OBJECTIVE PROBLEMS (JEE MAIN) 1. a There is no S-S bond in (A) S,0," (8) 5,0, (C) 5,0," (0) S,0," Which of the following molecules are expected to exhibit intermolecular H-bonding L. Acetic acid IL. o-nitrophenot IIL. m-nitrophenol IV. o-boric acid (A) 1, 11, I (8) 1, 1, IV (C) 1, M1, IV (D) 11, 111, IV In which of the dimerisation process, the achieve- ment of the octet is not the driving force. (A) 2A1C1,—+ ALC], (B) BeCl, —+ BeC, (solid) (C) 2ICl,—+1,C), (DB) 2NO, + N,0, ‘A: tetracyanomethane B : Carbondioxide C: Benzene D : 1, 3-buta-di-ene Ratio of c and x bond is in order: (A)A=B, NO} (A) NO; > NO >NO; (8) NO; > NO; >No; (€) NO; > NO} > NO} (D) NO; > NO; > NO; The molecule is not having 3c-2e bond. (A) BeH, (dimer) (8) BeH, (solid) (OCH, (0) 8,4, 9. In which of the following molecules / ions all the bonds are not of equal length. (A) SIF, (B) SF, (C) XeF, (0) BH, 10. The critical temperature of water is higher than that of O, because the H,O molecules has : (A) fewer electrons than O, (B) two covalents bonds (C) V - shape (D) dipole moment 11. Among KO,, AIO; ,B80, and NO; unpaired electron is present in : (A) KO, only (B) NO; and Bad, (C) KO, and AIG; (0) B20, only 12. Which has riaximum dipole moment ? al a a “ (8) | a cl (c) (0) | 1 13. Statement-1 : é-bonds are formed by four lobes interaction of d-orbitals. Statement-2 : 4,2 orbital does not have nodal plane. (A) Statement-1 is true , Statement-2 is true and ‘Staternent-2 is correct explanation for Statement-1 (B) Statement-1 is true, Statement-2 Is true and Statement-2 NOT the correct explanation for Statement-1 (C) Statement-1 is true , Statement-2 is false (D) Statement-1 is false, statement-2 is true.14. Compound with maximum ionic characteris formed from: (A) Na and Cl (C) Cs and! (8) Cs and F (0) Na and F 15.Mg,C, reacts with water forming propyne, C,* has (A) two sigma and two pi bonds (B) three sigma and one pi bonds (C) two sigma and one pi bonds (D) two sigma and thee pi bonds 16. Which of the following has a geometry different from the other three species (having the same Geometry)? (A) BF; (8) soy (©) XeF, (0) PH; 17. Which of the following molecule does not have ‘open book structure. (A) 0,F, (©s,c, (8) 0, (H.C, 18.Among the following species, Identify the isostructural pairs : NF,, NO3 ,BF,,H,0*HN, (A) [NF,,.NO; }@nd [BF ,H,Or) (B) [NF,,HN,] and [NO3 ,BF,) (C) [NF,,H,O*) and [NO3 ,BF,) (D) (NF, H,O°] and [HN,,BF,) 19. Number and type of bonds between two carbon atoms in CaC, are : (A) one sigma (2) and one pl (x) bond (B) one @ and two x bonds (C) one a and one and a half x bond (D) one «bond 20.C - C bond in C,H, undergoes heterolytic fission, the hybridisation of two resulting carbon atoms is, fare (A) sp both (C) sp’, sp” (B) sp? both (D) sp, sp? 21. The hybridisation and geometry of BrF, molecules are: (A) sp°d and T shaped (8) sp?d? and tetragonal (C) sp°d and bent —_(D) none of these 22. Pick out the incorrect statement ? (A) N, has greater dissociation energy than N,* (B) 0, has lower dissociation energy than 0,* (C) Bond length in N,* is less than N, (D) Bond length in NO" is less than in NO. 23. The correct order of increasing X - O - X bond angle is (X = H, F or Cl) : (A)H,O>CI,O>F,0 (B)CO>H,0>F,0 (C)F,O>C10>H,0 (D)F,0>H,0>Ci,0 24. Hybridization of carbon in C,0, is : (A) sp (B) sp* (C) sp (D)sp°d 25. Cyanogen , (CN),, hasa__ushape/structure : (A) Unear (8) Zig-Zag (C) Square (D) Cyclic '26.Ethanol has @ higher boiling point than dimethyl {ether though they have the same molecular weight. This Is due to : (A) resonance (C) hydrogen bonding (8) coordinate bonding (D) ionic bonding 27. Arrange the following in order of decreasing boiling point : (1) n-Butane (II) n-Butanol (If1) n-Butyl chloride (IV) Isobutane (A)IV>M> > (8)IV> I> MI>1 (C)I>t>t>v (0) U>Itl>I>1v 2B. Which of the following compounds would have sig- nificant intermolecular hydrogen bonding ? HF, CH,OH, N,O,, CH, (A) HF, N,O, (C) HF, CH,OH (B) HF, CH,, CH,OH (D) CH,OH, CH, 29. For H,0,, H,S, H,0 and HF , the correct order of decreasing extent of hydrogen bonding is : (A) H,O > HF > H,0, > HS (8) H,0 > HF > H,S > H,0, (C) HF > H,0 > H,0, > HS (D)H,0, > H,0 > HF > H,S30. A simplified application of MO theory to the hypo- thetical ‘molecule’ OF would give its bond order as (a2 (8)1.5 (21.0 (D)0.5 31. Which of the following contains electrovalent and covalent bonds ? (aycH, (C)NH,CI (8)H,0, (D) HCN 32. Which of the following species Is paramagnetic ? (A) NO (8) OF (C) CN" (0) CO 33. Bond order of Be, is aya (2 (c)3 (D)o ‘34.The shape of methy! radical (CH,) is : (A) linear (8) pyarmidal (C) planar (D) spherical ‘35. The structure of XeF,, Involves hybrdization of the type : (A) sp® (C) spd (8) dsp? (0) spr? 36.NH, and BF, combine readily because of the for- mation of : (A) 2 covalent bond —_(B) ahydrogen bond (C) a coordinate bond (D) anionic bond 37. The structure of diborane (B,H,) contains (A) Four (2C-2e") bonds and two (2C-3e")bonds (B) Four (2C-2e-) bonds and two (3C-2e")bonds (C) Four (2C-2e") bonds and four (3C-2e")bonds (D) None 38. Which of the following equilibria would have the lowest value of K, at a common temperature ? (A) Mgco, —— Mg0 + CO, (B) Caco, —— Cad + Co, (c) SrCo, —— Sr0 + Co, (0) Baco, —— Ba0 + co, 39. Which one of the following does not have inter- ‘molecular H-bonding ? (AHO (C) HF (B) o-nitro phenol ()CH,COOH 40. The order of strength of hydrogen bonds Is : (A) CIH...C1 > NH...N > OH...0 > FH...F (D) CIH...Cl < NH...N FH..F ‘41. The types of bond present in N,O, are (A) only covalent (8) only ionic (C) ionic and covalent (0) covalent & coordinate 42. Which of the following exhibits/s H-bonding ? (AycH, (B) H,Se ony (0)#,S 43. Select correct statement about hydrolysis of BCI, and NCI, (A) NCI, is hydfoysed and gives HOC! but BCI, is not hydrolysed: (8) Both NCI, and BCI, on hydrolysis gives HCI 9 NCI, on hydrolysis