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Core Lab RESERVOIR OPTIMIZATION Reservoir Fluid Study for Gran Tierra Costayaco-3 RFL 0903262 Core Laboratories ea 20 No, 168-52, ogo, Colonia “Tek o57 (1) 5200514 Fa +57 (1) 6730060 Webs hp. cexla.com Core Laboratories Cra. 20 Neo. 168-52 Bogota, Colombia Tol: 57 1 6740400 . ‘Web: htpivu.corelab.com 413th January, 2010 Gran Tierra Energy Bogota, Colombia, Attention: Eng. Fredy Torres Subject: Reservoir Fluid Study Well Costayaco-3, Formation: Caballos, Interval: File: 0903262 Dear Eng. Torres Four bottom hole samples from the subject well were collected on August 06th of 2009 by Core Laboratories representatives and delivered to our fiuid laboratory in Bogota for use in the performance of a Reservoir Fluid Study. The samples were transported to the laboratory whereupon sample validation and analysis commenced, ‘The final report of the Reservoir Fluid Study is presented in the following pages. It has been a pleasure to perform this study for Gran Tierra Energy. Should any questions arise or if we may be of further service in any way, please do not hesitate to contact us. Sincerely, CORE LABORATORIES , Project Coordinator Reservoir Fluids Laboratory Gran Tierra Energy Costayaco-3 RFL 0903262 Table of Contents ‘Section A-Summary of PVT Methods and Data Pag ‘Summary of analysis methods... ALAS ‘Summary of PVT date A4 ‘Section B - Summary of Samples Received and Validation Data) Well information... B4 B2 ‘Summary of samples received - ss ‘Compositional analysis of reservoir fluid sample to C36... ~ CAC2 D1-D2 Graph from constant composition expansion at 206°F. b3 Constant composition expansion at 206°F. Differential vaporization data. e4 Compositional Analysis of Differential Vaporisation Gas to C11+.. £2 Graphs from differential vaporization data... ares £3 Differential vaporization data converted to surface separator conditions... E4ES Reservoir fluid viscosity data at 206" Separator Test No. 1 data. ‘Separator Test No. 2 data... Data used in gas compositional calculations... Data used in liquid compositional calculations... Core Laboratories: Bogota, Colombia Gran Tierra Energy Costayaco-3 RFL 0903262 Core Laboratories Bogota, Colombia Gran Tierra Energy Costayaco-3 RFL 0903262 Summary of Analysis Methods ‘Sample Validation ‘The bubble point pressure at 60°F and free water content of each bottomhole sample were determined as intial quality checks. From this quality control, the measured bubble point pressures of the samples showed good agreement with one another and a low entrained water content. Heat Treatment The selected bottomhole fluid sample was heated to 200°F prior to subsampling for laboratory tests to avoid potential wax deposition problems. Pressurized Fluid Composition Approximately 30 cc of pressurized fluid was flashed to atmospheric pressure at 120 °F and separated into its respective gas and oil phases. The evolved gas and residual liquid were analyzed separately, using gas-liquid chromatography and recombined on a weight basis to produce a C36+ weight percent composition, Gas Compositions Gas composition were measured using a “one shot” Varian 3800 gas analyzer using GPA 2286 method. The gas chromatograph utilizes 3 columns to clearly identify all of