusO, + 2NaCl > Cu +Cl, +Na,SO, v vou foe ABV ead a ceeeeh eee Dain [cus0, + 1,0—2Cu +40, 1 +HA80, 1,3V > 1,3V=0,26= V=0,2 lit => my =o, +Mg,, +Mg, = 0,36.64 + 0,2,35,5+0,13.32 = 34,38 Cach 2: Anot 2Cl Cl, +2e yt 2H,0 > O, + 4H" +4e Catot Cu? +2e— Cu ESV +0,262=3,6V > V=0,2 lit 1,8V 33,6V 91,8 I v my = Mey + Mey, +My = LBV. 571+ 0,26.2 4 4,38 Dap énB [XETEED oan Thugng - 2015) Dign phan cb mang ngin véi dign cuc tro 400 ml dung dich hén hgp gém CuSO, xM va NaCl IM véi cuiting dd dong dign 5A trong 3860 gidy. Sau khi ngiing ign phan thay khdi ligng dung dich tao thanh bi gidm so véi ban dau lai:10,4 gam. Gid tri cita xl: A.0,2. B. 0,1. C.0,125, D.0,129. @ Huéng dan n, = 0,2 molcad act —Cl, +2 anot 0,2<—0,1-0,2 Cu +2e—>Cu 0,4x > 0,8x 0,4x catot 2H,0+2e > H, +201 2y 50,814 2y = 0,2 x= 0,125 mol > = —240,4x.64+ y.2+0,1.71=10,4 y= 0,05 mol Dap an C (Nguyén Trai - 2015) Dién phan dung dich chita x mol NaCl va y mol CuSO, véi dign cue ‘ro, mang ngan x6p dén khi nuiéc bj dién phan 6 2 dign cuic thi ngiing. Thé tich khi 6 anot sinh ra gp 1,5 lan thé tich hi 6 catot 6 cing digu kign nhiét 46 va ép suét. Quan hé gitta x va y l& A.x=6y B.x=3y mt Huéng dan Cy= 15x D.x=13y ‘Anot [ Catot Peslttenttt 2Cr + Cl, +2¢ yy - 2H,O—*>H, + 20H xXx a a aoe x_) a .franst =15 ~Theo dé 13 “155 =f Sa x=6y na x=2y+a —Hoxsdyta Dap an A (XETED (Ping ‘Ihite Huta - 2015)Cho m gam hén hgp CuSO, va NaCl vao nuiéc thu duge dung dich X. Dign phan X véi dign eye tro, mang ngin x6p, dén khi trén catot thu duige 4,48 lit khi & (dktc) thi ngting dign phan. Khi dé thu dugc dung dich ¥ va trén anot thu duge 6,72 lit kh & (dktc), Dung dich Y hoa tan t6i da 10,2 gam ALO,, Gié tri lén nhat clia m li: A. 53,25 gam. B.61,85 gam. .57,55 gam. D.77,25 gam. Hung din Aqiyo4 = O,1mol ‘Trudng hgp 1: NaCl du Al,03 + 20H’ —32A103 +H,0 0,1—90,2(CuSO, + 2NaCl + Cu + Cl, + NaS, a 2a 2NaCl-+ H,0—#42NaOH + Cl,-HH- mg {C2Ss!*_ spar Jo,2 NaCl: b H,O—>H, + x xd Peatot:ngy, =x +0,1=0,2-5 x= 041 = xe = Tanot:ngy, #mo, =@+O,l+%=03-3a=0,15 Cu 15 mol fs ISO, :0,15 mol 3 m=53,25¢ NaCl:0,5mol ‘Trudng hgp 2: CuSO, dz (CuSO, +2NaCl > Cu + Cl, +NazSO, b Je 2 caso, +H,0—-scu+ 10, -4H,80, 3 (CuSO, 22 dpgg | NaCl: H,0—3H, + 50: x x ox 8 2 3H,$0, + Al,0, + Al, (S04), +340 = X=Myys04 =3-Man0; = 0,3 mol Teatot ing, =x =0,2 mol Tanot:ng, + No, ~Zroased CuSO, :0,35_ NaCl:0,1 > nef 185g Dép in B (Lign Son - 2015)Dién phan dung dich chifa 2a mol CuSO, vi a mol NaCl véi cdc dién ae tro cé mang ngn cho dén khi catot bat dau cé khi thoat ra thi ngiing lai thu duigc dung dich X. Biét higu suat ciia qué trinh dign phén dat 100%, Xéc dinh a, biét dung dich X hoa tan vita hét 10,2 gam A,O,. A. 0,3. B.0,1. C.0,6. 