gives HOC! but BCI, gives ye Both NCI, and BCI, on hydrolysis gives HOC. ‘44, The state of hybridisation for the transition state of hydrolysis mechanism of BCI, and SF, are re~ spectively (A) 5p?, spd (C) sp, spa? (B) sp, sp* (D) sp, sp’d 45. The bond order depends on the number of elec- ‘rons in the bonding and antibonding orbitals. Which of the following statement is / are correct about bond order ? (A) Bond order cannot have a negative value. (8) It always has an integral value {C) It is a nonzero quantity. (D) It can assume any value-positive or negative, Integral or fractional, including zero. ‘48.1n the formation of N3 from N,, the electron is removed trom : (A) o orbital (C) o* orbital (B) x orbital (D) x* orbital47. The types of bonds present In CuSO,. SH,O are (A) electrovalent and covalent (8) electrovalent and coordinate covalent (C) covalent and coordinate covalent (©) electrovaient, covalent and coordinate covalent ‘48. The polarizibility of the following compounds is/are (Ah>Br>Ch>F (B)I'> Br >F >ct (Oh sp?> sp? (B) sp?> sp? > sp (C) sp? > sp > sp? (D)sp?> sp > sp?61. When 2s - 2s, 2p - 2p and 2p - 2s orbitals over- jap, the bond strength decreases in the order : (A)p-p>s-s>p-s (B)p-p>p-s>s-s (C)s-s>p-p>p-s (0)s-s>p-s>p-p 62.How many sigma and pi bonds are present in tetracyanoethylene ? (A) Nine cand ninex (8) Five xand nine o (C) Nine o and Seven x (D) Eight o and eight x 63. The volatility of HF is low because of : (A) its low polarizability (B) the weak dispersion interaction between the molecules, (C) its small molecular mass (0) its strong hydrogen bonding 64, The shapes of IF, and IF, are respectively (A) tetragonal pyramidal and pentagonal bipyramidal (B) octahedral and pyramidal (C) trigonal bipyramidal and square antiprismatic (D) distorted square planer and distorted octahe- oral 65. Which of the following has been arranged in order of decreasing dipole moment ? (A) CH,Cl > CH,F > CH,Br > CHL (B) CHF > CH,CI > CH,Br > CHIT (C) CHI > CH,Br > CH,L> CH, (0) CHF > CH,CI> CH, > 66. Which of the following has the least dipole mo- ment (ANF, (8)cO, (Cc) So, (D)NH, The experimental value of the dipole moment of HCI is 1.03 D. The length of the H - Cl bonds Is 1.275 A. The percentage of ionic character in HCI is: (a) 43 (B) 21 (c)17 (0)7 68. The dipole moment of Is 1.5D. The dipole a moment of cl (oo (@)150 (C)2.86D (D)2.25D 69. Which of the following sets of characteristics leads to the increase in solubility of ionic substances ? (A) High dipole moment, Strong attraction by an on and high solvation energy (B) Low dipole moment, weak attraction by an ion and high solvation energy (C) High dipole moment, Strong attraction by an ion and low solvation energy (0) High dipole moment, weak attraction by an ton and large solvation energy 70.The correct order of increasing s-character (in percentage) in the hybrid orbitals of following mol- ecules/ions is : ( coe (I) XeF, (ay 5 (yy nc, (V) Bec, (aylsill> (2) Si,0,~ (34. What is the state of hybridisation of Xe in cationic part of solid XeF, (Aysp’? — (B) spd? 32. Rotation around the bond (between the underlined atoms) is restricted in : (A) CH, (B) H,0, (C)sp'd (0) sp? (C) CH, (D) CH, 33. According to MOT (Molecular Orbital Theory), the molecular orbitals are formed by mixing of atomic orbitals through LCAO (linear combination of atomic orbitals). The correct statement(s) about molecular orbitals is/are ‘Statement (A) :bonding molecular orbitals are formed by addition of wave-functions of atomic orbitals of same phase ‘Statement (8) : anti-bonding molecular orbitals are formed by subtraction of wave-functions of atomic orbitals of same phase ‘Statement (C) : non-bonding molecular orbitals do not take part in bond formation because they belong to inner shells Statement (D) : anti-bonding molecular orbitals Provide stability to molecules while bonding molecular orbitals make the molecules unstable. (A) Statement a, (B) Statement a, b, c (C) Statement a, b,d (0) Statement a, b34.NO X - X bond exists in which of the following ‘compounds having general form of XH, ? (BH, (BVH, (CALH, (0) SiH, 35. Which of the following species is (are) isostructural with XeF, ? (Ay ice (BYE (C) BeFZ_—(D) X00, 36. In which of the following case central atom-F bond has partial double bond character? (A) NF, (B)CF, (C)PF, — (D)OF, 37. Which one of the following compounds has bond angle as nearly 90°? (A)NH, — (B)H,S_—(C)HO_— (0) SF, 38 The linear structure is assumed by : (A)Snci, (B)NCO"(C)CS, —_(D) NO,” 39. Which of the following statements is/are correct? (A) NH; shows Sp? - hybridisation whereas NH,- shows Sp? - hybridisation (8) Al (OH), has a regular tetrahedral geometry (C) Sp? - hybridized orbitals have equal s-and p- character (D) Usually hybridized orbitals form « - bonds, 40. Choose the correctwoption=for the following molecule in view of chemical bonding " x. G=C= Y A Na (A) non-planar (B)peo0 (C) A&B both (D)p=0 41, Of the following isoelectronic & isostructural species are NO,~, C10, SO, & CO,” (A) Noy” & CO,? ——(B) SO, & CO,? (C) NO, 8 Clo, (D) CO, & Clo, 42. Shape of NH, is very similar to : (A) Seo} (B) CH; (C) BH, 43. There is change in the type of hybridisation when (A) NH, combines with H (B) AIH, combines with H- (C)NH, forms NH; ——_(D) SIF, forms SiF3~ (0) cH; 44, Which of the following have same shape as NH; ? (A)CO, — (B)SnCI,_(C)SO, —_(D) Bec, 45. Which of the following is (are) linear? AG (81, (C)PHCI, (D) XeF, 46. Which of the following statement is/are correct (A) Hybridisation Is the mixing of pure atomic orbitals, having less energy difference (8) Sp? d? - hybrid orbitals are at 90° to one another (C) Sp? d - hybrid orbitals are directed towards the corners of a regular tetrahedron (0) sp? o? - hybrid orbitals are directed towards the corners of a regular octahedron 47, Which of the following statements Is/are true for BaO