the eluted components from N2, CO2 and C1 through C144. The chromatograph is calibrated weekly using air and synthetic hydrocarbon gas with @ known composition, The resultant calibration data is checked statistically against previous calibrations prior to performing analyses on unknown samples. Liquid Composition Residual/stocktank liquid composition were measured using a Varian 3400 chromatograph. The gas chromatograph utilizes a cold on column, "sandwich injection” technique to ensure that a representative sample is injected and swept onto the column. The sample is run twice; first the original fluid and then fluid spiked with n-tetradecane. This allows the laboratory to take into account any heavy end (C36+) losses that may have occurred during the chromatographic run, and make an accurate correction prior to reporting the liquid composition. The data obtained from the gas chromatograph is in weight %. Calculations to mole% and the plus fractions properties are described later. The chromatograph for liquid samples is checked daily, using a gravimetric n-paraffin mix containing a range of pure components from C8 through C36 and a synthetic gas-oil mix (02887) with known composition. The resultant calibration data is checked statistically against previous calibrations prior to performing analyses on unknown samples, Core Laboratories aA Bogots, Colombia Gran Tierra Energy Costayaco-3 RFL 0903262 ‘Summary of Analysis Methods (Continuat Calculation of Mole% Compositions and Plus Fraction Properties The residue or stocktank liquid whole sample molecular weight and density are measured using a cryscope and a PAAR densitometer respectively. The mole% data is calculated using GPSA mole weight and density data, where individual components are identified, from carbon dioxide through decanes. Katz and Firoozabadi data are used from undecanes through pentatriacontanes. The residue mole weight and density values are calculated so that the pseudo average mole weight and density are the same as the measured values. This can lead to anomalous residue mole weights and densities where the Katz and Firoozabadi values may not be suitable for the isomer groups detected. Other alternatives are to use an assumed C36+ molecular weight and density value, use a linear extrapolation technique for components from C10 to C35 to calculate the C36+ properties or to Utilise distillation analysis to produce a 11+, C20+ or C36+ residual oll fraction and physically measure the molecular weight and density. Constant Composition Expansion A portion of the bottomhole fluid sample was charged to a high pressure visual cell at ambient laboratory temperature . The sample was thermally expanded to the reservoir temperature and @ constant composition expansion was carried out during which the bubble point pressure at reservoir temperature was determined. Pressure-volume data for the single phase and two phase fluid were also determined. The density of the single phase fluid was determined by weighing measured volumes pumped from the cell at 6000 psig. Density data for other pressures were calculated using the volumetric data. Differential Vaporization This was carried out in a high pressure visual cell, at reservoir temperature. At several pressure stages below