tips
Thursday, November 8, 2018
T oipot
Ionization energy = ‘effective nuctear charg J someroaes
“IE potential is the energy to take out e. So itis high at F b/c F no want its e out. Zeff shows how strongly each valence e
is attracted to its nucleus, and it shows core energy charge. Atoms are getting smaller across due to e being strongly
compressed together at the nucleus. And it's hard to take e out due to Zeff.
7 ectronegativtydference t 9% ionic character
‘Pond distance = bond energy
multiple bonds are short but stronger
*each bond has 2e
Lewis Dot= look at valence e at electron configuration, get octet rule on each atom
JONIC BONDS
Bulk properties
Lattice energy (-) : energy released through cation + anion make ionic
Coulomb's Law= explains the force of attractions in relationship the charges of ions and the distance
More lattice = more attractions b/w ions
Find Lattice Energy:
1L. Look at charge. Higher + charge means higher lattice
a. Effect of ionic charge (more charge = more exo (-) )
2. Look at atomic radius. More atomic size
a. Effect of ionic size (more distance = less exo )
COVALENT BONDS
Discrete units
Bond Energy (+) = indicate the supply of energy to separate atoms
“found by intramolecular force (bonds within individual molecules)
Vs lattice = "energy released! (.) = bonds are formed
LOOK @ Intermolecular Force= the weaker attractions between neighboring molecular
“explains how s--> I—-> g
LDF: Occurs on every covalent/intermolecular forces. Big mass = more surface area (hotdog) = high Boiling point
Comparing intermolecular forces:
1L. Look for LDF. Find the largest mass. (needs to be large difference)Cpk (color of atoms model)
Thursday, November 8, 2018
1020 AM
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B c N ° P
si P s aa. Small atomic mass have tighter e clouds
b. Big atomic mass have loose e, so create more temporary dipole moments
2. Similar mass=LDF are equal
a. Look for h bonds
i, Combines with F ON with...
1) HasH donor
2) Lone pairs/valence electrons as H acceptors
a) HF works only (rest of Fno work = immiscibilty)
li, Exceptions: H bond donors on CCI3H and CF3H
b. Look for dipole dipole moment
i. Find electronegavity difference
1) PERIOD 2
a) Oto 4 =nonpolar
b) 5to2=polar
) Morethan
2) PERIOD 3&up
a) 0 =nonpolar
b) .1to2=polar
) Morethan 2= ionic
ii, Polar or nonpolar
SOuD
1. Fixed place = high inter force
uauID
1. Closer = weaker inter force
Gas
1. Empty space = lowest inter force