and MgO? (A) BaO Is more ionic than MgO (8) MgO is more ionic than B30, (C) B20 has a higher melting point than MgO (D) MgO has a higherimelting point than BaO 48. Polarization may be called the distortion of the ‘Shape"of an anion by an adjacently placed cation. Whiehof the following statements is/are incorrect: (A) Minimum polarization is brought about by a cation of low radius (8) Alarge cation is likely to bring about a large degree of polarization (C) Maximum polarization is brought about by a cation of high charge (D) A small anion is likely to undergo a large degree of polarization 49. Pick out among the following species isoelectronic with CO, : (AN; (B) (CNOY: (C) (NCN}* (D) NO,- ‘50. Which Is correct statement? As the s-character of a hybrid orbital decreases (1) The bond angle decreases (II) The bond strength increases (111) The bond length increases (IV) Size of orbital increases (A) (1), (11D) and (IV) (B) (11), (III) and (IV) (€) (0) and (11) (D) Al! are correct‘51. Resonating strctures of a molecule should have: (A) Identical bonding (B) identical ararngement of atoms (C) nearly the same energy content (D) the same number of paired electrons 52.Which of the following conditions apply to resonating structures ? (A) The contributing structures should have nearly similar energies (B) The contributing structures should be represented such that like charges reside on atoms that are far apart (C) The more electropositive element should preferably have positive charge and the more electronegative element have negative charge. (0) The contributing structures must have the same ‘number of unpaired electrons 53. A n-bond may between two p, orbitals containing ‘one unpaired electron each when they approach each other appropriately along : (A) x-axis (B) y-axis (C) z-axis {D) any direction ‘54. During the complete combustion of methane CH,, what change in hybridisation does the carbon atom undergo? (A) sp? to sp (B) sp? to sp? (C) sp? to sp (D) sp? to sp» 55. The octet rule is'riot obeyed In : (A)Co, (8) BCI,_..(C) PCI, (D) SIF, '56.N,O has a linear, unsymmetrical structure that may be thought of as a hybrid of two resonance forms. If a resonance form must have a satisficatory Lewis structure, which two of the five structures shown below are the two resonance foms of N,O ? (E) :NeN. 57. A, B, C are three substances. A does not conduct electricity In the solid, molten state and aqueous solution B. Conducts electricity both in the fused and aqueous states, while C conducts electricity only in the aqueous state. In solid state neither B nor C conducts electricity. Which of the following statements Is/are true regarding A, Band C ? (A) Ahas polar covalent linkage (8) Ahas nonpolar covalent linkage (C) Bis lonic in nature (D) Cation formed by C is highly polarizing ‘58. Three centre - two electron bonds exist in: 8H, (8) AL(CH,), (C) BeH}(s) (0) Bect,(5) 59. Which of the following statement(s) is/are correct regarding lonic compounds ? (A) They are good conductors of electricity at room temperature (B) They are always more soluble In polar solvents than covalent compounds (C) They consists of ions (D) They generally have high melting and boling points 60. Most ionic compounds have : (A) high melting points and low boiling points (B) high melting points and nondirectional bonds (C) high solubilities in polar solvents and low solubilities innonpolar solvents, (D) three-dimentional network structures, and are good conductors of electricity in the molten state. 61. In which of the following cases, the number of lone pair on the’¢entral atom.is two. (A) er, (B) XeF, (epic, (D) SO, Cl, ‘62: Which of the following have a three dimentional network structure ? (A) SiO, (C) P, (white) (8) (BN), (o) ca, 63. To which of the following species octet rule is not applicable. (A)BrF, = (B) SF, (C)IF, = (D) CO 64. Which of the following do not exists ? (A)SH,— (B)HFO, (C) Fel, (D) HCIO, 65.The species which contain an odd number of valance electrons and are paramagnetic : (A)NO. (B)NO, —(C) CIO, (D) NO, 66. Among the following, the element which show Inert-pair effect are. (A) Bi (c) Pb (B) Sn (oye 67. Which of the following have an (18 + 2) electron configuration ? (A) poi (0) BP+ (8) co (D) So,?‘68. Which of the following pair of species is/are having same bond order and same magnetic moment. (A) He-H and H,- (8) 0," and NO (C) He,* andi," (D) N° and N,- 69. Which of the following oxyacids of sulphur contain S~ S bonds ? (@)HS,0, (8) H,5,0, (C)H,S,0, (0) H,5,0, 70. Which of the following factors are responsible for origination of van der Waals forces? (A) Instantaneous dipole-induced dipole interaction (8) Dipole-induced dipole interaction and lon-induced dipole interaction (C) Dipole-dipole interaction and ion-induced dipole interaction (D) Small size of molecule 72. Which of the following are true? (A) Van der Waals forces are responsible for the formation of molecular crystals (B) Branching lowers the bolling points of isomeric organic compounds due to decrease in vander Waals forces of attraction (C) In graphite, van der Waals forces act between the carbon layers (D) In diamond, van der Waals forces act between the carbon layers 72. When Hr" is going to be added to the PO,*, then: the obtained formula will not have the structure of oO oO Meo ro-F |Z) .o“0- 4 ” ry ° se 73. Intermolecular hydrogen bonding increases the enthalpy of vapourization of a liquid due to the: (A) decrease in the attraction between molecules (8) increase in the attraction between molecules (C) decrease in the molar mass of unassociated liquid molecules (D) increase in the effective molar mass of hydrogen ~ bonded molecules 74.Which of the following molecules have intermolecular hydrogen bonds ? (A) KH,PO, (8) 1,80, (C)C,H,CO,H (0) CH,OH 75. Intramolecular hydrogen bonds occur in : (A) 2-chlorophenol (B) salicylic acid (C) the