1 Huéng din Cuso, du D.0,2.Se obras (CuSO, +2NaCl > Cu + Cl, +Na,SO, a fea CuS04:2a spar, |} tee cuso, + H,0—2c1+40, T+H:80, 03 3H,SO, + Al,O, ~ Al,(SO,); +3H,0 => igo, “0.3128 0,3+5 pa 0,2 80, Dap an D (Chuyén Lé Quy Dén - Da Nang - 2013) Dién phan 100 ml dung dich chita CuSO, 1M va NaCl 1M v6i cée dign cuc tro cé mang ngin. Cuding do dong dign 1a 10A trong théi gian 48 phut 15 gidy (H = 100%), thu duigc dung dich X, Khéi lugng Al t6i da c6 thé hda tan trong dung dich X.(tao ra H,) la: AQ? B09 cal DLB 1 Hung din n, =0,3.mol (CuSO, +2NaCl > Cu +Cl; + Na,S0, eeeaan 0,0s-—0,1 tee 0,1 | cuso, +H,0—24Cu +4o, T+H,80, 0,05 ————__—_——_—_30, 05 2A1+3H,S0,—>Al,(SO,); +3H 1 0 0,05 my =0,98 Dap dn B [XETEED (Chuyén Sut Pham Ha N@i - 2014)Dign phan dung dich chita a mol KCl va b mol CuSO, my phan dung , voi dign cuc tro’ cé mang ngan x6p, cho dén Kkhi dung dich vita hét mau xanh thi thu duige 1,12 Jit khé (dktc) va 500 ml dung dich cé pH = 1 gid tri cia a va b lan luot 1a: A.0,0475 vA0,054 ——B,0,0725va0,085 —C.0,075 va0,0625 —_D, 0,0525 va 0,065 1 Huéng din pH = 1=> CuSO, du (CuSO, + 2KCI—> Cu+Cl, +K,80, a aa ee gg SS CuSO, :b 2 272 fre sa 4 1 CuSO, +H,0O—24Cu +30 T+H,SO, X23 0,Sr—xpH=1>[H"]=0,1=n,, =0,05 mo! = Nyys04 =X = 0,025 mol = no, = 0,0125 mol Ney ,05 -0,0125 == 0,075 mol =>b=0,0625mol Dap an C [XEDEDD Dien phan 250 m! dung dich hén hgp CuSO, a mol/l va NaCl 1,5 mol/l v6i dién cuc tro, mang ngin x6p, cuding do dong dign khong d6i 5A trong thai gian 96,5 phuit (higu suat qué trinh dign phan 1A 100%, nutéc bay hoi khong dang ké) thu duigc dung dich cé khéi lugng gid so véi ban déu la 17,15 gam. Gia tri cia a li: AOS. B.03. C.06. D.04. @ Huéng dan (CuSO, :0,25a NaCl: 0,375 In, =0,3 mot ‘Truong hop 1: CuSO, du. CuSO, + 2NaCl—> Cu + Cl, + Na,S0, — Ste, 10,1875 0,375 + 0,1875 (CuSO, :0,252 NaCl: 0,375 mol cuso, +H,0—2cu +40; 1 4H,80, = m1 25,3125 >17,15 (loai) ‘Truidng hgp 2: NaCl du. (CuSO, + 2NaCl + Cu+ Cl, +Na;S0, iH a ayaa _ }9:25a 0,50 8 | Nacl:0,375 2NaCl+ H,O—25 2NaOH + Cl, P +H, T x PS 40,5a+x= a=0,4 =y 4 = AL 0,252.135436,5x=17,15 [X= 01 Dap an D (Chuyén Vinh lin 1 - 2012) Dign phan (dién cy tro, mang ngin x6p, higu swat 100%) dung dich chita déng théi 0,3mol CuSO, va 0,1 mol NaCl, kim logi thoat ra khi dign phan bam hoan toin vio catot. Khi 6 catot kh6i lugng ting lén 12,8gam thi 6 anot c6 V Iit khi thot ra (dite), Gid tri cha VI: A28 B56 C.4,48 D.2,24 iasas 