ANALISIS QUIMICO

a- Calcular el Balance iónico o análisis químico para comprobar la calidad

del análisis. Debe calcular el error de análisis y confirmar que el error
(E) <10 % de los pozos monitoreados.

𝑬 = 𝟏𝟎𝟎 ∗ (𝒄𝒂𝒕𝒊𝒐𝒏𝒆𝒔 − 𝒂𝒏𝒊𝒐𝒏𝒆𝒔)/(𝒄𝒂𝒕𝒊𝒐𝒏𝒆𝒔 + 𝒂𝒏𝒊𝒐𝒏𝒆𝒔)

Muestra A5
𝒎𝒈 𝟔𝟏𝒎𝒈
𝑯𝑪𝑶𝟑 = 𝟏𝟖𝟔, 𝟔𝟔 / = 3,06
𝑳 𝟏𝒑𝒆𝒒

𝒎𝒈 𝟒𝟖𝒎𝒈
𝑺𝑶𝟒 = 𝟖𝟏, 𝟔𝟏 / = 1,7
𝑳 𝟏𝒑𝒆𝒒

𝒎𝒈 𝟑𝟓,𝟓𝒎𝒈
𝑪𝑳 = 𝟐𝟗, 𝟗𝟗 / = 0,845
𝑳 𝟏𝒑𝒆𝒒

𝒎𝒈 𝟔𝟐𝒎𝒈
𝑵𝑶𝟑 = 𝟒𝟏, 𝟑𝟒 / = 0,667
𝑳 𝟏𝒑𝒆𝒒

∑ 𝟑, 𝟎𝟔 + 𝟏, 𝟕 + 𝟎, 𝟖𝟒𝟓 + 𝟎, 𝟔𝟔𝟕 = 𝟔, 𝟐𝟕𝟐

𝒂𝒏𝒊𝒐𝒏𝒆𝒔
𝒎𝒈 𝟐𝟑𝒎𝒈
𝑵𝒂 = 𝟑𝟎, 𝟓𝟗 / = 1,33
𝑳 𝟏𝒑𝒆𝒒

𝒎𝒈 𝟐𝟎𝒎𝒈
𝑪𝒂 = 𝟖𝟒, 𝟐𝟎 / = 4,21
𝑳 𝟏𝒑𝒆𝒒

𝒎𝒈 𝟑𝟗,𝟏𝒎𝒈
𝑲 = 𝟐, 𝟑𝟓 / = 0,06
𝑳 𝟏𝒑𝒆𝒒

𝒎𝒈 𝟏𝟐𝒎𝒈
𝑴𝒈 = 𝟐𝟒, 𝟗𝟑 / = 2,078
𝑳 𝟏𝒑𝒆𝒒

∑ 𝟏, 𝟑𝟑 + 𝟒, 𝟐𝟏 + 𝟎, 𝟎𝟔 + 𝟐, 𝟎𝟕𝟖 = 𝟕, 𝟔𝟕𝟖
𝒄𝒂𝒕𝒊𝒐𝒏𝒆𝒔

𝑬 = 𝟏𝟎𝟎 ∗ (𝟕, 𝟔𝟕𝟖 − 𝟔, 𝟐𝟕𝟐)/(𝟕, 𝟔𝟕𝟖 + 𝟔, 𝟐𝟕𝟐)

𝑬 = 𝟏𝟎𝟎 ∗ (𝟏, 𝟒𝟎𝟔)/(𝟏𝟑, 𝟗𝟓) = 𝟏𝟎, 𝟎𝟖%

Muestra P1
𝒎𝒈 𝟔𝟏𝒎𝒈
𝑯𝑪𝑶𝟑 = 𝟐𝟗𝟒, 𝟎𝟐 / = 4,82
𝑳 𝟏𝒑𝒆𝒒
 𝒎𝒈 𝟒𝟖𝒎𝒈
𝑺𝑶𝟒 = 𝟏𝟐, 𝟖𝟐 / = 0,267
𝑳 𝟏𝒑𝒆𝒒