enol form of acetylacetone (0) paranitrophenol 76. Which of the following are diamagnetic ? yc, (BOF (CU, — (DYN; 77. Which of the following are paramagnetic? (AB, (82)0, (CN, — (0) He, ‘7B. Which of the following species have a bond order of 37 (a)co (B) CN (C)NO- (0) O; 79.Among the following, the species with one unpaired electron are: (0; (B)NO_— (C)OF_—(0)B, ‘80. Which of the following pairs have identical values ‘of bond order? (A) Ny; and 0; (C) 0%; and.B, (8) F,and Ne, (D) Cand N, 81, Which of the following is correct ? (A) During N; formation, ane electron is removed from the bonding molecular orbitals (8) During ©; formation, one electron is removed from the antibonding molecular orbitals. (C) During 0; formation, one electron is added to the bonding molecular orbitals. (D) During CN formation, one electron is added to the bonding molecular orbitals. ‘82. Which of the following species are linear? ic; (8) (CNG (0) ClO, 83. The structure of XeF, is : (A) pentagonal bipyramidal (B) distorted octahedral (C) capped octahedral (D) square pyramidal ‘84. sp’ hybridisation is in: (A) AKG (B) CHS (C) COZ (D) NH 85. Choose the correct statements. (A) CH,NCS molecule is linear (8) SIH,NCS molecule is linear (C) GeH.NCS molecule is bent (0) P(SiH,), molecule is pyramidalMatch the Column 86. Match the Column Column-I 1,0, (e)sic (C)AL(CH), (0)5,0, Column-Ir (P) All atoms are sp? hybridised (Q) have non planar structure (R) have 3c - 4e bonds (S) have 3c - 2e bonds ‘87. Match the Column, ‘Column-1 (a) Ich, Column-Ii (P) Hybridisation of central atom is, similar in both dimer and monomer form. (Q) Both monomer and dimer forms are planar (R) In dimer form all atoms are sp? (8) AICI, (C) AIF, hybridised. (D) NO, (5) Does not exist in dimer form 88. Match the Column Column-I (Type of orbital) (A) dz: - orbital (B) s- orbital (0) day (0) p,- orbital Column-Ir (Orbitals involved in hybridisation) (P) sp? (Tetrahedral) (Q) spd? (Octahedral) (R) sp°d (TBP) (S)65p? (square’planar) COMPREHENSION TYPE QUESTIONS: yassage-1 Hydrogen bonding originates from the dipole-dipole interaction between H-atom and any of the other atom like F, 0, N and in some cases with Cl atom. There are two types of H-bonding like Intermolecular ‘and intramolecular H-bonding ‘89. Which of the following molecule does not consist of intramolecular H-bonding. (A) Chloral (B) Chloral hydrate (C) ortho hydroxy benzaldehyde (D) ortho chlorophenol 90. Which of the following plot for p (density) v/s T (temperature) for liquid H,0 Is correct. 91. Which of following statement is incorrect (A) Boiling point of H,0, is greater that of H,0 (B) Ethylene glycol is less viscous than glycerol. (C) o-nitrophenol can be separated from its meta and para isomer using its steam volatile property. (D) In ice each ‘O' atom is tetrahedrally arranged by four H-atoms which are all equidistant. Passage-2 Phosphorus forms different halide compounds with halogens. In crystalline state some of them exist as ion pairs. 92. What is hybridisation of central atom of anionic part of PBr, in crystalline state, (A) sp? (B) sp)“ (C)sP (D)net applicable 93. What is the difference"between bond angles in catlonlespecies of PCI, and PBr, in solid state. (A) 60° | (B)109°28'(c)0®—(D) 90% '$4, All possible bond angles in anionic part of PCI, are (A) 109928" (B) 90°, 180° (C) 90°, 1209, 180° (D) 72°, 90°, 180° Passage-3 Hybridisation is the mixing of atomic orbital of comparable energy and the number of hybrid orbitals formed is equal to the number of pure atomic orbitals mixed up and hybrid orbitals are occupied by o-bond pair and lone pair. 95. Which of the following geometry Is most likely to not form fram spd hybridisation of the central atom. (A) Linear (B) Tetrahedral (C) T-Shaped (0) See-Saw 96. The orbital Is not participated in sp*d hybridisation. (A) p, (Bd, (C) Fay (D)p, 97."The hybrid orbitals are at angle of X° to one another "this statement is not valid for which of the following hybridisation. (A) sp? (8) sp* (C)sp'? (0) spEXERCISE 4. The geometry & the type of hybrid orbitals present about the central atom in BF, is : (A) linear, sp (8) trigonal planar, sp* (C) tetrahedra sp? (D) pyramidal, sp 2. The correct order of increasing C - O bond length of, CO, CO,", CO, is (A) CO < Co, < CO (Cc) Co < Co, < Co, (8)CO, < Co < co (0) CO< CO, < CO 3. Inthe dichromate anion (A) 4 Cr-0 bonds are equivalent (B) 6 Cr-O bonds are equivalent (C) all Cr-O bonds are equivalent (0) all Cr-O bonds are non equivalent 4. The geometry of H,S and its dipole moment are (A) angular & non zero (B) angular & zero (C)linear &non zero. (0) linear & zero 5. In compounds type E Cl,, where E =B, P, As or Bi, the angles Cl - € - Cl for different E are in the order (A)B>P=As=Bi — (B)B>P>As>Bi (C)B O; (C) Diamagnetic and Bond order < 0, (0) Diamagnetic and Bond order > 0, 7. Which species has the maximum number of lone pair of electrons on the central atom ? [JE 2005) (A) clog (8) XeF, (CSF, (DDG 8. The percentage of p-character is the orbitals forming P-P bonds in P, is (DEE 2007) (a) 25 (B) 33. (C)S0 () 75 9. Among the following, the paramagnetic compound is [JEE 2007] (A)Na,O, (BJO, (C)N,O_— (0) KO, 10, The species having bond order different from that inCOis [JEE 2007) (AYN (B)NO*(C)CN" (D) N, 11. The structure of Xe0, is [JE 2007) (A)linear — (B) planar (C) pyramidal (D)T-shaped 12. Statement-1 : p-Hydroxybenzoic acid has a lower boiling point than o-hydroxybenzoic acid. Statement-2 : o-Hydroxybenzoic acid has Intramolecular hydrogen bonding, [DEE 2007) (A) Statement-1 is True,.Statement-2 is True ; Statement-2 is a correct explanation for Statement-1 (8) Statement-t\is True, Statement-2 Is True ; Statement+2 is’ NOT. a correct explanation for Statement-1 (C)Statement-1 Is True, Statement-2 is False. (D) Statement-1 is False, Statement-2 is True. 13. Statement-1 : In water, orthoboric