other elements such as nitrogen (N), phosphorus (P), and iron (Fe) and numerous minor elements are of immense biological importance but are usually minor contributors to total salinity. soft waters refers to waters of low salinity, which are usually derived from drainage of acidic igneous rocks (Hutchinson, 1957). Hard waters contain large concentrations of alkaline earths, usually derived from the drainage of calcareous deposits. The salinity of fresh waters is best expressed as the sum of the ionic composition of the major cations and anions in mass or milliequivalents per liter. The quantity total solids, an estimation of inorganic materials dissolved in water by evaporation to dryness (1050 C), is less satisfactory. Combustion of the residue at 5500 C yields the nonvolatile solids per unit mass or volume, as C02 from organic carbon is lost. However, MgC03 and some alkalis and chlorides, which are true nonvolatile solids at normal temperatures, will also release C02 at 5500C and cause a considerable underestimate of the nonvolatile solids.
ll. SALINITY DISTRIBUTION IN WORLD SURFACE
WATERS AND CONTROL MECHANISMS
The salinity of the surface waters of the world is
highly variable and depends upon ionic influences of drainage and exchange from the surrounding land, atmospheric sources derived from the rock—soil, ocean, and human activity, and equilibrium and exchange with sediments within the water body. The global mean salinity of river water is 120 mg liter-I (Table 10-1; Livingstone, 1963; Walling and Webb, 1986), a value somewhat lower than Clarke's (1924) average but based on better data that compensate for the large