𝒎𝒈 𝟑𝟓,𝟓𝒎𝒈
𝑪𝑳 = 𝟏𝟒𝟐, 𝟒𝟔 / = 4,013
𝑳 𝟏𝒑𝒆𝒒

𝒎𝒈 𝟔𝟐𝒎𝒈
𝑵𝑶𝟑 = 𝟎, 𝟐𝟓 / = 0,004
𝑳 𝟏𝒑𝒆𝒒

∑ 𝟒, 𝟖𝟐 + 𝟎, 𝟐𝟔𝟕 + 𝟒, 𝟎𝟏𝟑 + 𝟎, 𝟎𝟎𝟒 = 𝟗, 𝟏𝟎𝟒

𝒂𝒏𝒊𝒐𝒏𝒆𝒔
𝒎𝒈 𝟐𝟑𝒎𝒈
𝑵𝒂 = 𝟏𝟖𝟒, 𝟔𝟗 / = 8,03
𝑳 𝟏𝒑𝒆𝒒

𝒎𝒈 𝟐𝟎𝒎𝒈
𝑪𝒂 = 𝟏𝟎, 𝟔𝟎 / = 0,53
𝑳 𝟏𝒑𝒆𝒒

𝒎𝒈 𝟑𝟗,𝟏𝒎𝒈
𝑲 = 𝟏, 𝟏𝟕 / = 0,03
𝑳 𝟏𝒑𝒆𝒒

𝒎𝒈 𝟏𝟐𝒎𝒈
𝑴𝒈 = 𝟏𝟕, 𝟕𝟗 / = 1,483
𝑳 𝟏𝒑𝒆𝒒

∑ 𝟖, 𝟎𝟑 + 𝟎, 𝟓𝟑 + 𝟎, 𝟎𝟑 + 𝟏, 𝟒𝟖𝟑 = 𝟏𝟎, 𝟎𝟕𝟑

𝒄𝒂𝒕𝒊𝒐𝒏𝒆𝒔

𝑬 = 𝟏𝟎𝟎 ∗ (𝟏𝟎, 𝟎𝟕𝟑 − 𝟗, 𝟏𝟎𝟒)/(𝟏𝟎, 𝟎𝟕𝟑 + 𝟗, 𝟏𝟎𝟒)

𝑬 = 𝟏𝟎𝟎 ∗ (𝟎, 𝟗𝟔𝟗)/(𝟏𝟗, 𝟏𝟕𝟕) = 𝟓, 𝟎𝟓𝟑%
Pozo 7

Formula aplicada
(𝒄𝒂𝒕𝒊𝒐𝒏𝒆𝒔 − 𝒂𝒏𝒊𝒐𝒏𝒆𝒔)
𝑬 = 𝟏𝟎𝟎 ∗
(𝒄𝒂𝒕𝒊𝒐𝒏𝒆𝒔 + 𝒂𝒏𝒊𝒐𝒏𝒆𝒔)
𝒎𝒈
𝒎𝒆𝒒 𝒍
𝒑𝒓𝒊𝒎𝒆𝒓𝒐 𝒂𝒑𝒍𝒊𝒄𝒂𝒎𝒐𝒔 = ∗ 𝒗𝒂𝒍𝒆𝒏𝒄𝒊𝒂
𝑳 𝒑𝒆𝒔𝒐 𝒎𝒐𝒍𝒆𝒄𝒖𝒍𝒂𝒓

𝒎𝒈
𝟏𝟏𝟗𝟖, 𝟎𝟒
𝑯𝑪𝑶𝟑 = 𝑳 ∗ 𝟏 𝒎𝒆𝒒 = 𝟏, 𝟗𝟔𝟒 𝒎𝒆𝒒
𝟔𝟏 𝒎𝒈 𝒍
 𝒎𝒈
𝟏𝟒, 𝟏𝟐
𝑺𝑶𝟒 = 𝑳 ∗ 𝟐 𝒎𝒆𝒒 = 𝟎, 𝟓𝟖𝟖 𝒎𝒆𝒒
𝟒𝟖 𝒎𝒈 𝒍