1m Hudng din Catot ting lén 1A khéi lugng Ca: no, = 0,2 mol CuSO, + 2NaCl + Cu + Cl, +NazSO, t .I—+ 0,05 ) fese O3mol gy [O° 2 30,05 NaCl: 0,1 mol Cus04 +H,0—2 cu +40, T4H,80, [outs =n 1=0,05 + 0,075 = 0,125 mol =V=2,8lit Dp én A [XENEZD (Cd - 2014) Dien phan dung dich hén hop CuSO, 0,05 mol va NaCl bing ding dién c6 cudng do khong 46i 2A (dign cyc tro, mang ngan x6p). Sau thdi gian t gidy thi ngiing dién phan, thu dugc dung dich ¥ va khi 6 hai dign cuic o6 tng thé tich Ia 2,24 lit (dtc). Dung dich Y hoa tan t6i da 0,8g MgO. Biét higu sudt dién phn 100%, cdc kf sinh ra khong tan trong dung dich, Gid tri ctia tld: A. 6755 B72 C. 8685 D, 4825 m Huéng dan (CuSO, #2NaCl + Cu + Ch; +Na,SO, 0,03 — 0,06 ——30,03 — 0,03 cuso, + #02 s0u+40, T+H,80, CuSO, 20,05 gaa | — 10.02 NaClia 1 H,0—H, +50, wx 5 H,S0, + MgO ~ MgSO, + 1,0 => X= Myysoy = Myygo = 0,02 mol 1,5x +0,04=0,L=9 x =0,04 1g = ney, +4119, = 0,06 + 0,03.4=0,18 = te 18685 Dap an C BED (Chuyén Vinh Phic lan 2 - 2013) Dign phan dung dich hén hgp CuSO, a mol va NaCl b mol (dign cu tro, mang ngin x6p). Sau thdi giant gidy thi ngiing dién phan, thu duge dung dich Y va khi thot ra 6 catot e6 thé tich 1a 2,24 lit (dktc) thi ngiing dign phan. Dung dich Y hoa tan t6i da 4 g MgO. Biét higu sudt dign phan 100%, céc khf sinh ra khéng tan trong dung dich, Méi lién hé giita a va b ka: A.2a+0,2=b B.2a=b+0,2 C.2a=b D.2a 0,05 CuNO,), +H,0 Cu 30, +2HNO; x = my = 0,05.135+80x = 11,65 x = 0,06125 CuNO5} Cu(NO,), dir = | NaNO, HNO; Dap an A (Chuyén DHKH Hué lan 1- 2015) Dign phan dung dich chtta 0,2 mol NaCl va x mol Cu(NO,), (dign cuc tro mang ngin x6p) sau mét théi gian thu dugc dung dich X va khdi ktong dung dich gidm 21,5g. Cho thanh sit vio dung dich X dn khi céc phan tng xay ra hoan toan thay khhoi lyvong thanh sét gidm 2,6 g va thay thoat ra khi NO duy nhat, Gi trj cla x li A03 Boa co2 DoS aBeers ; 1 Huéng din ‘NaCl: 0,2mol |Cu(NO5), :x (Cu(NO,), #2NaCl->Cu + Cl) + 2NaNOs 10,1 = <—0,2 —30,1 0,1—0,2 |CuNO,), +8,0-3Ca #02 +2HNO, y =m =0,1 135+80y=21,5—y=0,! CuNO,), 12 CaQNO,), du = | NaNO, :0,2 E+: HINO; :0,2 '3Fe + 8HNO;— 3Fe(NO,), +2NO+4H,0 10,075 <—0,2 Fe+Cu(NO;) — Fe(NO,), + Cu aca my = 56(a + 0,075) - 64a = 2,6 a=0,2=9 x=0,1+ y+a=0,4 mol Dap énB (THPT Dé Luong 1 - 2016) Dign phan dung dich hn hgp CuSO, (0,05 mol) va NaCl bang dong dign cé cuding dé kh6ng d6i 2A (dién cuc tro, mang ngin x6p). Sau théi gian t giy thi ngiing dign phan, thu duge dung dich ¥ va khf c6 téng thé tich la 2,24 lit (dtc). Dung dich Y hoa tan t6i da 0,8 gam MgO. Biét higu suit