the observed saturation pressure, the sample was stabilized. The gases evolved were then pumped out of the cell and its volume, compressibility and gravities were determined. The final stage was carried out at atmospheric pressure when the residual liquid was pumped out of the cell and its volume, density and molecular weight were measured. Reservoir Fluid Viscosity Live-oil viscosity was measured in an electromagnetic viscometer at reservoir temperature and four temperature steps. Viscosity determinations were carried out over a wide range of pressures from above the reservoir pressure to 100 psig. ‘The measurements were repeated at each pressure stage until five or more results agreed to within 0.5%. The densities, obtained from the constant composition expansion and differential vaporization tests, were used in the caloulation of viscosities in _centipoise. Core Laboratories a2 Bogota, Colombia Gran Tierra Energy Costayaco-3 RFL 0903262 ‘Summary of Analysis Methods (Continuation) Separator Test Finally, two single-stage separator tests were carried out using a pressurized test separator cell. A portion of the bottomhole fluid sample, at a pressure above saturation pressure, was pumped into the separator cell and stabilized at the pressure and temperature required for the first stage separation. The gas evolved was pumped out of the cell and the volume and composition were determined. The final stage was carried out at atmospheric pressure and separator temperature and the density of the residual liquid was determined. Core Laboratories a3 Bogota, Colombia Gran Tierra Energy Costayaco-3 RFL 0903262 ‘Summary of PVT Data Saturation pressure (bubble-point) 336 psig ‘Average single phase compressibility 771 x10-6psit (rom 3098 psig to 336 psig) ‘Thermal expansion at 6000 psig 4.0582 vol/ vol (Vol at 206°F y(Vol at 60°F) Solution gas-oil ratio at saturation pressure 177 scfibbl of residual oil at 60°F Relative oil volume at saturation pressure 1.205 vol/ vol of residual il at 60°F Density at saturation pressure 0.7927 gem3 Viscosity at reservoir pressure 2.122 centipoise at 3098 psig Viscosity at saturation pressure 1.466. centipoise at 336 psig Test 1 336 206 41.154 113 25 158 ° 60 0.8765 Test 2 336 206 4.443 108 30 158 0 60 0.8761 Core Laboratories Aa Gran Tierra Energy Costayaco-3 RFL 0903262 ‘Section B - Summary of Samples Received and Validation Data Core Laboratories Bogoté, Colombia Gran Tierra Energy Costayaco-3 RFL 0903262 Repor and sampling information Reservoir and Well Information i a re Costayaco Wel . Costayaco-03 Reservoir Fluid aitiencieiaenc Blak Ol Formation, itsnninnneeeesesnncnes Caballos (upper and halt) Current Reservoir Pressure .... 3098 psig Reservoir Temperature. 206 °F ‘Sampling Information’ Eas E Date sampled. i 06-Aug-09 Time sampled ..... feces NIA, Type of Samples... BHS Sampling company. ; Core Lab NA NIA Flowing bottomhole pressure... NA Bottomhole temperature... soe NIA Separator pressure ses NIA Separator temperature NA Pressure base. 14.7 psia Temperature Base wen 60°F Separator gas rate... Separator oil rate Gas/oil rate. Water flowrate. Gas gravity (Air = 1)... Supercompressibilty factor. Has. co2 Bsaw...... Oil gravity ‘Comments: * Data provided by GranTierra Energy. Core Laboratories