𝒎𝒈
𝟒𝟏𝟗𝟖, 𝟕𝟎
𝒄𝒍 = 𝑳 ∗ 𝟏 𝒎𝒆𝒒 = 𝟏𝟒, 𝟏𝟔𝟕 𝒎𝒆𝒒
𝟑𝟓, 𝟓 𝒎𝒈 𝒍

𝒎𝒈
𝟎, 𝟖𝟏
𝑵𝑶𝟑 = 𝑳 ∗ 𝟏 𝒎𝒆𝒒 = 𝟎, 𝟎𝟏𝟑 𝒎𝒆𝒒
𝟔𝟐 𝒎𝒈 𝒍

𝒎𝒆𝒒 𝒎𝒆𝒒 𝒎𝒆𝒒 𝒎𝒆𝒒

{𝟏, 𝟗𝟔𝟒 + 𝟎, 𝟓𝟖𝟖 + 𝟏𝟒, 𝟏𝟔𝟕 + 𝟎, 𝟎𝟏𝟑
𝒍 𝒍 𝒍 𝒍
= 𝟏𝟔, 𝟕𝟑𝟐𝒂𝒏𝒊𝒐𝒏𝒆𝒔}

𝒎𝒈
𝟑𝟑𝟗𝟒, 𝟖𝟎
𝑵𝒂 = 𝑳 ∗ 𝟏 𝒎𝒆𝒒 = 𝟏𝟒, 𝟕𝟔𝟎 𝒎𝒆𝒒
𝟐𝟑 𝒎𝒈 𝒍

𝒎𝒈
𝟒𝟒, 𝟒𝟎
𝑪𝒂 = 𝑳 ∗ 𝟐 𝒎𝒆𝒒 = 𝟒, 𝟒𝟒 𝒎𝒆𝒒
𝟐𝟎 𝒎𝒈 𝒍

𝒎𝒈
𝟏𝟑𝟑, 𝟕𝟐
𝑲= 𝑳 ∗ 𝟏 𝒎𝒆𝒒 = 𝟑, 𝟒𝟐𝟖 𝒎𝒆𝒒
𝟑𝟗 𝒎𝒈 𝒍

𝒎𝒈
𝟏𝟒𝟕, 𝟔𝟐
𝑴𝒈 = 𝑳 ∗ 𝟐 𝒎𝒆𝒒 = 𝟐𝟒, 𝟔𝟎𝟑 𝒎𝒆𝒒
𝟏𝟐 𝒎𝒈 𝒍
 𝒎𝒆𝒒 𝒎𝒆𝒒 𝒎𝒆𝒒
{𝟏𝟒, 𝟕𝟔𝟎 + 𝟒, 𝟒𝟒 + 𝟑, 𝟒𝟐𝟖 + 𝟐𝟒, 𝟔𝟎𝟑
𝒍 𝒍 𝒍
= 𝟒𝟕, 𝟐𝟑𝟏 𝒄𝒂𝒕𝒊𝒐𝒏𝒆𝒔}

Formula aplicada
(𝟒𝟕, 𝟐𝟑𝟏 − 𝟏𝟔, 𝟕𝟑𝟐) 𝟑𝟎, 𝟒𝟗𝟗
𝑬 = 𝟏𝟎𝟎 ∗ = = 𝟎, 𝟒𝟕𝟔%
(𝟒𝟕, 𝟐𝟑𝟏 + 𝟏𝟔, 𝟕𝟑𝟐) 𝟔𝟑, 𝟗𝟔𝟑
𝑒𝑟𝑟𝑜𝑟 𝑎𝑑𝑚𝑖𝑠𝑖𝑏𝑙𝑒 𝑏𝑎𝑙𝑎𝑛𝑐𝑒 = 0,476

Pozo 8
(𝒄𝒂𝒕𝒊𝒐𝒏𝒆𝒔 − 𝒂𝒏𝒊𝒐𝒏𝒆𝒔)
𝑬 = 𝟏𝟎𝟎 ∗
(𝒄𝒂𝒕𝒊𝒐𝒏𝒆𝒔 + 𝒂𝒏𝒊𝒐𝒏𝒆𝒔)
𝒎𝒈
𝒎𝒆𝒒 𝒍
𝒑𝒓𝒊𝒎𝒆𝒓𝒐 𝒂𝒑𝒍𝒊𝒄𝒂𝒎𝒐𝒔 = ∗ 𝒗𝒂𝒍𝒆𝒏𝒄𝒊𝒂
𝑳 𝒑𝒆𝒔𝒐 𝒎𝒐𝒍𝒆𝒄𝒖𝒍𝒂𝒓