dign phan 100%, céc khi sinh ra khéng tan trong dung dich. Gid tri cia tla A. 4825. B. 10615. C. 8685, D.6755. Ht Huéng dan: Dung dich sau dign phan hoa tan 0,8 gam MgO suy ra trong dung dich o6 axit H,SO, CuSO, +2NaCl—>Cu+Cl, +Na,SO, a——>2aa 9a CuSO, + H0—s0u+0, +H,S0, bp—__>p 32a 2 H,SO, +MgO— MgSO, +H,0 b——b b=0,02=>a=0,05—0,02 = 0,03 H,O—*>H, +40, x KK x40,sxraed 0,1 = x =0,04 =n, =0,05.242x =0,18= = = t= 8685s + 96500 Dap dn C ca» cho fon Cho bt nteb ~ Bai todn dién phan c.mol MSO, trong thoi gian t gidy, duge y gam kim logi M duy nhat 6 catot va a mol khi é anot. ~ Con néu thdi gian dién phan 1a 2t gidy thi tong s6 mol khi thu ditge 6 cA hai dién cyic lab mol. ~ Théi gian t gidy catot M* +2e—>M anot 2H,0—+0, + 4H" +4e ada 4a ~ Théi gian dign phan 1a 2t giay anot: n, =2.4a=8a=9 no, = 2a my, =b-2a 2H,O—+0, +41" +4e 2a 8a 8a catot M** +2e—>M Jo—2¢ H,0+2e—>H, +20H” 2b~4a— b—2a S88 520+ 2b—4a = 8a = 2c-+2b=12a > c+b=6a ~ khi théi gian dign phan la 2t gidy catot cé khf H, nén ion kim logi M* dién phan hét [HEDMD (DH A - 2011): Hoa tan 13,68 gam mudi MSO, vao nuéc dugc dung dich X. Dign phan X (vdi dign cuc tro, cutdng 46 dong dign khong a6i) trong thoi gian t gidy, dug y gam kim logi M duy nat 6 catot va 0,035 mol khi 6 anot, Con néu thai gian dign phan la 2t gidy thi t6ng s6 mol khi thu duge 6 cd hai dign cy ld 0,1245 mol, Gid tri cita y la: A. 4,480. B. 3,920. C. 1,680. D. 4,788, 1 Huéng dan 1) n9, = 0,035mol Theo dé; 2t +n 1=0,1245 mol |Pe ae t8:2H,0—»0, 14H" +4e=9n, = 4.no, =0,l4mol 2ts=9 n, = 0,28; 2H,0—>0, +4” + 4e =n, =4:ng, =0,28=9 ng, = 0,07 mol = Nyy = 0,1245-0,07 = 0,054 mol Me 22M as2a B20 +0,0545.2 = 0,28 2H,0-—222 5H, +20H" =a =0,0855=M~=64M:Cu =y ous 64=4,48g Dap an A (Chuyén Khoa hoe Ty nhién Ha N@i lan 5 - 2014)Héa tan 2,88 gam XSO, vao nude dug dung dich ¥. Dign phan dung dich Y (v6i dign cuc tro) trong thé gian t giay thi dugc m gam kim loai 6 catét va 0,007 mol khi 6 anot, Néu théi gian dién phan la 2t gidy thi dugc kim loai vA tng s6 mol khi (8 cd 2 bén dign cufc) la 0,024 mol. Gié tri cia m la: A.0,784g. B.O9ig. C.0,896g D.0,336g, B Huéng dan tis) no, = 0,007 mol ‘Theo dé: 2t +n T=0,024 mol ts:2H,O—+0, +4H* + 4e =n, =4.ng, = 0,028 mol 2ts=9 n, = 0,056: 2H,0—30, +41" +4e ng, = 0,056 = no, =0,014 mol = ny, = 0,024—0,014=0,01 mol Met 2M 22a H+ 20+ 0,01.2= 0,056 2H,O—%* 5H, +20" =>a=0,018 => M= 64 M:Cu. Dap an [XETED (rich Dé thi dai hoc khéi A - 2014) Dién phan dung dich X chita a mol CuSO, va 0.2 mol KCl (dign cue tro, mang ngén xp, cung do dong dién khong déi) trong thai gian t gidy, thu duige 2,464 lit khi 6 anot (dktc). Néu thi gian dién phan la 2t gidy thi téng thé tich khi thu duge 6 cd hai dign cyc 18 5,824 It (dktc). Biét higu suat dign phin 100%, cdc Khi sinh ra khéng tan trong dung dich. Gia tri cia ala: A.0,15, B.0,18. C.0,24 D. 0,26. 