acid behaves as a weak monobasic acid. ‘Statement-2 : In water, orthoboric acid acts as 2 proton donor, [JEE 2007) (A) Staterent-1 is True, Statemnent-2is True ; Statement- 21s a correct explanation for Statement-1 (B) Statement-1 is True, Statement-2 Is True ; Statement-2 is NOT a correct explanation for ‘Statement-1 (C) Statement-1 is True, Statement-2 is False. (D) Statement-1 is False, Statement-2 is True. 14, Statement-1 : Pb" compounds are stronger oxidizing agents than Sn‘ compounds. [JEE 2008) ‘Statement-2 : The higher oxidation states of group 14 elements are more stable for the heavier members ‘of the group due to ‘inert pair effect’. (A)Statement-1 is True, Statement-2 is True ; Statemnent- 2's a correct explanation for Statement-1 (B) Statement-1 is True, Statement-2 is True ; Statement-2 is NOT a correct explanation for Statement-1 (C) Statement-1 is True, Statement-2 Is False. (D) Statement-1 is False, Statement-2 Is True.15. Match each of the diatomic molecules in Column - I with its property/ properties in Column-Il. Column-I Column-It (DEE 2009) (a)B, (P) Paramagnetic (B)N, (Q) Undergoes oxidation (C)0,- __(R) Undergoes reduction (0) 0, (S) Bond order 22 (T) Mixing of ‘s' and ‘p' orbitals 26. The nitrogen oxide(s) that contain(s) N-N bond(s) Is (are). [DEE 2009) (A)N,O — (B)N,0, (C)N,O, (D) NO, 17. In the reaction [3E 2009) 2X + BH, + (8H,(X),}°(BH,)- the amine(s) X is (are) : (A) NH, (8) CH,NH, (C) (CH,),NH (D) (CH,),N 18. The species having pyramidal shape is (EE 2010) (A) SO, (0) OSF,, (8) BF, (Cc) SIO 19, Assuming that Hund’s rule is violated, the bond order and magnetic nature of the diatomic molecule Bis (JEE-2010) (A) Land diamagnetic _(B)0 and diamagnetic (C) 1 and paramagnetic (D) 0 and paramagnetic 20. All the compounds listed in Column I react with water. Match the result of the respective reactions with the appropriate options listed in Column II. Columnn-r Column-II —[JEE 2010] (A) (CH,),SICI, —__(P) Hydrogen halide formation (8) XeF, (Q) Redox reaction (a, (R) Reacts with glass (D)vcl, (S) Polymerization (7) 0, formation 21.In Allen (C,H,), the type (s) of hybridisation of the carbon atoms is (are) (JEE 2012) (A) sp and sp? (8) sp and sp? (C) only sp? (D) sp? and sp? 22. The shape of Xe0,F, molecule is (A) trigonal bipyramidal (EE 2012) (B) square planar (C) tetrahedral (D) see-saw 23. With respect to graphite and diamond, which of the statement(s) given below is (are) correct? (DEE 2012) (A) Graphite is harder than diamond (B) Graphite has higher electrical conductivity than diamond. (C) Graphite has higher thermal conductivity than diamond. (D) Graphite has higher C - C bond order than diamond. 24, Decreasing order of the O-O bond length Present in them O,, KO, and O, [ASF,] [DEE 2004) 25. The number of water molecule(s) directly bonded to the metal centre in CuSO,.5H,O. Is (EE 2009) 26. Based on VSEPR theory, the number of 90 degree F-Br-FanglesinBrF,is [JEE 2010) 27. The value of niin the molecular formula Be,Al,Si,0,, is [DEE 2010) 28. _ The total number of diprotic acids among the following is [DEE 2010) HPO, 50," H,PO, H,CO, _H,S,0, Hj80, H,P0, H,Cr0, HO. 29. Among the following, the number of elements showing only ane non-zero oxidation state is : 0, C1,F,N,P,Sn,TI,Na, Ti [JE 2020) 30. Which ordering of compounds is according to the decreasing order of the oxidation state of nitrogen (A) HNO,, NO, NH,CI, N, (EE 2012) (B) HNO,, NO, N,,NH,CI (C) HNO,, NH,CI, NO, N, (D) NO, HNO,, NH,CI, N; 31. _ In Allene (C,H,), the type (5) of hybridisation of the carbon atoms is (are) (JEE 2012) (A) sp and sp* (B) sp and sp? (C) only sp? {D) sp? and sp? 32. The shape of Xe0,F, molecule is (A) trigonal bipyramidal (B) square planar (C) tetrahedral (D) see-saw (J8E 2012)Answers 2¢ aC 4A 5c 6.8 7.8 ac 9.8 10.0 122A 13.8 14.8 9 15.A 9 16.C 17.0 28.C) 19.B 20.6 22.C 23.8 24A 25.A 26.6 32A 33D 340 35.C 36.6 42.0 43.0 44.0 45D 46. 52.8 53.A 54D SSD 5S6A 28.C 829.0 30.8 38D 8639.8 40.8 48.4 49.0 50.8 588 59.C | GOA 62.A 63D 64A G65.A 66.8 67.C 68.8 69.A 70.A 72.8 73.C 740 75.C 76.0 82.C 83D 84.C 8685.8 8B.C 72D 79.8 B.A 88.A 898 90.8 | Answer Ex-ll | OBJECTIVE PROBLEMS (JEE ADVANCED) 2 = >neno9 >> wc 2A 3A S.A 6A TA Bc 10.¢ 11. A.C 12. A,B,C,D 13..A,8,C,0 15. A, B,D 16. A, B,C,D 17.A,C,0 48.4,8,C,D 20. A,C 21.8,C,0 22.4,8,0 23.8 25.B,C 26. A,B,C 27.4,8,0 28.8;0 30. A,B,C 31.8 32. A,B,C 33.0 35.A,C 36. 37.8.0 38.8,C,0 40.0 ana 42AB 43.8,0 45.A,D 46.4,8,0 47.40 48.A,B,0 50.A 51.B,C,D 52.4,8,C,D 53.B,C 55.8,C 56.8.€ 57.B,C,0 58. A,B,C 60.8,C,0 61.8, 62.48 63. A,B,C 65. A.B,C 66. A, 67.A,C 68. A,8,C,D 70. A,B,C 7LAB.C 72 ACD 73.B,D 75. A,B,C 76.AB,C 77.48 78. ABC 80. A 81.A,8,0 82. ABC 83.B,C 85.8,C,0 A-Q, BR, C+S, D-P BB. A-QR, B-PQRS, C-QS, D-PQRS 91. 0 4. 8Answer Ex- OBJECTIVE PROBLEMS (JEE ADVANCED) 1.8 2D 3.8 aA 5.8 6A 7A 8.8 9.8 10.4 o=N-0 a a B.A. = 180°, oeN=0 B.A. = 120° B—Neo sp? bent B.A.<120°, = NO," >NO, > NO,- 12 (a) H, B.O.=1 (ob) Hy BO.=05 (c) He, B. (@) BO.=1 (e) Be, B.0.=0 () B, 13. Her, B.0.=0.5 He, B.0.=0 14 0; «16. NO? oA? 23 23. 76.82% 24, 4.1652 x 10°" coulomb metre 25. 2.514K 26. 3.504, 6.064, 7.0K 27.85.32% 28.1.4A 29.84.35% 30. 25% [ EXERCISE - IV I PREVIOUS YEARS PROBLEMS ] 1 8 2. 3.8 4.8 5.8 6A 7A 8. 8 9B 10.4 11.0 12.C 13.8 14.0 15. DO 16.C, 17.8 18.c 19.0 20.4 21.