Bi Bogota, Colombia Gran Tierra Energy Costayaco-3. RFL 0903262 ‘Summary of samples received 14 815664 NIA NA 222«65—NIA 0 519 NA 12 815669 NIA NA 343 0«69)—NIA 0 526 NA 13 818428 NIA NA 273° 70—ONIA 0 515 NIA 14 818432, NIA NA 262268 NIA 0 516 NIA Note: 41) Sample cylinder number 815669 was selected for PVT analysis, B2 Core Laboratories Bogota, Colombia Gran Tierra Energy Costayaco-3 RFL 0903262 ‘Section C - Compositional Analysis of Reservoir Fluid Sample to C36+ Core Laboratories: Bogota, Colombia Gran Tierra Energy Costayaco-3 RFL 0903262 Hydrogen Hydrogen Sulphide Carbon Dioxide Nitrogen Methane Ethane Propane Butane Butane Neo-Pentane i-Pentane n-Pentane Hexane: ‘Methyl-Cyclopentane Benzene Cyclohexane © _Heptanes ‘Methy/-Cyclohexane Toluene x Octanes EthyiBenzene MiP-xylene O-xyiene © _Nonanes “Trimethy/Benzene w _Decanes: G;; Undecanes Cy Dodecanes Cy Tridecanes Cy Tetradecanes Cy Pentadecanes Cy Hexadecanes Cy Heptadecanes. Gy Octadecanes Cy Nonadecanes 262 xy Eicosanes 2.05 :, Heneicosanes 1.86 Cs» Docosanes 192 © Tricosanes 1.83 Cx Tetracosanes 71 a5 Pentacosanes 1.67 Cy Hexacosanes 151 ar Heptacosanes 146 Cy Octacosanes. 151 ay Nonacosanes 1.45 Gy Triacontanes 1.46 ©), Hentriacontanes 131 x» Dotriacontanes 427 Cx Tritriacontanes: 124 Cy Tetratriacontanes 412 ss Pentatriacontanes 113 Cust Hexalriacontanes + 31.90 Totals 400.00 ‘Note: 0.00 means less than 0.005. Core Laboratories: ca Bogots, Colombia Gran Tierra Energy Costayaco-3 RFL 0903262 Compo: lus Calculated Residue Properties ©, plus Mote % 7027 Mole Weight (g mol-1) 21 Density at 60°F (g cm-3) 0.8654 Cy plus Molo % 48,76 Mole Weight (g mol-) 340 Density at 60°F (g cm-3) 0.8896 Ca plus Mole % 2378 Mole Weight (g mol) 409 Density at 60°F (g cm-3) 09104 Os plus Mole % 9.69 Molecular Weight (g mol-t) 678 Density at 60°F (g cm-3) 0.9440 Calculated Whole Sample Properties: ‘Average mole weight (9 molt) 206 Core Laboratories Bogota, Colombia C2 Gran Tierra Energy Costayaco-3 RFL 0903262 Section D - Constant Composition Expansion (CCE) at 206°F Core Laboratories Bogotd, Colombia Gran Tierra Energy Costayaco-3 RFL 0903262 Constant Composition Expansion at 206°F Saturation pressure (bubble-point pressure) 336 psig ‘Thermal expansion factor of single phase fluid at 6000 psig (Vol at 206°F)/(Vol at 60°F) 1.0582 vol/vol ‘Average single phase compressibilly (From 3098 psig to 336 psig) 771 x 10-6 psi-t Density at saturation pressure 0.7927 gom-3 6000 000 610 x10-6 000 4000 632x106 4000 3000 661x106 3000 2000 703x106 2000 336 317x106 (1) Mean compressibility = (V2.V1) /(Vt4V2y!2] x 141 = P2) Core Laboratories Bogotd, Colombia ba Gran Tierra Energy Costayaco-3 RFL 0903262 Constant Composition Expansion at 206°F 297.0 1.0421 2973 258.0 4.0878 2.740 230.0 4.1780 2.433, 185.0 1.3652 2070 141.0 4.7301 4.715 113.0 24724 1.489 90.0 2.8018 1.304 680 3.9765 1126 (1) Relative Volume = V /Vsat ie. volume at indicated prossure per volume at saturation pressure, (2) Instantaneous compressibily = (V2.V1)/ V1 x 4(P1-P2) “@)Y-function = (Psat =P )/ (PabsKViVsat- 1). Core Laboratories Bogots, Colombia D2 Gran Tierra Energy Costayaco-3 RFL 0903262 Graphs of Constant Composition Expansion Data 3.500 3.000 2.000 ‘Yfuntion 10 60 10 160 210 260 310 360 Pressure (psig) Core Laboratories