1 Huéng din t() 9 150,11 mol cal‘Theo dé: 21 > n T=0,26 2Cl > Cl, +2e 0,2 0,1 2H,0—0, + 4H" +4e 2x 9K te) > x=0,015 n, =0,24mol 2CF Cl, +2€ 0,20,1 2H,0—30, +4H* +4¢ dy sy dy 2t(s) => n, = 0,48: => 4y+0,2=0,48 = y= 0,07 = ny, =0,26~0,17 = 0,09mol M22 9M. as 2a E422 +0,09.2=0,48 a= 015 2H,0—* 4H, +20H" Dap an A [XEIED (56 Gido Duc TRHCM - 2015)Dign phan dung dich X chtiaa mol CuSO, va 0,15 mol KCL (dign cuc tro, mang ngan x6p, cuding d6 dng dién khong d6i) trong thé’ gian t giay thu duoc 2,24 lit khi d anot (dktc). Néu thdi gian diém phan la 2t gidy thi t6ng thé tich kb thu duge & 2 dign cyc 1a 4,76 It (4ktc). Biét higu sudt cita qué trinh dién phan dat 100% va cdc khi sinh ra Khong tan trong dung dich. Gié tri cia a &: A.0,20. BOS. €.0,25, D.0,30. Hudng dan 1(s) 3 n T=0,1mol Theo dé: 2t > n T=0,2125 2cr + Cl, +2€ 0,15 3 0,075 rr? > x= 0,025 n, = 0,25 2H,0—0, +4H!' +4e 2x 9x | 2Cr Cl, +2e 0,15 + 0,075 2H,0—30, +4H* +4e 2y yay => 4y +0,075.2=0,5= y = 0,0875 2s) = n, = 0,5 =? My, =0,2125-0,1625 = 0,05 Mt 2 3M a 2a M20 +0,05.2=0,5=3a=0,2 2H,0— 5H, +20H" Dap an A3 Mega book (Chuyén Nguyén Hué - 2012) Hoa tan 4,5 gam tinh thé MSO,,5H,O vao nude duge dung dich X. Dign phan dung dich X v6i dign cyc tro va cudng dé dong dién 1,934. Néu thai gian dign phan la t (3) thi thu duige kim logi M & catot va 156,8 ml khf tai anot. Néu thoi gian dién phan la 2t (s) thi thu duige 537,6 ml Khi, Biét thé tich céc khi do 6 dktc, Kim loai M va théi gian. tan lugt la: A. Niva 1400s, B. Cuva 2800s, C.Niva 2800s. D.Cuva 1400s. i Huéng dan 3) ng, =0,007mo1 Theo dé:2t > n 1=0,024 1(s):2H,0—+0, +4H* + de=9n, = 4.n9, = 0,028mol 24(s) = n, = 0,056; 2H,0—30, + 4H" + 4e No, = 0,056 => no, = 0,014mol => my, ~0,024-0,014=0,01 mol =n, we 225M asa PE 422 +0,01.2= 0,056 2H,0 “24H, +200” =0=0,018= M = 64=3 M:Cu 1,934 (8) > no, = 0,007 mol = n, = 4.n9, = 0,028= => 1=1400s 02 le = Atl 3 ap anD [XETED (é Thi THPT Quéc Gia -2015) Dién phan dung dich mudi MSO, (M la kim loai) v6i dign cyc tro, cuiéing d6 dong dign khong déi. Sau thdi gian t giéy, thu dugc a mol khi 6 anot. Néu thai gien dign phan la 2t gidy thi t6ng s6 mol Khi thu duge 6-c4 hai din cyc la 2,5a mol. Gi sit higu sudt dign phan 18 100%, khi sinh ra khOng tan trong nuéc. Phat biéu nao sau day