feat of : ferriarroy WHS ¢ AP Chemistry 6 * Thermochemistry ENTHALPY . Calculate the heat evolved when 266 g of white phosphorus (Ps) burns in air according to the equation Pa(s) + 5 Ox(g) > PaOjo(s) AH = -3013 ki/mol 2004 Py Wr Lai | 3013 ES - = : 123 25% : ATO KI \mo) & . Determine the amount of heat (in kJ) given off when 1.2610" g of NO) are produced according to the equation 2 NO(g) + Ox(g) > 2NOxg) AH = 114.6 kJ/mol _ |, 26X10 %qNO2| { mol NOs [oI H-wkd Yo.ol 4 N03 fPmo! NO, ‘What is AU for the formation of 1 mole of CO at | atm and 25°C? Cleraphite) +4 0g) CO®) AH=-110.5kHmol AN= | - 1.57 25 AU= AH-RT SN _ = i0.5 — £008 3x28 +8] =— (NI eT /mo} Consider the reaction 2 H20(g) > 2 Hx(g) + Ox(g)_ AH = 483.6 kI/mol. If 2.0 moles of H:O(g) are converted to H:(g) and O2(g) against a pressure of 1.0 atm and 125°C, what is AU for this reaction? DU=sdbH-An RT 823 o= 1 a = 483. ERC] x 0085) 298) = HAO KJ /mul F5lereh Fe Which of the constant-pressure processes shown here has the smallest difference between AU and AH, and why? 7 Not jnvolve ‘a. Water -> water vapor For rxns ‘that do Water — ice gases AVIS Usually very small H. : aqliy the same as OW c. Ice watervapr So AU is Practica a |. 574101 eT # Which of the following does not have AH"; ~0 at 25°C? Why not? a ea Fa) Hp Mercury 'S liquid ©. Cul a ©. Erg) fle @ room +emp (most stable) 7. Benzene (CsHs) burns in air to produce carbon dioxide and liquid water. Calculate the heat released (in kilojouls) per gram of the compound reacted with oxygen, The standard enthalpy of formation of benzene is 49.04 kiimole. He, = En OHS (products )— =m DH (reactants) 2 CuHyt5O,—a!2C O76 HhO Dian = [i <-393,5) (6--45.0)]— 6) te) [fis-0)+ Oleot) 8. Calculate the heats of combustion for the following reactions from the standard enthalpies listed in — —U],83 Appendix 3 in your book. ° 2 Callie) +3 Ox@)>2.00%4)+ 2120) 1. DB ocx “ky b. 2HDS(g) +3 Ox(g) > 2 HO(4) + 2 SOXe) 4B.A) Min =[(2--285,0)4 (2--393.5)] ~ [(2-0)+(62.2)] = - 1410.9 KYnol 2) Drm =| (a+ 290.4)+(2+ 26.)| 7 [6-o) +02: 720.15)| = 1124.) T/mo} DHryen = Z Dp gered) — & DA} (rene