p> D.ch— Vo— 2016 2) DHARMSINH DESAI UNIVERSITY, NADIAD_ 2) wet Sr recnorncy SUBJECT: MASS TRANSFER Il Seat No Day Meudag Max. Marks o Examination Date Time TNSTRUCTIONS: 1. Answer each section in separate answer book. Figures to the right indicate maximum marks for that question ‘The symbols used carry tir usual meanings. ‘Assume suitablé data, ifrequjred & mention them clearly, Draw neat sketches wherever necessary. . S SECTION -1 Q1 Doas directed. Hoh (@) Enlist different types of distillation as separation technique. () State the effect of feed situation on feed line with sketch. (©) Express your view on minimum reflux ratio condition. (What is the function of reboiler ? State its types. (©) What do you mean by Relative volatility ? 2 Attempt Any TWO trom the following questions 110) (@)_- Explain Continuous rectification &derive the operating line equation for enriching section (®) Define Flash vaporization. Explain the material balance involved and derive the equation of operating line. (©) Describe Azeotropic distillation with simple sketch Q3 (A Liquid mixture containing 53 % benzene and rest toluene is continuously (071 rectified at the rate of 4500 kgmole/hr. The distillate is found with 96 % benzene while the residue is found with 4.% benzene. Actual reflux ratio is 0.948. ‘The equi.data are as under. The feed enters at its boiling point x 0.0 01 02 03 04 05 06 0.7 08 10 y 00 036 047 0.58 0.65 0.74 0.83 0.92 098 1.0 Calculate (1) Product flow rates (2) No. of actual trays wos) © Define differential distillation and draw its simple sketch. OR Q3 (@) Describe the differential distillation with simple sketch & drive Reyliegh’s Equation. {51 | © Explain the effect of minimum and maximum reflux ratio on operation of ISI distillation. SECTION — Il Q4 Doas directed {10} (@) Explain Critical moisture and free moisture. (&) State different types of crystallizers (©) Explain Humid volume and Humid heat. (2) What is critical point and what is triple point ? (© Define : Percentage absolute molal humidity & % Relative Saturation. QS _Atempt Any TWO from the following questions 110) (@ Discuss the construction and working of any one erystallizer with simple sketch, (®) State & explain the physical adsorption. (©) A batch of Urea is to be dried from 58% to 6 % moisture. The initial weight of the urea is $800 Kg and the unit cost of drying is found as 1.35 Rs/ Kg of moisture removed. Calculate the total amount of moisture removed and total cost of drying, ae 10Q6 a6 (@) Explain the construction and working of drum drier or tray drier with simple sketch. (©) Give the detail classification of industrial drier. (®) Discuss types, construction and working of various cooling towers with sketch ) Explain vapor pressure curv oR detail Page 2 0f2 (61 1 (1 5)FACULTY OF TECHNOLOGY DIPLOMA - SEMESTER V [CHEMICAL ENGINEERING] ‘SUBJECT: (DCH 502) ELEMENTS OF THERMODYNAMICS AND REACTION ENGINEERING 1a) DHARMSINH DESAI UNIVERSITY, NADIAD. Examination Seat No : Date Boye Day Taeteleg— Time Foo to Guo ps Max. Marks INSTRUCTION ‘Answer each section in separate answer book. Figures to the eight indicate maximum marks for that question The symbols used carry their usual meanings. ‘Assume suitable dat, ifrequired & mention them clearly. Draw neat sketches wherever necessary SECTION -1 QI Doas directed. [10] (a) Differentiate between Elementary and Non-Elementary Reactions with [2] examples (b) Give the unit of rate constant for a Zero order reaction n) (©) Give the relationship between Activation Energy and Rate of Reaction QI (d)_ The rate constant of a zero order reaction is 0.2mol/(I.h). What will be the [2] initial concentration of the reactant if, after half an hour, its concentration is 0,05 mot/it? (e) If every 2 minutes one reactor volume of feed at specified conditions is bein; [1] treated by the reactor, what is the space time? (f) Explain a Batch Reactor in brief RI Q2 Attempt Any TWO from the following questions. {10} (a) In studying the kinetics of a decomposition reaction, the concentration of reactants ‘was determined analytically at different times. The following results were obtained: Time | 0 | 10 20 ~| ~=(40 100 125 15} |_ cin) | Cone. 0.0714 | 0.0556 | 0.0385 | 0.02 | 0.0167 (molit) 1 Determine the Order and Rate constant of the reaction (b) In a homogeneous isothermal liquid polymerization, 20% of the monomer is disappeared in 34 minutes for initial monomer concentration of 0.04 and also 0.8 [5] mol/lt. Find a suitable rate equation to represent disappearance of the monomer (©) Fora reaction A -> Products, the following measurements of Rate v/s conversion for reactant A were obtained. Compare the volumes of a Mixed Flow Reactor (CSTR) [5] and a Plug Flow Reactor required to achieve 60% conversion. The feed conditions are