Rsait ‘A. Khi thu duoc 1,8a mol khi 6 anot thi vin chifa xu hign bot khi 6 catot. B. Tai thoi digm 2t gidy, c6 bot khi 6 catot. . Dung dich sau dign phan o6 pH <7 D. Tai thai digm t gidy, ion M* chuta bi dign phan hét. 1 Huéng dn Dé don gidn chon a=1 Sau thai gian t gidy, thu dudc a mol khi & anot 18 oxi 2H,O— +0, + 4H? +4e=9n, = 4.tto, =4 Sau thét gian 2¢ gia =n, =24=8-rn9, = = 2 ma theo dé 2tgidy thi t6ng 96 mol khi thu dutge & cd hai dién cuc la 2,5a=2,5 mol vay con of 5 mol khi H, 6 catotM?* +2e—_9M x 32x =n, 2H,0 + 2e—H, + 20H 1p =8=2x +0,0.2 9 x=3,5 Khi thu duge 1,8a mol khi 6 anot thi: 21,0 —0, +4H' #4e= a, = 41,872 Bao toane IM? +2e—>M_ x—32x ny =7,2=23,542y + y=0,1(y =m) 2H,0 +2e—>H, +20H Nén @ catot da xudt hign khi khi anot bay ra 1,8 mol khi oxi, nén A sai. ‘Tai thoi digm 2t giay, cb bot khi d catot nén B Diing, Dung dich sau dién phan cé pH <7, nén C ding, ‘Tai thdi digm t giay, ion MP* chwa bj dig phan hét vi tai t giay n,=4 M** +291 | 20M n= 42 2x9 x=2mMAx=35 x—92x nén x chifa dién phan hét, nén D ding. Dap nD Dung dich X chifa m gam chat tan gém Ca(NO,), (Mey¢n0,, > 5gam) va NaCl. Dign phan dung dich X véi dign cuic tro, mang ngin xp v6i cudng d6 dong dign khong Adi. Sau thdi gian t gidy thi thu dug dung dich ¥ chita m-18,79 gam chit tan va cé khi thodt ra 6 catot. Néu thdi gian dién phan la 2t gidy thi thu dugc dung dich Z chita a gam chit tan va hon hop khi T chia 3 Khi va cé ti kh6i hoi so véi hidro la 16. Cho Z vao dung dich chita 0,1 mol FeCl, vi 0,2 mol HCI thi thu dugc dung dich chita a + 16,46 gam chat tan va c6 khi thost ra, Tong gia tri m + ala A73,42 BI72,76 674,56 D.76,24 1m Huéng din Cu(NO,), 2x NaCl: y Sau thoi gian t catot Cu" $2e—3 Cu ax 2 2H,O—2 H, + 20H™ 22¢—2 922 (cmBe Seas Anot: 2c —3Cl, + 2€ (2x-+22)—(2x+22) 64x+ Tix + Tlz—22.17 =18,79 © 135x+372 = 18,79 ten, =2x422 Néu thoi gian dign phan la 2t gidy thi 20s =n, =4x442 catot Cu +2e—> Cu x32 2H, —> H, + 20H" xt dze— xt 229 20+ 42 Anot: 2cr —3Cl,T + 2e yh H,O—30,t + 4H” + de BEY dette y eaeedeny hn hop ki T chita 3 khi va cé ti khéi hoi so véi hidro la 16 cI, t 2% 2 worl, t AMERY og yy = SSDI SD By ne 4 axtidety Hy :xt2z 34x+27,5y +362 = 64x +962 +8y 9 30x +602~19,5p=0 dung djch Z chita a gam chit tan Ho + OH —+H,0 NO; 12x ea Na" iy + "Ch :0,1 Saen tora at é HOCI:0,2 ~~ \3Fe*+4H* = + © NO; —93Fe* +NO+2H,O OH”: y-2x Ol 0,242x-y x 0,2-+3,14+3Lx—15,5y-+17y—34x = 3,54 € 15-34 = 0,24 13524372 =18,79 x=0,12 =3 130x-+602-19,5y =0 = y2=0,07 1,5y—3x=0,24 y=0,4

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