¢ 22 060 23.4 24.8 25.0 26.8 27. Asin HCOO- Na" > all resonating structure are equivalent = so all bond lenth will be equ: ‘ gt ae, oe HH 'H rer Ny Ns, 2. PIF 30, UF uc According to fajan I> > F- (polarisibitty) = UF>LF (ionic character) 31. a Be has vacant orbital as electrophilic centre in it il) H,CrO, == CrO, OO Gromic™ Sreimic acid anhydrideoEroy 32. (Intramolecular H-bond which reduces B.P.) 33. F, 0,>0, He boc | 25, Ear YX = No of bond pair-lone pair repulsion =8 ° Oo coe ay ote Ans. (C)‘Sol? Q ° t ontizo _/N, N 367% G7 DS sp’ sp’ 180° = Bent (NO,*>NO-3>NO,-) (ASCP. 1, BA. + Ans. (C) y (a) ey ye V7 ® NY 7 < (3¢—2e") >< () 3C-2e) ae > (0) (Gc-28) Ans. (C) Sol. (A) Fe i Is : longer than {ero rOe © ror (equal length) W Sh canis (0) 7 SH 4 ans. B + HO 1s polar molecule Soh 10 = nce: H,0 has higher critical temp Ans. (D) ‘S014 K*O5 (0 contain one unpaired electron So paramagnetic Alo; = 308 = 10 Unpaired & OF 3182 sdia =Nounpaired = NO; 324 & =dimagnetic =o unpaired = ‘Ans. (A) 1 cl 1 Sol.12(A) 8) i © ©) 4 120° Hres=0 (20) Ec = Ahas max. Ans. A &-bond nS (4 Lobe Intraction) f _ area ny are = nonodal plane ans B Sol.14 for maximum ionic character, TE of cation must be less * EA of anion must be larger =CSand F =()SohiS cy > *C- Cae = a- bond = 2 a-bond = 2 Ans. A ‘Sol.26 (A) he SP} = Terahedral ° (8) of ‘SP? = Terahedral ° ror (c) ror SP3d? — Square Planer I (0) 474 \ySP2 = Terahedral 4 ans (C) Sol.17(A) (D)H—Cac—H (Sp) Unear o 0 9 i sours Ff”) g7 Sb (olanar) Prarial so! ip F. peor NEN-N SH Ans. ¢ € ‘Sol.19 Ca qu o- bond = 1 - bond =2 ans 8 How * Hy waza ld neraae, ff Ad ” t SP ans. ¢ al sangp spd = T- shaped Sol.22 (A) N,8.0=3 B.Oustability Nj’ BO = 2.5, Correct Statement (8) _Op-2B.0=2 0; 38.0 = 2:5 = Correct Statement (Cy 8.0.0 = incorrect statement (0) NO*, BO.=3 NO, B.O=2.5 Correct statement an ‘S0l.23(A) KR, (8) x ( aASa = ,0>H,0>F, (excepts) As EN of surrounding atom t BA | (VSEPR theory) Ans (B) mmorere 5p Sp SP Ans. ASol25 Nec—c=n sp 3D = Unear Ans. A mt lo pon (He bray = due to intermolecular H-bond, higher b.p. than CHOCH, ans (C) it has 01.27 (1) HC—CH,—CH,—CH, n-butane (IL) OH, 0H,—CH, CH, OF ~ OHCH,CH.CH,CH, t ay) oierLon I>ms>v ‘As Hsbond>d Interaction st. chain>Branch chain Sol.28 }—F—-H—F CH 9—H-0-cH, " 1N,0, (no H-bond as no H) CH, (no H-bond as no bonds H) Ans. ¢ $01.29 0-0-1 —H-0-0-H HS + NO H-bond HrHo-H#— 6H HE pn, DOP OPH tas Sol.30 (OF) at ans. 8 ‘Sol.31(A) ana (only covalent) (8)H-O-O-H (only covalent) © a & (covalent and ionic) {D) HCN (ony covalent) Ans. S0l.32(A) NO (162) = paramagnetic (8) OF (186) = diamagnetic (© (CM) 148) = diamagnetic (D) CO (148) =\Giamagnetic ans. A ‘Sol338e, Bo-2 = 1/2 (2-2)=0 ans. 0 ": Solsa (0-H = spz i min cen 2C-2e Bond = 4 3C-2e Bond=2 Ans. B$01.38 MgCO, > CaCO, > SrCO, > most stable least stable = BaCO, - Ba0+ C0, = 25 of cation * TS. b Kp T Sol.39 (A)HOH 9H 4 \H (8) (ner ceeuar ‘benemg) (C) EF 9° Il (D) CH-C—OH HO- FH, ° Ans. 8 ‘Sol.40 Strength of H-bond «polarity of H-atom EN of patom attach to the H-atom ans. 8 Sola. ANF of No (Covalent & coordinate) ans D NH,+3HOC! a, corps Ho —+ Ns L ot SH >» H+C1,B0H Way? B(OH), +3HC1 > » +H,0° san ght? Of Ae F + H oy +H,0— ate sed ans. ¢ sosse2ot ta tart? 2g? 1s, 1s, 2s, 2s, 2py, 2pz, 2px = € is removed from a - orbital ‘Sol.47 s aH 4 of aer ‘Ans. Asolubility, pare t 'Na,SO, 10H0, 8 ‘Sol.S2 ans 1 Sol.53 80 » —Tenagh & bond energy Sol A $01.54(A)NO_>NO. 3,0=2.58.0.=3 (Para) (ia) (8) 0; +0, unpaired e =1 BO-2.5 (Para) (On, of, (aia) (pana) (unpaired=2) 80-2 (Para) ans. H,B0,+H,0—>8(0H),+H" {no back Bond) on-F-OH OH (Back Bond) -2 B-0 Bond length changes (8) HOy+H,0 .»2H*+S0,7- (No Change in B.1.) (C) HNOs#H,0-+ NO, +H,0* frochergenBL) Ans. D ‘Sol.56 Hybridization is process of mixing of atomic orbital of nearly equal energy ans. A ‘Sol.55 (A) ‘Sol.57 more s~character less will be long piece = leser will be size Ans. A q be SoLse Peis _iK, (Tetranedra! cl 7 Or . icin see sam Pa, spd c al CPT C! 89°4 Trigonal bl pyramidal a ans. 8 320 Sol.s9 =o » S0l.60 = more 5, more EN of ¢ Ans. A Sol.61P-P>P-S>S-S (more directional character) = more overiap = more stability ans. B Mc. /GN ‘Sol.62 = nec” Now o-bond = 9 -bond=9, Anse A 'S0l.63 due'to H-bond, HF ‘has Low volatility ans. D r Sol.64 % ‘SP 3d? sq, Pyramidal F KAT Z|. $026? Pentagona! F r Pyramidal Sol.65 Polarity order C-Foc-O, Distance (Bond) C-Cl > C-F * Here as exception,distance factor is dominant CH,-Cl > CH,-F >CH. = oF >CHy-1 distance factor polarity a factor dominant. @ %sorQ 9 07% a (we0) 20 ans B a) 501.67 °% ionic character = | c5jc “100 uH-Cl = 1,03 D= 1.03x10-! esu. cm GH-Cl = 1.275A = 1.275x 10-18 0310" (4.8 «107 esu) «1.275210 217% 1 1 1 Soles weLSO a a %1C = 100 ci 1200" 120 a 1 = d.M. Of Cl at 120° will cancel each other = y=LsD Ans. B SOl.69A 9 ‘Sol.70 (1 SP2=33%S ‘ MAS F. 0 - cy) Pi me %S = 2100= 16% (ant 11-1 $044 2 + 100«20%S (vy) oka SP? = 25%S, (VY) —Be—c1 50%S. SP Ans. A Sol.71 (1) 's Pyramidal (11) NOs" Planer (ITT) BF; Planer (IY) ACH Pyramidal Qo () NENANS 4 ‘sostructural pair Il, It & and 1, 1V Ans. C Sol72 8 ‘$01.73 H-bond holds two ice cubes together Ans. ¢ Soh.74.03- 8.0. =3 of FBS LY ans. con 7" eS SATS ac. Son SP Sp ~ SP and SP? hybridized ans. C F F LF est FY Sue TN “TS rh F see saw tetrahedral Square planer LP=t LP=0 LPa ans D S01.77C1,> Br,> F,> I, Very less due to interelectronic repulsion due to small 2p orbital. Ans. 8rOe © PBS (0) CIF, all B.Lequal — SP'd Sot.so @=n Ans. A Sol.81 PH, 291° NH, ~107° (Drago’s rule in PH) Ans, A 4 ‘Sol.s2 @_12 ‘Sol.BS Hyper valent = voilating octet rule a? ‘a (e) A, (Hyper) (n0) 6. j 5 i an i) vt ° ~O (Hyper) (no) 1, Bare Hyper valent Ans. & %6 S86 07H, = due presence of bulky group B.A exceeds from 109° also and reaches 1109 => Hyb = SP? ans san SC ethone ethene H—-C=C—-H acetylene cH. —ch,>cH,-EH>cHa (stability free radical) “- Ans. D * to Loy, 2 orton, Keto (eno!) -bond=9 bond=1 tp=2 Ans. A Le Ne * OK I t SP3¢ P32 Ans. ‘Sol.90 According fajan’s rule Ans. BSoli 4.2742=0.1 mole 0.1Nx16{(valence electron of N")=1.6N ans C ° ° Sol.2 N2°0— peeps Ne ° ° ° ans. A SOB ols?,a* 1s’, 025",0° 25? 