same in both the cases and molar flow rate of ntering a reactor is 10 moV/sec (ace [06 0.8] [on ni 1 0.0667 coal \_(moliit.s) l Q3° (a) A reaction 2HI > Hy + Ib is studied over a ange ¢ of ‘omperatue. The results are [6] tabulated below _ 7 (TK 633 666 | 697 | 7s E 81 [RI | 710 | 1.07«107 | $.01x10" | 1.05*10° | 1STx10 Calculate the Activation Energy ofthis reaction graphically (b) Evaluate the Integrated Rate Equation for Ireversible Second Order Reaction in [4] Page tof 2Q3 Qa Q6 terms of Conversion and Halflife Also explain its characteristics OR (2) Derive the performance equation of a Plug Flow Reactor a (6) Compare Collision and Transition State Theory BI SECTION ~ II Do as directed. (10) a) A dead weight gauge with I-om-diameter piston is used to measure Presa very [2] eourately. In a particular instance, a mass of 6.14kg (including piston ‘and pan) 198 it into balance. If acceleration due to gravity is 9.82m/s", what is the gauge pressure being measured? Ifthe barometric pressure is 748 tor, what is the absolute pressure? (0) Explain the concept of Enthalpy and give its physical significance py {@) ALIPC, the reading of manometer filled with mercury is 60.5em. The local [2] acceleration of gravity is 9.784m/s?. To what pressure does this height of mercury correspond? At 27°C, density of mercury is 13.53 g/crr (a). Explain the setection criteria for choice of Refrigerants 2 {@) Calculate the Degrees of Freedom for pure liquid acetone in equilibrium with acetone [1] vapor and nitrogen (p Inacyelic process, heat transfers are 14.7kd,-25.2K1, -3.56k} and 31.5kJ. What is the (1 net work for this eyelic process? Attempt Any TWO from the following questions. {10} (a) A particular power plant operates with a heat reservoir 2 400°C and a heat sink a cmoit at 50°C. It has a thermal efficiency equal to $5% of the Camet erate operating between same heat reservoirs. (3) What is the ‘thermal efficiency of the [5] plant? (i) To what temperature must the heat source reservoir be raised to increase the sary efficiency of the plant to 35%, considering thermal efficiency the Camot engine as 55% (©) G The total energy ofa closed system of Skg mass travelling with a speed of 100 mis at an altitud: es above the ground level is SOkd. Determine the Internal Energy of hs ser, 151 (ii) A certain quantity of air is compressed inside the cylinder. The change in te Senergy of the system is 10k; work required for compression process is SOK. What is the amount of heat transfer involved? (©). Derive the relationship between Equilibrium constants Kp, Ke and K, for a general [5] reaction aA+bB+... 9 eCHID* (@) With a neat diagram, explain the Absorption Refrigeration Cycle for LiBrHLO [6] system in detail (b) Explain : Linde Liquefaction Process 14] OR (a) Explain Heat Pumps in detail m {b) Describe the Carnot refrigeration cycle along with T-S diagram BI page 20f 2DHARMSINH DESAI UNIVERSITY, NADIAD )) FACULTY OF TECHNOLOGY PMESTER V [CHEMICAL] SUBJECT: (DK 513) P.R& PLT. Examination: FINAL Seat No Date Beln (20 Day Time : bo 0 _4rcopss Max. Marks Answer each section in seargte answer book Piste inate maximum mars rt uesion The symbols us Assume suitahg. data, taped mension them clea ‘carry their ustial meanings. . 5._Draw neat sketches wherever nécessary Q2 Q3 Q3 Q4 Qs Q6 SECTION -I Do as directed. (10) (a) Give the significance of cloud point and pour point. (6) What do you mean by U.O.P Characterization factor? (©) State various methods of dehydration of crude. Which method is widely used? (d) Define : Sour and Sweet Crude oil. (©) List out various catalytic processes. Attempt Any TWO from the following questions. (10) (a) State and explain about various additives for gasoline. (b) State and explain thermal properties of petroleum fractions. (©) Explain about origin and formation of petroleum stating various theories, (a) Describe the Edeleanu process for improvement of smoke point of kerosene with [5] neat flow diagram. (b) Explain the treatment of gasoline by Unisol process with neat flow diagram. 15] - OR (a) What does it mean by sweetening? Describe any Doctor's sweetening process for [5] petroleum fraction treatment. (b) Describe about fluidized bed catalytic cracking with flow diagram. Is} SECTION - I Do as directed. (10) (a) What do you mean by Cracking and Reforming process? Why it is carried out, (b) State the applications of Petroleum Coke. (g) State various characteristics of petrochemical industry. (d) Write properties of Propylene oxide and its chemical reaction. (e) Why it is necessary to determine softening point of bitumen? Attempt Any TWO from the following questions. {10} (a) Describe the process of naphtha cracking with neat flow diagram (b) State various impurities in petroleum and state it’s adverse effect on petroleum products. (©) Explain visbreaking process giving sketch. State it’s importance. (a) Explain manufacturing process of butadiene via dehydrogenation of butane with flow [5] diagram, (b) Describe the manufacturing process of phthalic anhydride with flow diagram. 