AP Chemistry Ch 12 Chemical Kinetics 1. Which ofthe following does NOT inflyence the speed of a chemical me A ct Dp a) concentration of reactants ») nature of reactants my ot c) temperature Sy 4) presence of a catalyst © none of these 2. What would cause the change in the kinetic energy diagrams as shown? KE a) increasing the AH ,) ©) decreasing the temperature 9 ©) increasing the surface area,” @adiition of a catalyst on ig increasing the concentratiof of reactait 3. A time vs. concentration graph is presented below for the reaction A => B, What is the rate of appearance of ‘B’ 20 seconds after the start of the reaction? rae ee — ‘ ro 20 30 40 ‘time (seconds) d) 0.010 moV/L-s ©) 9.8 mol/L’s 0.050 mol/L's b). 3.2 mol/l ©) 2.2 mols ken Date) Name Period __ PRACTICE TEST 4, The reaction 302 —» 203 is proceeding with arate of disappearance of 02 equal to 0.60 mol/L's. What is the rate of a 05, in mol/L's? 0.600 "3 2) 0.60 @) 0.90 ®o.40 e) 1.20 ©) 0.10 ance of 5. A reaction has the rate law Rate = k[A}2[B].* * ‘What is the overall order of the reaction? a0 b2 1 d4 3 6. What are the correct units for a second order iy Marner rate constant? a) moV/L-s 4) Limol?-s b) Us e) moP/2s ()Limol's : fats : 7, The reaction + OCT —> 10° + CT is first order with respect to I” and first order with respect to OCI". The rate constant is 6.1 x 10-2 L/mol's, What is the rate of reaction when {I7] = 0.10 M and [OCT'] = 0.20 M? a)24x104M/s — d) 1.2.x 104 M/s GP12x103Ms &) 24x 105Ms ¢) 6.1.x 10°3 M/s i 2 (GuK! : 8. A reaction and its rate law are given below. When {C4Hg] = 2.0 M, the rate is 0.106 M/s. What is the rate when [CyHg] = 4.0 M? 2C4Hg > CgH}2 — Rate = k{CyHg]? a) 0.053 M/s @ 0.424 Mis b) 0.212 Mis ©) 0.022 M/s 1) 0.106 MisBaker revehenr Ye, Life 9. ‘The rate law for the reaction 13. What fraction of a reactant remains after 3 2NO(g) + O2(g) > 2NO2(g) half-lives of a first order reaction? ig Rate = k[NOJ?[O.]. What happens to the a 12 18 rate when the conentraton of NOS, b) 15 ) W2 : And erdort Ye tale, y tenes doubled? @v- ©) U6 > Yo, oe hy mde ey a) therate doubles d) the rate is halved b) the rate triples @) none of these 14, Assume a reaction oceurs by the mechanism (ihe rate quadruples aiven below, Whatisthe rate law forthe, | reaction? Baths. Ho 10. Below is some rate date for the hypothetical AtBerC fast Olt ty reaction, 2A +B > C. What ete ws C+D stow shew? Ty yak for this reaction, Pore Maky eat we a) Rate=KAIBIC] = od has Me Experiment | (AL TTB} ow waite b)Rate= KAP X. 2 [20M oom [Roa INS en — CepRate=k{AILB] coe 3 Kaom | om] 01004 “+ @) Rete= KIAIBY(D] mah a) Rate=K{AJ[B] d) Rate= k[AP(BP. ne « b) Rate = k[AP[B] @ Rate = k[BP ©) Rate = KA]IBP 15. According to collision theory, which of the following factors does NOT influence the 11. The acid catalyzed decomposition of pore tac __ hydrogen peroxide is a first order reaction «) collision frequency Y ose withthe rate constant given below. Foran +) collision energy © experiment in which the starting ©) collision orientation Y © "concentration of hydrogen peroxide is 0.110 M, what is the concentration of HO 450 ) none of these minutes after the reaction begins? gg WHO) + 20 +0) 11.33 x 104 mine) Z 202 > 2430 + Oz aa 16. What distance corresponds to the activation a) 0.0961 M 4) 0.00658 M energy for the reaction of X to Y? ©) 0.0156 M 12. What is the raté constant for a first order oe . reaction for which the halflife is 85.0 sec? L*S potential energy fapo.o08i4 sec! —d) 0.0118 sec! AG ib) 4.44 sect 2) 58.9 sec"! ¢) 0.170 sec"! reaction coordinate aja ad Or oe ee50m) ) + fog (0 0.112) oe o.assvoTats17, Atwhat point on the potential energy diagram given below does the transition state (activated at We - © ox oe a z 3 a & g 5 : 3 8 2 reaction coordinate aja dd b)b ee & Mot Tesfedk ~ 18, The rate constants, at two different temperatures, for the reaction CH3I+Br > CH;Br+T are given below. t=30°C #273 =k =138x 104 Mls t=49°C43°3 k=1.21x103 MIs What is the activation energy for this reaction? R= 8.314 I/molK. a) 92.7kiimol ——d)_ 343 ki/mol b) 200 