22,7 = 22D? 1920, = unpaired e=1 Ans. A Sol4 As B has a vacant orbital and Behas two vacant orbital ans, 8 salicyladehyde Ans. A Sol.6 Bases are connected by H-bond Ans. A Sol.? The central atom of PCI, have vacant d orbital therefore represent extended covalent bonding while in NCI, N have no vacant d orbital Ans. A OBJECTIVE PROBLEMS (JEE ADVANCED) ‘SOLS (C-Cl) bond in CH, =CH-Cl have partial double bond charcter same type partial double bond character present in chloro benzene Ans. ¢ Sol.9 (A) F-Be-F Linear 1 1 ‘Trigonal planar (8) (C) NH, THgonalpyramidal cf (D) ‘T-shapal Q a g 9 g I 10.0%i39 wee oo oS 2" SP 14, (A) C-Hg- c1(8) oa bent linear 0 CHeCH () Linear (0) oT sé Bent Ans. AC ¢ < O=C=0 12 (a) =” o sod 2 (8) 1-1-1, .y/H9-Cl spa sD linear linear8. unear beg gz 9 Oo 9o (0) "Bent Bent sp 0 .=2.5 (B) B.O.=1.5 OBR s2E 0 : Ge Na “ a agra 4a ‘Square plane no i ) Ay neo ch a org"? a5. (A) ® & spb T-shape planar (Planer) 4, P onreee © 6 (D) 3 sp} Tetrahedrat plane fron planar = Ans.:A,8,D 16. 4 N, F I we nH” a 1 F Ans.:A,C,D 4 a 18. Jonic and covalent both Ke -CeNn ionic and covalent both (c) a ae wm Beis { ><] 4 csi Le onic bond solo7. Ho’ OH (equivalent R.S.) (non equivalent R.S.) + AIBLL. equal = not all 8.L. equal i H-C-O-H (8) non equivalent R.S. all B.L. not equal ‘=o nS equivalent of R.S. alll B.L. equal nt (WNC 21. 22, ABD ° a 4-0-8 wa. Anos, eo 6 Oo ans.:B 24, Ans.:A,B (25. Consider Fajan rule Ans. : B,C 03°(148) gy NO“ (14€) (cy CREA) 26.) 2 BOs Oaa-3 Sonos; (o) CNI28) BO-2 Ans. A, BC 27... (A) Perioxideion (02) Oxygen(O2) Bo-1 ao-2 (8) 8.0. « ar = Peroxide has weaker bond compound to 0, (C) 03° (188) oncise) Gamagnatic Paramagnetic (0) correct Ans. : A, B,D 2. Ny co cN NOT (ase) (i4e) (He) 4) + t . + Diarnagnetic ‘Diamagnetic Diamagnetic Diamagnetic NaN Tso CaN N=O" (v=0) w#O ue He Unear Linear Unear Linear Ans. : B,D29. 31. 32. (A) 0} + toal = = 15 > Paramagnetic = Contain unpaird electron (B) 05 Toal @ = 17> paramagnetic = contain unpaired electron (C) No totale = 15> paramagnetic contain unparied & Ans.: A,B, C,D ff 0-51 WA \. a t é% (8) AlN} o=p-01 4 . no othe! d < i] S. Sve (5707S. o 0 S01 Yo (0) o ore ok. 7 Ans.: A,B,C XeF,—+XeFs + £ spe? Ans. > (B) # ~, A) ic mA 4 . a ‘no rotation \ (no rotation) (C) HC = CH (no rotation) 4 1 net Ru Ha (Rotation possible) Ans.: A,B,C Ans.:0 HH Ne a) WN no x-x Bond 4 HH Z =H ) ¥7 t “a (x-x bond exist) 4 Os (x-x bond) 4, H Nee” (0 y7F PN hw Ans. 3 AC XeF, = Square planer aa] (a) [2g] (8) Jl sp’? Planar (shape) | Or © i (0) JIS sp'é' Planar eae Ans. + A,C6 Partial double will occur due to Back Bonding Q (a) aS (no Back Bond) iPr (no Back Bond) F | c lr ®) 7 F F (C) FP . (Back bond from LP. of F “hy to vacant orbital of P) jouble bond character (>) ¥ mo back bond c 7 aN VY Hel “4 iM a4 ) " 107° no hybridisation mn (drago’s Rule) se 104° (all angle 90%) A 2 @)wet-o sp’ v-shape o-N-0 (s=c=s (linear (sp) linear Bcd XP In ye N ON av a = ” a ° WY nd bon so} (© 9 % = 1/3 « 100 33,33% ‘% p = 2/3 x 100 = 66.66% = unequallP-cnarater, (0) consider VBT theory ABD WS ee" C=C#CeCc Prereeg v=o odd no. of double bonds = Planer = Ans-D a 9 k io 0" oO g i ot 62> ty 129° a sp pyramidal ae sp planar Be sp planar Re sp’ planar 40e Ans. AQ a aa a2. Ps (wyramidsl) 2 -) Q B “ ot No- (8) “i 4 so x Pyramidal (pyramidal) e H Is © PA 0) Wn w sf planar perer Ans. AB 43. nH, "iin, (A) sp? sp3 = No charige in hybridisation (ey MMs“ al, spt sp — Hydridisation charge (ht, a sp = No charge in hybridisation F F f, Ni A ©) ¥ \y—— F 4 . sp spd © Hybridisation is changing, Ans. B,D "e F F 2 4s. a7. (a)o=C=0 linear, sp 5 ) Me coe o Ee Bent Bent (D)Cl-Be-1 + sp linear = Ans. B,C 1 S-1 spd, linear YE or” \, sp? Bent. 9 ky (C) of sp? ent O ca i sd linear AD (Consider VBT theory) ABD BaO < MgO (Covient character) = Ba > Mgo (onic Character) for mono atomic anion, Thermal stability x lattice Energy = MgO > Ba0 (Le) = M90 > Ba0 (Mp) SAD49, BE si. 52. nF Extent of polarisation of anion « —__ size of cation = extent of the charge on cation Ans. A, B,D © size of anion iselectronic -+ having same e~ CO, = 22 € (AN > 22e (8) CNO" > 22e° (C) (NCN*) => 22 (0) NO,” > 24 e ABC % S-character x B.A + strength x Size of orbital a B.C, AB,C,D ac cH, ST co, 4 4 sp sp a (A)O=C=0 (octet only obeyed) i ca does not follow octet rule (8) (c) crt, does not follow octet rule F l f (0) AY follow octet rule 61. BE +» Adoes not conduct electricity in aq. molten or solid = it must be non polar covalent comp, = _B only conduct electricity on fused form or in ag. solution hence it must be fone. = _C only conduct electricity in aq. solution hence B.C,0 H. Ho H Si yh SA Sa (3c - 2e bond exist) CH, ad Nic @) cH SoH Scr, (3c - 2e-bond exist) CH; CHy IN Be Be Be wo” Naz SHON (3c - 2e bond exist) va cl ee N Be” N“ Be ()% a7 N78 (3c - 2e bond absent) ABC cD 8C.D F IB ME no. of LP. = 3 IS w ©Oe (8) P&S no, of LLP. = 2 © oe no, of LP. = 2 i ) SC roof LR=0 © AG Ans. B,C Na rN (12 e° around Br) = octel rule not obeyed ef F Nv () | IS spdz (12 e* around s) = Octel rule not obeyed 7 of ase) = octet rule not followed Ans. A,B,C 64. (A) does not exists because d-orbitals cannot participate (8) ? x /fzo Ho” So (F cant expand its octet because no d-orbital) Combination of strong oxidizing and strong reducing agent does not exist. Ans, ABC V) N 6s. 0 (KX He) XA © Yo wo Y Fo Oe Se Ans. A,B,C 66. Inert pair effect is shown by Bi an pb Ans. A.C 67. Ph? = [Xe]aris, Sd, 6s?, 6p? = (18+ 2).e° system ‘Similarly Ca?* will have the same system ans. AC 68 (A)He-H> H,- Ge) Ge) 0," No ® ase) ase) (C) Hes (3e-) U,* (Se-) 1s?,a*, 1s! ais?, o*1s?, a2s! > same unpair e- = same magnetic moment. () N5Ca3e) Ny B.0=2.5 8.0.2.5 (1S e-) i,-0 "1S, 025?,0*282, n2py?, 2p22, adpx! > umpairede =1 unpaired e- = 1 Ans. A,8,C,0 Oo Oo 69. MW (A) HO-5- 0-0-5 —on o °mn aca 7 & C . . (b) oo wou (8) HO — 5) — 5 — On oo oo nou () Ho-~s—s—on oo nu (0) Ho — 5 ° 8.0 ABC AB ° " o. P No7 INO oo =H will add it self where. "is Resonance stabilised only > "Ans. A,C,D Bo ° H-bond), " 1 P—OH ~ PN ~ | ~~ OH vo” | 07! Tonic In solid state, Baric acid Individual units Blonl, hydrogen Bonded together in totwo dimensional sheet. © 4 ° on " 1 O-baped H-bond (Hy -0------------- H-0-cHy 1 4 H H-bond ) (D) N-O pe Intra H-bond (A) _G lle (8) 02- (18 e) (c) u, (6e) (0) N° lje = diamagnetic = Diamagnetic = Diamagnetic = paramagneticBi. onsi4 ans ABC 77. 