𝒎𝒈
𝟓𝟖𝟎, 𝟕𝟐
𝑯𝑪𝑶𝟑 = 𝑳 ∗ 𝟏 𝒎𝒆𝒒 = 𝟑𝟓, 𝟒𝟐𝟑 𝒎𝒆𝒒
𝟔𝟏 𝒎𝒈 𝒍

𝒎𝒈
𝟖, 𝟔𝟖
𝑺𝑶𝟒 = 𝑳 ∗ 𝟐 𝒎𝒆𝒒 = 𝟎, 𝟑𝟔𝟏 𝒎𝒆𝒒
𝟒𝟖 𝒎𝒈 𝒍

𝒎𝒈
𝟏𝟏𝟕𝟒, 𝟔𝟎
𝒄𝒍 = 𝑳 ∗ 𝟏 𝒎𝒆𝒒 = 𝟑, 𝟑𝟎𝟖 𝒎𝒆𝒒
𝟑𝟓, 𝟓 𝒎𝒈 𝒍

𝒎𝒈
𝟎, 𝟓𝟎
𝑵𝑶𝟑 = 𝑳 ∗ 𝟏 𝒎𝒆𝒒 = 𝟎, 𝟎𝟎𝟖 𝒎𝒆𝒒
𝟔𝟐 𝒎𝒈 𝒍
 𝒎𝒆𝒒 𝒎𝒆𝒒 𝒎𝒆𝒒 𝒎𝒆𝒒
{𝟑𝟓, 𝟒𝟐𝟑 + 𝟎, 𝟑𝟔𝟏 + 𝟑, 𝟑𝟎𝟖 + 𝟎, 𝟎𝟎𝟖
𝒍 𝒍 𝒍 𝒍
= 𝟑𝟗, 𝟏 𝒂𝒏𝒊𝒐𝒏𝒆𝒔}

𝒎𝒈
𝟓𝟐𝟖, 𝟕𝟕
𝑵𝒂 = 𝑳 ∗ 𝟏 𝒎𝒆𝒒 = 𝟐𝟐, 𝟗𝟗 𝒎𝒆𝒒
𝟐𝟑 𝒎𝒈 𝒍

𝒎𝒈
𝟏𝟐𝟎, 𝟒𝟎
𝑪𝒂 = 𝑳 ∗ 𝟐 𝒎𝒆𝒒 = 𝟏𝟐, 𝟎𝟒 𝒎𝒆𝒒
𝟐𝟎 𝒎𝒈 𝒍

𝒎𝒈
𝟑, 𝟓𝟐
𝑲= 𝑳 ∗ 𝟏 𝒎𝒆𝒒 = 𝟑𝟎, 𝟎𝟗𝟎 𝒎𝒆𝒒
𝟑𝟗 𝒎𝒈 𝒍

𝒎𝒈
𝟏𝟓𝟔, 𝟎𝟗
𝑴𝒈 = 𝑳 ∗ 𝟐 𝒎𝒆𝒒 = 𝟐𝟔, 𝟎𝟏𝟓 𝒎𝒆𝒒
𝟏𝟐 𝒎𝒈 𝒍

𝒎𝒆𝒒 𝒎𝒆𝒒 𝒎𝒆𝒒 𝒎𝒆𝒒

{𝟐𝟐, 𝟗𝟗 + 𝟏𝟐, 𝟎𝟒 + 𝟑𝟎, 𝟎𝟗𝟎 + 𝟐𝟔, 𝟎𝟏𝟓
𝒍 𝒍 𝒍 𝒍
= 𝟗𝟏, 𝟏𝟑𝟓 𝒄𝒂𝒕𝒊𝒐𝒏𝒆𝒔}

Formula aplicada
(𝟗𝟏, 𝟏𝟑𝟓 − 𝟑𝟗, 𝟏) 𝟓𝟐, 𝟎𝟑𝟓
𝑬 = 𝟏𝟎𝟎 ∗ = = 𝟎, 𝟑𝟗𝟗%
(𝟗𝟏, 𝟏𝟑𝟓 + 𝟑𝟗, 𝟏) 𝟏𝟑𝟎, 𝟐𝟑𝟓
𝑒𝑟𝑟𝑜𝑟 𝑎𝑑𝑚𝑖𝑠𝑖𝑏𝑙𝑒 𝑏𝑎𝑙𝑎𝑛𝑐𝑒 = 0,399%