15] OR (a) Describe manufacturing process of Acrylonitrile giving neat flow diagram. (5] (b) Describe manufacturing process methanol with flow diagram. 5} Page 1 oftDHARMSINH DESAI UNIVERSITY, NADIAD Ie )) FACULTY OF TECHNOLOGY D. Ch. &, SEMESTER V SUBJECT: FERTILIZER TECHNOLOGY Examination Seat No Date Day Time Max. Marks INSTRUCTIONS: Answer each section in separate answer book. 2. Figures to the right indicate maximum marks for that question, . 3. The symbols ysed cary their usual meanings. 4 5 Assume f dat, ireqyired & mention them cea. Draw neat sketches wherever necessary. - SECTION -1 Q1 Doasdicects, 01 (@) What is the importance of nitrogen for a plant? (©) Enlist various merits of synthetic fertilizers. (©) State the principle of Ammonia production, (@) State different methods of removal of carbon dioxide from synthesis gas. (©) Enlist various urea synthesis technologies with major change. 0.2 Attempt Any WO from the following questions. no (®) Describe the production of Ammonium Sulphate by any one process with net and clean flow diagram, (®) Explain the important properties of Ammonium Nitrace. (© Explain any one Ammonia synthesis process with flow diagram. Q3 (®) Describe the production of Urea with total recycle process with neat and clean flow [51 diagram (©) Describe steam hydrocarbon reforming process for the production of synthesis gas IS] with neat and clean flow diagram oR 3 (#) Explain the production of Ammonium chloride by any one Process. 51 (©) Enlist different feed stocks for Ammonia and prove natural gas as the best one, is] SECTION -11 Q4 Do as directed (@) How will you convert yellow phosphorous into red one? (©) Enlist various deposits of phosphate rock in the worl. (©) Enlist various important properties of phosphoric acid. (©) State the products of fully developed Phosphate industry. * (©) What is sylvanite ? State its composition 0), QS Attempt Any TWO fiom the following questions. 9} @) Describe the production of yellow phosphorous from phosphate rock with electric are process with flow diagram, (©) State the principal and chemical reagtion with process conditions involved in the IMI process and draw the necessary flow diagram. (©) Deseribe the production of TSP with necessary flow diagram. 6 (@) Describe the production of phosphoric acid by wet process with flow diagram. rm (©) Explain the role of phosphorous for agriculture sector. BL oR Q6 (8) Differentiate [1] NSP vs TSP [2] Red phosphorus vs Yellow phosphorus 6 (©) Draw only labeled flow diagram for manufacturing of DAP with raw materials & [4] utilities agerDHARMSINH DESAI UNIVERSITY, NADIAD )) FACULTY OF TECHNOLOGY DIPLOMA - SEMESTER V [CHEMICAL ENGINEERING] SUBJECT: (DCH 505) POLYMER TECHNOLOGY Examination Seat No Date Day Time Max. Marks INSTRUCTIONS: ‘Answer each section in separate answer book. 2. Figures othe right indicate maximnim marks for that question, 3. The symbols used carry their usual meanings. 4, Assume suitable dat, if equiced & mention them clearly. 5.__Draw neat sketches wherever necessary. SECTION -1 QU Doas directed. 9] (a) Define: Rubber BI (b) Write down the basic characteristics of Chloroprene rubber? QI (©) Write the properties of Polypropylene. 21 (d) What is meant by General Purpose Rubber? Bh (e) Why coatings are applied on the surface of metal? 2) Q2 Attempt Any TIVO from the following questions. 19) (2) With proper flow diagram explain the manufacturing and applications of Polyvinyl Alcohol (b) Explain Vulcanization process of Rubber. (©) Write a short note on Phenol formaldehyde and Amino resin. Q3 (a) Discuss the characteristics of Nylon fibers and Triexta, (5) (b) Explain in details the methods of applying the coatings. Is OR Q3 (a) Explain SBR. 1s (©) Explain manufacturing of Polystyrene. 15] SECTION -11 Q4 Doas directed. 110) (a) Define: Autoacceleration PI (b) Define: CMC 21 (©) Explain Flash. B) (@) What is the difference between Polymer and Plastic? PI (€) Give the difference between Tg & Tm? pI Q5 Attempt Any TWO from the following questions. 10) (a) Explain Melt spinning process with neat sketch (©) Discuss the polymers for the following materia Toys, optical use, floor tiles, leather clothes, stopclocks, chewing gum (©) Explain in detail Extrusion process with proper diagram, Q.6 (2) Discuss about Free Radical Polymerization (5) (b) Explain in detail Injection Moulding with proper diagram. 15) OR 6 (@) Explain Blow Moulding with neat sketch (51 (b) Give the distinguishing features of Chain and Step Polymerization Mechanism 15} rota