Bogota, Colombia D3 Gran Tierra Energy Costayaco-3 RFL 0903262 Core Laboratories: Bogota, Colombia Gran Tierra Costayaco-3 RFL 0903262 250 164 1199 1.355 0.7943 «0.986 0.07026 1.036 150 144 1189 1.861 0.7961 0.986 0.11295 1.139 90 123 1176 = 2.886 0.7999 0.987 0.17785 1316 0 0 1.089 0.8307 1.981 AL 60°F = 1.000 Density of residual oit 0.8877 gem at 6orF “APL ar7 (1) GOR in cubic feet of gas at 14.73 psa and 60°F per barelof residual ol at 60°F. (2) Volume of ol at incicated pressure and temperature por volume of residual ol at 60°F. (@) Volume of ol plus liberated gas at indicated pressure and temperature per volume of residual ol at 60°F. 4) Volume of gas at incited pressure and temperature por volume at 14.73 psia and 60°F. Core Laboratories Bogotd, Colombia E41 Gran Tierra Costayaco-3 RFL 0903262 Test Stage Stage Pressure (psig) He Hydrogen 0.00 0.00 0.00 0.00 28 Hydrogen Sulphide 0.00 0.00 0.00 0.00 60, Carbon Dioxide 645 748 7.15 1.56 Ne Nitrogen 2003 901 290 0.14 C, Methane 4197 3741 26.88 3.18 Ethane 1060 1462 1742 7.34 ©; Propane 11.51 1792 2490 27.20 IC, Butane 186 297 440 (865 nC, n-Butane 409 659 9.92 25.34 Cr Neo-Pentane 001 0.01 002 0.04 iG, i-Pentane 072 110 1.77 698 nCs__n-Pentane 70406 1.70 7. Hexanes: 423 MC Peniane 0.14 0.17 0.28 1.27 Benzene 001 001 02 009 Cyclohexane 0.12 012 020 071 © Heptanes. 029 046 1.71 W-C-Hexane 015 011 019 063 Toluene 0.08 003 0.05 0.09 & _Octanes 0.29 0.15 0.19 0.85 E-Benzene 0.02 0.01 0.11 0.05 MIP-xylene 003 001 002 007 O-xylene 0.01 0.01 001 0.03 G_Nonanes. 0.19 0.08 0.12 0.48 1,2,4-TMB 0.00 0.00 0.00 0.02 Cio _Decanes, ‘G.# Undecanes plus Gas Gravity (Air = 1.000) Note 0.00 means less than 0.008. 1.036 1.139 1.316 1.981 Core Laboratories: Bogotd, Colombia £2 Gran Tierra Costayaco-3 Graphs of Differential Vaporisation ‘Solution Gas-Oil Ratio vs. Pressure RFL 0903262 3 3 Gas-0ll Ratio (sof / bbl) i 100 150 200 350400 11.250 a 8 8 Relative Oil Volume (VIVe) 3 4.000 50 150200 Pressure (psig) 250 30400 Core Laboratories Bogots, Colombia Es to Production Separator Conditions 6000 0.8248 1.109 250 0.7943 101 1.148 0.07026 450 o.7961 at 1139 0.11295, 90 0.7999 6 4127 0.1785 Notes: (1) Ditferental data correctod to surface soparatorcondtions of = ‘Stage + 25 psig and 158° Slage2 psig and 60°F Rs = Refb - (Redo - Rsd) x (Bofb / Bodb) Bo = Bod x (Botb/Bodb) (2) Volume of gas at indicated pressure and temperature per volume at 14.73 psia and 60" Core Laboratories Bogotd, Colombia ea Gran Tierra Costayaco-3 RFL 0903262 Differential Vaporisation Data Converted to Production Separator Conditions 6000 0.8248 1.099 5000 0.8198 1105 4000 0.8146 4.112 3098 Reservoir pressure = 0.809819 3000 0.8092 1.120 2000 0.8036 1128 4000 07974 1.136 800 0.7960 1.138 700 0.7954 4.139 600 07947 4.140 500, 0.7939 4144 400 7932 4.142 336 Saturation pressure 0.7927 10848 250 0.7943 96 1.437 0.07026 150 0.7961 76 4.129 0.11295 80 0.7999 87 1116 0.1785 Notes (1) Diferential data corrected to surtace separator conditions of ‘Stage 1 30 psig and 158°F ‘Stage 2 © psig and 60°F Rs = Ref -(Rsdb- Red) x (Sof / Bod) Bo = Bed x (Bofb/Bodb) (2) Volume of gas at indicated pressure and temperature per volume at 14.73 psia and 60°F. Core Laboratories Bogota, Colombia 65 Gran Tierra Energy Costayaco-3 RFL 0903262 Core