kJ/mol e) none of these ©) 40.3 ki/mol 19, Which of the following is NOT true about a catalyst? _a) it speeds up the forward reaction | Cb)is acts as aninhibitor ares ©) it speeds up the reverse réaction d) it may be homogeneous 6) itmay bg heterogeneous Corte Rusts uote uP ai. Answer In the reaction, Hy + Bry -> 2HBr, the step Bre + Hy > HBr + He is what step? CS propagation e) termination a) initiation b) completion ©) inhibition In the reaction, Hy + Bry ~» 2HBr, the step Bre + Bre —» Bry is what step? a) b) completion 6) inhibition ation d) propagation (6c) termination ‘A free radical is a chemical species that possesses a) apositive charge b) anegative charge Jan unpaired electron “@) an oxygen atom ¢) unconventional political views 5: (please use CAPITAL letters) u 12. 13, 14. 18. weepe 16. V7. 18. 19. gerne ks PR Pe Mavis a whKinetics 1 Be rate of a reaction with just two reactants is (22 Shere to double when the concentration of one reactant is doubled and the second reactant is held constant. The rate is also observed to ee E increase by a factor of nine when the concentration of the second reactant is tripled, holding the concentration of the first reactant constant, What is the overall order fr this reaction? Cosas Je CA! 06s 2 os @: os 2, Which energy diagram represents a highly exothermic reaction that has a small activation energy? (Assume that all curves are plotted on the same scale.) pb at : Prodan o%® Lowe «© o a i 7 ! 3. Tritium decays by a first-order process that has por BO-Z balblife of 12.5 years, How many years will it Oe >}2-8 take to reduce the radioactivity of a tritium: sample to 15% of it original value? , & (a) 64y Oy chee. ¥ (B) S4y D) Ay park ibs. 4, What is the overall order of a reaction with a rate constant having the units L-mol"'-s"? ao 1 (D3 & 5. In a reaction with several steps, which step limits the rate of the reaction? (A) first (©) fastest @) test @piowest aw 2 gash: eo ny Skt age 1a 6 o@—Nowrow OIF © 1S What is the ratio of the rate of decomposition’ of NaOs to the rate of the formation of NOx? @i2 Old B21 4: 7. When reacted with water, the insecticides DDT decomposes with a half-life of 10 years Approximately how many yeats will it take for 99% of a given sample to decompose once ‘exposed to water in the environment? (A) 50 yr (©) 500 yr @y (D) 700 yr 8. Which property, if decreased, will cause an increase in the rate pf'a reaction involving a aL gees ey Sunk = ee (A) temperature (B) pressure (©) concentration (D) particle size 9. Which graph corresponds to the change in concentration of a reactant that is a first order Sanus Preranes Shaye ow Fh — Ke) af constant temperatts 1. activation energy Y 2. ending concentrations N° 3. reaction enthalpy AO D1 only (©) 1 and 2 only (B)3 only () 1,2, and311, A plot of reactant concentration versus time gives a straight line, What is the order of the reaction for this reactant? “80S @ezr (©) second @) frst (D) some other value 12. Which change does not increase the value of the al ehanige ‘ale constant fora reaction? mere (A) deoreasing the activation energy,” oc (B) raising the temperature (©) adding a catalyst ‘increasing the concentration of reactants Gas Wayeanwne te 13. A certain reaction has a AH =-75 KJ and an is found activation energy of 40 KI. A catalys that lowers the activation energy ofthe forward reaction by 15 kJ. What is the activation energy brs: OH of the reverse reaction in the presence of this same catalyst? (A) 25 kT (©) 90 Ks (B) 60s (D) 100 ky 14, Nitrogen(I) oxide and hydrogen react to form nitrogen and water according to this equation, My 15. ‘Ata certain tomperature the first-order decomposition of hydrogen peroxide exhibits these data |time (seconds, s) [H0;](mol L’ } (AD30. Crs [gh order‘ @)25s (D) 20.5 ya, ree gee he ohh awk goer : ; ow Yee aoe 2NO(g) + 2H -> Nag) + 2H.0(8) < According to these experimental results, what os. 4S are the orders for NO and H,0? - A nee? Tar beware Ley ho [NO] [14] h Joos 0. 020, a 10.015)0.040 40% “0.030 0.020 Order,NO Order,Hs ) 1 1 ® 1 2 © ©) 2 2