8, =paramagnetic ols, * 152, 0287, 0 * 257 (10e) (©) 0, >Paramagnetic *2yy, prs our ¥apys ® apn (6) = els removed from BMO (©) Ny > Diamagnetic @ oa ase) (0) He, > Diamagnetic als? o* 152, 0282.0 * 25%, apr? (er) . = 252 an. AB s2py?, x2pz", x* 2py!, x * 2p2' > eis removed from ABMO x 2pz 78. = (A)CO B.0.=3 ase) (C) e* will add in ABMO (d) e° will add in BMO- (B)CN- BO. 3 ans. 080 ase) (NOt BO.=3 (ae) a] (0)0,° BO ase) aye! 7. of a2 ay 2 linear igs ig O2ts Oa, Sap, py = spd Raat Bays Bap => unpairede- = 1 I 0," >"Unpaired & = 1 ow = NO = 15 = similar to 0,* ¢ = unpaired e =1 Ane ABC oe] spd, linear linear 8 . sod @) (8) (c) NEN? sp linear © Q (0) V (D) ( oe smear Ans, AC Ans ABCrie, nn. "aN, capped octahedral or distorted octahedral * Q Al c we (A) wn (8) wise sp’ sp’ Y? © 85 o,f” x Ans. AB,C,D “wet = 5 ss. 4) O Bent ® HSIZ=N=C=S Linear due to Back bond H,Ge N NeCc=S (© pent as no effective Back Band due to large size of Ge g (©) sing’ L>sits pyramidal Ans. B,C,D Match the column NO-ING-4 86.(A) ova AN, sp'd’ Jy = Ans. A+R B4P C45 DQ hy! AD 87.(A) os Na sp’d s'd’ planar planar a 1 ) Gara OK sp? planar ‘sp? nonplanar (€) AIF, ag dimer form ew P po oe o sp’ Planar sp’ Planar ans £3 B>RC>S, DPspd’ (4, 2nd by.) spd (TBP then dy») dsp'(de.4) A+QR B+ PQRs c3+Qs D> PQRS comprehensions Passage 1 cy Hh © © 4 Ans. A 90. density up to 4°C then decreases sharply Ans. A 91. (A) HO 1,0 (A6 greater no. of H « bond occuring (BP. order) inH,0 ® * —OH — CH,—OH cH,-OH = CH—OH 4, — OH Ethylene glycol = more no. of H-bond Less no of H- bond = Hence glycerol is more viscous than ethylene glycol. wo N10 © => due to Intramolecular H-bond exist = discrete form steam volatile (0) Not equi distant Ans. 0 Passage-2 92, PBr, ——» PB, +B anionic part Ans. D e\ \ 3 ‘93. PCL —+> PO, + PCI, s 5 Pc, + PC, ° PGr, ——+ PBr, + Br 109° 28° 109° 28° => difference in B.A. = 0 ans. 94, PCL PCL + PC, spd? 90°, 180° Ans. B Passage-3 ans.95 8 96. sp'd?(Ga_28nd dy ) Ans. B ans.97 ©I 1 spi trigonal planer. “~ 1 2. bond length * Song order © < CO, < CO, SCr—O Bond equal due to reso- nance effect. a B qe cr “ angular = peo Ans. A 5. ASE.N. of central atom f BAT Ans. B Ans.6 A 7. H,O due to H-bond has highest b.p. Ans. A 4 i 2 oNN wy o8 " se 13. 14, (pec 2 is of 3* transition series = all ligand will be strong field ligand ans. [ Exercise — IN [ OBJECTIVE PROBLEMS (JEE ADVANCED) F = typ = dsp Originally maT 11 In this compound due to SFL. mit) O OT asp Non o TL) B.A. = 180° odigo cM ge Se of one -” so wv ? 0,- $40, > no," (@) H, BO=L (b) H," BO. =0:! (c) He, B.0.=0 (@) U, BO.=1 (e) Be, = B.0.=0 (f) 8 BOT we He, o, °F oO, oF 80-1 = 8.0. bond strength 9,15. 16. 17. 18. (CO) 3, o* 03,7 = yas hy (NO) as 0%. a2) Oa = Mae Sat aoe (¢) drawlike n<14 (0) HCI draw liken > 14 NO B0.=25 NO BO.=3 NO” B.0.=25 NO 8.0.=2 >= B00 gr No GN Total e = 13 Paramagnetic (odd €-) CN total e~ = 14 even no. of e- = diamagnetice NH 80.=25 CN 8.0.=3 CN > CN (Stability) As the E.N. of of central. f es B.A alsorf ea. AS CCl,sis covalent not ionic SREB > Back bond from L.P. of N to vacant d of Si = HybofN > sp’ = planer Since in (SiH,),N the L.P. is delocalised => hence less availability of long pair. => Less basicity % LC. = 18.08, y=1.080 w= 1,08 x 10" esu cm 1.964 «10 «100 82107 1.596210" 4.810 1,596 «10 Similar to above question 2.5144 %LC. = use the formula of calctilation of Ionic char- acter bic iia 100 LC. = Fer 10 osu n1.94 xi d=1K = 10% cm yw =1,2D=1.2%10"esuem op fraction of charge = or 2 waaxd 1.210" esucm=9x10" an. = q=1.2«10"%cm[ EXERcIsE - IV I PREVIOUS YEARS PROBLEMS Levet JEE MAIN be 8 hybndised te BF,- = Tetrahedral wen (i) SF, square pyramidal HH (ili) square planar ve Chas 4 Bond pair hence sp’ hybridisation c If attractive force greater than repulsive force than potential energy lower hence ‘chemical bond formation take place 8 In squar planar complex dsp’ (s, P., P,. and ,,_,, orbital participate) 8 8 NO, and 0, have unsymmetrical neature therefore have permanent dipole moment. a (A) XeF, and CO, linear shaped (B) BF, trigonal planar Pci, Pyramidal (C) PF,Tgonal bipyramidal IF, square py- ramidal (D) CF,, Tetrahedral SF, square pyramidal H,S= 90° NH,= 107° BF,= 120° ‘SiHt,=109'28' Hence H,S0=0>0-C>F-F SCaSO,>MgSO,>BeSO, $f cation f thermal stability 4[ Exercise-1V [ ADVANCED SUBJECTIVE QUESTIONS i Bo 5 planar ‘Ans. 6. i HL yO HU Ke In molecular plane a N14 e- = unpaired e=0 (®) F,> 18e = no (©) 0- > 17e = paired e (©) 07 = c f () ° ao N pyramidal ae a Tor so plana 32e abe A 0," B.0.= 2.5 1Se" > paramagnetic unpaired e contain un- alle paired ‘ C, 5G se planar Be 10. 11. 12, » 3 > (A) 0, 18e- > diamagnetic (8) 0,24e- > diamagnetic (©) NO > 22e > diamagnetic ©) 0, = 17e = paramagnetic > co + BO.=3 We ‘The Speciés other then having 14 e- will have diff, 8.0, a i ra o sp’ tetrahedral PYramidal nonplanar 3° © Intramolecular H-bond reduces B.P. H- cope Inter molecular H-bond increases Boiling pointAns. 3. Ans. 14. 16. HO 9 4 1H eo H,BO, +H,0 B(OH), +H" lewis base | from water = H,B0, is not proton donor ¢ heavier members of 14% group show sta- bility in lower oxidation state due to inert pair effect of s-orbital electrons. A> PQRT B» QR,S,T C+ BQR D+ ROARS (A) O+ NaN (8) O=-N—O-N=O oo © t O=N—-N=O ON —0-N-0 0) ry 1 ° ABC reaction will be 1° and 2° amine only Bc 9 af 4 1 () of) Planar T-shaped z 0 u \ Si vs Planar 19. als?, o*1s?, a2s%, ae?25, 3*2py, «20x u w2pz = diamagnetic as no unpaired electron B.O. = 1/2[6- 4] =1 Sol.20 A-p,8 B-pa,rt C-p.q D-p Sol.21 8 q H,=C=CH, ra SP sp Due to LP-BP repulsion the bond angle de- creases, axial angle no longer remains 90°. Other angles also suffer distortion. ‘Sol.27 (3) 2n + 2x3 + 6x (4) + 18(-2)=0 Qn=6n=3 He04, HyPOs, COs, #5207, HyCr0. Hisotarg anggotg 2 "25207" MarOw ‘Sol29, (2) FandNa Sol30B Sol.31B Sol32.D