Laboratories Bogoté, Colombia Gran Tierra Energy Costayaco-3 RFL 0903262 Reservoir Fluid Viscosity Data at 206° ‘6000 2810 ‘5000 2573 4000 2.336 3000 2.098 2000 1.861 4000 1.624 RAISON ORT A 300 1.494 ‘0.0121 123.3 200 1.580 00116 136.4 400 1.687 0.0108 1556 0 11896 300 2.80 - te Hi ° ‘1000 2000 3000 4000 5000 ‘6000 7000 Pressure (psig) (7) Calculated using the method of Lee. Gonzales and Eakin, JPT, Aug 1966. Core Laboratories Bogota, Colombia Gran Tierra Energy Costayaco-3 RFL 0903262 Core Laboratories: Bogotd, Colombia Gran Tierra Energy Costayaco-3 RFL 0903262 Separator Test No. 1 Data 25 158 70 76 osi77 1.089 1.288 0 68 37 7 0.8733 1.004 1.693 0 80 0 0 0.8765 1.000 Total Rsfo —T15__ Density of residual oit 0.8765 gem-3 at 60°F APL 298 Note: (1) GOR in eubic fee of gas at 14.73 psia and 60°F por bara of ol at indicated pressure and temperature. (2) GOR in eubic feet of gas at 14.73 psia and 60°F per barel of stocktank oat 60°F. (@) Volume of saturated ol at 396 psig and 206° per volume ofstocktank ol at 60°F. (4) Volume of el at indicated pressure and temperature per volume ofstocktank ol at 60°F. Core Laboratories Ga Bogota, Colombia Gran Tierra Energy Costayaco-3 ‘Test No. 1 Gases to C11+ RFL 0903262 Test Stage 1 2 Stage Pressure (psig) 2 0 Hydrogen 0.00 0.00 HS Hydrogen Sulphide 000 © 0.00 60; Carbon Dioxide 619247 Ne Nitrogen’ 867 Ot ©; Methane 2635 5.42 Ethane 1588 11.92 © Propane 2529 37.01 iC. i-Butane 455 B97 nC, n-Butane 9.92 22.06 %Neo-Pentane 002 0.03 iC iPentane 160 3.98 nCs_n-Pentane 1483.66 GHexanes. 0972.15 WEC-Penitane 0210.42 Benzene 001 0.03 Cyclohexane 014 0.25 &_Heptanes 0320.50 M-C-Hexane 012 0.16 Toluene 002 0.03 Cy Octanes: 0150.15 E-Benzene 001 0.00, MWP-xylene oor ot O-xylene 0.00 0.00 ©) _Nonanes 0.07 0.05 4,2,4-TMB, 0.00 0.00 Cy _Decanes. 0.02 0.02 Gx.* Undecanes plus 0.00 0.00 Totals : 400.00 400.00, Gas Gravity (air= 1.000) Core Laboratories Bogotd, Colombia G2 Gran Tierra Energy Costayaco-3 RFL 0903262 Separator Test No. 2 Data 30 158 69, mm 0.8285 1.073 1311 0 6 34 34 0.8727 1.004 1.704 0 60. 0. o 0.8761 1.000 Total Rsf 108 — Density of residual oi! 0.8761 gem-3 at 60°F °APL 2939 Note: (1) GOR in eubic foot of gas at 14.73 psia and 60°F per bare of ol at indicated pressure and temperature. (2) GOR in cubic feet of gas at 14.73 psia and 60°F per barrel of stocktank oat 60°F. (3) Volume of saturated ol at 396 psig and 206° per volume ofstocktank ol at 60°F. (4) Volume of oi at indicated pressure and temperature per volume of stocktank ol at 60°F. Core Laboratories G3 Bogota, Colombia Gran Tierra Energy Costayaco-3 RFL 0903262 ositional to C11+ Test Stage 1 2 Stage Pressure (osig) 30 0 H, Hydrogen 0.00, 0.00 HS Hydrogen Suiphige 0.00 0.00 ©, Carbon Dioxide 501268 Ne Nitrogen | 609 0.38 Ci Methane 2591 527 © Ethane 4525147 Cc, Propane: 25.37 36.07 C.HButane 4779.00 nC, Butane 1020 2364 © Noo-Pentane 002 “0.03, iC. iPentane 188365 nGy_m-Pentane 175353 ._Hoxanes 4142.25 i-C-Peniane 028046 Benzene 002 003 Cyclohoxane 016 028 ci _Heptanes 033056 EC Hexane 0120.18 Toiene oc 908 Cx_Octanes 014 0.16, E-Bonzene ‘0000.01 MP-xylene oor 001 O-¥ylene 000 0.00 C._Nonanes 05005 ‘0000.00 Co 001 0.00, oi ‘0000.00 Totals 7000 | “F0O.00 Gas Gravity (air= 1.000) 1314 1.704 Core Laboratories Bogeta, Colombia Ga Gran Tierra Energy Costayaco-3 RFL 0903262 Core Laboratories Bogota, Colombia Gran Tierra Energy Costayaco-3 RFL 0903262 Data Used in sompositional Calculations ‘Hydrogen * 2016 NIA 33DMC5 * 100.20 0.6954 ‘Oxygeni(Argon) “* 31.999 4.1410 Cyclohexane: + eae 07827 Nirogen (Conected) “* 28013 0.8086 -2MOB230MC5 + 10020 06917 Mathane ~ 46043 0.2097 THDMcYcsaMcs = + «9920 «0.7253 Carbon Dioxide “44010 «0.8172 HSOMCYCS. + 981907528 Ethane “30070 0.3558 cISDMCYCSINECS «© 9920 © 0.7262 Hydrogen Sulphide “= 34.080 0.8006 {1ZDMCYCS + 981907554 Propane 44.097 0.5065 Heptanes (nC7) * 100.20 0.6875 Butane 58123 0.5623 2aDMoS + 4147306994 Butane “58123 0.5834 = MCYCS + 9819 07740 Noo-Pentane = * 72.15 0.5968 ECYCS + 981907704 iPentane “ 7a150 0.6238 22STMCSI248250MCS 11423 © 0.7060 n-Pentane “ 72150 0.6305 clet2aTMCYCS. = 12217511 220MCA + 86.18 0.8529 letzaTWCYCS «== 112.21 O7574 2aoMeAicyes «+ «7815 «O19 Toluene: + e244 e734 ‘2MC5 + 86.18 0.6572 Octanes (nC8) 7 114.23 0.7063 aMcs, + 66.18 0.9682 E-Benzene + 40617 08735 Hexanes (nC6) > «86.18 0.8631 MP Xylene + 40617 gor 220Me5 10020 0.6814 O-Xylene + 10617 08840 Mec-Pentane —* 8416. -——«O.7533.—_‘Nontanes (09) + 42825 o7212 2aDMes + 40020 06757 Decanes 36 2asTMce + 10020 0.6947 Undecanes MT Benzene + 7e41 018820 Dodecanes 461 Note : ‘The gas mole % compositions were calculated from the measured weight % compositions using the most detailed analysis results, involving as many of the above components as were identified. The reported component mole % compositions were then sub-grouped into the generic carbon number ‘components. Core Laboratories Ha Bogota, Colombia Gran Tierra Energy Costayaco-3 Data Used in Oil Compositional Calculations Hydrogen Hyd. sulphide Carbon Dioxide Nitrogen Methane Ethane Propane Butane Butane -Pentane n-Pentane Hexanes Me-cyclo-pentane Benzene Cyclo-hexane Heptanes Me-cyclo-hexane Toluene Octanes Ethy-benzene MetalPara-xylene Ortho-rylene. Nonanes 4-2-4-T-M-benzene Note : ‘The residue mole weight and density values ( eg heptanes plus, undecanes plus, eicosanes plus) are calculated so that the calculated average mole weights and densities correspond with the measured values. This can lead to anomalous residue mole weights and densities where the Katz and Firoozabadi values may not be suitable for the isomer groups detected. bane 2.016 34.080, 44.010 28.013 16.043 30.070 44.097 98.123, 58.123, 72.180 72.150 86.177 84.16 78.11 84.16 100.204 98.19 92.14 114.231 106.17 108.17 106.17 128.258, 120.19 142.285 Undecanes “ Dodecanes, oa Tridecanes Tetradecanes Pentadecanes Hexadecanes *** Heptadecanes —* Octadecanes Nonadecanes *** Eicosanes Heneicosanes *** Docosanes ‘ Th es Telracosanes Pentacosanes *** Nonacosanes “** Triacontanes —*** Hentriacontanes *** Dotriacontanes: Tritiacontanes Tetratriacontanes “** Pentatriacontanes *** 147 472 RFL 0903262 0.789 0.800 ost 0.822 0.832 0.839 08a7 0.852 0.887 0.867 0.872 o877 0.881 0.885 0.889 0.893 0.896 0.899 0.902 0.908 0.909 osi2 asta osi7 Core Laboratories Bogota, Colombia Ha Gran Tierra Energy Costayaco-3 RFL 0903262 Report prepared by fp Zs Akinloye Akinokun Project Coordinator Reservoir Fluid Laboratory Reservoir Fluid Laboratory Core Laboratories Bogota, Colombia

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